Nonaqueous Liquid Patents (Class 510/304)
  • Patent number: 6503876
    Abstract: This invention relates to laundry detergent products, such as heavy duty aqueous and/or non-aqueous and/or gelled liquid laundry detergents and granular and/or powder laundry detergents, which include one or more low density particles and one or more particulate solids, such as enzymes, bleaching agents, builders, chelants, alkalinity sources, anti-redeposition agents, catalysts, surfactants, and other detergent ingredients, and optionally one or more conventional cleaning adjunct materials.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: January 7, 2003
    Assignee: The Procter & Gamble Company
    Inventor: Walter August Maria Broeckx
  • Patent number: 6495502
    Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide, preferably held at 25° C. or less.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: December 17, 2002
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
  • Patent number: 6489282
    Abstract: The present invention relates to a bleaching composition comprising a peroxy carboxylic acid and a polymer system. The compositions are suitable to deliver improved bleaching performance whilst also being safe to colour and fabric. Furthermore, the compositions herein are also chemically and physically stable upon prolonged periods of storage time.
    Type: Grant
    Filed: May 7, 2001
    Date of Patent: December 3, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Gloria Di Capua, Pierre Antoine Dresco, Stefano Scialla
  • Patent number: 6479447
    Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: November 12, 2002
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
  • Publication number: 20020155967
    Abstract: There is provided a liquid nonaqueous detergent composition comprising an alcohol alkoxylate nonionic surfactant and a bleach precursor having a Krafft point of at least 10° C., said surfactant and said precursor being present in a molar ratio of nonionic surfactant to bleach precursor of at least 2:1.
    Type: Application
    Filed: December 22, 1998
    Publication date: October 24, 2002
    Inventors: STEVEN JOZEF LOUIS COOSEMANS, AXEL MEYER, JEAN-POL BOUTIQUE, JAMES PYOTT JOHNSTON
  • Patent number: 6462008
    Abstract: Detergent compositions comprising photobleach delivery systems, processes for preparing them, and their methods of use, the compositions combine selected hydrophobic photobleaches, especially based on Si(IV) phthalocyanines, with selected axial ligands, with certain water-soluble polymers, nonbonded ligands, detersuve surfactants, especially certain mid-chain branched types, and non-surfactant detersive adjuncts.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: October 8, 2002
    Assignee: Case Western Reserve University
    Inventors: Rafael Ortiz, David Johnathan Kitko, Michael Eugene Burns, Stephen Wayne Heinzman, Alan David Willey, Brian Jeffreys, James Charles Theophile Roger Burckett-St. Laurent, Phillip Kyle Vinson, Trace Wendell de Guzman Trajano
  • Patent number: 6455485
    Abstract: There is provided a liquid nonaqueous detergent composition comprising an alcohol alkoxylate nonionic surfactant and a bleach precursor having a Krafft point of at least 10° C., said surfactant and said precursor being present in a molar ratio of nonionic surfactant to bleach precursor of at least 2:1.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: September 24, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Steven Jozef Louis Coosemans, Axel Meyer, Jean-Pol Boutique, James Pyott Johnston
  • Patent number: 6399557
    Abstract: Laundry or cleaning composition comprising: (a) an effective amount, preferably from about 0.0001% to about 99.9%, more typically from about 0.1% to about 25%, of a bleach activator and/or organic percarboxylic acid; (b) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (c) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic percarboxylic acids.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: June 4, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent, Michael Eugene Burns
  • Patent number: 6384008
    Abstract: Non-aqueous, particulate-containing heavy duty liquid laundry detergent compositions that are in the form of a stable suspension of particulate material, essentially including from about 0.1% to about 10%, by weight of the detergent composition of an ethoxylated quaternized amine clay material. These compositions preferably include a peroxygen bleaching agent and an organic detergent builder, dispersed in a liquid phase preferably structured with a surfactant. Such compositions provide especially desirable cleaning and bleaching of fabrics laundered therewith and also exhibit especially desirable aesthetics.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: May 7, 2002
    Assignee: The Procter & Gamble Company
    Inventor: Diane Parry
  • Patent number: 6376447
    Abstract: Disclosed is a nonaqueous liquid detergent composition comprising an enzyme particle, said composition having an average particle size of the enzyme particle of less than 600 microns.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: April 23, 2002
    Assignee: Procter & Gamble Company
    Inventors: Jean-Pol Boutique, Axel Meyer, Lorenzo Matteo Pierre Gualco, James Pyott Johnston, Jean Wevers, Iwein Jozef Maria Jaak Goderis
  • Patent number: 6372703
    Abstract: A liquid non-aqueous detergent is presented containing a nonionic surfactant, a builder, a bleaching agent, and a cationic stabilizer of formula I, II or III: where the groups R1 independently of one another are C1-6 alkyl, alkenyl or hydroxyalkyl groups, the groups R2 independently of one another are C8-28 alkyl or alkenyl groups, R3 has the same meaning as R1 or represents (CH2)n—T—R2, R4 has the same meaning as R1 or R2 or represents (CH2)n—T—R2, T represents —CH2—, —O—CO— or —CO—O— and n is an integer of from 0 to 5. The solid bleaching agents in the stabilized non-aqueous liquid detergent retain their activity after prolonged storage.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: April 16, 2002
    Assignee: Henkel Komanditgesellschaft auf Aktien
    Inventors: Bernd Richter, Ulrich Pegelow
  • Patent number: 6348441
    Abstract: Disclosed is a method of laundering soiled fabrics comprising the steps of contacting said fabric in an aqueous laundering solution with a nonaqueous liquid detergent composition containing from about 40% to about 99% by weight of the composition of a surfactant-containing non-aqueous liquid phase and from about 1% to about 50% by weight of the composition of particulate material which is substantially insoluble in said liquid phase and which is selected from peroxygen bleaching agents, bleach activators, organic detergent builders, inorganic alkalinity sources and combinations thereof. A dye transfer inhibitor and suds suppressors are essential components in one aspect of the present invention.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: February 19, 2002
    Assignee: The Procter & Gamble Company
    Inventors: John Davis Aiken, III, Murali Sampath, Ronald Allen Swift, II
  • Patent number: 6306812
    Abstract: Laundry or cleaning composition comprising: a) an effective amount of a bleach activator and/or organic percarboxylic acid; b) a catalytically effective amount of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and c) at least about 0.1% of one or more laundry or cleaning adjunct materials. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic perearboxylic acids.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: October 23, 2001
    Assignee: Procter & Gamble Company, The
    Inventors: Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent, Michael Eugene Burns
  • Patent number: 6281187
    Abstract: Disclosed are non-aqueous, particulate-containing liquid laundry detergent compositions which are in the form of a suspension of particulate material, essentially including colored speckles and preferably including peroxygen bleaching agent and an organic detergent builder, dispersed in a liquid phase preferably structured with a surfactant. Such compositions provide especially desirable cleaning and bleaching of fabrics laundered therewith and also exhibit especially desirable aesthetics.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: August 28, 2001
    Assignee: The Procter & Gamble Company
    Inventor: Mark Allen Smerznak
  • Patent number: 6187739
    Abstract: A paste-form detergent composition containing (A) 20% to 58% by weight of a liquid surfactant component consisting primarily of a nonionic surfactant, (B) 2% to 40% by weight of solid builders, and (C) 2% to 40% by weight of a solid bleaching component consisting of a peroxygen-containing oxidizing agent and a bleach activator, based on the weight of the composition.
    Type: Grant
    Filed: March 20, 1998
    Date of Patent: February 13, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Merz, Khalil Shamayeli, Guenther Amberg, Heinz-Manfred Wilsberg
  • Patent number: 6165959
    Abstract: A nonaqueous liquid detergent composition comprising a bleach precursor composition comprising: a) a bleach precursor; and b) a surfactant system; and c) an organic acid.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: December 26, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Axel Meyer, Steven Jozef Louis Coosemans, Jean-Pol Boutique, James Pyott Johnston
  • Patent number: 6159922
    Abstract: Bleach compositions comprising a percarbonate bleach and an amino tricarboxylic acid exhibit a reduced tendency to deposit calcium carbonate insolubles on substrates being bleached. Laundry compositions comprising percarbonate bleach and methyl glycine diacetic acid are provided.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: December 12, 2000
    Assignee: The Procter & Gamble Company
    Inventor: Fiona Susan (Mac Beath) Williams
  • Patent number: 6015504
    Abstract: The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fiber material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: January 18, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Claude Eckhardt, Robert Hochberg, Werner Kaufmann, Georges Metzger
  • Patent number: 5965505
    Abstract: There is a provided a detergent composition containing: (a) a heavy metal ion sequestrant; and (b) an organic peroxyacid bleaching system wherein a means is provided for delaying the release to a wash solution of said peroxyacid bleach relative to the release of said heavy metal ion sequestrant. Preferably said composition additionally contains (c) a water soluble builder wherein a means is provided for delaying the release to a wash solution of said peroxyacid bleach relative to the release of said water soluble builder. A pretreat wash method is also provided.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: October 12, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Janice Jeffrey, John Scott Park, Barry Stoddart
  • Patent number: 5916481
    Abstract: Low hue photobleaching compositions comprising organosilicon(IV) phthalocyanine and naphthalocyanines having Q-band absorption maxima at wavelengths greater than 660 nm and increased triplet state yields whereby production of singlet oxygen is increased. Use of Si.sup.4+ phthalocyanine and naphthalocyanines compounds in photobleaching compositions allows for formulation of low hue laundry compositions, bleach compositions, and hard surface cleaners.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: June 29, 1999
    Assignee: The Procter & Gamble Company
    Inventor: Alan David Willey
  • Patent number: 5846927
    Abstract: The present invention relates to improved matrix or core shell enzyme capsule compositions comprising certain density modifying solids and defined core structural ingredients. Using these capsule compositions, much better active stability is obtained. In addition, higher active retention is accomplished during capsule formation. Release characteristics are not compromised. In a second embodiment of the invention, the invention relates to structured heavy duty liquid compositions comprising these capsules.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: December 8, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventor: Tirucherai Varahan Vasudevan
  • Patent number: 5814592
    Abstract: Disclosed are non-aqueous, particulate-containing liquid laundry detergent compositions which are in the form of a suspension of particulate material, preferably including peroxygen bleaching agent and an organic detergent builder, dispersed in a liquid phase structured with a surfactant and elasticized with finely divided particulate material such as silica or titanium dioxide. Such compositions provide especially desirable cleaning and bleaching of fabrics laundered therewith and also exhibit especially desirable pourability and chemical and phase stability.
    Type: Grant
    Filed: June 24, 1997
    Date of Patent: September 29, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Jay I. Kahn, Mark A. Smerznak, Axel Meyer, Angela L. Garland, Vincent J. Becks, Jean-Pol Boutique
  • Patent number: 5763382
    Abstract: A cold water washing formula and a method of reducing the soil load on a textile by introducing the textile and cold water into an internal assembly within a washing machine. The method includes a first break wash wherein the textile, water, and a solvent are introduced into the washing machine to initiate soil removal. In a second break wash, a surfactant and an alkali are added to the first break wash to continue the washing cycle. The combined first and second break washes are drained from the internal assembly and the textile is rinsed with water. After draining the first rinse from the internal assembly, a second rinse including ozonated water and an acid is introduced into the internal assembly. The second rinse is drained from the internal assembly and a third rinse, which includes ozonated water, is introduced into the internal assembly to rinse the textile.
    Type: Grant
    Filed: January 3, 1996
    Date of Patent: June 9, 1998
    Assignee: Cyclo3pss Textile Systems, Inc.
    Inventors: Theodore R. Cooper, Allyson T. Toney, John B. McParlane
  • Patent number: 5759981
    Abstract: Treatment of textiles whereby the textiles are contacted with a medium comprising a bleach, anionic species and a neutralizing system for the anionic species, wherein the neutralizing system comprises quaternary ammonium compounds. The composition for textile treatment contains less than 10% by weight of water, and is essentially free of alkanolamines. The composition may further contain a metallo catalyst.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: June 2, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Jean-Pol Boutique, Mark William Glogowski, Frederick Edward Hardy, James Pyott Johnston, Regine Labeque, Bruce Prentiss Murch, Rajan Keshav Panandiker
  • Patent number: 5733341
    Abstract: A process is described for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula (1), (2), (3), (4), (5), (6), (7), (8), (9), (10), (11), (12), (13) or (14) as defined in the specification. The compounds of formula (1), (2), (3), (4), (5), (6), (8), (9) (10), (11), (12), (13) or (14) are new compounds. The compounds used do not exhaust at all on to cotton, polyamide or polyester fibers, so that the compounds cannot lead to fiber discoloration problems.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: March 31, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Claude Eckhardt, Dieter Reinehr, Georges Metzger
  • Patent number: 5714449
    Abstract: A non-aqueous liquid cleaning composition comprising a non-aqueous organic solvent, particles of solid material dispersed in the solvent and a dispersant, wherein the dispersant is a hydrophobically modified material.
    Type: Grant
    Filed: June 1, 1994
    Date of Patent: February 3, 1998
    Assignee: Unilever Patent Holdings B.V.
    Inventors: Cornelis Bernard Donker, Pieter Versluis
  • Patent number: 5652207
    Abstract: Novel bleaches, a method for bleaching substrates using these materials and detergent compositions containing same are reported. The bleaches are phosphinoyl imines. Substrates such as fabrics may be bleached in an aqueous solution containing the phosphinoyl imines and a peroxygen compound.
    Type: Grant
    Filed: August 12, 1996
    Date of Patent: July 29, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventor: Naresh Dhirajlal Ghatlia