Nonaqueous Liquid Patents (Class 510/304)
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Patent number: 6503876Abstract: This invention relates to laundry detergent products, such as heavy duty aqueous and/or non-aqueous and/or gelled liquid laundry detergents and granular and/or powder laundry detergents, which include one or more low density particles and one or more particulate solids, such as enzymes, bleaching agents, builders, chelants, alkalinity sources, anti-redeposition agents, catalysts, surfactants, and other detergent ingredients, and optionally one or more conventional cleaning adjunct materials.Type: GrantFiled: August 3, 2001Date of Patent: January 7, 2003Assignee: The Procter & Gamble CompanyInventor: Walter August Maria Broeckx
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Patent number: 6495502Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide, preferably held at 25° C. or less.Type: GrantFiled: December 20, 2000Date of Patent: December 17, 2002Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
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Patent number: 6489282Abstract: The present invention relates to a bleaching composition comprising a peroxy carboxylic acid and a polymer system. The compositions are suitable to deliver improved bleaching performance whilst also being safe to colour and fabric. Furthermore, the compositions herein are also chemically and physically stable upon prolonged periods of storage time.Type: GrantFiled: May 7, 2001Date of Patent: December 3, 2002Assignee: The Procter & Gamble CompanyInventors: Gloria Di Capua, Pierre Antoine Dresco, Stefano Scialla
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Patent number: 6479447Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide.Type: GrantFiled: December 20, 2000Date of Patent: November 12, 2002Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
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Publication number: 20020155967Abstract: There is provided a liquid nonaqueous detergent composition comprising an alcohol alkoxylate nonionic surfactant and a bleach precursor having a Krafft point of at least 10° C., said surfactant and said precursor being present in a molar ratio of nonionic surfactant to bleach precursor of at least 2:1.Type: ApplicationFiled: December 22, 1998Publication date: October 24, 2002Inventors: STEVEN JOZEF LOUIS COOSEMANS, AXEL MEYER, JEAN-POL BOUTIQUE, JAMES PYOTT JOHNSTON
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Patent number: 6462008Abstract: Detergent compositions comprising photobleach delivery systems, processes for preparing them, and their methods of use, the compositions combine selected hydrophobic photobleaches, especially based on Si(IV) phthalocyanines, with selected axial ligands, with certain water-soluble polymers, nonbonded ligands, detersuve surfactants, especially certain mid-chain branched types, and non-surfactant detersive adjuncts.Type: GrantFiled: December 21, 2001Date of Patent: October 8, 2002Assignee: Case Western Reserve UniversityInventors: Rafael Ortiz, David Johnathan Kitko, Michael Eugene Burns, Stephen Wayne Heinzman, Alan David Willey, Brian Jeffreys, James Charles Theophile Roger Burckett-St. Laurent, Phillip Kyle Vinson, Trace Wendell de Guzman Trajano
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Patent number: 6455485Abstract: There is provided a liquid nonaqueous detergent composition comprising an alcohol alkoxylate nonionic surfactant and a bleach precursor having a Krafft point of at least 10° C., said surfactant and said precursor being present in a molar ratio of nonionic surfactant to bleach precursor of at least 2:1.Type: GrantFiled: December 22, 1998Date of Patent: September 24, 2002Assignee: The Procter & Gamble CompanyInventors: Steven Jozef Louis Coosemans, Axel Meyer, Jean-Pol Boutique, James Pyott Johnston
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Patent number: 6399557Abstract: Laundry or cleaning composition comprising: (a) an effective amount, preferably from about 0.0001% to about 99.9%, more typically from about 0.1% to about 25%, of a bleach activator and/or organic percarboxylic acid; (b) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (c) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic percarboxylic acids.Type: GrantFiled: April 11, 2001Date of Patent: June 4, 2002Assignee: The Procter & Gamble CompanyInventors: Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent, Michael Eugene Burns
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Patent number: 6384008Abstract: Non-aqueous, particulate-containing heavy duty liquid laundry detergent compositions that are in the form of a stable suspension of particulate material, essentially including from about 0.1% to about 10%, by weight of the detergent composition of an ethoxylated quaternized amine clay material. These compositions preferably include a peroxygen bleaching agent and an organic detergent builder, dispersed in a liquid phase preferably structured with a surfactant. Such compositions provide especially desirable cleaning and bleaching of fabrics laundered therewith and also exhibit especially desirable aesthetics.Type: GrantFiled: June 6, 2000Date of Patent: May 7, 2002Assignee: The Procter & Gamble CompanyInventor: Diane Parry
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Patent number: 6376447Abstract: Disclosed is a nonaqueous liquid detergent composition comprising an enzyme particle, said composition having an average particle size of the enzyme particle of less than 600 microns.Type: GrantFiled: December 22, 1998Date of Patent: April 23, 2002Assignee: Procter & Gamble CompanyInventors: Jean-Pol Boutique, Axel Meyer, Lorenzo Matteo Pierre Gualco, James Pyott Johnston, Jean Wevers, Iwein Jozef Maria Jaak Goderis
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Patent number: 6372703Abstract: A liquid non-aqueous detergent is presented containing a nonionic surfactant, a builder, a bleaching agent, and a cationic stabilizer of formula I, II or III: where the groups R1 independently of one another are C1-6 alkyl, alkenyl or hydroxyalkyl groups, the groups R2 independently of one another are C8-28 alkyl or alkenyl groups, R3 has the same meaning as R1 or represents (CH2)n—T—R2, R4 has the same meaning as R1 or R2 or represents (CH2)n—T—R2, T represents —CH2—, —O—CO— or —CO—O— and n is an integer of from 0 to 5. The solid bleaching agents in the stabilized non-aqueous liquid detergent retain their activity after prolonged storage.Type: GrantFiled: July 15, 1999Date of Patent: April 16, 2002Assignee: Henkel Komanditgesellschaft auf AktienInventors: Bernd Richter, Ulrich Pegelow
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Patent number: 6348441Abstract: Disclosed is a method of laundering soiled fabrics comprising the steps of contacting said fabric in an aqueous laundering solution with a nonaqueous liquid detergent composition containing from about 40% to about 99% by weight of the composition of a surfactant-containing non-aqueous liquid phase and from about 1% to about 50% by weight of the composition of particulate material which is substantially insoluble in said liquid phase and which is selected from peroxygen bleaching agents, bleach activators, organic detergent builders, inorganic alkalinity sources and combinations thereof. A dye transfer inhibitor and suds suppressors are essential components in one aspect of the present invention.Type: GrantFiled: November 15, 2000Date of Patent: February 19, 2002Assignee: The Procter & Gamble CompanyInventors: John Davis Aiken, III, Murali Sampath, Ronald Allen Swift, II
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Patent number: 6306812Abstract: Laundry or cleaning composition comprising: a) an effective amount of a bleach activator and/or organic percarboxylic acid; b) a catalytically effective amount of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and c) at least about 0.1% of one or more laundry or cleaning adjunct materials. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic perearboxylic acids.Type: GrantFiled: September 7, 1999Date of Patent: October 23, 2001Assignee: Procter & Gamble Company, TheInventors: Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent, Michael Eugene Burns
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Patent number: 6281187Abstract: Disclosed are non-aqueous, particulate-containing liquid laundry detergent compositions which are in the form of a suspension of particulate material, essentially including colored speckles and preferably including peroxygen bleaching agent and an organic detergent builder, dispersed in a liquid phase preferably structured with a surfactant. Such compositions provide especially desirable cleaning and bleaching of fabrics laundered therewith and also exhibit especially desirable aesthetics.Type: GrantFiled: December 16, 1999Date of Patent: August 28, 2001Assignee: The Procter & Gamble CompanyInventor: Mark Allen Smerznak
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Patent number: 6187739Abstract: A paste-form detergent composition containing (A) 20% to 58% by weight of a liquid surfactant component consisting primarily of a nonionic surfactant, (B) 2% to 40% by weight of solid builders, and (C) 2% to 40% by weight of a solid bleaching component consisting of a peroxygen-containing oxidizing agent and a bleach activator, based on the weight of the composition.Type: GrantFiled: March 20, 1998Date of Patent: February 13, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Merz, Khalil Shamayeli, Guenther Amberg, Heinz-Manfred Wilsberg
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Patent number: 6165959Abstract: A nonaqueous liquid detergent composition comprising a bleach precursor composition comprising: a) a bleach precursor; and b) a surfactant system; and c) an organic acid.Type: GrantFiled: December 22, 1998Date of Patent: December 26, 2000Assignee: The Procter & Gamble CompanyInventors: Axel Meyer, Steven Jozef Louis Coosemans, Jean-Pol Boutique, James Pyott Johnston
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Patent number: 6159922Abstract: Bleach compositions comprising a percarbonate bleach and an amino tricarboxylic acid exhibit a reduced tendency to deposit calcium carbonate insolubles on substrates being bleached. Laundry compositions comprising percarbonate bleach and methyl glycine diacetic acid are provided.Type: GrantFiled: March 24, 1999Date of Patent: December 12, 2000Assignee: The Procter & Gamble CompanyInventor: Fiona Susan (Mac Beath) Williams
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Patent number: 6015504Abstract: The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fiber material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.Type: GrantFiled: January 26, 1998Date of Patent: January 18, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Dieter Reinehr, Claude Eckhardt, Robert Hochberg, Werner Kaufmann, Georges Metzger
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Patent number: 5965505Abstract: There is a provided a detergent composition containing: (a) a heavy metal ion sequestrant; and (b) an organic peroxyacid bleaching system wherein a means is provided for delaying the release to a wash solution of said peroxyacid bleach relative to the release of said heavy metal ion sequestrant. Preferably said composition additionally contains (c) a water soluble builder wherein a means is provided for delaying the release to a wash solution of said peroxyacid bleach relative to the release of said water soluble builder. A pretreat wash method is also provided.Type: GrantFiled: June 4, 1997Date of Patent: October 12, 1999Assignee: The Procter & Gamble CompanyInventors: Gerard Marcel Baillely, Janice Jeffrey, John Scott Park, Barry Stoddart
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Patent number: 5916481Abstract: Low hue photobleaching compositions comprising organosilicon(IV) phthalocyanine and naphthalocyanines having Q-band absorption maxima at wavelengths greater than 660 nm and increased triplet state yields whereby production of singlet oxygen is increased. Use of Si.sup.4+ phthalocyanine and naphthalocyanines compounds in photobleaching compositions allows for formulation of low hue laundry compositions, bleach compositions, and hard surface cleaners.Type: GrantFiled: June 18, 1996Date of Patent: June 29, 1999Assignee: The Procter & Gamble CompanyInventor: Alan David Willey
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Patent number: 5846927Abstract: The present invention relates to improved matrix or core shell enzyme capsule compositions comprising certain density modifying solids and defined core structural ingredients. Using these capsule compositions, much better active stability is obtained. In addition, higher active retention is accomplished during capsule formation. Release characteristics are not compromised. In a second embodiment of the invention, the invention relates to structured heavy duty liquid compositions comprising these capsules.Type: GrantFiled: April 8, 1996Date of Patent: December 8, 1998Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventor: Tirucherai Varahan Vasudevan
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Patent number: 5814592Abstract: Disclosed are non-aqueous, particulate-containing liquid laundry detergent compositions which are in the form of a suspension of particulate material, preferably including peroxygen bleaching agent and an organic detergent builder, dispersed in a liquid phase structured with a surfactant and elasticized with finely divided particulate material such as silica or titanium dioxide. Such compositions provide especially desirable cleaning and bleaching of fabrics laundered therewith and also exhibit especially desirable pourability and chemical and phase stability.Type: GrantFiled: June 24, 1997Date of Patent: September 29, 1998Assignee: The Procter & Gamble CompanyInventors: Jay I. Kahn, Mark A. Smerznak, Axel Meyer, Angela L. Garland, Vincent J. Becks, Jean-Pol Boutique
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Patent number: 5763382Abstract: A cold water washing formula and a method of reducing the soil load on a textile by introducing the textile and cold water into an internal assembly within a washing machine. The method includes a first break wash wherein the textile, water, and a solvent are introduced into the washing machine to initiate soil removal. In a second break wash, a surfactant and an alkali are added to the first break wash to continue the washing cycle. The combined first and second break washes are drained from the internal assembly and the textile is rinsed with water. After draining the first rinse from the internal assembly, a second rinse including ozonated water and an acid is introduced into the internal assembly. The second rinse is drained from the internal assembly and a third rinse, which includes ozonated water, is introduced into the internal assembly to rinse the textile.Type: GrantFiled: January 3, 1996Date of Patent: June 9, 1998Assignee: Cyclo3pss Textile Systems, Inc.Inventors: Theodore R. Cooper, Allyson T. Toney, John B. McParlane
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Patent number: 5759981Abstract: Treatment of textiles whereby the textiles are contacted with a medium comprising a bleach, anionic species and a neutralizing system for the anionic species, wherein the neutralizing system comprises quaternary ammonium compounds. The composition for textile treatment contains less than 10% by weight of water, and is essentially free of alkanolamines. The composition may further contain a metallo catalyst.Type: GrantFiled: December 4, 1996Date of Patent: June 2, 1998Assignee: The Procter & Gamble CompanyInventors: Jean-Pol Boutique, Mark William Glogowski, Frederick Edward Hardy, James Pyott Johnston, Regine Labeque, Bruce Prentiss Murch, Rajan Keshav Panandiker
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Patent number: 5733341Abstract: A process is described for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula (1), (2), (3), (4), (5), (6), (7), (8), (9), (10), (11), (12), (13) or (14) as defined in the specification. The compounds of formula (1), (2), (3), (4), (5), (6), (8), (9) (10), (11), (12), (13) or (14) are new compounds. The compounds used do not exhaust at all on to cotton, polyamide or polyester fibers, so that the compounds cannot lead to fiber discoloration problems.Type: GrantFiled: December 14, 1995Date of Patent: March 31, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Claude Eckhardt, Dieter Reinehr, Georges Metzger
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Patent number: 5714449Abstract: A non-aqueous liquid cleaning composition comprising a non-aqueous organic solvent, particles of solid material dispersed in the solvent and a dispersant, wherein the dispersant is a hydrophobically modified material.Type: GrantFiled: June 1, 1994Date of Patent: February 3, 1998Assignee: Unilever Patent Holdings B.V.Inventors: Cornelis Bernard Donker, Pieter Versluis
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Patent number: 5652207Abstract: Novel bleaches, a method for bleaching substrates using these materials and detergent compositions containing same are reported. The bleaches are phosphinoyl imines. Substrates such as fabrics may be bleached in an aqueous solution containing the phosphinoyl imines and a peroxygen compound.Type: GrantFiled: August 12, 1996Date of Patent: July 29, 1997Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventor: Naresh Dhirajlal Ghatlia