With Polycarboxylic Acid Component, Or Salt Or Anhydride Thereof (e.g., Carboxylic Acid Copolymer, Etc.) Patents (Class 510/318)
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Patent number: 6165970Abstract: There is provided a detergent composition comprising (a) an organic polymer containing acrylic acid or its salts, having an average molecular weight of less than 15,000; and (b) an amino tricarboxylic acid or its salts or complexes or any mixture thereof exhibiting improved soil and stain removal.Type: GrantFiled: February 23, 1999Date of Patent: December 26, 2000Assignee: The Procter & Gamble CompanyInventors: Fiona Susan Williams (nee Mac Beath), David Jonathan Kitko, Susumu Murata, Toshiko Tsunetsugu, Shuichi Tsunetsugu
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Patent number: 6165959Abstract: A nonaqueous liquid detergent composition comprising a bleach precursor composition comprising: a) a bleach precursor; and b) a surfactant system; and c) an organic acid.Type: GrantFiled: December 22, 1998Date of Patent: December 26, 2000Assignee: The Procter & Gamble CompanyInventors: Axel Meyer, Steven Jozef Louis Coosemans, Jean-Pol Boutique, James Pyott Johnston
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Patent number: 6162259Abstract: Detergent compositions comprising an amino tricarboxylic acid with a rapid rate of dissolution in a washing liquor exhibit a reduced tendency to leave calcium carbonate, lime soap and other deposits on substrates being cleaned. Dishwashing and laundry compositions comprising percarbonate bleach and methyl glycine diacetic acid are provided.Type: GrantFiled: May 6, 1999Date of Patent: December 19, 2000Assignee: The Procter & Gamble CompanyInventor: Fiona Susan Williams (nee Mac Beath)
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Patent number: 6159922Abstract: Bleach compositions comprising a percarbonate bleach and an amino tricarboxylic acid exhibit a reduced tendency to deposit calcium carbonate insolubles on substrates being bleached. Laundry compositions comprising percarbonate bleach and methyl glycine diacetic acid are provided.Type: GrantFiled: March 24, 1999Date of Patent: December 12, 2000Assignee: The Procter & Gamble CompanyInventor: Fiona Susan (Mac Beath) Williams
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Patent number: 6147043Abstract: In machine dishwashing using low-alkaline detergents, the protection of silver was to be guaranteed. This was achieved by using 3-amino-5-alkyl-1,2,4-triazoles and salts thereof as silver protectors in machine dishwashing detergents. In addition, the dishwashing detergents may contain bleaching agents and builders.Type: GrantFiled: January 15, 1998Date of Patent: November 14, 2000Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Hinrich Moeller, Helmut Blum, Christian Nitsch, Juergen Haerer
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Patent number: 6096097Abstract: Raw native fibers and textile products therefrom can be simultaneously washed and bleached in one liquor if the liquor has added to it a combination product ofa) one or more bleach stabilizers,b) one or more surfactants from the group of the nonionic, amphoteric and cationic surfactants,c) optionally one or more dispersants andd) optionally further components.Type: GrantFiled: March 1, 1999Date of Patent: August 1, 2000Assignee: Bayer AktiengesellschaftInventors: Ferdinand Kummeler, Josef Pfeiffer, Michael Pirkotsch, Torsten Groth, Winfried Joentgen
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Patent number: 6096098Abstract: The present invention discloses asymmetrical bleach activators for use in both solid and liquid additive, bleaching and detergent compositions. The asymmetrical bleach activators display the unique ability to form both hydrophilic and hydrophobic bleaching agents in aqueous liquors such as bleaching solutions. Thus, fabrics, hard surfaces or dishes having hydrophobic stains such as dingy and or hydrophilic stains such as beverages can be effectively cleaned or bleached using the bleach activators of the present invention.Type: GrantFiled: April 15, 1999Date of Patent: August 1, 2000Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Robert Richard Dykstra, Kevin Lee Kott, Stefano Scialla
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Patent number: 6056787Abstract: Iminodisuccinic acids of the formula ##STR1## the substituents of which have the meaning given in the description, are bleaching regulators in H.sub.2 O.sub.2 bleaching of textile-forming natural plant fibers or silk, wool and their mixtures with synthetics.Type: GrantFiled: September 19, 1997Date of Patent: May 2, 2000Assignee: Bayer AktiengesellschaftInventors: Gerd Friedrich Renner, Michael Pirkotsch, Klaus Walz, Torsten Groth, Winfried Joentgen
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Patent number: 6043209Abstract: There is provided an aqueous composition for cleaning fabrics and carpets and inhibiting the resoiling of fabric and carpets. The composition includes a water miscible organic solvent, a peroxygen compound, a surfactant, a polymeric or copolymeric soil resist, and a fluorinated hydrocarbon soil resist. The solvent is selected from isopropanol, propylene glycol methyl ether, dipropylene glycol methyl ether, or mixtures of two or more thereof. Compositions formed with these solvents and both soil resists are particularly stable and non-turbid.Type: GrantFiled: January 6, 1998Date of Patent: March 28, 2000Assignee: Playtex Products, Inc.Inventors: Robert P Micciche, Ann Marie Lynch, Uma Tripathi
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Patent number: 6008176Abstract: Glycine-N,N-diacetic acid derivatives and their alkali metal, alkaline earth metal, ammonium and substituted ammonium salts are used as complexing agents for alkaline earth metal and heavy metal ions with the exception of .alpha.-alanine-N,N-diacetic acid as textile detergent builders in powder detergent formulations and as calcium sequestrants in oral hygiene products.Type: GrantFiled: May 6, 1998Date of Patent: December 28, 1999Assignee: BASF AktiengesellschaftInventors: Juergen Schneider, Birgit Potthoff-Karl, Alexander Kud, Richard Baur, Alfred Oftring, Thomas Greindl
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Patent number: 5998360Abstract: Soluble alkali metal silicates combined with antiredeposition agents can actually have a beneficial effect on bleach stabilisation if said antiredeposition agents are intimately mixed with an alkali metal silicate solution, the resulting product being then dried (spray drying, turbo drying, etc . . . ) into granules.Type: GrantFiled: April 13, 1998Date of Patent: December 7, 1999Assignee: Crosfield LimitedInventors: Keith R Cockett, Theo J Osinga
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Patent number: 5994290Abstract: A solid textile detergent formulation, comprising(A) 1-60% by weight of inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates,(B) 0.1-25% by weight of one or more glycine-N,N'-diacetic acid derivatives I ##STR1## where R is an organic radical and M is hydrogen or a cation, as organic cobuilders,(C) 1-40% by weight of anionic surfactants and(D) 0.5-30% by weight of nonionic surfactants.Type: GrantFiled: May 18, 1998Date of Patent: November 30, 1999Assignee: BASF AktiengesellschaftInventors: Birgit Potthoff-Karl, Beate Ehle, Angelika Funhoff, Dieter Kiessling, Richard Baur, Thomas Greindl
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Patent number: 5981460Abstract: There is provided a detergent composition suitable for use in laundry and dish washing methods comprising (a) a cationic ester surfactant; and (b) a grease dispersing agent.Type: GrantFiled: November 30, 1998Date of Patent: November 9, 1999Assignee: The Procter & Gamble CompanyInventors: Ian Martin Dodd, Christiaan Arthur Thoen, Michael Alan John Moss
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Patent number: 5977052Abstract: Textiles are washed with a liquid washing agent, softened water, and salts of at least one polycarboxylic acid. The polycarboxylic acids are present in part as sodium salt and in part as calcium or magnesium salt.Type: GrantFiled: January 13, 1998Date of Patent: November 2, 1999Assignee: Bayer AGInventors: Lutz Heuer, Winfried Joentgen, Torsten Groth, Paul Wagner, Klaus-Peter Heise
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Patent number: 5932531Abstract: Solid activator bodies for activating oxygen-based bleach at relatively low temperatures are provided which preferably include respective quantities of tetra acetyl ethylene diamine (TAED), phosphate sequestering agent, non-phosphate solidifying agent, surfactant and water. The activator bodies are readily dispersable in hot water to form dilute dispersions which can be added directly to cleaning equipment along with oxygen-based bleach. The activator enhances bleaching effectiveness and generates peracetic acid, a potential antimicrobial.Type: GrantFiled: September 26, 1997Date of Patent: August 3, 1999Assignee: Noramtech CorporationInventors: Michael Oberlander, Robert P. Langguth
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Patent number: 5925609Abstract: A non-phosphate builder-containing detergent composition comprising a surfactant, and a) at least 0.5% by weight of a source of hydrogen peroxide; b) from 0.01% to 10% by weight of an organic peroxyacid bleach precursor; c) from 0.001% to 5% by weight of a proteolytic enzyme; d) an alkalinity source having the capacity to deliver alkalinity to a wash solution as measured by the alkalinity release test described herein, such that the % weight of NaOH equivalent of the composition is greater than 10.6% by weight of the composition, and wherein the detergent composition has a Hydrogen peroxide Precursor Proteolytic enzyme (HPP) Index of at least 0.35 as defined by the formula: ##EQU1## wherein the % weight of proteolytic enzyme in the formulation is based on an enzyme activity of 13 knpu/g of the enzyme particle, and wherein the % AvO.sub.2 is the total amount of available oxygen present in the composition is provided.Type: GrantFiled: September 10, 1997Date of Patent: July 20, 1999Assignee: Procter & Gamble CompanyInventors: Gerard Marcel Baillely, Richard Timothy Hartshorn, Christian Leo Marie Vermote
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Patent number: 5902781Abstract: Composite particles comprise a bleach catalyst plus one or more detersive enzymes. The particles are especially useful in automatic dishwashing compositions. Thus, a cobalt (III) or manganese (III) bleach catalyst is combined with protease or amylase enzymes and a carrier. The resulting particles are used in combination with perborate or percarbonate bleach to clean dishware in an automatic machine.Type: GrantFiled: August 27, 1997Date of Patent: May 11, 1999Assignee: The Procter & Gamble CompanyInventor: Jeffrey Donald Painter
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Patent number: 5827815Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising an ethoxylated fatty alcohol nonionic surfactant, a sulfated ethoxylated fatty alcohol anionic surfactant, and an N-alkyl and/or unsaturated hydrocarbyl amine of an alkanoic acid or salt thereof as an amphoteric surfactant.Type: GrantFiled: April 29, 1997Date of Patent: October 27, 1998Assignee: Church & Dwight Co., Inc.Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
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Patent number: 5821216Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising a sulfated ethoxylated fatty alcohol anionic surfactant and two ethoxylated fatty alcohol nonionic surfactants having different average numbers of carbon atoms in the fatty alcohol and average numbers of ethoxy groups.Type: GrantFiled: April 21, 1997Date of Patent: October 13, 1998Assignee: Church & Dwight Co., Inc.Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
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Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits
Patent number: 5804543Abstract: Disclosed are detergent compositions and methods which are suitable for washing colored fabrics in aqueous washing solution with little or no transfer of dye between fabrics. The compositions utilized comprise certain nil-LAS detersive surfactants, detergent builder and certain selected polymeric dye transfer inhibiting agents. The detersive surfactants used must comprise alkyl ether sulfates and certain types of nonionic surfactants (polyhydroxy fatty acid amides and/or alcohol ethoxylates). The polymeric dye transfer inhibiting agents are polyamine N-oxides such as poly(4-vinylpyridine-N-oxide), i.e., PVNO and/or copolymers of N-vinylpyrrolidone and N-vinylimidazole, i.e., PVPVI.Type: GrantFiled: July 19, 1996Date of Patent: September 8, 1998Assignee: The Procter & Gamble CompanyInventors: William C. Wertz, Rajan K. Panandiker -
Patent number: 5795854Abstract: A bleach-containing detergent composition which contains a peroxygen bleaching compound and a bleach activator is disclosed. The bleach activator is in the form of substantially cylindrically-shaped extrudates having a mean extrudate length of from about 500 microns to about 3500 microns and a mean extrudate diameter of from about 450 microns to about 850 microns.Type: GrantFiled: November 20, 1997Date of Patent: August 18, 1998Assignee: The Procter & Gamble CompanyInventors: Adrian John Waynforth Angell, Joseph Adam Pauley, III, Steven Matthew Gabriel, Donald Ray Brown
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Patent number: 5792738Abstract: There is provided a granular, silicate-built, phosphate free laundry detergent composition comprising fine alkali metal percarbonate particles having mean particle diameter below 450 .mu.m, preferably below 400 .mu.m, wherein no more than 20%, preferably no more than 10%, of the particles have a diameter above 710 .mu.m, said particles having a coating comprising one or more soluble inorganic salts. The salts may be selected from alkali or alkaline earth metal carbonates, sulphates, chlorides and nitrates. The coated percarbonate particles have improved stability to storage and are capable of dissolving quickly in wash liquor.Type: GrantFiled: January 16, 1996Date of Patent: August 11, 1998Assignee: The Procter & Gamble CompanyInventors: Gerard Marcel Baillely, Anthony Dovey, Graham Alexander Sorrie, David William York
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Patent number: 5773401Abstract: Laundry detergent compositions comprise at least 10% detergent surfactant or at least 10% detergent builder system. The detergent builder system comprises a copolymer of maleic acid and acrylic acid having a molecular weight of from 5,000 to 15,000 and a mole ratio of acrylic units to maleic units of from about 3:7 to 7:3. The copolymer has an Index Ratio (IR) of not less than 110, wherein IR=Binding Index (BI).times.Dispersing Index (DI)100.Type: GrantFiled: February 28, 1997Date of Patent: June 30, 1998Assignee: The Procter & Gamble CompanyInventors: Susumu Murata, David Johnathan Kitko, Toshiko Shigematsu
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Patent number: 5763382Abstract: A cold water washing formula and a method of reducing the soil load on a textile by introducing the textile and cold water into an internal assembly within a washing machine. The method includes a first break wash wherein the textile, water, and a solvent are introduced into the washing machine to initiate soil removal. In a second break wash, a surfactant and an alkali are added to the first break wash to continue the washing cycle. The combined first and second break washes are drained from the internal assembly and the textile is rinsed with water. After draining the first rinse from the internal assembly, a second rinse including ozonated water and an acid is introduced into the internal assembly. The second rinse is drained from the internal assembly and a third rinse, which includes ozonated water, is introduced into the internal assembly to rinse the textile.Type: GrantFiled: January 3, 1996Date of Patent: June 9, 1998Assignee: Cyclo3pss Textile Systems, Inc.Inventors: Theodore R. Cooper, Allyson T. Toney, John B. McParlane
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Patent number: 5759989Abstract: Stable aqueous emulsions comprising dipicolinic acid or certain derivatives thereof and hydrophilic and hydrophobic nonionic surfactants are disclosed, as well as a process for preparing said compositions. The dipicolinic acid and derivatives thereof build viscosity in said compositions.Type: GrantFiled: November 10, 1997Date of Patent: June 2, 1998Assignee: The Procter & Gamble CompanyInventors: Stefano Scialla, Sergio Cardola, Giulia Ottavia Bianchetti
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Patent number: 5756445Abstract: A granular detergent component having a bulk density of less than 400 g/l comprises from 20% to 50%, by weight, of aluminosilicate, optionally up to 50%, by weight, of a co-filler, and 0.05% to 2%, by weight, of anionic surfactant, preferably C14-C20 alkyl sulphate. The low bulk density component is preferably mixed with other components such as percarbonate, silicate, layered silicate, carbonate, bicarbonate, sesquicarbonate, sulphate, citrate and mixtures thereof to provide a granular detergent composition.Type: GrantFiled: July 30, 1996Date of Patent: May 26, 1998Assignee: The Proctor & Gamble CompanyInventors: Andrew Dorset, Robin Gibson Hall
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Patent number: 5750489Abstract: The present invention relates to liquid detergent compositions comprising substantially linear, water soluble, highly salt-tolerant non-adsorbing, ionic polymers of MW 10,000 to 1,000,000 Daltons which, when added in defined minimum levels to structured heavy duty liquids, make the liquids highly shear thinning without decreasing pour viscosity of the composition or increasing it to a point where it is too thick. The compositions are also stable.Type: GrantFiled: January 18, 1996Date of Patent: May 12, 1998Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Rigoberto Felipe Garcia, Tirucherai Varahan Vasudevan, Albert Joseph Post, Feng-Lung Gordon Hsu
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Patent number: 5736498Abstract: Neutral or alkaline thickened aqueous hydrogen peroxide compositions and processes for the production thereof are provided. The compositions are thickened with a polymeric thickener comprising a polyethylene backbone, with pendant carboxylate groups and pendant groups of the formula --(OCH.sub.2 CH.sub.2).sub.m (OCHXCHY).sub.n --O--R, where m is a position integer, n is zero or a positive integer, X and Y are independently selected from hydrogen atoms, methyl and ethyl groups and R is a hydrophobic group comprising eight or more carbon atoms; and one or more surfactants selected from the group consisting of alcohol ethyoxylates, alkylbenzenesulphonates comprising ten or more carbon atoms, alkylsulphates comprising six or more carbon atoms, alcohol ether sulphates, alpha-sulphoesters and alkylglucosides.Type: GrantFiled: March 19, 1996Date of Patent: April 7, 1998Assignee: Solvay Interox LimitedInventor: Andrew Kevin Gray
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Patent number: 5736497Abstract: A phosphorus-free and boron-free cleaning composition containing a phosphorus-free aqueous solution containing an active ingredient (e.g., hydrogen peroxide or a compound capable of releasing hydrogen peroxide under the conditions prevailing in use of the composition), at least one organic stannate which is a tetravalent tin complexed with dicarboxylic acid, hydroxy carboxylic acid, or tricarboxylic acid, and optionally at least one organic stabilizer which is a benzoate, a sulfonic acid or salt, or mixtures thereof. The active ingredient is hydrogen peroxide or a percarbonate. The aqueous solution has an alkaline pH.Type: GrantFiled: March 29, 1996Date of Patent: April 7, 1998Assignee: Degussa CorporationInventor: Norbert N. Steiner
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Patent number: 5733858Abstract: Solutions comprising at least one polyamino disuccinic acid and one or more polyamino monosuccinic acids are useful in gas conditioning (preferably as the iron chelate). The copper chelates are also useful in electroless copper plating. Another aspect of the invention includes the use of the aminosuccinic acid mixtures in laundry detergent compositions.Type: GrantFiled: August 29, 1996Date of Patent: March 31, 1998Assignee: The Dow Chemical CompanyInventors: David A. Wilson, Druce K. Crump
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Patent number: 5712238Abstract: A multipurpose cleaning agent containing 6.5-8% sodium alkyl sulfate, 2.7-4% fatty acid coconut diethanolamide, 0.38-0.42% citric acid, 0.38-0.42% ethylene diamine tetraacetic acid, 0.42-0.48% sodium citrate, 2.88-3.2% water, 1.88-2.5% sodium polyoxyethylene alkyl ether sulfate, 0.5-1% sodium carboxy methyl cellulose, 0.2-0.4% sodium percarbonate, 2-5% sodium tripoly phosphate, 40.38-35.89% low density sodium carbonate, 40.38-35.89% Na.sub.2 SO.sub.4.H.sub.2 O, 0.4-0.8%, savinase 40T, and 1-2% celluzyme 0.7T.Type: GrantFiled: August 2, 1996Date of Patent: January 27, 1998Inventor: Wu Hsiung Chan
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Patent number: 5704947Abstract: The deposition of magnesium and calcium silicate in the bleaching of textiles with peroxides is prevented by contacting the textiles with a bleaching composition that is free from phosphorous and contains water-soluble polymers containing sulfonate and carboxylate groups, and polyhydroxymono- or dicarboxylates.Type: GrantFiled: January 16, 1997Date of Patent: January 6, 1998Inventors: Heribert Kaiser, Christian Nitsch, Claus-Peter Kurzendoerfer, Bernd Wahle, Bernd-Dieter Baehr, deceased, Sylvia Baehr, executrix, Hildegard Van Delden
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Patent number: 5703031Abstract: A granular laundry composition is disclosed which comprises a source of available-oxygen, a stabilizer like chelant together with an alkali metal salt of silicate. Such compositions allow to produced wash solutions wherein the bleaching activity is retained upon longer periods of time. Optionally said compositions may further comprise a soil suspender and be formulated so as to allow to keep the pH of the wash solution below 9.5 and thereby boost the cleaning performance on particulate soil (clay).Type: GrantFiled: March 12, 1996Date of Patent: December 30, 1997Assignee: Procter & Gamble CompanyInventors: Marina Trani, Guiseppe Trigiante, Ellie Marie Frasier
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Patent number: 5665693Abstract: Use of carboxyl-containing reaction products of(a) maleic anhydride, maleic acid and/or fumaric acid, and(b) proteins or protein hydrolyzateshaving an acid number of at least 1.5 mmol of NaOH/g of reaction product, as ingredient of reduced-phosphate and phosphate-free detergents and cleaners.Type: GrantFiled: October 10, 1995Date of Patent: September 9, 1997Assignee: BASF AktiengesellschaftInventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Alexander Kud, Volker Schwendemann
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Patent number: 5641739Abstract: Aqueous, acidic bleach laundry detergent compositions with selected chelants which remain substantially undissolved in the acidic product formulation are described. The chelants are chemically stable within the product even upon extended storage and provide improved in-use chelating as well as product performance.Type: GrantFiled: May 1, 1995Date of Patent: June 24, 1997Assignee: The Procter & Gamble CompanyInventors: Kevin Lee Kott, Alan David Willey
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Patent number: 5531915Abstract: Detergent compositions containing conventional detergent surfactants, detergent builders, and the like, and a chelant selected from ethylenediamine-N,N'-diglutaric acid (EDDG) and 2-hydroxypropylenediamine-N,N'-disuccinic acid (HPDDS) are disclosed. Such compositions provide enhanced removal of organic stains, such as food and beverage stains. The EDDG and HPDDS are biodegradable and contain no phorphorus.Type: GrantFiled: October 3, 1994Date of Patent: July 2, 1996Assignee: The Procter & Gamble CompanyInventor: Christopher M. Perkins