With Polycarboxylic Acid Component, Or Salt Or Anhydride Thereof (e.g., Carboxylic Acid Copolymer, Etc.) Patents (Class 510/318)
  • Patent number: 6165959
    Abstract: A nonaqueous liquid detergent composition comprising a bleach precursor composition comprising: a) a bleach precursor; and b) a surfactant system; and c) an organic acid.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: December 26, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Axel Meyer, Steven Jozef Louis Coosemans, Jean-Pol Boutique, James Pyott Johnston
  • Patent number: 6162259
    Abstract: Detergent compositions comprising an amino tricarboxylic acid with a rapid rate of dissolution in a washing liquor exhibit a reduced tendency to leave calcium carbonate, lime soap and other deposits on substrates being cleaned. Dishwashing and laundry compositions comprising percarbonate bleach and methyl glycine diacetic acid are provided.
    Type: Grant
    Filed: May 6, 1999
    Date of Patent: December 19, 2000
    Assignee: The Procter & Gamble Company
    Inventor: Fiona Susan Williams (nee Mac Beath)
  • Patent number: 6159922
    Abstract: Bleach compositions comprising a percarbonate bleach and an amino tricarboxylic acid exhibit a reduced tendency to deposit calcium carbonate insolubles on substrates being bleached. Laundry compositions comprising percarbonate bleach and methyl glycine diacetic acid are provided.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: December 12, 2000
    Assignee: The Procter & Gamble Company
    Inventor: Fiona Susan (Mac Beath) Williams
  • Patent number: 6147043
    Abstract: In machine dishwashing using low-alkaline detergents, the protection of silver was to be guaranteed. This was achieved by using 3-amino-5-alkyl-1,2,4-triazoles and salts thereof as silver protectors in machine dishwashing detergents. In addition, the dishwashing detergents may contain bleaching agents and builders.
    Type: Grant
    Filed: January 15, 1998
    Date of Patent: November 14, 2000
    Assignee: Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Hinrich Moeller, Helmut Blum, Christian Nitsch, Juergen Haerer
  • Patent number: 6096098
    Abstract: The present invention discloses asymmetrical bleach activators for use in both solid and liquid additive, bleaching and detergent compositions. The asymmetrical bleach activators display the unique ability to form both hydrophilic and hydrophobic bleaching agents in aqueous liquors such as bleaching solutions. Thus, fabrics, hard surfaces or dishes having hydrophobic stains such as dingy and or hydrophilic stains such as beverages can be effectively cleaned or bleached using the bleach activators of the present invention.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: August 1, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Gregory Scot Miracle, Robert Richard Dykstra, Kevin Lee Kott, Stefano Scialla
  • Patent number: 6096097
    Abstract: Raw native fibers and textile products therefrom can be simultaneously washed and bleached in one liquor if the liquor has added to it a combination product ofa) one or more bleach stabilizers,b) one or more surfactants from the group of the nonionic, amphoteric and cationic surfactants,c) optionally one or more dispersants andd) optionally further components.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: August 1, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ferdinand Kummeler, Josef Pfeiffer, Michael Pirkotsch, Torsten Groth, Winfried Joentgen
  • Patent number: 6056787
    Abstract: Iminodisuccinic acids of the formula ##STR1## the substituents of which have the meaning given in the description, are bleaching regulators in H.sub.2 O.sub.2 bleaching of textile-forming natural plant fibers or silk, wool and their mixtures with synthetics.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 2, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerd Friedrich Renner, Michael Pirkotsch, Klaus Walz, Torsten Groth, Winfried Joentgen
  • Patent number: 6043209
    Abstract: There is provided an aqueous composition for cleaning fabrics and carpets and inhibiting the resoiling of fabric and carpets. The composition includes a water miscible organic solvent, a peroxygen compound, a surfactant, a polymeric or copolymeric soil resist, and a fluorinated hydrocarbon soil resist. The solvent is selected from isopropanol, propylene glycol methyl ether, dipropylene glycol methyl ether, or mixtures of two or more thereof. Compositions formed with these solvents and both soil resists are particularly stable and non-turbid.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: March 28, 2000
    Assignee: Playtex Products, Inc.
    Inventors: Robert P Micciche, Ann Marie Lynch, Uma Tripathi
  • Patent number: 6008176
    Abstract: Glycine-N,N-diacetic acid derivatives and their alkali metal, alkaline earth metal, ammonium and substituted ammonium salts are used as complexing agents for alkaline earth metal and heavy metal ions with the exception of .alpha.-alanine-N,N-diacetic acid as textile detergent builders in powder detergent formulations and as calcium sequestrants in oral hygiene products.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: December 28, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Schneider, Birgit Potthoff-Karl, Alexander Kud, Richard Baur, Alfred Oftring, Thomas Greindl
  • Patent number: 5998360
    Abstract: Soluble alkali metal silicates combined with antiredeposition agents can actually have a beneficial effect on bleach stabilisation if said antiredeposition agents are intimately mixed with an alkali metal silicate solution, the resulting product being then dried (spray drying, turbo drying, etc . . . ) into granules.
    Type: Grant
    Filed: April 13, 1998
    Date of Patent: December 7, 1999
    Assignee: Crosfield Limited
    Inventors: Keith R Cockett, Theo J Osinga
  • Patent number: 5994290
    Abstract: A solid textile detergent formulation, comprising(A) 1-60% by weight of inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates,(B) 0.1-25% by weight of one or more glycine-N,N'-diacetic acid derivatives I ##STR1## where R is an organic radical and M is hydrogen or a cation, as organic cobuilders,(C) 1-40% by weight of anionic surfactants and(D) 0.5-30% by weight of nonionic surfactants.
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: November 30, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Birgit Potthoff-Karl, Beate Ehle, Angelika Funhoff, Dieter Kiessling, Richard Baur, Thomas Greindl
  • Patent number: 5981460
    Abstract: There is provided a detergent composition suitable for use in laundry and dish washing methods comprising (a) a cationic ester surfactant; and (b) a grease dispersing agent.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: November 9, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Ian Martin Dodd, Christiaan Arthur Thoen, Michael Alan John Moss
  • Patent number: 5977052
    Abstract: Textiles are washed with a liquid washing agent, softened water, and salts of at least one polycarboxylic acid. The polycarboxylic acids are present in part as sodium salt and in part as calcium or magnesium salt.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: November 2, 1999
    Assignee: Bayer AG
    Inventors: Lutz Heuer, Winfried Joentgen, Torsten Groth, Paul Wagner, Klaus-Peter Heise
  • Patent number: 5932531
    Abstract: Solid activator bodies for activating oxygen-based bleach at relatively low temperatures are provided which preferably include respective quantities of tetra acetyl ethylene diamine (TAED), phosphate sequestering agent, non-phosphate solidifying agent, surfactant and water. The activator bodies are readily dispersable in hot water to form dilute dispersions which can be added directly to cleaning equipment along with oxygen-based bleach. The activator enhances bleaching effectiveness and generates peracetic acid, a potential antimicrobial.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: August 3, 1999
    Assignee: Noramtech Corporation
    Inventors: Michael Oberlander, Robert P. Langguth
  • Patent number: 5925609
    Abstract: A non-phosphate builder-containing detergent composition comprising a surfactant, and a) at least 0.5% by weight of a source of hydrogen peroxide; b) from 0.01% to 10% by weight of an organic peroxyacid bleach precursor; c) from 0.001% to 5% by weight of a proteolytic enzyme; d) an alkalinity source having the capacity to deliver alkalinity to a wash solution as measured by the alkalinity release test described herein, such that the % weight of NaOH equivalent of the composition is greater than 10.6% by weight of the composition, and wherein the detergent composition has a Hydrogen peroxide Precursor Proteolytic enzyme (HPP) Index of at least 0.35 as defined by the formula: ##EQU1## wherein the % weight of proteolytic enzyme in the formulation is based on an enzyme activity of 13 knpu/g of the enzyme particle, and wherein the % AvO.sub.2 is the total amount of available oxygen present in the composition is provided.
    Type: Grant
    Filed: September 10, 1997
    Date of Patent: July 20, 1999
    Assignee: Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Richard Timothy Hartshorn, Christian Leo Marie Vermote
  • Patent number: 5902781
    Abstract: Composite particles comprise a bleach catalyst plus one or more detersive enzymes. The particles are especially useful in automatic dishwashing compositions. Thus, a cobalt (III) or manganese (III) bleach catalyst is combined with protease or amylase enzymes and a carrier. The resulting particles are used in combination with perborate or percarbonate bleach to clean dishware in an automatic machine.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: May 11, 1999
    Assignee: The Procter & Gamble Company
    Inventor: Jeffrey Donald Painter
  • Patent number: 5827815
    Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising an ethoxylated fatty alcohol nonionic surfactant, a sulfated ethoxylated fatty alcohol anionic surfactant, and an N-alkyl and/or unsaturated hydrocarbyl amine of an alkanoic acid or salt thereof as an amphoteric surfactant.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: October 27, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
  • Patent number: 5821216
    Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising a sulfated ethoxylated fatty alcohol anionic surfactant and two ethoxylated fatty alcohol nonionic surfactants having different average numbers of carbon atoms in the fatty alcohol and average numbers of ethoxy groups.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: October 13, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
  • Patent number: 5804543
    Abstract: Disclosed are detergent compositions and methods which are suitable for washing colored fabrics in aqueous washing solution with little or no transfer of dye between fabrics. The compositions utilized comprise certain nil-LAS detersive surfactants, detergent builder and certain selected polymeric dye transfer inhibiting agents. The detersive surfactants used must comprise alkyl ether sulfates and certain types of nonionic surfactants (polyhydroxy fatty acid amides and/or alcohol ethoxylates). The polymeric dye transfer inhibiting agents are polyamine N-oxides such as poly(4-vinylpyridine-N-oxide), i.e., PVNO and/or copolymers of N-vinylpyrrolidone and N-vinylimidazole, i.e., PVPVI.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: September 8, 1998
    Assignee: The Procter & Gamble Company
    Inventors: William C. Wertz, Rajan K. Panandiker
  • Patent number: 5795854
    Abstract: A bleach-containing detergent composition which contains a peroxygen bleaching compound and a bleach activator is disclosed. The bleach activator is in the form of substantially cylindrically-shaped extrudates having a mean extrudate length of from about 500 microns to about 3500 microns and a mean extrudate diameter of from about 450 microns to about 850 microns.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: August 18, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Adrian John Waynforth Angell, Joseph Adam Pauley, III, Steven Matthew Gabriel, Donald Ray Brown
  • Patent number: 5792738
    Abstract: There is provided a granular, silicate-built, phosphate free laundry detergent composition comprising fine alkali metal percarbonate particles having mean particle diameter below 450 .mu.m, preferably below 400 .mu.m, wherein no more than 20%, preferably no more than 10%, of the particles have a diameter above 710 .mu.m, said particles having a coating comprising one or more soluble inorganic salts. The salts may be selected from alkali or alkaline earth metal carbonates, sulphates, chlorides and nitrates. The coated percarbonate particles have improved stability to storage and are capable of dissolving quickly in wash liquor.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: August 11, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Anthony Dovey, Graham Alexander Sorrie, David William York
  • Patent number: 5773401
    Abstract: Laundry detergent compositions comprise at least 10% detergent surfactant or at least 10% detergent builder system. The detergent builder system comprises a copolymer of maleic acid and acrylic acid having a molecular weight of from 5,000 to 15,000 and a mole ratio of acrylic units to maleic units of from about 3:7 to 7:3. The copolymer has an Index Ratio (IR) of not less than 110, wherein IR=Binding Index (BI).times.Dispersing Index (DI)100.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: June 30, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Susumu Murata, David Johnathan Kitko, Toshiko Shigematsu
  • Patent number: 5763382
    Abstract: A cold water washing formula and a method of reducing the soil load on a textile by introducing the textile and cold water into an internal assembly within a washing machine. The method includes a first break wash wherein the textile, water, and a solvent are introduced into the washing machine to initiate soil removal. In a second break wash, a surfactant and an alkali are added to the first break wash to continue the washing cycle. The combined first and second break washes are drained from the internal assembly and the textile is rinsed with water. After draining the first rinse from the internal assembly, a second rinse including ozonated water and an acid is introduced into the internal assembly. The second rinse is drained from the internal assembly and a third rinse, which includes ozonated water, is introduced into the internal assembly to rinse the textile.
    Type: Grant
    Filed: January 3, 1996
    Date of Patent: June 9, 1998
    Assignee: Cyclo3pss Textile Systems, Inc.
    Inventors: Theodore R. Cooper, Allyson T. Toney, John B. McParlane
  • Patent number: 5759989
    Abstract: Stable aqueous emulsions comprising dipicolinic acid or certain derivatives thereof and hydrophilic and hydrophobic nonionic surfactants are disclosed, as well as a process for preparing said compositions. The dipicolinic acid and derivatives thereof build viscosity in said compositions.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: June 2, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Stefano Scialla, Sergio Cardola, Giulia Ottavia Bianchetti
  • Patent number: 5756445
    Abstract: A granular detergent component having a bulk density of less than 400 g/l comprises from 20% to 50%, by weight, of aluminosilicate, optionally up to 50%, by weight, of a co-filler, and 0.05% to 2%, by weight, of anionic surfactant, preferably C14-C20 alkyl sulphate. The low bulk density component is preferably mixed with other components such as percarbonate, silicate, layered silicate, carbonate, bicarbonate, sesquicarbonate, sulphate, citrate and mixtures thereof to provide a granular detergent composition.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: May 26, 1998
    Assignee: The Proctor & Gamble Company
    Inventors: Andrew Dorset, Robin Gibson Hall
  • Patent number: 5750489
    Abstract: The present invention relates to liquid detergent compositions comprising substantially linear, water soluble, highly salt-tolerant non-adsorbing, ionic polymers of MW 10,000 to 1,000,000 Daltons which, when added in defined minimum levels to structured heavy duty liquids, make the liquids highly shear thinning without decreasing pour viscosity of the composition or increasing it to a point where it is too thick. The compositions are also stable.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: May 12, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Rigoberto Felipe Garcia, Tirucherai Varahan Vasudevan, Albert Joseph Post, Feng-Lung Gordon Hsu
  • Patent number: 5736497
    Abstract: A phosphorus-free and boron-free cleaning composition containing a phosphorus-free aqueous solution containing an active ingredient (e.g., hydrogen peroxide or a compound capable of releasing hydrogen peroxide under the conditions prevailing in use of the composition), at least one organic stannate which is a tetravalent tin complexed with dicarboxylic acid, hydroxy carboxylic acid, or tricarboxylic acid, and optionally at least one organic stabilizer which is a benzoate, a sulfonic acid or salt, or mixtures thereof. The active ingredient is hydrogen peroxide or a percarbonate. The aqueous solution has an alkaline pH.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: April 7, 1998
    Assignee: Degussa Corporation
    Inventor: Norbert N. Steiner
  • Patent number: 5736498
    Abstract: Neutral or alkaline thickened aqueous hydrogen peroxide compositions and processes for the production thereof are provided. The compositions are thickened with a polymeric thickener comprising a polyethylene backbone, with pendant carboxylate groups and pendant groups of the formula --(OCH.sub.2 CH.sub.2).sub.m (OCHXCHY).sub.n --O--R, where m is a position integer, n is zero or a positive integer, X and Y are independently selected from hydrogen atoms, methyl and ethyl groups and R is a hydrophobic group comprising eight or more carbon atoms; and one or more surfactants selected from the group consisting of alcohol ethyoxylates, alkylbenzenesulphonates comprising ten or more carbon atoms, alkylsulphates comprising six or more carbon atoms, alcohol ether sulphates, alpha-sulphoesters and alkylglucosides.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: April 7, 1998
    Assignee: Solvay Interox Limited
    Inventor: Andrew Kevin Gray
  • Patent number: 5733858
    Abstract: Solutions comprising at least one polyamino disuccinic acid and one or more polyamino monosuccinic acids are useful in gas conditioning (preferably as the iron chelate). The copper chelates are also useful in electroless copper plating. Another aspect of the invention includes the use of the aminosuccinic acid mixtures in laundry detergent compositions.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: March 31, 1998
    Assignee: The Dow Chemical Company
    Inventors: David A. Wilson, Druce K. Crump
  • Patent number: 5712238
    Abstract: A multipurpose cleaning agent containing 6.5-8% sodium alkyl sulfate, 2.7-4% fatty acid coconut diethanolamide, 0.38-0.42% citric acid, 0.38-0.42% ethylene diamine tetraacetic acid, 0.42-0.48% sodium citrate, 2.88-3.2% water, 1.88-2.5% sodium polyoxyethylene alkyl ether sulfate, 0.5-1% sodium carboxy methyl cellulose, 0.2-0.4% sodium percarbonate, 2-5% sodium tripoly phosphate, 40.38-35.89% low density sodium carbonate, 40.38-35.89% Na.sub.2 SO.sub.4.H.sub.2 O, 0.4-0.8%, savinase 40T, and 1-2% celluzyme 0.7T.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: January 27, 1998
    Inventor: Wu Hsiung Chan
  • Patent number: 5704947
    Abstract: The deposition of magnesium and calcium silicate in the bleaching of textiles with peroxides is prevented by contacting the textiles with a bleaching composition that is free from phosphorous and contains water-soluble polymers containing sulfonate and carboxylate groups, and polyhydroxymono- or dicarboxylates.
    Type: Grant
    Filed: January 16, 1997
    Date of Patent: January 6, 1998
    Inventors: Heribert Kaiser, Christian Nitsch, Claus-Peter Kurzendoerfer, Bernd Wahle, Bernd-Dieter Baehr, deceased, Sylvia Baehr, executrix, Hildegard Van Delden
  • Patent number: 5703031
    Abstract: A granular laundry composition is disclosed which comprises a source of available-oxygen, a stabilizer like chelant together with an alkali metal salt of silicate. Such compositions allow to produced wash solutions wherein the bleaching activity is retained upon longer periods of time. Optionally said compositions may further comprise a soil suspender and be formulated so as to allow to keep the pH of the wash solution below 9.5 and thereby boost the cleaning performance on particulate soil (clay).
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: December 30, 1997
    Assignee: Procter & Gamble Company
    Inventors: Marina Trani, Guiseppe Trigiante, Ellie Marie Frasier
  • Patent number: 5665693
    Abstract: Use of carboxyl-containing reaction products of(a) maleic anhydride, maleic acid and/or fumaric acid, and(b) proteins or protein hydrolyzateshaving an acid number of at least 1.5 mmol of NaOH/g of reaction product, as ingredient of reduced-phosphate and phosphate-free detergents and cleaners.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 9, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5641739
    Abstract: Aqueous, acidic bleach laundry detergent compositions with selected chelants which remain substantially undissolved in the acidic product formulation are described. The chelants are chemically stable within the product even upon extended storage and provide improved in-use chelating as well as product performance.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: June 24, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Kevin Lee Kott, Alan David Willey
  • Patent number: 5531915
    Abstract: Detergent compositions containing conventional detergent surfactants, detergent builders, and the like, and a chelant selected from ethylenediamine-N,N'-diglutaric acid (EDDG) and 2-hydroxypropylenediamine-N,N'-disuccinic acid (HPDDS) are disclosed. Such compositions provide enhanced removal of organic stains, such as food and beverage stains. The EDDG and HPDDS are biodegradable and contain no phorphorus.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: July 2, 1996
    Assignee: The Procter & Gamble Company
    Inventor: Christopher M. Perkins