Plural Sulfur-containing, Anionically Substituted Surfactants Patents (Class 510/352)
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Patent number: 11499124Abstract: A solid granule or granular material used for cleaning agents includes an anionic surfactant component and a molding agent. The anionic surfactant component includes an anionic sulfonate surfactant and an anionic fatty alcohol-based sulfate surfactant. Based on the total amount of the cleaning granule being 100 wt %, the combined amount of the sulfonate surfactant and the sulfate surfactant is between 15.0 wt % and 100 wt %. The amount of molding agent is 5.0 wt % or less. The ratio of the sulfonate surfactant to the sulfate surfactant is 0.20 to 0.75, inclusive. A cohesion of the solid granule is between 1000 g/mm and 4000 g/mm.Type: GrantFiled: July 15, 2020Date of Patent: November 15, 2022Assignee: YFY Consumer Products, Co.Inventors: Yi-Da Ho, Hsien-Ming Kwo, Hsing-Nan Chen, Shiu-Chih Tsai
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Patent number: 11203733Abstract: Compositions for cleaning equipment, preferably paper or carpet making equipment, and methods of cleaning equipment, preferably paper or carpet making equipment using the said composition. The cleaning composition comprises of one or more fatty acid methyl esters, preferably vegetable oil methyl ester, more preferably soybean oil methyl ester, one or more alkene carbonate, preferably propylene carbonate; one of more surfactants, preferably nonionic surfactants; and one or more glycol ether and/or dibasic ester containing solvents.Type: GrantFiled: December 13, 2017Date of Patent: December 21, 2021Assignee: Kemira OyjInventors: Yong Zou, Frank Zimmermann
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Patent number: 9758445Abstract: The present invention relates to compositions comprising alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; methods for making alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. More particularly, the present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; methods for making 2-phenyl alkene benzenes or 2-phenyl alkene benzene sulfonates or 2-phenyl alkylbenzenes or 2-phenyl alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein.Type: GrantFiled: October 7, 2015Date of Patent: September 12, 2017Assignee: MATERIA, INC.Inventors: Adam M. Johns, Richard L. Pederson, Rosemary Conrad Kiser
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Publication number: 20150087521Abstract: Sulfate and sulfonate derivatives of unsaturated fatty alcohols, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol composition is made by reducing a metathesis-derived monounsaturated alkyl ester. The fatty alcohol composition is then converted to a sulfate or sulfonate derivative by one or more of alkoxylation, sulfation, sulfonation, and sulfitation. Of particular interest are the sulfate and ether sulfate derivatives.Type: ApplicationFiled: March 13, 2013Publication date: March 26, 2015Applicant: Stepan CompanyInventors: David R. Allen, Marcos Alonso, Mary Beddaoui, Randal J. Bernhardt, Aaron Brown, Scott Dillavou, Xue Min Dong, Wilma Gorman, John C. Hutchison, Gary Luebke, Renee Luka, Franz Luxem, Andrew D Malec, Ronald A. Masters, Dennis S. Murphy, Nicholas Pendleton, Irma Ryklin, Patti Skelton, Brian Sook, Chris Spaulding, Krista Turpin, Gregory Wallace, Michael Wiester, Patrick Shane Wolfe
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Patent number: 8969280Abstract: The present invention is directed to visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with granular laundry detergent composition.Type: GrantFiled: June 7, 2013Date of Patent: March 3, 2015Assignee: The Procter & Gamble CompanyInventors: Richard Lock, Michael Pickstock
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Patent number: 8846596Abstract: Liquid cleaning compositions are described herein that include a metal bleach catalyst which is a complex of a transition-metal and a macrocyclic ligand, the ligand having a calculated Octanol/Water Partition Coefficient value of from about ?1.50 to about ?0.10, a formulation enabling fraction comprising at least one formulation enabling ingredient, the formulation enabling fraction having a Hydrophilic Index of from about 4.0 to about 10.0, and a formulation deactivating fraction comprising at least one formulation deactivating ingredient that has a calculated Octanol/Water Partition Coefficient value of from about ?3.5 to about ?0.10.Type: GrantFiled: February 16, 2012Date of Patent: September 30, 2014Assignee: The Procter & Gamble CompanyInventors: Robert Richard Dykstra, Mario Elmen Tremblay, Xiaoru Jenny Wang, James Lee Danziger, Daniel Dale Ditullio, Jr., Consuelo Kong, Ismael Cotte-Rodriguez
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Patent number: 8691741Abstract: The present invention provides a liquid detergent composition containing the following components (a) to (c), wherein the total content of components (a) to (c), (a)+(b)+(c), is 40 to 90% by mass; a mass ratio of components (a) to (b), (a)/(b), is 25/75 to 90/10; and a mass ratio [(a)+(b)]/(c), is 95/5 to 70/30: component (a): 15 to 75% by mass of a nonionic surfactant produced by adding p1 mol of ethylene oxide to a compound represented by R—OH (wherein, R represents a hydrocarbon group having 8 to 18 carbon atoms), then adding q1 mol of an alkylene oxide having 3 to 5 carbon atoms, and then adding p2 mol of ethylene oxide, wherein p1 is the number of 3 to 30, q1 is the number of 1 to 5, and p1+p2 is 14 to 50, component (b): anionic surfactant, component (c): cationic surfactant, component (d): 5 to 40% by mass of water-miscible organic solvent.Type: GrantFiled: April 16, 2010Date of Patent: April 8, 2014Assignee: Kao CorporationInventors: Hitoshi Ishizuka, Kyoko Okada, Yoshiyuki Komatsu, Toshio Miyake
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Publication number: 20130217608Abstract: Laundry detergents useful for cold-water cleaning and boosted bargain detergents are disclosed. The detergents include a surfactant composition derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. For fatty alkyl ester sulfonate-containing detergents, the composition is selected from C10 betaines, C12 or C16 amidoamines, C12 ethanolamine amides, C16 amidoamine sulfonates, C18 diamidoamine dioxides, quaternized C18 diamidoamine betaines, sulfonated C18 low-EO fatty ester alkoxylates, C18 amidoamine carboxylates, and amidoamine oxides and sulfobetaines derived from cross-metathesis of palm or soybean oil. The bargain detergents include a performance booster selected from C12 low-EO fatty ester alkoxylate sulfonates, C18 amidoamine oxide esters, C18 amidoamine oxide carboxylates, and amidoamine sulfobetaines made from self metathesized palm or soybean oil.Type: ApplicationFiled: October 25, 2011Publication date: August 22, 2013Inventors: Dave R. Allen, Marcos Alonso, Randal J. Bernhardt, Dennis S. Murphy, Patrick Shane Wolfe, Aaron Brown
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Patent number: 8492481Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.Type: GrantFiled: March 25, 2011Date of Patent: July 23, 2013Assignee: Rhodia Inc.Inventors: Dominic Wai-Kwing Yeung, Vance Bergeron, Jean-Francois Bodet, Mark R. Sivik, Bernard W. Kluesener, William M. Scheper
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Publication number: 20130150278Abstract: The present invention is to a detergent composition comprising an anionic surfactant system, wherein the anionic surfactant system comprises; i) An alkyl sulfate surfactant of formula R1—O—SO3?M+, with R1 being a linear or branched, substituted or unsubstituted, optionally alkoxylated, C10-C16 alkyl and with M+ being a proton or a cation which provides charge neutrality, and ii) A linear or branched, substituted or unsubstituted C10-C16 alcohol ethoxylate sulfate surfactant having an average degree of ethoxylation of from 0.5 to 3 having a proton or a cation which provides charge neutrality.Type: ApplicationFiled: August 2, 2012Publication date: June 13, 2013Inventors: Euan John Magennis, Kerry Louise Swabey
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Patent number: 8461094Abstract: A process for making a laundry liquid detergent comprising anionic detersive surfactant, the process comprising the steps of: a) making a base composition comprising alkanolamine and sodium ions in a molar ratio of from about 0.1:1 to 60:1; and b) adding water to the base composition.Type: GrantFiled: April 12, 2011Date of Patent: June 11, 2013Assignee: The Procter & Gamble CompanyInventors: Stephen Joseph Hodson, Eugene Joseph Pancheri
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Publication number: 20130005626Abstract: A surfactant composition comprising alkylarylsulfonate molecules wherein more than 30 wt. % of the alkylarylsulfonate molecules of the surfactant composition are species of the formula: [R—X—Ar(SO3)?]a[Mn+]b wherein: X is a linear acyclic aliphatic hydrocarbyl chain; R is bound to a non-terminal carbon atom of X and is selected from H and C1 to C3 alkyl groups; X and R together have 10 or less carbon atoms, preferably 9 or 10 carbon atoms, most preferably 10 carbon atoms; Ar is an aromatic group; M is a cation or cation mixture, n is selected from 1, 2 and 3; and a and b are selected such that the alkylarylsulfonate molecule is electroneutral.Type: ApplicationFiled: June 28, 2011Publication date: January 3, 2013Inventors: Burkhard Breitzke, Britta Jakobs-Sauter, Clemens Schröder, Udo Schoenkaes, Giuseppe Giuffrida, Lee Matheson, Kermit Kinsley, Michael Cox, Geoffrey Lynn Russell, John Barry Winder
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Patent number: 8129323Abstract: A solid laundry detergent composition in particulate form comprising a plurality of particulate components, the composition comprises: alkyl benzene sulphonate anionic detersive surfactant; carboxylate polymer; carbonate salt; from 0% to less than 5%, by weight of the composition, of zeolite builder; from 0% to less than 5%, by weight of the composition, of phosphate builder; and essentially free silicate salt; wherein any particulate component that comprises at least 5%, by weight of the particulate component, of alkyl benzene sulphonate anionic detersive surfactant comprises a specific amount of carbonate salt to carboxylate polymer; and wherein the composition has a specific weight ratio of carbonate salt to carboxylate polymer.Type: GrantFiled: August 16, 2006Date of Patent: March 6, 2012Assignee: The Procter & Gamble CompanyInventors: Doris Appleby, Alan Thomas Brooker
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Publication number: 20110257067Abstract: A process for making a detergent composition including the step of forming a low-water-containing surfactant mixture including: i) a hexagonal-phase-in-water-forming surfactant; and ii) a sulphonate detersive surfactant.Type: ApplicationFiled: April 14, 2011Publication date: October 20, 2011Inventors: Nigel Patrick Somerville Roberts, Hossam Hassan Tantawy, Eric San Jose Robles, Marc Stephen Bardsley
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Patent number: 7928051Abstract: Polyethylene which comprises ethylene homopolymers and/or copolymers of ethylene with 1-alkenes and has a molar mass distribution width Mw/Mn of from 3 to 30, a density of from 0.945 to 0.965 g/cm3, a weight average molar mass Mw of from 50 000 g/mol to 200 000 g/mol, a HLMI of from 10 to 300 g/10 min and has from 0.1 to 15 branches/1000 carbon atoms, wherein the 1 to 15% by weight of the polyethylene having the highest molar masses have a degree of branching of more than 1 branch of side chains larger than CH3/1000 carbon atoms, a process for its preparation, catalysts suitable for its preparation and also injection moldings in which this polyethylene is present.Type: GrantFiled: April 25, 2005Date of Patent: April 19, 2011Assignee: Basell Polyolefine GmbHInventors: Jennifer Kipke, Shahram Mihan, Rainer Karer, Dieter Lilge
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Patent number: 7928050Abstract: An improved method for predicting stability of liquid detergent composition, identifying and designing liquid detergent compositions that provide said desired stability, consumer acceptance and performance.Type: GrantFiled: May 27, 2010Date of Patent: April 19, 2011Assignee: The Procter & Gamble CompanyInventors: Eva Schneiderman, Genevieve Cagalawan Wenning, Peggy Marion Teyssier, David Robert Nassano, David Kent Rollins, Donna Jane Wiedemann, Arturo Luis Casado Dominguez, Rajan Keshev Panandiker
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Patent number: 7910534Abstract: The present invention relates to a solid laundry detergent composition in particulate form comprising a plurality of particulate components, the composition comprises: (i) an alkyl benzene sulphonate; (ii) a hydratable material; (iii) from 0% to less than 5%, by weight of the composition, of zeolite builder; (iv) from 0% to less than 5%, by weight of the composition, of phosphate builder; and (v) optionally, from 0% to less than 5%, by weight of the composition, of silicate salt; wherein at least 30%, by weight of the composition, of the particulate components present in the composition comprise at least 15%, by weight of the particulate component, of the hydratable material, and wherein any particulate component comprising at least 5%, by weight of the particulate component, of alkyl benzene sulphonate also comprises at least 15%, by weight of the particulate component, of the hydratable material.Type: GrantFiled: August 16, 2006Date of Patent: March 22, 2011Assignee: The Procter & Gamble CompanyInventors: John Peter Eric Muller, Lourdes Marina Ramirez Hernandez
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Patent number: 7867969Abstract: Disclosed herein is a composition for washing keratin materials, comprising, in an aqueous medium: (a) at least one first anionic surfactant in the form of a magnesium salt, (b) at least one second anionic surfactant different from the first, (c) at least one amphoteric or zwitterionic surfactant, (d) at least one oxyethylenated sorbitan ester, and (e) at least one polymer chosen from cationic polymers and amphoteric or zwitterionic polymers. Also disclosed herein is a cosmetic treatment process comprising applying such a composition to the hair.Type: GrantFiled: October 30, 2006Date of Patent: January 11, 2011Assignee: L'Oreal S.A.Inventors: Sandrine Decoster, Béatrice Thomas
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Patent number: 7795196Abstract: A hand-washing method using an antimicrobial liquid hand soap which includes: (a) water; (b) a primary hand soap composition; (c) a biocide; and (d) a glutinous surfactant having a relative contact angle value with water of at least about +10° with respect to the primary hand soap composition. The glutinous surfactant is present in an amount effective to alter the tactile properties of the primary soap composition to promote longer and more thorough hand washing by eliciting a response to the soap's feel on the skin.Type: GrantFiled: March 11, 2009Date of Patent: September 14, 2010Assignee: Georgia-Pacific Consumer Products LPInventors: Phuong V. Luu, Kurt K. Konietzki, David W. White
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Patent number: 7754671Abstract: This invention relates to a aqueous liquid laundry composition which both cleans and conditions fabrics. The composition includes certain alcohol ethoxylates as a nonionic surfactant component, certain alkyl ether sulfates as an anionic component and a quaternary ammonium fabric softening agent. All of the foregoing are in specified proportions.Type: GrantFiled: December 21, 2005Date of Patent: July 13, 2010Assignee: The Dial CorporationInventors: Bin Lin, Michael Lewis, Thorsten Bastigkeit
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Patent number: 7648952Abstract: A liquid washing and cleaning composition comprising: one or more of constituents a1) through a4) a1) alkylbenzenesulfonate, a2) olefinsulfonate, a3) alkylsulfate, a4) alkyl ether sulfate or mixtures thereof, b) secondary alkanesulfonate, c) at least one soap, d) at least one nonionic surfactant and e) at least one cationic surfactant, wherein the mixing ratio of the secondary alkanesulfonate to the component AT formed from the one or more of constituents a1, a2, a3 and a4 is 4.9 to 0.1: 5.1 to 9.9.Type: GrantFiled: November 5, 2005Date of Patent: January 19, 2010Assignee: Clariant Produkte (Deutschland) GmbHInventor: Frank-Peter Lang
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Patent number: 7605116Abstract: A solid laundry detergent composition comprising: (a) from 0.1 wt % to 10 wt % of an alkoxylated anionic detersive surfactant; (b) from 1 wt % to 25 wt % of an non-alkoxylated anionic detersive surfactant; (c) from 0 wt % to 4 wt % zeolite builder; (d) from 0 wt % to 4 wt % phosphate builder; and (e) from 0 wt % to 10 wt % silicate salt.Type: GrantFiled: August 11, 2005Date of Patent: October 20, 2009Assignee: The Procter & Gamble CompanyInventors: Alan Thomas Brooker, Kevin Lee Kott, Nicola Ethel Davidson, Lindsey Heathcote, John Peter Eric Muller, Mark Allen Smerznak, Nigel Patrick Sommerville-Roberts, Kenji Shindo, Emmanuel Pantelis Fakoukakis, Jason Christopher King
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Patent number: 7553804Abstract: The present invention discloses aqueous LCD cleaning agent compounds and their fabrication methods. Said cleaning agent compounds comprise of double fatty acid polyethylene glycol ester, fatty alcohol polyoxyethylene ether, polyethylene(3) glycol alkyl ether tri(alkyl ethers)amine sulfate and/or polyethylene(3) glycol enyl ether tri(alkyl ethers)amine sulfate, alkyl benzenesulfonic acid, lecithins and water. In particular, the weight of the ingredients in the compounds as a weight percentage of the weight of the compounds is: double fatty acid polyethylene glycol ester (10-50 wt %), fatty alcohol polyoxyethylene ether (5-60 wt %), polyethylene(3) glycol alkyl ether tri(alkyl ethers)amine sulfate and/or polyethylene(3) glycol enyl ether tri(alkyl ethers)amine sulfate (5-20 wt %), alkyl benzenesulfonic acid (1-15 wt %), lecithins (1-10 wt %), water (5-50 wt %).Type: GrantFiled: December 26, 2006Date of Patent: June 30, 2009Assignee: BYD Company LimitedInventors: Dong Liu, Xuegang Chen, Junqing Dong, Qing Gong, Zhiql He
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Patent number: 7521404Abstract: An antimicrobial liquid hand soap composition includes: (a) water; (b) a primary hand soap composition; (c) a biocide; and (d) a glutinous surfactant having a relative contact angle value with water of at least about +10° with respect to the primary hand soap composition. The glutinous surfactant is present in an amount effective to alter the tactile properties of the primary soap composition to promote longer and more thorough hand washing by eliciting a response to the soap's feel on the skin.Type: GrantFiled: December 15, 2005Date of Patent: April 21, 2009Assignee: Georgia-Pacific Consumer Products LPInventors: Phuong V. Luu, Kurt K. Konietzki, David W. White
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Patent number: 7417017Abstract: A unique liquid laundry detergent with enhanced stain removal capacity on bleachable stains is described that comprises linear alkyl benzene sulfonate, alkyl ether sulfate, alcohol ethoxylate, alkali metal silicate, polyacrylate, and optionally carbonate. The composition is remarkably effective at stain removal although the composition is entirely devoid of enzymes and the wash conditions devoid of any bleach additives.Type: GrantFiled: September 7, 2006Date of Patent: August 26, 2008Assignee: The Dial CorporationInventors: Thorsten Bastigkeit, Jessica Lawshe, Joan Bergstrom, Daniel Wood
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Patent number: 7387992Abstract: A laundry detergent composition comprising from about 0.1% to about 80%, by weight of the composition, of a polyamine mono-anionic surfactant; and a solubiliser; in a defined weight ratio. Also, a process of making the polyamine mono-anionic surfactant and the laundry compositions containing the same.Type: GrantFiled: March 15, 2005Date of Patent: June 17, 2008Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Feng-Lung Gordon Hsu, Shui-Ping Zhu, Mei Shi
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Patent number: 7354892Abstract: A unique laundry detergent composition is described that comprises linear alkyl benzene sulfonate, alkyl ether sulfate, alcohol ethoxylate, fatty acid, an alkali metal silicate, polyacrylate, and optionally carbonate, that is low sudsing and that shows improved whiteness retention over other fatty acid soap containing detergents in the absence of silicates.Type: GrantFiled: September 7, 2006Date of Patent: April 8, 2008Assignee: The Dial CorporationInventors: Thorsten Bastigkeit, Jessica Lawshe, Daniel Wood, Aurora Stamper, Joan Bergstrom
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Patent number: 7115550Abstract: A liquid dish cleaning composition with desirable cleansing properties comprising two C8-18 ethoxylated alkyl ether sulfate surfactants, two anionic surfactant, an amine oxide surfactant, and water.Type: GrantFiled: January 23, 2006Date of Patent: October 3, 2006Assignee: Colgate-Palmolive CompanyInventor: Gregory Szewczyk
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Patent number: 7033986Abstract: A liquid dish cleaning composition with desirable cleansing properties comprising two C8-18 ethoxylated alkyl ether sulfate surfactants, two anionic surfactant, an amine oxide surfactant, and water.Type: GrantFiled: August 28, 2003Date of Patent: April 25, 2006Assignee: Colgate-Palmolive CompanyInventor: Gregory Szewczyk
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Patent number: 7008914Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.Type: GrantFiled: October 3, 2002Date of Patent: March 7, 2006Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi, John F. Knifton, Melvin Stockton
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Patent number: 6995127Abstract: This invention is directed to detergent compositions which employ sulfonated alkyltoluenes as surfactants, wherein the sulfonated alkyltoluenes have a higher content of the sulfonated 2-phenyl alkyltoluenes isomers than was previously available in sulfonated alkyltoluene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated alkyltoluenes having lower contents of the 2-phenyl alkyltoluene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkyltoluenes are also provided, including dry cleaning formulations containing same.Type: GrantFiled: September 19, 2000Date of Patent: February 7, 2006Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi
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Patent number: 6964945Abstract: The invention relates to solid detergent compositions comprising an aluminosilicate builder and an anionic surfactant and comprising (n) components (i), n being at least 2, whereby the level of aluminosilicate builder in said components together is at least 5% by weight of the composition and the level of the anionic surfactant in said components together is at least 5% by weight of the composition, and whereby the degree of mixture (M) of the anionic surfactant and the aluminosilicate builder is from 0 to 0.7, as defined in the description.Type: GrantFiled: September 25, 1998Date of Patent: November 15, 2005Assignee: The Procter & Gamble CompanyInventors: Richard Timothy Hartshorn, Zayeed Alam, Kevin Norwood
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Patent number: 6919304Abstract: Novel bleaching compositions comprising organic catalyst compounds, preferably branched organic catalyst compounds, and an anionic surfactant, methods for laundering fabrics using such bleaching compositions, and laundry additive products containing such bleaching compositions are provided.Type: GrantFiled: February 27, 2002Date of Patent: July 19, 2005Assignee: Procter & Gamble CompanyInventors: Robert Richard Dykstra, Marc Eric Gustwiller, Tonya Ann Howard
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Patent number: 6903060Abstract: The present invention relates to formulation components, such as organic catalyst compounds having increased stability, compositions and laundry methods employing such organic catalyst compounds. More particularly, this invention relates to organic catalysts compounds such as quaternary imine bleach boosting compounds, quaternary oxaziridinium bleaching species, modified amines and amine oxides, compositions and laundry methods employing such organic catalyst compounds.Type: GrantFiled: August 25, 2000Date of Patent: June 7, 2005Assignee: Procter & Gamble CompanyInventors: Robert Richard Dykstra, Penny Sue Weed
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Patent number: 6887839Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.Type: GrantFiled: February 19, 2003Date of Patent: May 3, 2005Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
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Patent number: 6797011Abstract: Compositions which are used directly in the conventional home laundry machine to clean and renourish articles made from leather, textile and synthetic leather. Specifically, two separate compositions are used during a typical washing cycle in the home washing machine. First, the leather laundry solution is added during the “wash cycle.” Subsequently a laundry rinse and dressing composition is added to the finishing rinse cycle of the washing machine. The composition may also be used as a wipe-on application after laundering.Type: GrantFiled: December 5, 2002Date of Patent: September 28, 2004Inventor: Anna Carner Blangiforti
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Patent number: 6730650Abstract: A liquid detergent composition includes an anionic surfactant component, a viscosity-enhancing agent, and a liquid carrier. The liquid detergent composition is substantially free of nonionic surfactant. The anionic surfactant component is present in an amount at least as great as about 2% by weight. The anionic surfactant component is also present in an amount no greater than about 7% by weight. The anionic surfactant component includes an alkyl ether sulfate material and a linear alkyl benzene sulfonate material which are present in a ratio in the range of from about 5:1 to about 1:0.5. The viscosity-enhancing agent is present in an amount sufficient so that the liquid detergent composition has a viscosity no less than about 120 centipoise.Type: GrantFiled: July 9, 2002Date of Patent: May 4, 2004Assignee: The Dial CorporationInventor: Daniel Wood
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Patent number: 6730649Abstract: A detergent composition comprising: (a) at least 5 wt % of a calcium-tolerant non-soap anionic surfactant system which comprises an alpha-olefin sulphonate; (b) at least 0.1 wt % of a cationic surfactant system in a weight ratio of (a):(b) of from 17:3 to 9:10, preferably from 3:1 to 1:1; and (c) the balance, if any, being other detergent ingredients.Type: GrantFiled: December 19, 2001Date of Patent: May 4, 2004Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.Inventors: Kenneth Metcalfe, Vincent Charles Mole
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Patent number: 6716807Abstract: A detergent composition comprising: (a) more than 10 wt % of a calcium-tolerant non-soap anionic surfactant system; (b) from 0.1% to 10%, preferably from 0.5% to 10%, more preferably from 1% to 10% by weight of a strong builder system selected from phosphate builders and aluminosilicate builders and mixtures thereof; and (c) the balance, if any, being other detergent ingredients wherein said composition comprises less than 35 wt %, preferably less than 25 wt %, more preferably less than 15 wt % of non-functional non-alkaline water soluble inorganic salt.Type: GrantFiled: December 19, 2001Date of Patent: April 6, 2004Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Philippus Cornelis Van der Hoeven, Kenneth Metcalfe
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Patent number: 6706676Abstract: Disclosed is a cleaning composition for removing ink from a variety of surfaces. The composition has a low amount of volatile organic compounds (VOC) and a near neutral pH.Type: GrantFiled: May 15, 2002Date of Patent: March 16, 2004Assignee: New Dawn Manufacturing CompanyInventor: Charles Christopher Swensen
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Patent number: 6689276Abstract: An apparatus, method, and composition provide a long-term, solid cartridge made of cleaning agents mixed at an equilibrium concentration with a solubility limiting agent for controlling an equilibrium concentration of the composition in a solvent, such as water, for example. In use, the cleaning agents are dissolved only to a predetermined concentration needed for a single dose of a cleaning appliance, such as a clothes washing machine, for example. The apparatus may be configured to cyclically expose the solid cartridge to the solvent. A dosing amount of the solvent dissolves a pre-determined concentration of cleaning agents, controlled by the solubility limiting agent. The apparatus discharges the dose of cleaning agent to a cleaning appliance, and readies itself again by dissolving a dose of cleaning agent from a surface of the solid cartridge into the solvent.Type: GrantFiled: May 13, 2002Date of Patent: February 10, 2004Assignee: Eco-Safe Technologies, L.L.C.Inventor: Eddie Lee Caruthers, Jr.
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Patent number: 6677289Abstract: The present invention relates to detergent compositions comprising a mid-chain branched surfactant and also containing a bleaching agent, aluminosilicate, silicate, and/or detersive enzyme.Type: GrantFiled: December 3, 2001Date of Patent: January 13, 2004Assignee: The Procter & Gamble CompanyInventors: Kenneth Nathan Price, Eugene Paul Gosselink, Randall Scott Deinhammer
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Patent number: 6635610Abstract: A detergent granule and tablets which comprises an anionic surfactant system which comprises an anionic sulphate surfactant and/or an anionic sulphonate surfactant and other detergent active ingredients, the granule comprising at least a first and a second particulate component and optionally a binding agent, characterised in that the ratio of anionic sulphate surfactant to anionic sulphonate surfactant in the particulate components and in the optional binding agent is less than 1:4 or more than 4:1, preferably even less than 1:5 or more than 5:1. The invention also relates to specific granules comprising restricted degree of mixing of anionic sulphonate surfactant and zeolite, anionic sulphate surfactant and carbonate salts and/or restricted degree of mixing of polymeric builder and anionic surfactant, in particular sulphate surfactants.Type: GrantFiled: July 23, 2001Date of Patent: October 21, 2003Assignee: The Procter & Gamble CompanyInventors: Teruaki Tatsuno, Richard Timonthy Hartshorn, Kevin Norwood, Paul R. Mort, III, David Scott Bohlen, Steven Matthew Gabriel, Rinko Katsuda, Noe Ongcoy Hidalgo
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Patent number: 6602839Abstract: Provided herein are sulfosuccinamates made using polyetheramines as intermediates. The sulfosuccinamates according to the invention exhibit excellent detergency when employed in formulations used as hard surface cleaners, laundry detergents, and dishwashing liquids. In addition, the sulfosuccinamates according to the invention have an unexpectedly high degree of water hardness tolerance, and are easier to produce than similar materials found in the prior art owing to the fact that the product and its intermediates exist in liquid form.Type: GrantFiled: January 5, 2001Date of Patent: August 5, 2003Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Raeda M. Smadi
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Publication number: 20030064905Abstract: A liquid detergent concentrate is provided. The liquid detergent concentrate includes about 1 wt. % to about 40 wt. % combination anionic surfactant component and nonionic surfactant component containing about 0.5 wt. % to about 30 wt. % anionic surfactant and about 0.5 wt. % to about 30 wt. % nonionic surfactant, about 5 wt. % to about 60 wt. % of a water conditioning agent, and about 40 wt. % to about 95 wt. % water. The liquid detergent concentrate can be diluted with water to provide a liquid detergent use solution containing greater than 95 wt. % water. A method for washing textiles is provided.Type: ApplicationFiled: July 17, 2001Publication date: April 3, 2003Inventors: David W. Gohl, Paul J. Mattia, Robert D. Hei, John W. Birckbichler, Richard D. Stardig
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Patent number: 6528474Abstract: The invention relates to a process for the production of substantially alumosilicate-free detergents containing a soluble builder system which provides free-flowing and storage-stable granules. In this process for the production of a particulate, substantially alumosilicate-free detergent, an anionic surfactant acid is sprayed onto a detergent component containing anionic surfactant and builders in order to increase the anionic surfactant content.Type: GrantFiled: July 5, 2000Date of Patent: March 4, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rene-Andres Artiga Gonzalez, Andreas Lietzmann, Maria Liphard, Wilfried Roehl
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Patent number: 6482788Abstract: A light duty, liquid comprising: a paraffin sulfonate, an alpha olefin sulfonate, an acid, a sultaine surfactant, an inorganic zinc salt, and water.Type: GrantFiled: May 13, 2002Date of Patent: November 19, 2002Assignee: Colgate-Palmolive CompanyInventor: Evangelia Arvanitidou
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Patent number: 6468956Abstract: Compositions containing a &agr;-sulfofatty acid ester and a hydrotrope. The &agr;-sulfofatty acid ester and the hydrotrope reduce the pH drift in the composition and solubilize the &agr;-sulfofatty acid ester in solution. Methods are also disclosed for making such compositions.Type: GrantFiled: May 24, 2000Date of Patent: October 22, 2002Assignee: Huish Detergents, Inc.Inventors: Paul Danton Huish, Laurie A. Jensen, Pule B. Libe
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Patent number: 6407054Abstract: There is provided a surfactant composition for detergents, which has its high detergency and foamability within a broad pH region even in the presence of solids. It has its excellent foamability, thickening property, water solubility and stability. The composition contains a component (a) represented by the following formula (I) and at least one component (b) represented by the formula (II) and (III), in the total amount of 0.1 to 80% by weight, at the ratio of (a)/(b) by weight of from 99.9/0.1 to 70/30. In the formula (I), R1CO— is a saturated or unsaturated acyl group which has 6 to 24 carbon atoms and which may have hydroxy group; R2 is a linear or branched alkyl group having 1 to 3 carbon atoms; and R3 is a linear or branched alkylene or alkenylene group having 1 to 6 carbon atoms.Type: GrantFiled: December 1, 2000Date of Patent: June 18, 2002Assignee: Kao CorporationInventors: Takaya Sakai, Makio Tetsu, Makoto Kubo, Akira Fujiu
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Patent number: 6403551Abstract: An apparatus, method, and composition provide a long-term, solid cartridge made of cleaning cleaning agents mixed at an equilibrium concentration with a solubility limiting agent for controlling an equilibrium concentration of the composition in a solvent, such as water, for example. In use, the cleaning agents are dissolved only to a predetermined concentration needed for a single dose of a cleaning appliance, such as a clothes washing machine, for example. The apparatus may be configured to cyclically expose the solid cartridge to the solvent. A dosing amount of the solvent dissolves a pre-determined concentration of cleaning agents, controlled by the solubility limiting agent. The apparatus discharges the dose of cleaning agent to a cleaning appliance, and readies itself again by dissolving a dose of cleaning agent from a surface of the solid cartridge into the solvent.Type: GrantFiled: November 10, 1999Date of Patent: June 11, 2002Assignee: Eco-Safe, L.L.C.Inventor: Eddie Lee Caruthers, Jr.