With Inorganic Phosphorus Containing Component Patents (Class 510/359)
  • Patent number: 10266791
    Abstract: Detergent compositions with improved sudsing profile, which are particularly suitable for hand-washing fabrics and dishware.
    Type: Grant
    Filed: November 8, 2016
    Date of Patent: April 23, 2019
    Assignee: The Procter & Gamble Company
    Inventors: Ming Tang, Qing Chen, Wenting Liu, Shuo Li
  • Publication number: 20090325850
    Abstract: The present invention relates to a process for preparing a spray-dried powder comprising (i) anionic detersive surfactant; (ii) from 0 wt % to 10 wt % zeolite builder; (iii) from 0 wt % to 10 wt % phosphate builder; and (iv) optionally from 0 wt % to 15 wt % silicate salt; wherein the process comprises the steps of: (a) forming an alkaline slurry in a mixer, the slurry having a viscosity of from X to Y s?1 at a temperature of 70° C.
    Type: Application
    Filed: June 8, 2009
    Publication date: December 31, 2009
    Inventors: Hossam Hassan Tantawy, Nigel Patrick Somerville Roberts, Simon Howe, Stuart Andrew Caldwell
  • Publication number: 20090305939
    Abstract: A detergent composition comprising at most 15% by weight of phosphate builder(s) and aluminosilicate builder(s), and comprising at least one short chain anionic surfactant selected from alkyl sulfate surfactant(s) and alkyl sulfonate surfactants.
    Type: Application
    Filed: June 4, 2009
    Publication date: December 10, 2009
    Inventors: Ming Tang, Qing Chen, Sen Liu, Kenneth Nathan Price
  • Patent number: 7375072
    Abstract: A builder-containing laundry detergent or cleaning composition is comprised of: (1) alkali metal percarbonate; (2) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 10% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (3) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise alkali metal percarbonates and contain only water-soluble builders.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: May 20, 2008
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Josef Penninger
  • Patent number: 7316995
    Abstract: A builder-containing laundry detergent or cleaning composition comprising: (1) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 5% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (2) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise only water-soluble builders.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: January 8, 2008
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Josef Penninger
  • Patent number: 6730649
    Abstract: A detergent composition comprising: (a) at least 5 wt % of a calcium-tolerant non-soap anionic surfactant system which comprises an alpha-olefin sulphonate; (b) at least 0.1 wt % of a cationic surfactant system in a weight ratio of (a):(b) of from 17:3 to 9:10, preferably from 3:1 to 1:1; and (c) the balance, if any, being other detergent ingredients.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: May 4, 2004
    Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.
    Inventors: Kenneth Metcalfe, Vincent Charles Mole
  • Patent number: 6716807
    Abstract: A detergent composition comprising: (a) more than 10 wt % of a calcium-tolerant non-soap anionic surfactant system; (b) from 0.1% to 10%, preferably from 0.5% to 10%, more preferably from 1% to 10% by weight of a strong builder system selected from phosphate builders and aluminosilicate builders and mixtures thereof; and (c) the balance, if any, being other detergent ingredients wherein said composition comprises less than 35 wt %, preferably less than 25 wt %, more preferably less than 15 wt % of non-functional non-alkaline water soluble inorganic salt.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: April 6, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Philippus Cornelis Van der Hoeven, Kenneth Metcalfe
  • Patent number: 6572842
    Abstract: The invention relates to a preparation for chemical-mechanical treatment of caries by means of a caries-dissolving two-component liquid. One of the components is an active, caries dissolving component and the other a component which reduces the aggressiveness of the active component to mucous membranes. The active component is a chloride compound comprising active chlorine, i.e. chlorine having a charge state of +1, Cl(+1), which chloride has a somewhat lower reactivity than sodium hypochlorite and then also a somewhat reduced dissolving effect on the carious substance.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: June 3, 2003
    Assignee: Mediteam Dental, AB
    Inventors: Rolf Bornstein, Lennart Carlsson, Stefan Dahlin
  • Patent number: 6528474
    Abstract: The invention relates to a process for the production of substantially alumosilicate-free detergents containing a soluble builder system which provides free-flowing and storage-stable granules. In this process for the production of a particulate, substantially alumosilicate-free detergent, an anionic surfactant acid is sprayed onto a detergent component containing anionic surfactant and builders in order to increase the anionic surfactant content.
    Type: Grant
    Filed: July 5, 2000
    Date of Patent: March 4, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rene-Andres Artiga Gonzalez, Andreas Lietzmann, Maria Liphard, Wilfried Roehl
  • Patent number: 6207635
    Abstract: A process for preparing detergent agglomerates is disclosed. The process includes the steps of (a) preparing a mixture of detergent components in a mixer, and (b) agglomerating the mixture from step (a) in a moderate speed mixer to produce detergent agglomerates. The detergent components include (1) from about 20% to about 35% of a surfactant compound selected from the group consisting of anionic surfactants and acid precursors of anionic surfactants; (2) from about 0% to about 65% of a particulate phosphate builder selected from the group consisting of polyphosphate, pyrophosphate, and mixtures thereof; (3) from about 6% to about 60% of a particulate carbonate selected from the group consisting of sodium carbonate, potassium carbonate, and mixtures thereof.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: March 27, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Donald Scott Adams, Bruce Albert Yeazell, Eric Fitzgerald Riddick, Junan Kao
  • Patent number: 6121225
    Abstract: A stabilized aqueous enzyme composition comprising water, from about 0.1% to about 75% by weight of a detergent surfactant selected from the group consisting of anionic surfactants or anionic surfactants and one or more non-anionic detergent actives, from about 0.001% to about 10% by weight proteolytic enzyme, and an effective amount of an enzyme stabilizer having the formula:X--O--(C.sub.n H.sub.2n O).sub.a --H [I]wherein "X" is an organic radical having from 14 to 22 carbon atoms, "a" is an integer from 10 to 26, and "n" is an integer from 2 to 4, and provided that "X" has a hydrophobicity similar to a linear alkyl group having from 14 to 22 carbon atoms.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: September 19, 2000
    Assignee: CONDEA Vista Company
    Inventors: Larry N. Britton, Geoffrey L. Russell, Allen M. Nielsen
  • Patent number: 5994285
    Abstract: A stable structured liquid laundry detergent composition is provided which is particularly effective for removing oily soils from fabrics. The detergent composition comprises, by weight:(a) from about 10% to about 20% of a linear alkyl benzene sulfonate anionic surfactant;(b) from about 0% to about 10% of an alkyl ether sulfate anionic surfactant;(c) from about 5% to about 30% of an alkali metal phosphorous-containing builder;(d) from about 2% to about 15% of sodium carbonate; the total amount of components (c) plus (d) in the detergent composition being at least about 10%;(e) from about 0.1% to about 5% of an ethoxylated amine quaternary cationic surfactant having the following structural formula: ##STR1## wherein R.sub.1 represents a linear branched or substituted C.sub.8 -C.sub.18 alkyl, alkaryl, aryl, alkenyl or ether moiety; R.sub.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: November 30, 1999
    Assignee: Colgate-Palmolive Co.
    Inventors: Amit Sachdev, Suzanne M. Jogun
  • Patent number: 5955413
    Abstract: Organic solvent free carpet cleaning compositions maintain the stainblocking properties of factory applied treatments. The compositions contain a methacrylic acid polymer component, a sequestering agent, an anionic surfactant, and optionally water.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: September 21, 1999
    Assignee: 3M Innovative Properties Company
    Inventors: Jason A. Campagna, Richard S. Smith
  • Patent number: 5872093
    Abstract: A detergent composition with excellent color care properties. The detergent composition comprises a dendritic macromolecule.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: February 16, 1999
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Daniel Convents, Rudolf Willem Pieter van Drunen, Jean Hypolites Koek
  • Patent number: 5837665
    Abstract: An effective carpet spot cleaner is provided which is comprised of sodium polyphosphate and/or sodium tripolyphosphate; sodium dodecylbenzenesulfonate and Butyl Cellosolve.
    Type: Grant
    Filed: June 9, 1997
    Date of Patent: November 17, 1998
    Inventor: Robert Young
  • Patent number: 5827815
    Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising an ethoxylated fatty alcohol nonionic surfactant, a sulfated ethoxylated fatty alcohol anionic surfactant, and an N-alkyl and/or unsaturated hydrocarbyl amine of an alkanoic acid or salt thereof as an amphoteric surfactant.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: October 27, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
  • Patent number: 5821216
    Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising a sulfated ethoxylated fatty alcohol anionic surfactant and two ethoxylated fatty alcohol nonionic surfactants having different average numbers of carbon atoms in the fatty alcohol and average numbers of ethoxy groups.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: October 13, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
  • Patent number: 5686402
    Abstract: Laundry detergent compositions containing a detergent surfactant, a detergent builder, and from about 0.1% to about 50% by weight ethylene dicysteate or its acid form are disclosed. These compositions provide enhanced removal of organic stains, such as food and beverage stains particularly polyphenolic stains such as wine, blueberry, tea, coffee, morello juice and the like.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: November 11, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Eddie Nelson Gutierrez, Shang-Ren Wu, Robert Vermeer
  • Patent number: 5633224
    Abstract: A high density granular detergent composition having a pH (1% in distilled water) of from about 9.0 to about 10.0, that contains from 5% to about 50% anionic detergent surfactant and from about 3% to about 40% acid pyrophosphate is disclosed. The composition is formed by agglomeration of the acid pyrophosphate and a portion of the surfactant, preferably in a V-blender. The composition contains less than about 1%, but preferably is free of, citric acid.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: May 27, 1997
    Assignee: The Procter & Gamble Company
    Inventor: Terrence J. Porter
  • Patent number: 5597794
    Abstract: The invention is a process for producing surfactant granules by mixing a water-containing surfactant with a solid to form granules, drying the granules and recycling the dried granules as a portion of the solid.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: January 28, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Volker Bauer, Wilfried Raehse, Andreas Syldath, Ditmar Kischkel
  • Patent number: 5573697
    Abstract: A continuous process for producing high active, high density detergent granules consists essentially of the following steps:(a) preparing a mixture in a high-speed mixer, the mixture being prepared from components fed to the mixer consisting essentially of the following:(1) from about 15% to about 35% anionic surfactant acid selected from alkylbenzene sulfonic acid and alkyl sulfuric acid and mixtures thereof;(2) from about 5% to about 65% phosphate builder selected from polyphosphates and pyrophosphates and mixtures thereof; and(3) from about 10% to about 65% particulate carbonate selected from sodium carbonate and potassium carbonate and mixtures thereof, the amount of carbonate being at least about 2 times the amount theoretically needed to neutralize the anionic surfactant acid;(b) agglomerating the mixture from step (a) in a moderate-speed mixer; whereby the anionic surfactant acid is neutralized by the carbonate, and the resulting detergent granules have a bulk density of greater than about 550 g/l and
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: November 12, 1996
    Inventors: Eric F. Riddick, Judith A. Lakes
  • Patent number: 5552078
    Abstract: A powdered laundry detergent composition comprising an active surfactant, at least about 70 wt. % of a water soluble alkaline carbonate salt, e.g., sodium carbonate, about 0.1 to 2 wt. % of a phosphorus-containing sequestering agent, e.g., sodium tripolyphosphate (STPP), about 0.1 to 2 wt. % of a polymeric polycarboxylate, e.g., a polyacrylate or a polymaleate, and about 1-12 wt. % water. Use of the foregoing detergent composition provides excellent cleaning and whitening of fabrics while avoiding the problem of eutrophication which occurs when a substantial amount of a phosphorus containing builder such as STPP is present in the composition, and while minimizing the problem of fabric encrustation often present when the composition contains a large amount of carbonate builder.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: September 3, 1996
    Assignee: Church & Dwight Co., Inc.
    Inventors: Charles D. Carr, Steven A. Bolkan, Joseph G. Becker