With Inorganic Phosphorus Containing Component Patents (Class 510/359)
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Patent number: 10266791Abstract: Detergent compositions with improved sudsing profile, which are particularly suitable for hand-washing fabrics and dishware.Type: GrantFiled: November 8, 2016Date of Patent: April 23, 2019Assignee: The Procter & Gamble CompanyInventors: Ming Tang, Qing Chen, Wenting Liu, Shuo Li
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Publication number: 20090325850Abstract: The present invention relates to a process for preparing a spray-dried powder comprising (i) anionic detersive surfactant; (ii) from 0 wt % to 10 wt % zeolite builder; (iii) from 0 wt % to 10 wt % phosphate builder; and (iv) optionally from 0 wt % to 15 wt % silicate salt; wherein the process comprises the steps of: (a) forming an alkaline slurry in a mixer, the slurry having a viscosity of from X to Y s?1 at a temperature of 70° C.Type: ApplicationFiled: June 8, 2009Publication date: December 31, 2009Inventors: Hossam Hassan Tantawy, Nigel Patrick Somerville Roberts, Simon Howe, Stuart Andrew Caldwell
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Publication number: 20090305939Abstract: A detergent composition comprising at most 15% by weight of phosphate builder(s) and aluminosilicate builder(s), and comprising at least one short chain anionic surfactant selected from alkyl sulfate surfactant(s) and alkyl sulfonate surfactants.Type: ApplicationFiled: June 4, 2009Publication date: December 10, 2009Inventors: Ming Tang, Qing Chen, Sen Liu, Kenneth Nathan Price
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Patent number: 7375072Abstract: A builder-containing laundry detergent or cleaning composition is comprised of: (1) alkali metal percarbonate; (2) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 10% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (3) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise alkali metal percarbonates and contain only water-soluble builders.Type: GrantFiled: August 10, 2005Date of Patent: May 20, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Josef Penninger
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Patent number: 7316995Abstract: A builder-containing laundry detergent or cleaning composition comprising: (1) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 5% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (2) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise only water-soluble builders.Type: GrantFiled: August 10, 2005Date of Patent: January 8, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Josef Penninger
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Patent number: 6730649Abstract: A detergent composition comprising: (a) at least 5 wt % of a calcium-tolerant non-soap anionic surfactant system which comprises an alpha-olefin sulphonate; (b) at least 0.1 wt % of a cationic surfactant system in a weight ratio of (a):(b) of from 17:3 to 9:10, preferably from 3:1 to 1:1; and (c) the balance, if any, being other detergent ingredients.Type: GrantFiled: December 19, 2001Date of Patent: May 4, 2004Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.Inventors: Kenneth Metcalfe, Vincent Charles Mole
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Patent number: 6716807Abstract: A detergent composition comprising: (a) more than 10 wt % of a calcium-tolerant non-soap anionic surfactant system; (b) from 0.1% to 10%, preferably from 0.5% to 10%, more preferably from 1% to 10% by weight of a strong builder system selected from phosphate builders and aluminosilicate builders and mixtures thereof; and (c) the balance, if any, being other detergent ingredients wherein said composition comprises less than 35 wt %, preferably less than 25 wt %, more preferably less than 15 wt % of non-functional non-alkaline water soluble inorganic salt.Type: GrantFiled: December 19, 2001Date of Patent: April 6, 2004Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Philippus Cornelis Van der Hoeven, Kenneth Metcalfe
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Patent number: 6572842Abstract: The invention relates to a preparation for chemical-mechanical treatment of caries by means of a caries-dissolving two-component liquid. One of the components is an active, caries dissolving component and the other a component which reduces the aggressiveness of the active component to mucous membranes. The active component is a chloride compound comprising active chlorine, i.e. chlorine having a charge state of +1, Cl(+1), which chloride has a somewhat lower reactivity than sodium hypochlorite and then also a somewhat reduced dissolving effect on the carious substance.Type: GrantFiled: October 17, 2001Date of Patent: June 3, 2003Assignee: Mediteam Dental, ABInventors: Rolf Bornstein, Lennart Carlsson, Stefan Dahlin
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Patent number: 6528474Abstract: The invention relates to a process for the production of substantially alumosilicate-free detergents containing a soluble builder system which provides free-flowing and storage-stable granules. In this process for the production of a particulate, substantially alumosilicate-free detergent, an anionic surfactant acid is sprayed onto a detergent component containing anionic surfactant and builders in order to increase the anionic surfactant content.Type: GrantFiled: July 5, 2000Date of Patent: March 4, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rene-Andres Artiga Gonzalez, Andreas Lietzmann, Maria Liphard, Wilfried Roehl
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Patent number: 6207635Abstract: A process for preparing detergent agglomerates is disclosed. The process includes the steps of (a) preparing a mixture of detergent components in a mixer, and (b) agglomerating the mixture from step (a) in a moderate speed mixer to produce detergent agglomerates. The detergent components include (1) from about 20% to about 35% of a surfactant compound selected from the group consisting of anionic surfactants and acid precursors of anionic surfactants; (2) from about 0% to about 65% of a particulate phosphate builder selected from the group consisting of polyphosphate, pyrophosphate, and mixtures thereof; (3) from about 6% to about 60% of a particulate carbonate selected from the group consisting of sodium carbonate, potassium carbonate, and mixtures thereof.Type: GrantFiled: August 27, 1998Date of Patent: March 27, 2001Assignee: The Procter & Gamble CompanyInventors: Donald Scott Adams, Bruce Albert Yeazell, Eric Fitzgerald Riddick, Junan Kao
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Patent number: 6121225Abstract: A stabilized aqueous enzyme composition comprising water, from about 0.1% to about 75% by weight of a detergent surfactant selected from the group consisting of anionic surfactants or anionic surfactants and one or more non-anionic detergent actives, from about 0.001% to about 10% by weight proteolytic enzyme, and an effective amount of an enzyme stabilizer having the formula:X--O--(C.sub.n H.sub.2n O).sub.a --H [I]wherein "X" is an organic radical having from 14 to 22 carbon atoms, "a" is an integer from 10 to 26, and "n" is an integer from 2 to 4, and provided that "X" has a hydrophobicity similar to a linear alkyl group having from 14 to 22 carbon atoms.Type: GrantFiled: December 21, 1998Date of Patent: September 19, 2000Assignee: CONDEA Vista CompanyInventors: Larry N. Britton, Geoffrey L. Russell, Allen M. Nielsen
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Patent number: 5994285Abstract: A stable structured liquid laundry detergent composition is provided which is particularly effective for removing oily soils from fabrics. The detergent composition comprises, by weight:(a) from about 10% to about 20% of a linear alkyl benzene sulfonate anionic surfactant;(b) from about 0% to about 10% of an alkyl ether sulfate anionic surfactant;(c) from about 5% to about 30% of an alkali metal phosphorous-containing builder;(d) from about 2% to about 15% of sodium carbonate; the total amount of components (c) plus (d) in the detergent composition being at least about 10%;(e) from about 0.1% to about 5% of an ethoxylated amine quaternary cationic surfactant having the following structural formula: ##STR1## wherein R.sub.1 represents a linear branched or substituted C.sub.8 -C.sub.18 alkyl, alkaryl, aryl, alkenyl or ether moiety; R.sub.Type: GrantFiled: June 14, 1999Date of Patent: November 30, 1999Assignee: Colgate-Palmolive Co.Inventors: Amit Sachdev, Suzanne M. Jogun
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Patent number: 5955413Abstract: Organic solvent free carpet cleaning compositions maintain the stainblocking properties of factory applied treatments. The compositions contain a methacrylic acid polymer component, a sequestering agent, an anionic surfactant, and optionally water.Type: GrantFiled: October 24, 1997Date of Patent: September 21, 1999Assignee: 3M Innovative Properties CompanyInventors: Jason A. Campagna, Richard S. Smith
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Patent number: 5872093Abstract: A detergent composition with excellent color care properties. The detergent composition comprises a dendritic macromolecule.Type: GrantFiled: December 12, 1996Date of Patent: February 16, 1999Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Daniel Convents, Rudolf Willem Pieter van Drunen, Jean Hypolites Koek
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Patent number: 5837665Abstract: An effective carpet spot cleaner is provided which is comprised of sodium polyphosphate and/or sodium tripolyphosphate; sodium dodecylbenzenesulfonate and Butyl Cellosolve.Type: GrantFiled: June 9, 1997Date of Patent: November 17, 1998Inventor: Robert Young
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Patent number: 5827815Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising an ethoxylated fatty alcohol nonionic surfactant, a sulfated ethoxylated fatty alcohol anionic surfactant, and an N-alkyl and/or unsaturated hydrocarbyl amine of an alkanoic acid or salt thereof as an amphoteric surfactant.Type: GrantFiled: April 29, 1997Date of Patent: October 27, 1998Assignee: Church & Dwight Co., Inc.Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
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Patent number: 5821216Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising a sulfated ethoxylated fatty alcohol anionic surfactant and two ethoxylated fatty alcohol nonionic surfactants having different average numbers of carbon atoms in the fatty alcohol and average numbers of ethoxy groups.Type: GrantFiled: April 21, 1997Date of Patent: October 13, 1998Assignee: Church & Dwight Co., Inc.Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
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Patent number: 5686402Abstract: Laundry detergent compositions containing a detergent surfactant, a detergent builder, and from about 0.1% to about 50% by weight ethylene dicysteate or its acid form are disclosed. These compositions provide enhanced removal of organic stains, such as food and beverage stains particularly polyphenolic stains such as wine, blueberry, tea, coffee, morello juice and the like.Type: GrantFiled: December 27, 1995Date of Patent: November 11, 1997Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Eddie Nelson Gutierrez, Shang-Ren Wu, Robert Vermeer
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Patent number: 5633224Abstract: A high density granular detergent composition having a pH (1% in distilled water) of from about 9.0 to about 10.0, that contains from 5% to about 50% anionic detergent surfactant and from about 3% to about 40% acid pyrophosphate is disclosed. The composition is formed by agglomeration of the acid pyrophosphate and a portion of the surfactant, preferably in a V-blender. The composition contains less than about 1%, but preferably is free of, citric acid.Type: GrantFiled: June 22, 1995Date of Patent: May 27, 1997Assignee: The Procter & Gamble CompanyInventor: Terrence J. Porter
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Patent number: 5597794Abstract: The invention is a process for producing surfactant granules by mixing a water-containing surfactant with a solid to form granules, drying the granules and recycling the dried granules as a portion of the solid.Type: GrantFiled: October 17, 1994Date of Patent: January 28, 1997Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Volker Bauer, Wilfried Raehse, Andreas Syldath, Ditmar Kischkel
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Patent number: 5573697Abstract: A continuous process for producing high active, high density detergent granules consists essentially of the following steps:(a) preparing a mixture in a high-speed mixer, the mixture being prepared from components fed to the mixer consisting essentially of the following:(1) from about 15% to about 35% anionic surfactant acid selected from alkylbenzene sulfonic acid and alkyl sulfuric acid and mixtures thereof;(2) from about 5% to about 65% phosphate builder selected from polyphosphates and pyrophosphates and mixtures thereof; and(3) from about 10% to about 65% particulate carbonate selected from sodium carbonate and potassium carbonate and mixtures thereof, the amount of carbonate being at least about 2 times the amount theoretically needed to neutralize the anionic surfactant acid;(b) agglomerating the mixture from step (a) in a moderate-speed mixer; whereby the anionic surfactant acid is neutralized by the carbonate, and the resulting detergent granules have a bulk density of greater than about 550 g/l andType: GrantFiled: May 31, 1995Date of Patent: November 12, 1996Inventors: Eric F. Riddick, Judith A. Lakes
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Patent number: 5552078Abstract: A powdered laundry detergent composition comprising an active surfactant, at least about 70 wt. % of a water soluble alkaline carbonate salt, e.g., sodium carbonate, about 0.1 to 2 wt. % of a phosphorus-containing sequestering agent, e.g., sodium tripolyphosphate (STPP), about 0.1 to 2 wt. % of a polymeric polycarboxylate, e.g., a polyacrylate or a polymaleate, and about 1-12 wt. % water. Use of the foregoing detergent composition provides excellent cleaning and whitening of fabrics while avoiding the problem of eutrophication which occurs when a substantial amount of a phosphorus containing builder such as STPP is present in the composition, and while minimizing the problem of fabric encrustation often present when the composition contains a large amount of carbonate builder.Type: GrantFiled: December 21, 1994Date of Patent: September 3, 1996Assignee: Church & Dwight Co., Inc.Inventors: Charles D. Carr, Steven A. Bolkan, Joseph G. Becker