The Component Is Organic (e.g., Chloro(iso)cyanurate Derivative, Etc.) Patents (Class 510/381)
  • Patent number: 9029311
    Abstract: This invention relates to extend the benefits of using hypochlorite compounds such as sodium hypochlorite to clean and disinfect articles while reducing or eliminating the side effects of treating an article with a strong oxidant material. The invention relates to a single step process involving mixing of precursor compositions of a suitable hypohalite or hypohalous acid with a solution of a reducing agent. Optionally a buffer may be present in either or both precursor compositions, such that at time of use such active hypohalous acid concentration in the resulting aqueous mixture remains at a sufficient activity level to effect one or more desired benefits against a target substrate for a desired period of time. The oxidant is substantially consumed by reaction with the reducing agent after the time needed for achieving the desired benefit has passed.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: May 12, 2015
    Assignee: The Clorox Company
    Inventors: Dewain Garner, William Smith, Jared Heymann
  • Patent number: 8883705
    Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: November 11, 2014
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Travers Anderson, William L. Smith, Erika Szekeres, Rui Zhang
  • Patent number: 8883706
    Abstract: The invention relates to a polymer-micelle complex. The polymer-micelle complexes include a negatively charged micelle that is electrostatically bound to a water-soluble polymer bearing a positive charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: November 11, 2014
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Travers Anderson, William L. Smith, Erika Szekeres, Rui Zhang
  • Patent number: 8772220
    Abstract: A chemical delivery product for delivering an oxidizing chemical into an aqueous system is disclosed. For instance, in one embodiment, a substrate containing an oxidizing chemical, such as trichloroisocyanuric acid, is coated with a water soluble polymer in order to prevent the oxidizing chemical from degrading prior to use and in order to facilitate handling. In accordance with the present disclosure, a neutralizing agent is contacted with the substrate in order to prevent the substrate from degrading the water soluble coating. In an alternative embodiment, a package is formed from a water soluble film forming composition combined with a base.
    Type: Grant
    Filed: August 24, 2007
    Date of Patent: July 8, 2014
    Assignee: Sekisui Specialty Chemicals America, LLC
    Inventors: Richard Vicari, Hang Wang, Bret Hann
  • Patent number: 8492419
    Abstract: Solid formulations for use in water conditioning of circulating reservoirs, processes of preparing same and methods for water conditioning utilizing same are disclosed. The solid formulations combine a sanitizer with a bath salt and/or an odoriferous substance.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: July 23, 2013
    Assignee: Bromine Compounds Ltd.
    Inventors: David Feldman, Theodore M. Fishler, Amiram Groweiss, Aharon Weissman, Gideon Shikolsky, Moshe Link
  • Publication number: 20120302485
    Abstract: A method and composition for removing stubborn stains that includes the application of a mixture comprising alkyl dimethyl benzyl ammonium chlorides, bleach, and water. A major advantage of the method is that the composition solution is strong enough to remove stubborn stains from soft and hard surfaces and restore original appearance and scent to old fabrics, yet sufficiently mild to not damage delicate and colored fabrics or pose a threat to the person treating the stain.
    Type: Application
    Filed: May 22, 2012
    Publication date: November 29, 2012
    Inventor: Beth Chester
  • Patent number: 7977299
    Abstract: A treated oxidizing agent is provided according to the invention. The treated oxidizing agent includes an oxidizing agent that is solid at room temperature and atmospheric pressure, and a chemical barrier composition provided on the oxidizing agent. The chemical barrier composition includes a hydrocarbon component having about 10 to about 85 carbon atoms, and wherein the chemical barrier composition is provided as a liquid at 25° C. A solid detergent composition is provided including the treated oxidizing agent. Methods for manufacturing are provided.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: July 12, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Jerry D. Hoyt, Brenda L. Tjelta, Michael E. Besse, Kent Richard Brittain
  • Publication number: 20090054295
    Abstract: A chemical delivery product for delivering an oxidizing chemical into an aqueous system is disclosed. For instance, in one embodiment, a substrate containing an oxidizing chemical, such as trichloroisocyanuric acid, is coated with a water soluble polymer in order to prevent the oxidizing chemical from degrading prior to use and in order to facilitate handling. In accordance with the present disclosure, a neutralizing agent is contacted with the substrate in order to prevent the substrate from degrading the water soluble coating. In an alternative embodiment, a package is formed from a water soluble film forming composition combined with a base.
    Type: Application
    Filed: August 24, 2007
    Publication date: February 26, 2009
    Applicant: Celanese International Corporation
    Inventors: Richard Vicari, Hang Wang, Bret Hann
  • Patent number: 7265081
    Abstract: The present invention relates to a process of removing coloured stains from plastic by treating the substrate in an automatic dishwashing machine with an aqueous liquor comprising a hydrophobic component having a density in the range of 0.06 to 1 gram cm3.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: September 4, 2007
    Assignee: Reckitt Benckisder N.V.
    Inventors: Daniele Fregonese, Chris Efstathios Housmekerides, Marcus Richter
  • Patent number: 7244700
    Abstract: An aqueous cleaning composition for the removal of mould and mildew is provided. The composition includes a water soluble source of chlorine, a surfactant, chitosan and water and has improved anti-fungal activity.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: July 17, 2007
    Assignee: Reckitt Benckiser (UK) Limited
    Inventor: Malcolm Tom McKechnie
  • Patent number: 7204931
    Abstract: A storable, stable composition that provides the effective antimicrobial benefits of halogenated agents is presented. The invention includes a water-soluble biocidal composition. The composition includes: about 0.01 to about 10 wt. % of a water-soluble inorganic halide; about 5 to about 60 wt. % of an oxidizing agent which, in aqueous solution, reacts with the inorganic halide to generate hypohalite ions; about 1 to about 15 wt. % of N-succinimide; and about 1 to about 30 wt. % of a pH buffering agent. The invention also includes a method of producing the above composition.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: April 17, 2007
    Assignee: Truox, Inc.
    Inventors: Perry L. Martin, Roy W. Martin
  • Patent number: 7074363
    Abstract: A water soluble sanitizing composition includes a chlorinated isocyanurate and an effervescent alkali base, the effervescent base including sodium carbonate agent, adipic acid and sodium bicarbonate in a weight ratio of approximately 1:1:1 to provide a sanitizing solution having a pH of from 6.8 to 7.4. A method for sanitizing a product such as in-ovo injection equipment includes the step of dissolving the composition in water to form a sanitizing solution and flushing the in-ovo injection equipment with the sanitizing solution prior to each in-ovo injection.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: July 11, 2006
    Assignee: Infowise Limited
    Inventor: Paul Stephen Edmondson
  • Patent number: 6916771
    Abstract: A composition is provided comprising two liquids which are separately maintained prior to forming an admixture during delivery to a surface to be treated, whereupon the admixture generates a foam sufficient for cleaning efficacy and stability. A first liquid preferably includes a hypohalite, or a hypohalite generating agent and a second liquid preferably includes a peroxygen agent. The first liquid is thickened to a specified rheology, resulting in the generation of a highly effective foam. As the two liquids are initially separated, the hypohalite generating agent can be maintained in an environment free of peroxygen agent and otherwise conducive to their cleaning activity and stability up to the time of use. When the two liquids are allowed to mix, for example, by simultaneously pouring into a drain, the hypohalite and peroxygen react to liberate oxygen gas. As foam generation occurs, the escaping gas contacts surfactant in the solution, and creates foam which expands to completely fill the drain pipe.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: July 12, 2005
    Assignee: The Clorox Company
    Inventors: Inderjeet K. Ajmani, Jessica Y. Chung
  • Patent number: 6900164
    Abstract: A composition is provided comprising two liquids which are separately maintained prior to forming an admixture during delivery to a surface to be treated, whereupon the admixture generates a foam sufficient for cleaning efficacy and stability. A first liquid preferably includes a hypohalite, or a hypohalite generating agent and a second liquid preferably includes a peroxygen agent. The first liquid is thickened to a specified rheology, resulting in the generation of a highly effective foam. As the two liquids are initially separated, the hypohalite generating agent can be maintained in an environment free of peroxygen agent and otherwise conducive to their cleaning activity and stability up to the time of use. When the two liquids are allowed to mix, for example, by simultaneously pouring into a drain, the hypohalite and peroxygen react to liberate oxygen gas. As foam generation occurs, the escaping gas contacts surfactant in the solution, and creates foam which expands to completely fill the drain pipe.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: May 31, 2005
    Assignee: The Clorox Company
    Inventors: Inderjeet K. Ajmani, Jessica Y. Chung
  • Patent number: 6825159
    Abstract: A cleaning composition including a less than fully ionized source of alkalinity within the cleaning composition, a source of chlorine, and a polar carrier. In at least some embodiments, it has been found that chlorine has an increased level of stability within the cleaning composition relative to a second composition having similar components and a similar level of titratable alkalinity, but that includes a fully ionized source of alkalinity as a sole source of alkalinity. Some other embodiments relate to methods of making, and methods of using such cleaning compositions.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: November 30, 2004
    Assignee: Ecolab, Inc.
    Inventors: Victor Fuk-Pong Man, Steven Eugene Lentsch, Janel Marie Kieffer
  • Publication number: 20040082491
    Abstract: Aqueous bleach solutions can be made by directing a spray of water onto a bulk or shaped solid (brick, tablet, block, etc.) comprising a continuous solid phase of an encapsulated source of an active halogen bleach or a solid comprising a source of an oxidizing active halogen bleach, and an encapsulated oxidizing halogen bleach source. Such shaped solids can be used to dispense an aqueous bleach concentrate to bleaching locus such as a washing machine.
    Type: Application
    Filed: July 7, 2003
    Publication date: April 29, 2004
    Applicant: Ecolab Center Inc.
    Inventors: Keith E. Olson, Victor F. Man
  • Patent number: 6660702
    Abstract: A composition is provided comprising two liquids which are separately maintained prior to forming an admixture during delivery to a surface to be treated, whereupon the admixture generates a foam sufficient for cleaning efficacy and stability. A first liquid preferably includes a hypohalite, or a hypohalite generating agent and a second liquid preferably includes a peroxygen agent. The first liquid is thickened to a specified rheology, resulting in the generation of a highly effective foam. As the two liquids are initially separated, the hypohalite generating agent can be maintained in an environment free of peroxygen agent and otherwise conducive to their cleaning activity and stability up to the time of use. When the two liquids are allowed to mix, for example, by simultaneously pouring into a drain, the hypohalite and peroxygen react to liberate oxygen gas. As foam generation occurs, the escaping gas contacts surfactant in the solution, and creates foam which expands to completely fill the drain pipe.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: December 9, 2003
    Assignee: The Clorox Company
    Inventors: Inderjeet K. Ajmani, Jessica Y. Chung
  • Patent number: 6617297
    Abstract: Solid automatic dishwasher detergent tablets have a chlorine source to most preferably provide 0.5 to 5 percent available chlorine; and a chlorine stability enhancing effective amount of preferably between about 0.5 to about 10 percent by weight of one or more nonionic surfactants having the following structure: R—(AO1)x(AO2)y—OR′ wherein: R is a C6-C18 alkyl group, AO1 represents propylene oxide or a mixture of propylene oxide and other alkylene oxides, AO2 represents ethylene oxide or a mixture of ethylene oxide and other alkylene oxides, R′ is an alkyl, arylalkyl, or benzalkyl group with 1 to about 10 carbon atoms, x is 2-20, y is 0-20, and the sum of x plus y is 5 or greater. The nonionic surfactant imparts improved chlorine stability to the tablet such that greater than 80 percent of the chlorine in the tablet remains active for eight weeks when the tablet is stored at 120° F.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: September 9, 2003
    Assignee: BASF Corporation
    Inventors: Glenis R. Mente, Kenneth L. Zack, Michael C. Welch
  • Patent number: 6495698
    Abstract: Novel, binder-free compacted forms of 1,3-dihalo-5,5-dimethylhydantoins in which one halogen atom is chlorine and the other is a bromine or chlorine atom are produced and used for microbiological control in aqueous media and water.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: December 17, 2002
    Assignee: Albemarle Corporation
    Inventor: Jonathan N. Howarth
  • Patent number: 6368420
    Abstract: A chemical cleaning system for a multi-tank or a single-tank mechanical warewashing machine is provided, having at least two separate components for aqueous dissolution or dilution to respective use concentrations, a first component comprising an enzyme or a mixture of an enzyme and a cleaning agent, and a second component comprising a bleach, wherein the first component is introduced into a wash zone or step and wherein the second component is introduced into a post-rinse zone or step.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: April 9, 2002
    Assignee: Diversey Lever, Inc.
    Inventors: Petrus Adrianus Angevaare, Paul Flu, John Richard Nicholson, Frederik Jan Schepers
  • Patent number: 6294510
    Abstract: A solid lavatory cleansing composition comprises: (i) a halogen-release agent containing at least 30 mole % of active halogen; (ii) a substantially non-oxidizable, substantially anhydrous surfactant component; and (iii) a substantially non-oxidizable solubility retardant agent.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: September 25, 2001
    Assignee: Jeyes Group Limited
    Inventors: Russell Norman, Brain Murie Wilson, John Marshall
  • Patent number: 6191089
    Abstract: An automatic dishwashing composition which is in the form of a tablet generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a lubricant, a dialkali metal disilicate, a nonionic surfactant, a polymer containing sulfonic acid groups, a wax coated chlorine bleach compound, and optionally an anionic surfactant.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: February 20, 2001
    Assignee: Colgate-Palmolive Company
    Inventors: Philip Gorlin, Leonard Zyzyck, Gary Jakubicki
  • Patent number: 6162777
    Abstract: An automatic dishwashing composition which is in the form of a tablet which generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a lubricant, a dialkali metal disilicate, a nonionic surfactant, a crosslinked polyacrylic acid polymer, a wax coated chlorine bleach compound, and optionally an anionic surfactant.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: December 19, 2000
    Assignee: Colgate-Palmolive Company
    Inventors: Philip Gorlin, Leonard Zyzyck
  • Patent number: 6143707
    Abstract: Automatic dishwashing detergent compositions comprising blooming perfume composition containing blooming perfume ingredients selected from the group consisting of: ingredients having a boiling point of less than about 260.degree. C. and a ClogP of at least about 3, and wherein said perfume composition comprises at least 5 different blooming perfume ingredients, bleaching agent, builder and optionally, bleach catalysts. Preferred automatic dishwashing compositions further comprise amylase and/or protease enzymes.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: November 7, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Toan Trinh, Dennis Ray Bacon, Alex Haejoon Chung, Patricia Ann Blondin
  • Patent number: 6136768
    Abstract: A water-dispersible effervescent drain cleaner having a composition of approximately 20-60% by weight of a mixture of metal hydroxides, 20-40% hypochlorite generator, and 10-40% effervescent materials. Lubricant, colors and fragrances may also be present. The components of this mixture are compressed into tablet, pellet, granules, or high density powder forms. The particles are of sufficient density to drop through water to the point of a clog. The effervescent materials work to break up the tablets or pellets and to agitate the mixture. The hypochlorite generator, in conjunction with the hydroxides reacts to dissolve hair. The hydroxide and hypochlorite generate heat, which will dissolve grease and soap clogs and accelerate the dissolution of hair.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: October 24, 2000
    Assignee: Chem-Link Laboratories LLC
    Inventors: Hilton G. Dawson, Robert P. Warnock, Richard A. DeSenna
  • Patent number: 6124251
    Abstract: A cleaning formulation, in tablet form, capable of providing a metered release of cleaning active while immersed in the tank of a toilet. The tablet comprises greater than about 85 to 99 weight percent of a halohydantoin plus about 1 to 15 weight percent of a longevity aid comprising boric acid.
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: September 26, 2000
    Assignee: The Clorox Company
    Inventors: James E. Rader, William K. Mainquist
  • Patent number: 6068001
    Abstract: Process for stainless steel pickling consisting in placing the material to be treated in a bath kept at a temperature ranging from 30.degree. C. to 70.degree. C. and containing:a) HClb) Fe.sup.3+c) HFd) emulsifiers, wetting agents, polishing agents, acid attack inhibitors;the bath being fed continuously with:an air flow equal to at least 3 m.sup.3 /h per m.sup.3 bath min. and an oxidizer quantity adjusted to the bath redox potential to be kept at 250 mV min.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: May 30, 2000
    Assignee: Novamax ITB S.R.L.
    Inventors: Cesare Pedrazzini, Paolo Giordani
  • Patent number: 5981461
    Abstract: The present invention relates to cleaning compositions containing one or more halogen bleaching agents and a sulfosuccinate salt. It has been unexpectedly found in accordance with the present invention that the addition of a sulfosuccinate salt to a halogen bleaching agent significantly enhances the cleaning capacity of the halogen bleaching agent compared to the cleaning capacity of either compound alone. The present invention further relates to a method of treating a contaminated surface by washing the contaminated surface with a cleaning composition containing one or more halogen bleaching agents and sulfosuccinate salts. A method of removing soil or oily substances from a substrate by treating the substrate with a cleaning composition containing one or more halogen bleaching agents and sulfosuccinate salts is also provided by this invention.
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: November 9, 1999
    Assignee: Lonza Inc.
    Inventors: Michael Wayne Counts, Michael Yao-Chi Chiang
  • Patent number: 5972864
    Abstract: The present invention is directed to a stable fragrant bleaching block which comprises (a) a bleaching agent having a reduction potential from about -0.7 v to about +0.4 v and (b) an organoleptic effective amount of a fragrant agent which (i) is stable to the bleaching agent, (ii) does not decompose the bleaching agent, and (iii) is not substantially hygroscopic. This invention also pertains to methods for making and employing the stable fragranced bleaching block.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: October 26, 1999
    Assignee: Lonza Inc.
    Inventor: Michael Wayne Counts
  • Patent number: 5925181
    Abstract: Cellulose esters according to formula (I):?(C.sub.6 H.sub.7 O.sub.2)(OR).sub.x (OR').sub.y (OH).sub.3-x-y !.sub.n (I)are described, where R is hydrophobic, R' is hydrophilic and not phthalyl or trimellityl, which may be designed, by the proper selection of R, R', x, y, and n, to dissolve under mild to alkaline conditions, and not before. A coating comprising a modified ester according to formula (I) may be used for controlled-release applications, particularly for a cleaning formulation.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: July 20, 1999
    Inventors: Phillip Michael Cook, Juanelle Little Lambert
  • Patent number: 5843240
    Abstract: Process for stainless steel pickling consisting in placing the material to be treated in a bath kept at a temperature ranging from 30.degree. C. to 70.degree. C. and containing:a) H.sub.2 SO.sub.4b) Fe.sup.3+c) HFd) emulsifiers, wetting agents, polishing agents, acid attack inhibitors;the bath being kept under agitation with:an air flow and continuously fed with a quantity of oxidizing agent adjusted to the bath redox potential to be kept at 250 mV min.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: December 1, 1998
    Assignee: Novamax ITB S.r.L.
    Inventors: Cesare Pedrazzini, Paolo Giordani
  • Patent number: 5763376
    Abstract: A toilet cleaning block that releases a halogen containing sanitizing agent in a controlled, substantially constant rate for about 2 to about 4 months of constant contact with water and is then completely dissolved in the water comprises an admixture of about 50% to about 80% by weight of a halogen containing sanitizing agent, about 20% to about 40% by weight of a bulking agent such as aluminum hydroxide, about 0% to about 20% by weight sodium bicarbonate, and about 1 to about 20% by weight of a sacrificial dissolution rate regulating agent such as sodium chloride.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 9, 1998
    Assignee: Block Drug Company, Inc.
    Inventors: Kenneth Ward, Richard Dolan, Paul Riccobono
  • Patent number: 5763384
    Abstract: Hard-surface scouring cleansers contain surfactant; water soluble abrasive/alkalinity mixture of water soluble carbonate and bicarbonate and optional sulfate salts; preferably bleach; optional buffer and/or minors. Such compositions combine the stain and soil removal properties of a strong active chlorine bleaching agent and bleach-stable surfactant in a abrasive cleanser having desirable surface safety and superior rinsing properties.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: June 9, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Raleigh Clair Ormerod, IV
  • Patent number: 5756440
    Abstract: A disinfectant and cleansing composition is provided in the form of an extruded solid. The active agent in the composition is a halogen-releasing agent such as a halogenated 5,5-dialkylhydantoin. An inert binder such as a fatty acid salt or a hectoritic clay is used to enable manufacture of the composition using an extrusion process. Fragrance, colorants, and other pressure-sensitive materials may be included; fragrance and colorants are preferably incorporated in encapsulated form. Methods for manufacturing the compositions are also provided, as are methods for using the compositions in sanitizing water, particularly in disinfecting and cleansing flush toilets.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: May 26, 1998
    Assignee: The Clorox Company
    Inventors: Erika Watanabe, Vincent N. DeMaso
  • Patent number: 5610126
    Abstract: A lavatory cleansing block is formed of a composition comprising a mixture of (A) a surface active component comprising one or more anionic surface active agents and (B) a halogen release agent component consisting of (i) a halogen release agent selected from N-chloro-succinimide, calcium hypochlorite, chloramine T, dichlorodimethylhydantoin and bromochlorodimethylhydantoin, and, optionally, (ii) another halogen release agent, in which the halogen release component forms from 10 to 65% by weight of the composition, halogen release component (i) forms not less than 5% by weight of the composite and halogen release component (ii), when present, forms not more than 30% by weight of the block.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 11, 1997
    Assignee: Jeyes Group Limited
    Inventors: Eric D. Barford, Peter J. Clark, John Marshall, Daniel J. Jeffrey
  • Patent number: 5578559
    Abstract: A toilet cleaning block that releases a halogen containing sanitizing agent in a controlled, substantially constant rate for about 2 to about 4 months of constant contact with water and is then completely dissolved in the water comprises an admixture of about 50% to about 80% by weight of a halogen containing sanitizing agent, about 20% to about 40% by weight of a bulking agent such as aluminum hydroxide and about 1 to about 20% by weight of a sacrificial dissolution rate regulating agent such as sodium chloride.
    Type: Grant
    Filed: May 14, 1993
    Date of Patent: November 26, 1996
    Assignee: Block Drug Company, Inc.
    Inventors: Richard Dolan, Paul Riccobono
  • Patent number: 5534178
    Abstract: Uniform, microscopic perforated water soluble film is herein described, and its use in packaging solid, pelletized or particulate detersire compositions containing strong acids, strong bases or a source of halogen whereby the package provides air to pass through without leakage of its contents. Also described is a method of manufacture of a sealed, water soluble, detersire package with microscopic perforations and an apparatus for said manufacture.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: July 9, 1996
    Assignee: Ecolab Inc.
    Inventors: Helen Bailly, Arthur Luedtke, Paul Pankratz, Joy Allen, Tina O. Outlaw, Lance K. Fisher, Kelvin D. Sundeen