Azeotropic Or Azeotropelike Composition Patents (Class 510/415)
  • Patent number: 8999909
    Abstract: Provided are azeotropic or azeotrope-like mixtures of 1,1,1,3,3-pentachloro-propane (240fa) and hydrogen fluoride. Such compositions are useful as an intermediate in the production of HFC-245fa and HCFO-1233zd.
    Type: Grant
    Filed: February 23, 2012
    Date of Patent: April 7, 2015
    Assignee: Honeywell International Inc.
    Inventors: Daniel C. Merkel, Hsueh Sung Tung, Konstantin A. Pokrovski, Hang T. Pham, Ryan Hulse
  • Patent number: 8858823
    Abstract: A composition based on 3,3,3-trifluoropropene and ammonia, and to the use thereof, especially as a heat transfer fluid. A heat-transfer composition including the composition based on 3,3,3-trifluoropropene and ammonia and also one or more additives chosen from lubricants, stabilizers, surfactants, tracers, fluorescers, odorant agents and solubilizers, and mixtures thereof. A process for heating or cooling a fluid or a body by means of a vapor compression circuit containing a heat-transfer fluid, said process successively including evaporation of the heat-transfer fluid, compression of the heat-transfer fluid, condensation of the heat fluid and depressurization of the heat-transfer fluid, in which the heat-transfer fluid is a composition based on 3,3,3-trifluoropropene and ammonia.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: October 14, 2014
    Assignee: Arkema France
    Inventors: Wissam Rached, Jean-Christophe Boutier
  • Patent number: 8791167
    Abstract: A composition including an effective amount of trans-1,3,3,3-tetrafluoropropene component combined with an effective amount of an alcohol selected from the group of methanol, ethanol, propanol, isopropanol, tert-butanol, isobutanol, 2-ethyl hexanol and any combination thereof, where the composition has azeotropic properties.
    Type: Grant
    Filed: February 13, 2012
    Date of Patent: July 29, 2014
    Assignee: Honeywell International Inc.
    Inventors: James M. Bowman, Rajiv R. Singh, David J. Williams, Hang T. Pham, Justin L. Becker
  • Patent number: 8680037
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of Z-1,1,1,4,4,4-hexafluoro-2-butene with ethanol, 2-chloro-3,3,3-trifluoropropene, methanol, E-1,1,1,4,4,5,5,5-octafluoro-2-pentene, 2-bromo-3,3,3-trifluoropropene, methyl acetate, acetone, chloroform, n-hexane or 1-chloro-3,3,3-trifluoropropene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: March 25, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Mark Robin
  • Publication number: 20140048739
    Abstract: Provided are compositions, preferably azeotrope or azeotrope-like compositions comprised of 1,1,1,4,4,4-hexafluoro-2-butene and chlorotrifluoropropene, particularly 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), and uses thereof.
    Type: Application
    Filed: November 25, 2010
    Publication date: February 20, 2014
    Applicant: Arkema France
    Inventors: Wissam Rached, Laurent Abbas, Jean-Christophe Boutier
  • Patent number: 8632703
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,5,5,5-Octafluoro-2-pentene with methyl formate, n-pentane, 2-methylbutane, 1,1,1,3,3-pentafluorobutane, trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, dimethoxymethane, cyclopentane or Z-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions as propellants. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media.
    Type: Grant
    Filed: September 5, 2008
    Date of Patent: January 21, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Mark L. Robin
  • Patent number: 8623233
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of Z-1,1,1,4,4,4-hexafluoro-2-butene, trans-1,2-dichloroethylene and 1,1,1,3,3-pentafluorobutane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as dielectrics.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: January 7, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Mark L. Robin, Joan Ellen Bartelt
  • Patent number: 8518293
    Abstract: The present invention pertains to azeotropic and azeotrope-like compositions of the following three blends: 1. Trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)), cis-1,3,3,3-tetrafluoropropene (HFO-1234ze(Z)) and hydrogen fluoride (HF); 2. HFO-1234ze(E), 1,1,1,3,3-pentafluoropropane (HFC-245fa) and HF; and 3. HFO-1234ze(Z), HFC-245fa and HF. These azeotropic and azeotrope-like compositions are useful as intermediates in the production of HFO-1234ze(E).
    Type: Grant
    Filed: September 3, 2010
    Date of Patent: August 27, 2013
    Assignee: Honeywell International Inc.
    Inventors: Ryan Hulse, Hang T. Pham, Rajiv Ratna Singh, Daniel C Merkel, Konstantin A. Pokrovski, Hsueh Sung Tung
  • Patent number: 8497401
    Abstract: The invention is directed to a ternary azeotrope-like mixture consisting essentially of effective amounts of 1,1,1,3,3-pentafluoropropane, 1-chloro-3,3,3-trifluoropropene, and hydrogen fluoride.
    Type: Grant
    Filed: November 7, 2011
    Date of Patent: July 30, 2013
    Assignee: Honeywell International Inc.
    Inventors: Ryan Hulse, Rajiv Ratna Singh, Hsueh Sung Tung, Ian Shankland
  • Patent number: 8492327
    Abstract: Provided are azeotrope-like compositions comprising difluoromethane and trifluoroiodomethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
    Type: Grant
    Filed: April 23, 2012
    Date of Patent: July 23, 2013
    Assignee: Honeywell International Inc.
    Inventors: Rajiv R. Singh, Hang T. Pham, David P. Wilson
  • Patent number: 8420585
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: June 22, 2012
    Date of Patent: April 16, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Patent number: 8410040
    Abstract: An azeotrope-like composition consisting essentially of 1,1,1,2,3-pentachloropropane and hydrogen fluoride is provided, as well as methods that involve such an azeotrope-like composition.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: April 2, 2013
    Assignee: Honeywell International Inc.
    Inventors: Hsueh S. Tung, Hang T. Pham, Rajiv R. Singh, Daniel C. Merkel
  • Patent number: 8338355
    Abstract: There is provided an azeotrope or azeotrope-like composition containing (A) 1,1,2,2-tetrafluoro-1-methoxyethane and (B) a compound formed of at least one selected from the group consisting of (Z)-1-chloro-3,3,3-trifluoropropene, 2-bromo-3,3,3-trifluoropropene, and (E)-2-bromo-1,3,3,3-tetrafluoropropene.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: December 25, 2012
    Assignee: Central Glass Company, Limited
    Inventors: Akira Ishihara, Yasuo Hibino
  • Patent number: 8262924
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene with methyl formate, n-pentane, 2-methylbutane, trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, n-butane or isobutane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.
    Type: Grant
    Filed: May 20, 2011
    Date of Patent: September 11, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventor: Mark L. Robin
  • Patent number: 8247366
    Abstract: An azeotrope-like composition consisting essentially of 1,1,2,3-tetrachloropropene and hydrogen fluoride is provided, as well as methods that involve such an azeotrope-like composition.
    Type: Grant
    Filed: August 4, 2011
    Date of Patent: August 21, 2012
    Assignee: Honeywell International Inc.
    Inventors: Hsueh S. Tung, Hang T. Pham, Rajiv R. Singh, Daniel C. Merkel, Robert Johnson
  • Patent number: 8222195
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: July 17, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Publication number: 20120157362
    Abstract: The present disclosure provides azeotropic and azeotrope-like compositions comprised of methylperfluoroheptene ethers and heptane. The present disclosure also provides for methods of use for the azeotropic and azeotrope-like compositions.
    Type: Application
    Filed: July 29, 2011
    Publication date: June 21, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: JEFFREY P. KNAPP, Joan Ellen Bartelt
  • Publication number: 20120157363
    Abstract: The present disclosure provides azeotropic and azeotrope-like compositions comprised of methylperfluoroheptene ethers and ethanol. The present disclosure also provides for methods of use for the azeotropic and azeotrope-like compositions.
    Type: Application
    Filed: July 29, 2011
    Publication date: June 21, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: JEFFREY P. KNAPP, Joan Ellen Bartelt
  • Patent number: 8163689
    Abstract: Provided are azeotrope-like compositions comprising difluoromethane and trifluoroiodomethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
    Type: Grant
    Filed: December 15, 2008
    Date of Patent: April 24, 2012
    Assignee: Honeywell International Inc.
    Inventors: Rajiv R. Singh, Hang T. Pham, David P. Wilson
  • Patent number: 8163197
    Abstract: The present invention relates to azeotropic or azeotrope-like compositions comprising a fluorinated olefin having the formula E- or Z—C3F7CH?CHC3F7, and at least one alcohol, halocarbon, hydrofluorocarbon, fluoroether, or alkanes and combinations thereof. In one embodiment, the one compound selected from the group consisting of alcohols, halocarbons, fluoroalkyl ethers, hydrofluorocarbons, alkanes is either methanol, ethanol, iso-propanol, n-propanol, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, n-propyl bromide, C4F9OCH3, C4F9OC2H5, HFC-43-10mee, HFC-365mfc, heptane, or combinations thereof. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: March 2, 2011
    Date of Patent: April 24, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Melodie A. Schweitzer, Allen Capron Sievert, Joan Ellen Bartelt, Barbara Haviland Minor
  • Patent number: 8114828
    Abstract: A composition including an effective amount of trans-1,3,3,3-tetrafluoropropene component combined with an effective amount of an alcohol selected from the group of methanol, ethanol, propanol, isopropanol, tert-butanol, isobutanol, 2-ethyl hexanol and any combination thereof, where the composition has azeotropic properties.
    Type: Grant
    Filed: April 16, 2007
    Date of Patent: February 14, 2012
    Assignee: Honeywell International Inc.
    Inventors: Jim M Bowman, David J Williams, Rajiv R Singh, Hang T Pham, Justin L Becker
  • Patent number: 8101672
    Abstract: The invention pertains to azeotrope-like compositions of 1,1,2,3,3-pentafluoropropene (HFC-1225yc) and any one of 1,1,1,2-tetrafluoropropene (HFC-1234yf) or the Z-isomer of 1,1,1,2,3-pentafluoropropene (HFC-1225yeZ), and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: January 24, 2012
    Assignee: Honeywell International Inc.
    Inventors: Ryan J. Hulse, Hang T. Pham, Rajiv R. Singh
  • Patent number: 8075797
    Abstract: The invention is directed to a ternary azeotrope-like mixture consisting essentially of effective amounts of 1,1,1,3,3-pentafluoropropane, 1-chloro-3,3,3-trifluoropropene, and hydrogen fluoride.
    Type: Grant
    Filed: January 25, 2010
    Date of Patent: December 13, 2011
    Assignee: Honeywell International Inc.
    Inventors: Ryan Hulse, Rajiv R. Singh, Hsueh S. Tung, Ian Shankland
  • Patent number: 8066900
    Abstract: Azeotrope-like compositions comprising 1-bromopropane and 1,1,1,2,3,3-hexafluoro-3-methoxy-propane, and uses thereof, are described.
    Type: Grant
    Filed: December 2, 2008
    Date of Patent: November 29, 2011
    Assignee: 3M Innovative Properties Company
    Inventor: John G. Owens
  • Patent number: 8044010
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: October 25, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Patent number: 8044015
    Abstract: Disclosed are compositions and systems having utility in numerous situations, including in particular solvent cleaning systems, as well as refrigerant lubricants and/or compatibilizing agents, and to methods which utilize such compositions and systems. More particularly, the present invention in preferred aspects is directed to solvents, blowing agents, heat transfer fluids and compatibilizing agents comprising the compound 3-chloro-1,1,1,6,6,6-hexafluoro-2,4-hexadiene.
    Type: Grant
    Filed: March 12, 2010
    Date of Patent: October 25, 2011
    Assignee: Honeywell International Inc.
    Inventors: Robert C. Johnson, Hsueh Sung Tung
  • Patent number: 8007677
    Abstract: Disclosed herein are azeotrope and near-azeotrope compositions comprising E-1,1,1,2,3-pentafluoropropene (E-HFC-1225ye) and hydrogen fluoride. The azeotrope and near-azeotrope compositions are useful in processes to produce and in processes to purify E-HFC-1225ye and/or Z-1,1,1,2,3-pentafluoropropene (Z-HFC-1225ye). Also disclosed are processes for the extractive distillation to separate E-HFC-1225ye from Z-HFC-1225ye.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: August 30, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Jeffrey P. Knapp, Barry Asher Mahler, Velliyur Nott Mallikarjuna Rao
  • Patent number: 8008243
    Abstract: An azeotrope-like composition consisting essentially of 1,1,2,3-tetrachloropropene and hydrogen fluoride is provided, as well as methods that involve such an azeotrope-like composition.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: August 30, 2011
    Assignee: Honeywell International Inc.
    Inventors: Hsueh S. Tung, Hang T. Pham, Rajiv R. Singh, Daniel C. Merkel, Robert Johnson
  • Publication number: 20110163253
    Abstract: A process for making CHF?CFCF3 is disclosed. The process involves (a) reacting CCl2FCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH2FCF2CF3; and (b) dehydrofluorinating CH2FCF2CF3 from (a) to form CHF?CFCF3. Also disclosed are compositions including CCl3CF2CF3 and HF, wherein the HF is present in an effective amount to form an azeotropic combination with the CCl3CF2CF3; and compositions including CCl2FCF2CF3 and HF, wherein the HF is present in an effective amount to form an azeotropic combination with the CCl2FCF2CF3.
    Type: Application
    Filed: March 14, 2011
    Publication date: July 7, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: ALLEN CAPRON SIEVERT
  • Patent number: 7972525
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene with methyl formate, n-pentane, 2-methylbutane, trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, n-butane or isobutane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.
    Type: Grant
    Filed: June 12, 2008
    Date of Patent: July 5, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Mark L. Robin
  • Patent number: 7972524
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of Z-1,1,1,4,4,4-hexafluoro-2-butene with methyl formate, pentane, 2-methylbutane, 1,1,1,3,3-pentafluorobutane, trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, dimethoxymethane, or cyclopentane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media.
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: July 5, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Mark L. Robin
  • Publication number: 20110147638
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of Z-1,1,1,4,4,4-hexafluoro-2-butene, trans-1,2-dichloroethylene and a third component. Also disclosed are compositions where the third component is cyclopentane, methanol, dimethyoxymethane, methyl formate or perfluoro ethyl isopropyl ketone. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media.
    Type: Application
    Filed: June 25, 2010
    Publication date: June 23, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Mark L. Robin, Joan Ellen Bartelt
  • Patent number: 7927502
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: July 22, 2010
    Date of Patent: April 19, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Patent number: 7875657
    Abstract: The present invention relates to a composition based on trans-1,2-dichloroethylene. A subject-matter of the invention is more particularly a nonflammable composition comprising trans-1,2-dichloroethylene and at least two hydrofluorocarbons and its uses.
    Type: Grant
    Filed: November 11, 2009
    Date of Patent: January 25, 2011
    Assignee: Arkema France
    Inventors: Laurent Latil, Vincent Enaux
  • Publication number: 20100243943
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,5,5,5-Octafluoro-2-pentene with methyl formate, n-pentane, 2-methylbutane, 1,1,1,3,3-pentafluorobutane, trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, dimethoxymethane, cyclopentane or Z-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions as propellants. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media.
    Type: Application
    Filed: September 5, 2008
    Publication date: September 30, 2010
    Inventor: Mark L. Robin
  • Patent number: 7786061
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: August 31, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Publication number: 20100200797
    Abstract: Azeotrope-like compositions comprising 1-bromopropane and 1,1,1,2,3,3-hexafluoro-3-methoxy-propane, and uses thereof, are described.
    Type: Application
    Filed: December 2, 2008
    Publication date: August 12, 2010
    Inventor: John G. Owens
  • Patent number: 7767638
    Abstract: Provided are azeotrope-like compositions comprising tetrafluoropropene and hydrofluorocarbons and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
    Type: Grant
    Filed: April 29, 2005
    Date of Patent: August 3, 2010
    Assignee: Honeywell International Inc.
    Inventors: Rajiv R. Singh, Hang T. Pham, Gary Knopeck, David J. Williams
  • Patent number: 7695635
    Abstract: An azeotropic or azeotrope-like composition comprising a mixture of methyl iodide, 1-chloro-3,3,3,-trifluoropropene, and optionally one or more of fluorocarbons and/or hydrofluorocarbons. The compositions are present as a gas, at temperatures of about 30° C. or below. The inventive compositions serve as a non-ozone-depleting gaseous fumigant which is useful in a variety of applications, in place of methyl bromide. These compositions serve as a drop-in replacement for gaseous methyl bromide, providing the benefits of a methyl iodide fumigant while also utilizing existing methyl bromide equipment.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: April 13, 2010
    Assignee: Honeywell International Inc
    Inventors: Rajiv R. Singh, Hang T. Pham, Andrew J. Poss
  • Patent number: 7622053
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: January 19, 2009
    Date of Patent: November 24, 2009
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Patent number: 7605117
    Abstract: Provided are azeotrope-like compositions comprising tetrafluoropropene and pentafluoropropene and uses thereof, including use in refrigerant compositions, blowing agent compositions, foamable compositions, foams, sterilant compositions, sprayable compositions, and systems and methods using same.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: October 20, 2009
    Assignee: Honeywell International Inc.
    Inventors: David P. Wilson, Hang T. Pham, Rajiv R. Singh, Raymond H. Thomas, David Nalewajek
  • Patent number: 7563384
    Abstract: Mixtures of heptafluorobutene with tetrafluoropropenes provide compositions that have boiling points within an acceptable range, have good chemical stability, low GWP and are preferably essentially non-flammable.
    Type: Grant
    Filed: July 28, 2006
    Date of Patent: July 21, 2009
    Assignee: Honeywell International Inc.
    Inventors: Raymond H. Thomas, Hang T. Pham, Rajiv R. Singh
  • Patent number: 7544306
    Abstract: Azeotropic and azeotrope-like compositions of methyl iodide and at least one fluorocarbon or hydrofluorocarbon such as 1,1,1,3,3-pentafluoropropane (HFC-245fa). The compositions are present as a gas, at temperatures of about 30° C. or below. The inventive compositions serve as a non-ozone-depleting gaseous fumigant which is useful in a variety of applications, in place of methyl bromide. These compositions serve as a drop-in replacement for gaseous methyl bromide, providing the benefits of a methyl iodide fumigant while also utilizing existing methyl bromide equipment.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: June 9, 2009
    Assignee: Honeywell International Inc.
    Inventors: Andrew J. Poss, Rajiv R. Singh, Hang T. Pham
  • Patent number: 7540973
    Abstract: Disclosed is an azeotrope-like composition comprising: from about 2% by weight to about 50% by weight of a hydrofluorocarbon selected from the group consisting of 1,1,1,2,2,3,4,5,5,5-decafluoropentane and 1,1,1,3,3-pentafluorobutane, from about 2% by weight to about 50% by weight 1,1,2,2,3,3,4-heptafluorocyclopentane, and an amount effective in dissolving oils and contaminants of trans-1,2-dichloroethylene. In another embodiment, are fluorocarbon solvent composition comprising from about 15 to about 99 weight percent 1,1,1,2,2,3,4,5,5,5-decafluoropentane and from about 85 to about 1 percent by weight 1,1,2,2,3,3,4-heptafluorocyclopentane wherein the freezing point of the composition is less than 0° C.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: June 2, 2009
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Joan Ellen Bartelt
  • Patent number: 7498296
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: February 28, 2007
    Date of Patent: March 3, 2009
    Assignee: E. I. DuPont de Nemours and Company
    Inventors: Melodie A. Schweitzer, Allen Capron Sievert, Joan Ellen Bartelt, Barbara Haviland Minor
  • Patent number: 7494603
    Abstract: The present invention relates to compositions comprising fluorinated olefins or fluorinated ketones, and at least one alcohol, halocarbon, hydrofluorocarbon, or fluoroether and combinations thereof. In one embodiment, these compositions are azeotropic or azeotrope-like. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.
    Type: Grant
    Filed: February 28, 2007
    Date of Patent: February 24, 2009
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Melodie A. Schweitzer
  • Patent number: 7473716
    Abstract: Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and at least one hydrocarbon selected from the group n-pentane, iso-pentane, cyclopentane, n-hexane and iso-hexane are provided. The compositions of the invention are useful in the preparation of polyurethane and polyisocyanurate foams.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: January 6, 2009
    Assignee: Honeywell International Inc.
    Inventors: Hilde Lund, legal representative, Robert Christian Parker, Ian Robert Shankland, Earl August Eugene Lund
  • Patent number: 7468142
    Abstract: Composition comprising at least one hydrofluoroalkane and at least one fluoropolyether.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: December 23, 2008
    Assignee: Solvay S.A.
    Inventor: Pierre Dournel
  • Patent number: 7449438
    Abstract: A method for improving the processability of foam premixes containing HFC and/or pentane-based blowing agents in polyols is provided, which method comprises adding trans-1,2-dichloroethylene to said premix in an amount effective to enhance said processability.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: November 11, 2008
    Assignee: Arkema Inc.
    Inventors: Jinhuang Wu, Laurent S. J. Caron
  • Publication number: 20080045432
    Abstract: Azeotropic or azeotropic-like compositions of 1,1,1-trifluoroethane (HFC-143a) and 1-chloro-2,2,2-trifluoroethane (R-133a).
    Type: Application
    Filed: August 17, 2006
    Publication date: February 21, 2008
    Inventors: Stephen A. Cottrell, Hang T. Pham, Rajiv R. Singh, Hseuhsung Tung