Polyoxyalkylene Containing Surfactant Devoid Of Covalently Bonded Anionic Substituents Patents (Class 510/421)
  • Patent number: 8901057
    Abstract: The present invention includes methods and compositions control hard water in an alkaline environment. According to the invention, a unique combination of polymers has been developed which helps to completely control and eliminate hard water. The composition includes a maleic polymer, a hydroxypolycarboxylic acid, and a starch based polymer in a unique synergistic combination that can be used alone, or in combination with standard alkaline detergents in any cleaning regime (laundry, warewash, etc.) where hard water conditions exist.
    Type: Grant
    Filed: October 29, 2012
    Date of Patent: December 2, 2014
    Assignee: Ecolab USA Inc.
    Inventor: Altony Miralles
  • Patent number: 8895492
    Abstract: This application relates to a dilutable aqueous liquid cleaning composition, typically a dishwashing liquid, which comprises a plurality of surfactants, the surfactants including surfactant active components comprising from greater than 30% to up to 55% by weight, based on the weight of the composition, wherein the composition has a viscosity of 100 to 500 mPas as measured at 25° C., and the composition is dilutable with water to form a non-gelling diluted composition having up to six times the volume of the undiluted composition and a viscosity within the range of 100 to 1600 mPas as measured at 25° C. at any dilution up to the six times dilution.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: November 25, 2014
    Assignee: Colgate-Palmolive Company
    Inventors: Jiashi Tarng, Joan Gambogi
  • Publication number: 20140342971
    Abstract: A liquid cleaning composition containing alkyl polyglycoside surfactants, an alkylated vegetable oil, water and a sodium-containing base provides excellent cleaning soil removal capabilities. The carbon materials from which it is manufactured are all renewable, and the composition is readily biodegradable.
    Type: Application
    Filed: August 4, 2014
    Publication date: November 20, 2014
    Inventors: Chris Shell, Benjamin P. Shell
  • Patent number: 8883705
    Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: November 11, 2014
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Travers Anderson, William L. Smith, Erika Szekeres, Rui Zhang
  • Patent number: 8883706
    Abstract: The invention relates to a polymer-micelle complex. The polymer-micelle complexes include a negatively charged micelle that is electrostatically bound to a water-soluble polymer bearing a positive charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: November 11, 2014
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Travers Anderson, William L. Smith, Erika Szekeres, Rui Zhang
  • Patent number: 8877699
    Abstract: A dishwasher detergent composition comprising: a compound of formula 1; a liquid non-ionic surfactant; and at least one solid non-ionic surfactant.
    Type: Grant
    Filed: June 29, 2010
    Date of Patent: November 4, 2014
    Assignee: Reckitt & Colman (Overseas) Limited
    Inventors: Judith Preuschen, Andrea Stein
  • Patent number: 8877702
    Abstract: The present invention relates to the detergent composition, containing (a) a nonionic surfactant represented by the formula (1); and (b) a sulfuric acid ester salt represented by the formula (2): R—O-(EO)m—(PO)n-(EO)m?—H??(1) wherein, R represents a hydrocarbon group having 6 to 24 carbon atoms; EO represents an ethyleneoxy group; PO represents a propyleneoxy group; m=0.1 to 25; m?=0 to 24.9; m+m?=0.5 to 25; and n=0.1 to 10; with the proviso that (EO)m, (PO)n, and (EO)m? are arranged in a block addition mode in this order; R1—O—(PO)x-(EO)y—SO3M??(2) wherein, R1 represents a hydrocarbon group having 6 to 24 carbon atoms; x=0.1 to 10; y=0 to 30; (PO)x and (EO)y are arranged in any order in any addition mode, being a block addition or a random addition, M is a counter ion.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: November 4, 2014
    Assignee: Kao Corporation
    Inventors: Masato Nomura, Katsuhisa Inoue, Hisato Fukuda
  • Patent number: 8871700
    Abstract: The present invention relates to cleaning and disinfecting liquid detergent compositions and, in one embodiment, liquid hand dishwashing compositions, comprising a metal salt, preferably a divalent metal salt, preferably Zn2+-salt and linear alkyl nucleophilic surfactant, preferably a linear alkyl chain amine oxide. The present invention further relates to methods of disinfecting dishware and/or dishwashing implements and/or skin using such a liquid detergent compositions.
    Type: Grant
    Filed: May 24, 2013
    Date of Patent: October 28, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Jamila Tajmamet, Jean-Luc Philippe Bettiol, Robby Renilde Francois Keuleers
  • Patent number: 8871704
    Abstract: An industrial cleaning composition is provided that includes: (a) from 5 to 50% by volume of an anionic surfactant having a log10P value in the range 5 to 7; (b) from 5 to 50% by volume of a first non-ionic surfactant having a log10P value in the range 0.1 to 3 and having the general formula, R?—(A0)n—OH, wherein R? is C9 to C20 alkyl, each AO unit is either —OCH2CH2— or —OCH2CH(CH3)—, the molar ratio [—OCH2CH(CH3)—]/[—OCH2CH2—] is in the range up to 8 and n is greater than 6; and (c) from 5 to 50% by volume of a second non-ionic surfactant having a log10P value in the range 0.1 to 3 having the general formula, R?—(OCH2CH2)n—OH wherein R? is C9 to C20 alkyl, and n is less than 6, each of said volume percentages being with respect to the total volume of (a), (b) and (c). Corresponding cleaners derived therefrom by water dilution are also disclosed.
    Type: Grant
    Filed: April 26, 2013
    Date of Patent: October 28, 2014
    Assignee: OTI Greentech Group AG
    Inventors: Jawahar Wakhloo, Alan Keasey, Caroline Kelly
  • Patent number: 8871701
    Abstract: The invention relates to an aqueous cleansing emulsion comprising a hydrophobic component H1 selected from the group consisting of the following categories: (i) aliphatic C10- or C15-terpene hydrocarbons; (ii) aliphatic C10- or C15-terpenoids; (iii) aliphatic C15-C40-hydrocarbons; and (iv) C6-C30-carboxylic acid C1-C30-alkyl esters. A hydrophobic component H2 selected from the group consisting of the following categories: (iii) aliphatic C15-C40-hydrocarbons; (iv) C6-C30-carboxylic acid C1-C30-alkyl esters; (v) aliphatic C6-C19-hydrocarbons; (vi) aromatic C10- or C15-terpenoids; (vii) aliphatic or aromatic C20-, C25-, C30- or C35-terpenoids; (viii) essential, animal or vegetable oils; and (ix) silicon oils. Furthermore, the emulsion contains an emulsifier E1 having a HLB value of 4±2; an emulsifier E2 having a HLB value of 9±2; and optionally, an emulsifier E3 having an HLB value of 16±4.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: October 28, 2014
    Assignee: Solenis LLC
    Inventors: Patric Bierganns, Markus Broecher, Charlotta Kanto-Oeqvist
  • Patent number: 8845817
    Abstract: Provided herein is an aqueous, non-toxic, non-flammable, non-explosive, biodegradable, hypoallergenic cleaning composition. Also provided are pre-loaded wipes containing the cleaning solution, kits, and methods of cleaning surfaces using the same.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: September 30, 2014
    Assignee: Green Way Laboratories
    Inventors: Thomas Bakehorn, Guy Roland Adams
  • Patent number: 8840731
    Abstract: A composition for machine dishwashing that includes a one copolymer obtainable by copolymerization of N-vinylamide, vinyl acetate, polyether, and alkoxylate.
    Type: Grant
    Filed: December 7, 2012
    Date of Patent: September 23, 2014
    Assignee: BASF SE
    Inventors: Sonja Fischer, Juergen Tropsch, Heike Weber, Roland Ettl
  • Patent number: 8822401
    Abstract: A water-soluble surfactant composition is provided comprising (A) a glycidyl ether-capped acetylenic diol ethoxylate and (B) a polyoxyalkylene alkyl ether having an HLB of 8-18. When compounded in inks and paper coatings, the surfactant composition exerts improved foam controlling, dispersing, wetting and penetrating capabilities, is water soluble, and complies with high-speed printing and application conditions.
    Type: Grant
    Filed: November 20, 2013
    Date of Patent: September 2, 2014
    Assignee: Nissin Chemical Industry Co., Ltd.
    Inventors: Toru Mizusaki, Ichiro Tanii
  • Patent number: 8809253
    Abstract: A container has: a) a collapsible receptacle, the wall of which is designed flexibly such that the internal volume of the receptacle is adapted to the volume of a liquid contained therein, and which has an outlet with an outlet valve; and b) in the receptacle a disinfectant composition in the form of a solution with a content of aliphatic alcohol of at most 20% by weight. It is possible that the disinfectant composition is not contaminated with spores or other germs also after the container has been opened, even upon repeated discharge from the container.
    Type: Grant
    Filed: January 8, 2014
    Date of Patent: August 19, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Sabine Behrends, Henning Reinstorff, Andreas Dettmann
  • Patent number: 8801864
    Abstract: An aqueous composition is disclosed, comprising at least one strain of Class 1 Bacillus bacterial spores, selected from Bacillus Cirulans, Bacillus Megaterium, Bacillus Licheniformis, Bacillus Pumilus, Bacillus Sphaericus, Bacillus Subtilis sub species 10144 and Bacillus Subtilis sub species 8646, a terpene and one or more surfactants. The terpene is preferably d-limonene. A method for cleaning surfaces is also disclosed, which method comprises deploying an aqueous composition comprising at least one strain of Class 1 Bacillus bacterial spores, selected from Bacillus Cirulans, Bacillus Megaterium, Bacillus Lichenforms, Bacillus Pumilus, Bacillus Sphaericus, Bacillus Subtilis sub species 10144 and Bacillus Subtilis sub species 8646, a terpene and one or more surfactants to a surface.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: August 12, 2014
    Assignee: Cleveland Biotech Limited
    Inventor: Anthony Brooke
  • Patent number: 8802613
    Abstract: The present invention is directed to a stabilized hydrogen peroxide solution containing stabilizers that maintain relatively high hydrogen peroxide stability in both concentrated form and when formulated into a cleaning solution that has a pH above 6 and contains components that normally would have a destabilizing effect on the hydrogen peroxide. The stabilizers include a first cyclic amino methane diphosphonic acid compound stabilizer in combination with a second phosphonic acid based stabilizer (different from the cyclic amino methane diphosphonic acid compound), wherein the weight ratio of the first stabilizer to the second stabilizer is at least about 2:1.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: August 12, 2014
    Assignee: Akzo Nobel N.V.
    Inventors: David J. Bonislawski, David C. Lovetro
  • Patent number: 8785364
    Abstract: Dual-usage aqueous liquid detergent compositions having suds compatability and improved cleaning, said composition containing from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system contains at least 35%, by weight of the surfactant system, of alkylethoxysulfate; from 0% to about 10%, by weight of the surfactant system, of nonionic surfactant; from 0% to about 10%, by weight of the surfactant system, of soap; further contains from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and the primary filler is modified silica; and mixtures thereof; and contains from about 0.01% to about 2.5%, by weight of the composition, of a structurant. Methods of using such detergent compositions for laundering textiles.
    Type: Grant
    Filed: June 21, 2013
    Date of Patent: July 22, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Eugene Steven Sadlowski, Shari Joy Soper
  • Patent number: 8785363
    Abstract: The invention discloses synergistic combinations of surfactants blends and cleaning composition. In certain embodiments a surfactant system is disclosed which includes extended anionic surfactants, linker surfactants, and a multiply charged cation component. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. In another embodiment anionic surfactants are combined with a solvent, and amine oxide to remove sunscreen stains. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.
    Type: Grant
    Filed: October 23, 2013
    Date of Patent: July 22, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Michael Charles DeNoma, Yvonne Marie Killeen, Steven E. Lentsch
  • Patent number: 8778093
    Abstract: The present invention is directed to a coating removal composition comprising at least one weak metal binding agent, a solvent system comprising at least one alcohol or ester, and a corrosion inhibition system. A method of removing a coating from an intentionally colored concrete floor is also disclosed. Utilization of the method results in at least 70% retention of colorant component after stripping a coating from an intentionally colored concrete surface, such as a floor.
    Type: Grant
    Filed: April 9, 2012
    Date of Patent: July 15, 2014
    Assignee: Diversey, Inc.
    Inventors: Charles A. Crawford, Carmine Savaglio, Lance D. Brown
  • Patent number: 8772216
    Abstract: The present invention relates to a low VOC hard surface cleaning composition comprising a surfactant, a glycol ether organic solvent, an aminoalcohol and fragrance, having a pH from 10.0 to 12.0. The present invention further encompasses a process to prepare a low VOC hard surface cleaning composition. Furthermore, the present invention encompasses a process of cleaning a hard surface with a low VOC hard surface cleaning composition.
    Type: Grant
    Filed: June 12, 2013
    Date of Patent: July 8, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Cedric Joseph Volont, William Tucker Campbell
  • Patent number: 8759276
    Abstract: The invention involves foam stabilization compositions that rely upon an electrostatic charge interaction. According to the invention, the positively charged class of polymers such as polyethyleneimine (PEI) polymers are used to provide a long range electrostatic interaction with detersive anionic or amphoteric surfactants present in the same. The interaction must be of sufficient character so that the components do not precipitate out, instead causing longer lasting and increased foam production. The system provides an environmentally friendly alternative for traditional foaming enhancers such as cocamide DEA.
    Type: Grant
    Filed: March 8, 2013
    Date of Patent: June 24, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen
  • Patent number: 8748364
    Abstract: Detergent compositions including at least one aminocarboxylate, at least one maleic/methylvinyl ether copolymer, an alkaline agent and optional additives. Embodiments of the present invention include reduced concentrations of aminocarboxylate compared to conventional compositions, while preventing scale accumulation and providing stain removal capability.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: June 10, 2014
    Assignee: Ecolab USA Inc.
    Inventor: Carter Silvernail
  • Patent number: 8741827
    Abstract: A multi-purpose cleaning compound comprising about 4.50% to about 16.50% by volume isopropyl alcohol; about 4.50% to about 16.50% by volume vinegar; about 2.00% and about 8.50% by volume ammonia; about 2.00% by volume of at least one pre-selected surfactant; between about 0.009% and about 0.05% by volume rosemary oil; and about 56.50% and about 86.90% by volume water.
    Type: Grant
    Filed: February 20, 2012
    Date of Patent: June 3, 2014
    Inventors: Lucyna Vyrostko, Joseph Vyrostko
  • Patent number: 8729001
    Abstract: The invention relates to compositions containing a) 45 to 65 wt. % of one or more secondary paraffin sulfonates with 8 to 22 carbon atoms, b) 1 to 10 wt. % of one or more alcohol alkoxylates which are produced from the reaction of alcohols R—OH, wherein R is an alkyl group with 9 to 11 carbon atoms, with alkoxylating agents selected from ethylene oxide, propylene oxide, or mixtures thereof and which contain on average 1 to 4 mol of structural units derived from the alkoxylating agents per 1 mol of structural units derived from the alcohols, and c) 25 to 52 wt. % water, in relation to the total weight of the composition in each case. The compositions can be used in an advantageous manner for producing washing and cleaning agents.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: May 20, 2014
    Assignee: Clariant International, Ltd
    Inventors: Johannes Himmrich, Wolfgang Walther
  • Patent number: 8729005
    Abstract: An aqueous liquid acidic hard surface cleaning composition having a pH of about 2-4 which necessarily comprises: an acid constituent, which is preferably an organic acid constituent, and especially preferably acetic acid, at least one nonionic surfactant, and especially preferably wherein the nonionic surfactants are derived from Guerbet alcohols; an organic solvent constituent which comprises at least one glycol ether solvent, preferably a glycol ether solvent; a sequestering polymer constituent; optionally a cosurfactant constituent, including one or more anionic, cationic, amphoteric or zwitterionic surfactants; optionally one or more further constituents selected coloring agents, fragrances and fragrance solubilizers, viscosity modifying agents including one or more thickeners, pH adjusting agents and pH buffers including organic and inorganic salts, optical brighteners, opacifying agents, hydrotropes, abrasives, and preservatives, as well as other optional constituents known to the art; and the balance,
    Type: Grant
    Filed: August 5, 2009
    Date of Patent: May 20, 2014
    Assignee: Reckitt & Colman (Overseas) Limited
    Inventors: Malcolm Tom McKechnie, Edward Staunton, Alfred Vincent Spencer, Neil Atkin, Wesley Bowyer
  • Patent number: 8729007
    Abstract: An acidic laundry detergent composition comprising less than about 20% of a surfactant system comprising surfactants selected from the group consisting of anionic surfactants, nonionic surfactants, cationic surfactants and mixtures thereof, wherein the surfactant system has a Hydrophilic Index of greater than or equal to about 9.00 and an organic acidulant at a level such that the ratio of surfactant system to organic acidulant is less or equal to about 3.0 and an alkaline neutralizer added in an amount necessary to raise the neat pH of the detergent composition above or equal to about 2.5 but no higher than or equal to about 3.0.
    Type: Grant
    Filed: January 17, 2013
    Date of Patent: May 20, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Eugene Steven Sadlowski, Cheyne Thomas, Peter De Nies, Nilgun Esin Aksoy
  • Patent number: 8709169
    Abstract: The present invention relates to the use of an alkyl di(lower alkyl)mono(polyoxyethylene) quaternary ammonium compound as a hydrotrope in 5 aqueous solutions for a nonionic surfactant, preferably a C8-C18-alcohol alkoxylate containing 1-20 ethyleneoxy units and 0-5 propyleneoxy units. It also relates to a composition comprising said quaternary ammonium compound and said nonionic surfactant. The cationic surfactant has the formula 10 R2+R(1)N(CH2CH2O)n H X R1 wherein R?C6-C22 alkyl; R1 and R2 are independently a C1-C4 alkyl group; n=8-25; and X? is an anion. The compositions may be used for the cleaning of hard surfaces, for example for vehicle cleaning or machine dishwashing.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: April 29, 2014
    Assignee: Akzo Nobel N.V.
    Inventors: Mahnaz Company, Kornelis Overkempe, Adrianus Marinus Groenewegen
  • Patent number: 8709168
    Abstract: Hard surfaces can be treated to improve soil resistance, particularly resistance to oily soils, by applying a composition of a quaternised, polyamine, polypropoxylate, polyethoxylate. The polyamine can be a polyethyleneimme, desirably having a molecular weight of from 10 to 50 kDa. The average length of the polypropylenoxy chains is desirably from 10 to 100 and the polyethylenoxy chains from 5 to 50 (each per NH group in the polyamine), particularly at a molar ratio of PO:EO of about 3:1. The degree of quaternization of the nitrogen atoms in the polyamine is desirably from 70 to 100%. The polymer will usually be used in solution in water or an aqueous formulation, which may include detergent and other detergent formulation components.
    Type: Grant
    Filed: October 4, 2010
    Date of Patent: April 29, 2014
    Assignee: Croda International PLC
    Inventors: Alan Geoffrey Waite, Trevor Graham Blease, Sean Alexander Robins
  • Patent number: 8685912
    Abstract: A detergent composition for metal according to the present invention contains a specific non-ionic surfactant, a specific nitrogen-containing organic compound, a specific carboxylic acid or salt thereof, and a specific alkanol amine, and has a pH of at least 9 that is measured at 25° C. when the detergent composition is diluted to 1% by mass of an aqueous solution. According to the present invention, the detergent composition for metal having excellent corrosion inhibition properties, excellent effluent treatment properties, excellent foaming suppressing properties and excellent liquid stability in addition to high detergent properties for metal, can be provided.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: April 1, 2014
    Assignee: Lion Corporation
    Inventors: Shigeru Maeyama, Kei Tamura, Akira Shinohara, Keita Someya
  • Patent number: 8669221
    Abstract: Cleaning compositions comprising amphiphilic water-soluble alkoxylated polyalkylenimines having an inner polyethylene oxide block and an outer polypropylene oxide block.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: March 11, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Dieter Boeckh, Christian Bittner, Andrea Margret Misske, Arturo Luis Casado Dominguez
  • Patent number: 8658582
    Abstract: The present invention is directed toward a composition comprising: (a) at least one alkoxylated monoamine; (b) at least one alkoxylated monoacid; (c) at least one lipophilic compound; (d) at least one surfactant; (e) optionally, at least one auxiliary ingredient; and (f) at least one cosmetically acceptable carrier; wherein the ratio by weight of (b):(a) is greater than 1 and wherein the ratio by weight of (a)+(b):(c) is greater than 2. The present invention also relates to methods for cleansing and conditioning keratinous substrates. The methods can provide hair with improved shine, condition, manageability, and styling ability.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: February 25, 2014
    Assignee: L'oreal
    Inventors: Hongjie Cao, Dina Burakov
  • Patent number: 8658587
    Abstract: A container has: a) a collapsible receptacle, the wall of which is designed flexibly such that the internal volume of the receptacle is adapted to the volume of a liquid contained therein, and which has an outlet with an outlet valve; and b) in the receptacle a disinfectant composition in the form of a solution with a content of aliphatic alcohol of at most 20% by weight. It is possible that the disinfectant composition is not contaminated with spores or other germs also after the container has been opened, even upon repeated discharge from the container.
    Type: Grant
    Filed: February 10, 2011
    Date of Patent: February 25, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Sabine Behrends, Henning Reinstorff, Andreas Dettmann
  • Patent number: 8653016
    Abstract: The present invention provides a biodegradable cleaning composition that includes a surfactant component including an ethoxylated 2-propyl heptanol, a chelating component including a tri-sodium salt of methylglycinediacetic acid and an emulsifier component including an ethoxylated hexanol having the formula C6H13O(CH2CH2O)H. The ethoxylated 2-propyl heptanol has the formula C5H11CH(C3H7)CH2O(C2H4O)pH, wherein p is a number of from 3 to 6. The composition also includes water and an acid component to establish a pH of the composition at less than 2. The composition is substantially free of solvents thereby reducing emission of volatile organic compounds and reducing potential environmental pollution and health hazards. The composition is also effective in removing rust, lime soap, and metal salts of fatty acids from hard surfaces including metal, vinyl, and fiberglass.
    Type: Grant
    Filed: November 23, 2010
    Date of Patent: February 18, 2014
    Assignee: BASF SE
    Inventors: Suzanne Gessner, Charles Kerobo, Sonia Patterson
  • Patent number: 8648026
    Abstract: A composition for dissolving and/or inhibiting deposition of scale on a surface of a system comprises an acidic component, a wetting agent, and a corrosion inhibitor. The composition may further comprise water. The acidic component comprises an alkanesulfonic acid, e.g. methanesulfonic acid (MSA). The wetting agent comprises a surfactant. The corrosion inhibitor comprises an amphoteric surfactant. The alkanesulfonic acid is present in an amount of at least about 50 weight percent (wt %), the surfactant is present in an amount of from about 0.1 to about 30 wt %, and the amphoteric surfactant is present in an amount of from about 0.025 to about 20 wt %, each based on 100 wt % of the alkanesulfonic acid, the surfactant, and the amphoteric surfactant combined. A method of dissolving and/or inhibiting deposition of scale on the surface of the system comprises the step of contacting the surface of the system with the composition.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: February 11, 2014
    Assignee: BASF SE
    Inventors: Joseph P Borst, Keith Hirsch, Stephen F Gross
  • Patent number: 8648027
    Abstract: A cleaning composition for sanitizing and/or disinfecting hard surfaces, comprising: a cationic biocide, surfactant and low levels of VOC solvents. The cleaning composition is adapted to clean a variety of hard surfaces without leaving behind a visible residue and creates low levels of streaking and filming on the treated surface. The cleaning composition contains less than 5% by weight of VOCs. The cleaning composition may be used alone as a liquid or spray formulation or in combination with a substrate, for example, a pre-loaded cleaning wipe.
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: February 11, 2014
    Assignee: The Clorox Company
    Inventors: Diana Mitchell, Sarah Coulter, Ashish Jha, William Ouellette, Gregory Van Buskirk
  • Patent number: 8642530
    Abstract: The present invention is directed to rinse aid compositions and methods for making and using the rinse aid compositions. The compositions of the invention include a sheeting agent, a defoaming agent, and an association disruption agent. The rinse aid compositions of the present invention result in a faster draining/drying time on most substrates compared to conventional rinse aids. The rinse aid compositions of the present invention are especially suitable for use on plastic substrates.
    Type: Grant
    Filed: April 5, 2013
    Date of Patent: February 4, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Janel Marie Kieffer, Victor Fuk-Pong Man, Steven E. Lentsch
  • Patent number: 8629094
    Abstract: A method and composition for deodorizing soft surfaces such as carpeting and upholstery are disclosed. The method includes the spraying of a liquid composition on a soft surface and allowing the composition to absorb into the soft surface, form liquid agglomerations within the soft surface to the agglomerations can make contact with malodorants disposed within the soft surface. The composition is capable of penetrating rapidly and deeply into the soft surfaces for contacting odor-causing substances embedded therein. The composition comprises an active ingredient such as a glycol or triethanolamine. Other ingredients that contribute to the surface penetration and/or agglomeration formation include ethanol, water, fragrance and a combination of at least one nonionic and at least one ionic surfactant.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: January 14, 2014
    Assignee: S.C. Johnson & Son, Inc.
    Inventors: Peter N. Nguyen, Cary E. Manderfield, Maciej K. Tasz
  • Patent number: 8628626
    Abstract: A heavy oil cleaning composition comprising: a) a blend of dibasic esters comprising dialkyl methylglutarate and at least one of a dialkyl adipate or dialkyl ethylsuccinate; b) at least one terpene; and c) at least one surfactant. Also described are methods for delivering a solvent at reduced concentration comprising the steps of: a) obtaining a terpene-based solvent; and b) mixing the terpene-based solvent with a carrier fluid (the carrier fluid comprising a microemulsion of i) a blend of dibasic esters selected from the group consisting of dialkyl methylglutarate, dialkyl adipate, dialkyl ethylsuccinate, dialkyl succinate, dialkyl glutarate and any combination thereof, ii) at least one surfactant selected from the group consisting of a terpene alkoxylate, an alcohol alkoxylate and any combination thereof; and iii) water) in order to obtain a mixture to clean heavy oils.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: January 14, 2014
    Assignee: Rhodia Operations
    Inventors: David Fluck, Amit Sehgal, Satyen Trivedi, Ruela Talingting Pabalan, Charles Aymes
  • Patent number: 8623151
    Abstract: A cleaning composition includes an alkali metal silicate, a polymer including maleic acid, vinyl acetate and alkyl acrylate monomers, and optionally water. The cleaning composition can include approximately 10% and approximately 90% by weight of at least one alkali metal silicate, greater than or equal to approximately 0.1% by weight of the polymer containing maleic acid, vinyl acetate and alkyl acrylate monomers, and approximately 0% to approximately 80% by weight water.
    Type: Grant
    Filed: March 23, 2012
    Date of Patent: January 7, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Erik C. Olson, Carter Silvernail
  • Patent number: 8617317
    Abstract: Renewable, non-volatile cleaning compositions incorporating ethyl ester solvents are disclosed. Preferred compositions employ non-volatile C8-16 ethyl ester solvents. All-purpose cleaning compositions incorporating the non-volatile C8-16 ethyl ester solvents, further include an alkyl polyglycoside surfactant, an alcohol ethoxylate surfactant, and water. Preferably the compositions are free of anionic, cationic and amphoteric surfactants and/or co-solvents. The invention also discloses methods employing the non-volatile solvent all-purpose cleaning compositions.
    Type: Grant
    Filed: July 31, 2012
    Date of Patent: December 31, 2013
    Assignee: Ecolab USA Inc.
    Inventor: Mark Dennis Levitt
  • Patent number: 8618041
    Abstract: The present invention relates to surfactant-based all-purpose cleaners useful for cleaning surfaces including household hard surfaces as well as glass. The cleaning compositions comprise an anionic sulfonate surfactant, a non-ionic aliphatic ethoxylated surfactant, an alcohol, and a residue-reducing agent. The cleaning compositions of the invention are effective in removing soils such as grease soil and in leaving un-rinsed or unwiped surfaces residue free.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: December 31, 2013
    Assignee: Colgate-Palmolive Company
    Inventors: Christine Toussaint, Nicole Andries, Myriam Mondin
  • Patent number: 8598106
    Abstract: The present invention describes a formulation comprising: (A) at least one surfactant; and (B) an anti-microbial composition that comprises (i) an anti-microbial agent with surfactant properties; (ii) a hydrophobic material and (iii) a polar solvent.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: December 3, 2013
    Assignee: Byotrol PLC
    Inventors: Ulrich Schwarz, Stephen Brian Falder, John Yates
  • Patent number: 8598105
    Abstract: The present invention provides a liquid detergent composition containing a specific amount of surfactant (A); a specific amount of a polymer compound (B) having the polyether chain moiety (i) and the polymer chain moiety (ii) composed of polymerization units derived from the specific unsaturated monoethylenic monomer; and water, wherein component (A) contains a specific amount of a specific alkoxyl nonionic surfactant (a1), and component (B) is a polymer compound having the polyether chain moiety (i) composed of polymerization units derived from an epoxide having 2 to 5 carbon atoms and the polymer chain moiety (ii) composed of polymerization units derived from one or more unsaturated carboxylic acid monomers selected from acrylic acid, methacrylic acid and maleic acid, the polymer compound having a graft structure wherein one of the chain moieties (i) and (ii) is the main chain and the other is a side chain.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: December 3, 2013
    Assignee: Kao Corporation
    Inventors: Toshio Miyake, Ayumi Watada, Ayako Kita, Kohei Nishida, Kenichi Shiba, Shinichi Inaba
  • Patent number: 8580727
    Abstract: The invention discloses synergistic combinations of surfactants blends and cleaning composition. In certain embodiments a surfactant system is disclosed which includes extended anionic surfactants, linker surfactants, and a multiply charged cation component. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. In another embodiment anionic surfactants are combined with a solvent, and amine oxide to remove sunscreen stains. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: November 12, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Michael Charles DeNoma, Yvonne Marie Killeen, Steven Eugene Lentsch
  • Patent number: 8580724
    Abstract: In one embodiment, a metal loss inhibitor concentrate is provided which contains water, (A) a component of dissolved organic compounds and polymers that contain at least two hydroxy moieties per molecule and an average of at least 0.4 hydroxy moieties per carbon atom; (B) a thiourea component; and (C) a dissolved component containing aryl and quaternary ammonium moieties; and, optionally: (D) a wetting agent, such as a component of an ethoxylate of an alcohol. Such solutions form useful inhibitor concentrates when combined with aqueous chelating cleaning solutions, wherein such solutions, when contacted with a metal surface, are effective in removing scale, smut and other deposits from the metal surface but exhibit a reduced tendency to attack or unduly etch the metal itself, or to inhibit the subsequent desired oxidation and dissolution of metallic copper deposits.
    Type: Grant
    Filed: December 12, 2011
    Date of Patent: November 12, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: David R. McCormick, Ronald F. Dubs
  • Patent number: 8575085
    Abstract: The present invention provides an anti-microbial composition comprising (i) an antimicrobial agent with surfactant properties, (ii) a siloxane selected from those having the formulae V:(H3C)[SiO(CH3)2]nSi(CH3)3, and (H3C)[SiO(CH3)HnSi(CH3)3, and mixtures thereof, wherein n is from 1 to 24; and (iii) a polar solvent, wherein the ratio of (i) to (ii) is from about 100:1 to about 5:1.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: November 5, 2013
    Assignee: Byotrol PLC
    Inventors: Ulrich Schwarz, Stephen Brian Falder
  • Patent number: 8568490
    Abstract: The invention provides a liquid detergent composition containing (a) a nonionic surfactant obtained by adding ethylene oxide and an alkylene oxide with from 3 to 5 carbon atoms to a compound represented by R—OH (wherein R represents an alkyl group or an alkenyl group with from 8 to 18 carbon atoms) under a specified condition, (b) an anionic surfactant and (c) a water-miscible organic solvent in specified ratios, respectively.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: October 29, 2013
    Assignee: Kao Corporation
    Inventors: Toshio Miyake, Hitoshi Ishizuka, Kohei Nishida, Ayako Kita
  • Patent number: 8569218
    Abstract: A gelled cleaning composition is provided that includes a standard temperature and pressure (STP) liquid oil or STP malleable wax present from 0.1 to 9.9 total weight percent. An emulsifier is present from 0.01 to 10 total weight percent, along with an alkylene glycol present from 0.002 to 11 total weight percent. A microemulsion is present in the composition from 0.2 to 15 total weight percent. Water forms a majority of the composition such that the composition is monophasic for at least 4 months storage at 20° Celsius. The composition is well suited for use in a process to remove a lipophilic substance from hands or an inanimate substrate by applying the composition and after allow sufficient time for the substance to be softened or solubilized, removing the composition and at least a portion of the substance. Silicone gaskets, as well as other cured resins and paints are readily removed.
    Type: Grant
    Filed: January 18, 2012
    Date of Patent: October 29, 2013
    Assignee: Illinois Tool Works, Inc.
    Inventor: Claudia E. Britton
  • Patent number: 8563493
    Abstract: Provided are: an oil composition for cosmetics which is readily miscible with a makeup stain and can rinse out freshly through washing with water without leaving oily feeling, regardless of whether the skin is wet or not, and excels in safety and temporal stability; and a cleansing cosmetic containing the oil composition for cosmetics. The oil composition for cosmetics contains 1 to 30 percent by weight of a medium-chain polyglycerol monoalkyl ether; 1 to 30 percent by weight of a long-chain polyglycerol monoalkyl ether; and 40 to 98 percent by weight of at least one oily ingredient selected from the group consisting of silicone oils, ester oils, and triglycerols.
    Type: Grant
    Filed: September 16, 2010
    Date of Patent: October 22, 2013
    Assignee: Daicel Corporation
    Inventor: Yuichi Sakanishi
  • Patent number: 8546314
    Abstract: A surface treatment composition comprising from about 6% to about 20%, by weight of the composition, of cationic polymer; from about 6% to about 40%, by weight of the composition, of anionic surfactant; and from about 4% to about 15%, by weight of the composition, of a shielding salt, wherein the weight ratio of anionic surfactant to cationic polymer is between about 0.5:1 and about 4:1. The shielding salt is defined by having a molecular weight of from about 25 to about 500 and being incapable of lowering the surface tension of water below 50 mN/m when added to water at concentrations of up to 0.01M.
    Type: Grant
    Filed: November 6, 2012
    Date of Patent: October 1, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Sherri Lynn Randall, Michelle Ann Tscheiner, Eric Scott Johnson, Mark Robert Sivik