Sulfur Containing Anionically Substituted Surfactant Patents (Class 510/424)
  • Patent number: 7387992
    Abstract: A laundry detergent composition comprising from about 0.1% to about 80%, by weight of the composition, of a polyamine mono-anionic surfactant; and a solubiliser; in a defined weight ratio. Also, a process of making the polyamine mono-anionic surfactant and the laundry compositions containing the same.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: June 17, 2008
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Shui-Ping Zhu, Mei Shi
  • Patent number: 7368417
    Abstract: A hard surface cleaning solution having improved cleaning and descaling properties. In one formulation, the cleaning solution comprises a first organic acid, a second organic acid, a surfactant, a solvent and a diluent. The first organic acid is a carboxylic acid preferably comprising lactic acid, while the second organic acid is a carboxylic acid preferably comprising gluconic acid. The surfactant is selected from the group consisting of sultaines, betaines and amino propionates. The solvent is a an alkoxylated alcohol preferably selected from the propylene glycol ether class of compounds. In a second formulation, the cleaning solution comprises a first organic acid, a surfactant, a solvent and a diluent. The first organic acid is a carboxylic acid preferably comprising lactic acid, while the surfactant is selected from the group consisting of sultaines, betaines and amino propionates and the solvent is a an alkoxylated alcohol preferably selected from the propylene glycol ether class of compounds.
    Type: Grant
    Filed: June 5, 2006
    Date of Patent: May 6, 2008
    Assignee: Jelmar LLC
    Inventor: Rosemary A. Gaudreault
  • Publication number: 20080039356
    Abstract: Removal chemistry solutions are described herein that include at least one sulfonic acid component having the formula: R—SO3H ??(Formula I) where R comprises at least one halo group, amino group, alkyl group, alkenyl group, alkynyl group or phenylamino group having the formula C6(NH2)H2XY, where X and Y may comprise at least one hydrogen, halo group, alkyl group, alkenyl group, alkynyl group, hydroxyl group, amino group or phenyl group. R may also comprise R1R2R3C, where R1, R2 and R3 may be the same or different and may comprise at least one hydrogen, halo group, alkyl group, alkenyl group, alkynyl group, hydroxyl group, amino group or aromatic group, and at least one solvent or solvent mixture. In some formulations, at least one fluoride source is added to the removal chemistry solution.
    Type: Application
    Filed: July 27, 2006
    Publication date: February 14, 2008
    Inventors: Ben Palmer, Deborah Yellowaga
  • Patent number: 7304022
    Abstract: Thickened acidic film forming hard surface cleaning and disinfecting compositions which are particularly useful in the cleaning of ceramic surfaces, especially lavatory surfaces.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: December 4, 2007
    Assignee: Reckitt Benckiser Inc.
    Inventors: Tak Wai Cheung, Edward Fu
  • Patent number: 7282475
    Abstract: The present invention provides lysis reagents, containers, methods and kits relating to the extraction or the extraction and isolation of a cellular component from a host cell. More specifically, the invention provides combinations of zwitterionic compounds that may be employed to aide in the extraction or the extraction and isolation of a cellular component from a host cell.
    Type: Grant
    Filed: August 23, 2005
    Date of Patent: October 16, 2007
    Assignee: Sigma-Aldrich Co.
    Inventors: Jeff Porter, Richard Mehigh
  • Publication number: 20070191251
    Abstract: The present invention relates to a bleach-free detergent tablet for use in the laundering of coloured garments. The tablet composition provides a pH through the wash of less than 9, comprises at least one surfactant and has a normalised soil removal index of greater than minus 2.
    Type: Application
    Filed: February 15, 2007
    Publication date: August 16, 2007
    Inventors: Joel Geny, Michael Alan John Moss
  • Patent number: 7226897
    Abstract: A composition having a first nonionic nonylphenol surfactant having an HLB value ranging from about 10 to about 15, a second nonionic nonylphenol surfactant having an HLB value ranging from about 16 to 20, an aqueous solvent, and optionally, a bio-film permeation agent. A total of the first surfactant and the second surfactant in the composition ranges from about 2 to about 20 percent by weight of a total weight of the composition, and a ratio of the second surfactant to the first surfactant in the composition ranges from about 2:1 to about 4:1.
    Type: Grant
    Filed: July 26, 2006
    Date of Patent: June 5, 2007
    Assignee: Innovation Services, Inc.
    Inventors: Jeffrey G. Hubrig, Joseph B. Dooley
  • Patent number: 7223722
    Abstract: A composition and method for use in imparting or maintaining a glossy or shiny finish on a hard surface. In one embodiment, the composition comprises a base polish component or components, and at least one poly[oxyalkylene] ammonium cationic surfactant. In another embodiment, a method of imparting a glossy finish on a hard surface by applying a composition to the hard surface, the composition comprising at least one poly[oxyalkylene] ammonium cationic surfactant. In some such embodiments, the composition comprises a base polish and the poly[oxyalkylene] ammonium cationic surfactant is dispersed in the base polish. Preferably, the poly[oxyalkylene] ammonium cationic surfactant comprises in the range of about 0.01 to about 10 wt. %, more preferably in the range of about 0.05 to about 5 wt. %, and more preferably in the range of about 0.1 to about 1 wt. % of the total composition.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: May 29, 2007
    Assignee: Ecolab Inc.
    Inventors: Gregory S. Conrad, Michael E. Besse, Terry J. Klos
  • Patent number: 7198680
    Abstract: A method for cleaning contaminated surfaces of surgical waste management equipment. The method includes rinsing surfaces of the equipment with water to remove water soluble contaminants and waste material. A rinse solution is applied to the surfaces of the equipment to provide a residual film thereon. The rinse solution includes a first nonionic nonylphenol surfactant having an HLB value ranging from about 10 to about 15, a second nonionic nonylphenol surfactant having an HLB value ranging from about 16 to 20, a bio-film permeation agent, and an aqueous solvent. A total of the first surfactant and the second surfactant in the solution ranges from about 2 to about 20 percent by weight of a total weight of the solution and a ratio of the second surfactant to the first surfactant in the solution ranges from about 2:1 to about 4:1.
    Type: Grant
    Filed: July 26, 2006
    Date of Patent: April 3, 2007
    Assignee: Innovation Services, Inc.
    Inventors: Joseph B. Dooley, Jeffrey G. Hubrig, Richard H. DeVault, Rodney D. Parker, John M. Izenbaard
  • Patent number: 7087567
    Abstract: A light duty, liquid cleaning composition comprising: at least two different surfactants, lauryol ethylene diamine triacetate, a zinc inorganic salt, and water.
    Type: Grant
    Filed: April 14, 2003
    Date of Patent: August 8, 2006
    Assignee: Colgate-Palmolive Company
    Inventors: Thomas Connors, Robert D'Ambrogio, Bruce Nascimbeni
  • Patent number: 7071155
    Abstract: A non-polymer thickening medium, and the inclusion of such a non-polymer thickening medium in a cleaning composition. In some embodiments, the non-polymer thickening medium includes a sparingly water soluble surfactant, and an organic solvent including an OH group, an ether group, or both an OH group and an ether group. At lease some of the two components of the thickening medium interact with each other thicken a composition to which they are added. In some embodiments, the thickening medium components are included within a cleaning composition which further includes a source of alkalinity, and a polar carrier. Some other embodiments relate to methods of making, and methods of using such thickening medium and cleaning compositions.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: July 4, 2006
    Assignee: Eoclab, Inc.
    Inventors: Greg G. Griese, Mike J. Bartelme, Victor Fuk-Pong Man, Ed D. Sowle
  • Patent number: 7037883
    Abstract: A process of making a liquid laundry detergent composition comprising a polyanionic ammonium surfactant, the process comprising: forming the polyanionic ammonium surfactant by mixing a liquid carrier with: (a1) from about 0.03% to about 85%, by weight of the composition, of a conjugate acid of an anionic surfactant; and (a2) from about 10% to about 50%, based on the molar equivalent of the amount of the conjugate acid, of a polyamine; (a3) wherein the mixing of (a1) and (a2) is carried out in the substantial absence of bases other than the polyamine. Also included is a process wherein the monoanionic surfactant is formed along with the polyanionic ammonium surfactant, in which case a base other than the polyamine may be present but than the amount of such base should be no greater than the required stoichiometric amount of the base to form the monoanionic surfactant.
    Type: Grant
    Filed: September 17, 2003
    Date of Patent: May 2, 2006
    Assignee: Unilever Home & Personal Care USA Division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Yun Peng Zhu
  • Patent number: 7030072
    Abstract: A cleanser is provided comprising a glycerin based mixture which may have been aerated. The aerated mixture may be combined with a selected fragrance and a selected colorant. The selected fragrance and colorant may correspond to a food product such as a vegetable, fruit, ice cream or the like. Moreover, first and second aerated mixtures may be extruded out of a funnel simultaneously into a rotating container to impart a swirl configuration on the mixtures filling the container. The aerated cleanser may be combined with real food products such as vegetable and fruits. Lastly, the aerated cleanser of the present invention may be formed into a scooped ice cream shape by scooping the same with an ice cream scoop.
    Type: Grant
    Filed: July 20, 2004
    Date of Patent: April 18, 2006
    Assignee: Primal Elements, Inc.
    Inventors: Faith Freeman, Scott H. Freeman, Frank H. Asbury
  • Patent number: 7022657
    Abstract: The present invention provides a shear thinning, transparent, gel laundry detergent composition, comprising a surfactant system containing surfactant material selected from an anionic surfactant, a nonionic surfactant or a mixture thereof, and from 1 to 8% by weight of a fatty alcohol gelling agent having the formula wherein R1, R2 and R3 are independently selected from hydrogen and saturated or unsaturated, linear or branched C1–C16 alkyl groups, whereby the total number of carbon atoms in the gelling agent is between 8 and 17. It has been found that this gel laundry composition can stable suspend particles or capsules either for improving visual appearance or for practical reasons.
    Type: Grant
    Filed: November 6, 2003
    Date of Patent: April 4, 2006
    Assignee: Unilever Home and Personal Care USA division of Conopco, Inc.
    Inventors: John David Hines, Feng-Lung Gordon Hsu, Yun-Peng Zhu
  • Patent number: 7018968
    Abstract: A liquid laundry detergent composition comprising: (a) from about 0.1% to about 80%, by weight of the composition, of a polyanionic ammonium surfactant; (b) a liquid carrier; (c) wherein the composition is substantially free of bases having pKa equal to or greater than 10, other than nitrogen-based bases.
    Type: Grant
    Filed: September 17, 2003
    Date of Patent: March 28, 2006
    Assignee: Unilever Home & Personal Care USA
    Inventors: Feng-Lung Gordon Hsu, Yun Peng Zhu, Tamara Padron, Kimball James Woelfel
  • Patent number: 7018970
    Abstract: According to the inventive method of making gels, the main mixture comprising most of the ingredients with the exception of a fatty alcohol is mixed, using at least one in-line mixer, with the gelling post-mix comprising the fatty alcohol. The preferred process includes the mixing of the main mixture and the gelling post-mix just prior to either filling or storing the composition.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: March 28, 2006
    Assignee: Unilever Home and Personal Care USA division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Yun-Peng Zhu, Charles Ebert, Agnes Boudou, Ronald Frederick Vogel, John David Hines
  • Patent number: 7012049
    Abstract: The present invention relates to a multiphase aqueous cleansing composition for cleansing human skin and hair, which when agitated forms a single application phase, and when left standing, the composition rapidly returns to an appearance having at least two visibly distinct aqueous phases. The multiphase aqueous cleansing composition of the present invention provides an esthetically interesting and useful cleansing composition for use as a body wash, shower gel, foam bath or shampoo. The aqueous multiphase cleansing composition comprises: a surfactant comprising a surfactant or salt thereof; one or more co-surfactants; a humectant; and a salt, wherein the cleansing composition is essentially free of a thickener or a detergent builder.
    Type: Grant
    Filed: March 26, 2004
    Date of Patent: March 14, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Cheryl Littau, Torsten Henning, Sandra Porter, Sam Cooper
  • Patent number: 7008914
    Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: March 7, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi, John F. Knifton, Melvin Stockton
  • Patent number: 6995128
    Abstract: The invention provides an improved, reduced streaking/filming dilute cleaning formulation which is to be used in a no-rinse cleaning application, preferably either by a dosing dispenser or in a combined cleaning tool which contains a cleaning head, a handle, a reservoir of the cleaning formulation mounted to said handle and a means for dispensing the cleaning formulation in a suitable direction relative to the cleaning head.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: February 7, 2006
    Assignee: The Clorox Co.
    Inventors: Shumanta Mitra, Scott T. Haubrich, Boli Zhou
  • Patent number: 6995127
    Abstract: This invention is directed to detergent compositions which employ sulfonated alkyltoluenes as surfactants, wherein the sulfonated alkyltoluenes have a higher content of the sulfonated 2-phenyl alkyltoluenes isomers than was previously available in sulfonated alkyltoluene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated alkyltoluenes having lower contents of the 2-phenyl alkyltoluene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkyltoluenes are also provided, including dry cleaning formulations containing same.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: February 7, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi
  • Patent number: 6972278
    Abstract: A shear-thinning lamellar gel detergent composition containing suspended particles, employing a non-neutralized fatty acid as a structuring agent, in a specific amount, depending on the total surfactant level. The weight % ratio of non-neutralized fatty acid to the total surfactant within a specific range, defined by the Gelling Index equation, results in gels with the desired properties. The inventive product offers an advantage of laundry pre-treater and a detergent in a single product and also provides a visual cue of suspended particles.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: December 6, 2005
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Yun Peng Zhu, John David Hines, Ronald Frederick Vogel
  • Patent number: 6969700
    Abstract: A liquid laundry detergent composition comprising from about 0.1% to about 80%, by weight of the composition, of a polyanionic ammonium surfactant; a substantially non-aqueous carrier; and a solid inorganic base having pKa equal to or greater than 10.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: November 29, 2005
    Assignee: Unilever Home & Personal Care, USA Division of Conopco, Inc
    Inventors: Gregory Hsu, Guanglin Sun, Feng-Lung Gordon Hsu
  • Patent number: 6964945
    Abstract: The invention relates to solid detergent compositions comprising an aluminosilicate builder and an anionic surfactant and comprising (n) components (i), n being at least 2, whereby the level of aluminosilicate builder in said components together is at least 5% by weight of the composition and the level of the anionic surfactant in said components together is at least 5% by weight of the composition, and whereby the degree of mixture (M) of the anionic surfactant and the aluminosilicate builder is from 0 to 0.7, as defined in the description.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: November 15, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Richard Timothy Hartshorn, Zayeed Alam, Kevin Norwood
  • Patent number: 6953772
    Abstract: The invention teaches the preparation of a concentrated sanitizing and cleaning preparation. The preparation has a dual use for cleaning and sanitizing food surfaces as well as food contact and non-food contact surfaces. The composition of the invention shows rapid microbicidal properties against representative gram positive and gram-negative bacteria. The invention uses GRAS, food additive ingredients and/or ingredients that are approved by the USFDA for use on food.
    Type: Grant
    Filed: September 9, 2003
    Date of Patent: October 11, 2005
    Inventor: John A. Lopes
  • Patent number: 6949492
    Abstract: New aqueous nacreous concentrated compositions, containing ethoxylated glycerides derived from carboxylic acids having 6 to 22 carbon atoms as emulsifying and/or dispersing agent are provided which show all the essential features required for this kind of composition, such as storage stability, excellent nacreous appearance, besides the possibility of acting as thickening agents and increasing the foaming power of the personal care cosmetic products.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: September 27, 2005
    Assignee: Kao Corporation
    Inventors: Pilar Castán Barberán, Hiroshi Abe
  • Patent number: 6949497
    Abstract: A liquid detergent composition comprising: a) an alkyl benzene sulfonic acid neutralized with an alkanolamine, said alkyl benzene sulfonic acid containing less than 25%, preferably less than 20%, of the 2-phenyl isomer; and b) an organic solvent; said composition containing less than 3 wt. % water.
    Type: Grant
    Filed: January 17, 2002
    Date of Patent: September 27, 2005
    Assignee: Reckitt Benckiser N.V.
    Inventors: Antonio Cordellina, Giorgio Franzolin, Daniele Fregonese, Alessandro Latini, Sara Quaggia
  • Patent number: 6949501
    Abstract: Aqueous liquid detergent dispersions are claimed which essentially comprise 5% by weight to 35% by weight of anionic surfactant 10% by weight to 50% by weight of builders, 0% by weight to 10% by weight of electrolytes and 0.1% by weight to 10% by weight of quaternary alkylhydroxyethylammonium salt, where the % by weight ratio of anionic surfactant to quaternary alkylhydroxyethylammonium salt is 50:1 to 2:1.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: September 27, 2005
    Assignee: Clariant GmbH
    Inventors: Johannes Himmrich, Ulrike Reploeg, Werner Skrypzak, Dennis Miller
  • Patent number: 6946437
    Abstract: An anionic surfactant powder prepared by subjecting a mixture of an anionic surfactant and a solvent to microwave irradiation to remove at least a part of the solvent, and a process for preparing the anionic surfactant. The anionic surfactant powder can be suitably used for laundry detergents, detergents for tableware and kitchenware, foaming agents for toothpastes, powdery shampoos, emulsifying agents for polymerization, foaming agents for cement plaster and the like.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: September 20, 2005
    Assignee: KAO Corporation
    Inventors: Kazunori Aizawa, Kazuhito Miyoshi, Osamu Tabata
  • Patent number: 6939839
    Abstract: A cleaning composition uses a terpene such as D-limonene or orange oil, a nonionic surfactant, a single anionic surfactant, an anti-oxidant, hydrogen peroxide, and the balance deionized water.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: September 6, 2005
    Inventor: Louis B. Johnson
  • Patent number: 6908894
    Abstract: A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula: wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said composition is electroneutral; R? is selected from H and C1 to C3 alkyl; R? is selected from H and C1 to C3 alkyl; R?? is selected from H and C1 to C3 alkyl; any of R? and R? is nonterminally attached to L and at least one of R? and R? is C1 to C3 alkyl; and A is aryl; and wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R?, R? and A to L; in at least about 60% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms thereof; and wherein further said alkylarylsulfonate surfactant system has
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: June 21, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kevin Lee Kott, Jeffrey John Scheibel, Thomas Anthony Cripe, Daniel Stedman Connor, Phillip Kyle Vinson
  • Patent number: 6906016
    Abstract: The invention relates to liquid cleansers which comprise water soluble or water swellable starch combining with linear C8 to C13 fatty acid to structure the composition.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: June 14, 2005
    Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.
    Inventor: Liang Sheng Tsaur
  • Patent number: 6903057
    Abstract: The invention relates to liquid cleansers which comprise water soluble or water swellable starch to structure the composition.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: June 7, 2005
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventor: Liang Sheng Tsaur
  • Patent number: 6897187
    Abstract: The present invention relates to a clear liquid detergent composition suitable for use in dishwashing and multipurpose cleaners for household applications as well as for industrial and institutional uses. The clear liquid detergent comprises a) 1 to 40 percent an anionic surfactant or group of anionic surfactants, b) 0.01 to 10 percent cationic surfactants, and c) optionally, 0.05 to 15 percent amphoteric and/or nonionic surfactants. More particularly, the light duty detergents of the present invention cationic compounds of the formula: wherein R1 is C8-C22-alkyl, C8-C22-alkenyl, C8-C22-alkyl/alkenylamidopropyl, C8-C22 alkoxyalkenylethyl, C8-C22-alkyl/alkenyi(poly)alkoxyalkyl, C8-C22-alkanoylethyl or C8-C22-alkenoylethyl, R2 is C1-C22-alkyl, Cl—C22-alkenyl or a group of the formula —A—(OA)n—OH, R3 and R4 are C1-C22-alkyl, C2-C21-alkenyl or a group of the formula —A—(OA)n—OH, A is —C2H4— and/or —C3H6— and n is a number from 0 to 20 and X is an anion.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: May 24, 2005
    Assignee: Clariant International Ltd.
    Inventors: Manlio Gallotti, George R. Nunez
  • Patent number: 6887839
    Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: May 3, 2005
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
  • Patent number: 6864220
    Abstract: A concentrate and a ready-to-use or diluted formulation for an aqueous vehicle cleaner can remove a wide range of different types of traffic film using either low pressure application, hand pressure application, water jet spray apparatus, clean-in-place systems or other manual or mechanical washing systems. The compositions may comprise, for example, one or more solutions that each or collectively contain or comprises: a) at least one anionic surfactant; b) at least one poly[oxyalkylene] ammonium cationic surfactant; and c) an alkaline agent. Optional additional ingredients may comprise at least one polycarboxylic acid chelating agent (preferably an aminocarboxylic acid chelating agent), at least one non-ionic or amphoteric surfactant, at least one hydrotrope, inorganic and/or organic acids and at least one silicate. The alkaline agent may provide a pH (when the finished product is diluted to 0.5 to 5% by weight in water) will be between about 9 to 13.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: March 8, 2005
    Assignee: Ecolab Inc.
    Inventors: Mark D. Levitt, Terry J. Klos, Michael E. Besse, Robert D. Hei, Jerry D. Hoyt, Cathleen O'Connor, Victor Fuk-Pong Man
  • Patent number: 6838426
    Abstract: The present invention is a sprayable gel cleaning composition and a method of making said sprayable gel cleaning composition. The gel stays on the stained surface until it is wiped off, unlike non-gelatinous compositions that have a very short surface contact time. The active agents of the sprayable gel cleaning composition are in contact with the stain for a longer period of time than other cleaners. The sprayable gel cleaning composition can be used to remove household and industrial spots and stains that are present on walls, cabinets, stove tops, doors, and trim. In addition, this invention can be used to clean concrete and brick, and remove caulk and paint from surfaces, as well as remove bug and tar stains present on automobiles, trucks, and other machinery and surfaces. The gelatinous composition may be water-based or solvent-based.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: January 4, 2005
    Assignee: Magic American Products, Inc.
    Inventor: Scott Zeilinger
  • Publication number: 20040248758
    Abstract: Compositions and method of making compositions comprising &agr;-sulfofatty acid ester and other detergent components. The &agr;-sulfofatty acid ester is formed into a first portion, and the other detergent components are formed into a second portion. The first portion is post-added to the second portion.
    Type: Application
    Filed: July 8, 2004
    Publication date: December 9, 2004
    Applicant: Huish Detergents, Inc.
    Inventors: Paul Danton Huish, Laurie A. Jensen, Pule B. Libe
  • Patent number: 6828290
    Abstract: The cleaning of hard surfaces is addressed, where no visible streaks or residues are left on the surfaces which have been cleaned. The invention encompasses several embodiments which combine a hydrophilic nonionic surfactant with a selected alcohol, in specific ratios, or a hydrophobic nonionic surfactant with a selected alcohol and a sulfated anionic surfactant, in specific ratios, or all these components together.
    Type: Grant
    Filed: November 3, 1998
    Date of Patent: December 7, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Marc François Theophile Evers, Roberta Margherita Romano
  • Patent number: 6824623
    Abstract: A terpene-free cleaning composition containing: (a) an oil-soluble anionic surfactant; (b) a water-soluble anionic surfactant; (c) a primary solvent consisting of a C1-4 alkyl ester; (d) a short-chain cosurfactant; and (e) water.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: November 30, 2004
    Assignee: Cognis Corporation
    Inventors: Stephen F. Gross, Martin J. Barabash, J. Frederick Hessel
  • Patent number: 6821937
    Abstract: Terpene-free hard surface cleaning compositions comprised of a C1-C4 alkyl ester of a C6-C22 saturated or unsaturated carboxylic acid and a surfactant having an HLB of from about 4 to about 10 are effective in cleaning hard surfaces. Terpene-free microemulsions having improved high and low temperature stability are also effective for cleaning hard surfaces and are comprised of an anionic surfactant; a primary solvent consisting of a C1-C4 alkyl ester of a C6-C22 saturated or unsaturated carboxylic acid and a short-chain cosurfactant. The disclosed cleaning compositions are especially effective in removing graffiti and paint from surfaces.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: November 23, 2004
    Assignee: Cognis Corporation
    Inventor: Stephen F. Gross
  • Patent number: 6815410
    Abstract: The present invention relates to a pouched cleaning composition wherein the pouch is constructed from a water-soluble film and contains a liquid composition comprising less than 5% by weight of the liquid composition, of water; an anionic surfactant; and at least 0.5% by weight of the liquid composition of a builder/chelant free of C8-22 alkyl or alkenyl chains characterized by a solubility in said liquid composition of less than 0.3% by weight. Such pouched cleaning compositions provide better cleaning performance and better pouch solubility while avoiding the formation of residues.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: November 9, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Jean-Pol Boutique, James Charles Theophile Roger Burckett-Saint-Laurent, Steven Jozef Louis Coosemans, Luca Goovaerts, Lorenzo Matteo Pierre Gualco, James Pyott Johnston
  • Patent number: 6815409
    Abstract: Gel detergent compositions which pile-up on a surface, upon dispensing, to minimize the spreading of the gel to a substantially larger area. The gels that can pile up are less messy to use and provide better stain removal, since more detergent is concentrated on the desired area of fabric (e.g., the spot). The composition comprises from about 10% to about 35% of a surfactant, from about 0.1 to about 5% of a non-neutralized fatty acid; from about 50 to about 85% of water; with the total of anionic surfactants selected from soap, linear alkyl benzene sulfonic acid, primary and secondary alkyl sulfates being more than 50% of total surfactant level.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: November 9, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Yun-Peng Zhu, Ronald Frederick Vogel, Agnes Boudou, Charles Ebert, Kwang H Lee
  • Publication number: 20040214740
    Abstract: New aqueous nacreous concentrated compositions, containing ethoxylated glycerides derived from carboxylic acids having 6 to 22 carbon atoms as emulsifying and/or dispersing agent are provided which show all the essential features required for this kind of composition, such as storage stability, excellent nacreous appearance, besides the possibility of acting as thickening agents and increasing the foaming power of the personal care cosmetic products.
    Type: Application
    Filed: January 30, 2004
    Publication date: October 28, 2004
    Inventors: Pilar Castan Barberan, Hiroshi Abe
  • Publication number: 20040204331
    Abstract: A light duty, liquid cleaning composition comprising: at least two different surfactants, lauryol ethylene diamine triacetate, a zinc inorganic salt, and water.
    Type: Application
    Filed: April 14, 2003
    Publication date: October 14, 2004
    Applicant: Colgate-Palmolive Company
    Inventors: Thomas Connors, Robert D' Ambrogio, Bruce Nascimbeni
  • Publication number: 20040198628
    Abstract: A detergent composition having cold water solubility and exhibiting high calcium tolerance can be produced from biodegradable branched ether derivative compositions derived from a branched ether primary alcohol represented by the formula: 1
    Type: Application
    Filed: April 2, 2004
    Publication date: October 7, 2004
    Inventors: Charles Lee Edwards, Kirk Herbert Raney, Paul Gregory Shpakoff
  • Patent number: 6797685
    Abstract: An aqueous liquid laundry detergent composition comprising a detergent surfactant (including anionic), an emulsifier with an HLB value below about 8.5; an oil; and an electrolyte in an amount to provide ionic strength indicator of from about 0.55 to about 6.7. The composition separates, upon standing for at most 24 hours at ambient temperature, into at least two layers, one of which is an emulsion with a continuous aqueous phase. The second layer is preferably a transparent composition.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: September 28, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Yun-Peng Zhu, Feng-Lung Gordon Hsu
  • Publication number: 20040186031
    Abstract: An antimicrobial formulation is provided which comprises an antimicrobial agent and a foam boosting surfactant where the viscosity of the formulation is less than about 50 cps at 24° C. The formulation has a low viscosity and has excellent foam properties when used in a foaming dispenser. The formulation is useful in providing antimicrobial effectiveness in surgical scrub applications.
    Type: Application
    Filed: January 27, 2004
    Publication date: September 23, 2004
    Inventors: Minh Q. Hoang, Jonathan K. Burkholz, Donald E. Hunt
  • Patent number: 6794353
    Abstract: The present invention relates to a cleaning wipe which is a water insoluble substrate impregnated with a cleaning composition containing a cellulosic polymer.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: September 21, 2004
    Assignee: Colgate-Palmolive Company
    Inventors: Barbara Thomas, Karen Wisniewski, Philip Gorlin, Josh Ghaim
  • Patent number: 6794348
    Abstract: A sher-thinnig lamellar gel detergent composition, employing non-neutralized fatty acid in a specific amount, depending on the total surfactant level. The weight % ratio of non-neutralized fatty acid to the total surfactant within a specific range, defined by the Gelling Index equation, results in gels with the desired properties. The inventive product offers an advantage of laundry pre-treater and a detergent in a single product.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: September 21, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Yun-Peng Zhu, Ronald Frederick Vogel, Agnes Boudou, Charles Ebert, Mohammad Hosseini-Nejad
  • Patent number: 6794351
    Abstract: Multipurpose cleaning articles are provided comprising a porous cleaning sheet containing an aqueous cleaning composition comprising (a) water as the major component; (b) 5% to 45% by weight water-immiscible solvent; (c) less than about 1.8% by weight emulsifier; and wherein the aqueous cleaning composition has a vertical wicking rate of about 1 cm/minute or more. The porous cleaning sheet can comprise any one of numerous materials, including hydrophobic materials, such as nonwoven webs, textile fabrics, foams and so forth. The cleaning articles are capable of removing water insoluble materials from various surfaces and including cleaning the skin and hands as well as hard surfaces.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: September 21, 2004
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Richard L. Shick, Ali Yahiaoui