Aqueous Coating Agent Patents (Class 510/442)
  • Patent number: 9290723
    Abstract: The present invention provides a coated lenticular or disc detergent particle having perpendicular dimensions x, y and z, the particle comprises: (i) from 40 to 90 wt % surfactant selected from: anionic surfactant; and, non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is selected: from anionic dyes; and, non-ionic dyes; and, (iv) from 0 to 3 wt % of perfume, wherein the inorganic salts and the dye are present on the detergent particle as a coating and the surfactant is present as a core.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: March 22, 2016
    Assignee: Conopco Inc.
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley, Jennifer Sian Roseblade
  • Patent number: 9290725
    Abstract: The present invention provides a coated lenticular or disc detergent particle having maximum perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm, and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from: anionic surfactant; and, non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and, (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is selected from: anionic dyes; and non-ionic dyes, wherein the inorganic salts are present on the detergent particle as a coating and the surfactant and the dye are present as a core.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: March 22, 2016
    Assignee: Conopco Inc.
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley, Jennifer Sian Roseblade
  • Patent number: 9290724
    Abstract: The present invention provides a coated lenticular or disc detergent particle having perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from anionic surfactant and non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is covalently bound to from 1 to 4 sulphonate groups, wherein the inorganic salts and the dye are present on the detergent particle as a coating and the surfactant is present as a core.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: March 22, 2016
    Assignee: Conopco, Inc.
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley
  • Patent number: 9279098
    Abstract: The present invention provides lenticular or disc detergent particles comprising (i) surfactant, (ii) inorganic salts, (iii) pigment, wherein the inorganic salts and the pigment are present on the detergent particle as a coating and the surfactant is present as a core. The particles show reduced staining.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: March 8, 2016
    Assignee: Conopco, Inc.
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley
  • Patent number: 9222061
    Abstract: The present invention provides lenticular or disc detergent particles comprising surfactant, inorganic salts and pigment, wherein the inorganic salts are present on the detergent particles as a coating and the surfactant and the pigment are present as a core. The particles show reduced staining.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: December 29, 2015
    Assignee: Conopco, Inc.
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley
  • Patent number: 8883702
    Abstract: A packaged particulate detergent composition, wherein the composition comprises greater than 40 wt % detergent surfactant, at least 70% by number of the particles comprising a core, comprising mainly surfactant, and around the core, a water soluble coating in an amount of from 10 to 45 wt % based on the coated particle, each coated particle having perpendicular dimensions x, y and z, wherein x is from 0.2 to 2 mm, y is from 2.5 to 8 mm, and z is from 2.5 to 8 mm, the packaged particles being substantially the same shape and size as one another.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: November 11, 2014
    Assignee: Conopco, Inc.
    Inventors: Judith Maria Bonsall, Stephen Thomas Keningley
  • Patent number: 8497234
    Abstract: A solid textile care composition having a water-soluble carrier, a water-soluble polymer, a textile care compound and a perfume. A solid textile care composition in which the water-soluble carrier is present in particulate form and has an envelope composed of the water-soluble polymer, the textile care compound and the perfume. Also textile care washing or cleaning compositions comprising the textile care composition.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: July 30, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Konstanze Mayer, Karl-Heinz Scheffler, Rene-Andres Artiga-Gonzalez, Hubert Harth, Mario Sturm, Tobias Segler, Daniel Tigges
  • Patent number: 8481476
    Abstract: Modified aminoalkyl- and polyoxyalkylene-functional organopolysiloxanes exhibit delayed antifoaming activity in washing operations, minimizing foaming of rinse water. When applied to a pulverulent carrier, they may also be used in powder detergent formulations.
    Type: Grant
    Filed: February 21, 2011
    Date of Patent: July 9, 2013
    Assignee: Wacker Chemie AG
    Inventor: Amit Kumar Paul
  • Patent number: 8183197
    Abstract: A particle for use in a detergent composition. The particle can have a coating layer having a binder selected from the group consisting of surfactant, surfactant precursor, film-forming polymer, film forming inorganic salt, and mixtures thereof. The particle can have a core being at least partially coated by the coating layer. The particle can have a hueing dye.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: May 22, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Manasvini Prabhat, Gillian Balfour Swan
  • Patent number: 8183410
    Abstract: The present invention concerns a process for the preparation of free flowing granules of low hygroscopicity of one or more methylglycine diacetic acid (MGDA) salts, of the formula wherein R?CH3 and M is hydrogen, alkali metal, alkaline earth metal, ammonium or substituted ammonium in the appropriate stoechiometric amounts, by a process comprising the steps of i) heating a concentrated slurry comprising methylglycine diacetic acid (MGDA) and/or any salts thereof, the slurry having a solids content in the range of 45% to 70% and suitably in the range from 50% to 70%, and a moisture content of 30% up to 55%, and suitably between 30% and 50%, to a temperature in the range of 50 to 120° C., preferably to about 80° C., and ii) spray granulating said slurry, using an air inlet temperature of 120° C. or less.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: May 22, 2012
    Assignee: Conopco, Inc.
    Inventors: Huig Euser, Jean-Paul Janssens, Robert Jan Moll, Jerome Georges M. Sonjon
  • Patent number: 8153578
    Abstract: In one embodiment, a method for recycling soap includes scraping the surface of a soap bar using a bladed implement; soaking the soap bar in a cleansing solution including dimethyl benzylammonium chlorides monohydrate; placing the soap bar on a rack in a Rational Clima Plus Combi unit; placing a pan under the rack; steaming the soap bar using the Rational Clima Plus Combi unit for five minutes at 212° F.; cooling the soap bar in a refrigerator unit at 38° F. for at least seven minutes; and packaging the soap for reuse.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: April 10, 2012
    Assignee: Clean The World Foundation, Inc.
    Inventors: Shawn Seipler, Paul Till, Steve Delisle, Edward C. Foster, Enrique Galarza, Steve Cooper, Noel Alamo
  • Patent number: 7897556
    Abstract: The invention relates to encapsulated bleaching agent particles. Said particles consist of a core that contains a bleaching-agent active ingredient and a coating of water-soluble material that at least partially surrounds said core, the core containing peroxocarboxylic acid and the coating material containing polyvinyl alcohol. The particles can be produced by introducing a particulate peroxocarboxylic acid into a fluidized bed, by spraying an aqueous solution containing polyvinyl alcohol onto said bed and by subsequent drying or spray drying.
    Type: Grant
    Filed: October 4, 2006
    Date of Patent: March 1, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventors: Georg Assmann, Horst-Dieter Speckmann, Frank Meier, Helga Werner
  • Patent number: 7897557
    Abstract: A shelf-stable liquid agent or detergent containing a bleaching agent in the form of a finely particulate bleaching agent encapsulated in a crosslinkable polymer matrix.
    Type: Grant
    Filed: November 19, 2008
    Date of Patent: March 1, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventors: Peter Schmiedel, Heinz-Juergen Voelkel, Heribert Kaiser, Wolfgang von Rybinski, Soeren Hoelsken, Volker Blank, Bernhard Guckenbiehl
  • Publication number: 20100093581
    Abstract: An environmentally friendly, human safe, aqueous-based cleaning composition which can be formulated for cleaning a variety of substrates comprises an alkyl polyglycoside nonionic surfactant, and an alkyl amphocarboxylate surfactant. The composition is free of hydrocarbon solvents, contains a minimal amount of organic polar solvents, and contains naturally derived adjuvants such as chelating agents, fragrances, and buffers.
    Type: Application
    Filed: October 15, 2008
    Publication date: April 15, 2010
    Applicant: RUBI ROSE, LLC.
    Inventors: Anthony E. Winston, Norman Usen
  • Patent number: 7632799
    Abstract: The present invention relates to a process for preparing coated granules comprising the steps of: (a) providing a core unit comprising an active component (b) contacting the core unit with a liquid dispersion comprising a solvent, a dissolved salt and solid dispersed particles wherein the solid particles constitute at least 10% w/w of the total dry matter of the dispersion (c) evaporating the solvent of the liquid dispersion to leave salt and solid particles coated onto the core unit.
    Type: Grant
    Filed: May 26, 2006
    Date of Patent: December 15, 2009
    Assignee: Novozymes A/S
    Inventors: Poul Bach, Ole Simonsen
  • Patent number: 7470654
    Abstract: The present invention relates to a detergent auxiliary composition comprising: (i) a liquid or liquefiable active component; and (ii) a water-insoluble solid support component and (iii) a water-soluble and/or water dispersible encapsulating material; and (iv) optionally one or more adjunct components, characterised in that the composition further comprises (v) a surface deposition enhancing cationic polymer or oligomer having cationic groups such that fewer than 50% are de-activated when a 1% by weight solution of the polymer or oligomer (prepared in deionised water and then adjusted to pH 7.0 with sodium carbonate or citric acid) is stored at 25° C.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: December 30, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Fabrizio Meli, Andre Chieffi, Rebecca Louise Selway, Stefan Frenzel
  • Patent number: 7419947
    Abstract: The present invention relates to a granule comprising a core and a coating, wherein the core comprises an active compound, and the coating comprises filaments prepared from atomizing a liquid coating composition having the property that liquid coating composition forms filaments upon atomization.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: September 2, 2008
    Assignee: Novozymes A/S
    Inventors: Poul Bach, Ole Simonsen
  • Patent number: 7276472
    Abstract: An oil containing starch granule is provided comprising: (a) a starch to form an effective matrix for said granule; (b) an oil, said oil being capable of providing a benefit-additive to a substrate upon contact therewith, said substrate being selected from the group consisting of fabrics, hard surfaces, hair and skin; and (c) an effective amount of an organic compound for inhibiting the migration of said oil to the surface of said starch granule, said compound being represented by the following structure: wherein R1 and R2 are each independently, H or are other structures as defined in the disclosure.
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: October 2, 2007
    Assignee: Colgate-Palmolive Company
    Inventors: Amjad Farooq, Sayed Ibrahim, Eugene E. Pashkovski, Natasha Dwight, Daniel W. Smith, Jeffrey Mastrull
  • Patent number: 7022660
    Abstract: A process for preparing a detergent particle having a coating layer of a water-soluble material is provided. The process comprises providing a particle core of a detergent active material and the particle core is then at least partially covered by a particle coating layer of a water soluble coating material including double salt combinations of alkali metal carbonates and sulfates that reduces the surface area of the particle.
    Type: Grant
    Filed: March 8, 2000
    Date of Patent: April 4, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Paul R Mort, III, Scott William Capeci
  • Patent number: 7012057
    Abstract: The invention concerns solid shaped detergent compositions comprising 0.5–95% by weight detergent active and 0–90% by weight of inorganic particulates and/or other conventional ingredients and wherein the external surface of said shaped detergent composition comprises at least one polymer film obtained by radiation curing or a radiation-curable resin composition.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: March 14, 2006
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Bir Kapoor, Samiran Mahapatra, Kamsu Venkatasatyanarayana Murthy
  • Patent number: 6979669
    Abstract: A granulate for particulate detergents or cleaning agents, the granulate containing a detergent or cleaning agent active ingredient and an outer encapsulation layer formed of polyvalent metal salts of an unbranched or branched, unsaturated or saturated, mono- or polyhydroxylated fatty acid having at least 12 carbon atoms or a mixture of the salts. Also, a process for making the granulate by applying to the granules an encapsulation material that comprises one or more polyvalent metal salt or salts, preferably in the form of an aqueous dispersion in a fluidized bed process.
    Type: Grant
    Filed: March 1, 2004
    Date of Patent: December 27, 2005
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wilfried Raehse, Dieter Baur, Werner Pichler
  • Patent number: 6900169
    Abstract: A process for preparing coated detergent granules in a fluidized bed. The fluidized bed is operated at a flux number of at least about 4 and at a Stokes Number of 10 to about 1000 using a coating solution or slurry having a viscosity from about 300 to about 100,000 centipoise, measured at 60° C. Upon drying, the resultant detergent particles have improved appearance and flow properties and may be packaged and sold as a detergent material or mixed with various other detergent ingredients to provide a fully formulated detergent composition.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: May 31, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Matthew Israel Wasserman, Mark William Ridyard, Scott William Capeci, Wayne Edward Beimesch, Paul R Mort, III
  • Patent number: 6858572
    Abstract: A process for preparing detergent particles having a coating layer of a water-soluble inorganic material is provided. The detergent particle comprises a particle core of a detergent active material. This particle core is then at least partially covered by a particle coating layer of a water soluble inorganic material. Particularly preferred are non-hydratable inorganic coating materials including double salt combinations of alkali metal carbonates and sulfates. The particle coating layer may also include detergent adjunct ingredients such as brighteners, chelants, nonionic surfactants, co-builders, etc. The process includes the steps of passing the particle core through a coating mixer such as a low speed mixer or fluid bed mixer and coating the particle core with a coating solution or slurry of the water soluble inorganic material.
    Type: Grant
    Filed: March 8, 2000
    Date of Patent: February 22, 2005
    Assignee: The Procter & Gamble Company
    Inventor: Paul R Mort, III
  • Patent number: 6849590
    Abstract: The present invention relates to a process for preparing particles for supporting a surfactant, comprising a step of giving a defect to a coating film containing a water-soluble component, wherein the coating film is formed on surfaces of raw material particles; and a process for preparing detergent particles comprising a step of mixing a surfactant composition and the particles for supporting a surfactant obtained by the above process, under conditions that the surfactant composition shows a liquid state. By using the process of the present invention, there can be obtained particles for supporting a surfactant, in which the supporting ability of the particles is improved, without lowering the detergency. In addition, by using the particles for supporting a surfactant, there can be obtained detergent particles having excellent detergency.
    Type: Grant
    Filed: December 28, 1999
    Date of Patent: February 1, 2005
    Assignee: KAO Corporation
    Inventors: Hiroki Yamaboshi, Shuji Takana, Teruo Kubota, Hitoshi Takaya, Hiroyuki Yamashita, Hideichi Nitta
  • Patent number: 6812200
    Abstract: A process for coating laundry detergent or cleaning product tablets that contain builder(s) and also, if desired, further laundry detergent and cleaning product ingredients, by transporting the tablets on a conveyor belt provided with a multiplicity of apertures and forcing coating material through the conveyor belt apertures from below with a force such that the coating material forced over the conveying plane forms a surge through which the tablets are transported.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: November 2, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Henriette Weber, Georg Assmann
  • Patent number: 6790821
    Abstract: A process for preparing coated detergent granules in a fluidized bed is provided. The fluidized bed is operated at a flux number of at least about 3.5 and/or a Stokes Number of greater than 1.0. Upon drying, the resultant detergent particles have improved appearance and flow properties and may be packaged and sold as a detergent material or mixed with various other detergent ingredients to provide a fully formulated detergent composition.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: September 14, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Matthew Israel Wasserman, Mark William Ridyard, Scott William Capeci, Wayne Edward Beimesch, Paul R Mort, III
  • Patent number: 6767880
    Abstract: A process for improving aesthetics of a liquid dishwashing detergent product is disclosed. The process includes the steps of providing a liquid dishwashing detergent composition and adding solid particles to the liquid dishwashing detergent composition. The particles are coated with a polymeric coating. The coating is prepared from materials which are insoluble in the liquid dishwashing detergent composition but soluble in dishwashing wash solution.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: July 27, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Peter Robert Foley, Brian Xiaoqing Song, Mary Ruth Leyendecker, Eugene Steven Sadlowski, Jeffrey Donald Painter, Joseph Herbert Thien
  • Patent number: 6767882
    Abstract: A process for preparing detergent particles having a coating layer of water-soluble inorganic material is provided. The detergent particle comprises a particle core of a detergent active material. This particle core is then at least partially covered by a particle coating layer of a water soluble inorganic material. Particularly preferred are non-hydrate inorganic coating materials including double salt combinations of alkali metal carbonates, and sulfates. The particle coating layer may also include detergent adjunct ingredients such as brighteners, chelants, nonionic surfactants, co-builders, etc. The process includes the steps of passing the particle core through a coating mixer such as a low speed mixer of fluid bed mixer and coating the particle core with a coating solution or slurry of the water soluble inorganic material.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: July 27, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Girish Jagannath, Manivannan Kandasamy, Ganapathy Venkata Ramanan, Eric San Jose Robles, Kenji Shindo, Tomotaka Inoue
  • Patent number: 6747000
    Abstract: A process for making beads of dry material for detergents, resulting in more robust beads, by contacting the beads with water to introduce very small levels of moisture to the beads. Colored beads, detergent formulations containing these beads and, in particular, softening through the wash compositions containing clay and the beads are disclosed.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: June 8, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Emma Jane Pearce, David Banks
  • Patent number: 6610752
    Abstract: Defoamer granules containing support materials and silicones for solid laundry detergent, dishwashing detergent and cleaning compositions, obtainable by applying silicones in the form of aqueous emulsions to an added intermediate product of support materials and simultaneously drying and granulating the products in a fluidized bed, with the proviso that at least 85% by weight of the particles have a mean diameter below 1.5 mm, are described.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: August 26, 2003
    Assignee: Cognis Deutschland GmbH
    Inventors: Karl Heinz Schmid, Michael Neuss, Detlef Stanislowski, Karin Koren, Andrea Borntraeger
  • Patent number: 6596683
    Abstract: Disclosed is a process for making a granular detergent composition comprising the steps of: (a) granulating a detersive material comprising a detergent surfactant and a builder; and (b) coating an inorganic aqueous solution on the granules substantially to coat the granules.
    Type: Grant
    Filed: June 15, 2001
    Date of Patent: July 22, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Fukuji Ebihara, Tatsuo Gobayashi, Takashi Kazuta
  • Patent number: 6589929
    Abstract: The present invention relates to enzyme-containing granules comprising (a) an enzyme and (b) a core which intrinsically is capable of absorbing at least 5% w/w (based on the weight of the core) of water and to processes for the production of such granules comprises (a) contacting absorbent cores, capable of absorbing at least 5% w/w (based on the weight of the core) of water, with a liquid medium, such as an aqueous medium, containing an enzyme in dissolved and/or dispersed form, the amount of the liquid medium employed being such that substantially no attendant agglomeration of the resulting product occurs; and (b) at least partially removing volatile components of the liquid medium from the resulting product.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: July 8, 2003
    Assignee: Novozymes A/S
    Inventors: Joao F. De Lima, Eder Manzini Bordin, Erik Kjaer Markussen, Kirsten Boegh Levring, Michael Bonde, Erik Marcussen, Grethe Saugmann
  • Patent number: 6528473
    Abstract: The invention concerns solid granulates of a system comprising at least a hydrophobic organic active substance (for example an active detergent substance) encapsulated in solid particles of an alkali-water soluble organic polymer derived by emulsion polymerisation, said particles being dispersed in and encapsulated by a matrix in a water soluble or water dispersible dry organic compound. The invention also concerns the use of said granulates in detergent compositions, in particular for cleaning hard surfaces or for washing clothes and the detergent compositions.
    Type: Grant
    Filed: September 20, 2000
    Date of Patent: March 4, 2003
    Assignee: Rhodia Chimie
    Inventors: Hélène Lannibois-Drean, Mikel Morvan, Daniel Joubert
  • Patent number: 6521583
    Abstract: Coated sodium percarbonate particles are provided which contain a sodium percarbonate core, and a coating layer substantially free from sulate, borate and magnesium compounds, having at least 30 and at most 75% w/w of an alkali metal carbonate and at least 25 and at most 70% w/w of an alkali metal silicate. The alkali metal carbonate and silicate being uniformly dispersed in the coating layer. Also provided is a process for the preparation of the coated sodium percarbonate particles and their use in detergent compositions.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: February 18, 2003
    Assignee: Solvay (Societe Anonyme)
    Inventors: Alun P. James, Graham R. Horne, Tom Candy, Richard Rösler, Manfred Mathes
  • Patent number: 6475972
    Abstract: Synthetic detergent formulations are made by spray drying an aqueous dispersion or emulsion of a synthetic detergent and a hydrophobic plasticizer and optionally a filler to produce a particulate product. In particular the synthetic detergent includes mild surfactants such as fatty isethionate or sulphosuccinate surfactants. By spray drying the emulsion or dispersion, a particularly uniform product is made which can readily be formed into synthetic detergent bars which may include soap to form combination bar products (combi-bars).
    Type: Grant
    Filed: February 17, 2000
    Date of Patent: November 5, 2002
    Assignee: Imperial Chemical INdustries PLC
    Inventor: Paul Clignet
  • Patent number: 6420333
    Abstract: A process for encapsulating a benefit agent and/or colorant for personal care or detergent compositions, the process comprising immersing an emulsion or a dispersion containing the benefit agent and/or colorant into an aqueous curing solution containing a high HLB surfactant and/or a super-wetting agent. The preferred process further includes increasing the density of the droplets, to allow for easier penetration into the curing solution.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: July 16, 2002
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Kristina Marie Neuser, MyongSuk Bae-Lee, Eric Charles Ehrnsperger, Tracy Bowens
  • Patent number: 6403549
    Abstract: The present invention relates to enzyme-containing granules comprising (a) an enzyme and (b) a core which intrinsically is capable of absorbing at least 5% w/w (based on the weight of the core) of water and to processes for the production of such granules comprises (a) contacting absorbent cores, capable of absorbing at least 5% w/w (based on the weight of the core) of water, with a liquid medium, such as an aqueous medium, containing an enzyme in dissolved and/or dispersed form, the amount of the liquid medium employed being such that substantially no attendant agglomeration of the resulting product occurs; and (b) at least partially removing volatile components of the liquid medium from the resulting product.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: June 11, 2002
    Assignee: Novozymes A/S
    Inventors: Joao F. De Lima, Eder Manzini Bordin, Erik Kjaer Markussen, Kirsten Boegh Levring, Michael Bonde, Erik Marcussen, Grethe Saugmann
  • Patent number: 6391844
    Abstract: A non-tower process for continuously preparing a granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the steps of: (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, while wetting the surfactant coated with the fine powder with finely atomized liquid, in a mixer, and (b) thoroughly mixing the agglomerates in a mixer. Step (b) can also be followed by further step (c), i.e., granulating the agglomerates from step (b) in one or more fluidizing apparatus, during which further coating can be used to prevent over-agglomeration.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: May 21, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Wayne Edward Beimesch, Manivannan Kandasamy
  • Patent number: 6379471
    Abstract: A cleaning tool for cleaning the walls of a swimming pool or other concrete structures. Two different sized aggregate or abrasives are combined with a binder to provide an improved cleaning device. The binder and the aggregates are matched so as to wear at substantially identical rates.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: April 30, 2002
    Inventor: Roy J. Walters
  • Patent number: 6352964
    Abstract: Cleansing bars are formed from compositions containing a liquid phase, particulate silica and a cleansing agent. The particulate silica is present in an amount to provide sufficient hardness to the composition to facilitate processing into a bar while maintaining good foaming despite a high liquid content.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: March 5, 2002
    Assignee: Imaginative Research Associates, Inc.
    Inventors: Jose E. Ramirez, Mohan Vishnupad
  • Patent number: 6335313
    Abstract: In the detergent granules including 10% by weight or more of a nonionic surfactant and 1% by weight or more of a crystalline alkali metal silicate having an average particle size of from 1 to 60 &mgr;m, the detergent granules characterized in that a proportion of the nonionic surfactant to the crystalline alkali metal silicate is in a weight ratio of from 20/1 to 1/20, and that the iron content calculated as Fe in the crystalline alkali metal silicate is 140 ppm or less. The granular detergent composition characterized in that the granular detergent composition includes the detergent granules described above.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: January 1, 2002
    Assignee: Kao Corporation
    Inventors: Katsuhiko Kasai, Shu Yamaguchi, Hitoshi Takaya, Taiji Nakamae, Itsuro Tsukahara
  • Patent number: 6239095
    Abstract: A process for the preparation of coated peroxygen compounds, in particular sodium percarbonate, by fluidized bed coating. By using a fluidized bed reactor with a radial inflow base, the passage openings of which allow the fluidized bed gas to emerge in the region of the opening at an angle of less than 35°, measured with respect to the horizontal, in the form of directed part streams, and in which are arranged spray nozzles, the pulse of which points in the same direction as the pulse of the fluidizing gas, it is possible to obtain products with an increased active oxygen stability. A circular reactor, the inflow base of which has lamellae overlapping like turbine blades and nozzles aligned in the direction of rotation of the fluidized bed is preferred.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: May 29, 2001
    Assignee: Degussa-Huls Aktiengesellschaft
    Inventors: Birgit Bertsch-Frank, Martin Bewersdorf, Lothar Kaiser, Rainer Kohlen, Ralph Overdick, Michael Scheibe
  • Patent number: 6211138
    Abstract: A non-tower process for continuously preparing granular detergent compositions having a density of at least of about 600 g/l comprises the steps of (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, while wetting the surfactant coated with the fine powder with finely atomized liquid, in a mixer, wherein first agglomerates are formed and (b) granulating the first agglomerates in one or more fluidizing apparatus.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: April 3, 2001
    Assignee: The Procter & Gamble Company
    Inventor: Wayne Edward Beimesch
  • Patent number: 6184193
    Abstract: A shrinkage prevention agent for water washing of clothing that would conventionally have been dry cleaned. The shrinkage prevention agent is compromised of a steam or vacuum dry-distilled liquid of two or more plants selected from sagebrush, beefsteak plant, tea, plantaginales, aloe, chrysanthemum, pine, cedar, cypress. The shrinkage prevention agent is used in a wet cleaning system that includes water washing.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: February 6, 2001
    Assignee: Nippon Mic, Co., LTD
    Inventor: Yukio Yamada
  • Patent number: 6180588
    Abstract: A cleaning tool for cleaning the walls of a swimming pool or other concrete structures. Two different sized aggregate or abrasives are combined with a binder to provide an improved cleaning device. The binder and the aggregates are matched so as to wear at substantially identical rates.
    Type: Grant
    Filed: January 13, 1999
    Date of Patent: January 30, 2001
    Assignee: Tracey Dalton
    Inventor: Roy J. Walters
  • Patent number: 6172034
    Abstract: A non-tower process for continuously preparing granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the steps of (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, in a mixer, wherein first agglomerates are formed, (b) thoroughly mixing the first agglomerates in a mixer, wherein second agglomerates are formed, and (c) spraying finely atomized liquid onto the second agglomerates in a mixer.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: January 9, 2001
    Assignee: The Procter & Gamble
    Inventors: Angela Gloria Del Greco, Manivannan Kandasamy
  • Patent number: 6156719
    Abstract: A non-tower process for continuously preparing granular detergent composition having a low density, preferably about 300 g/l to about 600 g/l is provided. The process comprises the steps of (a) (i) dispersing an aqueous or non-aqueous surfactant, and (ii) coating the surfactant with fine powders having a diameter from 0.1 to 500 microns, in the mixer which is operated under certain conditions to obtain irregular shape granules and excessive fine powders and, (b) spraying on finely atomized liquid to the irregular shape granules and excessive fine powders from step (a), in a mixer which is operated under certain conditions to bind the excessive fine powders onto the irregular-shaped granules.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: December 5, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Angela Gloria Del Greco, Manivanan Kandasamy
  • Patent number: 6150323
    Abstract: A non-tower process for continuously preparing granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the steps of (a) dispersing a surfactant, and coating the surfactant with fine powder in a mixer, wherein first agglomerates are formed, (b) thoroughly mixing the first agglomerates in a mixer, wherein second agglomerates are formed, and (c) granulating the second agglomerates in one or more fluidizing apparatus. The process can also comprise further step (b'), i.e., spraying finely atomized liquid onto the second agglomerates in a mixer, between step (b) and step (c).
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: November 21, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Angela Gloria Del Greco, Wayne Edward Beimesch, Manivannan Kandasamy
  • Patent number: 6143711
    Abstract: A non-tower process for continuously preparing granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the steps of (a) dispersing a surfactant and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns in a mixer fitted with choppers, and (b) granulating the agglomerates in one or more fluidizing apparatus, wherein finely atomized liquid is sprayed onto the first agglomerates in a mixer between step (a) and (b).
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: November 7, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Angela Gloria Del Greco, Wayne Edward Beimesch
  • Patent number: 6136772
    Abstract: The present invention relates to enzyme-containing granules comprising (a) an enzyme and (b) a core which intrinsically is capable of absorbing at least 5% w/w (based on the weight of the core) of water and to processes for the production of such granules comprises (a) contacting absorbent cores, capable of absorbing at least 5% w/w (based on the weight of the core) of water, with a liquid medium, such as an aqueous medium, containing an enzyme in dissolved and/or dispersed form, the amount of the liquid medium employed being such that substantially no attendant agglomeration of the resulting product occurs; and (b) at least partially removing volatile components of the liquid medium from the resulting product.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: October 24, 2000
    Assignees: Novo Nordisk A/S, Novo Nordisk Bio Industrial
    Inventors: Joao F. De Lima, Eder Manzini Bordin, Erik Kjaer Markussen, Kirsten Boegh Levring, Michael Bonde, Erik Marcussen, Grethe Saugmann