Carboxylic Acid Anhydride, Free Carboxyl Group, Or Salt Thereof In The Polymer Patents (Class 510/476)
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Patent number: 11028350Abstract: Process for making a powder or granule containing at least one chelating agent selected from alkali metal salts of methyl glycine diacetic acid (MGDA) and glutamic acid diacetate (GLDA) and iminodisuccinic acid (IDS), said process comprising the steps of (a) introducing an aqueous solution or aqueous slurry of the respective chelating agent (A) into a spray-dryer or spray-granulator, and removing most of said water by spray-drying or spray granulation using a gas with an inlet temperature of 125 to 250° C.Type: GrantFiled: June 1, 2017Date of Patent: June 8, 2021Assignee: BASF SEInventors: Michael Klemens Mueller, Armin Stamm, Frank Jaekel, Carsten Sueling
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Patent number: 10597611Abstract: A liquid detergent comprising: (a) from 30 to 80 wt % water; (b) from 5 to 50 wt % surfactants; and (c) from 0.5 to 10 wt % of an acrylic polymer comprising from 20 to 50 wt % polymerized units of (meth)acrylic acid and from 50 to 80 wt % polymerized units of a monomer of structure H2C?C(R)CO2(CH2CH2O)n(CH(R?)CH2O)mR?; wherein R is H or CH3, R? is C1-C2 alkyl; R? is C8-C22 alkyl or C8-C16 alkylphenyl; n is an average number from 6-30 and m is an average number from 0-10, provided that n?m and m+n is 6-30.Type: GrantFiled: July 7, 2017Date of Patent: March 24, 2020Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Anne Oberlin, Asghar A. Peera, Scott Backer, Matthew J. Jansma
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Patent number: 10351806Abstract: A liquid detergent comprising: (a) from 0 to 30 wt % water; (b) from 60 to 90 wt % surfactants; and (c) from 0.5 to 10 wt % of an acrylic polymer comprising from 20 to 50 wt % polymerized units of (meth)acrylic acid and from 50 to 80 wt % polymerized units of a monomer of structure H2C?C(R)CO2(CH2CH2O)n(CH(R?)CH2O)mR?; wherein R is H or CH3, R? is C1-C2 alkyl; R? is C8-C22 alkyl or C8-C16 alkylphenyl; n is an average number from 6-30 and m is an average number from 0-10, provided that n?m and m+n is 6-30.Type: GrantFiled: February 3, 2017Date of Patent: July 16, 2019Assignee: Dow Global Technologies LLCInventor: Anne Oberlin
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Patent number: 10072373Abstract: A clothes dryer for drying fabric items in accordance with a treating cycle of operation, includes a treating chamber receiving fabric items for treatment and a controller having a memory in which is stored a set of executable instructions comprising at least one user-selectable cycle of operation, the controller may receive an indication of a dye transfer event and implement a cycle of operation based thereon.Type: GrantFiled: January 22, 2014Date of Patent: September 11, 2018Assignee: Whirlpool CorporationInventors: Gregory R. Fulmer, Kaustav Ghosh, William L. Murch, Mir A. Quddus, Robert J. Pinkowski
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Patent number: 9803156Abstract: A water-based cutting fluid that comprises water and a water-soluble polyalkylene glycol (PAG) having cloud point from 30° C. to 80° C. The cutting fluid is water-based, i.e., it comprises at least 50 percent by weight (wt %) water. The cutting fluids are well suited for use with diamond wiresaws for the cutting of silicon ingots. The fluids exhibit one or more of low hydrogen generation, no wafer cleaning issues, good lubricity, good cooling efficiency, good swarf suspension and dispersion, low foaming, are generally non-sensitive to metal ions, and are nonflammable.Type: GrantFiled: December 6, 2012Date of Patent: October 31, 2017Assignee: Dow Global Technologies LLCInventors: Yi Ping Zhu, Bing Liang, Andong Liu, Wanglin Yu
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Patent number: 9657904Abstract: Technologies are described herein for photobleaching a display. A display may be photobleached by exposing the display to light emitted by an external lamp and/or may be photobleached using one or more display lights of the electronic device during a burn-in period. In some examples, the light emitted by the lamp is filtered to remove wavelengths below a certain wavelength. The light that is received by the display from the lamp may include wavelengths between about 310 nm and 700 nm. These wavelengths correspond to visible light and near-visible light. The display may be exposed to the light for some duration or until some dose of light is received by the display. In other configurations, a burn-in period is performed for about eighteen hours.Type: GrantFiled: February 23, 2015Date of Patent: May 23, 2017Assignee: Amazon Technologies, Inc.Inventors: Guneet Sethi, Nhi A. Duong, Tin Quang Pham, Heather Kulani Coursey, Weihsin Hou, Robert L. D. Zenner, Saket Patil
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Patent number: 9040473Abstract: A detergent for cleaning media is provided. The detergent comprises deionized water, between about 1% and about 5% by weight of a nonionic surfactant having an hydrophile/lipophile balance (HLB) value between about 10 and about 20, and an ethoxylation level between about 5 and about 20, between about 1% and about 5% by weight of a dispersing agent, between about 3% and about 10% by weight of a chelating agent comprising phosphonic acid, and between about 2% and about 6% by weight of an inorganic salt.Type: GrantFiled: July 21, 2010Date of Patent: May 26, 2015Assignee: WD Media, LLCInventors: EE Boon Quah, Kwai Cheang Wong, Ming Yean Liew, Chung Lieh Chua, Yasuhiro Suzuki
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Patent number: 9029314Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.Type: GrantFiled: February 18, 2014Date of Patent: May 12, 2015Assignee: Ecolab USA Inc.Inventors: Erik C. Olson, Devon Beau Hammel
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Patent number: 9023779Abstract: A dishwashing detergent composition is provided for consumer use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorus containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a phosphinosuccinic acid oligomer or mixture thereof is used as a corrosion inhibitor and can be included for aluminum protection in a number of different detergent compositions.Type: GrantFiled: March 15, 2013Date of Patent: May 5, 2015Assignee: Ecolab USA Inc.Inventor: Altony J. Miralles
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Patent number: 8969284Abstract: The present invention relates to a laundry detergent or a cleaning composition, preferably a granular detergent product, comprising a carboxyl-group containing polymer, which is useful in improving whiteness and/or anti-soil redeposition. Processes for making and methods of using the laundry detergent or cleaning composition are also encompassed by the present invention.Type: GrantFiled: August 15, 2013Date of Patent: March 3, 2015Assignee: The Procter & Gamble CompanyInventors: Xiaoli Wang, Brian Joseph Loughnane, Xiaoyan Liu, Jeffrey Scott Dupont, Atsuro Yoneda, Daisuke Michitaka
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Patent number: 8957010Abstract: The present invention relates to a cleaning composition, preferably a granular detergent product, comprising a carboxyl-group containing polymer, which is useful in improving whiteness and/or anti-soil redeposition. Processes for making and methods of using the cleaning composition are also encompassed by the present invention.Type: GrantFiled: August 15, 2013Date of Patent: February 17, 2015Assignee: The Procter & Gamble CompanyInventors: Xiaoli Wang, Brian Joseph Loughnane, Atsuro Yoneda, Akiko Hemmi
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Patent number: 8951956Abstract: A solidification matrix includes sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer or salt or derivative thereof, and additional functional ingredients. The sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer, and additional functional ingredients interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition. Methods of making solid detergent compositions are disclosed.Type: GrantFiled: January 4, 2013Date of Patent: February 10, 2015Assignee: Ecolab USA, Inc.Inventors: Caleb Jones, Katherine Molinaro, Darryl Bowling, Karen Rigley, Brenda L. Tjelta, Lisa M. Sanders, Michael E. Besse
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Patent number: 8940680Abstract: Composition in the form of a gel containing at least 35% by weight of water, at least one foaming surfactant chosen from nonionic or amphoteric surfactants, and at least one superabsorbent polymer. The superabsorbent polymer helps to thicken the composition without affecting its cosmetic properties.Type: GrantFiled: February 12, 2010Date of Patent: January 27, 2015Assignee: L'OrealInventors: Anne-Laure Bernard, Odile Aubrun-Sonneville, Laurence Leroy
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Patent number: 8901066Abstract: Branched polyesters with sulfonate groups can be obtained by reacting components A, B, optionally C, and optionally D to yield branched polyesters, then reacting these branched polyesters with hydrogen sulfite. Component A is at least one ?,?-olefinically unsaturated dicarboxylic acid, component B is at least one di- or higher-functional alcohol, optional component C is at least one di- or higher-functional carboxylic acid or hydroxycarboxylic acid without an ?,?-olefinically unsaturated bond, and optional component D is at least one compound of formula CH3(—O—CH2—CH2)n—OH. In reacting the branched polyesters with hydrogen sulfite, a molar amount of hydrogen sulfite is at most 95 mol %, based on an amount of ?,?-olefinically unsaturated dicarboxylic acid.Type: GrantFiled: June 13, 2012Date of Patent: December 2, 2014Assignee: BASF SEInventors: Monika Haberecht, Juergen Detering, Bernd Bruchmann, Helmut Witteler, Heike Weber, Karl Kolter
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Patent number: 8895493Abstract: The need for a stable, compact composition providing improved fabric care benefit, that is also convenient to use, can be met by incorporating a cationic cellulose polymer into a non-aqueous composition, using a non-aqueous dispersant. Such compositions have good physical stability, with little or no clumping of the cationic polymer in particulate form.Type: GrantFiled: June 14, 2011Date of Patent: November 25, 2014Assignee: The Procter & Gamble CompanyInventors: Regine Labeque, Rajae Boulaich, Marc Jennewein
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Patent number: 8889613Abstract: A detergent comprises an alkalinity source, a homopolymer of acrylic acid or a salt thereof, a homopolymer of methacrylic acid or a salt thereof, and a homopolymer of maleic acid or a salt thereof. Suitable weight ratios include a weight ratio of the homopolymer of methacrylic acid or a salt thereof to the homopolymer of acrylic acid or a salt thereof between approximately 1:3 and approximately 3:1, a weight ratio of the homopolymer of acrylic acid or a salt thereof to the homopolymer of maleic acid or a salt thereof between approximately 3:1 and approximately 1:6, and a weight ratio of the homopolymer of methacrylic acid or a salt thereof to the homopolymer of maleic acid or a salt thereof between approximately 2:1 and approximately 1:4.Type: GrantFiled: August 17, 2011Date of Patent: November 18, 2014Assignee: Ecolab USA Inc.Inventors: Carter Silvernail, Altony Miralles
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Publication number: 20140336101Abstract: Polymer obtainable by radical emulsion polymerization of (A) at least one acidic vinyl monomer or salt thereof; (B) at least one nonionic vinyl monomer, particularly preferably a hydrophobic nonionic vinyl monomer; (C) at least one monomer containing an unsaturated end group and a polyoxyalkylene part; (D) at least one crosslinking monomer; and (E) optionally, a protective colloid, characterized in that the polymerization is controlled such that (F) the gel effect occurs, at least at times, achieved by adding monomers of type (A), (B), and (C) (dosing time) during 120 minutes; and such that (G) the crosslinking monomer (D) is added, at the very earliest, 10 minutes after the first addition of the monomers (A), (B), and (C).Type: ApplicationFiled: June 15, 2012Publication date: November 13, 2014Applicant: BEIERSDORF AGInventor: Sascha Mertens
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Patent number: 8883705Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.Type: GrantFiled: October 30, 2012Date of Patent: November 11, 2014Assignee: The Clorox CompanyInventors: David R. Scheuing, Travers Anderson, William L. Smith, Erika Szekeres, Rui Zhang
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Patent number: 8871703Abstract: The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerization of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-liType: GrantFiled: November 24, 2010Date of Patent: October 28, 2014Assignee: Clariant Finance (BVI) LimitedInventors: Roman Morschhaeuser, Barbara Duecker, Frank-Peter Lang, Georg Borchers, Peter Naumann
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Patent number: 8871702Abstract: The invention relates to polyesters, obtainable by means of polymerization of the components including (a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and N is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), in which m is an integer from 1 to 10 and X is hydrogen or an alkali metal ion, and g); optionally one or more crosslinking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provideType: GrantFiled: November 24, 2010Date of Patent: October 28, 2014Assignee: Clariant Finance (BVI) LimitedInventors: Roman Morschhaeuser, Barbara Duecker, Hans Juergen Scholz
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Patent number: 8846599Abstract: Branched polyesters with sulfonate groups obtainable by the reaction of the components A, B, optionally C and optionally D to give branched polyesters, where the component A is selected from the group of ?,?-olefinically unsaturated dicarboxylic acids, and the component B is selected from the group of tri- or higher-functional alcohols, the optional component C is selected from the group of difunctional alcohols or of difunctional carboxylic acids without ?,?-olefinically unsaturated bonds, the optional component D is selected from fatty acids or fatty alcohols, and the subsequent reaction of the resulting branched polyesters with hydrogen sulfite, where the molar amount of hydrogen sulfite is at most 95 mol %, based on the amount of ?,?-olefinically unsaturated dicarboxylic acid.Type: GrantFiled: June 13, 2012Date of Patent: September 30, 2014Assignee: BASF SEInventors: Monika Haberecht, Frank Rittig, Bernd Bruchmann, Claudia Esper, Roland Ettl, Karl Kolter
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Publication number: 20140271521Abstract: A process for forming a personal care article, the process including (a) producing an extrudate from a twin screw extruder, and (b) forming the extrudate into the personal care article. The personal care article includes (i) from about 10% to about 60% of one or more anionic surfactants, wherein the one or more anionic surfactants have a Krafft point of less than 30° C.; (ii) from about 10% to about 50% of one or more water soluble polymers; (iii) from about 1% to about 30% of one or more plasticizers; and (iv) from about 10% to about 50% water.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: The Procter & Gamble CompanyInventors: Robert Wayne GLENN, JR., Todd Ryan THOMPSON, Ungyeong JUNG, Changwei ZHU, Alireza TABATABAEI-NAEINI
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Patent number: 8802617Abstract: The present invention includes a cleaning composition that includes at least one alkalinity source, at least one surfactant, water and at least one polyglycerol graft polymer. The polyglycerol graft polymer includes a polyglycerol and a residue of at least one carboxylic acid or carboxylate containing compound in an amount less than or equal to about 40% by weight of the polyglycerol graft polymer.Type: GrantFiled: November 8, 2012Date of Patent: August 12, 2014Assignee: Ecolab USA Inc.Inventors: Carter Silvernail, John Nording
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Patent number: 8802616Abstract: A detergent composition having at least two components. The first component is from 8 to 50 wt % surfactants. The second component is from 0.05 to 4 wt % of a polymer which has polymerized residues of 40 to 80 wt % C1-C4 alkyl acrylates, 20 to 52 wt % C3-C6 carboxylic acid monomers, and 0 to 10 wt % of monomers having an alkyl group having at least ten carbon atoms.Type: GrantFiled: July 8, 2011Date of Patent: August 12, 2014Assignee: Rohm and Haas CompanyInventors: Joseph Manna, Roy Roberts, Jan Edward Shulman
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Publication number: 20140178324Abstract: Disclosed is a pH responsive polymer made with mono-[2-(methacryloyloxy)ethyl]phthalate and/or mono-[2-(methacryloyloxy)ethyl hexahydro]phthalate. Also disclosed is an aqueous coating composition including at least one latex polymer derived from at least one monomer copolymerized or blended with alkali swellable acrylate copolymer. Also provided is an aqueous coating composition including at least one latex polymer derived from at least one monomer blended with alkali swellable acrylate copolymer, at least one pigment, and water. Also provided is a method of preparing an aqueous coating composition such as a latex paint including the above components. Also provided are methods of preparing mono-[2-(methacryloyloxy)ethyl]phthalate. Also provided are conpositions and methods using the polymer in hydraulic fracturing, personal care and or home and industrial cleaners.Type: ApplicationFiled: December 18, 2013Publication date: June 26, 2014Applicant: Rhodia OperationsInventors: Nemesio Martinez-Castro, Jennie McGuire, Herve Adam, James Woods
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Patent number: 8740993Abstract: A laundry detergent composition includes an alkalinity source, at least one nonionic surfactant and a polymer comprising maleic acid, vinyl acetate and alkyl acrylate monomers. The alkalinity source is present in an amount between about 1% and about 75% by weight of the laundry detergent composition and includes at least one member selected from alkali metal hydroxides, carbonates, and bicarbonates. The polymer comprising maleic acid, vinyl acetate and alkyl acrylate monomers is present in an amount equal to or greater than about 0.5% by weight of the laundry detergent composition.Type: GrantFiled: March 23, 2012Date of Patent: June 3, 2014Assignee: Ecolab USA Inc.Inventors: Stephen Christensen, Lauren M. Hunker, Carter Silvernail, Brandon G. Beyer, Kerrie E. Walters
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Patent number: 8735336Abstract: Methods for removing an organic material from a portion of oilfield equipment are described. The methods include forming a composition that includes a hybrid polymer and introducing the composition to the portion of the oilfield equipment from which the organic material is to be removed. The hybrid polymer includes a synthetic component formed from at least one or more olefinically unsaturated carboxylic acid monomers or salts thereof, and a natural component formed from a hydroxyl-containing natural moiety.Type: GrantFiled: February 18, 2013Date of Patent: May 27, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Jayachandran Perumalsamy, Colby Tate
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Patent number: 8729006Abstract: The present invention includes methods and compositions that employ sodium carboxymethyl cellulose as a scale inhibitor. According to the invention, scale inhibiting compositions are disclosed which include, sodium carboxymethyl cellulose and a polymer such as polymaleic acid, polyacrylic acid or mixtures, copolymers or terpolymers of the same and optionally may also include a phosphonate. The scale control composition may be incorporated into a detergent/cleaning composition.Type: GrantFiled: June 28, 2011Date of Patent: May 20, 2014Assignee: Ecolab USA Inc.Inventors: Altony Miralles, Xin Sun, Michelle Fung, John Krueger
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Publication number: 20140128310Abstract: The present invention includes a cleaning composition that includes at least one alkalinity source, at least one surfactant, water and at least one polyglycerol graft polymer. The polyglycerol graft polymer includes a polyglycerol and a residue of at least one carboxylic acid or carboxylate containing compound in an amount less than or equal to about 40% by weight of the polyglycerol graft polymer.Type: ApplicationFiled: November 8, 2012Publication date: May 8, 2014Applicant: ECOLAB USA INC.Inventors: Carter Silvernail, John Nordling
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Publication number: 20140116472Abstract: Phosphorus-free detergent compositions are provided. Detergent compositions including an aminocarboxylate, water conditioning agent, source of alkalinity and water beneficially do not require the use of additional surfactants and/or polymers to provide suitable detergency and prevent scale build-up on treated surfaces. The detergent compositions are used with a sanitizer to employ the phosphorus-free detergent compositions for use as low temperature ware wash detergents that beneficially reduce scale build-up. Methods of employing the phosphorus-free detergent compositions are also provided.Type: ApplicationFiled: October 26, 2012Publication date: May 1, 2014Inventors: Erin Jane Dahlquist, Carter Martin Silvernail, Steven E. Lentsch, Terrence P. Everson
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Publication number: 20140107011Abstract: The invention provides environmentally safe compositions and methods for cleaning surfaces to remove soap scum, iron oxide, calcium carbonate or calcium stearate deposits, or a combination thereof, from surfaces. The compositions of the invention comprise calcium chelating agents, one or more nonionic surfactants, one or more chelating agents, one or more anionic polymeric surfactants, an acid, and water, wherein the composition is alkaline. The compositions generally have a pH between 7.0 and 10, are biodegradable, non-toxic, free of VOCs, and are made of renewable, sustainable materials.Type: ApplicationFiled: October 15, 2013Publication date: April 17, 2014Applicant: Commercial Pool, Inc.Inventors: Tyler BANASZAK, Dakarai Kameron BROWN
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Patent number: 8691018Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.Type: GrantFiled: August 27, 2010Date of Patent: April 8, 2014Assignee: Ecolab USA Inc.Inventors: Erik Christian Olson, Devon Beau Hammel
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Patent number: 8673835Abstract: The present invention provides compositions which not only effectively kill a broad spectrum of microorganisms present on surfaces on contact but continue to kill microorganisms for a period of time thereafter.Type: GrantFiled: December 10, 2012Date of Patent: March 18, 2014Assignee: Reckitt Benckiser LLCInventors: Timothy Michael Cusack, Karen Ann McCue, Herbert W Ulmer
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Publication number: 20140017184Abstract: Personal care compositions comprising, as thickeners and suspending agents, crosslinked alkali swellable polyacrylates containing one or more acetoacetyl or cyanoacetyl groups.Type: ApplicationFiled: March 16, 2012Publication date: January 16, 2014Applicant: Lamberti SPAInventors: Chiara Fumagalli, Eva Baldaro, Giovanni Floridi, Giuseppe Li Bassi
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Patent number: 8623151Abstract: A cleaning composition includes an alkali metal silicate, a polymer including maleic acid, vinyl acetate and alkyl acrylate monomers, and optionally water. The cleaning composition can include approximately 10% and approximately 90% by weight of at least one alkali metal silicate, greater than or equal to approximately 0.1% by weight of the polymer containing maleic acid, vinyl acetate and alkyl acrylate monomers, and approximately 0% to approximately 80% by weight water.Type: GrantFiled: March 23, 2012Date of Patent: January 7, 2014Assignee: Ecolab USA Inc.Inventors: Erik C. Olson, Carter Silvernail
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Publication number: 20130331308Abstract: Self-adhesive detergent compositions are described including a pH-sensitive color-changing system. The color-changing system is useful with certain acidic compositions and certain alkaline compositions. The compositions have a given color upon application to a hard surface, e.g., a toilet bowl. In one embodiment, when the self-adhesive composition is exposed to a water-based rinse, such as on flushing a toilet, the color-changing system provides the released cleaning portion of the composition, and thereby the water, with a color different from the color of the composition to indicate cleaning is occurring. In another embodiment, following exposure to a plurality of rinses, the color-changing system changes the color of the composition when the composition is near depletion to provide an “end-of-use” cue.Type: ApplicationFiled: June 8, 2012Publication date: December 12, 2013Inventors: Wayne M. REES, Thomas A. STRASH
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Publication number: 20130274150Abstract: The present invention generally relates to controlling the viscosity of water-based mud systems. More particularly, the present invention relates to methods and compositions for thinning and deflocculating aqueous based fluids used in well drilling and other well operations in subterranean formations, especially subterranean formations containing oil and/or gas. The invention also relates to a drilling fluid thinner and/or dispersant having improved temperature stability, dispersing properties and “solids contamination” tolerance.Type: ApplicationFiled: December 16, 2011Publication date: October 17, 2013Applicant: Akzo Nobel Chemicals International B.V.Inventors: Stuart Holt, Klin Aloysius Rodrigues, Jannifer Sanders
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Publication number: 20130247936Abstract: The present invention is directed, in certain embodiments, to compositions useful for the removal of grease, lime scale, soap scum, feces, rust or other soils from surfaces such as those found in bathrooms, toilets and kitchens. Methods of removing soils and preventing soil adhesion are also contemplated.Type: ApplicationFiled: February 27, 2013Publication date: September 26, 2013Applicant: Colgate-Palmolive CompanyInventors: Michele Davister, Nathalie Dastbaz, Alain Jacques, Germaine Zocchi
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Publication number: 20130252870Abstract: The present invention is related to a cleaning composition including at least one alkalinity source and a biodegradable terpolymer including maleic acid, vinyl acetate and alkyl acrylate segments or monomers for controlling scale. The diluted use solution has a pH between about 7 and about 11.5.Type: ApplicationFiled: March 23, 2012Publication date: September 26, 2013Applicant: ECOLAB USA INC.Inventor: Carter Silvernail
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Patent number: 8530403Abstract: A solidification matrix includes a maleic-containing terpolymer, sodium carbonate, and water. The maleic-containing terpolymer, sodium carbonate, and water interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition.Type: GrantFiled: November 20, 2009Date of Patent: September 10, 2013Assignee: Ecolab USA Inc.Inventors: Brenda L. Tjelta, Lisa M. Sanders
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Patent number: 8524649Abstract: An aqueous dispersion of a copolymer with copolymerized units a) of at least one ethylenically unsaturated carboxylic acid, b) of at least one nonionic ethylenically unsaturated surfactant monomer, c) of at least one C1-C2-alkyl methacrylate, d) of at least one C2-C4-alkyl acrylate, where the alkyl chain length averaged over the number of alkyl groups of the alkyl acrylate is 2.1 to 4.0, is described. Following neutralization with alkali, the dispersion serves as associative thickener, in particular for liquid detergent and cleaner formulations. The thickeners are characterized by high transparency and high thickening effect coupled with high shear dilution.Type: GrantFiled: August 1, 2008Date of Patent: September 3, 2013Assignee: BASF SEInventors: Reinhold J Leyrer, Kati Schmidt
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Publication number: 20130195775Abstract: Ionic and ionogenic comb copolymers are disclosed along with personal care products that employ them as a modifier that results in increased sensory attributes and increased effectiveness in the deposition of actives and can also act as a thickening agent. The copolymer includes one or more repeating units derived from olefinically unsaturated anionic or anionogenic or zwitterionic comonomers, and one or more repeating units having the formula in which Y is a moiety forming part of a copolymer backbone, Z is a moiety that exhibits association with other Z moieties or with other moieties within the ultimate formulation in which the copolymer will be employed, and b is a bond or moiety that links the Z moiety to the Y moiety. In certain embodiments, the copolymer also includes repeating units derived from acrylamide monomers, olefinically unsaturated hydrophilic monomers or other olefinically unsaturated monomers.Type: ApplicationFiled: August 3, 2012Publication date: August 1, 2013Applicants: LANDEC CORPORATION, AIR PRODUCTS AND CHEMICALS, INC.Inventors: Richard Joseph Goddard, Mussarat Noor, Julian Everett Schafer, Steven Paul Bitler, David Dakin Taft, Shiying Zheng
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Patent number: 8496757Abstract: A cleaning solution and method for removing submicron particles from the surface and/or the bevel of an electronic substrate such as a semiconductor wafer. The cleaning solution comprises a polycarboxylate polymer or an ethoxylated polyamine. The method comprises the step of contacting a surface of the substrate with a cleaning solution comprised of a polycarboxylate polymer or an ethoxylated polyamine. Additional optional steps in the method include applying acoustic energy to the cleaning solution and/or rinsing the surface with a rinsing solution with or without the application of acoustic energy to the rinsing solution.Type: GrantFiled: July 22, 2012Date of Patent: July 30, 2013Assignee: Fontana TechnologyInventor: Mark Jonathan Beck
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Publication number: 20130189198Abstract: Disclosed are surfactant compositions containing at least one crosslinked acrylic copolymer. The crosslinked acrylic copolymer is polymerized in the presence of at least two different classes of crosslinking monomers. The crosslinked acrylic copolymers provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions.Type: ApplicationFiled: October 5, 2011Publication date: July 25, 2013Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventor: Krishnan Tamareselvy
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Patent number: 8486884Abstract: The present invention relates to a method for producing granular or pulverulent detergent compositions, comprising the production of a detergent base powder by drying an aqueous detergent slurry, which comprises adding to the slurry a copolymer which is obtained by free-radical copolymerization of (A) from 20 to 80% by weight of at least one monomer selected from the group consisting of monoethylenically unsaturated monocarboxylic acids, dicarboxylic acids and dicarboxylic anhydrides, and (B) from 20 to 80% by weight of at least one monomer selected from the group consisting of aliphatic or aromatic monoolefins.Type: GrantFiled: September 29, 2006Date of Patent: July 16, 2013Assignee: BASF AktiengesellschaftInventors: Tanja Seebeck, Helmut Guembel
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Patent number: 8480808Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a synergistic combination of polyacrylic and polymaleic polymers is used as corrosion inhibitors in traditional alkaline detergent compositions.Type: GrantFiled: July 31, 2012Date of Patent: July 9, 2013Assignee: Ecolab USA Inc.Inventors: Erik Christian Olson, Devon Beau Hammel
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Patent number: 8450262Abstract: [Objective] This invention is to provide a novel copolymer suitably applicable to a detergent composition having an excellent precipitation inhibitory ability and showing a good washing effect even under severe conditions of washing with water used to take Japanese bath. [Solution] A laundry detergent or cleaning composition which comprises a hydrophobic group-containing copolymer characterized by having 1 wt % or more but below 50 wt % of a structural unit (a) derived from at least one kind of monomer (A) selected from ether bond-containing monomers.Type: GrantFiled: September 1, 2009Date of Patent: May 28, 2013Assignee: The Procter & Gamble CompanyInventors: Jeffrey Scott Dupont, Atsuro Yoneda, Akiko Hemmi
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Publication number: 20130121945Abstract: The present invention relates to a thickener comprising i) at least one polymer preparable by polymerization of a) at least one water-soluble ethylenically unsaturated monomer comprising at least one anionic monomer and/or at least one nonionic monomer, b) at least one ethylenically unsaturated associative monomer, c) optionally at least one crosslinker, d) optionally at least one chain transfer agent, ii) at least one activator, where the ratio of activator to polymer is >10 to 100 [% by weight/% by weight].Type: ApplicationFiled: November 7, 2012Publication date: May 16, 2013Applicant: BASF SEInventor: BASF SE
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Publication number: 20130123164Abstract: A solidification matrix includes sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer or salt or derivative thereof, and additional functional ingredients. The sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer, and additional functional ingredients interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition. Methods of making solid detergent compositions are disclosed.Type: ApplicationFiled: January 4, 2013Publication date: May 16, 2013Applicant: ECOLAB USA INC.Inventor: ECOLAB USA INC.
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Publication number: 20130055508Abstract: Detergent compositions including at least one AMPS copolymer, at least one maleic acid polymer, an alkaline agent and optional additives are disclosed. Embodiments of the present invention are phosphorous free, and reduced scale accumulation for warewashing applications.Type: ApplicationFiled: September 1, 2011Publication date: March 7, 2013Applicant: ECOLAB USA INC.Inventors: Altony Miralles, Michelle Fung, John Krueger