Carboxylic Acid Anhydride, Free Carboxyl Group, Or Salt Thereof In The Polymer Patents (Class 510/476)
  • Patent number: 11028350
    Abstract: Process for making a powder or granule containing at least one chelating agent selected from alkali metal salts of methyl glycine diacetic acid (MGDA) and glutamic acid diacetate (GLDA) and iminodisuccinic acid (IDS), said process comprising the steps of (a) introducing an aqueous solution or aqueous slurry of the respective chelating agent (A) into a spray-dryer or spray-granulator, and removing most of said water by spray-drying or spray granulation using a gas with an inlet temperature of 125 to 250° C.
    Type: Grant
    Filed: June 1, 2017
    Date of Patent: June 8, 2021
    Assignee: BASF SE
    Inventors: Michael Klemens Mueller, Armin Stamm, Frank Jaekel, Carsten Sueling
  • Patent number: 10597611
    Abstract: A liquid detergent comprising: (a) from 30 to 80 wt % water; (b) from 5 to 50 wt % surfactants; and (c) from 0.5 to 10 wt % of an acrylic polymer comprising from 20 to 50 wt % polymerized units of (meth)acrylic acid and from 50 to 80 wt % polymerized units of a monomer of structure H2C?C(R)CO2(CH2CH2O)n(CH(R?)CH2O)mR?; wherein R is H or CH3, R? is C1-C2 alkyl; R? is C8-C22 alkyl or C8-C16 alkylphenyl; n is an average number from 6-30 and m is an average number from 0-10, provided that n?m and m+n is 6-30.
    Type: Grant
    Filed: July 7, 2017
    Date of Patent: March 24, 2020
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Anne Oberlin, Asghar A. Peera, Scott Backer, Matthew J. Jansma
  • Patent number: 10351806
    Abstract: A liquid detergent comprising: (a) from 0 to 30 wt % water; (b) from 60 to 90 wt % surfactants; and (c) from 0.5 to 10 wt % of an acrylic polymer comprising from 20 to 50 wt % polymerized units of (meth)acrylic acid and from 50 to 80 wt % polymerized units of a monomer of structure H2C?C(R)CO2(CH2CH2O)n(CH(R?)CH2O)mR?; wherein R is H or CH3, R? is C1-C2 alkyl; R? is C8-C22 alkyl or C8-C16 alkylphenyl; n is an average number from 6-30 and m is an average number from 0-10, provided that n?m and m+n is 6-30.
    Type: Grant
    Filed: February 3, 2017
    Date of Patent: July 16, 2019
    Assignee: Dow Global Technologies LLC
    Inventor: Anne Oberlin
  • Patent number: 10072373
    Abstract: A clothes dryer for drying fabric items in accordance with a treating cycle of operation, includes a treating chamber receiving fabric items for treatment and a controller having a memory in which is stored a set of executable instructions comprising at least one user-selectable cycle of operation, the controller may receive an indication of a dye transfer event and implement a cycle of operation based thereon.
    Type: Grant
    Filed: January 22, 2014
    Date of Patent: September 11, 2018
    Assignee: Whirlpool Corporation
    Inventors: Gregory R. Fulmer, Kaustav Ghosh, William L. Murch, Mir A. Quddus, Robert J. Pinkowski
  • Patent number: 9803156
    Abstract: A water-based cutting fluid that comprises water and a water-soluble polyalkylene glycol (PAG) having cloud point from 30° C. to 80° C. The cutting fluid is water-based, i.e., it comprises at least 50 percent by weight (wt %) water. The cutting fluids are well suited for use with diamond wiresaws for the cutting of silicon ingots. The fluids exhibit one or more of low hydrogen generation, no wafer cleaning issues, good lubricity, good cooling efficiency, good swarf suspension and dispersion, low foaming, are generally non-sensitive to metal ions, and are nonflammable.
    Type: Grant
    Filed: December 6, 2012
    Date of Patent: October 31, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Yi Ping Zhu, Bing Liang, Andong Liu, Wanglin Yu
  • Patent number: 9657904
    Abstract: Technologies are described herein for photobleaching a display. A display may be photobleached by exposing the display to light emitted by an external lamp and/or may be photobleached using one or more display lights of the electronic device during a burn-in period. In some examples, the light emitted by the lamp is filtered to remove wavelengths below a certain wavelength. The light that is received by the display from the lamp may include wavelengths between about 310 nm and 700 nm. These wavelengths correspond to visible light and near-visible light. The display may be exposed to the light for some duration or until some dose of light is received by the display. In other configurations, a burn-in period is performed for about eighteen hours.
    Type: Grant
    Filed: February 23, 2015
    Date of Patent: May 23, 2017
    Assignee: Amazon Technologies, Inc.
    Inventors: Guneet Sethi, Nhi A. Duong, Tin Quang Pham, Heather Kulani Coursey, Weihsin Hou, Robert L. D. Zenner, Saket Patil
  • Patent number: 9040473
    Abstract: A detergent for cleaning media is provided. The detergent comprises deionized water, between about 1% and about 5% by weight of a nonionic surfactant having an hydrophile/lipophile balance (HLB) value between about 10 and about 20, and an ethoxylation level between about 5 and about 20, between about 1% and about 5% by weight of a dispersing agent, between about 3% and about 10% by weight of a chelating agent comprising phosphonic acid, and between about 2% and about 6% by weight of an inorganic salt.
    Type: Grant
    Filed: July 21, 2010
    Date of Patent: May 26, 2015
    Assignee: WD Media, LLC
    Inventors: EE Boon Quah, Kwai Cheang Wong, Ming Yean Liew, Chung Lieh Chua, Yasuhiro Suzuki
  • Patent number: 9029314
    Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.
    Type: Grant
    Filed: February 18, 2014
    Date of Patent: May 12, 2015
    Assignee: Ecolab USA Inc.
    Inventors: Erik C. Olson, Devon Beau Hammel
  • Patent number: 9023779
    Abstract: A dishwashing detergent composition is provided for consumer use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorus containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a phosphinosuccinic acid oligomer or mixture thereof is used as a corrosion inhibitor and can be included for aluminum protection in a number of different detergent compositions.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: May 5, 2015
    Assignee: Ecolab USA Inc.
    Inventor: Altony J. Miralles
  • Patent number: 8969284
    Abstract: The present invention relates to a laundry detergent or a cleaning composition, preferably a granular detergent product, comprising a carboxyl-group containing polymer, which is useful in improving whiteness and/or anti-soil redeposition. Processes for making and methods of using the laundry detergent or cleaning composition are also encompassed by the present invention.
    Type: Grant
    Filed: August 15, 2013
    Date of Patent: March 3, 2015
    Assignee: The Procter & Gamble Company
    Inventors: Xiaoli Wang, Brian Joseph Loughnane, Xiaoyan Liu, Jeffrey Scott Dupont, Atsuro Yoneda, Daisuke Michitaka
  • Patent number: 8957010
    Abstract: The present invention relates to a cleaning composition, preferably a granular detergent product, comprising a carboxyl-group containing polymer, which is useful in improving whiteness and/or anti-soil redeposition. Processes for making and methods of using the cleaning composition are also encompassed by the present invention.
    Type: Grant
    Filed: August 15, 2013
    Date of Patent: February 17, 2015
    Assignee: The Procter & Gamble Company
    Inventors: Xiaoli Wang, Brian Joseph Loughnane, Atsuro Yoneda, Akiko Hemmi
  • Patent number: 8951956
    Abstract: A solidification matrix includes sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer or salt or derivative thereof, and additional functional ingredients. The sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer, and additional functional ingredients interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition. Methods of making solid detergent compositions are disclosed.
    Type: Grant
    Filed: January 4, 2013
    Date of Patent: February 10, 2015
    Assignee: Ecolab USA, Inc.
    Inventors: Caleb Jones, Katherine Molinaro, Darryl Bowling, Karen Rigley, Brenda L. Tjelta, Lisa M. Sanders, Michael E. Besse
  • Patent number: 8940680
    Abstract: Composition in the form of a gel containing at least 35% by weight of water, at least one foaming surfactant chosen from nonionic or amphoteric surfactants, and at least one superabsorbent polymer. The superabsorbent polymer helps to thicken the composition without affecting its cosmetic properties.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: January 27, 2015
    Assignee: L'Oreal
    Inventors: Anne-Laure Bernard, Odile Aubrun-Sonneville, Laurence Leroy
  • Patent number: 8901066
    Abstract: Branched polyesters with sulfonate groups can be obtained by reacting components A, B, optionally C, and optionally D to yield branched polyesters, then reacting these branched polyesters with hydrogen sulfite. Component A is at least one ?,?-olefinically unsaturated dicarboxylic acid, component B is at least one di- or higher-functional alcohol, optional component C is at least one di- or higher-functional carboxylic acid or hydroxycarboxylic acid without an ?,?-olefinically unsaturated bond, and optional component D is at least one compound of formula CH3(—O—CH2—CH2)n—OH. In reacting the branched polyesters with hydrogen sulfite, a molar amount of hydrogen sulfite is at most 95 mol %, based on an amount of ?,?-olefinically unsaturated dicarboxylic acid.
    Type: Grant
    Filed: June 13, 2012
    Date of Patent: December 2, 2014
    Assignee: BASF SE
    Inventors: Monika Haberecht, Juergen Detering, Bernd Bruchmann, Helmut Witteler, Heike Weber, Karl Kolter
  • Patent number: 8895493
    Abstract: The need for a stable, compact composition providing improved fabric care benefit, that is also convenient to use, can be met by incorporating a cationic cellulose polymer into a non-aqueous composition, using a non-aqueous dispersant. Such compositions have good physical stability, with little or no clumping of the cationic polymer in particulate form.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: November 25, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Regine Labeque, Rajae Boulaich, Marc Jennewein
  • Patent number: 8889613
    Abstract: A detergent comprises an alkalinity source, a homopolymer of acrylic acid or a salt thereof, a homopolymer of methacrylic acid or a salt thereof, and a homopolymer of maleic acid or a salt thereof. Suitable weight ratios include a weight ratio of the homopolymer of methacrylic acid or a salt thereof to the homopolymer of acrylic acid or a salt thereof between approximately 1:3 and approximately 3:1, a weight ratio of the homopolymer of acrylic acid or a salt thereof to the homopolymer of maleic acid or a salt thereof between approximately 3:1 and approximately 1:6, and a weight ratio of the homopolymer of methacrylic acid or a salt thereof to the homopolymer of maleic acid or a salt thereof between approximately 2:1 and approximately 1:4.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: November 18, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Carter Silvernail, Altony Miralles
  • Publication number: 20140336101
    Abstract: Polymer obtainable by radical emulsion polymerization of (A) at least one acidic vinyl monomer or salt thereof; (B) at least one nonionic vinyl monomer, particularly preferably a hydrophobic nonionic vinyl monomer; (C) at least one monomer containing an unsaturated end group and a polyoxyalkylene part; (D) at least one crosslinking monomer; and (E) optionally, a protective colloid, characterized in that the polymerization is controlled such that (F) the gel effect occurs, at least at times, achieved by adding monomers of type (A), (B), and (C) (dosing time) during 120 minutes; and such that (G) the crosslinking monomer (D) is added, at the very earliest, 10 minutes after the first addition of the monomers (A), (B), and (C).
    Type: Application
    Filed: June 15, 2012
    Publication date: November 13, 2014
    Applicant: BEIERSDORF AG
    Inventor: Sascha Mertens
  • Patent number: 8883705
    Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: November 11, 2014
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Travers Anderson, William L. Smith, Erika Szekeres, Rui Zhang
  • Patent number: 8871703
    Abstract: The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerization of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-li
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: October 28, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Roman Morschhaeuser, Barbara Duecker, Frank-Peter Lang, Georg Borchers, Peter Naumann
  • Patent number: 8871702
    Abstract: The invention relates to polyesters, obtainable by means of polymerization of the components including (a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and N is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), in which m is an integer from 1 to 10 and X is hydrogen or an alkali metal ion, and g); optionally one or more crosslinking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provide
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: October 28, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Roman Morschhaeuser, Barbara Duecker, Hans Juergen Scholz
  • Patent number: 8846599
    Abstract: Branched polyesters with sulfonate groups obtainable by the reaction of the components A, B, optionally C and optionally D to give branched polyesters, where the component A is selected from the group of ?,?-olefinically unsaturated dicarboxylic acids, and the component B is selected from the group of tri- or higher-functional alcohols, the optional component C is selected from the group of difunctional alcohols or of difunctional carboxylic acids without ?,?-olefinically unsaturated bonds, the optional component D is selected from fatty acids or fatty alcohols, and the subsequent reaction of the resulting branched polyesters with hydrogen sulfite, where the molar amount of hydrogen sulfite is at most 95 mol %, based on the amount of ?,?-olefinically unsaturated dicarboxylic acid.
    Type: Grant
    Filed: June 13, 2012
    Date of Patent: September 30, 2014
    Assignee: BASF SE
    Inventors: Monika Haberecht, Frank Rittig, Bernd Bruchmann, Claudia Esper, Roland Ettl, Karl Kolter
  • Publication number: 20140271521
    Abstract: A process for forming a personal care article, the process including (a) producing an extrudate from a twin screw extruder, and (b) forming the extrudate into the personal care article. The personal care article includes (i) from about 10% to about 60% of one or more anionic surfactants, wherein the one or more anionic surfactants have a Krafft point of less than 30° C.; (ii) from about 10% to about 50% of one or more water soluble polymers; (iii) from about 1% to about 30% of one or more plasticizers; and (iv) from about 10% to about 50% water.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: The Procter & Gamble Company
    Inventors: Robert Wayne GLENN, JR., Todd Ryan THOMPSON, Ungyeong JUNG, Changwei ZHU, Alireza TABATABAEI-NAEINI
  • Patent number: 8802617
    Abstract: The present invention includes a cleaning composition that includes at least one alkalinity source, at least one surfactant, water and at least one polyglycerol graft polymer. The polyglycerol graft polymer includes a polyglycerol and a residue of at least one carboxylic acid or carboxylate containing compound in an amount less than or equal to about 40% by weight of the polyglycerol graft polymer.
    Type: Grant
    Filed: November 8, 2012
    Date of Patent: August 12, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Carter Silvernail, John Nording
  • Patent number: 8802616
    Abstract: A detergent composition having at least two components. The first component is from 8 to 50 wt % surfactants. The second component is from 0.05 to 4 wt % of a polymer which has polymerized residues of 40 to 80 wt % C1-C4 alkyl acrylates, 20 to 52 wt % C3-C6 carboxylic acid monomers, and 0 to 10 wt % of monomers having an alkyl group having at least ten carbon atoms.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: August 12, 2014
    Assignee: Rohm and Haas Company
    Inventors: Joseph Manna, Roy Roberts, Jan Edward Shulman
  • Publication number: 20140178324
    Abstract: Disclosed is a pH responsive polymer made with mono-[2-(methacryloyloxy)ethyl]phthalate and/or mono-[2-(methacryloyloxy)ethyl hexahydro]phthalate. Also disclosed is an aqueous coating composition including at least one latex polymer derived from at least one monomer copolymerized or blended with alkali swellable acrylate copolymer. Also provided is an aqueous coating composition including at least one latex polymer derived from at least one monomer blended with alkali swellable acrylate copolymer, at least one pigment, and water. Also provided is a method of preparing an aqueous coating composition such as a latex paint including the above components. Also provided are methods of preparing mono-[2-(methacryloyloxy)ethyl]phthalate. Also provided are conpositions and methods using the polymer in hydraulic fracturing, personal care and or home and industrial cleaners.
    Type: Application
    Filed: December 18, 2013
    Publication date: June 26, 2014
    Applicant: Rhodia Operations
    Inventors: Nemesio Martinez-Castro, Jennie McGuire, Herve Adam, James Woods
  • Patent number: 8740993
    Abstract: A laundry detergent composition includes an alkalinity source, at least one nonionic surfactant and a polymer comprising maleic acid, vinyl acetate and alkyl acrylate monomers. The alkalinity source is present in an amount between about 1% and about 75% by weight of the laundry detergent composition and includes at least one member selected from alkali metal hydroxides, carbonates, and bicarbonates. The polymer comprising maleic acid, vinyl acetate and alkyl acrylate monomers is present in an amount equal to or greater than about 0.5% by weight of the laundry detergent composition.
    Type: Grant
    Filed: March 23, 2012
    Date of Patent: June 3, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Stephen Christensen, Lauren M. Hunker, Carter Silvernail, Brandon G. Beyer, Kerrie E. Walters
  • Patent number: 8735336
    Abstract: Methods for removing an organic material from a portion of oilfield equipment are described. The methods include forming a composition that includes a hybrid polymer and introducing the composition to the portion of the oilfield equipment from which the organic material is to be removed. The hybrid polymer includes a synthetic component formed from at least one or more olefinically unsaturated carboxylic acid monomers or salts thereof, and a natural component formed from a hydroxyl-containing natural moiety.
    Type: Grant
    Filed: February 18, 2013
    Date of Patent: May 27, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jayachandran Perumalsamy, Colby Tate
  • Patent number: 8729006
    Abstract: The present invention includes methods and compositions that employ sodium carboxymethyl cellulose as a scale inhibitor. According to the invention, scale inhibiting compositions are disclosed which include, sodium carboxymethyl cellulose and a polymer such as polymaleic acid, polyacrylic acid or mixtures, copolymers or terpolymers of the same and optionally may also include a phosphonate. The scale control composition may be incorporated into a detergent/cleaning composition.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: May 20, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Altony Miralles, Xin Sun, Michelle Fung, John Krueger
  • Publication number: 20140128310
    Abstract: The present invention includes a cleaning composition that includes at least one alkalinity source, at least one surfactant, water and at least one polyglycerol graft polymer. The polyglycerol graft polymer includes a polyglycerol and a residue of at least one carboxylic acid or carboxylate containing compound in an amount less than or equal to about 40% by weight of the polyglycerol graft polymer.
    Type: Application
    Filed: November 8, 2012
    Publication date: May 8, 2014
    Applicant: ECOLAB USA INC.
    Inventors: Carter Silvernail, John Nordling
  • Publication number: 20140116472
    Abstract: Phosphorus-free detergent compositions are provided. Detergent compositions including an aminocarboxylate, water conditioning agent, source of alkalinity and water beneficially do not require the use of additional surfactants and/or polymers to provide suitable detergency and prevent scale build-up on treated surfaces. The detergent compositions are used with a sanitizer to employ the phosphorus-free detergent compositions for use as low temperature ware wash detergents that beneficially reduce scale build-up. Methods of employing the phosphorus-free detergent compositions are also provided.
    Type: Application
    Filed: October 26, 2012
    Publication date: May 1, 2014
    Inventors: Erin Jane Dahlquist, Carter Martin Silvernail, Steven E. Lentsch, Terrence P. Everson
  • Publication number: 20140107011
    Abstract: The invention provides environmentally safe compositions and methods for cleaning surfaces to remove soap scum, iron oxide, calcium carbonate or calcium stearate deposits, or a combination thereof, from surfaces. The compositions of the invention comprise calcium chelating agents, one or more nonionic surfactants, one or more chelating agents, one or more anionic polymeric surfactants, an acid, and water, wherein the composition is alkaline. The compositions generally have a pH between 7.0 and 10, are biodegradable, non-toxic, free of VOCs, and are made of renewable, sustainable materials.
    Type: Application
    Filed: October 15, 2013
    Publication date: April 17, 2014
    Applicant: Commercial Pool, Inc.
    Inventors: Tyler BANASZAK, Dakarai Kameron BROWN
  • Patent number: 8691018
    Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: April 8, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Erik Christian Olson, Devon Beau Hammel
  • Patent number: 8673835
    Abstract: The present invention provides compositions which not only effectively kill a broad spectrum of microorganisms present on surfaces on contact but continue to kill microorganisms for a period of time thereafter.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: March 18, 2014
    Assignee: Reckitt Benckiser LLC
    Inventors: Timothy Michael Cusack, Karen Ann McCue, Herbert W Ulmer
  • Publication number: 20140017184
    Abstract: Personal care compositions comprising, as thickeners and suspending agents, crosslinked alkali swellable polyacrylates containing one or more acetoacetyl or cyanoacetyl groups.
    Type: Application
    Filed: March 16, 2012
    Publication date: January 16, 2014
    Applicant: Lamberti SPA
    Inventors: Chiara Fumagalli, Eva Baldaro, Giovanni Floridi, Giuseppe Li Bassi
  • Patent number: 8623151
    Abstract: A cleaning composition includes an alkali metal silicate, a polymer including maleic acid, vinyl acetate and alkyl acrylate monomers, and optionally water. The cleaning composition can include approximately 10% and approximately 90% by weight of at least one alkali metal silicate, greater than or equal to approximately 0.1% by weight of the polymer containing maleic acid, vinyl acetate and alkyl acrylate monomers, and approximately 0% to approximately 80% by weight water.
    Type: Grant
    Filed: March 23, 2012
    Date of Patent: January 7, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Erik C. Olson, Carter Silvernail
  • Publication number: 20130331308
    Abstract: Self-adhesive detergent compositions are described including a pH-sensitive color-changing system. The color-changing system is useful with certain acidic compositions and certain alkaline compositions. The compositions have a given color upon application to a hard surface, e.g., a toilet bowl. In one embodiment, when the self-adhesive composition is exposed to a water-based rinse, such as on flushing a toilet, the color-changing system provides the released cleaning portion of the composition, and thereby the water, with a color different from the color of the composition to indicate cleaning is occurring. In another embodiment, following exposure to a plurality of rinses, the color-changing system changes the color of the composition when the composition is near depletion to provide an “end-of-use” cue.
    Type: Application
    Filed: June 8, 2012
    Publication date: December 12, 2013
    Inventors: Wayne M. REES, Thomas A. STRASH
  • Publication number: 20130274150
    Abstract: The present invention generally relates to controlling the viscosity of water-based mud systems. More particularly, the present invention relates to methods and compositions for thinning and deflocculating aqueous based fluids used in well drilling and other well operations in subterranean formations, especially subterranean formations containing oil and/or gas. The invention also relates to a drilling fluid thinner and/or dispersant having improved temperature stability, dispersing properties and “solids contamination” tolerance.
    Type: Application
    Filed: December 16, 2011
    Publication date: October 17, 2013
    Applicant: Akzo Nobel Chemicals International B.V.
    Inventors: Stuart Holt, Klin Aloysius Rodrigues, Jannifer Sanders
  • Publication number: 20130247936
    Abstract: The present invention is directed, in certain embodiments, to compositions useful for the removal of grease, lime scale, soap scum, feces, rust or other soils from surfaces such as those found in bathrooms, toilets and kitchens. Methods of removing soils and preventing soil adhesion are also contemplated.
    Type: Application
    Filed: February 27, 2013
    Publication date: September 26, 2013
    Applicant: Colgate-Palmolive Company
    Inventors: Michele Davister, Nathalie Dastbaz, Alain Jacques, Germaine Zocchi
  • Publication number: 20130252870
    Abstract: The present invention is related to a cleaning composition including at least one alkalinity source and a biodegradable terpolymer including maleic acid, vinyl acetate and alkyl acrylate segments or monomers for controlling scale. The diluted use solution has a pH between about 7 and about 11.5.
    Type: Application
    Filed: March 23, 2012
    Publication date: September 26, 2013
    Applicant: ECOLAB USA INC.
    Inventor: Carter Silvernail
  • Patent number: 8530403
    Abstract: A solidification matrix includes a maleic-containing terpolymer, sodium carbonate, and water. The maleic-containing terpolymer, sodium carbonate, and water interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: September 10, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Brenda L. Tjelta, Lisa M. Sanders
  • Patent number: 8524649
    Abstract: An aqueous dispersion of a copolymer with copolymerized units a) of at least one ethylenically unsaturated carboxylic acid, b) of at least one nonionic ethylenically unsaturated surfactant monomer, c) of at least one C1-C2-alkyl methacrylate, d) of at least one C2-C4-alkyl acrylate, where the alkyl chain length averaged over the number of alkyl groups of the alkyl acrylate is 2.1 to 4.0, is described. Following neutralization with alkali, the dispersion serves as associative thickener, in particular for liquid detergent and cleaner formulations. The thickeners are characterized by high transparency and high thickening effect coupled with high shear dilution.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: September 3, 2013
    Assignee: BASF SE
    Inventors: Reinhold J Leyrer, Kati Schmidt
  • Publication number: 20130195775
    Abstract: Ionic and ionogenic comb copolymers are disclosed along with personal care products that employ them as a modifier that results in increased sensory attributes and increased effectiveness in the deposition of actives and can also act as a thickening agent. The copolymer includes one or more repeating units derived from olefinically unsaturated anionic or anionogenic or zwitterionic comonomers, and one or more repeating units having the formula in which Y is a moiety forming part of a copolymer backbone, Z is a moiety that exhibits association with other Z moieties or with other moieties within the ultimate formulation in which the copolymer will be employed, and b is a bond or moiety that links the Z moiety to the Y moiety. In certain embodiments, the copolymer also includes repeating units derived from acrylamide monomers, olefinically unsaturated hydrophilic monomers or other olefinically unsaturated monomers.
    Type: Application
    Filed: August 3, 2012
    Publication date: August 1, 2013
    Applicants: LANDEC CORPORATION, AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Richard Joseph Goddard, Mussarat Noor, Julian Everett Schafer, Steven Paul Bitler, David Dakin Taft, Shiying Zheng
  • Patent number: 8496757
    Abstract: A cleaning solution and method for removing submicron particles from the surface and/or the bevel of an electronic substrate such as a semiconductor wafer. The cleaning solution comprises a polycarboxylate polymer or an ethoxylated polyamine. The method comprises the step of contacting a surface of the substrate with a cleaning solution comprised of a polycarboxylate polymer or an ethoxylated polyamine. Additional optional steps in the method include applying acoustic energy to the cleaning solution and/or rinsing the surface with a rinsing solution with or without the application of acoustic energy to the rinsing solution.
    Type: Grant
    Filed: July 22, 2012
    Date of Patent: July 30, 2013
    Assignee: Fontana Technology
    Inventor: Mark Jonathan Beck
  • Publication number: 20130189198
    Abstract: Disclosed are surfactant compositions containing at least one crosslinked acrylic copolymer. The crosslinked acrylic copolymer is polymerized in the presence of at least two different classes of crosslinking monomers. The crosslinked acrylic copolymers provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions.
    Type: Application
    Filed: October 5, 2011
    Publication date: July 25, 2013
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventor: Krishnan Tamareselvy
  • Patent number: 8486884
    Abstract: The present invention relates to a method for producing granular or pulverulent detergent compositions, comprising the production of a detergent base powder by drying an aqueous detergent slurry, which comprises adding to the slurry a copolymer which is obtained by free-radical copolymerization of (A) from 20 to 80% by weight of at least one monomer selected from the group consisting of monoethylenically unsaturated monocarboxylic acids, dicarboxylic acids and dicarboxylic anhydrides, and (B) from 20 to 80% by weight of at least one monomer selected from the group consisting of aliphatic or aromatic monoolefins.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: July 16, 2013
    Assignee: BASF Aktiengesellschaft
    Inventors: Tanja Seebeck, Helmut Guembel
  • Patent number: 8480808
    Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a synergistic combination of polyacrylic and polymaleic polymers is used as corrosion inhibitors in traditional alkaline detergent compositions.
    Type: Grant
    Filed: July 31, 2012
    Date of Patent: July 9, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Erik Christian Olson, Devon Beau Hammel
  • Patent number: 8450262
    Abstract: [Objective] This invention is to provide a novel copolymer suitably applicable to a detergent composition having an excellent precipitation inhibitory ability and showing a good washing effect even under severe conditions of washing with water used to take Japanese bath. [Solution] A laundry detergent or cleaning composition which comprises a hydrophobic group-containing copolymer characterized by having 1 wt % or more but below 50 wt % of a structural unit (a) derived from at least one kind of monomer (A) selected from ether bond-containing monomers.
    Type: Grant
    Filed: September 1, 2009
    Date of Patent: May 28, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey Scott Dupont, Atsuro Yoneda, Akiko Hemmi
  • Publication number: 20130121945
    Abstract: The present invention relates to a thickener comprising i) at least one polymer preparable by polymerization of a) at least one water-soluble ethylenically unsaturated monomer comprising at least one anionic monomer and/or at least one nonionic monomer, b) at least one ethylenically unsaturated associative monomer, c) optionally at least one crosslinker, d) optionally at least one chain transfer agent, ii) at least one activator, where the ratio of activator to polymer is >10 to 100 [% by weight/% by weight].
    Type: Application
    Filed: November 7, 2012
    Publication date: May 16, 2013
    Applicant: BASF SE
    Inventor: BASF SE
  • Publication number: 20130123164
    Abstract: A solidification matrix includes sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer or salt or derivative thereof, and additional functional ingredients. The sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer, and additional functional ingredients interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition. Methods of making solid detergent compositions are disclosed.
    Type: Application
    Filed: January 4, 2013
    Publication date: May 16, 2013
    Applicant: ECOLAB USA INC.
    Inventor: ECOLAB USA INC.
  • Publication number: 20130055508
    Abstract: Detergent compositions including at least one AMPS copolymer, at least one maleic acid polymer, an alkaline agent and optional additives are disclosed. Embodiments of the present invention are phosphorous free, and reduced scale accumulation for warewashing applications.
    Type: Application
    Filed: September 1, 2011
    Publication date: March 7, 2013
    Applicant: ECOLAB USA INC.
    Inventors: Altony Miralles, Michelle Fung, John Krueger