Nitrogen Attached To The Polycarboxylic Component By Nonionic Bonding (e.g., Nitrilotriacetate Salt, Etc.) Patents (Class 510/480)
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Patent number: 12258541Abstract: The present invention relates to a crumbly phase composition containing on total weight of the composition (i) 70-87 wt % of organic compounds and salts thereof containing 85 to 100 wt % on total organic compounds and salts thereof of MGDA-Na3, wherein at least 60 wt % of the MGDA-Na3 is crystalline, and (ii) 13-30 wt % of water The invention furthermore relates to a process to prepare the above composition and a process to prepare crystals of MGDA-Na3 by drying the above composition.Type: GrantFiled: December 17, 2019Date of Patent: March 25, 2025Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.Inventors: Elwin Schomaker, Paulus Johannes Cornelis Van Haeren, Martin Heus, Marco Ypma, Stijn Richard Gerard Oudenhoven, Roy Gérard Doppen
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Patent number: 11889832Abstract: The disclosure relates to antimicrobial compositions and their methods of use and manufacture. In particular, the antimicrobial compositions described herein comprise an antimicrobial active, a primary foaming agent, and an L-amino acid to provide rapid antimicrobial efficacy. In a preferred embodiment, the antimicrobial compositions are dermal cleansers. In a most preferred embodiment, the antimicrobial compositions comprise a foam structure enhancing agent.Type: GrantFiled: May 18, 2020Date of Patent: February 6, 2024Assignee: Ecolab USA Inc.Inventors: Lilian Lam Josephson, Daniel E. Pedersen, Dale Curtis Larson
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Patent number: 11820944Abstract: According to one or more embodiments, sulfate ions may be removed from seawater to form an injection fluid by a method including passing the seawater and formation water to a mixing tank. The seawater may comprise sulfate ions. The formation water may comprise barium ions. The seawater and formation water may be passed to the mixing tank in a ratio determined by a computerized geochemical model. The method may further include mixing the seawater and formation water to form a mixed fluid and passing the mixed fluid to a clarifier, where a barium sulfate precipitate may be formed and at least a portion of the barium sulfate precipitate may be separated from the mixed fluid. The method may further include passing the mixed fluid to a microfiltration system, where at least a portion of the barium sulfate precipitate may be removed from the mixed fluid to form an injection fluid.Type: GrantFiled: April 10, 2023Date of Patent: November 21, 2023Assignee: Saudi Arabian Oil CompanyInventors: Peter Birkle, Yunjiao Fu
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Patent number: 11781227Abstract: The present invention discloses a method and a composition for removing metal sulfide scale present on the surface of a metal, said method comprising: providing a liquid composition comprising: a chelating agent and a counterion component selected from the group consisting of: sodium gluconate; gluconic acid; tetrasodium EDTA; EDTA; propylenediaminetetraacetic acid (PDTA); nitrilotriacetic acid (NTA); N-(2-hydroxyethyl) ethylenediaminetriacetic acid (HEDTA); diethylenetriaminepentaacetic acid (DTPA); hydroxyethyliminodiacetic acid (HEIDA); cyclohexylenediaminetetraacetic acid (CDTA); diphenylaminesulfonic acid (DPAS); ethylenediaminedi(o-hydroxyphenylacetic) acid (EDDHA); glucoheptonic acid; gluconic acid; oxalic acid; malonic acid; succinic acid; glutaric acid; adipic acid; pimelic acid; suberic acid; azelaic acid; sebacic acid; phthalic acid; terephthalic acid; aconitic acid; carballylic acid; trimesic acid; isocitric acid; citric acid; L-glutamic acid-N,N-diacetic acid (GLDA); salts thereof; and mixturType: GrantFiled: October 1, 2020Date of Patent: October 10, 2023Assignee: DORF KETAL CHEMICALS FZEInventors: Clay Purdy, Markus Weissenberger, Adrienne Lee
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Patent number: 11746280Abstract: A system and method for generating base water and precipitate, including combining produced water with seawater to precipitate barium sulfate from barium in the produced water and from sulfate in the seawater, and separating the precipitate to give the base water and the precipitate. The base water may have less than a specified amount of sulfate and be utilized for hydraulic fracturing fluid. The precipitate may give a weighting agent for drilling.Type: GrantFiled: June 14, 2021Date of Patent: September 5, 2023Assignee: Saudi Arabian Oil CompanyInventors: Fahd Ibrahim AlGhunaimi, Young Chul Choi, Regis Didier Alain Vilagines, Tao Chen, Nahr M. Abulhamayel, Sultan S. AlOtaibi
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Patent number: 11655413Abstract: According to one or more embodiments, sulfate ions may be removed from seawater to form an injection fluid by a method including passing the seawater and formation water to a mixing tank. The seawater may comprise sulfate ions. The formation water may comprise barium ions. The seawater and formation water may be passed to the mixing tank in a ratio determined by a computerized geochemical model. The method may further include mixing the seawater and formation water to form a mixed fluid and passing the mixed fluid to a clarifier, where a barium sulfate precipitate may be formed and at least a portion of the barium sulfate precipitate may be separated from the mixed fluid. The method may further include passing the mixed fluid to a microfiltration system, where at least a portion of the barium sulfate precipitate may be removed from the mixed fluid to form an injection fluid.Type: GrantFiled: February 4, 2021Date of Patent: May 23, 2023Assignee: Saudi Arabian Oil CompanyInventors: Peter Birkle, Yunjiao Fu
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Patent number: 11553718Abstract: The invention relates to a process for reducing the minimum inhibitory concentration (MIC) of a biocide against at least one strain of bacteria and/or at least one strain of yeast and/or at least one strain of mould in an aqueous preparation. The invention further relates to the use of a water soluble source of lithium ions for reducing the minimum inhibitory concentration (MIC) of a biocide against at least one strain of bacteria and/or at least one strain of yeast and/or at least one strain of mould in an aqueous preparation.Type: GrantFiled: July 8, 2020Date of Patent: January 17, 2023Assignee: Omya International AGInventors: Anita Zumsteg, Joachim Glaubitz, Simon Urwyler, Matthias Buri, Patrick A. C. Gane
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Patent number: 11473034Abstract: The present invention relates to new alkaline, preferably highly alkaline, cleaning solutions comprising surfactants with improved stability and cleaning performance under such conditions. It further relates to novel surfactants.Type: GrantFiled: February 5, 2019Date of Patent: October 18, 2022Assignee: Evonik Operations GmbHInventors: Eric Theiner, Buford Brian Smith, Khalil Yacoub, Larry Meyers
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Patent number: 10927397Abstract: Generation of foam when spraying biofilm-detection compositions onto a surface may entrain air and create bubbles, which lead to false positives. Aqueous biofilm-detecting compositions containing low-foaming surfactants, radical scavenger, solvent, thickener, hydrogen peroxide, chelating and coupling agent may be sprayed onto a surface to test for the presence of biofilm without generating excess bubbles or foam.Type: GrantFiled: October 16, 2019Date of Patent: February 23, 2021Assignee: Sterilex, LLCInventors: Ryan Alexander Simmons, Edward Fu
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Patent number: 10876043Abstract: A chelating agent may be used for reservoir acidification and stimulating injection. The raw material composition of the chelating agent comprises: 10.0%-20.0% of methanesulfonic acid, 10.0%-20.0% of methanol, 10.0%-20.0% of polyaspartic acid, 10.0%-15.0% of epoxy succinic acid, 5.0%-10.0% of sodium cetyl sulfonate, 10.0%-15.0% of cetyltrimethylammonium bromide and the balance of water. The present disclosure also provides a preparation method of the above chelating agent. The chelating agent for reservoir acidification and stimulating injection may be used in an acidizing and stimulating injection process, wherein it can effectively dissolve rock cracks, be used directly without need to be reversed.Type: GrantFiled: January 23, 2019Date of Patent: December 29, 2020Assignee: PetroChina Company LimitedInventors: Lijun Mu, Xianwen Li, Hongjun Lu, Yong Wang, Bin Yao, Zhenning Ji, Suiwang Zhang, Xiaobing Lu, Zhiying Deng, Lei SUi, Erzhen Wang, Zhaojie Song
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Patent number: 10119048Abstract: The present invention provides aqueous chemical mechanical planarization (CMP) polishing compositions that comprise a mixture of one or more surfactants chosen from an amine alkoxylate, an ammonium alkoxylate, or mixtures thereof, and colloidal silica particles having at least one cationic species, the colloidal silica particles being present in the amount of from 1 to 30 wt. %, as solids based on the total weight of the composition, and the compositions having a pH ranging from 2 to 6. The surfactants have a hydrophobic tail. The CMP polishing compositions exhibit tunable oxide:polysilicon and oxide:nitride removal rate ratios and reduce both silicon nitride and polysilicon removal rates significantly without significantly reducing dielectric (e.g. TEOS) removal rates.Type: GrantFiled: July 31, 2017Date of Patent: November 6, 2018Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.Inventors: Yi Guo, David Mosley, Naresh Kumar Penta
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Patent number: 9096820Abstract: Process to prepare coated particles containing a particle and a coating, wherein the particle contains glutamic acid N,N-diacetic acid or a (partial) salt thereof of the formula HnYm-GLDA, wherein Y is a cation selected from the group of sodium, potassium, lithium, and mixtures thereof, n+m=4, in which the particle is made from a solution containing glutamic acid N,N-diacetic acid or a partial salt thereof that has a pH of between 4 and 11, and subsequently or simultaneously the coating is applied on the particle, to an intermediate particle of HnYm-GLDA, wherein n is 0.1-3.2 and m is 0.8-3.9, the coated particle obtainable with the process, and the use thereof.Type: GrantFiled: December 21, 2010Date of Patent: August 4, 2015Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.Inventors: Cornelis Elizabeth Johannus Van Lare, Roy Gérard Doppen
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Patent number: 8940678Abstract: The present invention relates to a solid with sufficiently low hygroscopicity which comprises glutamic acid-N,N-diacetic acid (GLDA) or derivatives and/or salts thereof, and a method for its production.Type: GrantFiled: December 27, 2010Date of Patent: January 27, 2015Assignee: BASF SEInventor: Andreas Baranyai
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Patent number: 8927479Abstract: An aqueous aerosol bathroom cleaner includes a surfactant, a water-soluble or dispersible organic solvent, a chelating agent and a propellant that comprises n-butane. Comparative data demonstrate that the presence of n-butane in the composition enhances the rate of bathroom soap scum removal relative to aerosol compositions that do not contain n-butane in the propellant. The amount of surfactant present is sufficient so that the composition develops a stable foam upon being dispensed onto a soiled bathroom hard surface. The foam collapses after 10 to 60 seconds to deliver the cleaning components onto the surface.Type: GrantFiled: August 30, 2012Date of Patent: January 6, 2015Assignee: The Clorox CompanyInventor: Kristina Perlas
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Patent number: 8921299Abstract: This disclosure relates to detergent compositions containing tiron, a ligand capable of binding iron, an iron-displacing species, and iron. Methods for altering the color in a tiron-containing detergent composition are also disclosed.Type: GrantFiled: July 25, 2012Date of Patent: December 30, 2014Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Patrick Christopher Stenger, Jean-Pol Boutique
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Patent number: 8921295Abstract: A biodegradable concentrated neutral detergent composition comprises various chelate compounds, various corrosion inhibitors, an alkaline compound, at least one sequestrant, various surfactants and hydrotropes, and water. The detergent can be highly concentrated, has a good long term shelf life, and when diluted is very effective in cleaning metals such as surgical instruments and prevents corrosion resistance of the metal even in a hard water environment.Type: GrantFiled: June 29, 2011Date of Patent: December 30, 2014Assignee: American Sterilizer CompanyInventors: Ann Maria Kneipp, Nancy-Hope E. Kaiser, Althea Noel Johnson
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Patent number: 8883711Abstract: The invention relates to a cleaning composition with improved stain removal. The alkaline composition contains a hydrolysable dispersing polymer which is selected from carboxylated fructans and one or more biodegradable aminocarboxylate chelating agents.Type: GrantFiled: May 19, 2011Date of Patent: November 11, 2014Assignee: Italmatch Chemicals SpAInventors: Isabelle Leonard, Valerie Kochowski, Genevieve Bonnechere-Delstanche, Olivier Henry
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Patent number: 8846593Abstract: The present invention relates to formulations comprising (A) at least one aminocarboxylate, selected from methylglycine diacetate (MGDA), iminodisuccinic acid (IDA) and glutaminic acid diacetate (GLDA), and salts and derivatives thereof, and (B) at least one alkyleneimine polymer which is covalently modified with at least one carboxylic acid or at least one derivative of a carboxylic acid or at least one derivative of carbonic acid, where up to at most 75 mol % of the nitrogen atoms of the primary and secondary amino groups of the alkyleneimine polymer have been reacted with carboxylic acid or derivative of carboxylic acid or carbonic acid.Type: GrantFiled: April 24, 2013Date of Patent: September 30, 2014Assignee: BASF SEInventors: Stephan Hueffer, Alejandra Garcia Marcos, Markus Hartmann, Heike Weber, Mario Emmeluth
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Patent number: 8801806Abstract: The invention relates to methods and compositions for treating non-trans fats, fatty acids and sunscreen stains with a chelating agent. The invention also relates to methods for reducing the frequency of laundry fires with a chelating agent.Type: GrantFiled: November 30, 2010Date of Patent: August 12, 2014Assignee: Ecolab USA Inc.Inventors: Victor F. Man, Yvonne M. Killeen
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Patent number: 8758520Abstract: Methods of acidic warewashing are disclosed. The compositions can include other materials including surfactants and chelating agents, and are preferably phosphorous free. Methods of using the acidic compositions are also disclosed. Exemplary methods include using the acidic compositions together with other compositions, including alkaline compositions and rinse aids employed in an alternating alkaline/acid/alkaline manner. The methods also include acidic compositions that serve multiple roles.Type: GrantFiled: May 18, 2012Date of Patent: June 24, 2014Assignee: Ecolab USA Inc.Inventors: Lee J. Monsrud, Michael S. Rischmiller, Daniel Osterberg, John Mansergh
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Patent number: 8754026Abstract: A process for producing granules containing one or more complexing agent salts of the general formula from an aqueous starting solution, containing the one or more complexing agent salts in a concentration of from 10 to 80% by weight, based on the total weight of the aqueous starting solution, in a jet apparatus.Type: GrantFiled: September 23, 2011Date of Patent: June 17, 2014Assignee: BASF SEInventors: Stefan Blei, Michael Schoenherr, Franz Weber, Francois Becker
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Publication number: 20140158166Abstract: A cleaning composition comprises at least one surfactant and at least one colorant. The cleaning composition can have a pH of about 3 or less. The colorant exhibits one of several specified structures at a pH of about 7. A method for cleaning a surface utilizes the cleaning composition.Type: ApplicationFiled: October 23, 2013Publication date: June 12, 2014Applicant: MILLIKEN & COMPANYInventors: Yogesh Saraf, Eduardo Torres, Sanjeev K. Dey, Paul D. Halphen
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Patent number: 8748366Abstract: A process for the preparation of a spray-dried powder containing at least one glycine-N,N-diacetic acid compound of a formula MOOC—CHR—N(CH2COOM)2, where R is a C1-12-alkyl and M is an alkali metal, the process including: preparing an aqueous solution containing the glycine-N,N-diacetic acid compound; concurrently passing the aqueous solution and air into a spray-drying apparatus; atomizing the aqueous solution by feeding the aqueous solution onto a rotating disk or by compressing the aqueous solution with a pump to a pressure of ?20 bar absolute, to obtain fine liquid droplets; and drying the droplets, to obtain the spray-dried powder, where a temperature gradient between the aqueous solution and the air is in a range from 70 to 350° C., and a content of the glycine-N,N-diacetic acid compound in the aqueous solution is ?84% by weight, based on a total weight of the dry mass.Type: GrantFiled: May 19, 2010Date of Patent: June 10, 2014Assignee: BASF SEInventors: Frank Mrzena, Michael Schoenherr, Robert Heinz, Thomas Heidenfelder
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Patent number: 8735339Abstract: A liquid composition comprising 1-hydroxyethylidene-1,1-diphosphonic acid and a salt of ethylenediamine disuccinic acid which salt includes a counterion selected from 5 potassium, rubidium, caesium a substituted ammonium ion or mixtures thereof.Type: GrantFiled: December 8, 2011Date of Patent: May 27, 2014Assignee: Innospec LimitedInventor: Matthew Robert Giles
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Patent number: 8709990Abstract: Formulations comprising (A) at least one compound selected from aminocarboxylates and polyaminocarboxylates, (B) at least one homopolymer or copolymer of ethyleneimine, (C) sodium citrate and (D) at least one compound selected from alkali metal percarbonate, alkali metal perborate and alkali metal persulfate.Type: GrantFiled: October 18, 2012Date of Patent: April 29, 2014Assignee: BASF SEInventors: Stephan Hueffer, Alejandra Garcia Marcos, Markus Hartmann, Heike Weber
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Patent number: 8673834Abstract: The present invention comprises an iron complexing mixture and method of using same wherein beneficial performance and natural gas pipeline cleaning methods are employed. The synergistic improvement of combining two water-soluble metal complexing agents, THPS and IDS, prove to offer advantages in performance over the individual use of either chemical.Type: GrantFiled: December 17, 2010Date of Patent: March 18, 2014Inventor: David O. Trahan
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Publication number: 20140057816Abstract: The invention relates to a class of novel surfactants that have utility in the recovery and/or extraction of oil.Type: ApplicationFiled: November 5, 2012Publication date: February 27, 2014Applicant: Soane Energy, LLCInventors: David S. Soane, Rosa Casado Portilla, John H. Dise, Robert P. Mahoney
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Publication number: 20140050687Abstract: A variety of betaine esters, including dialkylaminoalkyl cocoate betaines and dialkylaminoalkyl hydrogenated cocoate betaines are disclosed. These betaines can be advantageously prepared in high yield and purity by a three-step transiterification chemoenzymatic process or a two-step direct esterficiation chemoenzymatic process. These betaine esters have excellent surfactant properties.Type: ApplicationFiled: October 30, 2013Publication date: February 20, 2014Applicant: Estman Chemical CompanyInventors: Christopher Harlan Burk, Stephanie Kay Clendennen, Neil Warren Boaz
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Patent number: 8653016Abstract: The present invention provides a biodegradable cleaning composition that includes a surfactant component including an ethoxylated 2-propyl heptanol, a chelating component including a tri-sodium salt of methylglycinediacetic acid and an emulsifier component including an ethoxylated hexanol having the formula C6H13O(CH2CH2O)H. The ethoxylated 2-propyl heptanol has the formula C5H11CH(C3H7)CH2O(C2H4O)pH, wherein p is a number of from 3 to 6. The composition also includes water and an acid component to establish a pH of the composition at less than 2. The composition is substantially free of solvents thereby reducing emission of volatile organic compounds and reducing potential environmental pollution and health hazards. The composition is also effective in removing rust, lime soap, and metal salts of fatty acids from hard surfaces including metal, vinyl, and fiberglass.Type: GrantFiled: November 23, 2010Date of Patent: February 18, 2014Assignee: BASF SEInventors: Suzanne Gessner, Charles Kerobo, Sonia Patterson
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Patent number: 8642310Abstract: A hydrolytic enzyme is to be stabilized in a liquid surfactant preparation. This is achieved by using a component that stabilizes the hydrolytic enzyme and encompasses a phthaloylglutamic acid and/or a phthaloylaspartic acid.Type: GrantFiled: January 25, 2013Date of Patent: February 4, 2014Assignee: Henkel AG & Co. KGaAInventors: Petra Siegert, Marion Merkel, Hendrik Hellmuth, Timothy O'Connell, Karl-Heinz Maurer
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Patent number: 8629093Abstract: The present application relates to a compact liquid detergent composition comprising a mixture of chelants suitable for use in laundry cleaning.Type: GrantFiled: September 1, 2010Date of Patent: January 14, 2014Assignee: The Procter & Gamble CompanyInventors: Regine Labeque, Eugene Joseph Pancheri
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Patent number: 8541357Abstract: Cleaning compositions and laundry detergents comprising amphoteric polymers are disclosed. The amphoteric polymers may be comb polymers having polycarboxylate backbones and polyalkoxylate tentacles. In particular, the amphoteric polymer includes: a cationic group structure unit derived from a cationic group-containing monomer; and a carboxyl structure unit derived from a carboxyl group-containing monomer. The cationic group structure unit may be present at a level of 1% to 99% by mass based on 100% by mass of all structure units derived from all monomers in the amphoteric polymer. The carboxyl structure unit may be present at a level of 1% to 99% by mass based on 100% by mass of all the structure units derived from all the monomers in the amphoteric polymer. The cleaning compositions have high anti-soil redeposition ability and solubility with surfactants.Type: GrantFiled: December 16, 2011Date of Patent: September 24, 2013Assignee: The Procter & Gamble CompanyInventors: Koushik Mukherjee, Kenneth Nathan Price, Yoneda Atsuro, Michitaka Daisuke
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Patent number: 8518868Abstract: Gemini surfactants having the structural formula: where: R1 is a radical represented by —H or —CH3, R2 is an alkyl or alkenyl chain, or cycloalkyl or aryl; R3 is a radical represented by —H, —CH3, —CH?CH—CH3, or —COOX; R4 is a radical represented by —H, —CH3, or —CH2—COOX; R5 is a radical represented by —H, an alkyl or alkenyl, cycloalkyl or aryl group, or a metal; R6 is a radical represented by an alkyl, alkenyl, cycloalkyl or aryl group; n and m can have values from 1 to 250, depending on the molecular weight of polyether used; and i can have values of 0 and 1: In the radical —COOX used in R3 and R4, X is represented by: —H, an alkyl, alkenyl group, a cycloalkyl or aryl group, or a metal.Type: GrantFiled: December 14, 2010Date of Patent: August 27, 2013Assignee: Instituto Mexicano del PetroleoInventors: Raul Hernandez Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Hiram Isaac Beltran Conde, Simon Lopez Ramirez
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Patent number: 8513178Abstract: The invention relates to methods and compositions for treating non-trans fats, fatty acids and sunscreen stains with a chelating agent. The invention also relates to methods for reducing the frequency of laundry fires with a chelating agent.Type: GrantFiled: September 17, 2010Date of Patent: August 20, 2013Assignee: Ecolab USA Inc.Inventors: Victor F. Man, Yvonne M. Killeen
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Patent number: 8481474Abstract: A cleaning composition including an ionic liquid, and preferably no co-surfactants are provided. The compositions are substantially free of alkyl phenol ethoxylates, including nonyl phenol ethoxylates. The cleaning compositions provide superior cleaning efficacy for various soils, including proteins and food soils, providing an effective, biorenewable, environmentally friendly alternative to nonyl phenol ethoxylates.Type: GrantFiled: May 15, 2012Date of Patent: July 9, 2013Assignee: Ecolab USA Inc.Inventors: Amanda R. Blattner, Charles A. Hodge
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Patent number: 8461089Abstract: A dishwashing detergent composition comprising a malodor control component, and methods of cleaning dishware are provided. In some embodiments, the dishwashing detergent composition comprises at least one volatile aldehyde and an acid catalyst.Type: GrantFiled: December 16, 2010Date of Patent: June 11, 2013Assignee: The Procter & Gamble CompanyInventors: Ricky Ah-Man Woo, Steven Anthony Horenziak, Rhonda Jean Jackson, Zaiyou Liu, Michael-Vincent Nario Malanyaon, Jason John Olchovy, Christine Marie Readnour
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Patent number: 8455422Abstract: A particle comprising an aminocarboxylic builder obtainable by a process comprising the steps of: a) providing a solution comprising the aminocarboxylic builder; b) optionally adding an acidifying agent; c) adding sulphate or citrate to the solution resulting from of step b) to form a mixture; and d) converting the mixture resulting from step c) into particles.Type: GrantFiled: April 18, 2011Date of Patent: June 4, 2013Assignee: The Procter & Gamble CompanyInventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Patent number: 8431518Abstract: Automatic dishwashing detergent composition for use in the main wash of a dishwasher to provide drying wherein the detergent comprises an esterified alkyl alkoxylated surfactant of general formula (I) where R is a branched or unbranched alkyl radical having 8 to 16 carbon atoms; R3, R1 independently of one another, are hydrogen or a branched or unbranched alkyl radical having 1 to 5 carbon atoms; R2 is an unbranched alkyl radical having 5 to 17 carbon atoms; l, n independently of one another, are a number from 1 to 5 and m is a number from 13 to 35; and a dispersant selected from the group of organic polymers, organic builders and mixtures thereof.Type: GrantFiled: December 10, 2010Date of Patent: April 30, 2013Assignee: The Procter & Gamble CompanyInventors: Anju Deepali Massey Brooker, Yvonne Bridget McMeekin, Phan Shean Lim, Fernando Solache Leon
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Patent number: 8420586Abstract: Cleaner compositions, associated cleaners, and associated methods are disclosed. The cleaner compositions are capable for use in making thickened cleaners that are capable of removing from vertical and inverted surfaces fresh, greasy soils and baked-on soils encountered in the food service industry. The cleaner compositions include one or more alkalinity sources, one or more chelants, one or more surfactants, one or more thickening agents, one or more buffers, and as a remainder, water. Cleaner compositions of the invention are substantially free of phosphates and have a low caustic content making them user and environmentally friendly. Yet the cleaners of the invention are surprisingly effective at removing tenacious baked-on soils encountered in the food service industry. Compositions of the invention have a viscosity of about 700 cps and are applied using a foaming or misting dispenser.Type: GrantFiled: September 2, 2010Date of Patent: April 16, 2013Assignee: Ecolab USA Inc.Inventors: Thomas J. Vinson, Karen O. Rigley, Tami J. Tadrowski
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Patent number: 8399396Abstract: Detergent compositions containing catechols, such as Tiron (1,2-dihydroxybenzene-3,5-disulfonic acid), which do not have or do not develop the reddish color associated with the catechol/ferric iron chelate are disclosed. Methods for reducing the intensity of red color in a Tiron (1,2-dihydroxybenzene-3,5-disulfonic acid) containing detergent composition are also disclosed.Type: GrantFiled: December 23, 2008Date of Patent: March 19, 2013Assignee: The Procter & Gamble CompanyInventors: Robb Richard Gardner, Allison Lynn Gerdes, Jeffrey Anderson Seeley
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Patent number: 8389460Abstract: The present invention washes clothes using a phosphorous-free detergent composition for clothes, which contains an organic alkaline chelating agent as an essential ingredient, and an anti-soil redeposition agent, but no surfactant.Type: GrantFiled: July 3, 2006Date of Patent: March 5, 2013Assignee: Miz Co., Ltd.Inventors: Kazuyoshi Arai, Tomoki Seo, Ryousuke Kurokawa
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Patent number: 8389458Abstract: An ADW composition comprising a builder and a water-soluble copolymer which comprises: (a) from about 30 to 60 mol % of the copolymer having a structural unit originating from a monoethylenic unsaturated dicarboxylic acid (or dicarboxylate) monomer having 4 to 6 carbon atoms or its anhydride at; (b) from about 30 to 60 mol % of the copolymer having a structural unit originating from a monoethylenic unsaturated monocarboxylic acid (or monocarboxylate) monomer having 3 to 8 carbon atoms; and (c) from about 5 to 15 mol % of the polymer having a structural unit originating from a monoethylenic unsaturated monomer having a sulfonic (or sulfonate) group; wherein the water-soluble copolymer has a weight average molecular weight of from about 1,000 to about 50,000 wherein the copolymer is polymerized with hydrogen peroxide.Type: GrantFiled: March 27, 2009Date of Patent: March 5, 2013Assignee: The Procter & Gamble CompanyInventors: Takahiro Tsumori, Masato Nakano
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Patent number: 8357649Abstract: The present application relates to benefit agent delivery compositions comprising a material selected from the group consisting of agglomerates comprising chelant and an encapsulated benefit agent; agglomerates comprising an encapsulated benefit agent having a shell comprising chelant; agglomerates comprising an encapsulated benefit agent having a core comprising chelant and combinations thereof, and processes for making and using such benefit agent delivery compositions.Type: GrantFiled: November 4, 2010Date of Patent: January 22, 2013Assignee: The Procter & Gamble CompanyInventors: Andre Chieffi, Julian David Martin, Nicolas Guillard
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Patent number: 8357650Abstract: A particle comprising an aminocarboxylic builder and sulphate or citrate wherein the aminocarboxylic builder and the sulphate or citrate are present in a weight ratio of from about 6:1 to about 1:1.Type: GrantFiled: April 18, 2011Date of Patent: January 22, 2013Assignee: The Procter & Gamble CompanyInventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Publication number: 20130000370Abstract: The invention relates to aminocarboxylates in solid form which have a relatively high storage stability and improved processability, and to the use thereof in household products, in particular detergents, cleaners and care compositions, and in industrial processes.Type: ApplicationFiled: June 26, 2012Publication date: January 3, 2013Applicant: BASF SEInventor: Frank-Peter LANG
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Patent number: 8323416Abstract: One exemplary embodiment can be a process for removing one or more scale deposits formed on a surface. The process can include contacting the surface with a composition for a period of time sufficient to remove the scale deposits that comprise coke or metal sulfides or mixtures thereof. Generally, the composition includes an effective amount of an organic acid and/or a salt thereof, and an effective amount of an oxidizing agent.Type: GrantFiled: July 28, 2009Date of Patent: December 4, 2012Assignee: UOP LLCInventors: Steven A. Bradley, Walter Zamechek
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Patent number: 8293696Abstract: Compositions, such as alkali builder compositions for the laundry industry, are provided and include water, an alkali metal hydroxide component, a chelating component and a hydroxyethyliminodiacetic acid (HEIDA) component. Methods for producing such compositions are also disclosed.Type: GrantFiled: February 6, 2009Date of Patent: October 23, 2012Assignee: Ecolab, Inc.Inventors: Kevin P. McLaren, Joseph C. Drozd, Gordon Renn
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Publication number: 20120260938Abstract: A method of dissolving and/or inhibiting the deposition of scale on a surface of a system comprises the step of bringing the surface of the system into contact with a composition. The composition can comprise from about 3 to about 15 parts by weight of a chelating component. The chelating component is selected from the group of MGDA, NTA, HEDTA, GLDA, EDTA, DTPA, and mixtures thereof. The composition can further comprise from about 3 to about 15 parts by weight of an acidic component, which is different than the chelating component. The composition can further comprise at least about 60 parts by weight of water. Each of the parts by weight ranges above are based on 100 parts by weight of the composition. The composition may further comprise a surfactant component and/or a corrosion inhibitor.Type: ApplicationFiled: April 13, 2012Publication date: October 18, 2012Inventors: Kenneth L. Zack, Joseph P. Borst, David Durocher, David E. Przybyla, Victor Leung, Gunter Decker
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Patent number: 8283301Abstract: An automatic dishwashing detergent composition having at least two components. The first component is a polymer containing polymerized residues of at least one C3-C6 carboxylic acid monomer and a lactone end group. The second component is a biodegradable builder selected from among nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glycine-N,N-diacetic acid, methylglycine-N,N-diacetic acid, 2-hydroxyethyliminodiacetic acid, glutamic acid-N,N-diacetic acid, 3-hydroxy-2,2?-iminodisuccinate, S,S-ethylenediaminedisuccinate aspartic acid-diacetic acid, N,N?-ethylenediamine disuccinic acid, iminodisuccinic acid, aspartic acid, aspartic acid-N,N-diacetate, beta-alaninediacetic acid, polyaspartic acid, salts thereof and combinations thereof.Type: GrantFiled: March 8, 2011Date of Patent: October 9, 2012Assignee: Rohm and Haas CompanyInventors: Joseph Manna, Jan Edward Shulman
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Patent number: RE44058Abstract: This invention relates to a cleaning composition comprising at least one surfacatant or at least one cosmetic vehicle and a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units: (a) at least one monomer compound of general formula I: (b) at least one hydrophilic monomer carrying a functional group with an acidic nature which is copolymerizable with (a) and which is capable of being ionized in the application medium; (c) optionally at least one hydrophilic monomer compound with ethylenic unsaturation with a neutral charge, carrying one or more hydrophilic groups, which is copolymerizable with (a) and (b).Type: GrantFiled: July 14, 2009Date of Patent: March 12, 2013Assignee: Rhodia ChimieInventors: Eric Aubay, Dominic Yeung