Inorganic Silicon Containing Component Patents (Class 510/511)
  • Patent number: 6013617
    Abstract: Pulverulent detergent compositions, particularly suitable for washing and dishwashing machines, include a surfactant and a builder therefor, such builder comprising an alkali metal silicate advantageously having a SiO.sub.2 /M.sub.2 O molar ratio ranging from about 1.6 to 3.5, at least 30% and preferably at least 50% of the silicon atoms of which being in the Q.sub.2 and Q.sub.3 configurations, or such builder comprising said alkali metal silicate sorbed onto a particulate inert support substrate. Also, detergent compositing comprising (a) an aqueous solution of an alkali metal silicate having an SiO.sub.2 /M.sub.2 O molar ratio ranging from about 1.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: January 11, 2000
    Assignee: Rhone-Poulenc Chimie
    Inventors: Patrick Boittiaux, Daniel Joubert, Pascal Taquet, Jean-Claude Kiefer, Jerome Le Roux
  • Patent number: 5998345
    Abstract: An automatic dishwashing composition which is in the form of a tablet generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a dialkali metal disilicate, a nonionic surfactant, optional a polymer containing sulfonic acid groups, a wax coated chlorine bleach compound, and a hydrotrope.
    Type: Grant
    Filed: March 25, 1999
    Date of Patent: December 7, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Philip Gorlin, Steve Phillips, Divaker Kenkare
  • Patent number: 5998360
    Abstract: Soluble alkali metal silicates combined with antiredeposition agents can actually have a beneficial effect on bleach stabilisation if said antiredeposition agents are intimately mixed with an alkali metal silicate solution, the resulting product being then dried (spray drying, turbo drying, etc . . . ) into granules.
    Type: Grant
    Filed: April 13, 1998
    Date of Patent: December 7, 1999
    Assignee: Crosfield Limited
    Inventors: Keith R Cockett, Theo J Osinga
  • Patent number: 5990073
    Abstract: A process for the production of a detergent composition or component having a bulk density of less than 700 g/l which involves mixing a particulate starting material compound with a liquid binder in a mixer/granulator having both a stirring and a cutting action wherein the starting material contains a component, which is not a detergent active compound, having a bulk density of not more than 600 g/l is disclosed.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: November 23, 1999
    Assignee: Lever Brothers Company
    Inventors: Marcelito Abad Garcia, David Alan Jordan, Donald Peter, Chandulal Kantilal Ranpuria
  • Patent number: 5990075
    Abstract: A powdered cleaning product designed to extract oil and grease from fabric. It consists of the dry mixture of powdered montmorillonite clay and powdered talc, which are combined in a specific ratio. The mixture absorbs oil and grease from garments without leaving any rim around the spot or otherwise damaging the fabric.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: November 23, 1999
    Inventor: Nicola Terziev
  • Patent number: 5981456
    Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25.degree. C. A method of using the polymers to prevent fading or corrosion of dishware is also described.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: November 9, 1999
    Assignee: Lever Brothers Company
    Inventors: Alla Tartakovsky, Joseph Oreste Carnali, Richard Gerald Gary
  • Patent number: 5972859
    Abstract: Novel chip compositions comprise alkylene glycol, benefit agent and thickening agent (e.g., fumed silica). Use of chips comprising excess of alkylene glycol over benefit agent and thickening agent has been found to allow significant deposition of benefit agent without compromising processing. In a second embodiment, the invention comprises bar compositions comprising mixtures of the chips of the invention and chips containing defined surfactant systems. A process for forming the chips of the invention and a method of enhancing deposition without compromising processing using the chips of the invention are also disclosed.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: October 26, 1999
    Assignee: Lever Brothers Company
    Inventors: Terence Farrell, Georgia Shafer, James Dalton
  • Patent number: 5965512
    Abstract: A biodegradable liquid degreaser for use as a parts cleaner is described. The composition includes from about 0.5% to about 2% by weight of an alkali metal hydroxide; from about 0.5% to about 5% by weight of a corrosion inhibitor; from about 1.5% to about 15% by weight of a biodegradable terpene solvent; from about 5% to about 30% by weight of a biodegradable surfactant; from about 5% to about 15% by weight of a biodegradable co-solvent/co-surfactant and the balance consisting of water. The composition provides excellent degreasing of machine parts while being safe and pleasant to use. The advantage is an inexpensive, completely biodegradable, non-volatile composition for use as a machine part degreaser.
    Type: Grant
    Filed: July 1, 1998
    Date of Patent: October 12, 1999
    Inventors: Teresa A. Smyth, Dennis R. Lambert
  • Patent number: 5962397
    Abstract: Disclosed are granular detergent components and processes for making these components. The processes comprise the steps of: i) forming the granular detergent component by drying an aqueous solution, the aqueous solution comprising at least 50% of a cationic surfactant, to form a powder; and then ii) densifying the powder in the presence of a detergent powder selected from the group consisting of aluminosilicate, carbonate, bicarbonate, silicate, sulphate, citrate, clay and mixtures thereof and an acid selected from the group consisting of citric, sulphuric, hydrochloric, polycarboxylic acids and mixtures thereof. This granular detergent component consists essentially of the cationic surfactant, the acid and the particulate builder and the granular detergent component has a reserve acidity of at least 1.0 g HCl/100 g.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: October 5, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Mark William Ridyard, David William York
  • Patent number: 5961663
    Abstract: A microwave-dried amorphous alkali metal silicate detergent builder is provided characterized by a surface area of at least 20 m.sup.2 /gram and a water content of at least about 13%, by weight. The microwave-dried silicate provides effective complexation with hardness ion in wash water and more rapid solubility than conventional spray-dried silicate powders. The microwave-dried silicate can function as an efficient builder in laundry detergent compositions and over a broad range of laundry detergent applications.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: October 5, 1999
    Assignee: Colgate-Palmolive Co.
    Inventor: Charles John Schramm, Jr.
  • Patent number: 5958865
    Abstract: A process of making a powdered detergent aggregate comprising in a single pass process the step of introducing an absorptive soda ash into an agglomerator, forming a soda ash curtain within the agglomerator, spraying a surfactant onto the soda ash curtain, forming a curtain of resultant soda ash/surfactant product, spraying a silicate thereon, and adding additional surfactant to produce a non-caking soda ash/silicate/surfactant aggregate having 40-69 weight percent soda ash, 7-14 weight percent silicate, and 14-26 weight percent surfactant having a loose bulk density of from 600-1000 g/l.
    Type: Grant
    Filed: June 20, 1997
    Date of Patent: September 28, 1999
    Assignee: FMC Corporation
    Inventors: Eric J. Kline, Jim Mahar, Anthony P. Zampirri
  • Patent number: 5958864
    Abstract: A process for producing a particulate amorphous alkali metal silicate having a molar ratio of M.sub.2 O to SiO.sub.2 of 1:1.5 to 1:3.3 bya) spray-drying an aqueous mixture of amorphous alkali metal silicate,b) impregnating the spray-dried amorphous alkali metal silicate with an aqueous dispersion or solution of detergent composition components containing at least one organic component, andc) optionally drying the impregnated amorphous alkali metal silicate.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: September 28, 1999
    Assignee: Henkel Kommandiggesellschaft auf Aktien
    Inventors: Rene-Andres Artiga Gonzalez, Hubert Freese, Manfred Greger, Kathrin Schnepp, Adolf Wiche
  • Patent number: 5955418
    Abstract: A process for preparing detergent particles containing secondary (2,3) alkyl sulfate surfactant comprises admixing secondary (2,3) alkyl sulfate surfactants with powdered detersive ingredients and admixing the resulting powder with a surfactant paste. The resulting detergent dough is extruded through an orifice and sized to provide particles. The particles are coated with a free-flow aid. The resulting detergent particles exhibit improved solubility and are especially useful in laundry detergents.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: September 21, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Takashi Kazuta, Fukuji Ebihara, Kinji Ogami
  • Patent number: 5955412
    Abstract: A powder blend of 95% Sodium metasilicate anhydrous and 5% sodium lauroyl sarcosinate which is hygroscopic. The mixture is formulated for effective use when 11.25 ounces are dissolved in one gallon of water or diluted up to six gallons of water. The constituent powders are added to the drum at their mixture ratio of 95% sodium metasilicate and 5% sodium lauroyl sarcosinate which will form the blend. The drum is resealed with the processing lid trapping only low moisture air inside. The drum is relocated to the blending machine which rolls and tilts the drum for blending for 30 minutes at 16 rpm, which ensures complete and uniform blending of the 2 constituent powders. Next, the drum is removed from the blending machine, and the processing drum lid is removed in the process room ensuring low moisture exposure. A filling lid is installed which includes an auger feed, and the drum is rotated and placed in the filling stand. An air motor is attached to the auger.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: September 21, 1999
    Inventors: Sarah E. Post, Donald J. Ashby, Benny Surratt
  • Patent number: 5945395
    Abstract: The method for producing nonionic detergent granules includes the steps of (I) blending the following (i) to (iii): (i) at least one of a nonionic surfactant and an aqueous nonionic surfactant solution; (ii) an acid precursor of an anionic surfactant capable of having a lamellar orientation; (iii) at least one of an alkali builder and an alkali, porous oil-absorbing carrier, to give a mixture of detergent starting materials containing the nonionic surfactant as a main surfactant component; and (II) heating the mixture obtained in step (I) at least up to a temperature capable of neutralizing the acid precursor of the anionic surfactant in an agitating mixer, and granulating while tumbling the agitating mixer thereby increasing a bulk density, to give nonionic detergent granules having a bulk density of from 0.6 to 1.2 g/ml.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: August 31, 1999
    Assignee: KAO Corporation
    Inventors: Hiroyuki Yamashita, Koji Toyoda, Masaaki Sakaue, Yasuji Yamada, Teruo Kubota, Hiroshi Kogurusu
  • Patent number: 5935919
    Abstract: An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n<m .ltoreq.3n.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: August 10, 1999
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Shinomiya, Minoru Ishida, Shoji Shiraishi, Tamotsu Sobata
  • Patent number: 5935917
    Abstract: Novel chip compositions comprise specifically defined carriers; benefit agent; and thickening agent (e.g., fumed silica). Use of chips comprising excess of these carriers over benefit agent and thickening agent has been found to allow significant deposition of benefit agent without compromising processing. In a second embodiment, the invention comprises bar compositions comprising mixtures of the chips of the invention and chips containing defined surfactant systems. A process for forming the chips of the invention and a method of enhancing deposition without compromising processing using the chips of the invention are also disclosed.
    Type: Grant
    Filed: November 5, 1997
    Date of Patent: August 10, 1999
    Assignee: Lever Brothers Company
    Inventors: Terrence Farrell, Georgia Shafer, James Dalton, Mengtao He, Gregory McFann
  • Patent number: 5929020
    Abstract: An alkaline cleaning composition containing: (a) from about 0.01 to about 50% by weight of an alkyl polyglycoside of formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is a divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; (b) from about 0.05 to about 20% by weight of a silicate component; (c) from about 0.01 to about 5% by weight of a chelating agent consisting of hydroxyethylidene diphosphonic acid; and (d) remainder, water, all weights being based on the weight of the composition.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: July 27, 1999
    Assignee: Henkel Corporation
    Inventor: Stephen F. Gross
  • Patent number: 5925613
    Abstract: An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n<m.ltoreq.3n.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: July 20, 1999
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Shinomiya, Minoru Ishida, Shoji Shiraishi, Tamotsu Sobata
  • Patent number: 5919745
    Abstract: A liquid aqueous laundry detergent composition having improved cleaning properties and comprising a nonionic surfactant; about 0.25 to about 20 wt. % of an N--C.sub.8 --C.sub.20 alkyl and/or N-unsaturated C.sub.16 -C.sub.18 hydrocarbyl amine of a C.sub.1 -C.sub.7 monocarboxylic acid or salt thereof as an amphoteric surfactant; an alkaline substance in an amount sufficient to cause the wash liquor containing said detergent composition to have a pH of about 8 to about 11 determined ten minutes after the initiation of washing under standard conditions; and about 30 to about 95 wt. % of water, based on the total weight of the composition.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: July 6, 1999
    Assignee: Church & Dwight Co., Inc
    Inventors: Francis R. Cala, Charles D. Carr, John Ip
  • Patent number: 5919747
    Abstract: Preparation of secondary (2,3) alkyl sulfate particles comprises admixing secondary (2,3) alkyl sulfate surfactants with a deagglomerating agent such as zeolite or silica. The resulting powder is agglomerated with a nonionic surfactant, and formed into particles. The particles are then coated with a free-flow aid. Secondary (2,3) alkyl sulfate particles treated in this manner have improved solubility characteristics for use in laundry detergents.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: July 6, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Takashi Kazuta, Fukuji Ebihara
  • Patent number: 5916868
    Abstract: A process for preparing a free-flowing high bulk density granular laundry detergent product comprises pre-blending a powder admixture comprising (1) between about 40-90 weight percent of a water soluble detergent builder wherein at least 70 weight percent of the detergent builder is sodium carbonate, and (b) between about 0.5-10 weight percent of alkali metal chloride salt, (2) forming a builder-surfactant powder by blending the step (1) admixture with between about 5-40 weight percent of a detergent active ingredient which is a blend of sulfated ethoxylated alcohols and nonionic ethoxylated alcohols, (3) subjecting the builder-surfactant powder to treatment with water under agglomerating conditions, and (4) drying the detergent composition to provide a free-flowing granular laundry detergent product having a bulk density of at least 650 grams per liter, and in which the detergent granule surfaces are coated with a glossy shell of alkali metal salt crystallites.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: June 29, 1999
    Assignee: Church & Dwight Co., Inc
    Inventors: Louis R. Mazzola, Anthony J. Falotico
  • Patent number: 5916867
    Abstract: A process for making a detergent component having a bulk density of at least 650 g/l, which comprises the steps of:(i) forming a structured paste comprising a uniform mixture of, by weight;(a) from 5% to 40% of water;(b) from 30% to 90% of an ingredient selected from the group consisting of anionic, zwitterionic, cationic, ampholytic and nonionic surfactant; water-soluble organic polymer; and mixtures thereof;(c) from 1% to 20% of water-soluble silicate salt;(d) at least 30% of linear alkyl benzene sulphonate;in a continuous process; wherein the maximum pressure reached in step (i) is not less than 10 bar; and (ii) subsequently dispersing said structured paste with one or more builders in powder form; in a high shear mixer at a tip speed of greater than 10 meters per second; wherein the ratio of the structured paste to the builder powder is from 9:1 to 1:5.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: June 29, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Yousef Georges Aouad, Hayden Guy William Dickenson
  • Patent number: 5916861
    Abstract: A stripping composition which does not contain methylene chloride or methyl ethyl ketone is comprised of 25% acetone, 16% toluene, 25% ethyl 3 ethoxypropionate, 30% methanol and 4% paraffin wax sealer. The stripping composition may be thickened with Methocel 311. The presence of methanol in the composition greatly enhances the stripping effects of ethyl 3 ethoxypropionate and the thickening effects of Methocel 311. The composition is suitable for application in a number of forms including as a semipaste and as a liquid.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: June 29, 1999
    Inventor: Walter J. Lyssy
  • Patent number: 5902415
    Abstract: An alkali metal cleaning composition for cleaning metal and for inhibiting corrosion of metal. The composition is composed of an alkali carbonate salt, a surfactant, and a corrosion inhibitor. A preferred corrosion inhibitor is an alkali metal silicate. Additional metal corrosion inhibitors such as a combination of a triazole compound and an alkali metal borate also can be employed. Such alkali carbonate compositions are readily water soluble and remain in solution over prolonged storage periods.
    Type: Grant
    Filed: January 29, 1998
    Date of Patent: May 11, 1999
    Assignee: Church & Dwight Co., Inc.
    Inventors: Steven Dunn, Gale A. Byrnes
  • Patent number: 5902781
    Abstract: Composite particles comprise a bleach catalyst plus one or more detersive enzymes. The particles are especially useful in automatic dishwashing compositions. Thus, a cobalt (III) or manganese (III) bleach catalyst is combined with protease or amylase enzymes and a carrier. The resulting particles are used in combination with perborate or percarbonate bleach to clean dishware in an automatic machine.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: May 11, 1999
    Assignee: The Procter & Gamble Company
    Inventor: Jeffrey Donald Painter
  • Patent number: 5900399
    Abstract: A tablet composition containing 2% to 100% by weight of amorphous crystalline or partly crystalline layer-form sodium silicates corresponding to the formula Na.sub.2 Si.sub.x --O.sub.2x+1.yH.sub.2 O wherein x is a number of 1.9 to 4 and y is a number of 0 to 20, with the proviso that the tablet composition only contains water in a quantity such that the maximum theoretical water-binding capacity of the components of the composition is not exceeded.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: May 4, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Seiter, Dieter Jung, Otto Koch, Birgit Stevermann
  • Patent number: 5898024
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: April 27, 1999
    Assignee: Charvid Limited Liability
    Inventor: Charles Bullick Talley
  • Patent number: 5895637
    Abstract: The invention relates to a process for preparing sodium disilicate in the .beta. form having a high ion-exchange capacity and a molar ratio Na.sub.2 O:SiO.sub.2 of about 1:2 from a silicate source and sodium hydroxide solution at elevated temperature, with the product formed being separated off by filtration, wherein the product is further heat treated at from 450.degree. to 780.degree. C. and/or is pressed to form compact parts.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: April 20, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jan Wilkens, Gunther Schimmel, Alexander Tapper
  • Patent number: 5888950
    Abstract: An aqueous composition for cleaning contact lenses comprises an aliphatic monohydric alcohol, a surface active agent having cleaning action for contact lens deposits, and an abrasive agent.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: March 30, 1999
    Assignee: Wilmington Partners LP
    Inventors: Chimpiramma Potini, Stanley J. Wrobel
  • Patent number: 5867937
    Abstract: A novel and improved method for relieving hydrophobicity of peat moss, bark and rockwool used in horticultural media for plant propagation using an effective level of a composition consisting of certain copolymerized alkane oxides is described. A more effective method of delivering these materials based on a composition of hydrous, amorphous silica using the compositions of the present invention is described.
    Type: Grant
    Filed: June 24, 1997
    Date of Patent: February 9, 1999
    Assignee: Smithers-Oasis Company
    Inventor: Andrew Robert Templeton
  • Patent number: 5863345
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled surfaces such as food fryers, baking pans, high temperature pasteurizers, beer kettles and similar equipment that normally requires caustic soda based cleaners to clean. The present invention is also useful in cleaning ceramics such as restaurant grade ceramic china plates and platters. The present invention is particularly useful in cleaning brass and aluminum parts and equipment without causing corrosion damage. Further, since the cleaning composition of the present invention is not based on caustic soda, the composition is not considered hazardous. Further, the cleaning composition of the present invention dissolves readily in water, providing a solution that can be used in mechanical sprayers, soak-tanks and clean-in-place equipment. Also the cleaning composition may be effectively used at lower temperatures than caustic cleaning agents.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: January 26, 1999
    Assignee: Charvid Limited Liability Company
    Inventor: Charles Bullick Talley
  • Patent number: 5858279
    Abstract: A defoaming composition comprising about 1 to about 90% by weight of a mixture of at least three defoaming agents, (a), (b), and (c) and about 99 to about 10% by weight of at least two stabilizers (d) and (e) therefor, and optionally a carrier therefor, where defoamer (a) is selected from a hydrophilic, fumed, particulate silica; defoamer (b) is an ethylene oxide-propylene oxide block copolymer; and defoamer (c) is a linear alcohol alkoxylate mixture of poly(oxyethylene/polyoxypropylene) mono- C.sub.6, C.sub.8, and C.sub.10 alkyl ethers; stabilizer (d) is an ethoxylated C.sub.12-18 fatty alcohol having a molecular weight of about 820; and stabilizer (e) is a cross-linked (meth)acrylic acid polymer.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: January 12, 1999
    Assignee: Church & Dwight Co., Inc
    Inventors: Michael S. Lunski, Steven A. Bolkan
  • Patent number: 5854192
    Abstract: In order to provide a particulate zero-phosphate laundry detergent composition with reduced tendency to agglomeration, the composition comprises:i) from 30 to 80 wt % of a granular base powder comprising:a) from 5 to 60 wt % (based on the composition) of organic surfactant, andb) from 10 to 80 wt % (based on the composition) of alkali metal aluminosilicate detergency builder,ii) from 1 to 5 wt % of sodium silicate not within the granular base powder,wherein the sodium silicate (ii) is all present in the form of separate cogranules consisting essentially of sodium silicate and sodium carbonate in a ratio within the range of from 3:1 to 1:3, and where the tendency of the composition to form granules having a particle size of 2000 .mu.m or larger on storage is less than if the sodium silicate (ii) were present in the form of separate granules of sodium disilicate.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: December 29, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventor: Jelles Vincent Boskamp
  • Patent number: 5854198
    Abstract: In order to enhance the stability of sodium percarbonate bleach in particulate detergent compositions, crystalline aluminosilicate and a water-soluble alkali metal silicate in an amount of from 1-20% by weight based on the aluminosilicate are included in the non-spray dried base powder. In order to obtain the stabilizing effect, the crystalline aluminosilicate comprises zeolite MAP or the alkali metal silicate is homogeneously dispersed with respect to the aluminosilicate.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: December 29, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Peter Willem Appel, Theodorus Johannes Arts, Jelles Vincent Boskamp, Andrew Paul Chapple, Fredericus Cornelis Dobbe, Christophe Michel Joyeux, Carolyn Angela Lanceley, Edwin Leo Lempers, Theo Jan Osinga
  • Patent number: 5851715
    Abstract: The invention relates to a process for the silylation of very finely divided inorganic oxides, in which the very finely divided inorganic oxides are treated with at least one silylating agent which is relatively nonvolatile in the temperature range of the overall process, with the proviso that the relatively nonvolatile silylating agent is admixed with the very finely divided inorganic oxides as a liquid, in the form of a very finely atomized aerosol. Furthermore, the invention relates to a highly apolar, pyrogenic silica prepared by this process.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: December 22, 1998
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Barthel, Mario Heinemann, Franz Herrmann, August Altenbuchner
  • Patent number: 5821208
    Abstract: Printing applicators such as metal stencils and screens used to apply solder paste to printed circuit boards are cleaned to remove accumulated solder paste therefrom by an aqueous alkaline salt cleaner. The aqueous cleaner of the present invention comprises alkaline salts such as alkali metal carbonates, a surfactant formulation which contains at least one nonionic surfactant, an alkali metal silicate corrosion inhibitor and stabilizers to maintain the components in aqueous solution. The cleaner of the present invention contains no VOCs and is an effective and safe replacement for alcohol solvents previously used to clean solder paste from screens and stencils.
    Type: Grant
    Filed: September 24, 1996
    Date of Patent: October 13, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Richard A. Reynolds, Eric E. Eichhorn
  • Patent number: 5821207
    Abstract: The method for producing a fine solid builder particle includes the steps of suspending a solid builder in a dispersion medium containing 20 to 100% by weight of a surfactant, and carrying out wet grinding of the solid builder. The builder composition containing the fine solid builder particle is obtainable by the above method. The detergent composition containing the fine solid builder particle is obtainable by the method. The method for producing a detergent composition includes the steps of carrying out wet grinding of a solid builder using a dispersion medium containing a surfactant to give a mixture of a fine solid builder particle and the surfactant, and further adding the mixture to a composition for a detergent.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: October 13, 1998
    Assignee: Kao Corporation
    Inventors: Hiroyuki Kanai, Mikio Sakaguchi, Shu Yamaguchi
  • Patent number: 5814597
    Abstract: The invention relates to a solid material (primary drying product) containing alkali metal silicate with a modulus (molar ratio of SiO.sub.2 to M.sub.2 O, M=alkali metal) of 0.8 to 4 in homogeneous admixture with other inorganic and/or organic useful materials and/or auxiliaries, which has been dried from a finely sprayed aqueous preparation of mixtures of the alkali metal silicates and the inorganic and/or organic useful materials and/or auxiliaries by means of a hot gas stream. The solid material according to the invention is characterized in that, as a primary drying product in homogeneous admixture with the alkali metal silicate, it contains at least 10% by weight of water-soluble inorganic and/or organic salts, has apparent densities of at least 150 g/l, possesses a microporous absorbent internal structure and has been dried with superheated steam as the hot gas stream.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: September 29, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wilfried Raehse, Johann F. Fues, Kathleen Paatz, Wilhelm Beck, Wolfgang Hlavacek
  • Patent number: 5814289
    Abstract: Cogranulates of high bulk density which easily disintegrate in water and comprise aluminosilicates and crystalline sodium silicates having a layered structure. The aluminosilicates contained therein are those of the formulaM.sub.2/n O.Al.sub.2 O.sub.3. XSiO.sub.2. yH.sub.2 Oin which M is an alkali metal or alkaline earth metal, n indicates the valency of the cation, x is.gtoreq.2 and y has a value of between 0 and 8. The sodium silicates have an SiO.sub.2 /Na.sub.2 O ratio of (1.8 to 4.2):1. These cogranulates are prepared by mixing the pulverulent aluminosilicates and sodium silicates with one another and introducing the mixture into a zone in which it is compacted between two rolls rotating in opposite directions to form a compact. After comminution of the compact, the desired particle sizes are finally separated off from the oversize and undersize material. The cogranulates can be used in detergents and cleaning agents.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: September 29, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Alexander Tapper, Gunther Schimmel, Gerd Wingefeld, Hans-Peter Rieck
  • Patent number: 5801137
    Abstract: A detergent composition containing in combination(a) a detergent builder system containing a carboxylate or polycarboxylate builder and having a major proportion by weight of non-carbonate builder compound;(b) an organo diphosphonic acid or its salts or complexes or any mixture thereof; and(c) an organic polymer containing acrylic acid or its salts, having an average molecular weight of less than 15,000.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: September 1, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Michael Crombie Addison, Lynda Anne Jones, Rhona Alexandra Knox
  • Patent number: 5798328
    Abstract: A detergent composition containing surfactants selected from anionic, cationic, nonionic, amphoteric and zwitterionic surfactants and a builder component containing 40% to 80% by weight of amorphous alkali metal silicates and 10% to 40% by weight of alkali metal carbonates in the form of a compound, with the proviso that the alkali metal carbonate content is always greater than the alkali metal silicate content, and at most 25% by weight of water, and wherein the compound does not have a homogeneous surface nor a uniform particle size distribution.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: August 25, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Beatrix Kottwitz, Joerg Poethkow, Horst Upadek
  • Patent number: 5789361
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: August 4, 1998
    Assignee: Charvid Limited Liability Co.
    Inventor: Charles Bullick Talley
  • Patent number: 5786314
    Abstract: Automatic dishwashing detergent compositions comprising a weight to weight ratio of calcium complexing component to carbonate source of at least 0.9 and having a pH between about 7 and about 11 are disclosed. The compositions exhibit enhanced filming performance, particularly preferred compositions additionally contain polymer dispersant and silicate.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: July 28, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Eugene Steven Sadlowski
  • Patent number: 5786315
    Abstract: Automatic dishwashing detergent compositions comprising a carbonate source and a pH from about 5.0 to about 9.5 for enhanced filming performance are disclosed. Particularly preferred compositions contain polymer dispersant and silicate.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: July 28, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Eugene Steven Sadlowski
  • Patent number: 5786317
    Abstract: A stain remover composition and method of use which selectively reduces food and beverage dyes in carpet stains without causing fading or discoloration of carpet dyes present in carpet fibers. The stain remover composition comprises generally between approximately 0.1 weight percent and approximately 2 weight percent of alkali metal silicate, between approximately 4 weight percent and approximately 12 weight percent of water soluble alcohol, between approximately 1 weight percent and approximately 5 weight percent of sequestering agent, between approximately 0.1 weight percent and approximately 2 weight percent of surfactant, between approximately 4 weight percent and approximately 12 weight percent of sodium bisulfite or other mild reducing agent, and the remainder water. The stain remover composition is generally prepared and stored as two separate solutions, with one solution containing the reducing agent and the other solution containing the remaining ingredients.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: July 28, 1998
    Inventor: Clint E. Townsend
  • Patent number: 5783536
    Abstract: An extruded toilet bar composition comprises mixtures of chips containing polyalkylene glycol, benefit agent and fumed silica, and chips containing a surfactant system.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: July 21, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Terence Farrell, Georgia Shafer, James Dalton
  • Patent number: 5783543
    Abstract: A carpet cleaning composition comprising: (a) a powder-form solid adsorbent; (b) rollable particles of porous material, each particle having a length greater than 1 mm, and a diameter equal to at least 10% of the length of the particle; and (c) water.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: July 21, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Theo Fleckenstein, Alexander Ditze, Franz Kresse, Thomas Hahn
  • Patent number: 5776893
    Abstract: A crystalline hydrated layered sodium and potassium silicate/amorphous sodium and potassium silicate composite material with predetermined hardness ion sequestration properties is achieved by controlling the process for forming the material. The process for producing the crystalline hydrated layered sodium and potassium silicate/amorphous is sodium and potassium silicate composite comprises hydrolyzing DB-1 crystalline sodium and potassium silicate glasses as a precursor material to produce the composite material known as DB-2. Hydrolysis of the DB-1 precursor material is achieved by adding typically up to 100.0 milliequivalents per gram of H.sub.3 O.sup.+ ions or up to 50 milliequivalents per gram of OH.sup.- ions. The resulting DB-2 material can sequester CA.sup.2+ ions, Mg.sup.+ ions, or both, depending on the results desired, processing conditions, and starting materials used.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 7, 1998
    Assignee: PQ Corporation
    Inventors: Eric Von Rehren Borgstedt, Raymond P. Denkewicz, Jr.
  • Patent number: 5770548
    Abstract: Disclosed are hard surface cleaners such as glass window cleaners. A silicate/hydrophobic acrylic polymer/surfactant composition is used to reduce water spotting, filming or streaking. These cleaners can also include a base and a sequestrant.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: June 23, 1998
    Assignee: S. C. Johnson & Son, Inc.
    Inventors: James J. Leskowicz, Marygrace G. Horner