Aluminum Or Boron Containing Metal Silicate Component (e.g., Aluminosilicate, Zeolite, Etc.) Patents (Class 510/532)
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Patent number: 12035719Abstract: The present invention relates to zeolites modified or functionalized with silane moieties, to compositions comprising said silane modified zeolites and to their use as antiviral and/or antibacterial agents. The invention also refers to materials and/or articles, such as, but not limited to, fabrics, fibers and/or polymeric coatings partly or fully covered and/or integrated with said silane-modified zeolites and/or compositions.Type: GrantFiled: November 16, 2021Date of Patent: July 16, 2024Assignee: SAES Getters S.p.A.Inventors: Paolo Vacca, Miriam Riva, Katarzyna Fidecka
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Patent number: 11591231Abstract: An organotemplate-free synthetic process for the production of a zeolite of TON framework type structure is provided. The process includes the steps of: (1) preparing a mixture comprising: (a) an alumina-coated silica; (b) a source of an alkali metal; (c) an alcohol; (d) a source of hydroxide ions; (e) seed crystals comprising a zeolitic material having a TON framework type structure; and (f) water; and (2) crystallizing the mixture obtained in step (1).Type: GrantFiled: June 25, 2021Date of Patent: February 28, 2023Assignee: CHEVRON U.S.A. INC.Inventors: Joel Edward Schmidt, Adeola Florence Ojo, Cong-Yan Chen
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Patent number: 8975056Abstract: Alpha-amylases from Bacillus subtilis (AmyE), variants thereof, nucleic acids encoding the same, and host cells comprising the nucleic acids are provided. Methods of using AmyE or variants thereof are disclosed, including liquefaction and/or saccharification of starch. Such methods may yield sugars useful for ethanol production or high fructose corn syrup production. In some cases, the amylases can be used at low pH, in the absence of calcium, and/or in the absence of a glucoamylase.Type: GrantFiled: October 25, 2012Date of Patent: March 10, 2015Assignee: Danisco US Inc.Inventors: Luis G. Cascao-Pereira, William A. Cuevas, David A. Estell, Sang-Kyu Lee, Scott D. Power, Sandra W. Ramer, Amr Toppozada, Louise Wallace
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Patent number: 8859487Abstract: A perfume tester or perfume includes a granule containing a friable peripheral portion incorporating fragrant compounds, which disintegrates as a perfumed powder when the granule is applied onto the skin. A method for making the perfume tester or perfume is by granulation, and the granule can be used in particular for perfume testing.Type: GrantFiled: July 30, 2007Date of Patent: October 14, 2014Assignee: Laboratoires Docteur Gaetano ZanniniInventors: Jean-Pierre Mathonnet, Gaetano Zannini
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Patent number: 8729008Abstract: The invention relates to solubilizers for metal ions and poorly soluble metal compounds, containing an oxidation product of starch hydrolysate as a solubilizing agent, to a method for solubilizing metal ions and to the use of said solubilizer.Type: GrantFiled: October 19, 2009Date of Patent: May 20, 2014Assignee: Suedzucker Aktiengesellschaft Mannheim/OchsenfurtInventors: Alireza Haji Begli, Markwart Kunz, Christine Kroener, Matthias Moser, Bart Levecke
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Patent number: 8680031Abstract: Exfoliating compositions, such as soaps, scrubs, and muds, for conditioning skin. The compositions include a carrier and particles that are insoluble in the carrier. The carrier may include one of more of a surfactant and an emollient, among other ingredients. The particles preferably include calcium carbonate, one or more phyllosilicates, and a quartz group tectosilicate, preferably have a calcium carbonate equivalent of less than 90%, and preferably embody a schistose texture. The exfoliating compositions with such particles have unexpected moisturizing and skin-conditioning properties.Type: GrantFiled: March 13, 2013Date of Patent: March 25, 2014Assignee: Roanoke CollegeInventor: DorothyBelle Poli
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Patent number: 8618039Abstract: A granular material for use in the treating of textile materials, comprising (i) a silicone material having at least one nitrogen containing substituent, (ii) an aluminosilicate carrier and (iii) a binder, preferably in conjunction with a surface active material. Also described is a process for preparing such granular materials, which comprises forming a water-in-oil emulsion of component (i) in conjunction with component (iii) by dispersing and agitating said components in water, followed by depositing said emulsion onto a free flowing powder form of component (ii), for example by spraying, and removing sufficient water from the product to obtain a free flowing granular material. The granules are useful in a process of treating textile materials in an aqueous medium, particularly where the textile material is denim. Preferably the granular material is added into the finishing steps of denim such as the desizing, the fading or the softening steps and helps with avoiding backstaining.Type: GrantFiled: December 11, 2007Date of Patent: December 31, 2013Assignees: Dow Corning India, Dow Corning CorporationInventors: Ganesh Srinivasan, Anick Colson, Alice Devinat, Jacqueline L'Hostis, Padmadas Nair
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Patent number: 8323945Abstract: Alpha-amylases from Bacillus subtilis (AmyE), variants thereof, nucleic acids encoding the same, and host cells comprising the nucleic acids are provided. Methods of using AmyE or variants thereof are disclosed, including liquefaction and/or saccharification of starch. Such methods may yield sugars useful for ethanol production or high fructose corn syrup production. In some cases, the amylases can be used at low pH, in the absence of calcium, and/or in the absence of a glucoamylase.Type: GrantFiled: June 5, 2009Date of Patent: December 4, 2012Assignee: Danisco US Inc.Inventors: Luis G. Cascao-Pereira, William A. Cuevas, David A. Estell, Sang-Kyu Lee, Scott D. Power, Sandra W. Ramer, Amr Toppozada, Louise Wallace
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Patent number: 8318652Abstract: This invention relates to non-bleeding and quick color releasing colored speckles for use in granular laundry detergents and other consumer products. The speckles are comprised of a porous carrier, a releasing agent, and a coloring agent.Type: GrantFiled: August 6, 2010Date of Patent: November 27, 2012Assignee: Milliken & CompanyInventors: Gregory Fernandes, Eduardo Torres
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Publication number: 20100261633Abstract: Detergent builder granules containing (component A) a water-soluble inorganic salt containing an inorganic salt having and/or being capable of forming a hydrate crystal and (component B) a clay mineral, wherein the component B is contained in an amount of 60% by weight or less, the component A and the component B are in a weight ratio, i.e. A/B, calculated as an anhydrate, of from 5/95 to 80/20, and a percentage of water loss upon heating to a temperature of 200° C. is from 3 to 30% by weight. According to the present invention, the detergent builder granules for laundry detergents having excellent dispersibility in cold water and a detergent composition containing the detergent builder granules can be obtained.Type: ApplicationFiled: October 20, 2008Publication date: October 14, 2010Inventors: Kazuo Oki, Toshima Kume, Motomitsu Hasumi, Tadanobu Asada, Yuya Kozaki, Jun Kozuka
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Patent number: 7638476Abstract: Aqueous washing and cleaning agents that contain capsules in addition to other constituents, the capsules each encompassing an active ingredient in a matrix. The introduction of a combination of aluminum silicate and silicic acid into the matrix improves the solubility characteristics of the capsules in a washing operation.Type: GrantFiled: February 8, 2008Date of Patent: December 29, 2009Assignee: Henkel AG & Co. KGaAInventors: Bernhard Orlich, Bernd Richter, Sören Hölsken, Stefan Van Der Burgh
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Patent number: 7637271Abstract: A cleaning composition with a limited number of ingredients contains a polyaluminum compound and surfactant. The cleaning composition optionally has an additional amount of fragrance. The cleaning composition optionally has a small amount of solvent. The cleaning composition optionally comprises a comprises a group selected from the group consisting of a dye, a builder, a fatty acid, a colorant, a preservative, a chelating agent, a colloidal silica and mixtures thereof.Type: GrantFiled: October 30, 2008Date of Patent: December 29, 2009Assignee: The Clorox CompanyInventors: Scott Cumberland, Maria Ochomogo
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Patent number: 7585825Abstract: Particles which comprise a specified inorganic carrier material, perfume and nonionic surfactant(s) in quantities of at least 0.1% by weight, a method for producing the particles, a detergent composition comprising the particles, and a method for washing textiles with the aid of the detergent composition.Type: GrantFiled: October 10, 2006Date of Patent: September 8, 2009Assignee: Henkel AG & Co. KGaAInventors: Rene-Andres Artiga Gonzalez, Stefan Hammelstein, Hubert Harth, Jürgen Hilsmann, Mario Sturm, Andreas Bauer, Wolfgang Lahn
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Patent number: 7560093Abstract: The present invention provides a process for the preparation of detergent builder Zeolite-A from Kimberlite tailing generated as solid waste during diamond mining is disclosed. The process comprises, reacting an acid treated Kimberlite tailing with alkali solution to obtain sodium silicate and reacting it with alkaline aluminum source at room temperature and crystallizing at higher temperature to obtain Zeolite-A. The product is useful as builder in detergent formulation.Type: GrantFiled: January 18, 2008Date of Patent: July 14, 2009Assignees: Council of Scientific and Industrial Research, National Mineral Development Corporation LimitedInventors: Raksh Vir Jasra, Rajesh Shantilal Somani, Haresh Mahipatlal Mody, Hari Chand Bajaj, Jatin Rameshchandra Chunawala, Hemal Ranpara, Dipti Barochiya, Devendra Ghelani, Suresh Chandra, Maharaj Kishen Dhar, Keshav Rao, Kamlesh Kumar
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Patent number: 7517366Abstract: A multiuse laundry cleaning device in a solid state containing a homogeneous quantity of cleaning agent configured to dissolve and release a substantially consistent quantity of cleaning agent over a plurality of laundry wash and rinse cycles. The cleaning agent includes a gas-releasing component, potassium silicate as a solubility control component to limit the solubility of the cleaning agent, an alkalinity agent as a pH regulator, and a water softener to solvate metal ions in a solution of water. Controlled dissolution of the cleaning agent composition releases a desired quantity of cleaning agent in each cleaning cycle over a plurality of cycles. A porous covering of bag may be disposed around the solid cleaning agent.Type: GrantFiled: February 10, 2005Date of Patent: April 14, 2009Assignee: Eco-Safe Technologies, LLCInventors: K. Donald Evans, Cory E. Cook, Eddie Caruthers, Jr.
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Patent number: 7517848Abstract: A multiuse cleaning device in a solid state containing a homogeneous quantity of cleaning agent configured to dissolve and release a substantially consistent quantity of cleaning agent over a plurality of wash and rinse cycles. The cleaning agent includes a gas-releasing component and potassium silicate as a solubility control component to limit the solubility of the cleaning agent. The cleaning agent may include other ingredients such as an alkalinity agent as a pH regulator, a water softener to solvate metal ions in a solution of water, an optical brightener, an anti-redeposition agent, fragrances, surfactants, and other ingredients. Controlled dissolution of the cleaning agent composition releases a desired quantity of cleaning agent in each cleaning cycle over a plurality of cycles. A porous enclosure may be disposed around the solid cleaning agent.Type: GrantFiled: September 27, 2006Date of Patent: April 14, 2009Assignee: Eco-Safe Technologies, LLCInventors: K Donald Evans, Cory E. Cook
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Patent number: 7470654Abstract: The present invention relates to a detergent auxiliary composition comprising: (i) a liquid or liquefiable active component; and (ii) a water-insoluble solid support component and (iii) a water-soluble and/or water dispersible encapsulating material; and (iv) optionally one or more adjunct components, characterised in that the composition further comprises (v) a surface deposition enhancing cationic polymer or oligomer having cationic groups such that fewer than 50% are de-activated when a 1% by weight solution of the polymer or oligomer (prepared in deionised water and then adjusted to pH 7.0 with sodium carbonate or citric acid) is stored at 25° C.Type: GrantFiled: September 6, 2005Date of Patent: December 30, 2008Assignee: The Procter & Gamble CompanyInventors: Fabrizio Meli, Andre Chieffi, Rebecca Louise Selway, Stefan Frenzel
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Patent number: 7211555Abstract: A process for efficiently preparing fine zeolite particles comprising synthesizing zeolite in the presence of an alkaline earth metal-containing compound and/or with controlling the preparation process of zeolite, thereby giving fine zeolite particles being composed of crystalline aluminosilicate, the fine zeolite particles having a fine average primary particle size, being excellent in the cationic exchange properties and the oil-absorbing ability, having a fine average aggregate particle size, and being excellent in the dispersibility; fine zeolite particles obtainable by the above process; and a detergent composition comprising the fine zeolite particles, the detergent composition being excellent in the detergency.Type: GrantFiled: September 30, 2004Date of Patent: May 1, 2007Assignee: Kao CorporationInventors: Kazuo Oki, Hiroji Hosokawa, Mikio Sakaguchi, Hiroshi Kitagaito, Kazuo Taguchi, Hitoshi Takaya
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Patent number: 7105477Abstract: The liquid detergent composition is provided with a high detergency and ensuring a good dispersion stability of builder particles and comprises a liquid dispersion containing (a) 30 mass % or more of a specific inorganic builder particle and (b) a block or graft polymer having a carboxyl group (i) and a polymer chain (ii), having, as its structural unit, an alkyleneoxy group, the composition having a viscosity (25° C.) of 3000 mPa·s or less and a volumetric separation rate (25° C., allowed to stand for 30 days) of 5% or less.Type: GrantFiled: May 7, 2002Date of Patent: September 12, 2006Assignee: Kao CorporationInventors: Osamu Takiguchi, Koji Yui, Takashi Oda
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Patent number: 6964945Abstract: The invention relates to solid detergent compositions comprising an aluminosilicate builder and an anionic surfactant and comprising (n) components (i), n being at least 2, whereby the level of aluminosilicate builder in said components together is at least 5% by weight of the composition and the level of the anionic surfactant in said components together is at least 5% by weight of the composition, and whereby the degree of mixture (M) of the anionic surfactant and the aluminosilicate builder is from 0 to 0.7, as defined in the description.Type: GrantFiled: September 25, 1998Date of Patent: November 15, 2005Assignee: The Procter & Gamble CompanyInventors: Richard Timothy Hartshorn, Zayeed Alam, Kevin Norwood
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Patent number: 6908895Abstract: A particulate zeolite-built laundry detergent composition having a bulk density of at least 550 g/l comprising at least two different granular components containing both surfactant and builder, preferably one prepared by non-tower granulation and another spray-dried, also contains from 1 to 10 wt % citric acid admixed as a separate particulate component. The admixed citric acid improves dispensing and dissolution properties, whether or not separately admixed sodium carbonate is present.Type: GrantFiled: May 14, 2002Date of Patent: June 21, 2005Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Vera Johanna Bakker, Arie Krijgsman, Edwin Leo Lempers, Jasper Mol
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Patent number: 6893632Abstract: A regimen for hunting includes using a number of zeolite-containing personal items in connection with a hunter's apparel and body to reduce the hunter's scent for improved hunting. The personal items include mouthwash, deodorant/anti-perspirant, body and boot powder, bar and liquid soap for cleansing the body and hair, laundry detergent and dryer sheets. Each of the personal items includes an effective amount of zeolite, so that use of the personal items reduces the available scent to be detected by animals in the wild. The regimen can also include the use of a seat cushion that is covered with an activated carbon-containing fabric for odor control and/or elimination.Type: GrantFiled: May 9, 2002Date of Patent: May 17, 2005Inventor: Louis B. Johnson
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Patent number: 6894016Abstract: To present a liquid detergent of a high cleaning power and an excellent storage stability while maintaining the ease of use. A liquid detergent composition comprising, at a specific ratio individually, (a) water, (b) a builder composed of a water-soluble inorganic salt of which solubility in distilled water is 0.5 g/15 g (25° C., distilled water) or more, and (c) a substance liquid at 25° C. containing at least one selected from the group consisting of surfactant (c1) and water-miscible organic solvent (c2) in which part of (b) is present in solid state in the composition, and its electric conductivity measured by a specific method is within a specified range.Type: GrantFiled: May 8, 2002Date of Patent: May 17, 2005Assignee: Kao CorporationInventors: Akira Ishikawa, Toshio Miyake, Kazutoshi Ide
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Patent number: 6894019Abstract: Base particles for supporting a surfactant, obtainable by a step of spray-drying a slurry comprising (A) a zeolite having an average aggregate particle diameter of 15 ?m or less and a variation coefficient of a distribution of an aggregate particle diameter of 29% or less, (B) a water-soluble polymer; (C) a water-soluble salt, and (D) a surfactant in an amount of 5% by weight or less of the slurry; detergent particles comprising the base particles; and a zeolite for a laundry detergent, wherein the zeolite has an average aggregate particle diameter of 15 ?m or less and a variation coefficient of a distribution of an aggregate particle diameter of 29% or less; and a process for preparing base particles for supporting a surfactant, comprising a step of spray-drying a slurry comprising a zeolite (A) having an average aggregate particle diameter of 15 ?m or less and a variation coefficient of a distribution of an aggregate particle diameter of 29% or less, a water-soluble polymer (B), a water-soluble salt (C), anType: GrantFiled: December 18, 2001Date of Patent: May 17, 2005Assignee: Kao CorporationInventors: Kazuo Oki, Hiroji Hosokawa, Shu Yamaguchi, Kimihiro Mizusawa
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Patent number: 6831056Abstract: A process for efficiently preparing fine zeolite particles comprising synthesizing zeolite in the presence of an alkaline earth metal-containing compound and/or with controlling the preparation process of zeolite, thereby giving fine zeolite particles being composed of crystalline aluminosilicate, the fine zeolite particles having a fine average primary particle size, being excellent in the cationic exchange properties and the oil-absorbing ability, having a fine average aggregate particle size, and being excellent in the dispersibility; fine zeolite particles obtainable by the above process; and a detergent composition comprising the fine zeolite particles, the detergent composition being excellent in the detergency.Type: GrantFiled: July 6, 2001Date of Patent: December 14, 2004Assignee: Kao CorporationInventors: Kazuo Oki, Hiroji Hosokawa, Mikio Sakaguchi, Hiroshi Kitagaito, Kazuo Taguchi, Hitoshi Takaya
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Patent number: 6784149Abstract: The invention relates to laundry detergents and cleaners comprising microdisperse, hydrophilic silicate-containing particles. The particle diameter of the particles is preferably 1 to 500 nm. The addition of the silicate-containing particles leads to improved soil release with a simultaneous reduction in the tendency for resoiling.Type: GrantFiled: December 12, 2001Date of Patent: August 31, 2004Assignee: Clariant GmbHInventors: Harald Bauer, Günther Schimmel
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Patent number: 6773693Abstract: A fine A-type zeolite particle having an average primary particle size of 0.1 &mgr;m or less and a variation coefficient of 90% or less, wherein a ratio of a peak area above a background level to all peak are in the range of 2&thgr;=20° to 40° in a powder X-ray diffraction spectrum of said fine A-type zeolite particle is 30% or more; a process for preparing the fine A-type zeolite particle, comprising reacting a silica source with an aluminum source in the presence of an organic compound having an oxygen-containing functional group and a molecular weight of 100 or more; and a detergent composition comprising a surfactant and the fine A-type zeolite particle. The fine zeolite particle is suitably used for detergent builders, water treatment agents, fillers for paper, resin fillers, oxygen-nitrogen separating agents, adsorbents, catalyst carriers, soil improvers for gardening, polishing agents, and the like.Type: GrantFiled: August 9, 2002Date of Patent: August 10, 2004Assignee: Kao CorporationInventors: Hiroji Hosokawa, Kazuo Oki
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Patent number: 6743766Abstract: The invention relates to a sparingly soluble alkali metal silicate which comprises alkali metal phyllosilicate in finely divided form in a non-phyllosilicatic alkali metal silicate environment of the formula x MI2O.y SiO2, in which MI is an alkali metal and y/x (1.9 to 500): 1; a process for its preparation and its use in detergents and cleaners.Type: GrantFiled: September 11, 2000Date of Patent: June 1, 2004Assignee: Clariant GmbHInventors: Harald Bauer, Josef Holz, Guenther Schimmel, Alexander Tapper
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Patent number: 6699831Abstract: The present invention provides a liquid detergent composition being excellent in detergency and dispersion stability and a process for producing the same. The invention provides a liquid detergent composition having a degree of separation by volume of 5% or less after storage for 1 month at 25° C., comprising a liquid phase as the phase (a), a polymeric dispersant as the component (b)] and at least one selected from the group consisting of a crystalline silicate compound and an aluminosilicate compound as the component (c), wherein the component (b) has a cation exchange capacity of not less than 120 CaCO3 mg/g when the water content of the composition is 5% by weight or less and then the aluminosilicate compound only is used as the component (c) or when the water content of the composition is larger than 5% by weight.Type: GrantFiled: June 7, 2001Date of Patent: March 2, 2004Assignee: Kao CorporationInventors: Tomoe Takano, Koji Yui, Takashi Oda, Akira Ishikawa, Osamu Takiguchi
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Patent number: 6693071Abstract: Rinse aid materials for coating, coating compositions, methods and articles of manufacture for use in automatic dishwashing appliances comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of dishware surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of rinse aid surface coating compositions, methods and articles of manufacture that create multi-use benefits to modified dishware surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that include at least one of the following improved surface properties: wetting and sheeting, uniform drying, anti-spotting, anti-staining, anti-filming, self cleaning, and durability benefits, relative to dishware surfaces unmodified with such nanoparticle systems.Type: GrantFiled: December 13, 2001Date of Patent: February 17, 2004Assignee: The Procter & Gamble CompanyInventors: Chanchal Kumar Ghosh, William Michael Scheper, Robert Henry Rohrbaugh, Michael Ray McDonald, John David Carter, Eugene Paul Gosselink
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Patent number: 6673766Abstract: The invention relates to detergent compositions comprising from 10-60 wt % of a surfactant system and having a maximum Residues Index of 25 and a maximum Secondary Residues Index of 15. The detergents claim provide good performance in the wash based on the quantities of detergent components in the compositions.Type: GrantFiled: July 11, 2001Date of Patent: January 6, 2004Assignee: The Procter & Gamble CompanyInventors: Richard Timothy Hartshorn, Zayeed Alam, Sylvestre Canceil, Alan Thomas Brooker, Gerard Marcel Baillely, Kevin Norwood, David Scott Bohlen
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Patent number: 6660713Abstract: Cleaning and deodorizing compositions comprising hydrophobic, nanozeolites for odor control on substrates are disclosed. Specifically, cleaning and deodorizing compositions for malodor control comprising nanozeolites and methods for removing odors from substrates using said compositions are disclosed.Type: GrantFiled: January 30, 2001Date of Patent: December 9, 2003Assignee: The Procter & Gamble CompanyInventors: John David Carter, Robert Corkery, Jun Ma, Robert Henry Rohrbaugh
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Patent number: 6624132Abstract: The present invention relates to a liquid enzyme cleaning composition in which the enzyme is stable at alkaline pH and in the presence of water at concentrations of at least about 50 to about 60 weight percent. In one embodiment, the composition of the invention stabilizes the enzyme with potassium borate.Type: GrantFiled: June 29, 2000Date of Patent: September 23, 2003Assignee: Ecolab Inc.Inventors: Victor Fuk-Pong Man, Steven Eugene Lentsch, Yvonne Marie Killeen
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Patent number: 6620209Abstract: A detergent composition comprising: (a) a surfactant selected from the group consisting of an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, a zwitterionic surfactant, and mixtures thereof; (b) a cationic polymer; and (c) a zeolite.Type: GrantFiled: September 7, 2001Date of Patent: September 16, 2003Assignee: Cognis Deutschland GmbH & Co. KGInventors: Ditmar Kischkel, Manfred Weuthen, Jutta Stute
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Patent number: 6479455Abstract: A process for improving storage stability and solubility of a laundry detergent powder includes the steps of: (a) forming a builder agglomerate which is free of sodium carbonate and (b) adding the builder agglomerate to a laundry detergent powder composition. The builder agglomerate is present in an amount in a range of from about 14% to about 21% by weight of the laundry detergent powder composition. The builder agglomerate has a composition including an aluminosilicate ion exchange and a binder selected from the group consisting of surfactants, polyethylene glycol, polyacrylates, and mixtures thereof. The builder agglomerate also includes sodium diethylenetriaminepentaacetate (DTPA) and balance water but the builder agglomerate is free of sodium carbonate.Type: GrantFiled: March 19, 2001Date of Patent: November 12, 2002Assignee: The Procter & Gamble CompanyInventors: Joseph Michael Cruse, Michael Chris Jensen
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Patent number: 6475982Abstract: The present invention relates to a composition containing MAP zeolite, ethoxylated nonionic surfactant and an alkali metal carbonate.Type: GrantFiled: July 10, 2000Date of Patent: November 5, 2002Assignee: Colgate Palmolive CompanyInventors: Charles Beagle, Richard Adams, David Beck
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Patent number: 6468500Abstract: An aluminosilicate in an acicular form, a platy form, or a columnar form and having the composition represented by aM2O.bAl2O3.cSiO2.dRmAn.yH2O, wherein M is at least one of Na and K; R is one or more elements selected from the group consisting of Na, K, Ca and Mg; A is one or more members selected from the group consisting of CO3, SO4, NO3, OH and Cl; a is from 1 to 6; b is from 2 to 8; c is from 2 to 12; d is from 0 to 4; m is from 1 to 2; n is from 1 to 3; and y is from 0 to 32; a polishing agent including the aluminosilicate; and a detergent composition including the aluminosilicate.Type: GrantFiled: April 28, 2000Date of Patent: October 22, 2002Assignee: Kao CorporationInventors: Mikio Sakaguchi, Takanori Kotera, Masaharu Jyono, Ichiro Sakamoto
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Patent number: 6465418Abstract: The present invention relates to a composition containing zeolite, ethoxylated nonionic surfactant and an alkali metal carbonate.Type: GrantFiled: October 31, 2000Date of Patent: October 15, 2002Assignee: Colgate-Palmolive Co.Inventors: Charles Beagle, Richard Adams, David Beck
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Patent number: 6465417Abstract: The present invention relates to a composition containing a MAP zeolite, ethoxylated nonionic surfactant and an alkali metal carbonate.Type: GrantFiled: July 10, 2000Date of Patent: October 15, 2002Assignee: Colgate-Palmolive Co.Inventors: Charles Beagle, Richard Adams, David Beck
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Patent number: 6455490Abstract: A non-spray-dried granular component suitable for use in a particulate zero-phosphate laundry detergent composition comprises from 10 to 30 wt % of organic surfactant and from 20 to 50 wt % of zeolite MAP, the component having a bulk density not exceeding 700 g/l. The component may be prepared by a mixing and agglomeration process using a high-speed mixer, a moderate- or low-speed mixer, and a gas fluidization granulator. The component may be used in conjunction with a spray-dried granular component of lower bulk density, for example, a spray-dried detergent base powder containing organic surfactant and zeolite A, or a spray-dried sodium-carbonate-based adjunct.Type: GrantFiled: June 8, 2000Date of Patent: September 24, 2002Assignee: Unilever Home & Personal Care USA Division of Conopco, In.cInventors: Daniel Pierre Marie Berthod, Christophe Michel Bruno Joyeux, Johannes Hendrikus Langeveld
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Patent number: 6440922Abstract: A detergent composition comprises a zeolite builder having a particle size, expressed as a d50 value, of less than 1.0 micrometers, an amylase enzyme, and an alkoxylated nonionic surfactant having a hydrophilic lipophilic balance value of less than 9.5 selected from the group consisting of alkoxylated adducts of fatty alcohols containing an average of less than 5 alkylene oxide groups per molecule. The detergent composition has been found to reduce white residue formation on fabrics washed with detergent containing small particle size zeolite.Type: GrantFiled: July 14, 1997Date of Patent: August 27, 2002Assignee: The Procter & Gamble CompanyInventors: Carolyn Jayne Garnett, Jonathan Richard Clare, Johan Juliaan Serafin Wauben
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Patent number: 6387873Abstract: This invention relates to detergent compositions having significantly improved calcium sequestration capacity as well as superior builder capacity in comparison to conventional aluminosilicate builder materials, while not redepositing on fabrics. More particularly, this invention relates to detergent compositions comprising microclusters of submicron crystallites of an aluminosilicate ion exchange material.Type: GrantFiled: March 29, 2001Date of Patent: May 14, 2002Assignee: The Procter & Gamble CompanyInventors: John David Carter, Eugene Joseph Pancheri, Robert Henry Rohrbaugh
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Patent number: 6387869Abstract: A granular surfactant composition comprising sodium silicate and linear alkylbenzenesulfonates, wherein the granular surfactant composition has a mean particle diameter of ≧50 &mgr;m and an ffc value of ≧7; a process for the preparation of this granular surfactant composition, its use, and detergents and cleaners which comprise such granular surfactant composition and a process for the making of the same; and, where appropriate, the granular surfactant composition comprises other active ingredients and auxiliaries.Type: GrantFiled: March 30, 2001Date of Patent: May 14, 2002Assignee: Clariant GmbHInventors: Harald Bauer, Josef Holz, Gunther Schimmel
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Patent number: 6372709Abstract: The invention relates to a finely divided crystalline layered sodium disilicate of the formula NaMSixO2x+1.yH2O, where M is sodium or hydrogen, x is a number from 1.9 to 4, and y is a number from 0 to 20, which comprises from 0 to 40% by weight of alpha-disodium disilicate from 0 to 40% by weight of beta-disodium disilicate from 40 to 100% by weight of delta-disodium disilicate from 0 to 40% by weight of amorphous components, to a process for its preparation and to its use.Type: GrantFiled: July 1, 1999Date of Patent: April 16, 2002Assignee: Clariant GmbHInventors: Harald Bauer, Josef Holz, Günther Schimmel
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Patent number: 6281180Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25° C. A method of using the polymers to prevent fading or corrosion of dishware is also described.Type: GrantFiled: September 15, 1999Date of Patent: August 28, 2001Assignee: Lever Brothers Company, division of Conopco, Inc.Inventors: Alla Tartakovsky, Joseph Oreste Carnali, Richard Gerald Gary
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Patent number: 6265371Abstract: A powdery detergent composition having a high detergency and an excellent storage stability (caking resistance), and comprising (a) a chelating agent composed of a compound having an average degree of neutralization in a molecule of 20 to 70%, a molecular weight of 600 or less, the number of carboxyl groups contained in one molecule of 3 to 5, and a constant of a chelating stability with Ca2+ of 6 to 13, (b) an alkali agent composed of a compound a 0.1% by weight aqueous solution or dispersion of which has the maximum pH of 10 or more at 20° C., at least 5 ml of 0.1 N HCl aqueous solution being required to adjust 1 liter of the aqueous solution or the dispersion to pH 9, and (c) a surfactant at specific ratios, respectively.Type: GrantFiled: January 6, 2000Date of Patent: July 24, 2001Assignee: Kao CorporationInventors: Genjiro Hagino, Shuji Tagata, Sachiko Noguchi
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Patent number: 6258768Abstract: P-type zeolite having the oxide formula M2/nAl2O3 (1.8-2.66) SiO2 y H2O and having a Calcium Binding Capacity of between 100 and 145 mg/g, preferably between 110 and 140 and a Calcium uptake rate of between 12 and 100 seconds, preferably below 50 seconds can be prepared from metakaolin.Type: GrantFiled: August 20, 1998Date of Patent: July 10, 2001Assignee: Imperial Chemical Industries PLCInventor: Abraham Araya
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Patent number: 6239096Abstract: A powdered abrasive cleanser that exhibits superior soil removal properties and surface safety is provided. The cleanser includes a surfactant, an optional source of active chlorine, a borax pentahydrate compound that is preferably sodium tetraborate pentahydrate, and optionally an alkaline detergent builder and/or calcium carbonate.Type: GrantFiled: July 1, 1999Date of Patent: May 29, 2001Assignee: The Clorox CompanyInventors: Robert L. Blum, Denise A. Garner, Carl M. Kling
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Patent number: 6235704Abstract: A solid textile detergent formulation comprises (A) from 1 to 30% by weight of inorganic builders based on carbonates, (B) from 0 to 12% by weight of inorganic builders based on crystalline or amorphous alumosilicates and/or crystalline or amorphous silicates, (C) from 0 to 5% by weight of inorganic builders based on phosphates, (D) from 1 to 40% by weight of one or more glycine-N,N-diacetic acid derivatives I where R is an organic radical and M is hydrogen or a cation, as organic builder component, (E) from 0 to 40% by weight of anionic surfactants and (F) from 0.5 to 50% by weight of nonionic surfactants.Type: GrantFiled: January 28, 2000Date of Patent: May 22, 2001Assignee: BASF AktiengesellschaftInventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter
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Patent number: RE38411Abstract: A washing method is described which has excellent washing power and a low surfactant concentration. The described clothes washing method comprises the use of a phosphorus-free clothes detergent composition comprising (a) one or more surfactants, (b) one or more alkali metal silicates, and (c) one or more metal ion capturing agents other than the alkali metal silicate (b). The above detergent composition is added to water in an amount sufficient to produce a washing liquid having the following washing conditions (1) a pH of not less than 10.60; (2) containing a material having an ion capturing capacity in an amount sufficient for theoretically changing the water hardness of said water to be not more than 0.5° DH; and (3) having a surfactant concentration of from 0.07 to 0.17 g/L.Type: GrantFiled: October 5, 2001Date of Patent: February 3, 2004Assignee: Kao CorporationInventors: Shu Yamaguchi, Noriaki Ushio, Akiko Ishikura, Katsuhiko Kasai, Masaki Tsumadori, Hiroyuki Yamashita