Inorganic Phosphorus Containing Component Patents (Class 510/534)
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Patent number: 8809249Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.Type: GrantFiled: June 7, 2013Date of Patent: August 19, 2014Assignee: Ecolab USA Inc.Inventors: Carter M. Silvernail, Erik C. Olson, Elizabeth R. Kiesel
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Patent number: 8481473Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.Type: GrantFiled: December 2, 2010Date of Patent: July 9, 2013Assignee: Ecolab USA Inc.Inventors: Carter Silvernail, Erik C. Olson, Elizabeth Kiesel
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Publication number: 20130000370Abstract: The invention relates to aminocarboxylates in solid form which have a relatively high storage stability and improved processability, and to the use thereof in household products, in particular detergents, cleaners and care compositions, and in industrial processes.Type: ApplicationFiled: June 26, 2012Publication date: January 3, 2013Applicant: BASF SEInventor: Frank-Peter LANG
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Patent number: 8138138Abstract: A solidification matrix includes a polycarboxylic acid polymer, sodium carbonate, and water. Exemplary polycarboxylic acid polymers include a polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, a modified polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, and a polymaleic acid polymer having a molecular weight of between about 500 and about 5,000. The polycarboxylic acid polymer, sodium carbonate, and water interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition.Type: GrantFiled: July 8, 2010Date of Patent: March 20, 2012Assignee: Ecolab USA Inc.Inventors: Brenda L. Tjelta, Lisa M. Sanders, Michael E. Besse
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Patent number: 7854770Abstract: A detergent composition comprising: from 0.01% to 90% by weight of a surfactant system, one or more detergency builder(s), comprising a phosphate builder, and the phosphate builder containing pyrophosphate, wherein the composition comprises at most 12% by weight of phosphate builder(s) and the phosphate builder(s) comprise(s) at least 40% by weight of pyrophosphate(s).Type: GrantFiled: November 24, 2008Date of Patent: December 21, 2010Assignee: The Procter & Gamble CompanyInventors: Junhua Du, Qing Chen, Li Ran, Ignacio Gallo-Perez, Ming Tang, Kenneth Nathan Price
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Patent number: 7763576Abstract: A solidification matrix includes a polycarboxylic acid polymer, sodium carbonate, and water. Exemplary polycarboxylic acid polymers include a polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, a modified polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, and a polymaleic acid polymer having a molecular weight of between about 500 and about 5,000. The polycarboxylic acid polymer, sodium carbonate, and water interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition.Type: GrantFiled: January 4, 2008Date of Patent: July 27, 2010Assignee: Ecolab Inc.Inventors: Brenda L. Tjelta, Lisa M. Sanders, Michael E. Besse
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Patent number: 7410938Abstract: A solid calcium hypochlorite composition comprising a mixture of: solid calcium hypochlorite; a scale-inhibiting effective amount of a primarily scale-inhibiting alkali metal phosphate; and an effective residue-dispersing amount of primarily residue-dispersing alkali metal phosphate.Type: GrantFiled: February 22, 2005Date of Patent: August 12, 2008Assignee: Arch Chemicals, Inc.Inventor: James P. Brennan
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Patent number: 7375072Abstract: A builder-containing laundry detergent or cleaning composition is comprised of: (1) alkali metal percarbonate; (2) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 10% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (3) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise alkali metal percarbonates and contain only water-soluble builders.Type: GrantFiled: August 10, 2005Date of Patent: May 20, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Josef Penninger
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Patent number: 7354888Abstract: Provided is an antibacterial aqueous solution comprising a phosphate, a citrate, and a silicate; a method of controlling bacterial contamination and/or growth in food substance; a method of prohibiting the formation of, and/or facilitating the removing of, silicate aggregation on metal article; and a method of reducing phosphate usage in industrial antibacterial process.Type: GrantFiled: November 10, 2004Date of Patent: April 8, 2008Assignee: Danisco A/SInventor: Charles R. Mostoller
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Patent number: 7316995Abstract: A builder-containing laundry detergent or cleaning composition comprising: (1) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 5% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (2) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise only water-soluble builders.Type: GrantFiled: August 10, 2005Date of Patent: January 8, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Josef Penninger
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Patent number: 7018975Abstract: A cleaning formulation comprising a cleaning agent, a particulate clay material and an aqueous carrier. The formulation has a pH less than about 4.0 and is characterized by at least a 90% reduction in viscosity at 25° C. at a shear rate of up to about 0.10 s?1. The cleaning formulation is thixotropic and has a highly desirable combination of acid stability, temperature stability, electrolyte stability and ultraviolet radiation stability.Type: GrantFiled: September 11, 2003Date of Patent: March 28, 2006Assignee: Trojan Technologies Inc.Inventor: Howard A. Ketelson
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Patent number: 6982242Abstract: An aqueous detergent composition is provided containing phosphoric acid or salt thereof, an organic phosphate surfactant, a nonionic surfactant, and water. The aqueous detergent composition may be employed to improved the adhesion of a coating to a substrate. Also provided is a method of improving the adhesion of a coating to a substrate.Type: GrantFiled: March 24, 2004Date of Patent: January 3, 2006Assignee: Rohm and Haas CompanyInventors: Audrey Brenda Liss, Joseph Martin Rokowski, Thomas James Ennis
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Patent number: 6635613Abstract: A cleaning formulation comprising a cleaning agent, a particulate clay material and an aqueous carrier. The formulation has a pH less than about 4.0 and is characterized by at least a 90% reduction in viscosity at 25° C. at a shear rate of up to about 0.10 s−1. The cleaning formulation is thixotropic and has a highly desirable combination of acid stability, temperature stability, electrolyte stability and ultraviolet radiation stability.Type: GrantFiled: September 19, 2000Date of Patent: October 21, 2003Assignee: Trojan Technologies, Inc.Inventor: Howard A. Ketelson
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Patent number: 6528474Abstract: The invention relates to a process for the production of substantially alumosilicate-free detergents containing a soluble builder system which provides free-flowing and storage-stable granules. In this process for the production of a particulate, substantially alumosilicate-free detergent, an anionic surfactant acid is sprayed onto a detergent component containing anionic surfactant and builders in order to increase the anionic surfactant content.Type: GrantFiled: July 5, 2000Date of Patent: March 4, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rene-Andres Artiga Gonzalez, Andreas Lietzmann, Maria Liphard, Wilfried Roehl
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Patent number: 6465413Abstract: This invention discloses laundering and dishwashing products which can be incorporated in a single compartment water soluble film sachet, the formulation comprising a granulated percarbonate compound mixed with and encapsulated in an encapsulating blend comprising sulfate, carboxy methyl cellulose and nonionic surfactant, wherein the detergent composition does not include zeolites or perborates.Type: GrantFiled: July 9, 1999Date of Patent: October 15, 2002Inventor: Gerald Thomas Hinton
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Patent number: 6372710Abstract: The invention of this application aims to offer the detergent composition that does not destroy natural ecosystem or pollute air, as the detergent contains neither organic synthetic surfactant that pollutes environment, rivers and lakes nor petroleum volatile solvent that is the source of air pollution. The invention of this application concerns the detergent composition and manufacturing methods of said detergent. The detergent composition contains at least one or more species of sodium (III) phosphate, sodium metasilicate, sodium sulfate, sodium tripolyphosphate, sodium chloride, sodium carbonate, potassium chloride, trisodium citrate and sodium hydroxide.Type: GrantFiled: May 31, 2001Date of Patent: April 16, 2002Inventor: Yasuo Sadoyama
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Patent number: 6281180Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25° C. A method of using the polymers to prevent fading or corrosion of dishware is also described.Type: GrantFiled: September 15, 1999Date of Patent: August 28, 2001Assignee: Lever Brothers Company, division of Conopco, Inc.Inventors: Alla Tartakovsky, Joseph Oreste Carnali, Richard Gerald Gary
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Patent number: 6265371Abstract: A powdery detergent composition having a high detergency and an excellent storage stability (caking resistance), and comprising (a) a chelating agent composed of a compound having an average degree of neutralization in a molecule of 20 to 70%, a molecular weight of 600 or less, the number of carboxyl groups contained in one molecule of 3 to 5, and a constant of a chelating stability with Ca2+ of 6 to 13, (b) an alkali agent composed of a compound a 0.1% by weight aqueous solution or dispersion of which has the maximum pH of 10 or more at 20° C., at least 5 ml of 0.1 N HCl aqueous solution being required to adjust 1 liter of the aqueous solution or the dispersion to pH 9, and (c) a surfactant at specific ratios, respectively.Type: GrantFiled: January 6, 2000Date of Patent: July 24, 2001Assignee: Kao CorporationInventors: Genjiro Hagino, Shuji Tagata, Sachiko Noguchi
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Patent number: 6235704Abstract: A solid textile detergent formulation comprises (A) from 1 to 30% by weight of inorganic builders based on carbonates, (B) from 0 to 12% by weight of inorganic builders based on crystalline or amorphous alumosilicates and/or crystalline or amorphous silicates, (C) from 0 to 5% by weight of inorganic builders based on phosphates, (D) from 1 to 40% by weight of one or more glycine-N,N-diacetic acid derivatives I where R is an organic radical and M is hydrogen or a cation, as organic builder component, (E) from 0 to 40% by weight of anionic surfactants and (F) from 0.5 to 50% by weight of nonionic surfactants.Type: GrantFiled: January 28, 2000Date of Patent: May 22, 2001Assignee: BASF AktiengesellschaftInventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter
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Patent number: 6225278Abstract: The invention relates to a solid textile detergent formulation containing (A) 1-60 wt. % inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates, (B) 1-40 wt. % of one or several glycin-N, N-diacetic acid derivatives of formula (I), wherein R stands for an organic radical and M means hydrogen or a cation, (C) 0-6 wt. % anionic surfactants with one or several sulphate groups, one or several sulphate groups or one or two carboxylate groups and (D) 0.5-50 wt. % non ionic surfactants.Type: GrantFiled: January 28, 2000Date of Patent: May 1, 2001Assignee: BASF AktiengesellschaftInventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter, Beate Ehle
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Patent number: 6221824Abstract: The storage stability of bleach-activating acetonitrile derivatives in solid detergent compositions was to be improved. This was essentially achieved by the use of compounded compounds corresponding to formula R1R2R3NxCH2CN X−, in which R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. “Compounds” of this type are produced by drying in vacuo, for which purpose a suspension of the acetonitrile derivative and a solid carrier material is introduced into a mixer and the resulting mixture is dried with superheated vapor. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach boosting compound.Type: GrantFiled: February 25, 2000Date of Patent: April 24, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Andreas Lietzmann, Artiga Gonzalez, Stefan Hammelstein, Christian Nitsch, Horst-Dieter Speckmann
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Patent number: 6204231Abstract: An aqueous alkaline composition for cleaning equipment used in the food industry wherein the composition contains potassium hydroxide or a mixture of potassium hydroxide and sodium hydroxide and wherein the potassium hydroxide is present in an amount of at least 20% by weight, based on the weight of hydroxide present in the composition. A process for regenerating the cleaning solution is also disclosed.Type: GrantFiled: September 1, 1998Date of Patent: March 20, 2001Assignee: Henkel Kommandigesellschaft Auf AktienInventors: Anja Patten, Ralf Krack, Dietmar Rossner
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Patent number: 6194367Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.Type: GrantFiled: April 27, 1999Date of Patent: February 27, 2001Assignee: Charvid Limited Liability Co.Inventor: Charles Bullick Talley
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Patent number: 6147042Abstract: The cleaner of the present invention contains, as an active ingredient, a polyphosphoric-acid-urea condensate or phosphoric-acid-urea polymer which is a reaction product from orthophosphoric acid and urea and is used for cleaning a metal surface and/or a glass surface in at least one process of a semiconductor device production process and a liquid crystal device production process. According to the present invention, an etching residue and impurities on metal (including semimetal) and glass surfaces can be cleaned off with high environmental and working safety and effectively without causing the problem of metal corrosion.Type: GrantFiled: July 2, 1999Date of Patent: November 14, 2000Assignees: Kishimoto Sangyo Co., Ltd., Otsuka Chemical Co., Ltd.Inventors: Takashi Yata, Yutaka Koinuma, Kazunori Fukumura, Yoshihito Fukumura
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Patent number: 6121219Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.Type: GrantFiled: August 10, 1999Date of Patent: September 19, 2000Assignee: Ecolab Inc.Inventors: Brandon L. Herdt, David A. Halsrud
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Patent number: 6071434Abstract: The reaction of compounds of the formula:X.sub.2 O.sub.3 P CHY CZ.sub.2where Y and each Z are each H, PO.sub.3 X.sub.2, SO.sub.3 X or CO.sub.2 X (e.g. vinyl phosphonic acid or vinylidene diphosphonic acid) with hypophosphorous acid in the presence of free radicals provides novel compounds X.sub.2 O.sub.3 PCHYCZ.sub.2 PO.sub.2 XH which react with monomers such as vinyl sulphonate, vinyl phosphonate, vinylidene diphosphonate and acrylic acid to form telomers useful for scale inhibition, especially barium scale in oil wells. The polymers show better absorption to rock than PVSA and better thermal stability than random copolymers containing equivalent phosphorus.Type: GrantFiled: February 18, 1998Date of Patent: June 6, 2000Assignee: Albright & Wilson UK LimitedInventors: Keith Philip Davis, Alan Craig Smith, David Robert Edward Walker, Gary Woodward
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Patent number: 5935708Abstract: In order to increase active oxygen stability, sodium percarbonate is coated with single or multiple layers of various substances. Sodium percarbonate particles consist of a core of sodium percarbonate fluidized bed spray granulate and sodium sulphate, which may be partially hydrated, as the sole constituent of a single coating layer. The particles exhibit both elevated active oxygen stability and very good ensilability. The coating layer is applied by spraying an aqueous Na.sub.2 SO.sub.4 solution onto the particles to be coated, which were themselves produced by fluidized bed spray granulation, in a fluidized bed and vaporizing water at a fluidized bed temperature of 35 to 100.degree. C.Type: GrantFiled: November 25, 1996Date of Patent: August 10, 1999Assignee: Degussa AktiengesellschaftInventors: Ruediger Schuette, Martin Bewersdorf, Claas-Juergen Klasen
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Patent number: 5900399Abstract: A tablet composition containing 2% to 100% by weight of amorphous crystalline or partly crystalline layer-form sodium silicates corresponding to the formula Na.sub.2 Si.sub.x --O.sub.2x+1.yH.sub.2 O wherein x is a number of 1.9 to 4 and y is a number of 0 to 20, with the proviso that the tablet composition only contains water in a quantity such that the maximum theoretical water-binding capacity of the components of the composition is not exceeded.Type: GrantFiled: October 10, 1996Date of Patent: May 4, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolfgang Seiter, Dieter Jung, Otto Koch, Birgit Stevermann
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Patent number: 5759976Abstract: Tableted detergents are formed from a hydrated phosphate sequestrant, caustic, free water and, optionally, fillers by combining the products and tableting the components without permitting the tablets or detergent to exceed 50.degree. C. In a preferred embodiment where fillers are incorporated, all free water is combined with the phosphate sequestrants, both anhydrous and hydrated. After the water has been absorbed by the sequestrants, the filler and caustic can be added and the detergent tableted. The free water is bound sufficiently tightly to the phosphate sequestrant that it does not rapidly react with the anhydrous caustic, maintaining the temperature at less than 50.degree. C., which in turn prevents the water of hydration in the phosphates from reacting and thereby weakening the formed tablets. The tablets can also be formed by combining the filler with the phosphate sequestrants and water and subsequently adding caustic if the detergent is cooled and its temperature maintained below 50.degree. C.Type: GrantFiled: July 22, 1997Date of Patent: June 2, 1998Assignee: Diversey Lever, Inc.Inventors: Kenneth James Roach, Patricia Anderson
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Patent number: 5541316Abstract: A process for the production of polycarboxylic acids or salts thereof from polysaccharides by oxidation with nitrogen dioxide/dinitrogen tetroxide with at least partial conversion of the primary alcohol groups of the polysaccharides into carboxyl groups and optionally at least partial neutralization of the carboxylic acid groups formed is provided. The oxidation reaction is carried out in a closed reaction system in the presence of oxygen under pressures of 2 bar to 10 bar and at a temperature above room temperature. Nitrogen dioxide/dinitrogen tetroxide is used in such quantities that, in the event of a theoretically complete shift of the equilibrium onto the nitrogen dioxide side, the nitrogen dioxide is present in quantities of at most 2 mole equivalents, based on the content of monomer unit of the polysaccharide containing one primary alcohol group.Type: GrantFiled: July 28, 1994Date of Patent: July 30, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Konrad Engelskirchen, Herbert Fischer, Hans-Wilhelm Verholt