The Oxygen Is Part Of A Carbonyl Group Patents (Class 512/26)
  • Patent number: 6323173
    Abstract: The compounds of the formula wherein the symbols R1, R2, R3 and R4 represent, independently of one another, a hydrogen atom or a linear or branched, saturated or unsaturated C1 to C3 lower alkyl radical, are advantageous as perfuming ingredients for the preparation of perfuming compositions and perfumed articles, to which they impart odoriferous notes of the lily of the valley type.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: November 27, 2001
    Assignee: Firmenich SA
    Inventors: Beat Winter, Philippe Schneider
  • Patent number: 6306818
    Abstract: The invention relates to fragrance precursors, In particular, the invention relates to the use of several classes of compounds which may act as fragrance precursors, e,g., in cosmetic products such as deodorants and antiperspirants and in laundry products such as detergents and fabric softners. These compounds are odorless, but upon contacting the skin as example, in skin care compositions or in personal care compositions, produce fragrances. The compounds also produce fragrances when used in the presence of lipases, e.g. as used in (laundry) detergents, thus providing a prolongation of the fabric scenting effect. The compounds under consideration are compounds of the formula I: The substituents are defined in the specification.
    Type: Grant
    Filed: May 24, 1999
    Date of Patent: October 23, 2001
    Assignee: Givaudan Roure (International) SA
    Inventors: Denise Anderson, Georg Frater
  • Publication number: 20010031720
    Abstract: The present invention relates to flavor or fragrance composition comprising at least one compound of the formula 1 1
    Type: Application
    Filed: March 7, 2001
    Publication date: October 18, 2001
    Applicant: Givaudan SA
    Inventors: Klaus Gassenmeier, Willi Grab, Christophe Galopin, Beatrice Bigler
  • Publication number: 20010005711
    Abstract: Perfume compositions, which comprise 4,8-dimethyl-3,7-nonadien-2-one can be used in fine perfumery and for the perfuming of industrial products.
    Type: Application
    Filed: December 13, 2000
    Publication date: June 28, 2001
    Inventors: Stefan Lambrecht, Erich Dilk, Peter Worner
  • Patent number: 6218355
    Abstract: The present invention describes a fragrance delivery system which releases fragrant aldehydes or ketones and/or fragrant compounds containing an olefin function upon exposure to light. This system comprises &agr;-keto esters of formula in which R′* and R″* have the meaning as defined in the application and which are generally, in case of R′*, an alkyl group carrying an abstractable hydrogen in &ggr;-position relative to the &agr;-keto function and carrying a moiety from which is derived a fragrant compound containing an olefin function, and, in case of R″*, the organic part of a primary or secondary alcohol from R″*OH which is derived a fragrant aldehyde or ketone.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: April 17, 2001
    Assignee: Firmenich SA
    Inventor: Andreas Herrmann
  • Patent number: 6187741
    Abstract: A two phase environmentally friendly fermentation process for producing high yields of &dgr;-decalactone and &dgr;-dodecalactone from the corresponding unsaturated starting materials is carried out under oxidative growth conditions using a saccharomyces species. The resulting products impart, augment and/or enhance the aroma and/or taste of consumable materials including foodstuffs, chewing gums, toothpastes, beverages, fragrance compositions, colognes and perfumed articles such as solid or liquid, anionic, cationic, non-ionic or zwitterionic detergents, fabric softeners, and hair preparations.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: February 13, 2001
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mohamad I. Farbood, Laura E. Kizer, James Morris, Gail Harris, Lynda B. McLean
  • Patent number: 6159929
    Abstract: A compound of formula ##STR1## wherein X represents a C.dbd.O group or a CH--OH group, in the form of an optically active isomer of formula ##STR2## wherein X has the meaning indicated above and, when X is a CH--OH group, the asymmetric carbon (2) has an R configuration, or in the form of a mixture of isomers, is very useful in the field of perfumery, having an unusual, fruity odor note that can be described as a fresh walnut odor together with a rhum type note.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: December 12, 2000
    Assignee: Firmenich SA
    Inventors: Roger L. Snowden, Herve Pamingle, Christian Vial
  • Patent number: 6159928
    Abstract: The present invention provides a cis-configurational unsaturated ester represented by the formula (1) ##STR1## (where R is a methyl group or a phenyl group, and n is 1 or 2) and also provides a fragrance composition containing the cis-configurational unsaturated ester in an effective amount. The cis-configurational unsaturated ester represented by the formula (1) can be produced byreacting a cyclic vinyl ether represented by the formula (2a) ##STR2## (where n is defined as above) with a Grignard reagent represented by the formula (3a)RMgX (3a)(where R is defined as above, and X is a chlorine atom, a bromine atom or an iodine atom)in the presence of a triarylphosphine and not more than 0.
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: December 12, 2000
    Assignee: Kuraray Co., Ltd.
    Inventors: Kunio Mayahara, Toshiki Mori, Yoshin Tamai
  • Patent number: 6153578
    Abstract: Fragrant silanes having the formula:(R.sup.1 O).sub.a (R.sup.2 O).sub.b (R.sup.3 O).sub.c (R.sup.4).sub.d (R.sup.5).sub.e SiR.sup.6where R.sup.1, R.sup.2 and R.sup.3 are derived from the group of alcohols consisting of R.sup.1 OH, R.sup.2 OH and R.sup.3 OH wherein R.sup.1 OH, R.sup.2 OH and R.sup.3 OH are fragrant alcohols or alternatively R.sup.1, R.sup.2 and R.sup.3 are derived from the group of fragrant esters, ketones, or aldehydes having the structure:R.sup.7 --CH.sub.2 (C.dbd.O)--R.sup.8wherein the fragrant ester, ketone or aldehyde is capable of exhibiting the enol form of the carbonyl moiety under reaction conditions, with R.sup.4 and R.sup.5 selected from the group consisting of monovalent hydrocarbon radical having from one to forty carbon atoms and monovalent alkoxy radicals having from one to forty carbon atoms, R.sup.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: November 28, 2000
    Assignee: General Electric Company
    Inventor: Robert J. Perry
  • Patent number: 6100233
    Abstract: The present invention relates to a fragrance delivery system which comprises one or more .beta.-ketoester pro-fragrances or pro-accords, said fragrance delivery system useful in a stable, preferably clear, aqueous odor-absorbing composition. The odor-absorbing composition can be further characterized in that they comprise solublized, uncomplexed cyclodextrin, and cyclodextrin compatible antimicrobial actives, cyclodextrin compatible surfactants, cyclodextrin compatible humectants, or mixtures thereof. The aqueous odor-absorbing composition are for use on inanimate surfaces, especially fabrics, and more specifically, clothes, in order to restore and/or maintain freshness by reducing malodor without the need for washing or dry cleaning.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: August 8, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Mark Robert Sivik, John Cort Severns, Frederick Anthony Hartman, Toan Trinh
  • Patent number: 6090774
    Abstract: Described is a single phase liquid mixture of benzophenone and a mixture of at least two other normally solid perfumery substances which mixture contains from about 25% up to about 60% by weight of benzophenone and from about 60% down to about 25% by weight of a mixture of normally crystalline perfumery ingredients, each of which has a melting point of between about 35.degree. C. and about 120.degree. C. at about 1 atmosphere pressure, containing at least two substances of the following classes:(i) coumarin derivatives;(ii) vanillin derivatives;(iii) resorcylic acid derivatives;(iv) methylene dioxybenzene derivatives;(v) trichloro-.alpha.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: July 18, 2000
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Murray Moscona, Mark A. Sprecker, Richard A. Weiss
  • Patent number: 6087322
    Abstract: The present invention relates to perfume and fragrance pro-accords which are suitable for use in personal care and personal hygiene compositions as fragrance delivery systems. The pro-accords of the present invention slowly release fragrance raw materials upon contact with human skin thereby providing a prolonged fragrance benefit. The pro-accords serve as a means for delivering any fragrance raw material as well as other adjunct materials inter alia astringents, carriers, and diluents.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: July 11, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Joseph Paul Morelli, Scott William Waite, Stacy Renee Hertenstein, Kyle David Jones
  • Patent number: 6077821
    Abstract: The present invention relates to perfume and fragrance pro-accords which are suitable for use in personal care and personal hygiene compositions as fragrance delivery systems. The pro-accords of the present invention slowly release fragrance raw materials upon contact with human skin thereby providing a prolonged fragrance benefit. The pro-accords serve as a means for delivering any fragrance raw material as well as other adjunct materials inter alia astringents, carriers, and diluents.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: June 20, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Joseph Paul Morelli, Scott William Waite, Stacy Renee Hertenstein
  • Patent number: 6051548
    Abstract: Described are trimethylcyclohexenylcyclopropyl ketones having the structure: ##STR1## wherein one of the dashed lines is a carbon--carbon double bond and the other of the dashed lines is a carbon--carbon single bond, uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, colognes and perfumed articles, and mixtures of same with 3-methyl-1-phenylpentanol-5 and/or butanoylcyclohexane derivatives and/or acetic or propionic acid esters of o-methylphenyl isopropanol.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: April 18, 2000
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Richard M. Boden, Marie R. Hanna
  • Patent number: 6043210
    Abstract: The invention is related to novel thiamacrolides, especially musk odorants, having extremely low threshold values, their use in functional perfumery such as fine perfumery, as well as to the preparation of thiamacrolide compounds.
    Type: Grant
    Filed: January 29, 1998
    Date of Patent: March 28, 2000
    Assignee: Givaudan Roure (International) SA
    Inventors: Jerzy A. Bajgrowicz, Georg Frater, Philip Kraft
  • Patent number: 6034052
    Abstract: Mixtures of ethylene dodecanedioate and ethylene undecanedioate which, because of their particular musk odor note, are products which can replace macrocyclic aromatic musk fragrances in inter alia perfume compositions.
    Type: Grant
    Filed: September 18, 1998
    Date of Patent: March 7, 2000
    Inventors: Alfred Korber, Peter Worner, Horst Surburg
  • Patent number: 6025323
    Abstract: The compounds of formula ##STR1## in which R stands for a methyl or ethyl group, are used as perfume ingredients for the preparation of perfuming compositions and perfumed articles, to which they confer aromatic and thujonic notes. The compounds can be used in the form of a mixture of enantiomers or in an enantiomerically pure state. The invention also comprises original processes for the preparation of these compounds.
    Type: Grant
    Filed: May 13, 1998
    Date of Patent: February 15, 2000
    Assignee: Firmenich SA
    Inventors: Charles Fehr, Christian Margot
  • Patent number: 6013618
    Abstract: The present invention relates to perfume or fine fragrance compositions inter alia perfumes, colognes, eau de toilettes, and after shave lotions, comprising pro-accord compounds which release their fragrance raw material components on a delayed basis therefore providing sustained fragrance levels to the user. Typically the pro-accords are comprised of orthoesters, ketals, acetals, orthocarbonates which release two or more fragrance raw materials upon hydrolysis. The present invention also relates to an article of manufacture comprising a first pro-accord containing reservoir and a second fragrance raw material reservoir and a means for admixing and applying the perfume material.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: January 11, 2000
    Assignee: Procter & Gamble Company
    Inventors: Joseph Paul Morelli, Scott William Waite, Stacy Renee Hertenstein, Mark Robert Sivik, Gregory Scot Miracle, Kenneth Nathan Price, Lon Montgomery Gray
  • Patent number: 5965518
    Abstract: A fragrance composition having antimicrobial activity comprises between 3 and 20% phenolic compounds, and between 20 and 80% non-aromatic terpenoids. The fragrance composition may also, either alternatively or additionally, include essential oils containing phenolic compounds as a major constituent, and/or essential oils containing non-aromatic terpenoids as a major constituent. The fragrance composition further has an Odor Intensity Index of less than 100, and an Odor Evaluation Acceptability Index of greater than 50. The fragrance composition is suitable for use in a variety of products.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: October 12, 1999
    Inventors: Tetsuo Nakatsu, Augustinus G. Van Loveren, Raphael K. L. Kang, Alba T. Cilia
  • Patent number: 5952292
    Abstract: 3-Methyl-2-oxo-ethylpentanoate or an isomer thereof are very useful compounds in the field of perfumery, having an unusual, fruity odor note that can be described as a fresh walnut odor together with a rum type note.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: September 14, 1999
    Assignee: Firmenich S.A.
    Inventors: Roger L. Snowden, Herve Pamingle, Christian Vial
  • Patent number: 5919752
    Abstract: The present invention relates to perfume or fine fragrance compositions inter alia perfumes, colognes, eau de toilettes, and after shave lotions, comprising pro-accord compounds which release their fragrance raw material components on a delayed basis therefore providing sustained fragrance levels to the user. Typically the pro-accords are comprised of orthoesters, ketals, acetals, orthocarbonates which release two or more fragrance raw materials upon hydrolysis. The present invention also relates to an article of manufacture comprising a first pro-accord containing reservoir and a second fragrance raw material reservoir and a means for admixing and applying the perfume material.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: July 6, 1999
    Assignee: Procter & Gamble
    Inventors: Joseph Paul Morelli, Scott William Waite, Stacy Renee Hertenstein, Mark Robert Sivik
  • Patent number: 5837671
    Abstract: Methyl (E)-4,7-octadienoate ?(E)-4,7-octadienoic acid methyl ester! (1), as well as odorant and/or flavorant compositions containing compound (1) as an organoleptic active substance and the manufacture of compound (1).
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: November 17, 1998
    Assignee: Givaudan-Roure (International) SA
    Inventor: Roman Kaiser
  • Patent number: 5830835
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; (B) a non-allylic perfume alcohol ester; and (C) optionally, (1) a carboxylic acid salt of a tertiary amine and/or a tertiary amine ester; and (2) a nonionic softener; wherein, preferably, the Iodine Value of the total number of fatty acyl groups present in (A), (C)(1), and (C)(2) is from about 3 to about 60. These compositions exhibit good antistatic properties as well as improved delivery from a substrate.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: November 3, 1998
    Assignee: Procter & Gamble Company
    Inventors: John Cort Severns, Mark Robert Sivik, Frederick Anthony Hartman, Hugo Robert Germain Denutte, Jill Bonham Costa, Alex Haejoon Chung, Rafael Ortiz
  • Patent number: 5814598
    Abstract: The compounds of formula ##STR1## having a double bond in one of the positions indicated by the dotted lines, are useful as perfuming ingredients for the preparation of perfuming compositions and perfumed articles, to which they impart a refreshing and natural chamomile-like character.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: September 29, 1998
    Assignee: Firmenich SA
    Inventors: Charles Fehr, Jose Galindo
  • Patent number: 5798385
    Abstract: Described is a composition which is both an insect repellent and a perfume containing:Para-isopropylcyclohexanol;3,7-dimethyl-2,6-octadien-1-al;5,9-dimethyl-4,8-decadienal;p-mentha-1,8-diene;o-methyl-betaphenylethyl alcohol; and4-cyclooctenyl methyl carbonate.Also described is a method of using such formulation in order to repel insects.
    Type: Grant
    Filed: August 21, 1997
    Date of Patent: August 25, 1998
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Anna Belle Marin
  • Patent number: 5747109
    Abstract: A method of preparing super-concentrated liquid rinse cycle fabric softeners is provided wherein the fabric softeners contain more than 35%, by weight, of a fabric softening system based on an amidoamine fabric softener, such as bis(tallow amidoethyl)-2-hydroxyethyl amine and a quaternary diester fabric softener, such as N-methyl, N,N,N-triethanolamine ditallow ester quaternary ammonium salt. A fatty alcohol ethoxylate surfactant and a polyethylene glycol polymer or a polyethylene glycol alkyl ether polymer are integral components of the liquid composition.
    Type: Grant
    Filed: March 19, 1997
    Date of Patent: May 5, 1998
    Assignee: Colgate-Palmolive Co.
    Inventors: Amjad Farooq, Jeffrey Joseph Mastrull
  • Patent number: 5747108
    Abstract: Super-concentrated liquid rinse cycle fabric softeners are provided which contain more than 35%, by weight, of a fabric softening system based on an amidoamine fabric softener, such as bis(tallow amidoethyl)-2-hydroxyethyl amine and a quaternary diester fabric softener, such as N-methyl, N,N,N-triethanolamine ditallow ester quaternary ammonium salt. A fatty alcohol ethoxylate surfactant and a polyethylene glycol polymer or a polyethylene glycol alkyl ether polymer are integral components of the liquid composition. The super-concentrated compositions may be used at low levels or may be further diluted prior to use.
    Type: Grant
    Filed: March 19, 1997
    Date of Patent: May 5, 1998
    Assignee: Colgate-Palmolive Co.
    Inventors: Amjad Farooq, Jeffrey Joseph Mastrull
  • Patent number: 5668102
    Abstract: The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced environmental impact.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: September 16, 1997
    Assignee: The Procter & Gamble Company
    Inventors: John Cort Severns, Mark Robert Sivik, Frederick Anthony Hartman, Hugo Robert Germain Denutte, Jill Bonham Costa, Alex Haejoon Chung, Rafael Ortiz
  • Patent number: 5652205
    Abstract: Laundry and cleaning compositions comprising a nonionic or anionic ester of an allylic alcohol perfume having the formula: ##STR1## especially geranyl and neryl esters.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: July 29, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Frederick Anthony Hartman, Mark Robert Sivik, John Cort Severns, Scott William Waite, Cynthia Lee Eddy
  • Patent number: 5562847
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; and (B) an ester of an alcohol perfume wherein the ester has at least one free carboxylic acid. The ester has the general formula: ##STR1## wherein R is selected from the group consisting of substituted or unsubstituted C.sub.1-C.sub.30 straight, branched or cyclic alkyl, alkenyl, alkynyl, alkylaryl, aryl group; or ring containing a heteroatom, R' is a perfume alcohol with a boiling point at 760 mm Hg of less than about 300 .degree. C.; and m and n are independently an integer of 1 or greater.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: October 8, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Scott W. Waite, John C. Severns, Mark R. Sivik, Frederick A. Hartman
  • Patent number: 5559088
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; (B) a non-allylic perfume alcohol ester; and (C) optionally, (1) a carboxylic acid salt of a tertiary amine and/or a tertiary amine ester; and (2) a nonionic softener; wherein, preferably, the Iodine Value of the total number of fatty acyl groups present in (A), (C)(1), and (C)(2) is from about 3 to about 60. These compositions exhibit good antistatic properties as well as improved delivery from a substrate.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: September 24, 1996
    Assignee: The Proctor & Gamble Company
    Inventors: John C. Severns, Mark R. Sivik, Frederick A. Hartman, Hugo R. G. Denutte, Jill B. Costa, Alex H. Chung
  • Patent number: 5531910
    Abstract: The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced enviromental impact.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: July 2, 1996
    Assignee: The Procter & Gamble Company
    Inventors: John C. Severns, Mark R. Sivik, Frederick A. Hartman, Hugo R. G. Denutte, Jill B. Costa, Alex H. Chung
  • Patent number: 5180710
    Abstract: Ethyl (2E,4Z,7Z)-2,4,7-decatrienoate, a novel compound, is a useful perfuming ingredient capable of imparting odor notes of the pear, green, violet leaf type to the compositions and articles into which it is incorporated. It can also be advantageously used in a variety of flavoring compositions.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: January 19, 1993
    Assignee: Firmenich S.A.
    Inventors: Ferdinand Naef, Rene Decorzani, Regula Naef, Pierre-Alain Blanc, Nicole van Beem
  • Patent number: 5143900
    Abstract: Perfumes containing normal perfuming components, such as essential oils, esters, ethers, aldehydes, alcohols, hydrocarbons, ketones and lactones, have the fragrances thereof desirably altered, and often significantly strenghtened, by incorporation with them, as another perfuming component, of a N-lower alkyl neoalkanamide, such as ethyl neodecanamide, or a mixture of such neoalkanamides. It has been found that the neoalkanamides are of desirable fragrances, are stable, even in alkaline media, such as built detergent compositions, maintaining their fragrance notes in the perfumes and in perfumed products during comparatively lengthy storage periods, and are significantly substantive to surfaces contacted by them, even when such contact is made in relatively dilute media, such as aqueous wash water, as when ther neoalkanamide (preferably methyl- or ethyl neodecanamide) is a component of a perfume that has been employed to perfume a detergent composition.
    Type: Grant
    Filed: March 6, 1991
    Date of Patent: September 1, 1992
    Assignee: Colgate-Palmolive Company
    Inventors: Robert J. Steltenkamp, Craig F. Eaton
  • Patent number: 5141921
    Abstract: A perfume composition containing 3-methyl-2-hexenoic acid and/or 7-octenoic acid is disclosed. The perfume composition has a fresh and natural animal note and excellent diffusibility and tastiness. The perfume composition produces psychological effects on humans, such as an awakening effect and/or a sedative effect.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: August 25, 1992
    Assignee: Takasago International Corporation
    Inventors: Kiyohito Sawano, Kenya Ishida, Akemi Shimada
  • Patent number: 5039659
    Abstract: Described are 2,2,3-trimethylcyclopentenyl acetone derivatives defined according to one or a mixture of compounds having the structures: ##STR1## organoleptic uses thereof, processes for preparing same using as a starting material the compound having the structure: ##STR2## which is reacted to form the compound having the structure: ##STR3## which is further reacted to form the novel intermediate: ##STR4## which is then converted to the 2,2,3-trimethylcyclopentenyl acetone derivatives or our invention using the allylic alcohol having the structure: ##STR5## wherein R.sub.3, R.sub.4, and R.sub.5 are the same or different hydrogen or methyl; R.sub.6 represents hydrogen, methyl, ethyl, or propyl or isopropyl; x is 0, 1 or 2; R.sub.7 is methyl or ethyl; R.sub.7 ' and R.sub.7 " represent methyl or ethyl or R.sub.7 ', (CH.sub.2).sub.x and R.sub.7 " taken together represents C.sub.2 -C.sub.6 alkylene; M represents Li, Mg, X or MgX; and X represents chloro or bromo.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: August 13, 1991
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Anubhav P. S. Narula, John J. De Virgilio, Vincent F. Kuczinski, Anton V. Ouwerkerk, Charles E. J. Beck, Kathleen E. Boardwick, Marie R. Hanna
  • Patent number: 5037802
    Abstract: The present invention relates to novel substituted cyclohexanol compounds possessing a sandalwood aroma which are useful as fragrance materials. The invention also provides methods for synthesis thereof through a novel aldehyde intermediate. The compounds of the invention have the formula: ##STR1## and wherein R.sub.1 is methyl or ethyl, R.sub.2 -R.sub.7 are independently hydrogen or methyl with the proviso that a maximum of two of the substituents R.sub.2 -R.sub.7 are methyl, and R.sub.8 is hydrogen, lower alkyl (C.sub.1 or C.sub.5) or acyl. The invention also provides fragrance compositions which utilize the compounds of the invention to impart a sandalwood aroma to perfume compositions, colognes and perfumed articles.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: August 6, 1991
    Assignee: BASF K & F Corporation
    Inventors: Robert Eilerman, Philip Christenson, John Yurecko, Jr., Thomas Zebovitz
  • Patent number: 4980342
    Abstract: A convenient process for the preparation of .gamma.-alkyl-substituted-.gamma.-butyrolactones and .delta.-valerolactones is provided. The process involves forming the .alpha.-alkylidene lactone by reacting essentially equimolar amounts of an .alpha.-acyl lactone, an aldehyde, and an alkali metal hydroxide in an inert diluent at an elevated temperature while removing water and hydrogenating the .alpha.-alkylidene lactone to obtain the corresponding .alpha.-alkyl lactone.
    Type: Grant
    Filed: September 1, 1989
    Date of Patent: December 25, 1990
    Assignee: Henkel Corporation
    Inventors: Louis Rebrovic, Eugene G. Harris
  • Patent number: 4933321
    Abstract: Described are triisobutylene alcohols and esters and halogenated intermediates for preparing same defined according to the generic structure: ##STR1## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 " and R.sub.2 " are the same or different and each represents hydrogen, chloro, bromo, hydroxyl or a C.sub.1 -C.sub.3 acyloxy with the provisos that when the dashed line in the 4-4' position is a carbon-carbon double bond then R.sub.1 " is hydrogen and R.sub.2 " is not hydrogen; and R.sub.1 " and R.sub.2 " are not both hydrogen.Also described are the uses of the triisobutylene alcohols and esters in augmenting or enhancing the aroma of perfume composition, colognes and perfumed articles including but not limited to perfumed polymers solid or liquid anionic, cationic, nonionic or switterionic detergents, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: June 12, 1990
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Robert P. Belko, Marie R. Hanna
  • Patent number: 4927805
    Abstract: Curcumin is subjected to the action of heat and pressure in the presence of water by a continuous or batch process to produce vanillin and other natural flavor products. The proportion of vanillin in the final product varies with the pH of the reaction mixture.
    Type: Grant
    Filed: January 25, 1989
    Date of Patent: May 22, 1990
    Assignee: Mallinckrodt, Inc.
    Inventors: Joseph E. Dolfini, Jerome Glinka, Andrew C. Bosch
  • Patent number: 4908349
    Abstract: Novel odorants of the formula ##STR1## namely, 1,1,2,4,4-pentamethyl-6-formyl-1,2,3,4-tetrahydronaphthalene (1a) and 1,1,2,4,4-pentamethyl-7-formyl-1,2,3,4-tetrahydronaphthalene (1b), possess powerful, very natural-warm, musk-like odor notes.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: March 13, 1990
    Assignee: Givaudan Corporation
    Inventor: Hans-Ulrich Gonzenbach
  • Patent number: 4837201
    Abstract: 4-methyl-4-phenyl-1-pentanals of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.2 is hydrogen or methyl, with the exception of 4-methyl-4-phenyl-1-pentanal, and the use of the methylphenylpentanals of the formula I for imparting fragrance properties to, or improving or modifying the fragrance properties of, perfumes and perfumed products, and the preparation of these compounds by hydroformylation of the corresponding 3-methyl-3-phenyl-1-butenes of the general formula II ##STR2## and, if required, subsequent reaction with formaldehyde and partial hydrogenation.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: June 6, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Gramlich, Norbert Goetz, Hardo Siegel, Gerhard Schindler
  • Patent number: 4758548
    Abstract: Aliphatic aldehydes of the general formula I ##STR1## where R.sup.1 is hydrogen or methyl,R.sup.2 is a straight-chain or branched alkyl radical of 1 to 4 carbon atoms and the two radicals X are each hydrogen or together form a further C--C bond, in particular2,5,7,7-tetramethyloctanal,2,4,5,7,7-pentamethyloctanal,2-ethyl-5,7,7-trimethyloctanal and2,5,7,7-tetramethyl-2-octen-1-al, are used in scent compositions and are prepared by a process in which an aldehyde of the general formula II ##STR2## is condensed with an aldehyde of the general formula III ##STR3## in the presence of an aldol condensation catalyst to give the substituted octenal of the general formula I, and, if required, the latter is partially hydrogenated or reduced to give the ocorresponding octanal of the formula I.
    Type: Grant
    Filed: June 30, 1987
    Date of Patent: July 19, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Gramlich, Hardo Siegel
  • Patent number: 4758680
    Abstract: A compound of the general formula, ##STR1## wherein R.sub.1 and R.sub.2 independently are --H, --CH.sub.3, or --CH.sub.2 CH.sub.3 ; and R.sub.3 is alkyl of from 1 to 10 carbons or aryl of from 6 to 10 carbons.
    Type: Grant
    Filed: November 9, 1987
    Date of Patent: July 19, 1988
    Assignee: Hercules Incorporated
    Inventors: Brian Byrne, Louise M. L. Lawter
  • Patent number: 4735932
    Abstract: Described are allyl ester of 2-cyclopentyloxyacetic acid, mixtures of same with 3,3-dimethyl-1-penten-4-oyl cyclohexane and/or methoxyisobutyl pyrazine and/or 3,3-dimethyl-1-(2-propenyl)-1-acetylcyclohexane, perfumery uses thereof and intermediates used in preparing said allyl ester, the allyl ester of 2-cyclopentyloxyacetic acid having the structure: ##STR1## the 3,3-dimethyl-1-penten-4-oyl cyclohexane having the structure: ##STR2## the methoxyisobutyl pyrazine having the structure: ##STR3## and the 3,3-dimethyl-1-(2-propenyl)-1-acetylcyclohexane having the structure: ##STR4##
    Type: Grant
    Filed: May 22, 1987
    Date of Patent: April 5, 1988
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Mark A. Sprecker