The Compound Is Polysiloxane Which Contains Repeating -(ocnh2n)- (i.e., Repeating Unsubstituted Oxyalkylene) Patents (Class 516/118)
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Patent number: 11267976Abstract: A composition contains a polyorganosiloxane dispersed in a combination of a condensation product of a polysiloxane resin and a polyoxyalkylene polymer, and a non-aqueous fluid carrier; wherein the weight-ratio of non-aqueous fluid carrier to condensation product is 0.5 or more and 10 or less; the weight-ratio of the combination of condensation product and non-aqueous fluid carrier to polyorganosiloxane is 0.01 or more and 0.50 or less; and wherein the composition contains less than one weight-part aromatic solvent per million weight parts composition.Type: GrantFiled: April 16, 2020Date of Patent: March 8, 2022Assignee: Dow Silicones CorporationInventors: Patrick J. Fryfogle, Yihan Liu, Timothy P. Mitchell, Jennifer A. Reil, Michael R. Reiter, John Roberts, Gary M. Wieber, Brett L. Zimmerman
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Patent number: 10829599Abstract: The present invention aims to provide an emulsion composition of an organopolysiloxane which has enhanced stability in a water-soluble solvent. The invention provides an organosilicone emulsion composition comprising (A) 100 parts by mass of an organopolysiloxane having a viscosity of at least 500 Pa·s at 25° C.; (B) 1 to 50 parts by mass of a polyether group-containing organosiloxysilicate; (C) 1 to 50 parts by mass of an organopolysiloxane having polyoxyalkylene residues at the both terminals; (D) 1 to 50 parts by mass of a nonionic surfactant; and (E) 10 to 1,000 parts by mass of water.Type: GrantFiled: June 5, 2018Date of Patent: November 10, 2020Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventor: Yuji Ando
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Patent number: 10407647Abstract: Provided is a defoaming agent for a liquid detergent, comprising the following components: component A1, a modified polyorganosiloxane formed by reacting a hydrogen-containing polyorganosiloxane, an unsaturated polyether and an ?-olefin; component A2, a modified polyorganosiloxane formed by reacting a hydrogen-containing polyorganosiloxane, an unsaturated polyether and a bivinyl-terminated polyorganosiloxane; component B, an organosilicon composition composed of a hydrogen-containing polyorganosiloxane, a polymer composed of an acrylate and an ?-olefin, silica and an organosilicon resin; component C, a thickening agent; and component D, water. An excellent compatibility between the modified polyorganosiloxanes A1 and A2 enables the defoaming agent to exhibit an excellent defoaming performance, stability and clarity in a laundry detergent.Type: GrantFiled: August 18, 2014Date of Patent: September 10, 2019Assignee: JIANGSU SIXIN SCIENTIRIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD.Inventors: Wei Hou, Fei Wu, Tian Cao, Wei Huang, Youzhong Yang
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Patent number: 10077387Abstract: Disclosed is an emulsion type silicone pressure sensitive adhesive composition and a process for the production thereof. Also provided is an emulsion type silicone pressure sensitive adhesive composition, comprising: (A) 100 parts by weight of a silicone pressure sensitive adhesive; (B) 1-30 parts by weight of an emulsifier selected from the group consisting of a polyvinylalcohol and a polyether modified MQ resin wherein M is R 3SiO 1/2, and Q is SiO 4/2, wherein R represents C 1-20 alkyl; (C) water; and (D) catalyst.Type: GrantFiled: June 25, 2015Date of Patent: September 18, 2018Assignees: Dow Silicones Corporation, Dow (Shanghai) Holding Co., Ltd.Inventors: Li Ding, Fuming Huang, Chung Mien Kuo, Zhihua Liu
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Patent number: 9907304Abstract: A method for rapid surface sanitization is provided, where the method includes contacting the surface with an effective amount of an antimicrobial composition comprising at least about 50 wt. % of a C1-6 alcohol, based upon the total weight of the antimicrobial composition; and an efficacy-enhancing amount of a C1-10 alkane diol.Type: GrantFiled: June 14, 2010Date of Patent: March 6, 2018Assignee: GOJO Industries, Inc.Inventors: David R. Macinga, Sarah L. Edmonds, Kristin E. Hartzell, Kelly A. Dobos, Carol A. Quezada
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Patent number: 9725619Abstract: Compositions including first and second silicon-containing compounds are described. The first silicon-containing compound includes a polyvalent transition metal having bonded thereto a hydrocarbyloxy group(s) and/or a (di-hydrocarbyl)(perfluoro/fluorinated-hydrocarbyl)silyloxy group(s), which is represented by Formula (I). The second silicon-containing compound includes a reaction product of a first reactant represented by Formula (II-A), which includes hyrdrocarbylsilyloxy groups, and a second reactant represented by Formula (II-B), which includes a perfluorohydrocarbyloxy group(s). The present invention also relates to, articles that include one or more layers formed from such compositions, methods of treating articles by applying thereover such compositions, and the second silicon-containing compound.Type: GrantFiled: February 3, 2016Date of Patent: August 8, 2017Assignee: Aculon, Inc.Inventors: Eric L. Hanson, Eric L. Bruner
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Publication number: 20140100293Abstract: The present invention provides a defoaming agent containing, as essential components, hydrophobic dry silica (S) prepared by hydrophobizing silica prepared using a dry process and having a primary particle diameter of 5 to 100 nm, water, and a hydrophobic liquid (Q) containing 1 to 25% by weight of an ester compound (E) represented by the following formula, (R1—COO)p-D, wherein R1 denotes an alkyl group or an alkenyl group; D denotes a residue resulting from the removal of a hydroxyl group contributing to an ester linkage from a compound (D?) containing 2 to 6 carbon atoms and 1 to 6 hydroxyl groups or a residue resulting from the removal of a hydroxyl group contributing to an ester linkage from an adduct prepared by adding an alkylene oxide to the compound (D?); and p denotes an integer from 1 to 3.Type: ApplicationFiled: June 3, 2011Publication date: April 10, 2014Applicant: SAN NOPCO LTD.Inventor: Tsuyoshi Ando
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Patent number: 8530401Abstract: Superior defoamer compositions contain a low viscosity linear organopolysiloxane, a higher viscosity, optionally branched organopolysiloxane, a polyethersiloxane with a low cloud point, and both colloidal silica and fumed silica.Type: GrantFiled: April 4, 2011Date of Patent: September 10, 2013Assignee: Wacker Chemie AGInventors: Richard Becker, Willibald Burger, Holger Rautschek
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Patent number: 8426478Abstract: Formulation comprising hydrophobicized particles of silicon dioxide, mineral oil and one or more emulsifiers, where the hydrophobicized silicon dioxide is a fumed silicon dioxide, possesses a BET surface area of 200 to 300 m2/g, has on the surface of the particles O—Si—(CnH2n+1)3 groups, where n is 1 to 3 and where the (CnH2n+1) units are alike or different, has a carbon content of 1.5% to 5% by weight, based on the hydrophobic silicon dioxide, and is present in the formulation with a fraction of 0.05% to 5% by weight.Type: GrantFiled: November 24, 2008Date of Patent: April 23, 2013Assignee: Evonik Degussa GmbHInventors: Lara Dabrowski, Frank Menzel, Horst-Werner Wollenweber
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Publication number: 20120256624Abstract: An oil compound used for defoaming includes (A) a substantially hydrophobic organopolysiloxane having a viscosity of 10 to 100,000 mm2/second at 25° C., and (B) finely divided silica that has undergone surface hydrophobization treatment, wherein when an insoluble matter is collected from the oil compound by using hexane and the spectra of the insoluble matter are measured by 29Si-CP/MAS-NMR, the peaks of the silica due to the SiO4/2 (Q) units on the silica surface are such that a ratio [(Q2+Q3)/Q4] between a total area (Q2+Q3) wherein Q2 is a peak area of a silicon atom having two unreacted silanol groups and Q3 is a peak area of a silicon atom having one unreacted silanol group and an area Q4 wherein Q4 is a peak area of a silicon atom having no unreacted silanol group is at 70/30 to 20/80.Type: ApplicationFiled: March 29, 2012Publication date: October 11, 2012Inventors: Kazuyuki TAKEWAKI, Chinami MATSUI, Takato SAKURAI
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Patent number: 8222303Abstract: (A) Siloxane-based antifoams and (B) silicone polyethers prepared by reacting organopolysiloxanes (1) containing 0.05% to 1.6% by weight of Si-bonded hydrogen atoms with unsaturated polyethers (3) of the formulae: CH2?CR1—(CH2)aO(C2H4O)bR1??(Ia) CH2?CR1—(CH2)aO(C2H4O)b(C3H6O)cR1??(Ib) CH2?CR1—(CH2)aO(C3H6O)cR1??(Ic), where R1 is a hydrogen or a C1-6 hydrocarbon radical, a is 0 to 16, b is 1 to 50, and c is 1 to 50, wherein the sum b+c is ?10 and at least two different polyethers (Ia), (Ib) and (Ic) are used, and optionally further reacting the reaction product with organopolysiloxanes (2) containing from 0.01% to 0.5% by weight of Si-bonded hydrogen atoms, wherein the first and second step reactions take place with a hydrosilylation catalyst, and the weight ratio of Si-bonded hydrogen in organopolysiloxane (1) to Si-bonded hydrogen in organopolysiloxane (2) is at least 1.5.Type: GrantFiled: June 29, 2010Date of Patent: July 17, 2012Assignee: Wacker Chemie AGInventors: Christian Herzig, Willibald Burger, Martina Joachimbauer, Josef Wimmer
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Patent number: 7964032Abstract: The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified trisiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.Type: GrantFiled: October 17, 2006Date of Patent: June 21, 2011Assignee: Momentive Performance Materials Inc.Inventors: Suresh K. Rajaraman, Alain Lejeune, Alexander Borovik, George A. Policello, Mark D. Leatherman, Wenqing Peng, Zijun Xia
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Patent number: 7893115Abstract: An oil-in-water emulsion useful as a defoamer for pulp and paper mill applications is described. The defoamer has an oil blend (of a triglyceride oil or a mixture of triglyceride oils and silicone), a stabilizing agent (to make the oil blend stable in the emulsion), hydrophobic silica particles, surfactants, dispersants, and other components. The emulsion is usable directly at low concentrations to control foam.Type: GrantFiled: December 8, 2005Date of Patent: February 22, 2011Assignee: Hercules IncorporatedInventors: Huai N. Cheng, Eric O. Fernandez, John M. Sheepy
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Patent number: 7879917Abstract: A defoamer made from a composition that has at least one triglyceride oil or triglyceride oil mixture, at least one silicone, at least one silicone-triglyceride stabilizing agent, hydrophobic silica particles, optionally one or more surfactants and/or dispersants, and optionally one or more thickeners, and optionally one or more biocides. The defoamers described herein have utility in controlling foam in industrial applications. Typically, the defoamer can be used to control foam in pulp and paper applications.Type: GrantFiled: December 8, 2005Date of Patent: February 1, 2011Assignee: Hercules IncorporatedInventors: Huai N. Cheng, Eric Oswaldo Fernandez, John M. Sheepy
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Patent number: 7879918Abstract: The invention relates to low-foaming gas processing compositions comprising (a) a silicone antifoam component comprising a base silicone fluid and a particulate metal oxide; (b) an emulsifying component in an amount suitable for the at least substantial emulsification of the silicone antifoam component in water; (c) a polypropylene glycol component at least partially soluble, emulsifiable, and/or dispersible in water; (d) a water-soluble or water-dispersible gas processing agent; and (e) water. The invention also relates to methods for processing a gas by treating the gas with these foam suppressing compositions.Type: GrantFiled: January 8, 2010Date of Patent: February 1, 2011Assignee: Momentive Performance Materials Inc.Inventors: Kalman Koczo, David George Quinn
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Publication number: 20110003921Abstract: Formulation comprising hydrophobicized particles of silicon dioxide, mineral oil and one or more emulsifiers, where the hydrophobicized silicon dioxide is a fumed silicon dioxide, possesses a BET surface area of 200 to 300 m2/g, has on the surface of the particles O—Si—(CnH2n+1)3 groups, where n is 1 to 3 and where the (CnH2n+1) units are alike or different, has a carbon content of 1.5% to 5% by weight, based on the hydrophobic silicon dioxide, and is present in the formulation with a fraction of 0.05% to 5% by weight.Type: ApplicationFiled: November 24, 2008Publication date: January 6, 2011Applicant: EVONIK DEGUSSA GmbHInventors: Lara Dabrowski, Frank Menzel, Horst-Werner Wollenweber
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Patent number: 7759402Abstract: The object of the present invention is to provide antifoams which have a good antifoam effect in aqueous dispersions of polymeric organic substances, cause no wetting defects when these dispersions are applied to a surface and at the same time retain their antifoam activity even after prolonged storage at temperatures down to the freezing point.Type: GrantFiled: August 30, 2007Date of Patent: July 20, 2010Assignee: Evonik Goldschmidt GmbHInventors: Joachim Venzmer, Sascha Herrwerth, Sandra Maslek, Christian Mund, Peter Schwab
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Publication number: 20100113855Abstract: The invention relates to low-foaming gas processing compositions comprising (a) a silicone antifoam component comprising a base silicone fluid and a particulate metal oxide; (b) an emulsifying component in an amount suitable for the at least substantial emulsification of the silicone antifoam component in water; (c) a polypropylene glycol component at least partially soluble, emulsifiable, and/or dispersible in water; (d) a water-soluble or water-dispersible gas processing agent; and (e) water. The invention also relates to methods for processing a gas by treating the gas with these foam suppressing compositions.Type: ApplicationFiled: January 8, 2010Publication date: May 6, 2010Applicant: Momentive Performance Materials Inc.Inventors: Kalman Koczo, David George Quinn
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Patent number: 7678835Abstract: The invention relates to low-foaming gas processing compositions comprising (a) a silicone antifoam component comprising a base silicone fluid and a particulate metal oxide; (b) an emulsifying component in an amount suitable for the at least substantial emulsification of the silicone antifoam component in water; (c) a polypropylene glycol component at least partially soluble, emulsifiable, and/or dispersible in water; (d) a water-soluble or water-dispersible gas processing agent; and (e) water. The invention also relates to methods for processing a gas by treating the gas with these foam suppressing compositions.Type: GrantFiled: April 10, 2006Date of Patent: March 16, 2010Assignee: Momentive Performance Materials Inc.Inventors: Kalman Koczo, David George Quinn
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Patent number: 7645360Abstract: Defoamer compositions of high effectiveness containing at least one siloxane-based antifoam and polysiloxane copolymers obtained by coupling a polysiloxane bearing active-hydrogen-containing hydrophilic polymer moieties by means of a di- or polyisocyanate.Type: GrantFiled: May 24, 2006Date of Patent: January 12, 2010Assignee: Wacker Chemie AGInventors: Willibald Burger, Christian Herzig, Josef Wimmer
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Publication number: 20090234029Abstract: An oil compound is prepared by kneading (A) an essentially hydrophobic organopolysiloxane and (B) finely divided silica with (C) a minor amount of a silica surface treating agent and (D) water or with (E) aqueous ammonia, heat treating the resulting mixture, further kneading the mixture with (C) a major amount of the silica surface treating agent, and heat treating the resulting mixture. The oil compound is used to form a silicone-based antifoam composition having effective foam-breaking, persistent antifoaming ability and internal addition stability in foaming liquids.Type: ApplicationFiled: March 5, 2009Publication date: September 17, 2009Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuyuki TAKEWAKI, Akinari Itagaki
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Patent number: 7407991Abstract: A foam control composition comprises a polydiorganosiloxane fluid comprising units of the formula where each group R, which may be the same or different, is selected from an alkyl group having 1 to 36 carbon atoms or an aryl group or aralkyl group having up to 36 carbon atoms, the mean number of carbon atoms in the groups R being at least 1.3, and an additive composition having a melting point of at least 35° C. comprising 5-50 parts by weight of a non-polar component (A) and 50-95 parts by weight of a component (B) which is miscible with component (A) and is more polar than component (A), at least one of (A) and (B) being miscible with the polysiloxane fluid.Type: GrantFiled: August 1, 2003Date of Patent: August 5, 2008Assignee: Dow Corning CorporationInventors: Serge Creutz, Guzman Nachon, Houria Seghir, Bertrand Michel, Virginie Caprasse, Louise Batchelor
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Publication number: 20080167390Abstract: Defoamer compositions effective for the suppression of oil-based and water-based foams. The defoamer compositions comprise a fumed metal oxide, such as fumed silica, or another silica-based material dispersed in an organic solvent. The fumed metal oxide of silica-based material is preferably present at a low weight percentage and may be coated with polydimethylsiloxane (“PDMS”). The defoamer composition may also include one or more traditional defoamer compositions.Type: ApplicationFiled: June 1, 2006Publication date: July 10, 2008Inventors: James Archer, Daniel K. Durham, George Thornton
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Publication number: 20080121104Abstract: There is provided herein a composition which comprises a silicone copolymer and/or terpolymer component containing a polyether moeity (a); and, a water-soluble and/or water dispersible gas-processing component (b); said composition being substantially free of metal oxide-filled non-polyether moiety-containing silicone fluid. There is also provided herein a method for processing a gas comprising treating the gas with said composition.Type: ApplicationFiled: November 27, 2006Publication date: May 29, 2008Inventor: David George Quinn
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Patent number: 6908893Abstract: A novel cleaning composition for dry cleaning applications is described. The cleaning composition utilizes a stain removal composition having a stain removal surfactant and a stain removal solvent, and the dry cleaning applications use a solvent which is a gas at standard temperature and pressure, a biodegradable functionalized hydrocarbon or a silicone comprising solvent.Type: GrantFiled: September 4, 2001Date of Patent: June 21, 2005Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventor: Dennis Stephen Murphy
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Publication number: 20040229964Abstract: The invention relates to the use of water-insoluble organopolysiloxane derivatives of the general formula (I) 1Type: ApplicationFiled: July 14, 2003Publication date: November 18, 2004Inventors: Wilfried Knott, Kathrin Lehmann, Martina Luger, Stefan Silber
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Patent number: 6686320Abstract: The invention relates to the use of water-insoluble polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble polyoxyalkylene-polysiloxane block copolymers as well as coating materials, printing inks and cooling lubricants containing the inventive defoaming compositions.Type: GrantFiled: March 18, 2002Date of Patent: February 3, 2004Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6605183Abstract: Antifoam formulations contain a siloxane antifoam and a polyether/polysiloxane copolymer of the general formula (R2R*SiO)2(RR′SiO)x(R2SiO)y(RR″SiO)2 (I) wherein R* is either R, R′, or R″, and wherein R′ is R1O—(CH2CH2O)a[CH2CH(CH3)O]b[CH2CH(CH2CH3)O]c—R2— (R′) and wherein R″ is —R2—O—(CH2CH2O)d[CH2CH(CH3)O]e[CH2CH(CH2CH3)O]f—R2— (R″) wherein R, R1, R2, a, b, c, d, e, f, x, y, and z are defined herein.Type: GrantFiled: July 27, 2000Date of Patent: August 12, 2003Assignee: Wacker-Chemie GmbHInventors: Holger Rautschek, Willibald Burger, Josef Wimmer, Erika Zscheile, Christine Wolf
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Patent number: 6579908Abstract: This invention relates to foam control agents for paints and coatings comprising a (a) a siloxane polyalkyleneoxide copolymer, (b) N,N′-ethylene bisstearamide, and (c) a carrier.Type: GrantFiled: March 18, 2002Date of Patent: June 17, 2003Assignee: Ashland Inc.Inventors: Thomas J. Penny, Andrew A. Romano
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Patent number: 6525103Abstract: The invention relates to the use of water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers.Type: GrantFiled: February 19, 2002Date of Patent: February 25, 2003Assignee: Goldschmift AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6521587Abstract: A foam control agent, comprising (A) an organopolysiloxane material having at least one silicon-bonded substituent of the formula X-Ph, wherein X denotes a divalent aliphatic organic group bonded to silicon through a carbon atom and Ph denotes an optionally substituted aromatic group, (B) a water-insoluble organic fluid, (C) an organosilicon resin and (D) a hydrophobic filler. The foam control agent may be provided as an emulsion or as a particulate material. It is especially useful as a detergent foam control agent.Type: GrantFiled: August 11, 2000Date of Patent: February 18, 2003Assignee: Dow Corning S.A.Inventors: Jacqueline L'Hostis, Franck Renauld, George Sawicki
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Patent number: 6521586Abstract: A foam control agent comprises (A) an organopolysiloxane material having at least one silicon-bonded substituent of the formula X—Ph, wherein X denotes a divalent aliphatic hydrocarbon group and Ph denotes an optionally substituted aromatic group, (B) an organosilicon resin and (C) a hydrophobic filler. The organosilicon resin (B) preferably consists of siloxane units of the formula R′aSiO4−a/2 wherein R′ denotes a hydroxyl, hydrocarbon or hydrocarbonoxy group, particularly trialkylsiloxy units and SiO4/2 units, wherein a has a value of from 0.5 to 2.4. The foam control agent may be provided as an emulsion or as a particulate material. It is especially useful as a detergent foam control agent.Type: GrantFiled: August 11, 2000Date of Patent: February 18, 2003Assignee: Dow Corning S.A.Inventors: Jan Hoogland, Anick Colson, Franck Renauld, Jacqueline L'Hostis, George Sawicki, Sophie Stassen
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Patent number: 6512015Abstract: This invention relates to silicone foam control compositions comprising a silicone antifoam agent, mineral oil, a polydiorganosiloxane containing at least one polyoxyalkylene group, and a finely divided filler. The foam control compositions of this invention can be advantageously utilized to control foam in foam producing systems, provide improvement in the control of foaming behavior, and are stable and easily dispersible.Type: GrantFiled: June 30, 2000Date of Patent: January 28, 2003Assignee: Dow Corning CorporationInventors: Russell Allen Elms, Margaret Ann Servinski
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Publication number: 20020137804Abstract: The invention relates to the use of water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers for defoaming aqueous media.Type: ApplicationFiled: February 19, 2002Publication date: September 26, 2002Inventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Publication number: 20020132860Abstract: The invention relates to the use of water-insoluble polyoxyalkylene-polysiloxane block copolymers for defoaming aqueous media.Type: ApplicationFiled: March 18, 2002Publication date: September 19, 2002Inventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6451863Abstract: The invention relates to the use of water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said Water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers.Type: GrantFiled: May 11, 2000Date of Patent: September 17, 2002Assignee: Golschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6448298Abstract: Disclosed are methods and compositions for defoaming alcoholic fermentations. An aqueous composition of polydimethylsiloxane, an ethylene oxide/propylene oxide block copolymer and a silicone/silica blend is employed to treat the fermentation for foaming.Type: GrantFiled: May 15, 2000Date of Patent: September 10, 2002Assignee: BetzDearborn, Inc.Inventors: Raimundo Romualdo, Claudio Cândido Luiz, Luiz Antonio Fernandes
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Patent number: 6433028Abstract: The invention relates to the use of water-insoluble polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble polyoxyalkylene-polysiloxane block copolymers as well as coating materials, printing inks and cooling lubricants containing the inventive defoaming compositions.Type: GrantFiled: May 11, 2000Date of Patent: August 13, 2002Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6426379Abstract: This invention relates to a defoamer composition comprising (a) hydrophobic silica; (b) a linear polysiloxane having end-blocked polyoxypropylene groups; (c) a polysiloxane having a pendant polyoxypropylene group; (d) a nonionic surfactant; and preferably (e) an inert diluent. The defoamer compositions are used in paints and coatings.Type: GrantFiled: June 22, 2000Date of Patent: July 30, 2002Assignee: Ashland Inc.Inventors: Rosanna P. Rudy, Andrew A. Romano
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Patent number: 6417258Abstract: An antifoaming composition contains (A) 58 to 90% by weight of an oil compound and (B) 10 to 42% by weight of a mixture. The oil compound (A) consisting essentially of (i) 80 to 99.9% by weight of an organopolysiloxane composed of R13SiO1/2, R12SiO2/2 and R1SiO3/2 units in a ratio of (0.1 to 5):(90 to 99.8):(0.1 to 5) by mol % and (ii) 0.1 to 20% by weight of finely divided silica. The mixture (B) consisting essentially of (iii) 30 to 90% by weight of a polyoxyalkylene-modified silicone oil having a viscosity of 120,000 to 1,000,000 centipoise at 25° C. and (iv) 1 to 70% by weight of a polyhydric alcohol alkyl ether having a molecular weight of 50 to 300. The composition has improved antifoaming properties, water dispersibility and stability.Type: GrantFiled: February 29, 2000Date of Patent: July 9, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshitaka Aoki, Akinari Itagaki
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Patent number: 6391831Abstract: The invention relates to the use of a water-insoluble polyoxyarylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble block copolymers.Type: GrantFiled: May 11, 2000Date of Patent: May 21, 2002Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6221922Abstract: The present invention teaches that low foaming, superspreading compositions may be made the combination of three components (a) a tri or tetra-siloxane alkoxylate; (b) a siloxane polyether copolymer; and (c) a silicone foam control agent which is a tri or tetra siloxane propoxylate.Type: GrantFiled: March 23, 1999Date of Patent: April 24, 2001Assignee: Crompton CorporationInventors: George A. Policello, Sue L. Yang
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Patent number: 6177481Abstract: The present invention relates to mixtures comprising at least one polysiloxane defoamer, at least one emulsifier, at least one nonionic surfactant, at least one polyurethane thickener and water, to a process for the production thereof and to the use thereof.Type: GrantFiled: September 15, 1999Date of Patent: January 23, 2001Assignee: Bayer AktiengesellschaftInventors: Wolfgang Grape, J{umlaut over (u)}rgen Krott, Jan Mazanek, Karl-Heinz Kaesler
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Patent number: 6083998Abstract: Disclosed are methods and compositions for defoaming alcoholic fermentations. An aqueous composition of polydimethylsiloxane, an ethylene oxide/propylene oxide block copolymer and a silicone/silica blend is employed to treat the fermentation for foaming.Type: GrantFiled: April 24, 1998Date of Patent: July 4, 2000Assignee: BetzDearborn Inc.Inventors: Raimundo Romualdo, Claudio Candido Luiz, Luiz Antonio Fernandes
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Patent number: 6004918Abstract: Liquid foam control compositions provide good control for liquid detergent formulations, while being storage stable both before and after incorporation into liquid detergent.Type: GrantFiled: October 16, 1998Date of Patent: December 21, 1999Assignee: Wacker Silicones CorporationInventor: William Kiger Adams
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Patent number: 6001887Abstract: A defoamer emulsion, based on organofunctionally modified polysiloxanes, is obtained by mixing one or several more closely defined organofunctionally modified siloxanes and, optionally, finely divided silica, and emulsifying the mixture by means of a low-shear stirrer with water which contains a hydrophilic, organofunctionally modified polysiloxane.Type: GrantFiled: June 21, 1996Date of Patent: December 14, 1999Assignee: Th. Goldschmidt AGInventors: Michael Keup, Roland Sucker
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Patent number: 5990181Abstract: Disclosed are antifoam emulsions useful in control of foam in aqueous foaming systems which comprise:(A) polydiorganosiloxane;(B) fine solid particles of inorganic oxide, bearing on the surface thereof a polydiorganosiloxane component; wherein the total amount of polydiorganosiloxane present in components (A) and (B) comprises 5 wt % to 60 wt % of the emulsion and the weight ratio of the total amount of polydiorganosiloxane present in components (A) and (B) to the amount of said inorganic oxide is 10:1 to 200:1;(C) an organic surfactant dispersing agent selected from the group consisting of non-ionic tetrafunctional block copolymers terminating in primary or secondary hydroxyl groups and mixtures thereof, which agent comprises 0.Type: GrantFiled: December 11, 1997Date of Patent: November 23, 1999Assignee: Witco CorporationInventors: Konstantinos Spyropoulos, Daniel Yves Sane