The Compound Is Polysiloxane Which Contains Repeating -(ocnh2n)- (i.e., Repeating Unsubstituted Oxyalkylene) Patents (Class 516/124)
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Patent number: 9637311Abstract: A conveyor belt includes a bottom fabric layer having a lower first surface forming a backside of the conveyor belt and an upper first surface, wherein the lower first surface is impregnated with an impregnation having: a) one or more thermoplastic polyolefins selected from the group consisting of ethene homopolymers, propene homopolymers, ethene/?-olefin copolymers, propene/?-olefin copolymers and terpolymers of ethene with two or more different ?-olefins; and b) a thermoplastic polymeric dispersing agent containing repetitive units derived from at least one ethylenically unsaturated monomer of a comparatively lipophilic nature and from at least one ethylenically unsaturated monomer of a comparatively hydrophilic nature and earring an anionic carboxylate group. A process for the manufacture of such belts includes applying the thermoplastic polyolefin(s) and the thermoplastic polymeric dispersing agent as an aqueous dispersion and heating the lower first surface having the dispersion applied thereonto.Type: GrantFiled: June 18, 2013Date of Patent: May 2, 2017Assignee: Habasit Italiana S.p.A.Inventors: Paola Borio, Elio Bibbò
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Publication number: 20150038388Abstract: A granulated antifoam composition comprising an antifoam, a siloxane wax binder, and a carrier. The antifoam includes a hydrophobic fluid wherein the hydrophobic fluid has a surface tension which is greater than or approximately equal to the dynamic surface tension of an aqueous dispersion of the detergent at above the critical micelle concentration of the surfactant and less than about 62 mN/m. The antifoam further includes a finely divided solid hydrophobic filler dispersed in the hydrophobic fluid.Type: ApplicationFiled: August 15, 2012Publication date: February 5, 2015Inventors: Laurence Gallez, Corina Pagnoni, Christel Simon, Nicolas Ziolkowski
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Publication number: 20130345318Abstract: Silicone polyethers and a process for preparation thereof wherein polyethers modified laterally with methylidene groups are reacted with hydrosiloxanes in a hydrosilylation reaction.Type: ApplicationFiled: June 21, 2013Publication date: December 26, 2013Inventors: Frank SCHUBERT, Michael Ferenz, Wilfried Knott
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Patent number: 8362095Abstract: The invention relates to the defoaming of ionic liquids and also to compositions comprising at least one ionic liquid and at least one antifoam and, if appropriate, a solvent and/or further auxiliaries or additives.Type: GrantFiled: February 3, 2009Date of Patent: January 29, 2013Assignee: Evonik Goldschmidt GmbHInventors: Peter Schwab, Christian Mund, Kerstin Kugel, Hans-Juergen Koehle, Rene Haensel
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Publication number: 20120282210Abstract: The invention relates to a method for producing siloxanes selectively carrying primary amino groups by reacting them with ammonia, and to compounds produced in this way.Type: ApplicationFiled: December 29, 2010Publication date: November 8, 2012Applicant: Evonik Goldschmidt GmbHInventors: Frauke Henning, Wilfried Knott, Horst Dudzik
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Patent number: 8222303Abstract: (A) Siloxane-based antifoams and (B) silicone polyethers prepared by reacting organopolysiloxanes (1) containing 0.05% to 1.6% by weight of Si-bonded hydrogen atoms with unsaturated polyethers (3) of the formulae: CH2?CR1—(CH2)aO(C2H4O)bR1??(Ia) CH2?CR1—(CH2)aO(C2H4O)b(C3H6O)cR1??(Ib) CH2?CR1—(CH2)aO(C3H6O)cR1??(Ic), where R1 is a hydrogen or a C1-6 hydrocarbon radical, a is 0 to 16, b is 1 to 50, and c is 1 to 50, wherein the sum b+c is ?10 and at least two different polyethers (Ia), (Ib) and (Ic) are used, and optionally further reacting the reaction product with organopolysiloxanes (2) containing from 0.01% to 0.5% by weight of Si-bonded hydrogen atoms, wherein the first and second step reactions take place with a hydrosilylation catalyst, and the weight ratio of Si-bonded hydrogen in organopolysiloxane (1) to Si-bonded hydrogen in organopolysiloxane (2) is at least 1.5.Type: GrantFiled: June 29, 2010Date of Patent: July 17, 2012Assignee: Wacker Chemie AGInventors: Christian Herzig, Willibald Burger, Martina Joachimbauer, Josef Wimmer
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Publication number: 20120064022Abstract: Provided herein are cyclosiloxane-substituted polysiloxane compounds, compositions that include the polysiloxane compounds, and methods for preparation and use of the polysiloxane compounds. Provided are mechanical lubricant compositions, hydraulic fluid compositions, anti-foam compositions, water repellant agent compositions, release agent compositions, personal care compositions, cosmetic compositions, household care compositions and drug delivery compositions that include one or more of the cyclosiloxane-substituted polysiloxane compounds provided herein.Type: ApplicationFiled: August 4, 2011Publication date: March 15, 2012Inventors: Daniel X. Wray, Michael B. Halsdorff, Robert L. De Armond
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Publication number: 20120035275Abstract: The present invention has objectives to provide an emulsion suitable as a cosmetic raw material and to easily obtain the aforementioned emulsion of organopolysiloxane exhibiting superior storage stability. The present invention provides an emulsion comprising (A) an organopolysiloxane, (B) a methyl polyglycerol-modified silicone-based surfactant having a specified structure, and (C) an aqueous medium, and provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of (A) a organopolysiloxane and (B) a silicone-based surfactant, which is obtained by synthesizing the silicone-based surfactant of component (B) in the component (A).Type: ApplicationFiled: December 21, 2009Publication date: February 9, 2012Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima, Tadashi Okawa
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Patent number: 8084566Abstract: Mixtures of silicone resin with an organopolysiloxane copolymer prepared by hydrosilylating a substantially linear polymer containing an isocyanate reactive group with an Si—H containing organopolysiloxane, and reacting this intermediate with a diisocyanate, are useful as long lasting defoamers which are compatible with numerous media.Type: GrantFiled: November 16, 2009Date of Patent: December 27, 2011Assignee: Wacker Chemie AGInventors: Holger Rautschek, Elisabeth Brehm, Christian Herzig
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Publication number: 20110313060Abstract: A non-aqueous silicone emulsion is provided. It comprises a continuous phase of a polar organic liquid containing droplets of an organopolysiloxane dispersed therein. An organic wax, which has a melting point in the range 40 to 100° C. and is sparingly soluble in the polar organic liquid at 25° C., is dispersed in the polar organic liquid continuous phase as a network of interconnected particles which stabilises the organopolysiloxane droplets in emulsion in the polar organic liquid. A process for the production of the emulsion is also disclosed.Type: ApplicationFiled: December 21, 2009Publication date: December 22, 2011Applicant: DOW CORNING CORPORATIONInventors: Severine Cauvin, Anick Colson, Tatiana Dimitrova, Jean-Paul Lecomtc
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Patent number: 7994095Abstract: Aqueous concentrates and aqueous compositions (e.g., agrochemical) containing a water-insoluble liquid antifoam agent (e.g., liquid silicone-containing antifoam agent) are disclosed. The water-insoluble liquid antifoam agent is incorporated into the concentrate or composition as a solution of the water-insoluble liquid antifoam agent solubilized in an organic solvent (e.g., isopropyl myristate, butyl cocoate or butyl laurate).Type: GrantFiled: May 27, 2004Date of Patent: August 9, 2011Assignee: Syngenta Crop Protection, Inc.Inventors: Carl Formstone, James Hogbin, Rowena Landham, Daniel Lipin, Rupert Sohm
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Patent number: 7662757Abstract: Defoamant solution exhibiting improved foam control performance over an extended time under ASTMD 892 or test method comprising base defoamant diluted in GTL fluid and/or hydrodewaxed waxy feed fluid and/or hydroisomerized/catalytic (and/or solvent) dewaxed waxy feed, the defoamant solution remaining clear with no separation over extended periods of time of storage prior to use.Type: GrantFiled: June 15, 2007Date of Patent: February 16, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Marc Andre Poirier, Susan Marie Mattingly
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Patent number: 7645360Abstract: Defoamer compositions of high effectiveness containing at least one siloxane-based antifoam and polysiloxane copolymers obtained by coupling a polysiloxane bearing active-hydrogen-containing hydrophilic polymer moieties by means of a di- or polyisocyanate.Type: GrantFiled: May 24, 2006Date of Patent: January 12, 2010Assignee: Wacker Chemie AGInventors: Willibald Burger, Christian Herzig, Josef Wimmer
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Patent number: 7638116Abstract: The present invention relates to a series of novel polyesters that are prepared by crosslinking polyglycerol and dimer acid. The nature of the water loving polyglycerol group as well as the fact that a C-36 fatty diacid is used in preparation of the products results in unique products.Type: GrantFiled: October 29, 2007Date of Patent: December 29, 2009Assignee: Zenitech LLCInventors: Carter LaVay, Anthony J. O'Lenick, Jr.
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Patent number: 7550514Abstract: Compositions comprising (A) an organosilicon compound of the formula Ra(R1O)bR2cSiO(4-a-b-c)/2??(I) in which R2 independently denotes a monovalent, SiC-bonded, optionally substituted, aliphatic cyclic or aliphatic branched hydrocarbon radical having at least 3 carbon atoms, R, and R1 are hydrogen or hydrocarbon radicals, the sum a+b+c?3, the organosilicon compound has at least one unit of the formula (I) with c other than 0, and in at least 50% of all of the units of the formula (I) in the organosilicon compound the sum a+b+c is 2; at least one additive (B) selected from (B1) filler particles and/or (B2) organopolysiloxane resin(s) and optionally (C) an organosilicon compound which has units of the formula (III), R5g(R6O)hSiO(4-g-h)/2 where R5 and R6 are hydrogen or a hydrocarbon radical, g+h?3 and in at least 50% of the units (III), g+h=2, are highly effective and long lasting defoamers.Type: GrantFiled: July 7, 2005Date of Patent: June 23, 2009Assignee: Wacker Chemie AGInventors: Holger Rautschek, Christian Herzig, Richard Becker
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Publication number: 20080121104Abstract: There is provided herein a composition which comprises a silicone copolymer and/or terpolymer component containing a polyether moeity (a); and, a water-soluble and/or water dispersible gas-processing component (b); said composition being substantially free of metal oxide-filled non-polyether moiety-containing silicone fluid. There is also provided herein a method for processing a gas comprising treating the gas with said composition.Type: ApplicationFiled: November 27, 2006Publication date: May 29, 2008Inventor: David George Quinn
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Patent number: 7294653Abstract: Silicone antifoaming agent of the present invention demonstrates excellent antifoaming effect with regard to aqueous foaming systems, and is especially suitable for use in conjunction with inks where it significantly suppresses development of cissing during use of ink. The silicone antifoaming agent is characterized by comprising a polyoxyalkylene-modified silicone that has polyoxyalkylene groups expressed by general formula (1) and (2) given below and contains 10 to 200 diorganosiloxane units in one molecule, said polyoxyalkylene-modified silicone satisfying the following conditions: 3?E?90 and 0.01?E/(E+P)?0.45, wherein P is the total number of oxypropylene units (—C3H6O—) and E is the total number of oxyethylene units (—C2H4O—) contained in one molecule.Type: GrantFiled: March 20, 2002Date of Patent: November 13, 2007Assignee: Dow Corning Toray Company, Ltd.Inventor: Jianren Zeng
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Patent number: 7105581Abstract: An antifoam formulations comprise (A) antifoam agent based on siloxanes and (B) branched polyether/polysiloxane copolymers comprising structural units of the formula Y[—CnH2n—(R2SiO)m—Ap—R2Si—G]x??(I) in which Y is a multivalent, optionally heteroatom-containing hydrocarbon radical, R are monovalent optionally halogenated hydrocarbon radicals, A is a radical —R2Si—R2—(R2SiO)m—, G is a monovalent radical —CfH2f-2k—Z or a divalent radical —CnH2n— bonded to a radical Y, Z —(R6)v—(OCH2CH2)a[OCH2CH(CH3)]b[OCH2CH(CH2CH3)]c—OR3, in which R3 is hydrogen, a hydrocarbon radical, or a radical R—C(O)—, R6 is a divalent hydrocarbon radical, v is 0 or 1, a, b and c are 0 or an integer between 1 and 1000, the sum (a+b+c) being from 2 to 2000, x is 3 to 10, f is 2 to 12, k is 0 or 1, n is 2 to 12, m is at least 1, and p is 0 or a positive integer, the branched polyether/polysiloxane copolymers (B) containing on average at least one group Z.Type: GrantFiled: November 7, 2003Date of Patent: September 12, 2006Assignee: Wacker-Chemie GmbHInventors: Willibald Burger, Holger Rautschek, Christian Herzig
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Patent number: 6858663Abstract: The invention relates to the use of water-insoluble organopolysiloxane derivatives of the general formula (I) in which the radicals R1 are alkyl radicals, preferably having 1 to 4 carbon atoms or aryl radicals, but at least 80% of the radicals R1 are methyl radicals, and R2 at least once in the molecule has the definition (a) for defoaming aqueous media, especially printing inks and paints.Type: GrantFiled: July 14, 2003Date of Patent: February 22, 2005Assignee: Goldschmidt AGInventors: Wilfried Knott, Kathrin Lehmann, Martina Lüger, Stefan Silber
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Publication number: 20040122113Abstract: Silicone antifoaming agent of the present invention demonstrates excellent antifoaming effect with regard to aqueous foaming systems, and is especially suitable for use in conjunction with inks where it significantly suppresses development of cissing during use of ink. The silicone antifoaming agent is characterized by comprising a polyoxyalkylene-modified silicone that has polyoxyalkylene groups expressed by general formula (1) and (2) given below and contains 10 to 200 diorganosiloxane units in one molecule, said polyoxyalkylene-modified silicone satisfying the following conditions: 3≦E≦90 and 0.01≦E/(E+P)≦0.45, wherein P is the total number of oxypropylene units (—C3H6O—) and E is the total number of oxyethylene units (—C2H4O—) contained in one molecule.Type: ApplicationFiled: February 10, 2004Publication date: June 24, 2004Inventor: Jianren Zeng
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Patent number: 6686320Abstract: The invention relates to the use of water-insoluble polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble polyoxyalkylene-polysiloxane block copolymers as well as coating materials, printing inks and cooling lubricants containing the inventive defoaming compositions.Type: GrantFiled: March 18, 2002Date of Patent: February 3, 2004Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6605183Abstract: Antifoam formulations contain a siloxane antifoam and a polyether/polysiloxane copolymer of the general formula (R2R*SiO)2(RR′SiO)x(R2SiO)y(RR″SiO)2 (I) wherein R* is either R, R′, or R″, and wherein R′ is R1O—(CH2CH2O)a[CH2CH(CH3)O]b[CH2CH(CH2CH3)O]c—R2— (R′) and wherein R″ is —R2—O—(CH2CH2O)d[CH2CH(CH3)O]e[CH2CH(CH2CH3)O]f—R2— (R″) wherein R, R1, R2, a, b, c, d, e, f, x, y, and z are defined herein.Type: GrantFiled: July 27, 2000Date of Patent: August 12, 2003Assignee: Wacker-Chemie GmbHInventors: Holger Rautschek, Willibald Burger, Josef Wimmer, Erika Zscheile, Christine Wolf
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Patent number: 6593274Abstract: The present invention teaches the composition of terminally modified, amino, polyether, siloxanes, known hereforth as amino siloxane alkokylates, and their use as adjuvants. The amino siloxane alkoxylates of the present invention enhance the efficacy of agrichemicals on plants as compared to conventional TSE's alone. The amino siloxane alkoxylates have at one end, an amine functionality and at the other end, a polyalkyleneoxide functionality.Type: GrantFiled: March 20, 2001Date of Patent: July 15, 2003Assignee: Crompton CorporationInventor: George A. Policello
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Patent number: 6576736Abstract: Products of the reaction between I) the reaction product of reactants comprising A) a linking agent of formula I R4(Y)3 (I) wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an oxygen atom, which is attached to two adjacent carbon atoms in the R4 group to form an epoxy group, and R4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound formula II R3(EO)n(PO)m(BO)pX (II) wherein R3 is a substituted or unsubstituted, saturated or unsaturated, aliphatic or araliphatic oxy or thio group having from 1 to 36 carbon atoms or a secondary amino group having from 2 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or X can be a mercapto group or an amino group in place of a terminal —OH group, provided that when X is mercapto or amino; the sum of n, m, and p must be at least 1; and the mole ratio of A:B is from about 0Type: GrantFiled: March 6, 2002Date of Patent: June 10, 2003Assignee: Cognis CorporationInventors: Michael S. Wiggins, Ronald W. Broadbent, Ramesh L. Narayan, Ayaz Khan
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Patent number: 6552092Abstract: The invention relates to compositions for defoaming aqueous media, comprising as defoamers urea derivatives of the formula I where R1—is a hydrocarbon radical, preferably having 4 to 30 carbon atoms or a hydrocarbon radical, preferably having 4 to 24 carbon atoms and one nitrogen atom or a hydrocarbon radical, preferably having 4 to 30 carbon atoms and one carbonyl group, R2—is a hydrogen atom or a hydrocarbon radical, preferably having 1 to 24 carbon atoms, R3—is a hydrogen atom or a hydrocarbon radical, preferably having 1 to 24 carbon atoms, R4—is an organic radical, preferably having 2 to 30 carbon atoms, and n—is from 0 to 5; in the form of solid particles, which are obtained by crystallization from a clear homogeneous melt dispersed in a carrier medium, and a process of preparation thereof.Type: GrantFiled: February 5, 2002Date of Patent: April 22, 2003Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Michael Gippert, Martina Hartmann, Wolfgang Josten, Peter Muss, Stefan Silber, Roland Sucker
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Patent number: 6525103Abstract: The invention relates to the use of water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers.Type: GrantFiled: February 19, 2002Date of Patent: February 25, 2003Assignee: Goldschmift AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6512016Abstract: Defoaming compositions consisting essentially of: A) at least one organosilicone compound having defoaming activity in aqueous based compositions; and B) at least one base catalyzed reaction product of: a) a linking agent of formula I R4(Y)3 (I) wherein each Y group is a halogen atom or a halogen and two Y groups on adjacent carbons in R4 and an oxygen may be an epoxy group, and R4 is an alkane triyl group having 3 to 10 carbon atoms; and b) a compound of formula II R3(EO)n(PO)m(BO)pX (II) wherein R3 is defined in the specification; n, m, and p are 0 to 50; X is hydrogen, mercapto group or amino group; when X is other than hydrogen, the sum of m, n, and p must be at least 1; the mole ratio of I:II is from about 0.6:1 to about 5:1; and aqueuos compositions containing them.Type: GrantFiled: July 20, 2001Date of Patent: January 28, 2003Assignee: Cognis CorporationInventors: Ayaz Khan, Samuel A. Firman, III, David W. Brown, John E. Nowicki
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Patent number: 6451863Abstract: The invention relates to the use of water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said Water-insoluble poly(oxy-1,4-butanediyl)-containing polyoxyalkylene-polysiloxane block copolymers.Type: GrantFiled: May 11, 2000Date of Patent: September 17, 2002Assignee: Golschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6433028Abstract: The invention relates to the use of water-insoluble polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble polyoxyalkylene-polysiloxane block copolymers as well as coating materials, printing inks and cooling lubricants containing the inventive defoaming compositions.Type: GrantFiled: May 11, 2000Date of Patent: August 13, 2002Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6426379Abstract: This invention relates to a defoamer composition comprising (a) hydrophobic silica; (b) a linear polysiloxane having end-blocked polyoxypropylene groups; (c) a polysiloxane having a pendant polyoxypropylene group; (d) a nonionic surfactant; and preferably (e) an inert diluent. The defoamer compositions are used in paints and coatings.Type: GrantFiled: June 22, 2000Date of Patent: July 30, 2002Assignee: Ashland Inc.Inventors: Rosanna P. Rudy, Andrew A. Romano
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Patent number: 6420324Abstract: The invention relates to compositions for defoaming aqueous media, comprising as defoamers urea derivatives of the formula I where R1 is a hydrocarbon radical, preferably having 4 to 30 carbon atoms or a hydrocarbon radical, preferably having 4 to 24 carbon atoms and one nitrogen atom or a hydrocarbon radical, preferably having 4 to 30 carbon atoms and one carbonyl group, R2 is a hydrogen atom or a hydrocarbon radical, preferably having 1 to 24 carbon atoms, R3 is a hydrogen atom or a hydrocarbon radical, preferably having 1 to 24 carbon atoms, R4 is an organic radical, preferably having 2 to 30 carbon atoms, and n is from 0 to 5; in the form of solid particles, which are obtained by crystallization from a clear homogeneous melt dispersed in a carrier medium, and a process of preparation thereof.Type: GrantFiled: April 13, 2000Date of Patent: July 16, 2002Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Michael Gippert, Martina Hartmann, Wolfgang Josten, Peter Muss, Stefan Silber, Roland Sucker
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Patent number: 6417258Abstract: An antifoaming composition contains (A) 58 to 90% by weight of an oil compound and (B) 10 to 42% by weight of a mixture. The oil compound (A) consisting essentially of (i) 80 to 99.9% by weight of an organopolysiloxane composed of R13SiO1/2, R12SiO2/2 and R1SiO3/2 units in a ratio of (0.1 to 5):(90 to 99.8):(0.1 to 5) by mol % and (ii) 0.1 to 20% by weight of finely divided silica. The mixture (B) consisting essentially of (iii) 30 to 90% by weight of a polyoxyalkylene-modified silicone oil having a viscosity of 120,000 to 1,000,000 centipoise at 25° C. and (iv) 1 to 70% by weight of a polyhydric alcohol alkyl ether having a molecular weight of 50 to 300. The composition has improved antifoaming properties, water dispersibility and stability.Type: GrantFiled: February 29, 2000Date of Patent: July 9, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshitaka Aoki, Akinari Itagaki
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Patent number: 6391831Abstract: The invention relates to the use of a water-insoluble polyoxyarylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble block copolymers.Type: GrantFiled: May 11, 2000Date of Patent: May 21, 2002Assignee: Goldschmidt AGInventors: Thomas Ebbrecht, Wolfgang Josten, Michael Keup, Stefan Silber, Roland Sucker
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Patent number: 6238684Abstract: The present invention teaches the composition of terminally modified, amino, polyether, siloxanes, known henceforth as amino siloxane alkokylates, and their use as adjuvants. The amino siloxane alkoxylates of the present invention enhance the efficacy of agrichemicals on plants as compared to conventional TSE's alone. The amino siloxane alkoxylates have at one end, an amine functionality and at the other end, a polyalkyleneoxide functionality.Type: GrantFiled: December 10, 1998Date of Patent: May 29, 2001Assignee: OSi Specialties, Inc.Inventor: George A. Policello
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Patent number: 6235681Abstract: The present invention teaches the composition of terminally modified, amino, polyether, siloxanes, known henceforth as amino siloxane alkokylates, and their use as adjuvants. The amino siloxane alkoxylates of the present invention enhance the efficacy of agrichemicals on plants as compared to conventional TSE's alone. The amino siloxane alkoxylates have at one end, an amine functionality and at the other end, a polyalkyleneoxide functionality.Type: GrantFiled: February 24, 2000Date of Patent: May 22, 2001Assignee: CK Witco CorporationInventor: George A. Policello
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Patent number: 6221922Abstract: The present invention teaches that low foaming, superspreading compositions may be made the combination of three components (a) a tri or tetra-siloxane alkoxylate; (b) a siloxane polyether copolymer; and (c) a silicone foam control agent which is a tri or tetra siloxane propoxylate.Type: GrantFiled: March 23, 1999Date of Patent: April 24, 2001Assignee: Crompton CorporationInventors: George A. Policello, Sue L. Yang
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Patent number: 6177481Abstract: The present invention relates to mixtures comprising at least one polysiloxane defoamer, at least one emulsifier, at least one nonionic surfactant, at least one polyurethane thickener and water, to a process for the production thereof and to the use thereof.Type: GrantFiled: September 15, 1999Date of Patent: January 23, 2001Assignee: Bayer AktiengesellschaftInventors: Wolfgang Grape, J{umlaut over (u)}rgen Krott, Jan Mazanek, Karl-Heinz Kaesler
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Patent number: 6162330Abstract: A method for restricting air entrapment in white water of a paper making process is described, which comprises adding to said white water a polysiloxane having an Si--C bonded substituent with at least one ether or alcohol oxygen. Preferably certain siloxane oxyalkylene copolymers or certain siloxane oxyalcohols are used.Type: GrantFiled: February 22, 2000Date of Patent: December 19, 2000Assignee: Dow Corning S.A.Inventors: Christina Northfleet, Franck Renauld
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Patent number: 6004918Abstract: Liquid foam control compositions provide good control for liquid detergent formulations, while being storage stable both before and after incorporation into liquid detergent.Type: GrantFiled: October 16, 1998Date of Patent: December 21, 1999Assignee: Wacker Silicones CorporationInventor: William Kiger Adams
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Patent number: 6001887Abstract: A defoamer emulsion, based on organofunctionally modified polysiloxanes, is obtained by mixing one or several more closely defined organofunctionally modified siloxanes and, optionally, finely divided silica, and emulsifying the mixture by means of a low-shear stirrer with water which contains a hydrophilic, organofunctionally modified polysiloxane.Type: GrantFiled: June 21, 1996Date of Patent: December 14, 1999Assignee: Th. Goldschmidt AGInventors: Michael Keup, Roland Sucker
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Patent number: 5968872Abstract: The present invention teaches silicone polyether copolymers with a low degree of polymerization (3 to 4 Si units) provide control for foams generated by organosilicone based surfactants in water without the need for an additional antifoam component. The copolymer foam control agent is a compound of the formula(CH.sub.3).sub.3 SiO[SiO(CH.sub.3).sub.2 ].sub.X [SiOCH.sub.3 R.sup.1 ].sub.Y Si(CH.sub.3).sub.3wherein X+Y=1 to 2, Y.gtoreq.1, R.sup.1 is an alkyleneoxide group of the formula C.sub.a H.sub.2a O(C.sub.3 H.sub.6 O).sub.z R.sup.2 wherein a=3 to 4, z is 1 to 15, R.sup.2 is hydrogen, a hydrocarbon radical of 1 to 4 carbons or acetyl. This invention provides compositions for use in agricultural formulations that give improved foam control for foams generated from organosilicone surfactants in aqueous systems. The copolymer foam control agent is soluble in a surfactant matrix comprised of an organosilicone surfactant alone or in mixtures with short chain conventional surfactants.Type: GrantFiled: February 20, 1997Date of Patent: October 19, 1999Assignee: Witco CorporationInventors: George Policello, Gerald Murphy