Ingredient Is Inorganic Halogen Containing Material Patents (Class 521/119)
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Patent number: 11634860Abstract: Articles and methods for treating textiles and other materials with an antimicrobial compound during laundry and/or drying cycles. The articles include a porous substrate and a core composition that is releasably associated with the substrate and that includes a metal ion having antimicrobial activity. Methods include the use of the articles in laundry and/or drying cycles to provide antimicrobial treatment of the textiles and materials.Type: GrantFiled: May 12, 2017Date of Patent: April 25, 2023Assignee: Applied Silver, Inc.Inventors: Russell Bik, William Morris, James Charles Copeland, Robert Babcock
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Patent number: 10645992Abstract: Described are methods for manufacturing a plastic component, in particular a cushioning element for sports apparel, a plastic component manufactured with such methods, for example a sole or a part of a sole for a shoe, and a shoe with such a sole. The method for the manufacture of a plastic component includes loading a mold with a first material includes particles of an expanded material and fusing the surfaces of the particles by supplying energy. The energy is supplied in the form of at least one electromagnetic field.Type: GrantFiled: February 4, 2016Date of Patent: May 12, 2020Assignee: adidas AGInventors: Tru Huu Minh Le, Christopher Edward Holmes, Christopher Robertson, Maximilian Philipp Kurtz, Victor Romanov
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Patent number: 10385147Abstract: A method for efficiently producing polyvinylamine crosslinked polymer particles by simple operation without using an organic solvent is provided. In the present invention, polyvinylamine crosslinked polymer particles can be produced by performing suspension polymerization in salt water containing N-vinylcarboxylic acid amide and a polyvinyl compound in the presence of a dispersant to obtain particles of a polyvinyl carboxylic acid amide crosslinked polymer and subsequently hydrolyzing the polyvinyl carboxylic acid amide crosslinked polymer. Divinylbenzene is preferred as the polyvinyl compound. N-Vinylcarboxylic acid amide, acrylonitrile, and a polyvinyl compound may be used.Type: GrantFiled: May 26, 2015Date of Patent: August 20, 2019Assignee: Hymo CorporationInventor: Go Honda
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Patent number: 9289362Abstract: An effervescent foamable two-component oral care composition in which a first component contains an acid, and a second component contains an alkaline source such as a carbonate; wherein one or both of the first and second components also contains a surfactant; and, wherein the first and second components are combinable to form an effervescing oral care foam.Type: GrantFiled: February 15, 2006Date of Patent: March 22, 2016Inventors: Martin S. Giniger, Matthew S. Spaid
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Patent number: 8865783Abstract: A liquid flame retardant composition having one or more flame retarding agents, which are the epoxides obtainable by reacting tetrabromobisphenol A with epichlorohydrin and their end-capped derivatives represented by Formula (1), is provided. The liquid composition is especially useful in the preparation of rigid polyurethane foams.Type: GrantFiled: May 14, 2007Date of Patent: October 21, 2014Assignee: Bromine Compounds Ltd.Inventors: Mark Gelmont, Michael Peled, Dina Alon, Ron Frim, Yoav Bar-Yaakov
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Patent number: 8748501Abstract: A polyurethane foam composition that includes polyol, isocyanate, a catalyst, a surfactant, a physical blowing agent, a chemical blowing agent, a nucleating agent and a silsesquioxane compound is provided.Type: GrantFiled: June 30, 2010Date of Patent: June 10, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sung-Woo Hwang, Myung-Dong Cho, Sang-Ho Park
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Patent number: 8716357Abstract: A hydrophilic polymeric ionomer obtainable by reacting, in a solvent, components comprising a polymer and an ionic component selected from a strong acid or a strong base. The present invention also comprises methods of forming such membranes.Type: GrantFiled: October 27, 2010Date of Patent: May 6, 2014Assignee: ITM Power (Research) LtdInventor: Shaun Wright
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Publication number: 20130295371Abstract: Combinations of gelatinous elastomer containing one or more phase change materials, known as “phase change gel”, and polyurethane foam may be made by introducing at least partially cured phase change gel particles comprising plasticized triblock copolymer resin and/or diblock copolymer resin and one or more phase change materials, into a mixture of polyurethane foam-forming components including a polyol and an isocyanate. The phase change gel can be crosslinked to form a cured gelatinous gel, which is then reduced in size before introduction. After the foam-forming components polymerize to make polyurethane foam, the phase change gel particles are discrete visible particles dispersed throughout the foam. The polyurethane reaction is exothermic and can generate sufficient temperature to at least partially melt the styrene-portion of the triblock copolymer resin thereby extending the crosslinking.Type: ApplicationFiled: July 1, 2013Publication date: November 7, 2013Inventors: Bruce W. Peterson, Mark L. Crawford
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Publication number: 20120220677Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.Type: ApplicationFiled: February 20, 2012Publication date: August 30, 2012Applicant: HONEYWELL INTERNATIONAL INC.Inventors: DAVID J. WILLIAMS, MARY C. BOGDAN, CLIFFORD P. GITTERE, ANDREW J. POSS
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Patent number: 8053484Abstract: A polyurethane foam composition includes a polyol, a polyisocyanate, a catalyst, a foam stabilizer, a blowing agent and a fluorinated carbonate wherein the fluorinated carbonate is a compound represented by Formula 1: a compound represented by Formula 2: or a mixture thereof. Also disclosed is a polyurethane foam derived from the composition.Type: GrantFiled: August 24, 2009Date of Patent: November 8, 2011Assignee: Samsung Electronics Co., Ltd.Inventors: Sung Woo Hwang, Myung Dong Cho, Sang Ho Park, Kwang Hee Kim
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Publication number: 20110190408Abstract: A process for producing a polyurethane product comprises steps of (a) supplying at least one polyisocyanate (b) supplying at least one polyol composition comprising at least about 5 weight percent based on total weight of polyols of at least one natural oil based polyol (b1) having a hydroxyl number of at most about 300 and a viscosity below about 10000 mPa·os; and (c) exposing the polyisocyanate and the polyol composition to reaction conditions such that urethane bonds are formed, wherein reaction conditions include the presence of at least one bismuth catalyst. Use of bismuth catalysts is particularly applicable to preparation of open celled, flexible polyurethane foams using polyols made from renewable resources, optionally with other polyols. The invention includes foams made by the process, including viscoelastic foams, preferably having a velvet feel.Type: ApplicationFiled: August 26, 2008Publication date: August 4, 2011Applicant: Dow Global Technologies Inc.Inventors: Francois M. Casati, Jean-Marie Sonney, Herve Wuilay
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Publication number: 20110190409Abstract: A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.Type: ApplicationFiled: October 16, 2009Publication date: August 4, 2011Inventors: Naiying Du, Michael D. Guiver, Gilles P. Robertson
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Publication number: 20110124752Abstract: The object of the invention is a method for the production of foams on silicon basis from polymer mixtures (A) containing silicon, wherein at least one compound (V) is used that contributes to the formation of the polymer network, and which carries at least one alkoxy silyl group of the general formula [1a], [1b], or [1c] ?Si—O—(R1)(R2)(R3) [1a], ?Si(R5)—O—C(R1)(R2)(R3) [1b], ?Si—O—C(O)—U [1c], from which upon curing of the polymer mixtures (A) at least one molecule (XY) is split which is gaseous during processing and causes the formation of foam in the polymer mixture (A), and a catalyst (K) selected from a Brönstedt acid, Brönstedt base, Lewis acid, and Lewis base, where R1, R2, R3, R5, and U have the meanings as stated in claim 1, and where polymer mixtures (A) which form SiO2 during the cross-linking process are excluded.Type: ApplicationFiled: July 14, 2009Publication date: May 26, 2011Applicant: WACKER CHEMIE AGInventors: Christian Peschko, Johann Mueller
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Publication number: 20110015288Abstract: A process for producing polymer foams by precise control of their morphology through use of microfluidic processes, foams produced in this way and use thereof.Type: ApplicationFiled: March 26, 2009Publication date: January 20, 2011Applicant: BASF SEInventors: Meik Ranft, Armin Alteheld, Andre Guerin Moreira, Wiebke Drenckhan, Antje van der Net, Alexander Gryson, Florence Elias
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Patent number: 7541388Abstract: A fully imidized, solvent-free polyimide foam having excellent mechanical, acoustic, thermal, and flame resistant properties is produced. A first solution is provided, which includes one or more aromatic dianhydrides or derivatives of aromatic dianhydrides, and may include one or more aromatic diamines, dissolved in one or more polar solvents, along with an effective amount of one or more blowing agents. This first solution may also advantageously include effective amounts respectively of one or mores catalysts, one or more surfactants, and one or more fire retardants. A second solution is also provided which includes one or more isocyanates. The first and second solutions are rapidly and thoroughly mixed to produce an admixture, which is allowed to foam—in an open container, or in a closed mold—under ambient conditions to completion produce a foamed product. This foamed product is then cured by high frequency electromagnetic radiation, thermal energy, or a combination thereof.Type: GrantFiled: May 5, 2005Date of Patent: June 2, 2009Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Juan M. Vazquez, Roberto J. Cano, Brian J. Jensen, Erik S. Weiser
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Publication number: 20080306175Abstract: The present invention relates to a composition based on trans-1,2-dichloroethylene. A subject-matter of the invention is more particularly a nonflammable composition comprising trans-1,2-dichloroethylene and at least two hydrofluorocarbons and its uses.Type: ApplicationFiled: February 3, 2006Publication date: December 11, 2008Applicant: ARKEMA FRANCEInventors: Laurent Latil, Vincent Enaux
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Patent number: 7393879Abstract: A method for producing a novel silicone foam by reaction of a polyisocyanate with a silicone oligomer having a plurality of functional end groups with active hydrogens, optionally in the presence of fire-retardants, under foam forming conditions which creates a new silicone foam for use in items such as residential upholstered furniture industry, seat cushions and bedding etc., and specifically for use in applications that require, high resilience and fire-retardant properties such as aircraft and surface transportation seat cushioning, military and shipboard mattresses etc.Type: GrantFiled: June 6, 2002Date of Patent: July 1, 2008Assignee: Chestnut Ridge Foam, Inc.Inventors: Jiri E. Kresta, David Munoz Rojas, Ramon Moliner, Chandrasiri Jayakody, Dan Myers
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Patent number: 7144925Abstract: A macrocellular foam is described having improved cell size and Fire-test-response Characteristics, among other features, which is obtained by selecting a particle size less than 1 micron for the flame retardant adjuvant. The inventors found that the amount of fire retardant adjuvant can be increased for a given foam cell size or the foam cell size can be increased for a given amount of fire retardant adjuvant, allowing the production of foams having exceptionally large, well-formed, cells that have excellent Fire-test-response Characteristics. The benefits are especially noteworthy in relation to thermoplastic foams and inorganic flame retardation adjuvants, due to the unexpected reduction in the nucleation effect of the adjuvant. The foams are useful for improving the acoustic performance of products that are required to meet certain Fire-test-response Characteristics.Type: GrantFiled: May 9, 2002Date of Patent: December 5, 2006Assignee: Dow Global Technologies Inc.Inventors: Sandrine Burgun, Jonathan Kammerer, Chung P. Park, William G. Stobby, Suresh Subramonian
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Patent number: 6956066Abstract: A fully imidized, solvent-free polyimide foam having excellent mechanical, acoustic, thermal, and flame resistant properties is produced. A first solution is provided, which includes one or more aromatic dianhydrides or derivatives of aromatic dianhydrides, and may include one or more aromatic diamines, dissolved in one or more polar solvents, along with an effective amount of one or more blowing agents. This first solution may also advantageously include effective amounts respectively of one or mores catalysts, one or more surfactants, and one or more fire retardants. A second solution is also provided which includes one or more isocyanates. The first and second solutions are rapidly and thoroughly mixed to produce an admixture, which is allowed to foam—in an open container, or in a closed mold—under ambient conditions to completion produce a foamed product. This foamed product is then cured by high frequency electromagnetic radiation, thermal energy, or a combination thereof.Type: GrantFiled: February 11, 2004Date of Patent: October 18, 2005Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Juan M. Vazquez, Roberto J. Cano, Brian J. Jensen, Erik S. Weiser
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Patent number: 6906110Abstract: In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.Type: GrantFiled: November 4, 2000Date of Patent: June 14, 2005Assignee: BASF AktiengesellschaftInventors: Reinhard Lorenz, Stephan Bauer, Dieter Junge, Eva Baum, Kathrin Harre, Jörg Erbes, Thomas Ostrowski, Georg Heinrich Grosch
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Patent number: 6653361Abstract: A polyurethane foam or elastomer comprises an organic polyisocyanate component, an active hydrogen-containing component reactive with the polyisocyanate component, wherein the viscosity of this component is less than about 500 cP at room temperature, a catalyst component, a surfactant, and a flame retarding composition. The components may be low VOC. A preferred flame retarding composition comprises an antimony-based compound, a halogenated, active hydrogen-containing component reactive with the polyisocyanate component, and a halogenated flame-retarding agent. Such polyurethanes are useful as gaskets, seals, padding, in automotive applications, and the like.Type: GrantFiled: April 25, 2002Date of Patent: November 25, 2003Assignee: World Properties, Inc.Inventors: Amy L. Gilman, Scott S. Simpson, Petr Svoboda
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Publication number: 20030040548Abstract: A polyurethane foam or elastomer comprises an organic polyisocyanate component, an active hydrogen-containing component reactive with the polyisocyanate component, wherein the viscosity of this component is less than about 500 cP at room temperature, a catalyst component, a surfactant, and a flame retarding composition. The components may be low VOC. A preferred flame retarding composition comprises an antimony-based compound, a halogenated, active hydrogen-containing component reactive with the polyisocyanate component, and a halogenated flame-retarding agent. Such polyurethanes are useful as gaskets, seals, padding, in automotive applications, and the like.Type: ApplicationFiled: April 25, 2002Publication date: February 27, 2003Inventors: Amy L. Gilman, Scott S. Simpson, Petr Svoboda
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Patent number: 5889286Abstract: Premixes intended for the preparation of polyurethane or polyisocyanurate foams comprising at least one polyol, at least one hydrofluoroalkane corresponding to the general formula CF.sub.3 --CR.sup.1 R.sup.2 --CF.sub.2 --R.sup.3, where R.sup.1 and R.sup.2 represent, independently, a hydrogen atom or an optionally fluorinated C.sub.1 -C.sub.3 alkyl group and where R.sup.3 represents a hydrogen atom or a methyl group, and at least one stabilizer chosen from nitroalkanes, diketones, alkaline-earth metal salts and brominated compounds.Type: GrantFiled: September 23, 1996Date of Patent: March 30, 1999Assignee: Solvay (Societe Anonyme)Inventors: Pierre Barthelemy, Annie Leroy
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Patent number: 5677357Abstract: An antistatic additive including a hexahalogenated ionic compound, and an antistatic additive composition for organic polymer compositions including an antistatically-effective amount of the hexahalogenated ionic compound, a solvent for the hexahalogenated ionic compound, and a diluent compatible with the hexahalogenated ionic compound, the solvent and the organic polymer composition. The hexahalogenated phosphate compound is preferably either potassium hexafluorophosphate, sodium hexafluorophosphate, and ammonium hexafluorophosphate. Organic polymer compositions containing the additive also are disclosed, as are methods of manufacturing both the additive and the polymer compositions.Type: GrantFiled: July 5, 1995Date of Patent: October 14, 1997Assignees: Cellular Technology International, Inc., Chemfoam International, Inc.Inventor: Dennis R. Spicher
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Patent number: 5605721Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH .ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: June 7, 1995Date of Patent: February 25, 1997Inventor: Joseph W. Di Geronimo
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Patent number: 5514722Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH.ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: August 12, 1994Date of Patent: May 7, 1996Assignee: Presidential Sports Systems, Inc.Inventor: Joseph W. Di Geronimo
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Patent number: 5502150Abstract: The present invention is directed to polyurethane moldings produced via the RIM process. These polyurethane moldings have excellent reactivity, demold properties (at a 30s demold), and good elongation and tear strength, and comprise the reaction product of an HDI prepolymer having an NCO content of 5 to 25%, a functionality of less than 2.3, and a monomer content of less than 10%, with an isocyanate-reactive component comprising b1) at least one relatively high molecular weight organic compound containing at least about two isocyanate-reactive hydroxyl groups; b2) at least one relatively low molecular weight organic compound selected from the group consisting of diols, aminoalcohols, and mixtures thereof; and b3) at least one relatively low molecular weight hydroxyl-based crosslinking compound containing no more than one aliphatic amine hydrogen atoms capable of reacting with isocyanate groups; in the presence of at least one catalyst.Type: GrantFiled: June 29, 1994Date of Patent: March 26, 1996Assignee: Bayer CorporationInventors: David D. Steppan, Ronald A. Cageao, Neil H. Nodelman, William E. Slack, Frank Sanns, Jr.
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Patent number: 5428104Abstract: Polyol compositions comprising a polyol, an insoluble fluorinated compound and a surfactant composition which is the reaction product of a stoichiometric excess of a polyisocyanate and a polyalkylene glycol monoalkyl ether of formula R--A--OH, wherein R is C.sub.1-25 alkyl and A is a polypropylenoxy chain, optionally containing up to 25% polyethylenoxy units, having a total length of from 4 to 39 units.Type: GrantFiled: November 22, 1993Date of Patent: June 27, 1995Assignee: Imperial Chemical Industries PLCInventors: Martin Barker, Karen Van Der Sande
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Patent number: 5173559Abstract: The present invention relates to reactive systems comprising(a) a storable mixture of (i) a polyisocyanate component comprising at least one organic polyisocyanate, and (ii) an epoxide component stabilized by heating in the presence of an alkylating agent, wherein said heating is optionally carried out in the further presence of part of the polyisocyanate component (i),(b) an isocyanate-reactive component containing at least two isocyanate-reactive groups in a quantity such that 0.1 to 0.9 isocyanate-reactive groups are present for every isocyanate group in component (a), wherein at least 10% by weight of component (b) comprises compounds having a molecular weight greater than about 2000,(c) optionally, tertiary amines in a quantity such that the total storable mixture contains at least 0.005 mole of tertiary amine nitrogen atoms for each 100 g of the total amount of the storable mixture, and, optionally,(d) other auxiliaries and additives.Type: GrantFiled: October 20, 1989Date of Patent: December 22, 1992Assignee: Bayer AktiengesellschaftInventors: Hanns-Peter Muller, Otto Ganster, Bruno Luckas
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Patent number: 5089534Abstract: This invention relates to the use of phosphorus-containing compounds, specifically cyclic organophosphorus compounds, as carbodiimidization catalysts in the preparation of open-celled flexible polyurethane foam for the purpose of controlling foam density and providing softer foams. foams that are softer and of lower density can be prepared with significantly reduced quantities of blowing agents in comparison to foams prepared in the absence of such phosphorus-containing compounds. Additionally, use of such catalysts provides for a reduced reaction exotherm during the preparation of the foam thereby minimizing foam discoloration or scorching. Preferred phosphorus-containing compounds are the 1-alkyl-1-oxophospholenes, especially 1-methyl-1-oxophospholene.Type: GrantFiled: March 23, 1990Date of Patent: February 18, 1992Assignee: The Dow Chemical CompanyInventors: Johan A. Thoen, Robert A. Sewell, Ulrich Muller
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Patent number: 5077330Abstract: A water reaction synthesis with polyoxyethylene diol, diisocyanate and dibutyltin bis lauryl mercaptide produces a high molecular weight thermoplastic polyurethane-urea linear polymer with surface resistivity 10.sup.11 -10.sup.6 ohm/sq. Thermoplastic and/or elastomeric antistatic compositions containing other melt processable polymers and/or filler, and the polymer exhibit permanent protection. Antistatic protection can be increased when the polymer complexes with a metal salt such as lithium chloride, or lithium acetate.Type: GrantFiled: May 4, 1990Date of Patent: December 31, 1991Assignee: Armstrong World Industries, Inc.Inventors: Wendell A. Ehrhart, Nowaf Halout, Kenneth K. Ko, David A. Smith
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Patent number: 5023280Abstract: The present invention relates to a process for the production of polyurethane foams by the reaction of 1) polyisocyanates with 2) polyesters, polycarbonates, polylactones, or polyamides having a molecular weight range of about 400 to about 10,000 and containing at least two isocyanate reactive hydrogen atoms, or mixtures thereof, in the presence of 3) water and/or organic blowing agents, 4) catalysts and 5) flame-retardants, and optionally in the presence of 6) compounds with molecular weights of from 32 to 399 containing at least two isocyanate reactive hydrogen atoms and 7) surface-active additives and other auxiliary agents known in the art. The flame-retardants consist of graphite which has been modified with inorganic expandable materials, either alone or in combination with an inorganic co-flame-retardant.Type: GrantFiled: April 7, 1989Date of Patent: June 11, 1991Assignee: Bayer AktiengesellschaftInventors: Peter Haas, Hans Hettel
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Patent number: 5019599Abstract: A deodorizing urethane foam comprising a urethane foam substrate and a deodorizing component. The deodorizing component is composed of (A) a Diels-Alder reaction-type addition reaction product between an alpha,beta-unsaturated dicarboxylic anhydride and an olefin or a derivative of the reaction product and optionally (B) a copper compound. This urethane foam is produced by foaming a mixture of materials for the urethane foam substrate and the Diels-Alder reaction-type addition reaction product between an alpha,beta-unsaturated dicarboxylic anhydride and an olefin or its derivative of the reaction product and optionally the copper compound.Type: GrantFiled: March 22, 1989Date of Patent: May 28, 1991Assignee: Nippon Zeon Co., Ltd.Inventors: Yoshiaki Miki, Tsunehisa Ueda
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Patent number: 5001165Abstract: Polyol blend compositions are provided containing a polyester polyol, especially an aromatic polyester polyol, a compatibilizing block copolymer of ethylene oxide and at least one other alkylene oxide having three or more carbon atoms in the molecule, the block copolymer being terminated by ethylene oxide blocks, and optionally other polyols. The blends are miscible with halohydrocarbon blowing agents such as trichlorofluoromethane and suitable for reaction with polyisocyanates to give polyisocyanurate and polyurethane foams.Type: GrantFiled: May 17, 1989Date of Patent: March 19, 1991Assignee: Sloss Industries CorporationInventors: John S. Canaday, Ernest K. Moss
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Patent number: 4966920Abstract: The present invention provides a composition comprising a combustible material containing urethane linkages; and as a smoke and toxic gas suppressant, a polyester which has an acid value below 30 mg KOH/g, preferably below 10 mg KOH/g, and which is derived from:Ia.[A] a component which contains 4 carboxyl groups or anhydride thereof, and which is preferably an aromatic component, orIb. a mixture of [A] and [B]:[B] one or more components which contain 2 to 12, preferably 2 to 4, carboxyl groups or 1 to 6, preferably 1 or 2, carboxylic anhydride groups, selected from:[B.sub.1 ] an aliphatic carboxylic acid compnent containing 2-16 carbon atoms; [[B.sub.2 ] a cyclic non-aromatic carboxylic acid containing 7-17 carbon atoms; and[B.sub.3 ] an aromatic carboxylic acid containing 8-16 carbon atoms; andII.Type: GrantFiled: January 19, 1989Date of Patent: October 30, 1990Assignee: Ciba-Geigy CorporationInventors: James Gainer, Robert L. Bentley
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Patent number: 4957954Abstract: Polyvinyl chloride resin stabilizer compositions are provided, comprising a 2,2,6,6-tetramethyl piperidinyl compound and an ammonium or metal perchlorate; and also stabilized polyvinyl chloride resin compositions containing such stabilizers, and optionally including a plasticizer, and particularly as molded articles with polyurethane foam backing.Type: GrantFiled: January 25, 1989Date of Patent: September 18, 1990Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Shunichi Iizuka, Yoshiyuki Sakamaki, Noriyuki Shimoyama
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Patent number: 4948818Abstract: A precipitation polymerization process for producing a macroporous cross-linked copolymeric lattice, capable of adsorbing hydrophilic and lipophilic fluids, in which process there is copolymerized at least one monounsaturated monomer and at least one polyunsaturated monomer in the presence of an organic liquid which is a solvent for the monomers but not for the copolymer, initiating the copolymerization of the monomers by means of a free radical generating catalytic compound, precipitating a copolymer in the solvent in the form of a powder, and forming a dry powder by removing the solvent from the precipitated copolymeric powder. One monomer is a hydrophilic compound and the other monomer is a lipophilic compound.Type: GrantFiled: May 15, 1989Date of Patent: August 14, 1990Assignee: Dow Corning CorporationInventors: Walter J. Carmody, Anthony J. Buzzelli
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Patent number: 4944947Abstract: A new therapeutic polymeric foam dental appliance is disclosed for utilization in the treatment of teeth and/or gums, as well as a method of preparing said appliance by reaction of a polyurethane foam prepolymer with an aqueous treatment solution. A sterile, prepackaged therapeutic dental appliance in ready to use form by dental professionals is also disclosed.Type: GrantFiled: April 26, 1988Date of Patent: July 31, 1990Inventor: Martin H. Newman
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Patent number: 4937273Abstract: The present invention provides a process for producing an antibacterial flexible polyurethane foam containing an antibacterial agent dispersed therein from a foaming mixture composed of polyols, organic isocyanates, catalysts, and blowing agents. The process is characterized in that the antibacterial agent is added to the foaming mixture and the catalyst is an organic amine which is used alone or in combination with a tin compound. In the latter case, the tin compound is a tetravalent tin compound or a divalent tin compound which is used in an amount less than 1 part by weight for 1 part by weight of the antibacterial agent. The antibacterial flexible polyurethane foam retains the antibacterial action for a long time and is safe because it contains an inorganic antibacterial agent dispersed therein which does not yield resistant bacteria.Type: GrantFiled: December 15, 1988Date of Patent: June 26, 1990Assignee: Bridgestone CorporationInventors: Toru Okuyama, Yasuo Kamimura, Kuniaki Yasunaga
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Patent number: 4927863Abstract: A process is disclosed comprising mixing selected shrinkage-minimizing halocarbons with selected two-carbon hydrogen-containing halocarbons, HCFC-123, HCFC-123a and HCFC-141b, and using this mixture as a blowing agent to produce minimal shrinkage closed-cell polyurethane foams.Type: GrantFiled: September 18, 1989Date of Patent: May 22, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Philip L. Bartlett, Joseph A. Creazzo
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Patent number: 4925881Abstract: A foamable thermosetting resin system is disclosed comprising:(a) about 50 to about 85 weight percent, based on the weight of the composition, of a trimerisable polyisocyanate;(b) about 5 to about 20 weight percent of a liquid epoxy resin having an epoxy group content in the range from about 3500 to about 7500 mmol/kg;(c) about 5 to about 20 weight percent of a vinyl ester of a saturated aliphatic monocarboxylic acid in which the carboxyl group is attached to a tertiary or quarternary carbon atom;(d) about 1 to about 20 weight percent of a foaming agent, and(e) about 0.005 to about 5 weight percent of an isocyanate trimerization catalyst.Type: GrantFiled: October 12, 1988Date of Patent: May 15, 1990Assignee: Shell Oil CompanyInventor: Anne C. Udding
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Patent number: 4912141Abstract: Disclosed is new type of implantable material for replacement of cartilaginous or fibrous tissue. The material has controlled porosity and is biocompatible. A method for making this material is also disclosed.Type: GrantFiled: July 28, 1987Date of Patent: March 27, 1990Inventor: Joseph H. Kronman
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Patent number: 4902511Abstract: Disclosed is new type of implantable material for replacement of cartilaginous or fibrous tissue. The material has controlled porosity and is biocompatible. A method for making this material is also disclosed.Type: GrantFiled: July 24, 1989Date of Patent: February 20, 1990Inventor: Joseph H. Kronman
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Patent number: 4902721Abstract: Foamed products are prepared by subjecting a crosslinked polymer such as an ethylene-carbon monoxide copolymer susceptible to heating by high frequency electromagnetic radiation such as microwave or radio frequency which has been imbibed or impregnated with a suitable mechanical or physical blowing agent such as a halogenated hydrocarbon to sufficient high frequency electromagnetic radiation to cause foaming of the polymer.Type: GrantFiled: July 19, 1989Date of Patent: February 20, 1990Assignee: The Dow Chemical CompanyInventors: Tu-Anh Pham, Gerald M. Lancaster
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Patent number: 4885315Abstract: Foamed products are prepared by subjecting a crosslinked polymer such as an ethylene-carbon monoxide copolymer susceptible to heating by high frequency electromagnetic radiation such as microwave or radio frequency which has been imbibed or impregnated with a suitable mechanical or physical blowing agent such as a halogenated hydrocarbon to sufficient high frequency electromagnetic radiation to cause foaming of the polymer.Type: GrantFiled: September 7, 1988Date of Patent: December 5, 1989Assignee: The Dow Chemical CompanyInventors: Tu-Anh Pham, Gerald M. Lancaster
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Patent number: 4861805Abstract: This invention is an antistatic polyurethane shoe sole which is prepared by reacting in a closed mold a reaction mixture comprising(a) a relatively high equivalent weight polyester polyol or a relatively high equivalent weight polyether polyol containing about 5-25 weight percent repeating units derived from ethylene oxide and about 75-95 weight percent repeating units derived from a C3-C6 cyclic ether,(b) a chain extender compound, in an amount from about 5 to about 40 parts per 100 parts of component (a),(c) a sufficient amount of a blowing agent to provide a density of about 10 to about 65 pounds per cubic foot,(d) a polyisocyanate, in an amount to provide about 0.9 to about 1.2 isocyanate groups per active hydrogen-containing group present in the reaction mixture, and(e) a non-volatile ionizable metal salt, in an amount from about 0.Type: GrantFiled: December 5, 1986Date of Patent: August 29, 1989Assignee: The Dow Chemical CompanyInventors: Jose V. Saavedra, Douglas L. Hunter, Steve A. Sims, Donald M. Maschmeyer, Thomas M. Knobel
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Patent number: 4791142Abstract: A method and apparatus for creating molten thermoplastic material foam by separately pressurizing the molten thermoplastic material and a gas and by delivering that material and gas sequentially to a premixing chamber, through a sintered metal insert and a post mixing chamber, to a discharge orifice of a spray nozzle. The apparatus for practicing this method comprises a nozzle assembly, including a nozzle adaptor and a nozzle, the adaptor of which has flow passages for delivering the pressurized gas and molten material to a premixing cavity and subsequently to and through a sintered metal insert contained within the nozzle.Type: GrantFiled: August 5, 1987Date of Patent: December 13, 1988Assignee: Nordson CorporationInventors: Harald Pleuse, Peter E. Muller
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Patent number: 4774040Abstract: There is provided a process for the manufacture of molded bodies of polyurethane integral foam, such as body parts for the automotive industry, in which the first step of the process, the polyol component is prepared and in the second step of the process the polyol component is reacted with the isocyanate component according to the reaction injection molding method. In the mold and/or after removal from the mold, the molded bodies are subjected to thermal aftertreatment within the framework of a third process step for thirty minutes to three hours at 120.degree. to 180.degree. C. Also, the polyol component may contain nucleating agents, so that the nucleated molded bodies may or may not need be thermally aftertreated.Type: GrantFiled: September 4, 1987Date of Patent: September 27, 1988Assignee: Phoenix AktiengesellschaftInventors: Thies Timm, Herbert Schaper, Reinhard Krassig
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Patent number: 4743624Abstract: Flame-retardant polyurethane products are produced by mixing and reacting a basic salt-forming compound with an acidic salt-forming compound containing phosphorus and/or halogen compounds in a polyol and/or a polyisocyanate, then reacting the polyol and polyisocyanate.The flame-retardant polyurethane products may be used for thermal and sound insulation, as a coating agent, as an adhesive. for caulking, for cushioning and for molding useful objects.Type: GrantFiled: June 11, 1987Date of Patent: May 10, 1988Inventor: David H. Blount
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Patent number: 4736008Abstract: Disclosed herein is a process for preparing heat-resistant polymers by reacting an organic polyisocyanate with one or more compounds selected from the group consisting of organic polycarboxylic acids and organic polycarboxylic acid anhydrides in the presence of an alkali metal fluoride or an alkali metal fluoride combined with a quaternary onium salt as a catalyst.Type: GrantFiled: December 19, 1986Date of Patent: April 5, 1988Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Masahiro Kouno, Akihiro Yamaguchi, Masanori Osawa, Kohei Shizuka, Hiromi Nakano, Kazumi Mizutani