At Least One Polymer Is Derived From An Aldehyde Or Derivative Or Wherein The Polymer-forming System Contains The Same Type Of Reactant Patents (Class 521/136)
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Patent number: 10563100Abstract: An adhesive composition is disclosed, and includes an aldehyde-based resin selected from the group consisting of urea-formaldehyde resins, melamine-formaldehyde resins, melamine-urea-formaldehyde resins, phenol-containing resins, and mixtures, combinations, and sub-combinations thereof, and a formaldehyde scavenger selected from the group consisting of chitosan, nano-chitosan, functionalized chitosan, and mixtures, combinations, and sub-combinations thereof.Type: GrantFiled: March 14, 2018Date of Patent: February 18, 2020Inventors: Ali Shalbafan, Hedi Hassannejad, Mehdi Rahmaninia
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Patent number: 10465050Abstract: The invention relates to a vulcanizable polymer composition comprising a) an polymer having an iodine value of lower than 400 g/100 g polymer, whereby the polymer is an elastomeric polymer that is a copolymer of ethylene, one or more C3 to C23 ?-olefins and a polyene monomer, preferably a copolymer of ethylene, propylene and a polyene monomer are b) an organic peroxide having aromatic groups and c) a zeolite having a pore size of 3 to 6 ?.Type: GrantFiled: December 1, 2014Date of Patent: November 5, 2019Assignee: LANXESS Deutschland GmbHInventors: Martin Van Duin, Philip James Hough
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Patent number: 9975311Abstract: A phenolic resin foam laminated sheet comprising a phenolic resin foam; and a face material for covering a surface of the phenolic resin foam, wherein the phenolic resin foam contains a hydrocarbon, a chlorinated aliphatic hydrocarbon or a combination thereof, a density of the phenolic resin foam is 10 kg/m3 or higher and 100 kg/m3 or lower, an average cell diameter of the phenolic resin foam is 5 ?m or larger and 200 ?m or smaller, a closed cell content of the phenolic resin foam is 85% or higher and 99% or lower, and an absolute value of a dimensional charge rate of the phenolic resin foam after 70° C. for 48 hours is 0.49% or lower.Type: GrantFiled: March 25, 2011Date of Patent: May 22, 2018Assignee: ASAHI KASEI CONSTRUCTION MATERIALS CORPORATIONInventors: Masato Hamajima, Yoshimitsu Inoue, Hisashi Mihori, Yoshihito Fukasawa
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Patent number: 9944781Abstract: A polymeric composition that provides reduced fogging from low molecular weight, volatile organic materials may include at least a first elastomeric polymer having a Mooney viscosity (ML 1+4) at 125° C.) of least 10 MU, at least a second elastomeric polymer having a Mooney viscosity (ML 1+4) at 125° C.) of less than 10 MU, a phenol formaldehyde resin cross-linker, an activator package, and a VOC absorber.Type: GrantFiled: September 19, 2014Date of Patent: April 17, 2018Assignee: LANXESS Deutschland GMBHInventors: Philip Hough, Van Martin Duin
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Patent number: 9815962Abstract: This invention relates to a vehicular tire containing at least one carbon black reinforced polyurethane component.Type: GrantFiled: May 4, 2015Date of Patent: November 14, 2017Assignee: The Goodyear Tire & Rubber CompanyInventors: Aruna Mani Velamakanni, Frank James Feher, Anthony Ryan Lame
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Patent number: 9174247Abstract: The present invention relates to a cleaning implement comprising elastic compressed foam and to a method of cleaning a hard surface with said cleaning implement.Type: GrantFiled: October 23, 2013Date of Patent: November 3, 2015Assignee: The Procter & Gamble CompanyInventors: Denis Alfred Gonzales, Geert Andre Deleersnyder, Peter Nessel, Tobias Heinz Steinke
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Publication number: 20140378567Abstract: Soft, heat activated sealant compositions heat stabilized through the addition of a phenolic resin to provide a uniform volume expansion over a wide range of temperatures are disclosed.Type: ApplicationFiled: June 13, 2014Publication date: December 25, 2014Inventors: Craig Chmielewski, Abraham Kassa
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Patent number: 8772366Abstract: A phenolic foam is made by foaming and curing a foamable phenolic resin composition that comprises a phenolic resin, a blowing agent, an acid catalyst and an inorganic filler. The blowing agent comprises a blend of chlorinated aliphatic hydrocarbon containing 2 to 5 carbon atoms and an aliphatic hydrocarbon containing from 3 to 6 carbon atoms mixed in a ratio of 60/40 to 5/5 parts by weight. The inorganic filler is at least one selected from a metal hydroxide, a metal oxide, a metal carbonate and a metal powder. The phenolic foam has a pH of 5 or more and a water uptake less than 1 kg/m2. A phenolic foam with a higher pH value compared with conventional phenolic foam reduces corrosion risk when in contact with metallic materials. The phenolic foam maintains excellent long-term stable thermal insulation performance, low water uptake and fire resistance performance and by using the said blowing agent, does not harm the environment as an ozone or global warming depleting material.Type: GrantFiled: September 5, 2012Date of Patent: July 8, 2014Assignee: Kingspan Holdings (IRL) LimitedInventors: Vincent Coppock, Ruud Zeggelaar, Hiroo Takahashi, Toshiyuki Kato
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Patent number: 8765829Abstract: A phenolic foam is made by foaming and curing a foamable phenolic resin composition that comprises a phenolic resin, a blowing agent, an acid catalyst and an inorganic filler. The blowing agent comprises an aliphatic hydrocarbon containing from 1 to 8 carbon atoms and the inorganic filler is at least one selected from a metal hydroxide, a metal oxide, a metal carbonate and a metal powder. The phenolic foam has a pH of 5 or more. The phenolic foam has a higher pH value compared with conventional phenolic foam and reduces corrosion risk when in contact with metallic materials. The phenolic foam maintains excellent long-term stable thermal insulation performance, low water uptake and fire resistance performance and by using a hydrocarbon blowing agent, does not harm the environment as an ozone depleting or global warming material.Type: GrantFiled: June 1, 2012Date of Patent: July 1, 2014Assignee: Kingspan Holdings (IRL) LimitedInventors: Vincent Coppock, Ruud Zeggelaar, Hiroo Takahashi, Toshiyuku Kato
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Patent number: 8629195Abstract: The invention relates to a process for producing polyurethane foams, by frothing and drying mixtures of specific polyurethane dispersions and crosslinkers.Type: GrantFiled: April 17, 2012Date of Patent: January 14, 2014Assignee: Bayer MaterialScience AGInventors: Jan Schönberger, Michael Mager, Thorsten Rische, Sebastian Dörr, Thomas Feller, Michael Heckes, Melita Dietze, Burkhard Fugmann
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Patent number: 8603681Abstract: The present invention relates to a novel porous film material which comprises at least one carbonaceous semimetal oxide phase, and to a process for production thereof. The invention also relates to the use of these porous film materials as a separator layer or for production of such separator layers in electrochemical cells, particularly in lithium cells and especially in lithium secondary cells.Type: GrantFiled: June 28, 2010Date of Patent: December 10, 2013Assignee: BASF SEInventors: Nicole Hildebrandt, Arno Lange, Klaus Leitner, Phillip Hanefeld, Claudia Staudt
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Patent number: 8586643Abstract: A composition used for preparing foaming material comprising a polyhydroxyalkanoate, a polylactic acid and a foaming agent, which posses certain tensile strength, elongation in break and expansion ratio as well as full bio-degradability, thus can be used in packaging industry.Type: GrantFiled: October 16, 2006Date of Patent: November 19, 2013Inventors: Weichuan Lu, Mei Li
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Publication number: 20130274360Abstract: The invention is related to a process for preparing a vulcanizable rubber composition comprising at least one elastomeric polymer, at least one phenol formaldehyde resin cross-linker, an activator package, and at least one activated zeolite, and a vulcanizable rubber composition prepared by said process. The invention also relates to a process for the manufacture of a vulcanized article comprising the steps of preparing a vulcanizable composition by the process mentioned before, shaping, and vulcanizing the vulcanizable rubber composition. The invention further relates to a vulcanized article.Type: ApplicationFiled: April 9, 2013Publication date: October 17, 2013Applicant: LANXESS ELASTOMERS B.V.Inventors: Philip James HOUGH, Martin VAN DUIN
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Patent number: 8552076Abstract: Disclosed herein is a method of preparing a fused aerogel-polymer composite in which aerogel and an organic polymer is mixed in a dry state to adsorb polymer particles on the surface of the aerogel and are then subjected to thermal treatment, thus forming a polymer coating on the aerogel. The fused aerogel-polymer composite can be used for thermal insulation in a variety of applications. The fused aerogel-polymer composite exhibits high thermal insulation properties and superior physical strength and processability while still maintaining the properties of an aerogel that does not have a polymer coated on its surface.Type: GrantFiled: April 10, 2008Date of Patent: October 8, 2013Assignee: Samsung Electronics Co., Ltd.Inventor: Myung Dong Cho
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Patent number: 8461221Abstract: Antifoam particles contain: (A) porous copolymers of urea or melamine or a mixture thereof with an alkanal, and (B) a silicone antifoam composition which is liquid at 0° C. The invention also provides pulverulent antifoam agents which comprise antifoam particles and optionally further carrier materials.Type: GrantFiled: May 5, 2010Date of Patent: June 11, 2013Assignee: Wacker Chemie AGInventors: Richard Becker, Herbert Siegl
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Publication number: 20130065975Abstract: The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.Type: ApplicationFiled: March 14, 2011Publication date: March 14, 2013Inventors: Hiroshi Natsui, Hiroshi Yamauchi, Hiroyuki Morita
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Publication number: 20130056151Abstract: The present invention relates to heat-curable compositions containing a mixture of reactive epoxy resins that contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and at least one latent hardener.Type: ApplicationFiled: November 5, 2012Publication date: March 7, 2013Applicant: Henkel AG & Co. KGaAInventor: Henkel AG & Co. KGaA
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Patent number: 8304465Abstract: A method for the preparation of high strength air-dried organic aerogels. The method involves the sol-gel polymerization of organic gel precursors, such as resorcinol with formaldehyde (RF) in aqueous solvents with R/C ratios greater than about 1000 and R/F ratios less than about 1:2.1. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be air dried at ambient temperatures and pressures. The method significantly reduces the time and/or energy required to produce a dried aerogel compared to conventional methods using either supercritical solvent extraction. The air dried gel exhibits typically less than 5% shrinkage.Type: GrantFiled: January 18, 2006Date of Patent: November 6, 2012Assignee: Lawrence Livermore National Security, LLCInventors: Paul R. Coronado, Joe H. Satcher, Jr.
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Publication number: 20120232006Abstract: The invention relates to a process for producing polyurethane foams, by frothing and drying mixtures of specific polyurethane dispersions and crosslinkers.Type: ApplicationFiled: April 17, 2012Publication date: September 13, 2012Applicant: Bayer MaterialScience AGInventors: Jan Schönberger, Michael Mager, Thorsten Rische, Sebastian Dörr, Thomas Feller, Michael Heckes, Melita Dietze, Burkhard Fugmann
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Publication number: 20120225963Abstract: The invention is related to a vulcanizable rubber composition comprising an elastomeric polymer, a phenol formaldehyde resin cross-linker, and an activator package characterized in that the vulcanizable rubber composition comprises an activated zeolite. The invention also relates to a process for the manufacture of a vulcanized article comprising the steps of preparing a vulcanizable rubber composition, shaping the vulcanizable rubber composition and vulcanizing the shaped rubber composition. The invention further relates to a vulcanized article.Type: ApplicationFiled: October 7, 2011Publication date: September 6, 2012Applicant: LANXESS ELASTOMERS B.V.Inventors: Van Martin Duin, Philip James Hough
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Publication number: 20120122694Abstract: The invention refers to microcapsules whose capsule wall comprise resin, and which results through reaction of at least one aromatic alcohol or its ether or derivative and at least one aldehyde component, which includes at least two C-atoms per molecule.Type: ApplicationFiled: March 12, 2010Publication date: May 17, 2012Applicant: Follmann & Co. Gesellschaft fur Chemie-Werkstoffe und Verfahrenstechnik mbH & Co. KGInventors: Klaus Last, Daniel Mues
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Publication number: 20120064287Abstract: An aerogel composite comprises a support comprising a melamine-formaldehyde copolymer, wherein the support comprises a plurality of micro-openings, and an aerogel matrix disposed in the micro-openings.Type: ApplicationFiled: March 30, 2011Publication date: March 15, 2012Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Sang Ho PARK, Myung Dong CHO, Kwang Hee KIM, Sung Woo HWANG
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Publication number: 20120009407Abstract: A rigid polyurethane foam includes the reaction product of a resin composition and an isocyanate composition. The resin composition includes a novolac polyol that has a general chemical structure: In this structure, R is an alkyl or alkylene group and the novolac polyol has an average hydroxyl functionality of from 2 to 30 calculated by dividing the weight average molecular weight of the novolac polyol by the equivalent weight of the novolac polyol. The novolac polyol is present in an amount of from 3 to 65 parts by weight per 100 parts by weight of the resin composition.Type: ApplicationFiled: July 8, 2011Publication date: January 12, 2012Inventors: Calvin T. Peeler, Todd Wishneski, Greg P. Gardin
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Publication number: 20120009414Abstract: A formulation to prepare a low- to medium-index (1 to 2.5) polyurethane or polyisocyanurate foam includes from 20 to 60 percent by weight of a formulated polyol comprising an aromatic polyester polyol having a functionality greater than or equal to 2 and a hydroxyl number greater than about 50 mg KOH/g; from 10 to 30 percent by weight of a Novolac-type polyol; and from 5 to 40 percent by weight of a sucrose- or sorbitol-initiated polyether polyol having a hydroxyl number greater than about 200 mg KOH/g and a functionality of at least about 4. The foams may exhibit improved processability, resulting in, for example, reduced shrinkage and deformation in sandwich panels, and improved fire behavior as tested according to German Standard DIN 4102.Type: ApplicationFiled: March 17, 2010Publication date: January 12, 2012Applicant: Dow Global Technologies LLCInventor: Paolo Golini
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Publication number: 20110230578Abstract: A composite foam comprising A) foamed particles comprising A1) from 25 to 95% by weight of styrene polymer(s), A2) if appropriate, a blowing agent, and A3) if appropriate, one or more additives, and B) an aminoplastic component comprising B1) from 1 to 65% by weight of cured, if appropriate modified and if appropriate foamed aminoplastic resin, B2) from 0.1 to 20% by weight of one or more flame-retardant organic phosphorus compounds having from 5 to 80% by weight phosphorus content (based on the respective compound), and/or expandable graphite, B3) if appropriate, one or more flame-retardant synergists for component B2), B4) if appropriate, a blowing agent, and B5) if appropriate, one or more additives, where—unless otherwise stated—the percentages by weight are based on the entirety of components A1), B1) and B2), is particularly suitable as insulation material.Type: ApplicationFiled: March 17, 2011Publication date: September 22, 2011Applicant: BASF SEInventors: Maxim Peretolchin, Tobias Heinz Steinke, Matthias Pfeiffer, Sabine Fuchs, Ingo Bellin, Klaus Hahn, Günter Scherr, Karl-Heinz Schmitz
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Publication number: 20110039090Abstract: A light wood-containing material having an average density in the range from 200 to 600 kg/m3, comprising, based in each case on the wood-containing material: A) from 30 to 95% by weight of wood particles; B) from 1 to 15% by weight of a filler having a bulk density in the range from 10 to 100 kg/m3, selected from the group consisting of foamable plastic particles and already foamed plastic particles; C) from 3 to 50% by weight of a binder comprising an aminoplast resin and an organic isocyanate having at least two isocyanate groups and, if appropriate, D) additives.Type: ApplicationFiled: September 16, 2008Publication date: February 17, 2011Applicant: BASE SEInventors: Stephan Weinkötz, Michael Finkenauer, Michael Schmidt, Maxim Peretolchin
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Publication number: 20110003136Abstract: A light wood-containing material having an average density in the range from 200 to 600 kg/m3, comprising, based in each case on the wood-containing material: A) from 30 to 95% by weight of wood particles; B) from 1 to 25% by weight of a filler having a bulk density in the range from 10 to 150 kg/m3, selected from the group consisting of foamable plastic particles and already foamed plastic particles; C) from 0.1 to 50% by weight of a binder and, if appropriate, D) additives, the following relationship being true for the d? values according to Rosin-Rammler-Sperling-Bennet of the wood particles A) and of the particles of the filler B): d? of the particles A)?2.5×d? of the particles B).Type: ApplicationFiled: October 18, 2007Publication date: January 6, 2011Applicant: BASF SEInventors: Michael Schmidt, Michael Finkenauer, Günter Scherr, Frank Braun, Stephan Weinkötz, Jürgen von Auenmüller, Oliver Richter, Maxim Peretolchin
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Patent number: 7718751Abstract: The present invention concerns a pre-mix for a syntactic phenolic foam composition; a syntactic phenolic foam composition; and a process for preparing the syntactic phenolic foam composition. The pre-mix comprises thermally expandable and/or expanded thermoplastic microspheres, the microspheres comprising a thermoplastic polymer shell made of a homopolymer or copolymer of 100 to 25, for example 93 to 40, parts by weight of a nitrile-containing, ethylenically unsaturated monomer, or a mixture thereof; and 0 to 75, for example 7 to 60, parts by weight of a non-nitrile-containing, ethylenically unsaturated monomer, or a mixture thereof; and a propellant, or a mixture thereof, trapped within the thermoplastic polymer shell; and one of either a highly reactive phenolic resole resin capable of fully crosslinking at temperatures between 15° C. and 60° C.Type: GrantFiled: March 15, 2006Date of Patent: May 18, 2010Assignee: Pyro Technologies LimitedInventor: Murray Orpin
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Publication number: 20100021513Abstract: The invention relates to a cellular substance, the method of preparation and uses thereof, in particular as an absorbent substance, and in particular for the manufacture of sponges and other products for household use. The cellular substance of the invention comprises a mixture of fibers of a hydrophilic polymer, and at least one elastomer, and has a cellular structure formed by cells whose size is between 0.2 ?m and 10 mm, at least 1% of the cells, by volume as compared to the total cell volume, having a size of between 0.2 ?m and 10 ?m. The invention has application, particularly, in the area of absorbent products.Type: ApplicationFiled: August 28, 2007Publication date: January 28, 2010Applicant: HUTCHINSONInventors: Nicolas Garois, Philippe Sonntag, Natacha Carniol
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Patent number: 7605189Abstract: A process for producing a strong, lightweight, pH-neutral phenolic foam by providing a novelac resin and a resole resin with a solid-state blowing agent activated at a specific time in a melt for the formation of a foam.Type: GrantFiled: May 22, 2006Date of Patent: October 20, 2009Inventor: Gregory R. Brotz
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Publication number: 20090005466Abstract: The invention relates to a foam which has been made hydrophobic/oleophobic and comprises a foam matrix having open cells and having an impregnation which is made up essentially of a polyvinylidene halide (co)polymer which may optionally comprise further substituents and, if appropriate, additionally a fluorocarbon resin and/or silicone resin. The invention further relates to a process for producing this foam.Type: ApplicationFiled: August 22, 2006Publication date: January 1, 2009Applicant: BASF SEInventors: Horst Baumgartl, Christof Mock, Bernhard Vath
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Patent number: 7273894Abstract: Disclosed are novel compositions for the preparation of void-containing articles comprising a polymer matrix and a voiding agent The voiding agent comprises at least one first polymer and at least one second polymer, which are selected on the basis of physical properties such as glass transition temperature, tensile modulus, melting point, surface tension, and melt viscosity. Shaped articles such as sheet, film, bottles, tubes, labels, and sleeves may prepared from these compositions. Also disclosed are polyester shrink films prepared using a voiding agent comprising a novel blend of cellulosic and olefinic polymers. The resulting shrink films have better opacity, lower density, reduced shrink force, and improved printability as compared with most standard voiding agents. The films are useful for sleeve label and other shrink film applications and their lower density allows them to be readily separated from soft drink bottles, food containers and the like during recycling operations.Type: GrantFiled: September 16, 2004Date of Patent: September 25, 2007Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Tony Wayne Helton, Emerson Eston Sharpe, Jr.
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Patent number: 7115673Abstract: The present photosensitive resin composition 2 comprises a polyamic acid resin 4, a photosensitive agent, a dispersible compound 3 dispersible in the polyamic acid resin 4, and a solvent. The porous resin is obtained by removing the solvent from the photosensitive resin composition 2 to form a composition in which the dispersible compound 3 is dispersed in the polyamic acid resin 4, removing the dispersible compound to make the composition porous, and curing the porous photosensitive resin composition. The porous resin enables forming a fine circuit pattern and has a low dielectric constant and, when used as an insulating layer of a circuit board, brings about improved high frequency characteristics.Type: GrantFiled: December 17, 2003Date of Patent: October 3, 2006Assignee: Nitto Denko CorporationInventors: Amane Mochizuki, Takahiro Fukuoka, Mitsuhiro Kanada, Takayuki Yamamoto, Tomohiro Taruno
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Patent number: 6841584Abstract: Disclosed are compositions of short fiber reinforced phenolic foams, methods of making and using the same. The disclosed fiber-reinforced phenolic foams have a seven-fold increase in peel resistance over the unreinforced counterpart foam. The phenolic foam has enhanced fracture toughness without sacrificing the critical fire retardant properties.Type: GrantFiled: March 18, 2003Date of Patent: January 11, 2005Assignee: University of Southern CaliforniaInventors: Steven R. Nutt, Hongbin Shen
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Patent number: 6797737Abstract: This invention relates to crosslinked polymer foam compositions of an ethylene vinyl acetate copolymer, an acid copolymer or ionomer, and a crosslinking agent. Such compositions exhibit enhanced melt strength, as well as lower density and compression set. They are especially useful as midsoles or insoles for footwear.Type: GrantFiled: June 23, 2000Date of Patent: September 28, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Chin-Fu Hsu, Richard T. Chou, Wayne C. Whelchel, Yun-Tong Ou
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Patent number: 6790870Abstract: A method of producing a foamed material comprises contacting a mixture comprising a first thermoplastic polymer and a second thermoplastic polymer with a blowing agent, wherein the first thermoplastic polymer has a higher percent crystallinity that the second thermoplastic polymer; and subjecting the mixture to conditions sufficient to create a thermodynamic instability in the blend foam the mixture, wherein the mixture comprising the first and second thermoplastic polymers has a percent crystallinity lower than the first thermoplastic polymer.Type: GrantFiled: March 1, 2000Date of Patent: September 14, 2004Assignees: North Carolina State University, The University of North Carolina at Chapel HillInventors: Joseph M. DeSimone, Saad A. Khan, Joseph R. Royer, Richard J. Spontak, Teri Anne Walker, Yvon J. Gay, Srinivas Siripurapu
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Patent number: 6727293Abstract: Provided is a foamable composition adapted to form a cross-linked novolac-epoxy resin foam. The foamable composition is formulated from a composition comprising at least one novolac resin, at least one epoxy resin, and at least one blowing agent.Type: GrantFiled: June 19, 2003Date of Patent: April 27, 2004Assignee: American Foam Technologies, Inc.Inventor: Samuel L. Rader
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Publication number: 20040039074Abstract: Hydrophilic open-celled resilient foams comprising melamine-formaldehyde resins, obtainable byType: ApplicationFiled: March 10, 2003Publication date: February 26, 2004Inventors: Hans-Joachim Hahnle, Horst Baumgartl, Norbert Herfert
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Patent number: 6607817Abstract: A melamine resin foam endowed with excellent oil repellency and which is improved in fragility without deteriorating the superior properties inherently possessed by melamine resin foams. The melamine resin foam with excellent oil repellency is obtained by coating an oleophobic component on a base material produced by foaming a resin composition comprising, as the main components, a melamine-formaldehyde condensate and a foaming agent.Type: GrantFiled: April 4, 2000Date of Patent: August 19, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Yasuo Imashiro, Shun Hasegawa, Takahiko Matsumoto
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Patent number: 6541530Abstract: A urethane-modified polyisocyanurate foam obtained by reacting (A) a polyisocyanate compound component, (B) a polyol component, containing a modified phenolic resin obtained by adding 20 to 100 parts by weight of a polyhydric alcohol or its alkylene oxide adduct to 100 parts by weight of a benzylic ether type phenolic resin and heating under a reduced pressure, in an amount of at least 3 wt % to the total resin component, (C) water and (D) a foam stabilizer comprising a mixture of at least 2 silicone type surfactants having different surface tensions wherein a surfactant having a higher surface tension has a surface tension of higher than 22 dyne/cm and a surfactant having a lower surface tension has a surface tension of at most 22 dyne/cm, in the presence of (E) a urethane-forming catalyst and/or a trimerization catalyst.Type: GrantFiled: November 27, 2001Date of Patent: April 1, 2003Assignee: Hodogaya Chemical Co., Ltd.Inventors: Tsuyoshi Sato, Tsutomu Nakamura
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Patent number: 6492432Abstract: Provided is a foamable composition adapted to form a cross-linked novolac-epoxy resin foam. The foamable composition is formulated from a composition comprising at least one novolac resin, at least one epoxy resin, and at least one blowing agent.Type: GrantFiled: November 9, 1999Date of Patent: December 10, 2002Assignee: American Foam Technologies, Inc.Inventor: Samuel L. Rader
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Patent number: 6455602Abstract: An expandable composition comprising: (A) about 60 to about 98 percent by weight of a polyolefin or mixture of polyolefins wherein the polyolefin or mixture has an &eegr;0 of less than about 9.0 kilopascal.seconds (kPa.s), a Jr greater than about 50×10−5/pascals (Pa), and an Ea greater than about 6.7 kilocalories per mole (kcal/mol); and (B) about 2 to about 40 percent by weight of a polyolefin or mixture of polyolefins having an nRSI greater than about 4.5, and no greater than about 19; or (C) a polyolefin or mixture of polyolefins wherein the polymer or mixture has an &eegr;0 of less than about 9.0 kilopascal.seconds, a Jr greater than about 50×10−5/pascals, an Ea greater than about 6.7 kilocalories/mole, and an nRSI greater than about 9.Type: GrantFiled: October 24, 2000Date of Patent: September 24, 2002Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Sandra Maki, Geoffrey David Brown, Scott Hanley Wasserman, David John Frankowski, Vicky Yafen He
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Publication number: 20010038831Abstract: A superporous hydrogel composite is formed by polymerizing one or more ethylenically-unsaturated monomers, and a multiolefinic crosslinking agent, in the presence of particles of a disintegrant and a blowing agent. The disintegrant, which rapidly absorbs water, serves to greatly increase the mechanical strength of the superporous hydrogel and significantly shorten the time required to absorb water and swell. Superporous hydrogel composites prepared by this method have an average pore size in the range of 10 &mgr;m to 3,000 &mgr;m. Preferred particles of disintegrant include natural and synthetic charged polymers, such as crosslinked sodium carboxymethylcellulose, crosslinked sodium starch glycolate, and crosslinked polyvinylpyrrolidone. The blowing agent is preferably a compound that releases gas bubbles upon acidification, such as NaHCO3. Improved hydrogel composites formed without a blowing agent are also provided.Type: ApplicationFiled: March 16, 2001Publication date: November 8, 2001Inventors: Kiham Park, Haesun Park
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Publication number: 20010009930Abstract: A foamed elastomer is presented, manufactured from a foam precursor composition comprising at least one elastomer resin, preferably an ethylene-propylene-diene resin, at least one thermoset resin, preferably a melamine-formaldehyde resin, a curing agent, and a blowing agent. The elastomer composition optionally further includes cure activators, polymerization accelerators, and a filler material. An important feature of the present invention is that the foamed elastomer has a low density and a high modulus, making it particularly suitable as a shock absorber for a bicycle suspension apparatus.Type: ApplicationFiled: February 10, 1999Publication date: July 26, 2001Inventors: MICHAEL S. LUNT, VINCENT R. LANDI, MURALI SETHUMADHAVAN
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Patent number: 6031012Abstract: Provided is a curable composition comprising (A) a phenolic compound having a carbon-carbon double bond, (B) a compound having an SiH group, and (C) a foaming agent. The composition can be foamed and cured at room temperature or under heat at relatively low temperatures, and is poorly corrodable and poorly toxic.Type: GrantFiled: October 27, 1998Date of Patent: February 29, 2000Assignee: Kaneka CorporationInventors: Naoaki Nakanishi, Koji Himeno, Shintaro Komitsu
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Patent number: 5990184Abstract: Process for making polyisocyanate based aerogels by trimerisation of an organic polyisocyanate in an organic solvent in the presence of a (co)polymer containing an isocyanate-reactive group, gellation and supercritically drying of the obtained sol-gel.Type: GrantFiled: March 31, 1998Date of Patent: November 23, 1999Assignee: Imperial Chemical Industries PLCInventor: Guy Leon Jean Ghislain Biesmans
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Patent number: 5973015Abstract: A flexible aerogel and process of fabrication. An aerogel solution is mixed with fibers in a mold and allowed to gel. The gel is then processed by supercritical extraction, or by air drying, to produce a flexible aerogel formed to the shape of the mold. The flexible aerogel has excellent thermal and acoustic properties, and can be utilized in numerous applications, such as for energy absorption, insulation (temperature and acoustic), to meet the contours of aircraft shapes, and where space is limited since an inch of aerogel is a 4-5 times better insulator than an inch of fiberglass. The flexible aerogel may be of an inorganic (silica) type or an organic (carbon) type, but containing fibers, such as glass or carbon fibers.Type: GrantFiled: February 2, 1998Date of Patent: October 26, 1999Assignee: The Regents of the University of CaliforniaInventors: Paul R. Coronado, John F. Poco
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Patent number: 5945084Abstract: This pertains to the general field of gels, foams, and aerogels, particularly, to low density open cell organic foams and low density open cell carbon foams, and methods for preparing them. These low density open cell organic foams are derived from organic gels which may be prepared from hydroxylated benzenes (such as phenol, catechol, resorcinol, hydroquinone, and phloroglucinol) and aldehydes (such as formaldehyde and furfural) using lower than conventional catalyst concentrations (e.g, an R/C value of greater than about 1000, yielding an initial room temperature pH typically lower than about 6.0). These organic foams are characterized by relatively large particle and pore sizes, high porosity, and high surface area. Low density open cell carbon foams derived from such organic foams are also shown, as are methods for preparing same. These carbon foams are also characterized by relatively large particle and pore sizes, high porosity, high surface area, and high electrical capacitance.Type: GrantFiled: July 5, 1997Date of Patent: August 31, 1999Assignee: Ocellus, Inc.Inventor: Michael W. Droege
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Patent number: 5900320Abstract: The present invention aims to improve soundproof and heat insulating properties of a foamed plastic by reducing internal cells pressure inside foamed resins. A base polymer such as a polyester-based polyol and a volatile foaming agent having an conjugate unsaturated group (i.e., conjugate double carbon bonds and/or triple carbon bonds) such as chloroprene (bp. 51.degree. C.) and calcium stearate were blended and then mixed with a hardening agent such as hexamethylene diisocyanate. The volatile foaming agent existing in open cells of the foamed plastic sealed in the Al laminated film and between the film and the foamed plastic, i.e., gap, possesses an unsaturated group, such as isoprene. Thus polymerization may occur by irradiating with electron rays, and the inside of the foams and the gap region may be reduced in pressure while the bag of the laminated film retains its shape.Type: GrantFiled: May 26, 1993Date of Patent: May 4, 1999Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Kazufumi Ogawa
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Patent number: 5859082Abstract: An insulating foam composition, comprising a polyisocyanate component and a resin component that includes a polyepoxide, an aromatic polyester polyol, and a melamine resin. The foam will remain stable at temperatures up to 400.degree. F., continuously, and up to 450.degree. F., intermittently, and can be applied by spraying, pouring, or frothing directly onto surface of high temperature industrial apparatus.Type: GrantFiled: November 5, 1997Date of Patent: January 12, 1999Inventor: Aniq Sufi