Interpolymer Patents (Class 521/144)
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Patent number: 11220592Abstract: Compositions may include a tactile polymer composition prepared from a mixture of polyolefin and a rubber component, wherein the mixture is prepared in a post-reactor process, and wherein the tactile polymer composition has a complex viscosity at 0.10 rad/s according to ASTM D4440 in the range of 1,000 to 40,000 Pa·s. Methods may include preparing a tactile polymer composition by combining a mixture of polyolefin and a rubber component at elevated temperature to produce a blended polymer composition; wherein the tactile polymer composition has a complex viscosity at 0.10 rad/s according to ASTM D4440 in the range of 1,000 to 40,000 Pa·s.Type: GrantFiled: May 6, 2019Date of Patent: January 11, 2022Assignee: Braskem S.A.Inventors: Leonardo Souza Bento, Augusto Cesar Esteves
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Patent number: 11015035Abstract: Foamed compositions that include: one or more foamable polymers; one or more ionomeric additives; and wherein the foam composition exhibits shrinkage as determined at 70° C.*1 h according to the PFI method between 0.1 and 3.5%. Methods may include preparing a polymer composition by combining one or more foamable polymers and one or more ionomeric additives in a mixer to produce the polymer composition; and foaming the polymer composition to generate a polymer foam exhibiting shrinkage as determined at 70° C.*1 h according to the PFI method of between 0.1 and 3.5%.Type: GrantFiled: November 5, 2018Date of Patent: May 25, 2021Assignee: Braskem S.A.Inventors: Ana Paula Rodrigues Camilo, Giancarlos Delevati, Gislene Zehetmeyer, Mauro Alfredo Soto Oviedo
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Patent number: 10920039Abstract: To improve the thermal stability of a brominated polymer type flame retardant in a flame-retardant resin composition containing a styrene-based resin and the brominated polymer type flame retardant to provide a flame-retardant resin molded article in which occurrences of black foreign substances and discoloration decrease The flame-retardant resin composition contains a styrene-based resin, a brominated polymer type flame retardant, an epoxy compound, and a halogen capture agent, wherein a content of bromine is 18 to 42% by mass.Type: GrantFiled: September 29, 2017Date of Patent: February 16, 2021Assignee: TOYO STYRENE CO., LTD.Inventors: Katsunori Konno, Takaaki Okada, Toshiharu Kurata, Hiromi Daigo
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Patent number: 10899902Abstract: A composition for an expandable sealant including at least one polymeric material selected from the group consisting of low density polyethylenes (LDPE), linear low density polyethylenes (LLPDE), ethylene vinyl acetate (EVA), ethylene methacrylate (EMA), and ethylene-butyl acrylate (EnBA); and a chemical blowing agent, wherein the composition is substantially free of a cross-linking agent.Type: GrantFiled: June 22, 2016Date of Patent: January 26, 2021Assignee: SIKA TECHNOLOGY AGInventors: Leslie Michele Wolschleger, Jena Mabilia, Sascha Pasula
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Patent number: 10550258Abstract: To improve the thermal stability of a brominated polymer type flame retardant in a flame-retardant resin composition containing a styrene-based resin and the brominated polymer type flame retardant to provide a flame-retardant resin molded article in which occurrences of black foreign substances and discoloration decrease. The flame-retardant resin composition contains 0.8 to 15 parts by mass of a halogen capture agent, 0.8 to 7 parts by mass of an antioxidant, and 0.8 to 6 parts by mass of liquid paraffin based on a total of 100 parts by mass of a styrene-based resin and brominated polymer type flame retardant, and a content of bromine is 18 to 42% by mass.Type: GrantFiled: September 29, 2017Date of Patent: February 4, 2020Assignee: TOYO STYRENE CO., LTDInventors: Takaaki Okada, Katsunori Konno, Toshiharu Kurata, Hiromi Daigo
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Patent number: 9909002Abstract: There are provided a resin composition capable of affording a cross-linked foam excellent in heat storage performance, a cross-linked product of the resin composition, and a method for producing the cross-linked product. Specifically, there is provided a resin composition containing an olefin polymer comprising a main chain containing monomer units derived from ethylene and branch chains having 5 or more carbon atoms, the number of the branch chains being within the range of 20 chains to 40 chains per 1000 carbon atoms constituting the olefin polymer, and having a melting peak temperature measured with DSC of within the range of 10° C. to 50° C., a crystallization peak temperature measured with DSC of within the range of 0° C. to 40° C., and a melt enthalpy measured with DSC of 50 J/g or more, and an olefin polymer having a melting peak temperature measured with DSC of within the range of 50° C. to 180° C.Type: GrantFiled: April 8, 2015Date of Patent: March 6, 2018Assignee: Sumitomo Chemical Company, LimitedInventors: Yasutoyo Kawashima, Yoshinobu Nozue
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Patent number: 9381723Abstract: Cellular thin films include a first side separated from a second side, the separation of which defines the thickness of the thin film; at least one layer of a polymeric material arranged along the thickness of the thin film, wherein the polymeric material includes cells and the first and second sides of the thin film have exterior surfaces that have substantially the same thickness as the interior walls forming the cells. The surfaces of the thin films have bumps caused by the cells. The thin exterior surfaces of the thin films is advantageous to allow the films to be flexible.Type: GrantFiled: September 12, 2008Date of Patent: July 5, 2016Assignee: University of WashingtonInventors: Vipin Kumar, John Chunpo Lu, Henry G. Schirmer, Dustin Miller
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Publication number: 20150133575Abstract: The invention relates to a process for the production of polyethylene. The polymerisation takes place in the presence of a catalyst system comprising a hydrocarbon solution containing 1) a dialkoxy magnesium compound and 2) an organic oxygen containing titanium compound further comprising an inorganic oxide support and an activator.Type: ApplicationFiled: April 22, 2013Publication date: May 14, 2015Inventors: Nicolaas Hendrika Friederichs, Remy Peter Theresia Smeets, Matthijs van Kessel
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Publication number: 20150017365Abstract: Multimodal polyolefin resin having excellent characteristics such as moldability, mechanical strength, external appearance and a polyolefin resin molded product are disclosed. The polyolefin resin satisfies all requirements of following (1) to (5), (1) density (d): 0.934 to 0.963 g/cm3, (2) melt flow index (MIE, 190° C., 2.16 kg load condition): 0.01 to 1.0 g/10 minutes, (3) ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) measured by Gel Permeation Chromatography (GPC) (Mw/Mn, Molecular weight distribution (MWD)): 12 to 60, (4) at least two peaks appear when the molecular weight of the polyolefin resin is measured with GPC, and (5) amount of polyolefin having Mw of 10,000 or less exceeds 15 weight % and amount of polyolefin having Mw of 1,000,000 or more exceeds 1.5 weight %, when the molecular weight of the polyolefin resin is measured with GPC.Type: ApplicationFiled: September 30, 2014Publication date: January 15, 2015Inventors: Byung-Keel Sohn, Seung-Tack Yu, Sang-Won Yoo, Young-Jae Jun, Sah-Mun Hong
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Publication number: 20140357743Abstract: A method is presented for forming a collapsed foam film-like structure, the method including positioning a composition applicator adjacent to a hot non-permeable dryer surface, producing a first frothed dispersion or frothed solution from a first dispersion or solution, applying the first frothed dispersion or frothed solution to the dryer surface, allowing the first frothed dispersion or frothed solution to convert to a collapsed foam film-like structure, and scraping the collapsed foam film-like structure from the dryer surface. The method can further include producing a second dispersion or solution, blending the first dispersion or solution and the second dispersion or solution, frothing the blended dispersion or solution, applying the blended frothed dispersion or frothed solution to the dryer surface, and allowing the frothed dispersion or frothed solution to convert to a collapsed foam film-like structure.Type: ApplicationFiled: May 30, 2013Publication date: December 4, 2014Applicant: Kimberly-Clark Worldwide, Inc.Inventors: Keyur Desai, Jian Qin, Jeffrey Frank Jurena, Frank Paul Abuto, Susan Elaine Shawver, Donald Eugene Waldroup, Deborah Joy Calewarts
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Patent number: 8901182Abstract: Process for producing expanded polyolefin resin particles with use as a foaming agent in water contained in an aqueous dispersion medium. The process includes dispersing polyolefin resin particles with use as a foaming agent of water contained in an aqueous dispersion medium. The process includes dispersing polyolefin resin particles together with the aqueous dispersion medium into a closed vessel, heating the polyolefin resin particles up to or above a softening temperature of the polyolefin resin particles and pressurizing the polyolefin resin particles, and releasing the polyolefin resin particles into a zone whose pressure is lower than an internal pressure of the closed vessel. The polyolefin resin particles are composed of a polyolefin resin composition including a polyolefin resin, polyethylene glycol homopolymer and a foam nucleating agent.Type: GrantFiled: February 27, 2013Date of Patent: December 2, 2014Assignee: Kaneka CorporationInventors: Jun Fukuzawa, Hiroshi Tsuneishi
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Patent number: 8901183Abstract: Expandable composite resin particles for long-term storage, comprising 500 to 5000 ppm of water and 7.5 to 11.0% by weight of pentane in composite resin of polyolefin-based resin and polystyrene-based resin.Type: GrantFiled: March 14, 2014Date of Patent: December 2, 2014Assignee: Sekisui Plastics Co., Ltd.Inventors: Yasutaka Tsutsui, Masahiko Ozawa
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Patent number: 8871825Abstract: There is provided a polypropylene resin composition comprising a propylene polymer (A) containing 0 to 70% by mass of a propylene homopolymer (A-1) and 30 to 100% by mass of a propylene-ethylene block copolymer (A-2) defined below, an ethylene-?-olefin copolymer (B) defined below, and an inorganic filler (C), wherein the proportion of the amount of the (A), the proportion of the amount of (B), and the proportion of the amount of (C) relative to the total amount of the (A), the (B) and the (C) are 40 to 94% by mass, 5 to 30% by mass, and 1 to 30% by mass, respectively, the propylene-ethylene block copolymer (A-2) is a mixture of a propylene homopolymer component and a propylene-ethylene random copolymer component, wherein the intrinsic viscosity, as measured in Tetralin of 135° C., of the propylene-ethylene random copolymer component is within the range of 2.0 to 8.Type: GrantFiled: October 30, 2008Date of Patent: October 28, 2014Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroyoshi Nakajima, Yoshitaka Kobayashi, Takashi Fujimoto
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Publication number: 20140208619Abstract: Disclosed are footwear soles comprising a propylene-based elastomer. The presence of the propylene-based elastomer provides the footwear sole with a well-balanced combination of desired properties, including low density, low compression set, and weldability.Type: ApplicationFiled: January 29, 2013Publication date: July 31, 2014Applicant: ExxonMobil Chemical Patents Inc.Inventors: Leander Kenens, Randal H. Kerstetter, III
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Patent number: 8785531Abstract: A dispersion and methods for forming a dispersion that includes a catalytic linear multi-block olefin interpolymer, and at least one dispersing agent, wherein the catalytic linear multi-block olefin interpolymer includes at least one hard segment and at least one soft segment is disclosed. Various applications of the dispersion are also disclosed.Type: GrantFiled: July 2, 2007Date of Patent: July 22, 2014Assignee: Dow Global Technologies LLCInventors: Mark W. VanSumeren, Ronald Wevers, Charles F. Diehl, Gary M. Strandburg, Brad Maurice Moncla, Kevin D. Maak
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Patent number: 8779019Abstract: A noncrosslinked polyethylene resin expanded particle is provided having a bulk density BD in a range of 10 g/L to 100 g/L, the particle being obtained by expanding a polyethylene resin particle whose density is in a range of 0.920 g/cm3 to 0.940 g/cm3, the noncrosslinked polyethylene resin expanded particle having a shrinkage factor in a range of 2% to 30%, the shrinkage factor being obtained by the following formula (1): Shrinkage Factor =(BD?VBD)×100/VBD??(1), wherein: the BD of the noncrosslinked polyethylene expanded particle is a bulk density at 23° C. and at 0.1 MPa (at a normal atmospheric pressure); and the VBD of the noncrosslinked polyethylene expanded particle is a bulk density at 23° C. and at a reduced pressure of 0.002 MPa or less.Type: GrantFiled: January 14, 2011Date of Patent: July 15, 2014Assignee: Kaneka CorporationInventor: Kiyotaka Nakayama
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Patent number: 8765826Abstract: Expandable composite resin particles for long-term storage, comprising 500 to 5000 ppm of water and 7.5 to 11.0% by weight of pentane in composite resin of polyolefin-based resin and polystyrene-based resin.Type: GrantFiled: March 2, 2010Date of Patent: July 1, 2014Assignee: Sekisui Plastics Co., Ltd.Inventors: Yasutaka Tsutsui, Masahiko Ozawa
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Patent number: 8735471Abstract: Polyolefin dispersions, froths, and foams and articles manufactured therefrom are disclosed. Also disclosed is a method for generating a thermoplastic foam from an aqueous dispersion. The aqueous dispersion may include a thermoplastic resin, water, and a stabilizing agent. The method may include adding at least one frothing surfactant to the aqueous dispersion to form a mixture, adding a flame retardant and/or a phase change material, frothing the mixture to create a froth, and removing at least a portion of the water to produce the foam.Type: GrantFiled: July 2, 2013Date of Patent: May 27, 2014Assignee: Dow Global Technologies LLCInventor: Bruce Menning
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Publication number: 20140128490Abstract: The present invention relates to a foam rubber material for a weather strip comprising a crosslinked rubber sponge material having a load value ratio satisfying the following relationship: load value ratio (%)=B/A×100?50, wherein A is a load value at 50% compression in the course of compression deformation, and B is a load value at 50% compression in the course of returning from the deformation.Type: ApplicationFiled: November 4, 2013Publication date: May 8, 2014Applicant: NISHIKAWA RUBBER CO., LTD.Inventor: Michio KIJIMA
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Patent number: 8658732Abstract: Solid state draw a polymer billet, wherein at least 50 percent of all polymers in the billet is a continuous phase of polyethylene polymer having a density of 0.941-0.959 grams per cubic centimeter and a weight-average molecular weight that is 110,000 grams per mole or greater, at a drawing rate of 1.2 meters per minute or faster using a tensile force to create an oriented and cavitated polymer composition whose cross section dimensions all exceed two millimeters.Type: GrantFiled: March 2, 2010Date of Patent: February 25, 2014Assignee: Eovations, LLCInventors: Kevin L. Nichols, William J. Michie, Jr., Mridula Kapur
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Patent number: 8652621Abstract: The present invention provides an article with at least one switching segment. The switching segment comprises a shape-memory compound and an isolating region surrounding the shape memory compound. The present invention also provides a method of producing such an article.Type: GrantFiled: October 30, 2009Date of Patent: February 18, 2014Assignee: Helmholtz-Zentrum Geesthacht Zentrum fur Material und Kustenforschung GmbHInventors: Thomas Weigel, Andreas Lendlein, Karola Lützow, Frank Klein, Samy Madbouly
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Publication number: 20130310476Abstract: Polypropylene resin expanded particles comprising: a polypropylene resin as a base material resin, the propylene resin having at least two melting peaks on a DSC curve for a second temperature rise measured at a heating rate of 10 g/min with use of a heat flux differential scanning calorimeter (DSC), the at least two melting peaks including (i) a lowest temperature melting peak of not lower than 100° C. and not higher than 130° C. and (ii) a highest temperature melting peak of not lower than 140° C. and not higher than 160° C., the propylene resin having a resin DSC ratio change rate of 0.5%/° C. to 3.0%/° C., the expanded particles having two melting peaks in a DSC measurement made at a first temperature rise at the heating rate of 10 g/min, the two melting peaks including, (i) on a lower temperature side, a melting peak temperature of not lower than 100° C. and not higher than 130° C. and, (ii) on a higher temperature side, a melting peak temperature of not lower than 140° C. and not higher than 160° C.Type: ApplicationFiled: February 1, 2012Publication date: November 21, 2013Applicant: KANEKA CORPORATIONInventor: Kenichi Senda
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Publication number: 20130302583Abstract: Polyolefin dispersions, froths, and foams and articles manufactured therefrom are disclosed. Also disclosed is a method for generating a thermoplastic foam from an aqueous dispersion. The aqueous dispersion may include a thermoplastic resin, water, and a stabilizing agent. The method may include adding at least one frothing surfactant to the aqueous dispersion to form a mixture, adding a flame retardant and/or a phase change material, frothing the mixture to create a froth, and removing at least a portion of the water to produce the foam.Type: ApplicationFiled: July 2, 2013Publication date: November 14, 2013Inventor: Bruce A. Menning
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Patent number: 8513317Abstract: Provided is a process for producing expanded polyolefin resin particles whose cells are not made nonuniform or extremely smaller as seen in conventional expanded particles, whose cell diameter and expansion ratio can be easily controlled independently, and which, when subjected to in-mold expansion molding, give in-mold expanded molded products satisfactory in fusibility and excellent in surface properties.Type: GrantFiled: December 3, 2008Date of Patent: August 20, 2013Assignee: Kaneka CorporationInventors: Jun Fukuzawa, Hiroshi Tsuneishi
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Patent number: 8492447Abstract: A closed cell foam material contains a propylene based polymer comprising from about 5% to about 32% by weight ?-olefin units. The propylene based polymer has a heat of fusion, as determined by DSC, of less than 80 J/g. The material also contains 0.5 to 5 phr peroxide, 1.0 to 5.0 phr blowing agent, and 0.1 to 10 phr co-agent. The cells of closed cell foam material have a diameter in the range of 0.1 to 1.5 mm.Type: GrantFiled: April 1, 2008Date of Patent: July 23, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sunny Jacob, Abdelhadi Sahnoune, Jun Tong, Randal Howard Kerstetter
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Patent number: 8461222Abstract: There is provided a shoe sole component that has properties such as strength and cushioning property that are suppressed from being changed even under a wide temperature range from severe cold at ?10° C. or lower to high temperature conditions exceeding 30° C. A shoe sole component includes a cross-linked foam of a resin composition, the resin composition containing a thermoplastic polyolefin resin, in which tan ? (?20° C. to 40° C.) at a frequency of 10 Hz measured according to JIS K 7244-4 is 0.01 to 0.5, and tan ? (?20° C.)/tan ? (40° C.) at a frequency of 10 Hz is 0.7 to 1.3.Type: GrantFiled: July 19, 2011Date of Patent: June 11, 2013Assignee: ASICS CorporationInventors: Sadaki Mori, Katsuhiro Imazato, Kenichi Harano, Akiyuki Morikawa
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Publication number: 20130116356Abstract: Olefin polymer-based, durable, open-cell foam compositions, structures and articles derived from same; methods for preparation of such foams; and use of the dry durable foams in various applications are disclosed. Further described is use of the foams and structures and articles made of same in absorption, filtration, insulation, cushioning and backing applications, and in particular for odor removal, hygiene and medical applications due to, among other properties, good absorption capabilities, softness and/or flexibility of the foams and their recyclable nature.Type: ApplicationFiled: December 14, 2012Publication date: May 9, 2013Applicant: Dow Global Technologies LLCInventor: Dow Global Technologies LLC
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Publication number: 20130101847Abstract: Dispersions and methods for forming dispersions that include a higher crystallinity polyolefin and at least one dispersing agent are disclosed. Various applications for use of the dispersions are also disclosed.Type: ApplicationFiled: October 23, 2012Publication date: April 25, 2013Applicant: Dow Global Technologies LLCInventor: Dow Global Technologies LLC
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Patent number: 8420707Abstract: Disclosed herein are a biomass composite composition and a foaming method thereof. The biomass composite composition includes (a) polyester alloy containing biodegradable polyester and petrochemical plastic, (b) reinforcing agent, (c) foaming agent, (d) compatibilizer, (e) lubricant, and (f) impact modifier. The biomass composite composition of the present invention is biodegradable and of heat resistance and melt strength suitable for manufacture of foam products.Type: GrantFiled: October 19, 2010Date of Patent: April 16, 2013Inventors: Jong-Wu Chen, Hsiang-Jen Hsiao, Chia-Hung Li, Chin-Fu Chen
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Publication number: 20130053465Abstract: The ethylene-?-olefin copolymer contains monomer units derived from ethylene and monomer units derived from an ?-olefin having 3 to 20 carbon atoms for producing a foam. The ethylene-?-olefin copolymer has a melt flow rate of 0.1 to 100 g/10 minutes, a density of 850 to 940 kg/m3, a molecular weight distribution of 2 to 12, a swell ratio of 1.61 or more, and a value of g* as defined by a formula (I) of 0.50 to 0.78.Type: ApplicationFiled: April 19, 2011Publication date: February 28, 2013Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Toshihiko Manami, Yoshinobu Nozue
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Patent number: 8344037Abstract: A resin composition for cross-linking foam molding having a polymer composition which comprises 100 parts by weight of the following component (A) and 0.5 to 20 parts by weight of the following component (B); a foaming agent; and a cross-linking agent, wherein the component (A) is an ethylene-based polymer satisfying the following conditions (a1) to (a2): (a1) the density is 860 to 935 kg/m3, and (a2) the melt flow rate (MFR) is 0.1 to 10 g/10 minutes, and the component (B) is an ethylene-?-olefin copolymer satisfying the following conditions (b1) to (b3): (b1) the density is 890 to 925 kg/m3, (b2) the intrinsic viscosity [?] determined in a tetralin solution is 4 to 15 dL/g, and (b3) the activation energy of flow (Ea) is less than 50 kJ/mol.Type: GrantFiled: August 27, 2009Date of Patent: January 1, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Katsuhiro Yamada, Yoshinobu Nozue
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Patent number: 8338543Abstract: Thermoplastic vulcanizate elastomer obtained by dynamic vulcanization of a heterophasic polyolefin composition in presence of at least (i) an alkenyl-substituted alkoxysilane grafting agent and (ii) water; wherein said heterophasic polyolefin composition has flexural modulus equal to or lower than 150 MPa, and comprises: (a) a crystalline propylene homopolymer or copolymer of propylene with up to 15% of ethylene or other alpha-olefin comonomer(s), or their combinations, and (b) a copolymer or a composition of copolymers of ethylene with other alpha-olefins, containing from 15% to 40% of ethylene, said thermoplastic vulcanizate elastomer having compression set values in the range from 45-65%, the ratio of elongation at break to compression set values over 10 and hardness shore A values below 90.Type: GrantFiled: May 15, 2007Date of Patent: December 25, 2012Assignee: Basell Poliolefine Italia s.r.l.Inventors: Gilberto Moscardi, Enrico Costantini
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Publication number: 20120283347Abstract: A noncrosslinked polyethylene resin expanded particle is provided having a bulk density in a range of 10 g/L to 100 g/L, the particle being obtained by expanding a polyethylene resin particle whose density is in a range of 0.920 g/cm3 to 0.940 g/cm3, the noncrosslinked polyethylene resin expanded particle having a shrinkage factor in a range of 2% to 30%, the shrinkage factor being obtained by the following formula (1): Shrinkage Factor=(BD?VBD)×100/VBD??(1), wherein: the BD of the noncrosslinked polyethylene expanded particle is a bulk density at 23° C. and at 0.1 MPa (at a normal atmospheric pressure); and the VBD of the noncrosslinked polyethylene expanded particle is a bulk density at 23° C. and at a reduced pressure of 0.002 MPa or less.Type: ApplicationFiled: January 14, 2011Publication date: November 8, 2012Inventor: Kiyotaka Nakayama
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Publication number: 20120123006Abstract: Disclosed is a resin composition for crosslinking/foam molding which comprises a resin ingredient, a blowing agent, and a crosslinking agent, wherein the resin ingredient is an ethylene/?-olefin copolymer that comprises monomer units based on ethylene and monomer units based on an ?-olefin having 3 to 20 carbon atoms and satisfies all of the following: (1) to have a density of 860-950 kg/m3, (2) to have a melt flow rate (MFR) of 0.01-10 g/10 min, (3) to have a ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn), Mw/Mn, of 5.5-30, (4) to have a ratio of Z-average molecular weight (Mz) to weight-average molecular weight (Mw), Mz/Mw, of 2-4, and (5) to have a melt tension (MT) of 8 cN or higher.Type: ApplicationFiled: May 25, 2010Publication date: May 17, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Katsuhiro Yamada, Yoshinobu Nozue
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Publication number: 20120046373Abstract: Methods of making a foam article comprise the steps of compressing a foam at an elevated temperature in a mold for shaping the foam; and cooling the mold to a temperature greater than room temperature, wherein the foam comprises at least one ethylene/?-olefin block interpolymer. The foam may further comprise an ethylene vinyl acetate copolymer and an additive such as a filler or a crosslinking agent. The ethylene/?-olefin block interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block.Type: ApplicationFiled: January 28, 2010Publication date: February 23, 2012Inventors: Bee T. Low, Stephen Yausang Cheng
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Publication number: 20120040232Abstract: This invention relates to microporous membranes comprising polyolefin, the use of such membranes as battery separators, and methods for producing such microporous membranes. In particular, the invention relates to microporous membranes having a shutdown temperature in the range of 120.0° C. to 130.0° C. and a maximum solid state heat shrinkage ?30.0%.Type: ApplicationFiled: March 5, 2010Publication date: February 16, 2012Applicant: Toray Tonen Specialty Separator Godo KaishaInventors: Takeshi Ishihara, Satoshi Miyaoka, Koichi Kono, Donna J. Crowther, Patrick Brant
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Patent number: 8088835Abstract: It is an object of the present invention to provide a method for easily and economically producing an expansion-molded polypropylene-based resin article stably with a high porosity, that has continuous voids and that can be used as materials such as a sound absorbing material and a draining material. More specifically, the present invention relates to a method for producing an expansion-molded polypropylene-based resin article, in which a mold is filled with expanded polypropylene-based resin particles, and the expanded particles are heated and fused using water vapor, and then cooled, wherein expanded polypropylene-based resin particles are used in which a polypropylene-based resin having a melt index (MI) of not less than 0.1 g/10 minutes and not more than 9 g/10 minutes is used as a base resin, a cell size is not more than 150 ?m, two melting peaks are present on a DSC curve obtained by differential scanning calorimetry, and ?/(?+?) is not less than 0.35 and not more than 0.Type: GrantFiled: July 27, 2005Date of Patent: January 3, 2012Assignee: Kaneka CorporationInventors: Tomonori Iwamoto, Takayuki Gouda
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Patent number: 8008363Abstract: There is provided a shoe sole component that has properties such as strength and cushioning property that are suppressed from being changed even under a wide temperature range from severe cold at ?10° C. or lower to high temperature conditions exceeding 30° C. A shoe sole component includes a cross-linked foam of a resin composition, the resin composition containing a thermoplastic polyolefin resin, in which tan ? [?20° C. to 40° C.] at a frequency of 10 Hz measured according to JIS K 7244-4 is 0.01 to 0.5, and tan ? [?20° C.]/tan ? [40° C.] at a frequency of 10 Hz is 0.7 to 1.3.Type: GrantFiled: May 10, 2006Date of Patent: August 30, 2011Assignee: ASICS CorporationInventors: Sadaki Mori, Katsuhiro Imazato, Kenichi Harano, Akiyuki Morikawa
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Publication number: 20110172322Abstract: The invention relates to a long chain branched medium and low density polyethylene having a combination of the following properties: a) a density of from 0.910 to 0.945 g/cm3; b) an HLMI of from 2 to 150 dg/min and an MI2 of from 0.01 to 2 dg/min; c) a polydispersity index (PDI) Mw/Mn of at least 7, wherein Mw is the weight average molecular weight and Mn is the number average molecular weight of the polyethylene; and d) and a minimum amount of long chain branching measured by a value selected from one of grheo and LCBI. The invention also relates to a process for obtaining said polyethylene comprising the following steps: a) injecting ethylene, one or more alpha-olefinic comonomers comprising 3 to 10 carbon atoms and an activated chromium-based catalyst into a gas phase polymerisation reactor; b) copolymerising said ethylene and comonomer in said reactor in the gas phase; and c) retrieving an ethylene copolymer having a density of from 0.910 to 0.Type: ApplicationFiled: April 13, 2007Publication date: July 14, 2011Applicant: Total Petrochemicals Research FeluyInventors: Jacques Michel, Guy Debras, Philippe Bodart, Mieke Dams, Pascal Charlier
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Patent number: 7977397Abstract: The present invention relates to compositions comprising blends of alkenyl aromatic polymers such as styrenic polymers (i.e. PS and HIPS) and bio-based or biodegradable polymers (i.e. PLA, PGA, PHA, PBS, PCL) compatibilized with styrene-based copolymers (i.e. styrene-ethylene-butylene-styrene (SEBS) block copolymers, maleated SEBS, styrene-maleic anhydride (SMA) copolymer, styrene-methyl methacrylate (SMMA) copolymer) or a mixture of two or more styrene-based copolymers such as SEBS and SMA. These novel compositions can be extruded and thermoformed to produce very low density food service and consumer foam articles such as plates, hinged lid containers, trays, bowls, and egg cartons with good mechanical properties.Type: GrantFiled: March 14, 2008Date of Patent: July 12, 2011Assignee: Pactiv CorporationInventors: Yunwa Wilson Cheung, David V. Dobreski, Richard Turner, Mark Wheeler, Y. Paul Handa
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Publication number: 20110165407Abstract: The present invention relates to a multilayer insulation based on expandable and crosslinkable elastomeric material with improved low temperature resistance and flexibility, the process for manufacturing of such material and system, and the use of such material and system.Type: ApplicationFiled: January 7, 2011Publication date: July 7, 2011Inventors: Jürgen Weidinger, Steve Weiss
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Patent number: 7956096Abstract: The invention relates to thermally expandable thermoplastic microspheres comprising a polymer shell made from ethylenically unsaturated monomers encapsulating a propellant, said ethylenically unsaturated monomers comprising from 40 to 70 wt % of acrylonitrile, from 5 to 40 wt % of methacrylonitrile, from 10 to 50 wt % of monomers selected from the group consisting of esters of acrylic acid, esters of methacrylic acid and mixtures thereof, and said propellant comprising at least one of methane, ethane, propane, isobutane, n-butane and neo-pentane. The invention further relates to the production and use of the microspheres.Type: GrantFiled: February 9, 2007Date of Patent: June 7, 2011Assignee: Akzo Nobel N.V.Inventors: Ove Nordin, Heléne Ström, Christina Nyholm, Claes Hammer
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Patent number: 7947754Abstract: The present invention provides a foam comprising (a) a polylactic acid resin, (b) at least one thermoplastic resin selected from a polyolefin resin and a polystyrene resin, and (c) a block copolymer of a vinyl aromatic compound and a conjugated diene, wherein a ratio of (a) to (b) by weight (a/b) is 80/20 to 20/80, and the foam comprises 0.5 to 20 parts by weight of (c) with respect to 100 parts by weight of (a) and (b) in total.Type: GrantFiled: January 18, 2007Date of Patent: May 24, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Tohru Okuda, Shoichiro Harada, Yoshihito Fukasawa
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Patent number: 7947752Abstract: Disclosed is a microporous high density polyethylene film for a battery separator and a method of producing the same. The microporous high density polyethylene film includes high density polyethylene with a weight average molecular weight of 2×105-5×105, containing 5 wt % or less molecule with a molecular weight of 1×104 or less. The microporous high density polyethylene film has tensile strengths of 1,100 kg/cm2 or more in transverse and machine directions respectively, a puncture strength of 0.22 N/?m or more, a gas permeability (Darcy's permeability constant) of 1.3×10?5 Darcy or more, and shrinkages of 5% or less in machine and transverse directions, respectively. Particularly, the microporous high density polyethylene film has an excellent extrusion-compoundabiliy and stretchability and a high productivity, and can improve the performances and stability of a battery produced using the same.Type: GrantFiled: February 12, 2008Date of Patent: May 24, 2011Assignee: SK Energy Co., Ltd.Inventors: Young Keun Lee, Jang Weon Rhee, Won Young Cho, Jung Moon Sung, Byoung Cheon Jo, Chol Ho Lee, In Hwa Jung, Byung Rae Jung
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Publication number: 20110098373Abstract: A foam form sheet material having a first large surface comprising substantially only closed cells and an opposite large surface and an interior comprising substantially only open cells. This material comprises a cross linked olefin thermoplastic polymer or copolymer. The foam is made by mixing the polymer with a blowing agent and a cross linking agent. The mixture is maintained in a two roll mill means for a time sufficient to initiate cross linking and to initiate foaming to form closed cells. The sheet material is then disposed in a second two roll mill means having a nip that is larger than the thickness of the foamed sheet material and maintained under elevated temperature and pressure sufficient to initiate further cross linking and foaming. The fully cross linked cell foam is then compressed to rupture the closed cells that are disposed in the interior to form open cells.Type: ApplicationFiled: July 9, 2008Publication date: April 28, 2011Applicant: SENSTAT PRODUCTS & TECHNOLOGIES, INC.Inventor: Edward Benjaminsen
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Patent number: 7923478Abstract: A nanoporous material is provided. The pores of the nanoporous material are formed between nanoparticles that have a polymeric surface layer. The nanoporous material is produced by (a) suspending the nanoparticles in a medium material, wherein the nanoparticles are phase separated from the medium material, (b) heating the suspension to a temperature above the melting point of the nanoparticle surface layer, and (c) cooling the suspension. Alternatively, the nanoporous material may be produced by dissolving nanoparticles having a polymeric surface layer in a solvent, and then adding a medium material that causes the nanoparticles to phase separate from the solution.Type: GrantFiled: December 12, 2007Date of Patent: April 12, 2011Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Mindaugas Rackaitis
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Patent number: 7872056Abstract: The present invention relates to compositions comprising blends of alkenyl aromatic polymers such as styrenic polymers (i.e. PS and HIPS) and bio-based or biodegradable polymers (i.e. PLA, PGA, PHA, PBS, PCL) compatibilized with styrene-based copolymers (i.e. styrene-ethylene-butylene-styrene (SEBS) block copolymers, maleated SEBS, styrene-maleic anhydride (SMA) copolymer, styrene-methyl methacrylate (SMMA) copolymer) or a mixture of two or more styrene-based copolymers such as SEBS and SMA. These novel compositions can be extruded and thermoformed to produce very low density food service and consumer foam articles such as plates, hinged lid containers, trays, bowls, and egg cartons with good mechanical properties.Type: GrantFiled: February 2, 2009Date of Patent: January 18, 2011Assignee: Pactiv CorporationInventors: Yunwa Wilson Cheung, David V. Dobreski, Richard Turner, Mark Wheeler, Y. Paul Handa
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Publication number: 20100240784Abstract: Thermoplastic vulcanizate elastomer obtained by dynamic vulcanization of a heterophasic polyolefin composition in presence of at least (i) an alkenyl-substituted alkoxysilane grafting agent and (ii) water; wherein said heterophasic polyolefin composition has flexural modulus equal to or lower than 150 MPa, and comprises: (a) a crystalline propylene homopolymer or copolymer of propylene with up to 15% of ethylene or other alpha-olefin comonomer(s), or their combinations, and (b) a copolymer or a composition of copolymers of ethylene with other alpha-olefins, containing from 15% to 40% of ethylene, said thermoplastic vulcanizate elastomer having compression set values in the range from 45-65%, the ratio of elongation at break to compression set values over 10 and hardness shore A values below 90.Type: ApplicationFiled: May 15, 2007Publication date: September 23, 2010Applicant: Bassell Poliolefine Italia s.r.l.Inventors: Gilberto Moscardi, Enrico Costantini
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Patent number: 7795321Abstract: Rheology modification of an ethylene/?-olefin interpolymer is achieved by blending the interpolymer with at least one branched polyolefin. The polyolefins can be homopolymers or interpolymers and have a branching index of less than 1. The ethylene/?-olefin interpolymer is a block copolymer having at least a hard block and at least a soft block. The soft block comprises a higher amount of comonomers than the hard block. The block interpolymer has a number of unique characteristics disclosed here. Rheology-modified ethylene/?-olefin interpolymer, i.e., the resulting polymer blends, can be extruded or molded into many useful articles, such as films, sheets, profiles, gaskets, foams, etc.Type: GrantFiled: March 15, 2006Date of Patent: September 14, 2010Assignee: Dow Global Technologies Inc.Inventors: Yunwa W. Cheung, Felipe Martinez, Pankaj Gupta
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Publication number: 20100113637Abstract: The present subject matter relates generally to polymer compositions, and more particularly to irradiated polymer compositions comprising at least one non-phenolic stabilizer. The present polymer compositions comprise an unexpected balance of properties after being subjected to irradiation treatments, including an unexpected combination of a lower melt flow rate ratio (MFRr) and high melt tension after being irradiated, while minimizing negative yellowing effects.Type: ApplicationFiled: June 27, 2008Publication date: May 6, 2010Applicant: Basell Poliolefine Italia s.r.l,Inventors: Jeffrey D. Abata, Ronald F. Becker, Vu A. Dang, Anthony J. De Nicola, JR., Theodore Dziemianowicz