From Reactant Containing Two Or More Ethylenic Unsaturated Groups Patents (Class 521/150)
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Patent number: 5902845Abstract: A rubber-modified styrenic resin composition comprising 100 parts by weight of a rubber-modified styrenic resin (A) having 10 to 40% by weight of the content of a soft component particle and a mean particle diameter of the said particle of 0.1 to 1.2 .mu.m, and 1 to 30 parts by weight of fine particles having a mean particle diameter of 0.1 to 5 .mu.m and not having a glass transition temperature between -130 to 90.degree. C.A rubber-modified styrenic resin composition having superior plane impact strength, rigidity and gloss, and its molded article are provided.Type: GrantFiled: March 1, 1996Date of Patent: May 11, 1999Assignee: Sumitomo Chemical Company, LimitedInventors: Shuji Yoshimi, Hayato Kihara, Takahiro Ishii
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Patent number: 5863958Abstract: Polymers are made from 1,3,7-octatriene or like conjugated polyenes and a crosslinking agent having at least 2 activated double bonds such as ethylene glycol dimethacrylate. These polymers can be used to make absorbent foams that are useful in absorbent articles such as diapers, as well as latexes that are useful as binders and adhesives.Type: GrantFiled: September 19, 1997Date of Patent: January 26, 1999Assignee: The Procter & Gamble CompanyInventors: John Collins Dyer, Bryn Hird, Pui Kwan Wong, Sharon Marie Beshouri
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Patent number: 5863957Abstract: The present invention relates to porous crosslinked polymeric microbeads having cavities joined by interconnecting pores wherein at least some of the cavities at the interior of each microbead communicate with the surface of the microbead. The present invention also relates to a process for producing a porous, crosslinked polymeric microbead as well as the product of this process. This process involves combining an oil phase with an aqueous discontinuous phase to form an emulsion, adding the emulsion to an aqueous suspension medium to form an oil-in-water suspension of dispersed emulsion droplets, and polymerizing the emulsion droplets to form microbeads. At least 10% of the microbeads produced in accordance with the present invention are substantially spherical or substantially ellipsoidal or a combination of the two.Type: GrantFiled: June 27, 1996Date of Patent: January 26, 1999Assignee: Biopore CorporationInventors: Nai-Hong Li, James R. Benson, Naotaka Kitagawa
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Patent number: 5856409Abstract: A method for altering a macroporous cross-linked hydrophobic copolymeric lattice produced by precipitation polymerization in a solvent of at least one monounsaturated ester monomer and at least one polyunsaturated ester monomer soluble therein, in order to render the hydrophobic copolymeric lattice hydrophilic. The method involves saponifying the hydrophobic copolymeric lattice by reacting the surface of the hydrophobic copolymeric lattice with an aqueous alkali. The surface can also be rendered hydrophilic by polymerizing an acrylate monomer onto the lattice in order to form a surface containing carboxylic acid sites. The carboxylic acid sites formed on the surface of the lattice are converted to carboxylate anions.Type: GrantFiled: August 9, 1993Date of Patent: January 5, 1999Assignee: Dow Corning CorporationInventors: Maris Jazeps Ziemelis, William Robb Roy Park
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Patent number: 5830925Abstract: The invention provides a process for preparing a bitumen composition comprising blowing a mixture with an oxygen-containing gas which mixture comprises a bitumen having a penetration of less than 300 and a thermoplastic rubber which is present in an amount of less than 5% w, based on total mixture; bitumen compositions obtainable by such process; and the use of such bitumen compositions in asphalt mixtures for road applications.Type: GrantFiled: November 21, 1996Date of Patent: November 3, 1998Assignee: Shell Oil CompanyInventors: Jacques Chion, Marie-Francoise Morizur
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Patent number: 5804608Abstract: This invention relates to a reinforced closed-section structural-member structure making use of a heat-foamable filling reinforcement. The structure has been formed by connecting plural closed-section structural members (11-15) together. These closed-section structural members (11-15) are internally filled with a heat-foamed filling reinforcement (1) which comprises an epoxy resin material, a synthetic rubber material and a thermoplastic resin material as components.Type: GrantFiled: September 20, 1996Date of Patent: September 8, 1998Assignee: Mitsubishi Jidosha Kogyo Kabushiki KaishaInventors: Kazuyuki Nakazato, Hideki Fukudome
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Patent number: 5801209Abstract: Disclosed are foamable EPDM compositions comprising EPDM, a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g and a blowing agent which are advantageous for use in applications where UHF microwave curing is utilized and for replacing foamable EPDM compositions incorporating similar amounts of conventional blends of carbon blacks. Also disclosed are foamed, cured EPDM compositions comprising: EPDM and a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g which have advantageously lower sponge density and lower sponge compression set than EPDM compositions incorporating similar amounts of conventional low reinforcing carbon blacks. Further disclosed is a process for producing the foamed, cured EPDM compositions of the present invention. Additionally disclosed is use of the foamed, cured EPDM compositions of the present invention as weatherstripping.Type: GrantFiled: August 15, 1997Date of Patent: September 1, 1998Assignee: Cabot CorporationInventors: Bin Chung, Bruce E. Mackay, Ivan Zlatko Podobnik
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Patent number: 5798009Abstract: A foamed rubber composition for tire comprises a particular amount of particles having specified hardness and average particle size and containing aluminum-bonded hydroxy group and/or silicon-bonded hydroxy group at its surface, and a particular amount of at least one specified silane coupling agent, and develops excellent performances on ice. Further, pneumatic tires contain the foamed rubber composition as a tread rubber.Type: GrantFiled: December 27, 1995Date of Patent: August 25, 1998Assignee: Bridgestone CorporationInventor: Hiroyuki Teratani
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Patent number: 5786406Abstract: A polyolefin based crosslinked foam excellent in impact absorbability, vibration absorbability and heat insulation, which can be used for various kinds of industrial applications such as materials for the interior of automobiles, cushioning, building, furniture, home use electric appliances, which foam comprises:a polyolefin based resin (A), and a conjugated diene polymer (B) having the peak tan .delta. value (obtained by dynamic viscoelasticity measurement) between -20.degree. C. and 40.degree. C.This invention also relates to a method for manufacturing said impact and vibration absorbable crosslinked foam.The polyolefin based crosslinked foam of this invention is excellent in impact absorbability and vibration absorbability while keeping moldability and heat resistance over a wide range of degrees of crosslinking.Type: GrantFiled: February 8, 1996Date of Patent: July 28, 1998Assignee: Toray Industries, Inc.Inventors: Nario Uejyukkoku, Yukinari Nakatsu
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Patent number: 5776991Abstract: A foamed rubber composition for pneumatic tires comprises at least one diene polymer as a rubber ingredient and includes closed cells in a matrix rubber, each of these cells being covered with a coat layer made from a given amount of a resin or resin composite having a JIS-C hardness of not less than 75, a particle size of 10-200 .mu.m and a reacted conjugate diene unit content of not less than 10% by weight. In the production of the foamed rubber composition, the melting point or glass transition point of the resin or resin composite is restricted to at least 5.degree. C. lower than the vulcanizing temperature.Type: GrantFiled: March 27, 1996Date of Patent: July 7, 1998Assignee: Bridgestone CorporationInventor: Hiroyuki Teratani
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Patent number: 5770634Abstract: The present invention relates to compressable polymeric foam materials useful as insulation. These polymeric foams are prepared by polymerization of certain water-in-oil emulsions having a relatively high ratio of water phase to oil phase, commonly known as "HIPEs." The polymeric foam materials comprise a generally hydrophobic, flexible or semi-flexible, nonionic polymeric foam structure of interconnected open-cells. The foam structures have:(a) a specific surface area per foam volume of at least about 0.01 m.sup.2 /cc;(b) an expanded density of less than about 0.05 g/cc; and(c) a ratio of expanded to compressed thickness of at least about 3:1;wherein when the foam is compressed to 33% of its original expanded thickness and is thereafter maintained without artificial restraint on its surface, said foam will reexpand by no more than 50% after 21 days at ambient temperature (22.degree. C.).Type: GrantFiled: June 7, 1995Date of Patent: June 23, 1998Assignee: The Procter & Gamble CompanyInventors: John Collins Dyer, Thomas Allen DesMarais
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Patent number: 5767168Abstract: Biodegradable and/or compostable polymers are made from isoprene, 2,3-dimethyl-1,3-butadiene or like conjugated dienes and a crosslinking agent having a cleavable linking group such as ethylene glycol dimethacrylate. These polymers can be used to make absorbent foams that are useful in absorbent articles such as diapers, as well as other biodegradable articles such as films, and latexes useful as binders and adhesives.Type: GrantFiled: January 10, 1996Date of Patent: June 16, 1998Assignee: The Proctor & Gamble CompanyInventors: John Collins Dyer, Bryn Hird, Pui Kwan Wong
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Patent number: 5760097Abstract: The present invention relates to porous crosslinked polymeric microbeads having cavities joined by interconnecting pores wherein at least some of the cavities at the interior of each microbead communicate with the surface of the microbead. The present invention also relates to a process for producing a porous, crosslinked polymeric microbead as well as the product of this process. This process involves combining an oil phase with an aqueous discontinuous phase to form an emulsion, adding the emulsion to an aqueous suspension medium to form an oil-in-water suspension of dispersed emulsion droplets, and polymerizing the emulsion droplets to form microbeads. At least 10% of the microbeads produced in accordance with the present invention are substantially spherical or substantially ellipsoidal or a combination of the two.Type: GrantFiled: April 10, 1996Date of Patent: June 2, 1998Assignee: Biopore CorporationInventors: Nai-Hong Li, James R. Benson, Naotaka Kitagawa
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Patent number: 5750582Abstract: The disclosure is a liquid absorbable material comprising a porous formed article possessed of partitioning walls of a cross-linked polymer and continued micropores, characterized in that said material has a density in the range of 0.2 to 1.0 g/cm.sup.3, and (a) that said partitioning walls exhibit a swelling degree to kerosine in the range of 2 to 10, and that said material has an absorption capacity per unit volume, the capacity being at least 4 cm.sup.3 /cm.sup.3 for water, ethanol, toluene and kerosine, respectively, or (b) that said material has an absorption capacity per unit weight, the capacity being at least 10 g/g for water, ethanol, toluene and kerosine, respectively, the liquids being at a temperature not less than the softening point of the cross-linked polymer. The liquid absorbable material can absorb liquids such as water and petroleum quickly and expand with the absorbed liquid.Type: GrantFiled: June 4, 1996Date of Patent: May 12, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuyuki Harada, Katsuyuki Wada, Hisanori Obara, Toru Inaoka
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Patent number: 5744507Abstract: A foamable, curable organosiloxane composition comprising an alkenyl-functional polyorganosiloxane, an organohydrogensiloxane, a blowing agent, a platinum catalyst and an adhesion promoter comprising an epoxy-functional compound, a hydroxyl-functional compound, a tetraalkylorthosilicate, an organotitanate and an aluminum or zirconium compound.Type: GrantFiled: May 1, 1997Date of Patent: April 28, 1998Assignee: Dow Corning CorporationInventors: Gloria Lynne Angell, Michael Andrew Lutz
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Patent number: 5733944Abstract: Aqueous polymer dispersions whose polymer is built up ofa) at least 50% by weight of butadiene, isoprene or a mixture thereof,b) at least 10% by weight of an ester of (meth)acrylic acid and a C.sub.1 -C.sub.8 -alkanol andc) from 0 to 10% by weight of other comonomers,where the total amount of monomers a) and b) makes up at least 90% by weight of the total amount of monomers, are useful for producing flame-resistant latex foam rubber which contains only hydrates of inorganic salts as flame retardants.Type: GrantFiled: May 22, 1996Date of Patent: March 31, 1998Assignee: BASF AktiengesellschaftInventors: Roelof Balk, Peter Claassen, Onno Graalmann, Leonardus Aan de Meulen, Marinus Visseren
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Patent number: 5731359Abstract: A vibration-absorbing element comprised of a foamed thermoplastic polymer selected from the group consisting of polyamide elastomers, EPDM polymers and SEBS polymers containing conventional additives, the foam structure having a pore size which decreases from the inside towards the outer surface and terminating in a smooth closed surface.Type: GrantFiled: July 5, 1995Date of Patent: March 24, 1998Assignees: A. Raymond GmbH & Co. KG, EMS-Inventa AGInventors: Rene Moser, Hans-Jurgen Lesser
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Patent number: 5700845Abstract: Disclosed are foamable EPDM compositions comprising EPDM, a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g and a blowing agent which are advantageous for use in applications where UHF microwave curing is utilized and for replacing foamable EPDM compositions incorporating similar amounts of conventional blends of carbon blacks. Also disclosed are foamed, cured EPDM compositions comprising: EPDM and a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g which have advantageously lower sponge density and lower sponge compression set than EPDM compositions incorporating similar amounts of conventional low reinforcing carbon blacks. Further disclosed is a process for producing the foamed, cured EPDM compositions of the present invention. Additionally disclosed is use of the foamed, cured EPDM compositions of the present invention as weatherstripping.Type: GrantFiled: October 3, 1994Date of Patent: December 23, 1997Assignee: Cabot CorporationInventors: Bin Chung, Bruce E. Mackay, Ivan Zlatko Podobnik
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Patent number: 5683527Abstract: A foamable, curable organosiloxane composition comprising an alkenyl-functional polyorganosiloxane, an organohydrogensiloxane, a blowing agent, a platinum catalyst and an adhesion promoter comprising an epoxy-functional compound, a hydroxyl-functional compound, a tetraalkylorthosilicate, an organotitanate and an aluminum or zirconium compound.Type: GrantFiled: December 30, 1996Date of Patent: November 4, 1997Assignee: Dow Corning CorporationInventors: Gloria Lynne Angell, Michael Andrew Lutz
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Patent number: 5672633Abstract: The present invention relates to powdery, insoluble, water-swellable, cross-linked polymers absorbing water, aqueous or serous liquids, which are formed ofa) 55-99.9%-wt. polymerized unsaturated, polymerizable acid-groups--comprising monomers which are neutralized to the extent of at least 25 mol-%,b) 0-40%-wt. polymerized unsaturated monomers which are co-polymerizable with a),c) 0.1-5.0%-wt. of a cross-linking agent, andd) 0-30%-wt. of a water-soluble polymer,with the weight amounts of a) to d) being relative to anhydrous polymer, and the polymer powder is heated with an at least bifunctional compound reactive with acid groups to a temperature of 150.degree. C.-250.degree. C. under cross-linkage of the surface, and the polymer powder that is thus already surface-cross-linked is subjected to a repeated surface-cross-linking treatment using an at least bifunctional compound reactive with acid groups at a temperature of 150.degree. to 250.degree. C.Type: GrantFiled: March 26, 1996Date of Patent: September 30, 1997Assignee: Chemische Fabrik Stockhausen GmbHInventors: Helmut Brehm, Hans-Georg Hartan
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Patent number: 5668190Abstract: A silicone sponge rubber having a great tensile strength even when it has a low foam density can be obtained from a foamable silicone rubber composition including:(A) a polyolefin dispersion obtained by polymerizing monomers having polymerizable aliphatic unsaturated double bonds, dispersed in a dispersion medium of an organopolysiloxane having a viscosity of from 50 cSt to 1,000,000 cSt at 25.degree. C. whose molecular chain both terminals are terminated with silanol groups, to form a polyolefin in the silanol group-containing organopolysiloxane;(B) an organohydrogenpolysiloxane having at least two hydrogen atoms in one molecule;(C) at least one selected from the group consisting of water, an alcohol, a silanol group-containing organosilane, and a silanol group-containing siloxane having a viscosity of less than 50 cSt at 25.degree. C.; and(D) a platinum family metal catalyst.Type: GrantFiled: December 24, 1996Date of Patent: September 16, 1997Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Atsushi Yaginuma, Takeshi Miyao, Hironao Fujiki
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Patent number: 5665785Abstract: Shaped microcellular structures having substantially non-cellular skins are produced from reactive liquid polymer systems incorporating thermoplastic microspheres containing volatile materials such as low boiling point halogenated or non-halogenated organic materials. Use of thermoplastic microspheres encapsulating such volatile materials facilitates the removal of the shaped foamed structure from molds, eliminating the need for release agents. Various products based on this process, such as bathroom fixtures, bicycle and wheel chair tires, shoe soles, and automotive parts, are provided.Type: GrantFiled: September 27, 1995Date of Patent: September 9, 1997Assignee: Urethane Technologies, Inc.Inventors: Thomas Roy McClellan, John T. Mizulo, Edwin S. Nelson, Grant R. Pato
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Patent number: 5652276Abstract: A foaming resin composition consisting essentially of (A) an organic compound having a carbon-carbon double bond, (B) a compound having an SiH group, and (C) a compound having an OH group is foamed and cured at room temperature or under heat at relatively low temperatures, to obtain hard, semi-hard or soft plastic foam having good weather resistance and good compatibility with coating compositions and adhesives.Type: GrantFiled: September 5, 1996Date of Patent: July 29, 1997Assignee: Kanegafuchi Chemical Industry Co., Ltd.Inventors: Hiroshi Ando, Kensuke Kondo, Naoaki Nakanishi, Hiroshi Ito, Shigeki Hamaguchi, Kazuya Yonezawa
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Patent number: 5650222Abstract: Low density collapsed absorbent foams materials that, upon contact with aqueous fluids, in particular urine, can expand and absorb these fluids. These low density foams typically have an expanded thickness from about 6 to about 10 times the thickness of the foams in their collapsed state. These low density foams are made by polymerizing high internal phase emulsions (HIPEs) where the volume to weight ratio of the water phase to the oil phase is in the range of from about 55:1 to about 100:1.Type: GrantFiled: November 29, 1995Date of Patent: July 22, 1997Assignee: The Procter & Gamble CompanyInventors: Thomas Allen DesMarais, Keith Joseph Stone, John Collins Dyer, Bryn Hird, Stephen Allen Goldman, Paul Seiden
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Patent number: 5646224Abstract: A rubber composition excellent in shape-retainability also in processibility, compression set and the like, which comprises a single ethylene-.alpha.-olefin-non-conjugated diene copolymer which has (1) a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 80 to 200, (2) a weight average molecular weight/number average molecular weight ratio of 6 or more as measured by a gel permeation chromatography (GPC), and (3) a stress-retention of 0.2 or more after 100 seconds at 80.degree. C. in a compression type stress-relaxation test.Type: GrantFiled: January 3, 1996Date of Patent: July 8, 1997Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Takashi Kawata, Shoei Tsuji, Yoji Mori
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Patent number: 5632737Abstract: Absorbent foams materials that are capable of acquiring and distributing aqueous fluids, especially discharged body fluids such as urine. These absorbent foams combine relatively high capillary absorption pressures and capacity-per-weight properties that allow them to acquire fluid, with or without the aid of gravity. These absorbent foams also give up this fluid efficiently to higher absorption pressure storage materials, including foam-based absorbent fluid storage components, without collapsing. These absorbent foams are made by polymerizing high internal phase emulsions (HIPEs).Type: GrantFiled: May 14, 1996Date of Patent: May 27, 1997Assignee: The Procter & Gamble CompanyInventors: Keith J. Stone, Thomas A. DesMarais, Gary D. LaVon, Stephen A. Goldman, Paul Seiden
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Patent number: 5629353Abstract: Condensation polymerization followed by a supercritical extraction step can be used to obtain highly cross-linked nanoporous polymers with high surface area, controlled pore sizes and rigid structural integrity. The invention polymers are useful for applications requiring separation membranes.Type: GrantFiled: May 22, 1995Date of Patent: May 13, 1997Assignee: The Regents of the University of CaliforniaInventors: Warren P. Steckle, Jr., Paul G. Apen, Michael A. Mitchell
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Patent number: 5618853Abstract: A molded structure 1 produced by extrusion, such as an expanded plastic foam, a sheet, a profile or the like, contains at least 10% by volume of open cells 2, 4 which have a polyhedron-like shape and are adjacent to one another. A higher temperature during the extrusion in comparison with the extrusion of thermoplastic molded structures having a closed-cell structure results in deformation-free opening of the cells. Webs 3 of cell walls 5, 6 remain intact in shape whether they have orifices 7 or no passages, so that the mechanical strength of the cell skeleton or of the space matrix is retained.Type: GrantFiled: October 27, 1995Date of Patent: April 8, 1997Assignee: Hoechst AktiengesellschaftInventors: Hub A. G. Vonken, Hendrik-Jan Muntendam, Jos van der Hoeven, Udo Piqu e
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Patent number: 5583162Abstract: The present invention relates to porous crosslinked polymeric microbeads having cavities joined by interconnecting pores wherein at least some of the cavities at the interior of each microbead communicate with the surface of the microbead. Approximately 10% of the microbeads of the present invention are substantially spherical or substantially ellipsoid or a combination of the two. The present invention also relates to a process for producing a porous, crosslinked polymeric microbead as well as the product of this process. This process involves combining a continuous phase with an aqueous discontinuous phase to form an emulsion, adding the emulsion to an aqueous suspension medium to form an oil-in-water suspension of dispersed emulsion droplets, and polymerizing the emulsion droplets to form microbeads. Also included in the invention are modifications of the microbeads as well as methods for using the microbeads in a variety of applications.Type: GrantFiled: June 6, 1994Date of Patent: December 10, 1996Assignee: Biopore CorporationInventors: Nai-Hong Li, James R. Benson
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Patent number: 5563179Abstract: Absorbent foams materials that are capable of acquiring and distributing aqueous fluids, especially discharged body fluids such as urine. These absorbent foams combine relatively high capillary absorption pressures and capacity-per-weight properties that allow them to acquire fluid, with or without the aid of gravity. These absorbent foams also give up this fluid efficiently to higher absorption pressure storage materials, including foam-based absorbent fluid storage components, without collapsing. These absorbent foams are made by polymerizing high internal phase emulsions (HIPEs).Type: GrantFiled: January 10, 1995Date of Patent: October 8, 1996Assignee: The Proctor & Gamble CompanyInventors: Keith J. Stone, Thomas A. DesMarais, John C. Dyer, Bryn Hird, Gary D. La Von, Stephen A. Goldman, Michelle R. Peace, Paul Seiden
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Patent number: 5525636Abstract: The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 75 to 98% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 2 to 25% by weight of at least one styrene-soluble elastomer,c) from 1 to 15% by weight, based on the sum of a) and b), of a low-boiling blowing agent, and, if desired,d) conventional additives in effective amounts,where the unfoamed beads have a structure in which the elastomer phase is dispersed in the polystyrene phase in the form of cell particles, and to foams and foam moldings produced therefrom.Type: GrantFiled: May 12, 1995Date of Patent: June 11, 1996Assignee: BASF AktiengesellschaftInventors: Rolf Henn, Klaus Hahn, Wolfgang Loth, Walter Heckmann, Uwe Blumenstein, Hans-Dieter Schwaben, Karl-Heinz Wassmer, Hermann Tatzel
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Patent number: 5525637Abstract: The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 50 to 90% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 5 to 30% by weight of at least one styrene-soluble elastomer,c) from 5 to 20% by weight of at least one block copolymer containing styrene as one component,d) from 1 to 15% by weight, based on the sum of a), b) and c), of a low-boiling blowing agent, and, if desired,e) conventional additives in effective amounts,where, in the unfoamed polystyrene beads, component b) is in the form of cell particles and component c) is in the form of particles having a mean size of from 0.2 to 2 .mu.m in the polystyrene phase, and to foams and foam moldings produced therefrom.Type: GrantFiled: May 12, 1995Date of Patent: June 11, 1996Assignee: BASF AktiengesellschaftInventors: Rolf Henn, Klaus Hahn, Andreas Deckers, Wolfgang Loth, Uwe Blumenstein, Hans-Dieter Schwaben, Erich Klement
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Patent number: 5512604Abstract: Novel porous copolymers are disclosed which can be used to prepare ion-exchange resins and polymeric adsorbents. The copolymers comprise a copolymer of at least one monovinylidene monomer and a crosslinking monomer and have a unique cellular pore structure. The cellular structure comprises a macroporous void phase which is dispersed within a continuous copolymer phase. The porous void phase comprises a plurality of cellular void spaces which are at least partially enclosed by walls of the continuous copolymer phase. Also disclosed are processes which can be used to prepare the porous copolymers, as well as ion-exchange resins and polymeric adsorbents using the porous copolymers.Type: GrantFiled: August 28, 1992Date of Patent: April 30, 1996Assignee: The Dow Chemical CompanyInventor: Tom N. Demopolis
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Patent number: 5506035Abstract: An improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Methods for making the foam and absorbent products, members and articles containing the foam are also disclosed.Type: GrantFiled: November 17, 1994Date of Patent: April 9, 1996Assignee: The Procter & Gamble CompanyInventors: Dean Van Phan, Paul D. Trokhan
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Patent number: 5504163Abstract: Residual chloromethyl groups in methylene-bridged aromatic polymer adsorbents are susceptible to hydrolysis to benzyl alcohol groups and oxidation to benzoic acid groups. The introduction of these hydroxyl and carboxylic acid groups contributes to the water adsorption capacity or hydrophilicity of these adsorbents. Unfortunately, this hydrophilicity interferes with the utility of these resins as adsorbents for volatile organic compounds. By capping these residual chloromethyl groups with hydrophobic aromatic compounds prior to their opportunity to hydrolyze or oxidize, the hydrophobicity of methylene-bridged aromatic polymer adsorbents is increased and their utility for the absorption of organic compounds is enhanced.Type: GrantFiled: December 21, 1994Date of Patent: April 2, 1996Assignee: The Dow Chemical CompanyInventors: Marvin H. Tegen, Kenneth C. Jones
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Patent number: 5496864Abstract: The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 50 to 75% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 5 to 30% by weight of a styrene-soluble elastomer,c) from 5 to 20% by weight of at least one block copolymer containing styrene as one component,d) from 15 to 50% by weight of at least one polyolefin,e) from 1 to 15% by weight, based on the sum of a) and b), of a low-boiling blowing agent, and, if desired,f) conventional additives in effective amounts,and to foams produced therefrom.Type: GrantFiled: May 12, 1995Date of Patent: March 5, 1996Assignee: BASF AktiengesellschaftInventors: Rolf Henn, Klaus Hahn, Hans Ho/ nl, Walter Heckmann, Karl-Heinz Wassmer, Erich Klement, Joachim Fischer
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Patent number: 5494939Abstract: The material contains interrelated micro- and anisodiametric macropores which latter are disposed mainly on peripheral portions. The volume ratio of micro- and macropores is 1:3-7.The process involves freezing a polymer dispersion at a temperature ensuring a 3-11:1 ratio of dispersed phase to the noncrystallized dispersion medium, seasoning the conjugate-dispersed system at a temperature and within a time sufficient for reversal of phases, followed by thawing. The used polymer dispersion contains a liquid crystallizable dispersion medium and a polymer phase capable of autohesion at temperatures below the initial melting temperature of crystals in the dispersion medium.Type: GrantFiled: January 10, 1994Date of Patent: February 27, 1996Assignees: A. H. Hides, Skins Australia Pty Ltd.Inventors: Efim S. Vainerman, Irina B. Portnaya
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Patent number: 5492940Abstract: An acrylic/lactam monomer based polymeric resin is provided which has excellent weatherability, outstanding transparency and optical clarity, improved heath and solvent resistance, as well as improved impact strength. The acrylic/lactam monomer based polymeric resin is formulated by the catalytic activation at ambient temperature of a polymerization syrup which contains from about 300 to about 2970 parts by volume of an acrylic monomer, from about 30 to about 2700 parts by volume of a lactam monomer, from about 0.3 parts to about 40 parts by volume of a mercaptan chain transfer agent and from about 0.3 to about 40 parts by volume of a crosslinking agent capable of crosslinking the acrylic monomer and the lactam monomer. To prevent further polymerization of the polymeric constituents of the polymerization syrup, as well as to enhance the shelf life of the polymerization syrup, an effective amount of a polymerization inhibitor and an ultraviolet light stabilizer are incorporated into the polymerization syrup.Type: GrantFiled: May 19, 1995Date of Patent: February 20, 1996Inventor: Bill R. Edwards
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Patent number: 5453453Abstract: This invention is directed to a fire-resistant, essentially halogen-free epoxy composition that emits low amounts of smoke and toxic gas while burning. The one-part composition is particularly useful in aerospace applications for bonding, sealing and/or insulating metal, plastic and composite parts.Type: GrantFiled: April 6, 1994Date of Patent: September 26, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alain H. Lamon, Sylvie C. Le Cozannet
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Patent number: 5362759Abstract: There is provided a process for reclaiming elastomeric waste material, particularly rubber, which includes the steps impregnating the elastomeric waste material with an essential oil and then heat treating the impregnated material under reduced pressure with microwave radiation.Type: GrantFiled: March 21, 1994Date of Patent: November 8, 1994Assignee: James R. HuntInventors: James R. Hunt, David Hall
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Patent number: 5352711Abstract: Normally hydrophobic foams, such as polyurethane foams and polymerized water-in-oil emulsion foams, are rendered hydrophilic by means of treatment with simple surfactants and hydrophilizing agent salts. Thus, a surfactant-containing foam is treated with a solution of, for example, calcium chloride, and is dried to leave a substantially uniformly distributed residue of hydrated or hydratable calcium chloride on the surfactant-containing internal foam surfaces. In-use, the combination of surfactant and calcium chloride hydrate provides a hydrophilic surface to the foam. Other hydratable calcium or magnesium salts such as magnesium chloride can be used. The resulting hydrophilized foams are suitable for use in absorbent devices, including diapers, sanitary napkins, bandages, and the like.Type: GrantFiled: August 12, 1991Date of Patent: October 4, 1994Assignee: The Proctor & Gamble CompanyInventor: Thomas A. DesMarais
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Patent number: 5350776Abstract: A foamed elastomeric polymer with a camouflage appearance on its surface and throughout its mass, characterized by distinct, randomly sized regions of various colors, having curved, nonangular borders with substantially no blend of colors, and being free from gas pockets and blisters. A process for manufacturing a foamed elastomeric polymer of the above description.Type: GrantFiled: September 24, 1993Date of Patent: September 27, 1994Inventor: Eduardo A. Raad
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Patent number: 5340842Abstract: Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and polymerization initiators are obtained by using saccharide fatty acid esters as surfactants. The amount of surfactants necessary to form stable high internal phase water-in-oil emulsions is decreased by using saccharide fatty acid esters as surfactants. Further, hydrophobic foams can be obtained by using saccharide fatty acid esters.Type: GrantFiled: January 19, 1994Date of Patent: August 23, 1994Assignee: Shell Oil CompanyInventors: Robert P. Adamski, Maryanne Mores, Pui K. Wong, Diana D. Davis
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Patent number: 5338766Abstract: An improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Methods for making the foam and absorbent products, members and articles containing the foam are also disclosed.Type: GrantFiled: March 26, 1993Date of Patent: August 16, 1994Assignee: The Procter & Gamble CompanyInventors: Dean V. Phan, Paul D. Trokhan
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Patent number: 5334621Abstract: Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and initiators, useful in preparing low density porous crosslinked polymeric foams, are obtained by using a surfactant system containing (a) one or more sorbitan fatty acid ester or saccharide fatty acid ester and (b) a glycerol monofatty acid ester. A higher water to oil ratio water-in-oil emulsions can be formed with the same formulation by using the glycerol monofatty acid ester cosurfactant.Type: GrantFiled: November 4, 1993Date of Patent: August 2, 1994Assignee: Shell Oil CompanyInventor: Sharon M. Beshouri
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Patent number: 5331015Abstract: Disclosed are absorbent foam materials suitable for use as or in the absorbent cores of absorbent articles, such as diapers which absorb and retain aqueous body fluids. Such foam materials comprise hydrophilic, flexible open-celled structures which are preferably prepared by polymerizing high internal phase (HIPE) water-in-oil emulsions. Such foam materials have a pore volume of from about 12 to 100 mL/g, and a capillary suction specific surface area of from about 0.5 to 5.0 m.sup.2 /g. These materials also exhibit a resistance to compression deflection such that a confining pressure of 5.1 kPa produces after 15 minutes a strain of from about 5% to 95% compression when the material is saturated at 37.degree. C. to its free absorbent capacity with synthetic urine.Type: GrantFiled: November 23, 1993Date of Patent: July 19, 1994Assignee: The Procter & Gamble CompanyInventors: Thomas A. DesMarais, Keith J. Stone, Hugh A. Thompson, Gerald A. Young, Gary D. LaVon, John C. Dyer
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Patent number: 5328935Abstract: A method of making an improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Absorbent products, members and articles containing the foam are also disclosed.Type: GrantFiled: March 26, 1993Date of Patent: July 12, 1994Assignee: The Procter & Gamble CompanyInventors: Dean Van Phan, Paul D. Trokhan
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Patent number: 5308877Abstract: Organic resins with high surface areas and porosities, which are insoluble in organic solvents and contain few or no flexible groups in the resin structure, are disclosed. Also disclosed is a process for making such resins from polyfunctional aryl alkali metal compounds and a second polyfunctional monomer. Such resins are useful as absorbants.Type: GrantFiled: November 16, 1990Date of Patent: May 3, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Bruce E. Smart, Owen W. Webster
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Patent number: 5306733Abstract: Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and polymerization initiators are obtained by using saccharide fatty acid esters as surfactants. The amount of surfactants necessary to form stable high internal phase water-in-oil emulsions is decreased by using saccharide fatty acid esters as surfactants. Further, hydrophobic foams can be obtained by using saccharide fatty acid esters.Type: GrantFiled: August 30, 1993Date of Patent: April 26, 1994Assignee: Shell Oil CompanyInventors: Robert P. Adamski, Maryanne Mores, Pui K. Wong, Diana D. Davis
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Patent number: 5304580Abstract: The invention provides an expandable polyolefin resin composition comprising (a) 40 to 100 wt. % of a polypropylene resin having a melt index of 0.5 to 12, (b) 0 to 60 wt. % of a polyethylene resin having a melt index of 2 to 50 (c) 0.5 to 10 parts by weight of the di(meth)acrylate of an aliphatic dihydric alcohol having a methylene group with 2 to 18 carbon atoms between the (meth)acryloyloxy groups at both ends per 100 parts by weight of the combination of the resins (a) and (b), and (d) 1 to 50 parts by weight of a thermally decomposable blowing agent. Preferably the composition further comprises (e) 0.5 to 5 parts by weight of a monofunctional monomer. When uniformly crosslinked, the composition affords an expandable polyolefin resin composition suited to production of a crosslinked polyolefin resin foam excellent in heat resistance, toughness and moldability of formability and appearing homogeneous.Type: GrantFiled: June 25, 1992Date of Patent: April 19, 1994Assignee: Sekisui Chemical Co., Ltd.Inventors: Koichi Shibayama, Masao Ogasa, Toshihiro Arai, Eiichi Takahashi