From Reactant Containing Two Or More Ethylenic Unsaturated Groups Patents (Class 521/150)
  • Patent number: 5902845
    Abstract: A rubber-modified styrenic resin composition comprising 100 parts by weight of a rubber-modified styrenic resin (A) having 10 to 40% by weight of the content of a soft component particle and a mean particle diameter of the said particle of 0.1 to 1.2 .mu.m, and 1 to 30 parts by weight of fine particles having a mean particle diameter of 0.1 to 5 .mu.m and not having a glass transition temperature between -130 to 90.degree. C.A rubber-modified styrenic resin composition having superior plane impact strength, rigidity and gloss, and its molded article are provided.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: May 11, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shuji Yoshimi, Hayato Kihara, Takahiro Ishii
  • Patent number: 5863958
    Abstract: Polymers are made from 1,3,7-octatriene or like conjugated polyenes and a crosslinking agent having at least 2 activated double bonds such as ethylene glycol dimethacrylate. These polymers can be used to make absorbent foams that are useful in absorbent articles such as diapers, as well as latexes that are useful as binders and adhesives.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: January 26, 1999
    Assignee: The Procter & Gamble Company
    Inventors: John Collins Dyer, Bryn Hird, Pui Kwan Wong, Sharon Marie Beshouri
  • Patent number: 5863957
    Abstract: The present invention relates to porous crosslinked polymeric microbeads having cavities joined by interconnecting pores wherein at least some of the cavities at the interior of each microbead communicate with the surface of the microbead. The present invention also relates to a process for producing a porous, crosslinked polymeric microbead as well as the product of this process. This process involves combining an oil phase with an aqueous discontinuous phase to form an emulsion, adding the emulsion to an aqueous suspension medium to form an oil-in-water suspension of dispersed emulsion droplets, and polymerizing the emulsion droplets to form microbeads. At least 10% of the microbeads produced in accordance with the present invention are substantially spherical or substantially ellipsoidal or a combination of the two.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: January 26, 1999
    Assignee: Biopore Corporation
    Inventors: Nai-Hong Li, James R. Benson, Naotaka Kitagawa
  • Patent number: 5856409
    Abstract: A method for altering a macroporous cross-linked hydrophobic copolymeric lattice produced by precipitation polymerization in a solvent of at least one monounsaturated ester monomer and at least one polyunsaturated ester monomer soluble therein, in order to render the hydrophobic copolymeric lattice hydrophilic. The method involves saponifying the hydrophobic copolymeric lattice by reacting the surface of the hydrophobic copolymeric lattice with an aqueous alkali. The surface can also be rendered hydrophilic by polymerizing an acrylate monomer onto the lattice in order to form a surface containing carboxylic acid sites. The carboxylic acid sites formed on the surface of the lattice are converted to carboxylate anions.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: January 5, 1999
    Assignee: Dow Corning Corporation
    Inventors: Maris Jazeps Ziemelis, William Robb Roy Park
  • Patent number: 5830925
    Abstract: The invention provides a process for preparing a bitumen composition comprising blowing a mixture with an oxygen-containing gas which mixture comprises a bitumen having a penetration of less than 300 and a thermoplastic rubber which is present in an amount of less than 5% w, based on total mixture; bitumen compositions obtainable by such process; and the use of such bitumen compositions in asphalt mixtures for road applications.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: November 3, 1998
    Assignee: Shell Oil Company
    Inventors: Jacques Chion, Marie-Francoise Morizur
  • Patent number: 5804608
    Abstract: This invention relates to a reinforced closed-section structural-member structure making use of a heat-foamable filling reinforcement. The structure has been formed by connecting plural closed-section structural members (11-15) together. These closed-section structural members (11-15) are internally filled with a heat-foamed filling reinforcement (1) which comprises an epoxy resin material, a synthetic rubber material and a thermoplastic resin material as components.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: September 8, 1998
    Assignee: Mitsubishi Jidosha Kogyo Kabushiki Kaisha
    Inventors: Kazuyuki Nakazato, Hideki Fukudome
  • Patent number: 5801209
    Abstract: Disclosed are foamable EPDM compositions comprising EPDM, a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g and a blowing agent which are advantageous for use in applications where UHF microwave curing is utilized and for replacing foamable EPDM compositions incorporating similar amounts of conventional blends of carbon blacks. Also disclosed are foamed, cured EPDM compositions comprising: EPDM and a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g which have advantageously lower sponge density and lower sponge compression set than EPDM compositions incorporating similar amounts of conventional low reinforcing carbon blacks. Further disclosed is a process for producing the foamed, cured EPDM compositions of the present invention. Additionally disclosed is use of the foamed, cured EPDM compositions of the present invention as weatherstripping.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: September 1, 1998
    Assignee: Cabot Corporation
    Inventors: Bin Chung, Bruce E. Mackay, Ivan Zlatko Podobnik
  • Patent number: 5798009
    Abstract: A foamed rubber composition for tire comprises a particular amount of particles having specified hardness and average particle size and containing aluminum-bonded hydroxy group and/or silicon-bonded hydroxy group at its surface, and a particular amount of at least one specified silane coupling agent, and develops excellent performances on ice. Further, pneumatic tires contain the foamed rubber composition as a tread rubber.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: August 25, 1998
    Assignee: Bridgestone Corporation
    Inventor: Hiroyuki Teratani
  • Patent number: 5786406
    Abstract: A polyolefin based crosslinked foam excellent in impact absorbability, vibration absorbability and heat insulation, which can be used for various kinds of industrial applications such as materials for the interior of automobiles, cushioning, building, furniture, home use electric appliances, which foam comprises:a polyolefin based resin (A), and a conjugated diene polymer (B) having the peak tan .delta. value (obtained by dynamic viscoelasticity measurement) between -20.degree. C. and 40.degree. C.This invention also relates to a method for manufacturing said impact and vibration absorbable crosslinked foam.The polyolefin based crosslinked foam of this invention is excellent in impact absorbability and vibration absorbability while keeping moldability and heat resistance over a wide range of degrees of crosslinking.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: July 28, 1998
    Assignee: Toray Industries, Inc.
    Inventors: Nario Uejyukkoku, Yukinari Nakatsu
  • Patent number: 5776991
    Abstract: A foamed rubber composition for pneumatic tires comprises at least one diene polymer as a rubber ingredient and includes closed cells in a matrix rubber, each of these cells being covered with a coat layer made from a given amount of a resin or resin composite having a JIS-C hardness of not less than 75, a particle size of 10-200 .mu.m and a reacted conjugate diene unit content of not less than 10% by weight. In the production of the foamed rubber composition, the melting point or glass transition point of the resin or resin composite is restricted to at least 5.degree. C. lower than the vulcanizing temperature.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: July 7, 1998
    Assignee: Bridgestone Corporation
    Inventor: Hiroyuki Teratani
  • Patent number: 5770634
    Abstract: The present invention relates to compressable polymeric foam materials useful as insulation. These polymeric foams are prepared by polymerization of certain water-in-oil emulsions having a relatively high ratio of water phase to oil phase, commonly known as "HIPEs." The polymeric foam materials comprise a generally hydrophobic, flexible or semi-flexible, nonionic polymeric foam structure of interconnected open-cells. The foam structures have:(a) a specific surface area per foam volume of at least about 0.01 m.sup.2 /cc;(b) an expanded density of less than about 0.05 g/cc; and(c) a ratio of expanded to compressed thickness of at least about 3:1;wherein when the foam is compressed to 33% of its original expanded thickness and is thereafter maintained without artificial restraint on its surface, said foam will reexpand by no more than 50% after 21 days at ambient temperature (22.degree. C.).
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 23, 1998
    Assignee: The Procter & Gamble Company
    Inventors: John Collins Dyer, Thomas Allen DesMarais
  • Patent number: 5767168
    Abstract: Biodegradable and/or compostable polymers are made from isoprene, 2,3-dimethyl-1,3-butadiene or like conjugated dienes and a crosslinking agent having a cleavable linking group such as ethylene glycol dimethacrylate. These polymers can be used to make absorbent foams that are useful in absorbent articles such as diapers, as well as other biodegradable articles such as films, and latexes useful as binders and adhesives.
    Type: Grant
    Filed: January 10, 1996
    Date of Patent: June 16, 1998
    Assignee: The Proctor & Gamble Company
    Inventors: John Collins Dyer, Bryn Hird, Pui Kwan Wong
  • Patent number: 5760097
    Abstract: The present invention relates to porous crosslinked polymeric microbeads having cavities joined by interconnecting pores wherein at least some of the cavities at the interior of each microbead communicate with the surface of the microbead. The present invention also relates to a process for producing a porous, crosslinked polymeric microbead as well as the product of this process. This process involves combining an oil phase with an aqueous discontinuous phase to form an emulsion, adding the emulsion to an aqueous suspension medium to form an oil-in-water suspension of dispersed emulsion droplets, and polymerizing the emulsion droplets to form microbeads. At least 10% of the microbeads produced in accordance with the present invention are substantially spherical or substantially ellipsoidal or a combination of the two.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: June 2, 1998
    Assignee: Biopore Corporation
    Inventors: Nai-Hong Li, James R. Benson, Naotaka Kitagawa
  • Patent number: 5750582
    Abstract: The disclosure is a liquid absorbable material comprising a porous formed article possessed of partitioning walls of a cross-linked polymer and continued micropores, characterized in that said material has a density in the range of 0.2 to 1.0 g/cm.sup.3, and (a) that said partitioning walls exhibit a swelling degree to kerosine in the range of 2 to 10, and that said material has an absorption capacity per unit volume, the capacity being at least 4 cm.sup.3 /cm.sup.3 for water, ethanol, toluene and kerosine, respectively, or (b) that said material has an absorption capacity per unit weight, the capacity being at least 10 g/g for water, ethanol, toluene and kerosine, respectively, the liquids being at a temperature not less than the softening point of the cross-linked polymer. The liquid absorbable material can absorb liquids such as water and petroleum quickly and expand with the absorbed liquid.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: May 12, 1998
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Nobuyuki Harada, Katsuyuki Wada, Hisanori Obara, Toru Inaoka
  • Patent number: 5744507
    Abstract: A foamable, curable organosiloxane composition comprising an alkenyl-functional polyorganosiloxane, an organohydrogensiloxane, a blowing agent, a platinum catalyst and an adhesion promoter comprising an epoxy-functional compound, a hydroxyl-functional compound, a tetraalkylorthosilicate, an organotitanate and an aluminum or zirconium compound.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: April 28, 1998
    Assignee: Dow Corning Corporation
    Inventors: Gloria Lynne Angell, Michael Andrew Lutz
  • Patent number: 5733944
    Abstract: Aqueous polymer dispersions whose polymer is built up ofa) at least 50% by weight of butadiene, isoprene or a mixture thereof,b) at least 10% by weight of an ester of (meth)acrylic acid and a C.sub.1 -C.sub.8 -alkanol andc) from 0 to 10% by weight of other comonomers,where the total amount of monomers a) and b) makes up at least 90% by weight of the total amount of monomers, are useful for producing flame-resistant latex foam rubber which contains only hydrates of inorganic salts as flame retardants.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: March 31, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Roelof Balk, Peter Claassen, Onno Graalmann, Leonardus Aan de Meulen, Marinus Visseren
  • Patent number: 5731359
    Abstract: A vibration-absorbing element comprised of a foamed thermoplastic polymer selected from the group consisting of polyamide elastomers, EPDM polymers and SEBS polymers containing conventional additives, the foam structure having a pore size which decreases from the inside towards the outer surface and terminating in a smooth closed surface.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: March 24, 1998
    Assignees: A. Raymond GmbH & Co. KG, EMS-Inventa AG
    Inventors: Rene Moser, Hans-Jurgen Lesser
  • Patent number: 5700845
    Abstract: Disclosed are foamable EPDM compositions comprising EPDM, a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g and a blowing agent which are advantageous for use in applications where UHF microwave curing is utilized and for replacing foamable EPDM compositions incorporating similar amounts of conventional blends of carbon blacks. Also disclosed are foamed, cured EPDM compositions comprising: EPDM and a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g which have advantageously lower sponge density and lower sponge compression set than EPDM compositions incorporating similar amounts of conventional low reinforcing carbon blacks. Further disclosed is a process for producing the foamed, cured EPDM compositions of the present invention. Additionally disclosed is use of the foamed, cured EPDM compositions of the present invention as weatherstripping.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: December 23, 1997
    Assignee: Cabot Corporation
    Inventors: Bin Chung, Bruce E. Mackay, Ivan Zlatko Podobnik
  • Patent number: 5683527
    Abstract: A foamable, curable organosiloxane composition comprising an alkenyl-functional polyorganosiloxane, an organohydrogensiloxane, a blowing agent, a platinum catalyst and an adhesion promoter comprising an epoxy-functional compound, a hydroxyl-functional compound, a tetraalkylorthosilicate, an organotitanate and an aluminum or zirconium compound.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: November 4, 1997
    Assignee: Dow Corning Corporation
    Inventors: Gloria Lynne Angell, Michael Andrew Lutz
  • Patent number: 5672633
    Abstract: The present invention relates to powdery, insoluble, water-swellable, cross-linked polymers absorbing water, aqueous or serous liquids, which are formed ofa) 55-99.9%-wt. polymerized unsaturated, polymerizable acid-groups--comprising monomers which are neutralized to the extent of at least 25 mol-%,b) 0-40%-wt. polymerized unsaturated monomers which are co-polymerizable with a),c) 0.1-5.0%-wt. of a cross-linking agent, andd) 0-30%-wt. of a water-soluble polymer,with the weight amounts of a) to d) being relative to anhydrous polymer, and the polymer powder is heated with an at least bifunctional compound reactive with acid groups to a temperature of 150.degree. C.-250.degree. C. under cross-linkage of the surface, and the polymer powder that is thus already surface-cross-linked is subjected to a repeated surface-cross-linking treatment using an at least bifunctional compound reactive with acid groups at a temperature of 150.degree. to 250.degree. C.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: September 30, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Brehm, Hans-Georg Hartan
  • Patent number: 5668190
    Abstract: A silicone sponge rubber having a great tensile strength even when it has a low foam density can be obtained from a foamable silicone rubber composition including:(A) a polyolefin dispersion obtained by polymerizing monomers having polymerizable aliphatic unsaturated double bonds, dispersed in a dispersion medium of an organopolysiloxane having a viscosity of from 50 cSt to 1,000,000 cSt at 25.degree. C. whose molecular chain both terminals are terminated with silanol groups, to form a polyolefin in the silanol group-containing organopolysiloxane;(B) an organohydrogenpolysiloxane having at least two hydrogen atoms in one molecule;(C) at least one selected from the group consisting of water, an alcohol, a silanol group-containing organosilane, and a silanol group-containing siloxane having a viscosity of less than 50 cSt at 25.degree. C.; and(D) a platinum family metal catalyst.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: September 16, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Atsushi Yaginuma, Takeshi Miyao, Hironao Fujiki
  • Patent number: 5665785
    Abstract: Shaped microcellular structures having substantially non-cellular skins are produced from reactive liquid polymer systems incorporating thermoplastic microspheres containing volatile materials such as low boiling point halogenated or non-halogenated organic materials. Use of thermoplastic microspheres encapsulating such volatile materials facilitates the removal of the shaped foamed structure from molds, eliminating the need for release agents. Various products based on this process, such as bathroom fixtures, bicycle and wheel chair tires, shoe soles, and automotive parts, are provided.
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: September 9, 1997
    Assignee: Urethane Technologies, Inc.
    Inventors: Thomas Roy McClellan, John T. Mizulo, Edwin S. Nelson, Grant R. Pato
  • Patent number: 5652276
    Abstract: A foaming resin composition consisting essentially of (A) an organic compound having a carbon-carbon double bond, (B) a compound having an SiH group, and (C) a compound having an OH group is foamed and cured at room temperature or under heat at relatively low temperatures, to obtain hard, semi-hard or soft plastic foam having good weather resistance and good compatibility with coating compositions and adhesives.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: July 29, 1997
    Assignee: Kanegafuchi Chemical Industry Co., Ltd.
    Inventors: Hiroshi Ando, Kensuke Kondo, Naoaki Nakanishi, Hiroshi Ito, Shigeki Hamaguchi, Kazuya Yonezawa
  • Patent number: 5650222
    Abstract: Low density collapsed absorbent foams materials that, upon contact with aqueous fluids, in particular urine, can expand and absorb these fluids. These low density foams typically have an expanded thickness from about 6 to about 10 times the thickness of the foams in their collapsed state. These low density foams are made by polymerizing high internal phase emulsions (HIPEs) where the volume to weight ratio of the water phase to the oil phase is in the range of from about 55:1 to about 100:1.
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: July 22, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Thomas Allen DesMarais, Keith Joseph Stone, John Collins Dyer, Bryn Hird, Stephen Allen Goldman, Paul Seiden
  • Patent number: 5646224
    Abstract: A rubber composition excellent in shape-retainability also in processibility, compression set and the like, which comprises a single ethylene-.alpha.-olefin-non-conjugated diene copolymer which has (1) a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 80 to 200, (2) a weight average molecular weight/number average molecular weight ratio of 6 or more as measured by a gel permeation chromatography (GPC), and (3) a stress-retention of 0.2 or more after 100 seconds at 80.degree. C. in a compression type stress-relaxation test.
    Type: Grant
    Filed: January 3, 1996
    Date of Patent: July 8, 1997
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Takashi Kawata, Shoei Tsuji, Yoji Mori
  • Patent number: 5632737
    Abstract: Absorbent foams materials that are capable of acquiring and distributing aqueous fluids, especially discharged body fluids such as urine. These absorbent foams combine relatively high capillary absorption pressures and capacity-per-weight properties that allow them to acquire fluid, with or without the aid of gravity. These absorbent foams also give up this fluid efficiently to higher absorption pressure storage materials, including foam-based absorbent fluid storage components, without collapsing. These absorbent foams are made by polymerizing high internal phase emulsions (HIPEs).
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: May 27, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Keith J. Stone, Thomas A. DesMarais, Gary D. LaVon, Stephen A. Goldman, Paul Seiden
  • Patent number: 5629353
    Abstract: Condensation polymerization followed by a supercritical extraction step can be used to obtain highly cross-linked nanoporous polymers with high surface area, controlled pore sizes and rigid structural integrity. The invention polymers are useful for applications requiring separation membranes.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: May 13, 1997
    Assignee: The Regents of the University of California
    Inventors: Warren P. Steckle, Jr., Paul G. Apen, Michael A. Mitchell
  • Patent number: 5618853
    Abstract: A molded structure 1 produced by extrusion, such as an expanded plastic foam, a sheet, a profile or the like, contains at least 10% by volume of open cells 2, 4 which have a polyhedron-like shape and are adjacent to one another. A higher temperature during the extrusion in comparison with the extrusion of thermoplastic molded structures having a closed-cell structure results in deformation-free opening of the cells. Webs 3 of cell walls 5, 6 remain intact in shape whether they have orifices 7 or no passages, so that the mechanical strength of the cell skeleton or of the space matrix is retained.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: April 8, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hub A. G. Vonken, Hendrik-Jan Muntendam, Jos van der Hoeven, Udo Piqu e
  • Patent number: 5583162
    Abstract: The present invention relates to porous crosslinked polymeric microbeads having cavities joined by interconnecting pores wherein at least some of the cavities at the interior of each microbead communicate with the surface of the microbead. Approximately 10% of the microbeads of the present invention are substantially spherical or substantially ellipsoid or a combination of the two. The present invention also relates to a process for producing a porous, crosslinked polymeric microbead as well as the product of this process. This process involves combining a continuous phase with an aqueous discontinuous phase to form an emulsion, adding the emulsion to an aqueous suspension medium to form an oil-in-water suspension of dispersed emulsion droplets, and polymerizing the emulsion droplets to form microbeads. Also included in the invention are modifications of the microbeads as well as methods for using the microbeads in a variety of applications.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: December 10, 1996
    Assignee: Biopore Corporation
    Inventors: Nai-Hong Li, James R. Benson
  • Patent number: 5563179
    Abstract: Absorbent foams materials that are capable of acquiring and distributing aqueous fluids, especially discharged body fluids such as urine. These absorbent foams combine relatively high capillary absorption pressures and capacity-per-weight properties that allow them to acquire fluid, with or without the aid of gravity. These absorbent foams also give up this fluid efficiently to higher absorption pressure storage materials, including foam-based absorbent fluid storage components, without collapsing. These absorbent foams are made by polymerizing high internal phase emulsions (HIPEs).
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: October 8, 1996
    Assignee: The Proctor & Gamble Company
    Inventors: Keith J. Stone, Thomas A. DesMarais, John C. Dyer, Bryn Hird, Gary D. La Von, Stephen A. Goldman, Michelle R. Peace, Paul Seiden
  • Patent number: 5525636
    Abstract: The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 75 to 98% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 2 to 25% by weight of at least one styrene-soluble elastomer,c) from 1 to 15% by weight, based on the sum of a) and b), of a low-boiling blowing agent, and, if desired,d) conventional additives in effective amounts,where the unfoamed beads have a structure in which the elastomer phase is dispersed in the polystyrene phase in the form of cell particles, and to foams and foam moldings produced therefrom.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: June 11, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Henn, Klaus Hahn, Wolfgang Loth, Walter Heckmann, Uwe Blumenstein, Hans-Dieter Schwaben, Karl-Heinz Wassmer, Hermann Tatzel
  • Patent number: 5525637
    Abstract: The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 50 to 90% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 5 to 30% by weight of at least one styrene-soluble elastomer,c) from 5 to 20% by weight of at least one block copolymer containing styrene as one component,d) from 1 to 15% by weight, based on the sum of a), b) and c), of a low-boiling blowing agent, and, if desired,e) conventional additives in effective amounts,where, in the unfoamed polystyrene beads, component b) is in the form of cell particles and component c) is in the form of particles having a mean size of from 0.2 to 2 .mu.m in the polystyrene phase, and to foams and foam moldings produced therefrom.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: June 11, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Henn, Klaus Hahn, Andreas Deckers, Wolfgang Loth, Uwe Blumenstein, Hans-Dieter Schwaben, Erich Klement
  • Patent number: 5512604
    Abstract: Novel porous copolymers are disclosed which can be used to prepare ion-exchange resins and polymeric adsorbents. The copolymers comprise a copolymer of at least one monovinylidene monomer and a crosslinking monomer and have a unique cellular pore structure. The cellular structure comprises a macroporous void phase which is dispersed within a continuous copolymer phase. The porous void phase comprises a plurality of cellular void spaces which are at least partially enclosed by walls of the continuous copolymer phase. Also disclosed are processes which can be used to prepare the porous copolymers, as well as ion-exchange resins and polymeric adsorbents using the porous copolymers.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: April 30, 1996
    Assignee: The Dow Chemical Company
    Inventor: Tom N. Demopolis
  • Patent number: 5506035
    Abstract: An improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Methods for making the foam and absorbent products, members and articles containing the foam are also disclosed.
    Type: Grant
    Filed: November 17, 1994
    Date of Patent: April 9, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Dean Van Phan, Paul D. Trokhan
  • Patent number: 5504163
    Abstract: Residual chloromethyl groups in methylene-bridged aromatic polymer adsorbents are susceptible to hydrolysis to benzyl alcohol groups and oxidation to benzoic acid groups. The introduction of these hydroxyl and carboxylic acid groups contributes to the water adsorption capacity or hydrophilicity of these adsorbents. Unfortunately, this hydrophilicity interferes with the utility of these resins as adsorbents for volatile organic compounds. By capping these residual chloromethyl groups with hydrophobic aromatic compounds prior to their opportunity to hydrolyze or oxidize, the hydrophobicity of methylene-bridged aromatic polymer adsorbents is increased and their utility for the absorption of organic compounds is enhanced.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: April 2, 1996
    Assignee: The Dow Chemical Company
    Inventors: Marvin H. Tegen, Kenneth C. Jones
  • Patent number: 5496864
    Abstract: The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 50 to 75% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 5 to 30% by weight of a styrene-soluble elastomer,c) from 5 to 20% by weight of at least one block copolymer containing styrene as one component,d) from 15 to 50% by weight of at least one polyolefin,e) from 1 to 15% by weight, based on the sum of a) and b), of a low-boiling blowing agent, and, if desired,f) conventional additives in effective amounts,and to foams produced therefrom.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: March 5, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Henn, Klaus Hahn, Hans Ho/ nl, Walter Heckmann, Karl-Heinz Wassmer, Erich Klement, Joachim Fischer
  • Patent number: 5494939
    Abstract: The material contains interrelated micro- and anisodiametric macropores which latter are disposed mainly on peripheral portions. The volume ratio of micro- and macropores is 1:3-7.The process involves freezing a polymer dispersion at a temperature ensuring a 3-11:1 ratio of dispersed phase to the noncrystallized dispersion medium, seasoning the conjugate-dispersed system at a temperature and within a time sufficient for reversal of phases, followed by thawing. The used polymer dispersion contains a liquid crystallizable dispersion medium and a polymer phase capable of autohesion at temperatures below the initial melting temperature of crystals in the dispersion medium.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: February 27, 1996
    Assignees: A. H. Hides, Skins Australia Pty Ltd.
    Inventors: Efim S. Vainerman, Irina B. Portnaya
  • Patent number: 5492940
    Abstract: An acrylic/lactam monomer based polymeric resin is provided which has excellent weatherability, outstanding transparency and optical clarity, improved heath and solvent resistance, as well as improved impact strength. The acrylic/lactam monomer based polymeric resin is formulated by the catalytic activation at ambient temperature of a polymerization syrup which contains from about 300 to about 2970 parts by volume of an acrylic monomer, from about 30 to about 2700 parts by volume of a lactam monomer, from about 0.3 parts to about 40 parts by volume of a mercaptan chain transfer agent and from about 0.3 to about 40 parts by volume of a crosslinking agent capable of crosslinking the acrylic monomer and the lactam monomer. To prevent further polymerization of the polymeric constituents of the polymerization syrup, as well as to enhance the shelf life of the polymerization syrup, an effective amount of a polymerization inhibitor and an ultraviolet light stabilizer are incorporated into the polymerization syrup.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: February 20, 1996
    Inventor: Bill R. Edwards
  • Patent number: 5453453
    Abstract: This invention is directed to a fire-resistant, essentially halogen-free epoxy composition that emits low amounts of smoke and toxic gas while burning. The one-part composition is particularly useful in aerospace applications for bonding, sealing and/or insulating metal, plastic and composite parts.
    Type: Grant
    Filed: April 6, 1994
    Date of Patent: September 26, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Alain H. Lamon, Sylvie C. Le Cozannet
  • Patent number: 5362759
    Abstract: There is provided a process for reclaiming elastomeric waste material, particularly rubber, which includes the steps impregnating the elastomeric waste material with an essential oil and then heat treating the impregnated material under reduced pressure with microwave radiation.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: November 8, 1994
    Assignee: James R. Hunt
    Inventors: James R. Hunt, David Hall
  • Patent number: 5352711
    Abstract: Normally hydrophobic foams, such as polyurethane foams and polymerized water-in-oil emulsion foams, are rendered hydrophilic by means of treatment with simple surfactants and hydrophilizing agent salts. Thus, a surfactant-containing foam is treated with a solution of, for example, calcium chloride, and is dried to leave a substantially uniformly distributed residue of hydrated or hydratable calcium chloride on the surfactant-containing internal foam surfaces. In-use, the combination of surfactant and calcium chloride hydrate provides a hydrophilic surface to the foam. Other hydratable calcium or magnesium salts such as magnesium chloride can be used. The resulting hydrophilized foams are suitable for use in absorbent devices, including diapers, sanitary napkins, bandages, and the like.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: October 4, 1994
    Assignee: The Proctor & Gamble Company
    Inventor: Thomas A. DesMarais
  • Patent number: 5350776
    Abstract: A foamed elastomeric polymer with a camouflage appearance on its surface and throughout its mass, characterized by distinct, randomly sized regions of various colors, having curved, nonangular borders with substantially no blend of colors, and being free from gas pockets and blisters. A process for manufacturing a foamed elastomeric polymer of the above description.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: September 27, 1994
    Inventor: Eduardo A. Raad
  • Patent number: 5340842
    Abstract: Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and polymerization initiators are obtained by using saccharide fatty acid esters as surfactants. The amount of surfactants necessary to form stable high internal phase water-in-oil emulsions is decreased by using saccharide fatty acid esters as surfactants. Further, hydrophobic foams can be obtained by using saccharide fatty acid esters.
    Type: Grant
    Filed: January 19, 1994
    Date of Patent: August 23, 1994
    Assignee: Shell Oil Company
    Inventors: Robert P. Adamski, Maryanne Mores, Pui K. Wong, Diana D. Davis
  • Patent number: 5338766
    Abstract: An improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Methods for making the foam and absorbent products, members and articles containing the foam are also disclosed.
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: August 16, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Dean V. Phan, Paul D. Trokhan
  • Patent number: 5334621
    Abstract: Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and initiators, useful in preparing low density porous crosslinked polymeric foams, are obtained by using a surfactant system containing (a) one or more sorbitan fatty acid ester or saccharide fatty acid ester and (b) a glycerol monofatty acid ester. A higher water to oil ratio water-in-oil emulsions can be formed with the same formulation by using the glycerol monofatty acid ester cosurfactant.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: August 2, 1994
    Assignee: Shell Oil Company
    Inventor: Sharon M. Beshouri
  • Patent number: 5331015
    Abstract: Disclosed are absorbent foam materials suitable for use as or in the absorbent cores of absorbent articles, such as diapers which absorb and retain aqueous body fluids. Such foam materials comprise hydrophilic, flexible open-celled structures which are preferably prepared by polymerizing high internal phase (HIPE) water-in-oil emulsions. Such foam materials have a pore volume of from about 12 to 100 mL/g, and a capillary suction specific surface area of from about 0.5 to 5.0 m.sup.2 /g. These materials also exhibit a resistance to compression deflection such that a confining pressure of 5.1 kPa produces after 15 minutes a strain of from about 5% to 95% compression when the material is saturated at 37.degree. C. to its free absorbent capacity with synthetic urine.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: July 19, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Thomas A. DesMarais, Keith J. Stone, Hugh A. Thompson, Gerald A. Young, Gary D. LaVon, John C. Dyer
  • Patent number: 5328935
    Abstract: A method of making an improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Absorbent products, members and articles containing the foam are also disclosed.
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: July 12, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Dean Van Phan, Paul D. Trokhan
  • Patent number: 5308877
    Abstract: Organic resins with high surface areas and porosities, which are insoluble in organic solvents and contain few or no flexible groups in the resin structure, are disclosed. Also disclosed is a process for making such resins from polyfunctional aryl alkali metal compounds and a second polyfunctional monomer. Such resins are useful as absorbants.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: May 3, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bruce E. Smart, Owen W. Webster
  • Patent number: 5306733
    Abstract: Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and polymerization initiators are obtained by using saccharide fatty acid esters as surfactants. The amount of surfactants necessary to form stable high internal phase water-in-oil emulsions is decreased by using saccharide fatty acid esters as surfactants. Further, hydrophobic foams can be obtained by using saccharide fatty acid esters.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: April 26, 1994
    Assignee: Shell Oil Company
    Inventors: Robert P. Adamski, Maryanne Mores, Pui K. Wong, Diana D. Davis
  • Patent number: 5304580
    Abstract: The invention provides an expandable polyolefin resin composition comprising (a) 40 to 100 wt. % of a polypropylene resin having a melt index of 0.5 to 12, (b) 0 to 60 wt. % of a polyethylene resin having a melt index of 2 to 50 (c) 0.5 to 10 parts by weight of the di(meth)acrylate of an aliphatic dihydric alcohol having a methylene group with 2 to 18 carbon atoms between the (meth)acryloyloxy groups at both ends per 100 parts by weight of the combination of the resins (a) and (b), and (d) 1 to 50 parts by weight of a thermally decomposable blowing agent. Preferably the composition further comprises (e) 0.5 to 5 parts by weight of a monofunctional monomer. When uniformly crosslinked, the composition affords an expandable polyolefin resin composition suited to production of a crosslinked polyolefin resin foam excellent in heat resistance, toughness and moldability of formability and appearing homogeneous.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: April 19, 1994
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Koichi Shibayama, Masao Ogasa, Toshihiro Arai, Eiichi Takahashi