Abstract: A process for producing a magnetic core material is disclosed. The process includes distributing particles within a solution medium to form a colloidal solution. The process further includes modifying a surface chemistry of the particles by adding one or more additives to the colloidal solution. The process further includes gelating the colloidal solution to form the magnetic core material.

Abstract: An object of the present invention is to provide copper nanoparticles that suppress the oxidation of copper, have an average particle diameter of 10 nm or less and therefore undergo a remarkable reduction in the melting point, are highly dispersible, can be sintered at a low temperature, allow the removal of the protective layer during low-temperature sintering at 150° C. or less, and can be suitably used as a conductive copper nanoink material; and to also provide a method for preserving copper nanoparticles, whereby the copper nanoparticles can be stably preserved at room temperature for a long period of time, and can be transported.

Abstract: The present disclosure provides a series of new and improved porous polyamide aerogels derived from multifunctional aromatics that combine the high mechanical strength of aramids with the pore structure of aerogels. The polyamide aerogels have a hyperbranched structure, relatively low density, high porosity and may be derived from functionalized monomers having more aromatic groups than functional groups. The present disclosure also provides a new method for producing the porous polyamide aerogels by polymerizing an aromatic multifunctional carboxylic acid or a ferrocene multifunctional carboxylic acid with a polyfunctional aromatic isocyanate at moderate reaction conditions followed by drying with liquid CO2. Also disclosed are various methods of use of these polyamide aerogels in a variety of applications.

Abstract: A novel aluminum chelate latent curing agent that can cure a glycidyl ether epoxy compound at a lower temperature and more quickly than an aluminum chelate latent curing agent produced by emulsification and interfacial polymerization of a polyfunctional isocyanate in the presence of both a radical polymerizable monomer, such as divinyl benzene, and a radical polymerization initiator, is micro-encapsulated in a core-shell form, wherein an aluminum chelate curing agent and a cationic polymerizable compound are included in a capsule formed from an interfacial polymerization product of a polyfunctional isocyanate.

Abstract: Disclosed are a type of catalyst which can catalyse the ring-addition reaction of CO2 and an alkylene oxide at 0˜180° C. under 0.1˜8.0 MPa to produce a corresponding cyclic carbonate, and the preparation thereof. The catalyst is a conjugated microporous macromolecule polymer complexed with cobalt, chromium, zinc, copper or aluminium, and by using the macromolecule catalysts complexed with different metals to catalyse the reaction of CO2 and alkylene oxide at normal temperature and normal pressure, a yield of the corresponding cyclic carbonate of 35%˜90% can be obtained. The catalyst is easy to recover and the re-use of the catalyst has no influence on the yield; additionally, the yield can reach over 90% by controlling the reaction conditions.

Abstract: The present invention relates to a novel porous film material which comprises at least one carbonaceous semimetal oxide phase, and to a process for production thereof. The invention also relates to the use of these porous film materials as a separator layer or for production of such separator layers in electrochemical cells, particularly in lithium cells and especially in lithium secondary cells.

Abstract: The invention provides mesostructured materials and methods of preparing mesostructured materials including metal-rich mesostructured nanoparticle-block copolymer hybrids, porous metal-nonmetal nanocomposite mesostructures, and ordered metal mesostructures with uniform pores. The nanoparticles can be metal, metal alloy, metal mixture, intermetallic, metal-carbon, metal-ceramic, semiconductor-carbon, semiconductor-ceramic, insulator-carbon or insulator-ceramic nanoparticles, or combinations thereof. A block copolymer/ligand-stabilized nanoparticle solution is cast, resulting in the formation of a metal-rich (or semiconductor-rich or insulator-rich) mesostructured nanoparticle-block copolymer hybrid. The hybrid is heated to an elevated temperature, resulting in the formation of an ordered porous nanocomposite mesostructure. A nonmetal component (e.g., carbon or ceramic) is then removed to produce an ordered mesostructure with ordered and large uniform pores.

Abstract: The present invention relates to compounds and their use as ligands, in particular in metal catalyst complexes. The ligands of the invention are capable of binding to a solid support. The invention includes the ligands in their own right and when bound to a support and the compounds may be used to prepare metal catalyst complexes.

Abstract: A process for the preparation of thermoplastic auxetic foams comprising the steps of: a) taking conventional thermoplastic foam; b) subjecting said foam to at least one process cycle wherein the foam is biaxially compressed and heated; c) optionally subjecting the foam to at least one process cycle wherein the biaxial compression is removed and the foam mechanically agitated prior to reapplying biaxial compression and heating; d) cooling said foam to a temperature below the softening temperature of said foam; and e) removing said compression and heat.

Abstract: An embodiment of the present invention includes a method for chemically modifying inner surfaces of channels capable of further regulating characteristics of the internal environment of channels, by forming a polymer complex having a specific channel group B, the channel environmental characteristics of which are regulated by substituents A, followed by utilizing the channels of the channel group B as a reaction field to convert the substituent A to a different substituent. The method may comprise including a guest molecule in the channel of the channel group B in which the substituents A are arranged; and reacting the guest molecule with the substituent A in the channel to convert the substituent A to a substituent A?, and to arrange the substituent A? regularly directing to the inside of the channel of the channel group B or any channel of other channel groups.

Abstract: The invention relates to a titanium based polycarboxylate inorganic-organic hybrid solid material that has a pseudo-cubic crystalline structure, to a method for preparing the same using a solvo-thermal procedure, and to the uses thereof in particular for the storage of gases, the adsorption of liquids, the separation of liquids or gases, and the applications thereof in optics or catalysis, in the biomedical (controlled release drug), cosmetic fields, etc.

Abstract: The invention provides mesostructured materials and methods of preparing mesostructured materials including metal-rich mesostructured nanoparticle-block copolymer hybrids, porous metal-nonmetal nanocomposite mesostructures, and ordered metal mesostructures with uniform pores. The nanoparticles can be metal, metal alloy, metal mixture, intermetallic, metal-carbon, metal-ceramic, semiconductor-carbon, semiconductor-ceramic, insulator-carbon or insulator-ceramic nanoparticles, or combinations thereof. A block copolymer/ligand-stabilized nanoparticle solution is cast, resulting in the formation of a metal-rich (or semiconductor-rich or insulator-rich) mesostructured nanoparticle-block copolymer hybrid. The hybrid is heated to an elevated temperature, resulting in the formation of an ordered porous nanocomposite mesostructure. A nonmetal component (e.g., carbon or ceramic) is then removed to produce an ordered mesostructure with ordered and large uniform pores.

Abstract: The invention relates to gas adsorbents based on metal-organic microporous coordination polymers of the metallic bispyrmidinolate-type with a sodalite-type topology, having an adsorbent performance that is typical of crystalline microporous materials. The aforementioned materials also have a large accessible pore volume of between 25 and 45% of the total volume of the material with a monodispersion of pores having diameters of less than 1.3 nm. In addition, the materials have a high capacity for adsorption of small gases, such as carbon monoxide, carbon dioxide, hydrogen, nitrogen, methane, acetylene, etc., which is reversible such that, once said gases have been stored, they can be desorbed.

Abstract: The present invention discloses a method for fabricating aerogels, a method for fabricating surface-modified aerogels, and a method for fabricating biocomposites. Take the fabricating method of biocomposites for example, first, a precursor solution is provided and the precursor solution comprises a hydrophilic ionic liquid, a catalyzed hydrolysis and/or condensation reagent, at least one biomolecule. Next, a curing process is performed for the precursor solution to hydrolyze and polymerize the at least one alkoxide monomer and/or aryloxide monomer to wrap at least one biomolecule and thus form biocomposite. Afterwards, an extracting process is performed by a solvent for the biocomposite to substitute the ionic liquid in the biocomposite. Finally, a drying process for the biocomposite is carried out after the extracting process so as to remove the solvent in the biocomposite. Therefore, the biocomposite is formed.

Abstract: The present invention relates to compounds and their use as ligands, in particular in metal catalyst complexes. The ligands of the invention are capable of binding to a solid support. The invention includes the ligands in their own right and when bound to a support and the compounds may be used to prepare metal catalyst complexes.

Abstract: A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymers obtained.

Abstract: A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymer is obtained.

Abstract: A mesoporous material is described. It includes a network of interconnected pores within an L3 phase structure. The pores include pore walls of a silicate material functionalized with at least one metal cation—usually a transition metal. Articles which include the mesoporous material are also disclosed, along with methods for making the mesoporous material.

Abstract: Disclosed herein is a sol-gel polymerization process for synthesizing metal-doped organic gels. The process polymerizes metal salts of hydroxylated benzenes or hydroxylated benzene derivatives with alkyl or aryl aldehydes to form metal-doped, wet, organic gels. The gels can then be dried by supercritical solvent extraction to form metal-doped aerogels or by evaporation to form metal-doped xerogels. The aerogels and xerogels can then be pyrolyzed.

Abstract: A fully imidized, solvent-free polyimide foam having excellent mechanical, acoustic, thermal, and flame resistant properties is produced. A first solution is provided, which includes one or more aromatic dianhydrides or derivatives of aromatic dianhydrides, and may include one or more aromatic diamines, dissolved in one or more polar solvents, along with an effective amount of one or more blowing agents. This first solution may also advantageously include effective amounts respectively of one or mores catalysts, one or more surfactants, and one or more fire retardants. A second solution is also provided which includes one or more isocyanates. The first and second solutions are rapidly and thoroughly mixed to produce an admixture, which is allowed to foam—in an open container, or in a closed mold—under ambient conditions to completion produce a foamed product. This foamed product is then cured by high frequency electromagnetic radiation, thermal energy, or a combination thereof.

Abstract: A mesoporous material is described. It includes a network of interconnected pores within an L3 phase structure. The pores include pore walls of a silicate material functionalized with at least one metal cation—usually a transition metal. Articles which include the mesoporous material are also disclosed, along with methods for making the mesoporous material.

Abstract: A process for the preparation of crystalline microporous titanium silicates using ethylsilicate-40 and titanium peroxide as silicon and titanium sources respectively is described. The process permits a significant decrease in the production cost of titanium silicate containing higher amount of titanium (Si/Ti=20) because of cheaper raw materials as well as reduction in the quantity of tetarpropylammonium hydroxide (TPAOH) template (SiO2:TPAOH=1:0.06-0.1) required for preparation. The material obtained by the present invention is useful as an active catalyst in the reactions such as oxidation of hydrocarbons, alcohols, sulphides, and thioethers.

Abstract: Disclosed herein is a sol-gel polymerization process for synthesizing metal-doped organic gels. The process polymerizes metal salts of hydroxylated benzenes or hydroxylated benzene derivatives with alkyl or aryl aldehydes to form metal-doped, wet, organic gels. The gels can then be dried by supercritical solvent extraction to form metal-doped aerogels or by evaporation to form metal-doped xerogels. The aerogels and xerogels can then be pyrolyzed.

Abstract: The invention discloses methods for making foams comprising functionalized metal oxide nanoparticles by photopolymerizing or thermally polymerizing emulsions comprising a reactive phase and a phase immiscible with the reactive phase components. Foams made from water-in-oil emulsions, including high internal phase emulsion are also disclosed. Articles and uses for the foams are also described.

Abstract: Polymer-metal ion composites and methods are provided for reversibly binding target compounds using such composites. Broadly, the composites comprise an amorphous polymer matrix having a plurality of channels with metal ion-ligand complexes immobilized therein. The composites are formed by polymerizing a polymeric moiety with a metal complex template in the presence of a solvent. The template is formed of a metal ion having a ligand bonded thereto as well as to polymer matrix. The metal ion and ligand are selected to yield a composite having a particular chemical and/or physical environment around the metal sites, depending upon the desired end use. Preferred metal ions include ions of the transition metals. The composites can be contacted with target compounds for reversibly binding the compounds. Exemplary compounds include those selected from the group consisting of oxygen, carbon monoxide, carbon dioxide, compounds having an atom of P, S, or N, and mixtures thereof.

Abstract: A foamable rubber composition comprising 100 parts by weight of a nitrile group-containing highly saturated copolymer rubber, 5 to 100 parts by weight of polyethylene, 3 to 100 parts by weight of a metal salt of an ethylenically unsaturated carboxylic acid, 0.5 to 10 parts by weight of an organic peroxide and 1 to 15 parts by weight of a foaming agent is foamed and shaped into a foamed rubber product.

Abstract: The invention discloses methods for making foams comprising functionalized metal oxide nanoparticles by photopolymerizing or thermally polymerizing emulsions comprising a reactive phase and a phase immiscible with the reactive phase components. Foams made from water-in-oil emulsions, including high internal phase emulsion are also disclosed. Articles and uses for the foams are also described.

Abstract: Polymer-metal ion composites and methods are provided for reversibly binding target compounds using such composites. Broadly, the composites comprise an amorphous polymer matrix having a plurality of channels with metal ion-ligand complexes immobilized therein. The composites are formed by polymerizing a polymeric moiety with a metal complex template in the presence of a solvent. The template is formed of a metal ion having a ligand bonded thereto as well as to polymer matrix. The metal ion and ligand are selected to yield a composite having a particular chemical and/or physical environment around the metal sites, depending upon the desired end use. Preferred metal ions include ions of the transition metals. The composites can be contacted with target compounds for reversibly binding the compounds. Exemplary compounds include those selected from the group consisting of oxygen, carbon monoxide, carbon dioxide, compounds having an atom of P, S, or N, and mixtures thereof.

Abstract: Disclosed are polymeric foam materials obtained using monomers based on silicon and/or germination. The copolymerization of silicon- or germanium-based monomers provide foams that have low glass transition temperatures and low densities. These foams also exhibit relatively high yield stress values, which make the foams suitable for absorption of fluids, particularly aqueous fluids such as urine and menses (when the foams are rendered hydrophilic). The foams have a variety of other uses, including insulation applications.

Abstract: Polymeric foams with novel chemical compositions are prepared by the condensation of specially-synthesized precursors, which contain (in addition to carbon and hydrogen) one or more of the following elements: oxygen, fluorine, nitrogen (in structures with stable chemical bonds), silicon, boron, phosphorus (in high oxidation states), and certain metals (and/or their oxides and hydroxides). Upon mixing in the proper proportions and/or heating these precursors react rapidly to generate polymeric networks, consisting of heterocyclic crosslink centers, connected with heterochain segments; hydrogen is largely eliminated or replaced by fluorine. These structures possess inherent nonflammability and high thermoxidative stability. Foaming is effected by the gaseous by-products of the condensation reactions, as well as by the addition of foaming agents. The resulting foam products can be formulated to have a wide range of densities and flexibilities.

Abstract: A foamed polymethacrylimide resin having improved creep resistance at high temperature and reduced moisture absorption is obtained by heating a foamable resin composition consisting of (1) a copolymer formed between 47 to 53 percent by weight of methacrylonitrile monomer, 53 to 47 percent by weight of methacrylic acid monomer, and 0.01 to 4 percent, by weight of said monomers, of a metal salt of acrylic or methacrylic acid, and (2) 0.5 to 4 percent, also by weight of the monomers, of a blowing agent mixture of formamide or monomethyl formamide and a monohydric aliphatic alcohol having from 3 to 8 carbon atoms in the molecule.

Abstract: The present invention discloses a novel and unique family of agents which reversibly binds molecular oxygen at room temperature.

Abstract: A metal-containing polyaldehyde microsphere composed of a polyaldehyde microsphere to which a transition metal, e.g. Au, Ag, Pt, Pd, Tc, Fe, Ni or Co, is bound may be obtained in accordance with this invention. The polyaldehyde, e.g. polyacrolein or polyglutaraldehyde, may be encapsulated in agarose, and the microsphere may be radioactive or magnetic. The microphere may additionally have a compound having at least one amine group, e.g. a drug, antibody, antigen, enzyme or other protein, bound to its surface.In one embodiment a transition metal is bound to a polyaldehyde microsphere by contacting the polyaldehyde microsphere with a suitable amount of an appropriate salt or acid of the transition metal under suitable conditions so as to cause the salt or acid to be reduced to a lower valence state and to bind to the microsphere. Some salts or acids may thus be reduced to the elemental state; others are further reduced with an appropriate reducing agent.

Abstract: The present invention discloses a novel and unique family of agents which reversibly binds molecular oxygen at room temperature.

Abstract: This invention relates to a novel elastomeric foamed material which has been found to exhibit a variety of unusual and desirable features both in its physcial properties and in its process of manufacture. These foamed compositions of a lightly sulfonated elastomeric gum contain a non-volatile polar plasticizer and preferably extenders such as oil and fillers. These elastomer foams exhibit an unusal profile of physical properties including extremely rapid production, melt reprocessability of fabricated articles, a novel memory characteristic, and high temperature reshaping of foamed objects while maintaining a good foam structure. These novel foams can be manufactured with relatively uniform cell structures and with small cell sizes at foam densities from near bulk density to less than 0.1g/cc.

Abstract: This invention relates to a novel elastomeric foamed material which has been found to exhibit a variety of unusual and desirable features both in its physical properties and in its process of manufacture. These foamed compositions of a lightly sulfonated elastomeric gum contain a non-volatile polar plasticizer and preferably extenders such as oil and fillers. These elastomer foams exhibit an unusual profile of physical properties including extremely rapid production, melt reprocessability of fabricated articles, a novel memory characteristic, and high temperature reshaping of foamed objects while maintaining a good foam structure. These novel foams can be manufactured with relatively uniform cell structures and with small cell sizes at foam densities from near bulk density to less than 0.1g/cc.

Abstract: This invention relates to a process for the manufacture of an organo-metallate polymere which comprises reacting in a liquid phase a metallate with a pseudohalide compound and/or other polymerizable compound and allowing the reaction to proceed to completion.