Treating A Cellular Solid Polymer By Adding A Material Thereto Which Reacts With The Polymer Or Forms A Composition Therewith, Or Products Of Said Treating Process Patents (Class 521/53)
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Patent number: 7972695Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: January 11, 2011Date of Patent: July 5, 2011Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H. Piispanan, Michael T. Williams
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Patent number: 7943676Abstract: A method of recycling waste plastic foam materials firstly is to smash a waste material including polyurethane foam into fine particles so as to obtain a first starting material. The first starting material is then crisped and followingly milled into powder so as to obtain a second starting material. The second starting material is then placed into a mixer to mix with a first foaming reaction solution including polyol, catalyst and additives injected into the mixer so as to form a semi-treated foaming material. And then, the semi-treated foaming material is mixed with a second foaming reaction solution including diisocyanate injected into the mixer so as to obtain a completed-treated foaming material. Lastly, the completed-treated foaming material is poured into a mold and then water vapor is uniformly introduced into the mold so as to induce the completed-treated foaming material to proceed foaming reaction.Type: GrantFiled: February 7, 2008Date of Patent: May 17, 2011Inventor: Kun-Huang Chang
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Patent number: 7919541Abstract: The present invention concerns a method of manufacturing flame-retardant polyethylene or polypropylene foam using a derivative of carboxylic acid of phenylphosphinic acid and the flame-retardant polymer foam made thereby. More specifically, this invention concerns a method of manufacturing highly expanded flame-retardant polymer foam prepared by mixing the above mentioned phosphorous flame retardant in a polymer resin and expanding the mixture with a volatile blowing agent or by applying a solution of an organic phosphorous compound to an already-made highly expanded foam and then drying the highly-expanded polymer foam, and the flame-retardant foam prepared thereby.Type: GrantFiled: May 2, 2007Date of Patent: April 5, 2011Inventor: Chung Poo Park
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Publication number: 20110065818Abstract: The present invention relates to a porous resin bead containing a first aromatic monovinyl compound-divinyl compound-(meth)acrylonitrile-second aromatic monovinyl compound copolymer, in which the second aromatic monovinyl compound contains a group capable of binding with a carboxyl group by dehydration condensation reaction, and in which the porous resin bead has a dry volume of from 2 to 3 ml/g.Type: ApplicationFiled: September 16, 2010Publication date: March 17, 2011Applicant: NITTO DENKO CORPORATIONInventors: Kenjiro MORI, Tatsuya KONISHI, Eri MAETA
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Patent number: 7906560Abstract: The present invention provides a vulcanized foamed rubber molded product which has surface smoothness equal to or higher than that of a non-foamed vulcanized rubber molded product, has excellent mechanical strength properties, compression set resistance and abrasion resistance and a non-foamed vulcanized rubber molded product which is superior in surface smoothness to a conventional non-foamed vulcanized rubber molded product and has excellent compression set resistance, mechanical strength properties and abrasion resistance, as well as a method of producing the same. The molded product of the present invention is characterized in that the amount of sulfur atoms present in the surface thereof is at least 1.2 times as high as the amount of sulfur atoms present in a cut face obtained by cutting the surface to a depth of 1.0 mm in the vertical direction.Type: GrantFiled: August 10, 2007Date of Patent: March 15, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Hidenari Nakahama, Mikio Hosoya, Masaaki Kawasaki
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Patent number: 7892645Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: August 19, 2010Date of Patent: February 22, 2011Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H Piispanen, Michael T Williams
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Publication number: 20110002874Abstract: Biomimetic polymer networks comprising a heteropolymer network having a cavity, the cavity having a selective affinity for a moiety, methods for making biomimetic polymer networks, and methods for using biomimetic polymer networks.Type: ApplicationFiled: July 7, 2010Publication date: January 6, 2011Applicant: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEMInventors: Nicholas A. Peppas, James Z. Hilt, Mark E. Byrne
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Publication number: 20100304112Abstract: The present invention relates to a microporous material which is a non-network polymer having a chain comprised of repeating units bonded to each other and each including a first generally planar species and a rigid linker, the linker having a point of contortion such that two adjacent first planar species connected by a rigid linker are held in a non-coplanar orientation, the rigid linker further being such that the polymer chain has a rigid contorted structure, and the polymer being such that said repeating units comprised of the first generally planar species and the rigid linker are bonded predominately to two other such repeating units.Type: ApplicationFiled: February 19, 2010Publication date: December 2, 2010Applicant: THE UNIVERSITY OF MANCHESTERInventors: Neil B. McKeown, Peter M. Budd, Kadhum Msayib, Bader Ghanem
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Patent number: 7785711Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: April 29, 2010Date of Patent: August 31, 2010Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David A. Cowan, Dennis H. Piispanen, Michael T. Williams
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Publication number: 20100197817Abstract: A method for immobilizing dyes and antimicrobial agents on a polymeric cover or housing for a medical device is disclosed and described. The surface may be that of a catheter, a connector, a drug vial spike, a bag spike, a prosthetic device, an endoscope, a surface of an infusion pump, a key pad, a touch screen or a handle. The surfaces may also be one or more of those associated with a infusion of a medicament or dialysis treatment, such as peritoneal dialysis or hemodialysis, where it is important that the working surface for the dialysis fluid be sterile. These surfaces include connectors for peritoneal dialysis sets or for hemodialysis sets, bag spikes, dialysis catheters, and so forth. A method for determining whether a surface has been sterilized, and a dye useful in so indicating, is also disclosed.Type: ApplicationFiled: April 13, 2010Publication date: August 5, 2010Applicants: BAXTER INTERNATIONAL INC., BAXTER HEALTHCARE S.A.Inventors: Tuan Bui, Ton That Hai, Mark Nordhaus, Paul Sanders, Cong Jiang, David Lamb, Ozlem Yardimci
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Patent number: 7736740Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: July 3, 2006Date of Patent: June 15, 2010Assignee: NOVA Chemicals Inc.Inventors: Jainsheng Tang, David Allen Cowan, Dennis H. Piispanen, Michael T. Williams
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Publication number: 20100126341Abstract: The instant invention generally provides polymer pi-bond-philic filler composite comprising a molecularly self-assembling material and a pi-bond-philic filler, and a process of making and an article comprising the polymer pi-bond-philic filler composite. The instant invention also generally provides a process of separating a pi-bond-philic gas from a separable gas mixture comprising the pi-bond-philic gas.Type: ApplicationFiled: November 20, 2009Publication date: May 27, 2010Inventors: Scott T. Matteucci, Shawn D. Feist, Peter N. Nickias, Leonardo C. Lopez, Michael S. Paquette, Jeffrey C. Munro
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Patent number: 7696256Abstract: There is presented a new flame retardant composition comprising a brominated aromatic composition and a butyl substituted phenyl phosphate.Type: GrantFiled: October 16, 2009Date of Patent: April 13, 2010Assignee: Crompton CorporationInventors: Stephen B. Falloon, Richard S. Rose, Matthew D. Phillips
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Publication number: 20100056652Abstract: A process of forming an integral hydrophilic membrane from a porous hydrophobic membrane includes exposing a porous hydrophobic polymer membrane to a plasma, wherein the plasma contains reactive carbon dioxide species configured to covalently bond carboxylic functional groups to a surface of the polymer membrane and form the integral hydrophilic membrane.Type: ApplicationFiled: August 28, 2008Publication date: March 4, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Hieu Minh Duong, Ryan Austin Hutchinson, David Roger Moore
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Patent number: 7615168Abstract: There is presented a new flame retardant composition comprising a brominated aromatic composition and a butyl substituted phenyl phosphate.Type: GrantFiled: March 20, 2006Date of Patent: November 10, 2009Assignee: Chemtura CorporationInventors: Stephen B. Falloon, Richard S. Rose, Matthew D. Phillips
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Publication number: 20090215913Abstract: The present invention relates to highly porous polymeric materials comprising covalently grafted biologically active species. The invention also relates to a process for the preparation of highly porous materials comprising functional monomers capable of grafting to a biologically active molecular species comprising the steps of: (a) preparing an emulsion composition comprising a droplet phase and a continuous phase and containing monomers, (b) curing the emulsion and (c) optionally removing the water/droplet phase. The invention further relates to a process for grafting biologically active species to such a highly porous polymeric material comprising the steps of: (i) exposing the highly porous material to a solution of the biologically active species in a suitable solvent medium, (ii) optionally adding an activating agent, (iii) optionally heating, and (iv) rinsing the porous material with solvent medium to remove non-grafted species.Type: ApplicationFiled: April 21, 2006Publication date: August 27, 2009Inventors: Jens Christoph Thies, Sebastien Pierre, Neil Ronald Cameron
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Publication number: 20090191408Abstract: The present invention relates to absorbent compositions which exhibit swelling, deswelling, and reswelling behavior. More specifically, absorbent compositions of this invention swell and absorb fluids after exposure to aqueous fluids, deswell and release fluids from the swollen absorbent compositions, and may also reswell and absorb fluids. The swelling-deswelling-reswelling behavior allows enhanced liquid distribution in absorbent composites.Type: ApplicationFiled: January 30, 2008Publication date: July 30, 2009Inventors: Gonglu Tian, Scott J. Smith, Yaru Shi, Richard N. Dodge, Jian Qin
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Publication number: 20090081459Abstract: Disclosed is an expanded organic foam material having excellent thermal resistance and durability. The expanded plastic foam material is produced by preparing plastic beads or plastic foams, modifying silicate with at least one selected from among an alkaline earth metal compound, an alkaline earth metal compound-containing material, and an acid, coating the modified silicate on the prepared plastic beads or plastic foams, melt-molding the coated plastic beads or plastic foams while applying heat and pressure thereto, and drying the molded material. Also, the expanded organic plastic foam material has good impact-absorbing properties, easy formability, excellent sound-insulating and sound-absorbing performance and thermal insulating performance, good flame retardancy and thermal resistance, and improved water resistance and durability.Type: ApplicationFiled: February 8, 2007Publication date: March 26, 2009Inventors: Jong-Hyeon Yoon, Beom-Gyu Baek, Yoon-Sik Lee
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Publication number: 20090075539Abstract: Fire-retardant, heat-resistant, smoke-suppressant plastic materials, such as polyvinyl chloride, having incorporated therein an intumescent material are disclosed. The intumescent material comprise and intumescent catalyst selected from the group consisting of salts of phosphoric acid and salts of sulfuric acid; and a carbonific material selected from the group consisting of starches, sugars, sugar alcohols, oils, and plasticizers. The fire-retardant, heat-resistant, smoke-suppressant plastic materials may be in the form of a foamed or non-foamed plastic. Methods of making such plastic materials are also disclosed.Type: ApplicationFiled: September 27, 2005Publication date: March 19, 2009Applicant: TPR2 Vinyl CorporationInventors: Felix A. Dimanshteyn, Richard J. Barone
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Patent number: 7504439Abstract: Melamine foams exhibiting a very low level of water absorption and low residual formaldehyde are provided. The foams may be prepared by repeatedly soaking a melamine foam with an aqueous polysiloxane emulsion and squeezing out the emulsion, followed by a drying step and then a high-temperature annealing step.Type: GrantFiled: November 1, 2005Date of Patent: March 17, 2009Assignee: Polymer Technologies, Inc.Inventor: Jarred M. Prybutok
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Publication number: 20080281003Abstract: A process for preparing functionalised microporous polymers (which are also known as micro-cellular polymers or polyHIPE polymers (PHPs)) using intensified internal heating (for example by microwave irradiation).Type: ApplicationFiled: April 13, 2006Publication date: November 13, 2008Applicant: University of Newcastle Upon Tyne School Of Chemical Engineering and Advanced MaterialsInventors: Galip Akay, Zainura Zainon Noor, Omer Faruk Calkan, Teresa Manguangua Ndlovu, David Robert Burke
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Publication number: 20080214687Abstract: Methods of forming a hydrophilic porous polymeric membrane which include preparing a porous polymeric membrane from a polymer blend which typically contains a hydrophobic non crosslinkable component (e.g. PVdF) and a component which is cross-linkable (for instance, PVP) and treating said porous polymeric membrane under cross linking conditions to produce a modified membrane with greatly improved water permeability and hydrophilic stability. Cross linking condition include chemical (e.g. peroxodisulfate species), thermal or radiation and/or combinations thereof. Non cross linked material may be washed out if desired.Type: ApplicationFiled: June 20, 2006Publication date: September 4, 2008Inventors: Heinz-Joachim Muller, Dongliang Wang, Ashvin Kumar
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Patent number: 7378453Abstract: A surface crosslinking treatment method of a water-absorbing resin powder is disclosed that can overcome various problems in production encountered in the production of surface crosslinked water-absorbing resin powders on an industrial scale and can produce a water-absorbing resin powder having excellent physical properties without causing deterioration in physical properties of resin.Type: GrantFiled: March 12, 2004Date of Patent: May 27, 2008Assignee: Nippon Shokubai Co., Ltd.Inventors: Kozo Nogi, Shigeru Sakamoto, Noriaki Mizutani, Yorimichi Dairoku, Kunihiko Ishizaki
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Patent number: 7294654Abstract: A heterogenous hybrid thermally regenerable salt sorbent resin is formed from a hybrid precursor resin. The hybrid precursor resin is formed by intimately mixing a dry, solid crosslinked macroporous copolymer with a solution containing a polyunsaturated monomer, a monoethylenically unsaturated monomer containing a haloalkyl group and a polymerization initiator, followed by heating to cause polymerization. The hybrid precursor resin is then treated with a weak base, then subjected to hydrolysis conditions to form, respectively, weak base groups and weak acid groups to produce the hybrid thermally regenerable salt sorbent resin.Type: GrantFiled: March 29, 2005Date of Patent: November 13, 2007Assignee: Novation Environmental Technologies, Inc.Inventors: Roger E. Johnson, Gerald Colombo
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Patent number: 7294655Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: January 31, 2004Date of Patent: November 13, 2007Assignee: Nova Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H. Piispanen, Michael T. Williams
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Patent number: 7291653Abstract: Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems.Type: GrantFiled: August 26, 2004Date of Patent: November 6, 2007Assignee: The Regents of the University of CaliforniaInventors: Theodore F. Baumann, Joe H. Satcher, Jr., Alexander E. Gash
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Patent number: 7232210Abstract: A foam used in a print cartridge and a method of forming the same. The foam includes 0.1-5.0 wt % of silver nanoparticles, based on the total weight of the foam. The print cartridge has a deodorizing, antibacterial, and disinfectant function.Type: GrantFiled: October 18, 2004Date of Patent: June 19, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Seo-hyun Cho, Hyung-hyu Hwang
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Patent number: 7214724Abstract: A plastic is converted from an initial condition with a higher density into a foamed condition with a lower density using a blowing agent, wherein the plastic is cross-linked prior to foaming by means of a first cross-linking agent and during the foaming by means of at least one second cross-linking agent.Type: GrantFiled: June 15, 2004Date of Patent: May 8, 2007Assignee: Henkel Kommanditgesellschaft Auf AktienInventor: Marcel Salamon
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Patent number: 7148264Abstract: The present invention relates to a method of producing one or more macroporous cross-linked polymer particles, which comprises polymerization and cross-linking of divinyl ether monomers in an inert solvent, in which method the polymerization is free radical initiated. The invention also relates to particles so produced, which are useful as separation medium e.g. in RPC or, after suitable derivatization, in other chromatographic methods.Type: GrantFiled: August 9, 2004Date of Patent: December 12, 2006Assignee: GE Healthcare Bio-Sciences ABInventors: Tobias Söderman, Anders Larsson, Philippe Busson
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Patent number: 7030167Abstract: Methods for producing nanoporous structures are provided. In the subject methods, two or more, e.g., first and second, different types of self-assembling molecules are combined with each other under conditions sufficient to produce a composite ordered structure from the two or types of molecules. A feature of two or more molecules that are combined in this first step is that a portion of the molecules include cross-linking functionalities not found in the other portion of the molecules. The resultant self-assembled composite structure is then subjected to conditions sufficient for cross-linking of the portion of the molecules that includes the cross-linking functionalities to produce a stabilized composite structure. Finally, the remaining non-cross-linked molecules of the stabilized composite structure are separated from the stabilized composite structure to produce a nanoporous structure.Type: GrantFiled: June 25, 2003Date of Patent: April 18, 2006Assignee: Agilent Technologies, Inc.Inventor: Janelle Gunther
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Patent number: 6946496Abstract: An artificial soil includes a plurality of foam plastic fragments. A gel coating is disposed about substantially each of the fragments. Minerals are disposed within the gel coating.Type: GrantFiled: September 23, 2003Date of Patent: September 20, 2005Inventor: Paul S. Mankiewicz
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Patent number: 6900282Abstract: A process for preparing the polyurethane derivative, the process including: providing a polyurethane having a urethane amino moiety, providing a multifunctional linker reagent of a formula: LG-RL-(FG)n, wherein n is an integer from 1 to 3, FG is a functional group, which is a halogen, a carboxyl group, a sulfonate ester, or an epoxy group, LG is a leaving group, which is a halogen, a carboxyl group, a sulfonate ester, or an epoxy group, and RL is an (n+1)-valent organic radical having at least one carbon atom; providing a protected thiol-containing reagent of a formula R—C(O)SH, or a salt thereof, wherein R is a C1 to C6 alkyl group; reacting the multifunctional linker reagent with the urethane amino moiety to form a polyurethane substituted with at least one substituent group of a formula: —RL-(FG)n; reacting the polyurethane with a protected thiol-containing reagent to form the polyurethane derivative.Type: GrantFiled: September 26, 2003Date of Patent: May 31, 2005Assignee: The Children's Hospital of PhiladelphiaInventors: Ivan Alferiev, Ilia Fishbein, Robert J. Levy
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Patent number: 6881761Abstract: Disclosed are (1) a porous polymer particle comprising a polymer substrate having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, (2) an alkali-resistant, high-strength porous polymer particle having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, a part of the ester bonds being saponified and converted to a hydroxyl group(s), (3) a porous polymer particle comprising a polymer substrate having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, the porous polymer particles being treated with an alkaline solution to generate a hydroxyl and/or a carboxyl group on a surface of the substrate, (4) an anion exchanger comprising any one of the particles (1) to (3) above, (5) a packing material for anion chromatography comprising the anion exchanger (4) above, (6) a column for anion chromatography using the anion exchanger (4) above, and (7) a method for measType: GrantFiled: March 7, 2001Date of Patent: April 19, 2005Assignee: Showa Denko K.K.Inventors: Takashi Kotsuka, Kuniaki Shimbo, Hiroshi Suzuki, Hisako Sakuma, Toshio Tokuda
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Patent number: 6811980Abstract: The present invention relates to a process for immobilization of nucleic acid molecules on a substrate, wherein the substrate is treated with atomic oxygen plasma prior to immobilizing the nucleic acid molecules thereon. The invention is further related to immobilized nucleic acid molecules and uses thereof.Type: GrantFiled: November 19, 2001Date of Patent: November 2, 2004Assignee: Sony International (Europe) GmbHInventors: William E. Ford, Jurina Wessels, Oliver Harnack
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Publication number: 20040198851Abstract: The invention relates to polyurethane foams comprisingType: ApplicationFiled: April 26, 2004Publication date: October 7, 2004Applicant: BASF AktiengesellschaftInventors: Armin Becker, Bernd Bruchmann, Andreas Arlt, Ulrich Treuling, Rainer Rahm, Juergen Decker, Ulrich Steuerle, Martin Kreyenschmidt, Willi Riegel, Werner Bertleff
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Patent number: 6713520Abstract: A foam profile prepared by a process comprising the steps of foaming a thermoplastic vulcanizate, where the thermoplastic vulcanizate is prepared by a process comprising the step of dynamically vulcanizing a rubber within a mixture that includes from about 15 to about 95 percent by weight of the rubber and from about 5 to about 85 percent by weight of a thermoplastic component based upon the total weight the rubber and thermoplastic component combined, where the thermoplastic component includes from about 65 to about 90 percent by weight of a conventional thermoplastic resin and from about 10 to about 35 percent by weight of a random propylene copolymer based upon the total weight of the thermoplastic component.Type: GrantFiled: June 19, 2002Date of Patent: March 30, 2004Assignee: Advanced Elastomer Systems, L.P.Inventors: Abdelhadi Sahnoune, Terry M. Finerman
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Patent number: 6710130Abstract: A propylene polymer composition of high melt tension, which is especially favorable for foam moldings of uniform thickness, and foam moldings thereof having a uniform thickness, are obtained by melt-kneading a polymer mixture of a specific ethylene polymer (A) and a specific olefin multi-stage polymer (B) to satisfy the following formula: Log(MS)>0.91−0.Type: GrantFiled: March 29, 2002Date of Patent: March 23, 2004Assignees: Chisso Corporation, Chisso Petrochemical CorporationInventors: Akira Yamauchi, Yoshitaka Kobayashi, Tadamitu Hamasaki, Shunji Kawazoe, Jun Shinozaki, Hiroyuki Maehara
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Patent number: 6692857Abstract: Process for the production of a composite membrane comprising a porous film of a first polymer, the pores of which contain a second polymer, by depositing the second polymer from a solution in the pores of the first polymer, characterized in that the film of the first polymer is contacted with the surface of a first electrode which, together with at least one counterelectrode, is present in the solution of the second polymer and with such a potential difference being applied across the first electrode and the counterelectrode that the second polymer moves towards the first electrode, in which process it must pass the film.Type: GrantFiled: October 18, 2001Date of Patent: February 17, 2004Assignee: DSM N.V.Inventor: Edwin H. A. Steenbakkers
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Patent number: 6689861Abstract: The invention relates to methods of making polyurethane derivatives which can be readily further derivatized using stabilizing agents such as anti-calcification agents, anti-thrombogenesis agents, and chemical and mechanical degradation-inhibiting agents. The invention also includes methods of making polyurethane derivatives so further derivatized and to polyurethanes derivatives made using such methods.Type: GrantFiled: November 2, 2001Date of Patent: February 10, 2004Assignee: The Children's Hospital of PhiladelphiInventors: Robert J. Levy, Ivan Alferiev
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Patent number: 6670405Abstract: The invention relates to a method for producing block-shaped and plate-shaped polymethacrylimide foamed materials by copolymerizing methylacrylic acid and methylacryl nitrile, by subjecting the copolymerizate to a post-polymerization and cyclization in order to form polyimide, and by converting the same into a foamed material. The invention is characterized in that the copolymerization is carried out in the presence of a mixture containing at least three initiators with graduated half-life periods. The polymerization can be controlled especially well and yields polymerizate plates with thicknesses of up to 80 mm which can be easily foamed. The invention makes it possible to produce filling materials, especially plates and blocks containing electrically conductive particles.Type: GrantFiled: October 16, 2001Date of Patent: December 30, 2003Assignee: Roehm GmbH & CO KGInventors: Sabine Servaty, Werner Geyer, Norbert Rau, Manfred Krieg
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Patent number: 6642282Abstract: Provided is a porous para-oriented aromatic polyamide film which contains fine particles composed of a heat-resistant resin in an amount of 10 to 400 parts by weight based on 100 parts by weight of a pare-oriented aromatic polyamide and has a linear thermal expansion coefficient at 200 to 300° C. of from −50×10−6/° C. to +50×10−6/° C. The porous para-oriented aromatic polyamide film shows excellent tear propagation resistance and has light weight and low linear thermal expansion coefficient, and is suitable as a prepreg material used for a base substrate for printed circuit board.Type: GrantFiled: March 25, 2002Date of Patent: November 4, 2003Assignee: Sumitomo Chemical Company, LimitedInventors: Yasuo Shinohara, Tsutomu Takahashi
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Publication number: 20030153638Abstract: The present invention relates to crosslinking of porous materials made of biodegradable polymers. The method comprises: (a) placing a porous biodegradable polymer in a chamber; (b) introducing a supercritical fluid containing a crosslinking agent into the chamber to effect crosslinking of the porous biodegradable polymer; and optionally (c) introducing a pure supercritical into the chamber to wash the crosslinked polymer until the crosslinking agent is substantially removed from the polymer.Type: ApplicationFiled: November 1, 2001Publication date: August 14, 2003Applicant: Industrial Technology Research InstituteInventors: Huey-Min Lai, Kuang-Rong Lee, Chin-Chin Tsai, Hsi-Hsin Shih, Yuan-Chia Chang
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Patent number: 6569911Abstract: A method of manufacturing a support media from a cross-linked polymerisate based on vinyl compounds, and exhibiting residual vinyl groups. The characteristic feature of the method is that the polymerisate is subjected to a heating step that preferably is carried out under reduced access of oxygen. The use of the support media is also described.Type: GrantFiled: March 5, 2001Date of Patent: May 27, 2003Assignee: Amersham Biosciences ABInventors: Torunn Arntsen, Jan Roger Karlson, Geir Fonnum, Steinar Hagen
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Process for preparing post-crosslinked polymer bead whose surface area and pore volume are increased
Patent number: 6541527Abstract: The present invention relates to a process for preparing post-crosslinked polymer bead with increased surface area and pore volume, and suitable pore size, allowing the separation of organic compounds by post-crosslinking gel-type copolymer bead whose crosslinking degree is low and initial surface area is small, or macroporous-type copolymer bead whose crosslinking degree is high and initial surface area is intermediate in the presence of a Friedel-Crafts catalyst, and polymer beads produced thereby. Though the surface area and pore volume of polymer beads may be varied depending on physical properties of copolymer beads and Friedel-Crafts reaction conditions, the present invention provides polymer beads with larger surface area than that of commercially available polymeric adsorbents produced by the conventional method employing a porogen only.Type: GrantFiled: January 18, 2000Date of Patent: April 1, 2003Assignee: Korea Advanced Institute of Science and TechnologyInventors: Son Ki Ihm, Chang Gun Oh, Jou Hyeon Ahn, Jin Eun Jang -
Patent number: 6495209Abstract: The present invention relates to methods of fabricating composite membranes wherein at least one of the components is initially provided in the form of a precursor. The composite material comprising the precursor is processed to transform the precursor and obtain a membrane having a desired property. Including a thermoplastic precursor to a desired component, which itself is less thermoplastic, permits separate pieces of the membrane to be joined by welding or other thermal processes relying on the meltability of the components to achieve a bond. The invention also encompasses fabricating a reinforced ion conducting membrane by melting and mixing a non ion-conducting precursor to an ion-conducting polymer with an essentially inert polymer. The composite material is then processed to transform the non ion-conducting polymer into the ion-conducting form.Type: GrantFiled: February 20, 1998Date of Patent: December 17, 2002Assignee: Lynntech, Inc.Inventor: Alan J. Cisar
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Patent number: 6492431Abstract: The present invention relates to methods of fabricating composite membranes wherein at least one of the components is initially provided in the form of a precursor. The composite material comprising the precursor is processed to transform the precursor and obtain a membrane having a desired property. Including a thermoplastic precursor to a desired component, which itself is less thermoplastic, permits separate pieces of the membrane to be joined by welding or other thermal processes relying on the meltability of the components to achieve a bond. The invention also encompasses fabricating a reinforced ion conducting membrane by melting and mixing a non ion-conducting precursor to an ion-conducting polymer with an essentially inert polymer. The composite material is then processed to transform the non ion-conducting polymer into the ion-conducting form.Type: GrantFiled: October 5, 2000Date of Patent: December 10, 2002Assignee: Lynntech, Inc.Inventor: Alan J. Cisar
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Publication number: 20020168509Abstract: Polymeric materials having a plurality of cells formed therein are described. The polymeric materials include a foamed layer comprising a plurality of uniform microcells, nanocells or combinations thereof in a closed cell network, a transition layer positioned adjacent to the foamed layer, and at least one unfoamed outer layer positioned adjacent to the transition layer. The foamed layer may be present in a volume ranging from about 80 to about 99 percent based on the volume of the polymeric material, the transition layer may present in a volume ranging from about 0 to about 10 percent based on the volume of the polymeric material, and the at least one outer layer may be present in a volume ranging from about 0.01 to about 10 percent based on the volume of the polymeric material. Methods of making such polymeric materials are also described, as are apparatus for providing foamed polymeric materials.Type: ApplicationFiled: March 27, 2002Publication date: November 14, 2002Inventors: Joseph M. DeSimone, Srinivas Siripurapu, Saad A. Khan, Richard J. Spontak, Joseph Royer
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Publication number: 20020147246Abstract: There is obtained a chlorinated vinyl chloride resin composition from which a siding molded article having good appearance and excellent heat resistance, impact resistance and weatherability is obtained. A chlorinated vinyl chloride resin composition for siding extrusion molding is obtained and a siding molded article is prepared therefrom, said chlorinated vinyl chloride resin composition comprising 100 parts by weight of a chlorinated vinyl chloride resin and 3 to 20 parts by weight of an acrylic graft rubber copolymer, wherein the acrylic graft rubber copolymer has a glass transition temperature of at most 0° C. and contains 30 to 90% by weight of acrylic hollow rubber particles whose average void ratio is 3 to 90% by volume in a latex state.Type: ApplicationFiled: December 28, 2001Publication date: October 10, 2002Inventors: Atsushi Takai, Toshio Okuhara, Kazumasa Yamane
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Patent number: 6462100Abstract: The invention discloses methods for making foams comprising functionalized metal oxide nanoparticles by photopolymerizing or thermally polymerizing emulsions comprising a reactive phase and a phase immiscible with the reactive phase components. Foams made from water-in-oil emulsions, including high internal phase emulsion are also disclosed. Articles and uses for the foams are also described.Type: GrantFiled: July 23, 2001Date of Patent: October 8, 2002Assignee: 3M Innovative Properties CompanyInventors: Kristin LaVelle Thunhorst, Douglas Alan Hanggi
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Publication number: 20020115734Abstract: The present invention is directed, in general, to an improved material and method of planarizing a surface on a semiconductor wafer and, more specifically, to a method of altering the properties of polymers, preferably thermoplastic foam polymers, used in polishing applications. The chemical and mechanical properties thermoplastic foam substrates can be transformed by inorganic, inorganic-organic, and or organic-organic grafting techniques, such that the polymer foam is endowed with new set of properties that more desirable and suitable for polishing.Type: ApplicationFiled: November 27, 2001Publication date: August 22, 2002Inventors: Yaw S. Obeng, Edward M. Yokley