Including Step Of Surface Coating A Particle Or Process Of Expanding A Surface Coated Particle Patents (Class 521/57)
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Patent number: 11795286Abstract: The present invention relates to an in-mold expanded beads molded article of expanded beads of an olefin thermoplastic elastomer, a cushion for shoe sole, and a method of producing expanded beads provided with through-holes and composed of a block copolymer of a polyethylene block and an ethylene/?-olefin copolymer block, and with respect to the in-mold expanded beads molded article of expanded beads of an olefin thermoplastic elastomer, a voidage of the expanded beads molded article is 5 to 40%; a density of the expanded beads molded article is 30 to 150 g/L; and a flexural modulus of the olefin thermoplastic elastomer that constitutes the expanded beads molded article is 10 to 100 MPa.Type: GrantFiled: November 13, 2017Date of Patent: October 24, 2023Assignee: JSP CorporationInventors: Shota Takagi, Masaharu Oikawa
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Patent number: 11312834Abstract: A styrene resin extruded foam includes graphite and a styrene resin. The graphite is in an amount of 0.5 to 10.0 parts by weight relative to 100 parts by weight of the styrene resin. The graphite has an average particle diameter of 2.5 ?m to 9 ?m. A laser scattering intensity is not less than 5 {%/(mg/mL)}/wt % per unit solution concentration of the graphite as measured by a particular method.Type: GrantFiled: September 9, 2019Date of Patent: April 26, 2022Assignee: KANEKA CORPORATIONInventors: Takenori Kikuchi, Daishi Takahashi, Shunji Kurihara
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Patent number: 11094939Abstract: The present invention provides a sulfur-based active material prepared using an inexpensive polymer material as a starting material and a method of preparing the sulfur-based active material. A non-aqueous electrolyte secondary battery such as a lithium-ion secondary battery provided with an electrode comprising the sulfur-based active material has a large charging and discharging capacity and an excellent cyclability.Type: GrantFiled: March 20, 2020Date of Patent: August 17, 2021Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Tatsuya Kubo, Fumiya Chujo
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Patent number: 11074900Abstract: The present invention is a thermal and acoustic insulating sphere that has an evacuated hollow interior. The spheres are constructed of insulating materials, and the inner and outer surfaces of each sphere have highly reflective coatings evenly applied to them. The coatings applied to the inner and outer surfaces reduce the transmission of heat by conduction, convection, and radiation. Additionally, the spheres provide superior acoustic insulation due to the inability of sound to travel through the interior vacuum. The spheres can be used to produce insulating materials, for example, by embedding or positioning them within or between other materials, to provide thermal and acoustic insulation.Type: GrantFiled: July 1, 2018Date of Patent: July 27, 2021Inventor: Afzal Muhammad Chaudhry
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Patent number: 10442114Abstract: Disclosed herein is a resin pellet and a process to make said resin pellet. The resin pellet comprises a major polyester comprising a catalytic titanium compound, and a minor polyester comprising a phosphorus compound. The major polyester is present in a first compartmentalized zone of the resin pellet and the minor polyester is present in a second compartmentalized zone of the resin pellet.Type: GrantFiled: June 3, 2016Date of Patent: October 15, 2019Assignee: APG Polytech, LLCInventor: Gianluca Ferrari
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Patent number: 10370547Abstract: A powdery opacifying additive, comprising a polymer of one or more monomers from the group comprising vinyl esters, (meth)acrylic esters, vinylaromatics, olefins, 1,3 dienes and vinyl halides and, if appropriate, further monomers which are copolymerizable therewith, in the form of agglomerated polymer particles with included air-voids, having a volume mean particle size dv of 20 to 80 ?m.Type: GrantFiled: March 30, 2015Date of Patent: August 6, 2019Assignee: Wacker Chemical CorporationInventor: Richard Henry Bott
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Patent number: 10184036Abstract: Carbon black-containing composite resin pre-expanded particles comprising 100 to 400 parts by mass of a polystyrene-based resin with respect to 100 parts by mass of a carbon black-containing polyolefin-based resin; having a carbon black content of 0.5 to 5.0% by mass and a bulk density of 0.015 to 0.25 g/cm3; and having an outermost layer of 30 to 80 pm after undergoing the following tests: (a) one of the carbon black-containing composite resin pre-expanded particles is sliced into a 1-mm slice in such a way that cross-section surfaces of cells are exposed on both surfaces of the slice; (b) the obtained slice is immersed in toluene at 25° C. for 24 hours to extract a polystyrene-based resin component as described above; (c) the cross-section surface of the slice is then subjected to magnified photographing by a microscope; (d) the obtained microscope image is observed.Type: GrantFiled: September 11, 2014Date of Patent: January 22, 2019Assignee: SEKISUI PLASTICS CO., LTD.Inventors: Akira Isayama, Masahiko Ozawa
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Patent number: 10030080Abstract: There is provided a method for preparing a fine particle having an enclosed void using a core polymer containing carboxylic acid, primary middle shell monomers, and secondary hard shell monomers. The method may be a multi-staged emulsion polymerization method. The primary middle shell monomers may include a multi-functionality monomer that is a cross-linking monomer having two or more double bonds.Type: GrantFiled: April 4, 2016Date of Patent: July 24, 2018Inventors: Moonsoo Kim, Namwoo Kim, Sihyung Kim
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Patent number: 9777144Abstract: A method of production of an aqueous dispersion of hollow polymer particles including forming, on the outer layers of core polymer particle (A) on which inside shell layer (B) and intermediate shell layer (C) are formed, outside shell layer (D) obtained by using a monomer mixture (d) with a ratio of content of an acidic group-containing monomer controlled to 0.15 wt % or less and adding a base to an aqueous dispersion of the obtained polymer particle to make the pH of the aqueous dispersion 7 or more is provided.Type: GrantFiled: March 13, 2014Date of Patent: October 3, 2017Assignee: ZEON CORPORATIONInventor: Atsushi Yamaguchi
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Patent number: 9493625Abstract: The present invention provides a thermally expandable microcapsule that has a high expansion ratio and durability at high temperatures, and is not likely to cause discoloration and odor when used for foam molding. The thermally expandable microcapsule of the present invention includes: a shell formed from a polymer; and a volatile expansion agent as a core agent encapsulated by the shell, the shell obtained by polymerizing a monomer composition that contains a nitrile monomer and a compound having a glycidyl group in a molecule, the shell exhibiting a value y of 50% or higher and a ratio y/x of 1.1 or higher, in which x represents a gel fraction at ordinary temperature, and y represents a gel fraction upon heating at 180° C. for 30 minutes.Type: GrantFiled: September 22, 2014Date of Patent: November 15, 2016Assignees: SEKISUI CHEMICAL CO., LTD., TOKUYAMA SEKISUI CO., LTD.Inventors: Hiroshi Yamauchi, Hiroyuki Morita, Satoshi Haneda, Yasuko Wada
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Patent number: 9212270Abstract: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.Type: GrantFiled: January 6, 2011Date of Patent: December 15, 2015Assignee: BASF SEInventors: Andreas Füβl, Bangaru Sampath, Maximilian Hofmann, Ingo Bellin, Sameer Nalawade, Klaus Hahn, Andreas Künkel, Robert Loos
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Patent number: 8889749Abstract: Provided is a method for preparing hydrophobic monolithic silica aerogel, comprising dipping monolithic wet silica gel obtained by using an alkoxide precursor into an alkylsilane solution as a dipping solution to perform hydrophobitization of the surface and inner part of the monolithic wet silica gel by a dipping process. The method is economical by virtue of the use of a small amount of alkylsilane compound and imparts hydrophobic property to monolithic silica aerogel simply in a cost efficient and time efficient manner. In addition, the method reduces shrinkage of hydrophobic monolithic silica aerogel, enables production of hydrophobic monolithic silica aerogel in a translucent form, and allows the hydrophobic monolithic silica aerogel to maintain low heat conductivity similar to the heat conductivity of hydrophilic silica aerogel. The hydrophobic monolithic silica aerogel may be used directly as a heat insulating panel by virtue of excellent hydrophobic property and heat insulating property.Type: GrantFiled: November 23, 2012Date of Patent: November 18, 2014Assignee: Korea Institute of Science and TechnologyInventors: Dong Jin Suh, Gi Seok Yang, Jae Wook Choi, Young Hyun Yoon, Yun Su Lee, Jeong Myeong Ha
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Publication number: 20140288199Abstract: A thermally expandable microcapsule, which shows excellent heat resistance and a high expansion ratio and thereby can be suitably used for molding processes involving high shearing force, such as kneading molding, calender molding, extrusion molding, and injection molding. The thermally expandable microcapsule also provides a foamed product using the thermally expandable microcapsule. The thermally expandable microcapsule contains a shell made of a polymer; and a volatile expansion agent as a core agent encapsulated in the shell, the storage elastic modulus (E?) of the shell at a temperature of 200° C. and a frequency of 10 Hz being 1×105 N/m2 or more, the storage elastic modulus (E?) of the shell at a temperature of 250° C. and a frequency of 10 Hz being 1×105 N/m2 or more, and a maximum displacement amount measured by thermomechanical analysis being 300 ?m or more.Type: ApplicationFiled: June 4, 2014Publication date: September 25, 2014Applicant: Sekisui Chemical Co., Ltd.Inventors: Yasuhiro KAWAGUCHI, Yoshiyuki KOSAKA
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Patent number: 8796344Abstract: A process for producing pre-expanded particles, comprising the steps of: impregnating 100 parts by weight of polystyrene type resin particles with a volatile blowing agent in the presence of 0.1 to 2.0 parts by weight of a first antistatic agent to obtain expandable resin particles; and bringing 100 parts by weight of the expandable resin particles into contact with 0.1 to 2.0 parts by weight of a second antistatic agent in the presence of an antifoaming agent, and then pre-expanding the particles, thereby obtaining pre-expanded particles, wherein the second antistatic agent and the antifoaming agent are used in a ratio by weight of 1:0.04 to 1.50.Type: GrantFiled: December 25, 2009Date of Patent: August 5, 2014Assignee: Sekisui Plastics Co., Ltd.Inventors: Yuichi Gondo, Hideyasu Matsumura
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Patent number: 8486531Abstract: The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.Type: GrantFiled: January 23, 2012Date of Patent: July 16, 2013Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Ichiro Takahara, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Publication number: 20130146241Abstract: Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk.Type: ApplicationFiled: February 7, 2013Publication date: June 13, 2013Applicant: INTERNATIONAL PAPER COMPANYInventor: INTERNATIONAL PAPER COMPANY
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Publication number: 20130065975Abstract: The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.Type: ApplicationFiled: March 14, 2011Publication date: March 14, 2013Inventors: Hiroshi Natsui, Hiroshi Yamauchi, Hiroyuki Morita
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Publication number: 20120301648Abstract: There is disclosed unexpanded or pre-expanded polystyrene beads electrostatically coated with a media capable of supporting the growth of bacteria which assist in the decomposition of the polystyrene. There is also disclosed methods of making the beads, a method of making an expanded polystyrene foam and an expanded polystyrene foam prepared by the method.Type: ApplicationFiled: November 18, 2010Publication date: November 29, 2012Applicant: SAFEPS PTY LTD.Inventor: Michel Serge Maxime Lefebvre
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Patent number: 8298447Abstract: A conductive paste, a printed circuit board using the conductive paste, and a method of manufacturing the printed circuit board are disclosed. A conductive paste that includes conductive particles, a polymer, and a polymer foam, can reduce the number of printing repetitions, to simplify the manufacturing process, decrease process times, and improve reliability.Type: GrantFiled: March 13, 2008Date of Patent: October 30, 2012Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Ki-Hwan Kim, Jee-Soo Mok, Myung-Sam Kang
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Publication number: 20120245240Abstract: The disclosure relates to processes for preparing an emulsion containing core-sheath-shell polymer particles which, when dried, contain a microvoid which causes opacity in compositions in which they are contained. The particles can serve as binding or opacifying agents in paints, coating, impregnating, and molding compositions primarily, also extended to paper coatings and to some extent in leather, textiles and water based construction materials.Type: ApplicationFiled: January 20, 2012Publication date: September 27, 2012Applicant: ORGANIK KIMYA SANAYI VE TIC. A.S.Inventors: Guillermo PEREZ, Sibel ALTINOK
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Patent number: 8268901Abstract: The present invention relates to a particulate expandable polylactic acid which functions as a starting material for producing foamed moulded products. The present particulate expandable polylactic acid is provided with a coating so as to improve the fusion properties. The present invention also relates to a method for producing a particulate expandable polylactic acid as well as to a method for producing a foamed moulded product and to the moulded product obtained thereby.Type: GrantFiled: April 21, 2008Date of Patent: September 18, 2012Assignee: Synbra Technology B.V.Inventors: Robin Nicholas Britton, Franciscus Adrianus Hendrikus Cornelis Van Doormalen, Jan Noordegraaf, Karin Molenveld, Geraldus Gerardus Johannes Schennink
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Patent number: 8247640Abstract: The present invention concerns highly swellable absorption mediums with a reduced caking tendency at high humidity and/or high temperatures, wherein a swellable polymer is coated with a non-ionic, nitrogen-containing surfactant and optionally a Lewis acid and then reacted by heating.Type: GrantFiled: March 5, 2010Date of Patent: August 21, 2012Assignee: Evonik Stockhausen GmbHInventors: Gerd Jonas, Richard Mertens, Markus Frank
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Patent number: 8247465Abstract: Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.Type: GrantFiled: October 9, 2008Date of Patent: August 21, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Takeshi Inohara, Yoshiaki Shirakabe, Ikuo Yosejima, Kenichi Kitano, Toshiaki Masuda
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Publication number: 20120136078Abstract: Embodiments of the present disclosure include organic polymeric particles, paper coating compositions, coated paper, and methods of forming coated paper with the paper coating compositions. The embodiments of the organic polymeric particle include an organic hydrophilic polymer with a unit for hydrogen bonding, and a hollow porous structure that comprises an organic polymer that at least partially surrounds the organic hydrophilic polymer, where the hollow porous structure has a pore surface area greater than 1 percent of a total theoretical exterior surface area of the hollow porous structure and the organic hydrophilic polymer and the hollow porous structure give the organic polymeric particle a void volume fraction of 40 percent to 85 percent.Type: ApplicationFiled: April 1, 2010Publication date: May 31, 2012Inventors: David J. Brennan, John P. Kelly, Brian J. Ninness, James G. Galloway, Alan B. Chaput, JR., John A. Roper, III, John D. Oates
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Patent number: 8129438Abstract: Foamed polyolefin resin beads having antistatic properties obtained by a process, which includes dispersing polyolefin resin beads into an aqueous medium, injecting a blowing agent, stirring and allowing the polyolefin resin beads to foam and expand. The polyolefin resin beads are composite resin beads comprising a core layer of a core layer polyolefin resin and a covering layer of a covering layer polyolefin resin.Type: GrantFiled: March 2, 2011Date of Patent: March 6, 2012Assignee: JSP CorporationInventors: Tokunobu Nohara, Mitsuru Shinohara, Masaharu Oikawa
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Patent number: 8114476Abstract: Process for improving the insulating capacity of expanded vinyl aromatic which includes: 1) preparing beads of expandable vinyl aromatic polymers containing 1-10% by weight, calculated with respect to the polymer, of an expanding agent englobed in the polymeric matrix, and 0.01-25% by weight, calculated with respect to the polymer, of an athermanous additive comprising carbon black homogeneously distributed in the polymeric matrix; 2) treating the surface of the beads, before deposition of the coating, with a liquid lubricating agent; and 3) thermally treating the beads with hot air at a temperature ranging from 30 to 60° C.Type: GrantFiled: October 1, 2010Date of Patent: February 14, 2012Assignee: Polimeri Europa S.p.A.Inventors: Dario Ghidoni, Antonio Ponticiello, Alessandra Simonelli, Loris Zamperlin
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Publication number: 20120003478Abstract: A method of reducing a volatile organic compound of composite resin particles comprising the step of: blowing a gas from a bottom part of a container in order to fluidize composite resin particles containing a polyolefin-based resin and a polystyrene-based resin in the container until an amount of volatile organic compounds contained in the whole composite resin particles becomes 50 ppm or less, wherein the gas has a temperature of (T?40) to (T?10)° C. when a softening temperature of the composite resin particles is defined as T° C.Type: ApplicationFiled: March 24, 2010Publication date: January 5, 2012Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Hideyasu Matsumura, Shinji Ishida
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Patent number: 8088835Abstract: It is an object of the present invention to provide a method for easily and economically producing an expansion-molded polypropylene-based resin article stably with a high porosity, that has continuous voids and that can be used as materials such as a sound absorbing material and a draining material. More specifically, the present invention relates to a method for producing an expansion-molded polypropylene-based resin article, in which a mold is filled with expanded polypropylene-based resin particles, and the expanded particles are heated and fused using water vapor, and then cooled, wherein expanded polypropylene-based resin particles are used in which a polypropylene-based resin having a melt index (MI) of not less than 0.1 g/10 minutes and not more than 9 g/10 minutes is used as a base resin, a cell size is not more than 150 ?m, two melting peaks are present on a DSC curve obtained by differential scanning calorimetry, and ?/(?+?) is not less than 0.35 and not more than 0.Type: GrantFiled: July 27, 2005Date of Patent: January 3, 2012Assignee: Kaneka CorporationInventors: Tomonori Iwamoto, Takayuki Gouda
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Patent number: 8084509Abstract: The present invention provides a pre-expanded particulate polyolefin-based resin capable of easily attaining satisfactory secondary expandability, satisfactory surface appearance, and satisfactory dimensional stability even when it is intended to obtain an in-mold expansion molded article having a thin-wall shape. The present invention provides a pre-expanded particulate polypropylene-based resin including a polypropylene-based resin X as a base resin, where the resin X includes a resin mixture of at least a polypropylene-based resin A having a melting point of 140° C. or lower and a polypropylene-based resin B having a melting point of 145° C. or higher, and the resin mixture is modified by an organic peroxide so as to have a melt index of 5 g/10 min or more and less than 20 g/10 min.Type: GrantFiled: November 18, 2005Date of Patent: December 27, 2011Assignee: Kaneka CorporationInventors: Tetsuya Shibata, Tomonori Iwamoto
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Patent number: 8058320Abstract: A thermally foamable microsphere having a structure that a foaming agent is encapsulated in an outer shell formed from a polymer, wherein the foaming agent contains isododecane, and a production process of the thermally foamable microsphere by a suspension polymerization process using a polymerizable monomer and a foaming agent containing dodecane.Type: GrantFiled: September 13, 2005Date of Patent: November 15, 2011Assignee: Kureha CorporationInventors: Tetsuo Ejiri, Mitsuhiro Matsuzaki, Shunzo Endo
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Publication number: 20110269858Abstract: Expandable, thermoplastic polymer bead material, comprising A) from 45 to 97.8 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin with a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin with a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a block or graft copolymer with weight-average molar mass Mw of at least 100,000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C.Type: ApplicationFiled: December 16, 2009Publication date: November 3, 2011Applicant: BASF SEInventors: Carsten Schips, Klaus Hahn, Konrad Knoll, Holger Ruckdäschel, Jens Assmann, Georg Grässel, Maximilian Hofmann
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Patent number: 7994229Abstract: The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 ?m and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.Type: GrantFiled: February 6, 2008Date of Patent: August 9, 2011Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Katsushi Miki, Toshiaki Masuda, Ichiro Takahara, Takashi Fujie, Ikuo Yosejima
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Publication number: 20110178192Abstract: A coating formulation intended for expandable particulate styrene polymer and comprising (A) from 10 to 90% by weight of a tristearyl ester whose melting point is in the range from 60 to 65° C., (B) from 10 to 90% by weight of a triglyceride of a hydroxy-C16-C18 oleic acid whose melting point is in the range from 70 to 95° C., and also expandable particulate styrene polymer which has at least one coating composed of said coating-composition formulation.Type: ApplicationFiled: August 8, 2008Publication date: July 21, 2011Applicant: BASF SEInventors: Andreas Keller, Olaf Kriha, Wolfram Husemann, Klaus Hahn, Bernhard Schmied, Michael Riethues
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Publication number: 20110172319Abstract: The composition and the preparation of multifunctional high-concentrate masterbatches for production of expanded materials of aromatic polyesters are disclosed in this invention. The masterbatch includes a thermoplastic wax having a vicat softening temperature not higher than 100° C. and a high-percentage of a multifunctional compound, wherein the preparation involves a) a low temperature process with a masterbatch temperature lower than 100° C. before cooling and b) cooling without contact of the mixture with water during the whole process. The high-concentrate masterbatch can be applied in production of expanded materials of polyester.Type: ApplicationFiled: January 11, 2011Publication date: July 14, 2011Applicant: ARMACELL ENTERPRISE GMBHInventor: Jie LI
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Patent number: 7972695Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: January 11, 2011Date of Patent: July 5, 2011Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H. Piispanan, Michael T. Williams
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Patent number: 7947751Abstract: Resin beads having an average particle size of from 0.001 mm to 10 mm and containing a continuous phase and a particulate dispersed phase are described. The continuous phase includes elastomeric polymers; the dispersed phase includes homopolymers and/or copolymers containing repeat units resulting from the polymerization of one or more aryl polymerizable monomers. The unexpanded polymer resin beads can be prepared by dispersing an organic phase containing elastomeric polymers and one or more monomers, into droplets and polymerizing the monomers in the organic droplets in a low shear flow pattern. The beads can be impregnated with blowing agents, expanded and can be used to make molded articles. Resin beads having a continuous phase comprising a nitrile rubber, and a dispersed phase comprising one or more homopolymers and/or copolymers containing repeat units resulting form the polymerization of one or more aryl polymerizable show prolonged retention of blowing agents in unexpanded form.Type: GrantFiled: November 13, 2009Date of Patent: May 24, 2011Assignee: NOVA Chemicals Inc.Inventors: Grazyna Petela, Michel F. J. Berghmans, Karel Cornelis Bleijenberg, Paul E. Arch
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Patent number: 7892645Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: August 19, 2010Date of Patent: February 22, 2011Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H Piispanen, Michael T Williams
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Patent number: 7863342Abstract: A method for forming a fire resistant material is disclosed. The method comprises providing a plurality of expandable beads of a polymeric material. The beads are coated with an exfoliable graphite. The exfoliable graphite is adhered to the beads with a resin having a solubility parameter of the polymeric material. The beads are thereafter caused or allowed expand and fuse.Type: GrantFiled: June 30, 2010Date of Patent: January 4, 2011Assignee: Synbra Technology B.V.Inventor: David Charles Aslin
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Publication number: 20100317753Abstract: A process comprising heating an aqueous dispersion of first structured polymer particles at a temperature of at least about 155° C., optionally in the presence of a base and/or a swelling agent, to produce an aqueous dispersion of heat treated structured polymer particles.Type: ApplicationFiled: November 29, 2007Publication date: December 16, 2010Inventors: Melinda H. Keefe, James G. Galloway, Ray E. Drumright, Michael J. Devon, Dwayne J. Nicholson
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Patent number: 7825165Abstract: Process for improving the insulating capacity of expanded vinyl aromatic which comprises: 1) preparing beads of expandable vinyl aromatic polymers containing 1-10% by weight, calculated with respect to the polymer, of an expanding agent englobed in the polymeric matrix and 0.001-25% by weight, calculated with respect to the polymer (a), of an athermanous additive comprising carbon black homogeneously distributed in the polymeric matrix; 2) treating the surface of the beads, before deposition of the coating, with a liquid lubricating agent; and 3) thermally treating the beads with hot air at a temperature ranging from 30 to 60° C.Type: GrantFiled: April 13, 2006Date of Patent: November 2, 2010Assignee: Polimeri Europa S.p.A.Inventors: Dario Ghidoni, Antonio Ponticiello, Alessandra Simonelli, Loris Zamperlin
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Publication number: 20100267851Abstract: A method for forming a fire resistant material is disclosed. The method comprises providing a plurality of expandable beads of a polymeric material. The beads are coated with an exfoliable graphite. The exfoliable graphite is adhe red to the beads with a resin having a solubility parameter of the polymeric material. The beads are thereafter caused or allowed expand and fuse.Type: ApplicationFiled: June 30, 2010Publication date: October 21, 2010Applicant: SYNBRA TECHNOLOGY B.V.Inventor: David Charles Aslin
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Patent number: 7807729Abstract: A production process for heat-expanded microspheres includes the step of providing a gaseous fluid containing heat-expandable microspheres, which includes a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 ?m. The gaseous fluid is fed through a gas-introducing tube having a dispersion nozzle on its outlet that is fixed inside a conduit having a hot gas flow flowing therethrough. A jet of the gaseous fluid is emitted through the dispersion nozzle. Further, the gaseous fluid is collided on a collision plate fixed under the dispersion nozzle so as to disperse the heat-expandable microspheres in the hot gas flow. The dispersed heat-expandable microspheres are heated in the hot gas flow at a temperature not lower than their expansion initiating temperature and thus expanded.Type: GrantFiled: November 15, 2004Date of Patent: October 5, 2010Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Takashi Fujie, Ichiro Takahara, Ikuo Yosejima, Katsushi Miki
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Patent number: 7785711Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: April 29, 2010Date of Patent: August 31, 2010Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David A. Cowan, Dennis H. Piispanen, Michael T. Williams
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Publication number: 20100204350Abstract: Disclosed herein is an expandable polystyrene bead having improved adiabaticity and flame-retardance and a method of producing the expandable polystyrene bead. The expandable polystyrene bead comprises 10 to 60 wt % of a flame retardant which is made of one or more selected from among metal or nonmetal oxides, metal or nonmetal hydroxides, silicates, borates and carbonates, having a particle size of 150 ?m. Expanded polystyrene foam having improved adiabaticity and flame-retardance can be obtained using the expandable polystyrene bead. A thin flame-retardant thermal insulator including the expanded polystyrene foam can be widely used in various fire-related fields.Type: ApplicationFiled: May 8, 2008Publication date: August 12, 2010Inventors: Jae-Cheon Kim, Hee-Seop Park
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Patent number: 7772294Abstract: A method for forming a fire resistant material is disclosed. The method comprises providing a plurality of expandable beads of a polymeric material. The beads are coated with an exfoliable graphite. The exfoliable graphite is adhered to the beads with a resin having a solubility parameter of the polymeric material. The beads are thereafter caused or allowed to expand and fuse.Type: GrantFiled: November 27, 2003Date of Patent: August 10, 2010Assignee: Synbra Technology B.V.Inventor: David Charles Aslin
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Patent number: 7736740Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: July 3, 2006Date of Patent: June 15, 2010Assignee: NOVA Chemicals Inc.Inventors: Jainsheng Tang, David Allen Cowan, Dennis H. Piispanen, Michael T. Williams
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Publication number: 20100143697Abstract: Thermoplastic particle foams which have cells having a mean cell size in the range from 20 to 500 ?m and in which the cell membranes have a nanocellular or fibrous structure having pore or fiber diameters below 1500 nm, and also processes for producing them.Type: ApplicationFiled: April 8, 2008Publication date: June 10, 2010Applicant: BASF SE Patents, Trademarks and LicensesInventors: Carsten Schips, Klaus Hahn, Georg Gräßel, Daniela Longo, Jens Aßmann, Andreas Gietl
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Publication number: 20100120929Abstract: A production method for heat-expandable microspheres, which have high expanding ratio and are thermally expanded into hollow particulates having excellent repeated-compression durability, and application thereof are provided. The method produces heat-expandable microspheres a shell of thermoplastic resin and a blowing agent being encapsulated therein and having a boiling point not higher than the softening point of the thermoplastic resin.Type: ApplicationFiled: May 14, 2008Publication date: May 13, 2010Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Hiroki Naito, Satoshi Kawanami, Katsushi Miki, Ikuo Yosejima, Kenichi Kitano
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Patent number: 7714029Abstract: An expandable polystyrene bead production method, which is a two-step process, is disclosed. The method includes obtaining suspendable, homogenous micropellets from a mixed composition prepared by mixing graphite particles with a styrene-based resin and extruding the composition, and carrying out seed polymerization by suspending graphite-containing micropellets in water and adding a styrene-based monomer and an aromatic hydrocarbon having 6 to 10 carbon atoms, and impregnation by adding a blowing agent. The produced expandable polystyrene beads, which contain graphite particles, are considerably low in thermal conductivity. In addition, the expandable polystyrene beads exhibit a little change in the thermal conductivity over time due to the use of the graphite particles, so that the heat insulation property can be sustained for an extended period of time.Type: GrantFiled: June 3, 2008Date of Patent: May 11, 2010Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Jin-Hee Lee, Han-Bae Bang, Hae-Ri Lee
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Publication number: 20100087556Abstract: The present invention relates to a particulate expandable polylactic acid which functions as a starting material for producing foamed moulded products. The present particulate expandable polylactic acid is provided with a coating so as to improve the fusion properties. The present invention also relates to a method for producing a particulate expandable polylactic acid as well as to a method for producing a foamed moulded product and to the moulded product obtained thereby.Type: ApplicationFiled: April 21, 2008Publication date: April 8, 2010Inventors: Robin Nicholas Britton, Franciscus Adrianus Hendrikus Cornelis Van Doormalen, Jan Noordegraaf, Karin Molenveld, Geraldus Gerardus Johannes Schennink