Expandible System Contains Two Or More Solid Polymers Or At Least One Solid Polymer And At Least One Polymer-forming System Patents (Class 521/59)
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Patent number: 8568633Abstract: Thermoplastic particle foams which have cells having a mean cell size in the range from 20 to 500 ?m and in which the cell membranes have a nanocellular or fibrous structure having pore or fiber diameters below 1500 nm, and also processes for producing them.Type: GrantFiled: January 29, 2013Date of Patent: October 29, 2013Assignee: BASF SEInventors: Carsten Schips, Klaus Hahn, Georg Gräβel, Daniela Longo-Schedel, Jens Assmann, Andreas Gietl
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Patent number: 8569390Abstract: An object of the present invention is to provide an in-mold foamed article having good surface appearances and high rigidity produced by using a common molding machine that withstands a pressure of up to 0.4 MPa. The present invention provides polypropylene resin pre-expanded particles containing a base resin which is a resin having a melt flow rate of 5 g/10 min or more and 20 g/10 min or less and a melting point of 140° C. or higher and 155° C. or lower and satisfying the conditional formula below, and an in-mold foamed article produced from molding the pre-expanded particles: [Heat of crystal fusion (J/g)]?1.2×[Melting point (° C.)]?96.Type: GrantFiled: December 21, 2005Date of Patent: October 29, 2013Assignee: Kaneka CorporationInventors: Taro Kiguchi, Tomonori Iwamoto
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Publication number: 20130281556Abstract: A freeze-thaw damage resistance and scaling damage resistance admixture for a cementitious composition including an aqueous slurry comprising a water insoluble superabsorbent polymer and expandable polymeric microspheres. A method for preparing a freeze-thaw damage resistant and scaling damage resistant cementitious composition including forming a mixture of a hydraulic cement and an admixture including an aqueous slurry of a water insoluble superabsorbent polymer and expanded polymeric microspheres.Type: ApplicationFiled: March 15, 2013Publication date: October 24, 2013Inventors: Frank Shaode ONG, James C. SMITH, Raymond FETE, Rick PAPONETTI
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Patent number: 8557885Abstract: The present invention relates to an extruded thermoplastic resin foam, particularly relates to a board extruded thermoplastic resin which has low heat conductivity, an excellent heat insulating property over a long period of time, high flame retardancy, and excellent mechanical strength. The extruded thermoplastic resin foam having an apparent density of 20 to 50 kg/m3, a closed cells ratio of 85% or more and a thickness of 10 to 150 mm, and containing a non-halogen organic physical blowing agent, wherein the thermoplastic resin composing the extruded foam contains a mixture of 100 parts by weight of a polystyrene resin (A) and 5 to 150 parts by weight of a polyester resin (B), and an endothermic calorific value of the polyester resin (B) less than 5 J/g (including 0) for fusion of the polyester resin on a DSC curve obtained by heat flux differential scanning calorimetry based on JIS K7122 (1987).Type: GrantFiled: April 6, 2011Date of Patent: October 15, 2013Assignee: JSP CorporationInventors: Akira Okuda, Tatsuyuki Ishikawa, Naochika Kogure, Kazunobu Sato
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Publication number: 20130237621Abstract: The present disclosure provides a high heat radiation composite material including a hybrid filler comprising expanded graphite filled with expandable polymeric beads, and a fabrication method thereof. In the method, a dispersion solution is prepared by dispersing expandable polymeric beads in ethanol. Expanded graphite is immersed in the dispersion solution, and heat-treated to remove ethanol, thereby producing the hybrid filler. The hybrid filler is dispersed into the matrix polymer via an extrusion/injection process, thereby producing the composite material.Type: ApplicationFiled: July 3, 2012Publication date: September 12, 2013Applicant: HYUNDAI MOTOR COMPANYInventors: Jin Woo Kwak, Han Saem Lee, Kyong Hwa Song, Byung Sam Choi
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Publication number: 20130225703Abstract: Compositions based on self-extinguishing expandable vinyl aromatic polymers in granules comprising: a. a polymeric matrix and, homogeneously englobed in the polymeric matrix, b. 3-10% by weight, calculated with respect to the polymer (a), of an expanding system; c. 0.005-5% by weight, calculated with respect to the polymer (a), of a brominated flame-retardant agent; d. 0.001-2% by weight, calculated with respect to the polymer (a), of a synergic additive; e. 0.005-5% by weight, calculated with respect to the polymer (a), of at least one stabilizing additive selected from: i. pyrophosphates of alkaline or alkaline earth metals, an ammonium group or a unit deriving from melamine; ii. melamine polyphosphate; iii. partially or completely salified polycarboxylic acids; iv. citrates of alkaline or alkaline earth metals; v. polyfunctional alcohols with 2 or more alcohol functions; vi. esters of poly-functional alcohols.Type: ApplicationFiled: September 20, 2011Publication date: August 29, 2013Applicant: VERSALIS S.p.A.Inventors: Antonio Ponticiello, Dario Ghidoni, Attilio Arienti, Alessandra Simonelli
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Patent number: 8519049Abstract: Disclosed is a curable composition including an organic polymer containing a crosslinkable silyl group, an ultraviolet ray absorbing agent having a triazine skeleton and a hindered amine based light stabilizer. The composition exhibits improved weather resistance in a thin layer and thick layer portion. Further, disclosed is a curable composition including an organic polymer containing a crosslinkable silyl group, a (meth)acrylic polymer containing an epoxy group, a divalent tin organic carboxylate and an organic amine compound. The composition exhibits excellent properties. Also, disclosed is a curable composition and sealing material including a reactive organic polymer containing at least one crosslinkable silyl group in one molecule thereof, a reactive organic polymer containing less than one crosslinkable silyl group in one molecule thereof, and thermally expandable hollow spheres. The composition has good physical properties. Also, disclosed is a fire-resistant structure forming method.Type: GrantFiled: July 9, 2012Date of Patent: August 27, 2013Assignee: Cemedine Co., Ltd.Inventors: Atsushi Saito, Masaki Ito, Shingo Kano, Hisashi Maekawahara, Naomi Okamura
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Patent number: 8507091Abstract: A method of reducing an odor of composite resin particles comprising the step of: fluidizing the composite resin particles, which contain a polyolefin-based resin and a polystyrene-based resin and which are used for producing an expanded molded article, in a container with a gas that is blown thereinto from its bottom and that has a temperature of (T?40)° C. to (T?10)° C. (T is a softening temperature of the composite resin particles), to reduce the odor generated from a raw material of the composite resin particles and generated according to a method of the composite resin particles, wherein the composite resin particles whose odor is reduced are impregnated with a blowing agent; and the resultant is pre-expanded and then subject to an in-mold forming to make the expanded molded article have an odor strength of 3 or less in average value in odor test in which odor of an isovaleric acid diluted 100000 times is defined as 3, which means a reference odor, within 0 to 5 levels of the odor strength.Type: GrantFiled: March 24, 2010Date of Patent: August 13, 2013Assignee: Sekisui Plastics Co., Ltd.Inventors: Shinji Ishida, Hideyasu Matsumura
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Publication number: 20130184363Abstract: Modified polystyrene-based resin particles comprising polyacrylic acid ester-based resin microparticles having an average particle diameter in the range of from 30 to 1,000 nm being dispersed in polystyrene-based resin particles, such that the polyacrylic acid ester-based resin microparticles are present (1) in the area ratio of from 0.1 to 15% in a surface area, which includes areas up to 20 ?m from the surface of each resin particle, and (2) present in the area ratio of from 11 to 50% in the inner area, which includes the area between the center of each resin particle and an point 30% of the radius from the center of each particle.Type: ApplicationFiled: September 30, 2011Publication date: July 18, 2013Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Yasutaka Tsutsui, Shingo Terasaki
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Publication number: 20130184362Abstract: The present invention aims to provide a foamable resin composition which enables foam molding at high expansion ratios and reduction of open cells. The present invention also aims to provide a foam molded body produced from the foamable resin composition. The present invention is a foamable resin composition including a thermoplastic resin, thermal expansion microcapsules, and a chemical foaming agent, wherein Ts is not lower than 120° C., Tmax is not lower than 190° C., and Ts-Tc is not lower than ?30° C. and not higher than 6° C., where Ts denotes a foaming starting temperature of the thermal expansion microcapsules, Tmax denotes a maximum foaming temperature of the thermal expansion microcapsules, and Tc denotes a decomposition temperature of the chemical foaming agent.Type: ApplicationFiled: September 1, 2011Publication date: July 18, 2013Inventors: Hiroshi Yamauchi, Hiroyuki Morita, Hiroshi Natsui
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Patent number: 8476325Abstract: A method for producing styrene-modified polyethylene-based resin beads, including the steps of: dispersing 100 parts by weight of polyethylene-based resin beads which contain an inorganic nucleating agent and have a melting point of 95° C. to 115° C., 20 parts by weight or more and less than 300 parts by weight of a styrene-based monomer and a polymerization initiator into an aqueous suspension containing a dispersant; impregnating the polyethylene-based resin beads with the styrene-based monomer under heating the resulting dispersion at such a temperature that the styrene-based monomer does not substantially polymerize; and performing polymerization of the styrene-based monomer at a temperature of (T)° C. to (T+25)° C. (where T° C. is a melting point of the polyethylene-based resin beads.Type: GrantFiled: August 19, 2005Date of Patent: July 2, 2013Assignee: Sekisui Plastics Co., Ltd.Inventors: Hideyasu Matsumura, Tatsuya Matsugashita
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Publication number: 20130150469Abstract: A method of making flame retardant expandable polystyrene-based polymerized beads includes: mixing (a) about 70 to about 95 wt % of a styrene monomer, (b) about 1 to about 10 wt % of a char-generating thermoplastic resin, and (c) about 4 to about 29 wt % of inorganic foam particles to prepare a dispersion; and polymerizing the dispersion. The method of the present invention can eliminate further processing steps, can exhibit excellent productivity, and can allow easy control of the size of the beads.Type: ApplicationFiled: February 7, 2013Publication date: June 13, 2013Applicant: CHEIL INDUSTRIES INC.Inventor: CHEIL INDUSTRIES INC.
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Publication number: 20130150470Abstract: The rigid polyurethane foam includes thermally expandable fine particles disposed between two or more adjacent cells, so as to be exposed to the inside and/or the outside of a unit cell, and a filler which is dispersed on the surface of the thermally expandable fine particles and/or on the inner and/or outer surfaces of the unit cell. The cells of the rigid polyurethane foam can be small and uniform in size and can be highly insulating.Type: ApplicationFiled: February 7, 2013Publication date: June 13, 2013Applicant: CHEIL INDUSTRIES INC.Inventor: CHEIL INDUSTRIES INC.
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Publication number: 20130150468Abstract: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.Type: ApplicationFiled: January 6, 2011Publication date: June 13, 2013Applicant: BASF SEInventors: Andreas Füssi, Bangaru Sampath, Maximilian Hofmann, Ingo Bellin, Sameer Nalawade, Klaus Hahn, Andreas Künkel, Robert Loos
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Patent number: 8455560Abstract: The invention relates to a foam ply based on a biodegradable polyester mixture, comprising i) from 70 to 5% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, and ii) from 30 to 95% by weight, based on the total weight of components i to ii, of poly-lactide, and iii) from 0.1 to 5% by weight, based on the total weight of components i to ii, of a copolymer which comprises epoxy groups and is based on styrene, acrylates, and/or methacrylates, and iv) from 0.5 to 15% by weight of additives; and v) from 0 to 50% by weight of inorganic or organic filler, and also to processes for production of the foam ply mentioned, and to the use of the foam plies for the production of moldings and foils, and also to moldings and foils comprising the foam plies mentioned.Type: GrantFiled: February 11, 2008Date of Patent: June 4, 2013Assignee: BASF SEInventors: Björn Dietrich, Daniela Longo-Schedel, Gabriel Skupin, Florian Krückl
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Publication number: 20130116352Abstract: Provided is expandable starch beads including a starch-monomer copolymer and a foaming agent impregnated in the starch-monomer copolymer, in which the starch-monomer copolymer is prepared by bonding at least one monomer selected from the group consisting of styrene, ?-methylstyrene, lactide, lactic acid, acrylic acid, methacrylic acid, acrylic ester, methacrylic ester, acrylonitrile, acrylamide, and caprolactone to starch, and the foaming agent includes at least one selected from the group consisting of C2 to C7 aliphatic hydrocarbon, C2 to C7 halogenated hydrocarbon, and carbon dioxide. Since the expandable starch beads have the similar properties to expandable polystyrene beads, and thereby can be foam-molded by equipment for foaming the expandable polystyrene beads, it is possible to produce foams with various sizes and various shapes.Type: ApplicationFiled: July 14, 2011Publication date: May 9, 2013Applicant: DAESANG CORPORATIONInventors: Young Mo Jo, Ssang Ok Kim, Gun Kyu Lee, Jee Young Yoon, Young Seung Jeon
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Publication number: 20130065977Abstract: Expandable composite resin particles for frozen storage comprising: composite resin particles of a polyolefin-based resin and a polystyrene-based resin; 7.5 to 11% by weight of volatile blowing agent contained in the composite resin particles and containing pentane; and 0.5 to 1.5% by weight of moisture attached to surfaces of the composite resin particles.Type: ApplicationFiled: January 24, 2011Publication date: March 14, 2013Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Yasutaka Tsutsui, Masahiko Ozawa
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Publication number: 20130065976Abstract: The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability and exhibits an excellent foaming property in a wide temperature range from low temperatures to high temperatures. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing acrylic monomer and an amide group-containing acrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing acrylic monomer and an ester group-containing acrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, and a weight ratio of the monomer A and the monomer B being 5:5 to 9:1.Type: ApplicationFiled: March 3, 2011Publication date: March 14, 2013Inventors: Hiroyuki Morita, Hiroshi Yamauchi, Hiroshi Natsui
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Publication number: 20130059933Abstract: A process for producing an expandable pelletized polymeric material which comprises: a) providing a polymer component, consisting of a styrene polymer component having a glass transition temperature of ?130° C., formed from and one or more thermoplastic polymers selected from the group consisting of aromatic polyethers; polyolefins; polyacrylates; polycarbonates; polyesters; polyamides; polyether sulfones; polyether ketones and polyether sulfides, (b) heating the polymer component to form a polymer melt, (c) introducing a blowing agent component into the polymer melt to form a foamable melt, (d) homogenizing the mixture, (f) extruding the blowing agent-containing polymer melt through a die plate, (g) pelletizing the blowing agent-containing melt in a liquid-filled chamber to form a pelletized material.Type: ApplicationFiled: August 30, 2012Publication date: March 7, 2013Applicant: BASF SEInventors: Holger Ruckdäschel, Alexandre Terrenoire, Jan Kurt Walter Sandler, Klaus Hahn, Ingo Bellin, Georg Grässel, Martin Weber
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Publication number: 20120328889Abstract: A thermally foamable resin composition contains foamable resin particles and a resin composition. Each of the foamable resin particles contains a solid resin and a thermally expandable substance contained in the solid resin.Type: ApplicationFiled: February 25, 2011Publication date: December 27, 2012Applicant: NITTO DENKO CORPORATIONInventors: Youhei Hayashi, Yoshiaki Mitsuoka, Takehiro Ul
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Patent number: 8268902Abstract: Expandable particle composite material suitable for the preparation of expanded materials having a density lower than 40 g/l and a content of closed cells of at least 60%, including heterophase cavities and/or heterophase domains, whose matrix is a synthetic thermoplastic resin having at least 60% by weight of a vinyl aromatic polymer and in which an expanding system is contained, together with a heterogeneously distributed graphite material, having a graphitization degree, calculated by means of the Maire and Mering formula, of at least 0.2.Type: GrantFiled: May 15, 2008Date of Patent: September 18, 2012Assignee: Polimeri Europa S.p.A.Inventors: Alessandro Casalini, Riccardo Felisari, Dario Ghidoni, Antonio Ponticiello, Alessandra Simonelli
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Patent number: 8236431Abstract: A coating for paperboard comprises an aqueous dispersion of a hollow core binder comprising a first polymer that, when dry, has at least one void, the first polymer being substantially encapsulated by at least one second polymer having a glass transition temperature (Tg) ranging from more than ?15° C. and up to and including 30° C., wherein the weight ratio of the said second polymer to the said first polymer ranges from 1:1 to 4:1. One or both of the first polymer and the second polymer may be formed from, as polymerized units, at least one ethylenically unsaturated monomer. The hollow core binder allows for glossy, bright and smooth paperboard coatings while reducing the amount of binder and opacifying pigment necessary to achieve such coating properties. The present invention also provides coated paperboard articles, as well as paper and paperboard that is made from a mixture of pulp with the inventive hollow core binder.Type: GrantFiled: September 17, 2007Date of Patent: August 7, 2012Assignee: Rohm and Haas CompanyInventor: Ravi Mukkamala
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Publication number: 20120189848Abstract: Provided is a method for producing single-hole hollow polymer particles which have an extremely uniform outside diameter and inside diameter, and thus do not require a classifying operation. Further provided are single-hole hollow polymer particles produced by such a method for producing single-hole hollow polymer particles. The invention relates to a method for producing single-hole hollow polymer particles, which includes: preparing a dispersion of swollen particle droplets by mixing a seed particle dispersion obtained by dispersing uncrosslinked polymer-containing seed particles in a water-containing dispersion medium, with a radical polymerizable monomer, an oil-soluble solvent and an oil-soluble polymerization initiator, and causing the radical polymerizable monomer, the oil-soluble solvent and the oil-soluble polymerization initiator to be absorbed in the seed particles; and polymerizing the radical polymerizable monomer in the swollen particle droplets.Type: ApplicationFiled: July 27, 2010Publication date: July 26, 2012Inventors: Hiroshi Yamauchi, Yasuyuki Yamada
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Publication number: 20120149792Abstract: Disclosed is expandable modified resin beads (1), comprising a modified resin as a base resin in which a dispersion phase (3) containing a styrene resin as a major component is dispersed in a continuous phase (2) containing an olefin resin as a major component, and a physical blowing agent. Further disclosed are expanded modified resin beads obtained by expanding the expandable modified resin beads (1), and a foamed molded article formed from the expanded modified resin beads obtained by molding the expanded modified resin beads in a mold. A volume average diameter of the dispersion phase (3) dispersed in the continuous phase (2) is 0.55 ?m or more. The expandable modified resin beads (1) have, as a base resin, the modified resin contains 80 to 50 parts by mass of the styrene resin with respect to 20 to 50 parts by mass parts of the olefin resins.Type: ApplicationFiled: July 20, 2010Publication date: June 14, 2012Applicant: JSP CORPORATIONInventor: Masaomi Shima
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Publication number: 20120115968Abstract: A seed beads dispersing disperse system is obtained by dispersing olefin resin seed beads 1 with a specific tubular shape in an aqueous medium. Then, the olefin resin seed beads 1 are impregnated with styrene monomers and the styrene monomers are polymerized in the presence of a polymerization initiator by heating at a temperature in a specified range, to thereby obtain tubular thermoplastic resin composite beads. Expandable thermoplastic resin composite beads obtained by impregnating the thermoplastic resin composite beads with a blowing agent, expanded thermoplastic resin composite beads obtained by foaming and expanding the expandable thermoplastic resin composite beads, and a foamed molded article formed from the expanded thermoplastic resin composite beads by molding are also obtained.Type: ApplicationFiled: November 7, 2011Publication date: May 10, 2012Applicant: JSP CORPORATIONInventors: Masaomi SHIMA, Mitsuru Shinohara
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Publication number: 20120065282Abstract: A method for preparing polyamide foam is described. Polyamide foam produced according to the method is also described. A method including heating a composition including at least one polyamide and at least one polyurethane, and stabilizing the resulting cellular structure is also described. Use of a composition including at least one polyamide and at least one polyurethane for preparing polyamide foam is also described.Type: ApplicationFiled: May 10, 2010Publication date: March 15, 2012Applicant: RHODIA OPERATIONSInventors: Lise Trouillet-Fonti, Eric Roche
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Publication number: 20120053255Abstract: Composite polystyrene particles have an average size less than 1200 ?m and methods of making them are provided. The composite polystyrene particles can include recycled polystyrene obtained from a variety of sources. The composite polystyrene particles can be used in a variety of applications, including packaging materials and molded supports for the shipment of fragile objects.Type: ApplicationFiled: March 2, 2011Publication date: March 1, 2012Applicant: RAPACInventors: Dennis W. Koerner, Michael Pate, David Wilson
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Publication number: 20120041086Abstract: An expandable pelletized material comprising A) a polymer matrix composed of A1) at least 55% by weight of polyester (based on the entirety of components A1) and A2)) with a total enthalpy of fusion of up to 60 J/g, optionally of one or more melting points in the range from 100 to 300° C. and of one or more glass transition temperatures in the range from 0 to 250° C., and A2) from 0 to 45% by weight (based on the entirety of components A1) and A2)) of one or more thermoplastic polymers different from component A1); B) a physical blowing agent component, and C) optionally further additives is suitable for producing moldable foams for use in the automobile industry, airline industry, construction industry, packaging industry, sports and leisure industry, in transport, in engineering, in lightweight construction, and/or in composite construction.Type: ApplicationFiled: August 15, 2011Publication date: February 16, 2012Applicant: BASF SEInventors: Bangaru Dharmapuri Sriramulu Sampath, Olaf Kriha, Holger Ruckdäschel, Philippe Desbois, Freddy Gruber, Klaus Hahn
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Patent number: 8084509Abstract: The present invention provides a pre-expanded particulate polyolefin-based resin capable of easily attaining satisfactory secondary expandability, satisfactory surface appearance, and satisfactory dimensional stability even when it is intended to obtain an in-mold expansion molded article having a thin-wall shape. The present invention provides a pre-expanded particulate polypropylene-based resin including a polypropylene-based resin X as a base resin, where the resin X includes a resin mixture of at least a polypropylene-based resin A having a melting point of 140° C. or lower and a polypropylene-based resin B having a melting point of 145° C. or higher, and the resin mixture is modified by an organic peroxide so as to have a melt index of 5 g/10 min or more and less than 20 g/10 min.Type: GrantFiled: November 18, 2005Date of Patent: December 27, 2011Assignee: Kaneka CorporationInventors: Tetsuya Shibata, Tomonori Iwamoto
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Patent number: 8084510Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided.Type: GrantFiled: October 25, 2007Date of Patent: December 27, 2011Assignee: Sekisui Plastics Co., Ltd.Inventors: Ikuo Morioka, Yasutaka Tsutsui, Hideyasu Matsumura
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Patent number: 8076381Abstract: The object is to provide a molded product of foamed particles obtained by charging biodegradable resin foamed particles which are of vegetable origin and excellent in environmental compatibility into a mold, followed by heat molding, which molded product is not accompanied by post shrinkage after the molding with a wide range of variation of processing in the molding. Further, P3HA resin foamed particles being composed of a resin composition that comprises an isocyanate compound, and a polymer, poly(3-hydroxyalkanoate), having a recurring unit represented by the general formula (1): [—O—CHR—CH2—CO—]??(1) (wherein R represents an alkyl group represented by CnH2n+1, wherein n is an integer of from 1 to 15) produced by a microorganism are provided.Type: GrantFiled: April 10, 2006Date of Patent: December 13, 2011Assignees: Kaneka Corporation, Meredian, Inc.Inventors: Toshio Miyagawa, Fuminobu Hirose, Kenichi Senda
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Publication number: 20110294910Abstract: An expandable pelletized material comprising A) a polymer matrix composed of A1) at least 55% by weight of polyamide (based on the entirety of components A1) and A2)) with a crystallinity of up to 30% and if appropriate a melting point in the range from 100 to 340° C. and a glass transition temperature in the range from 0 to 150° C., and A2) from 0 to 45% by weight of one or more thermoplastic polymers that differ from component A1); B) a physical blowing agent composition, and C) optionally further additives, is suitable for producing a moldable foam for use in the automobile industry, airline industry, construction industry, packaging industry, or sports and leisure industry, or in the transport sector, and/or in engineering.Type: ApplicationFiled: April 27, 2011Publication date: December 1, 2011Applicant: BASF SEInventors: Olaf Kriha, Klaus Hahn, Philippe Desbois, Volker Warzelhan, Holger Ruckdäschel, Maximilian Hofmann, Christian Exner, Roland Hingmann
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Patent number: 8063177Abstract: A pre-expanded polypropylene resin particle can be produced in the following manner: a polypropylene resin particle produced by an under water cut method, water, a dispersing agent, and a foaming agent are charged in a pressure-resistant container, the resulting mixture is heated to a temperature equal to or higher than the softening temperature of the polypropylene resin particle to allow the polypropylene resin particle to be impregnated with the foaming agent under pressure, and the resulting product is released into the atmosphere having a pressure lower than the pressure of the inside of the pressure-resistant container. As the polypropylene resin composition, a composition is used which comprises 100 parts by weight of a polypropylene resin and 1 to 20 parts by weight of a polyethylene resin having a melt viscosity of 10 to 2000 mPa·s at 140° C.Type: GrantFiled: September 29, 2008Date of Patent: November 22, 2011Assignee: Kaneka CorporationInventors: Tetsuya Minami, Tetsuya Shibata, Hidekazu Oohara
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Patent number: 8058320Abstract: A thermally foamable microsphere having a structure that a foaming agent is encapsulated in an outer shell formed from a polymer, wherein the foaming agent contains isododecane, and a production process of the thermally foamable microsphere by a suspension polymerization process using a polymerizable monomer and a foaming agent containing dodecane.Type: GrantFiled: September 13, 2005Date of Patent: November 15, 2011Assignee: Kureha CorporationInventors: Tetsuo Ejiri, Mitsuhiro Matsuzaki, Shunzo Endo
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Publication number: 20110269858Abstract: Expandable, thermoplastic polymer bead material, comprising A) from 45 to 97.8 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin with a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin with a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a block or graft copolymer with weight-average molar mass Mw of at least 100,000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C.Type: ApplicationFiled: December 16, 2009Publication date: November 3, 2011Applicant: BASF SEInventors: Carsten Schips, Klaus Hahn, Konrad Knoll, Holger Ruckdäschel, Jens Assmann, Georg Grässel, Maximilian Hofmann
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Publication number: 20110206923Abstract: Methods of preparing silicone materials using electron beam curing are described. The materials are hot melt processed and cured in the absence of an effective amount of catalysts and initiators. Both functional and nonfunctionalized silicone materials may be used. Exemplary cured materials include silicone pressure sensitive adhesives, silicone foams, and non-tacky silicon films.Type: ApplicationFiled: October 29, 2009Publication date: August 25, 2011Inventors: Junkang J. Liu, Clayton A. George
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Publication number: 20110144220Abstract: Interpolymer resin particles comprised of 20% to 60% by weight of uncross-linked polyolefin e.g. polyethylene, polypropylene, and from 40% to 80% by weight based on the weight of the particles of a vinyl aromatic monomer, e.g. styrene, that is polymerized in a suspension process to form an interpenetrating network of polyolefin with polymerized vinyl aromatic monomer particles and having a gel content of 0 to 1.5% by weight based on the weight of the particles for improved processability in end-use applications and improved ESCR properties. The interpolymer resin particles have a VICAT softening temperature from about 90° C. to about 115° C., and a melt index from 0.2 to 35.0 g/10 minutes (Condition G). The particles can be mixed with a blowing agent to form extruded foam articles, such as foam board, and can be used in extrusion, injection molding, rotomolding, and thermoforming processes to form a layer, e.g.Type: ApplicationFiled: February 4, 2011Publication date: June 16, 2011Applicant: NOVA CHEMICALS INC.Inventor: Steven M. Krupinski
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Publication number: 20110123807Abstract: The present invention provides a thermally expandable microsphere having a core-shell structure comprising: a shell including a thermoplastic polymer and a long-chain crosslinking agent having a weight-average molecular weight between cross-linking sites of more than about 500; and a core including a foaming agent. The thermally expandable microsphere of the present invention can have excellent foaming characteristics and an even (uniform) microsphere diameter.Type: ApplicationFiled: November 23, 2010Publication date: May 26, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Jung Bae Jun, Kyung Hyun Baek, Jung Kyu Ju
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Patent number: 7947751Abstract: Resin beads having an average particle size of from 0.001 mm to 10 mm and containing a continuous phase and a particulate dispersed phase are described. The continuous phase includes elastomeric polymers; the dispersed phase includes homopolymers and/or copolymers containing repeat units resulting from the polymerization of one or more aryl polymerizable monomers. The unexpanded polymer resin beads can be prepared by dispersing an organic phase containing elastomeric polymers and one or more monomers, into droplets and polymerizing the monomers in the organic droplets in a low shear flow pattern. The beads can be impregnated with blowing agents, expanded and can be used to make molded articles. Resin beads having a continuous phase comprising a nitrile rubber, and a dispersed phase comprising one or more homopolymers and/or copolymers containing repeat units resulting form the polymerization of one or more aryl polymerizable show prolonged retention of blowing agents in unexpanded form.Type: GrantFiled: November 13, 2009Date of Patent: May 24, 2011Assignee: NOVA Chemicals Inc.Inventors: Grazyna Petela, Michel F. J. Berghmans, Karel Cornelis Bleijenberg, Paul E. Arch
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Publication number: 20110065819Abstract: Expandable, thermoplastic polymer bead material, comprising A) from 45 to 98.8 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin whose melting point is in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin whose melting point is below 105° C., C1) from 0.1 to 9.9 percent by weight of a styrene-butadiene block copolymer, C2) from 0.1 to 9.9 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent where the entirety of A) to E) gives 100% by weight, and also processes for production of the same, and use for the production of elastic molded-foam moldings.Type: ApplicationFiled: March 12, 2009Publication date: March 17, 2011Applicant: BASF SE Patents, Trademarks and LicensesInventors: Carsten Schips, Klaus Hahn, Georg Grässel, Daniela Longo-Schedel, Jens Assmann, Andreas Gietl, Konrad Knoll, Holger Ruckdäschel, Maximilian Hofmann, Christof Zylla, Jürgen Lambert, Geert Janssens
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Patent number: 7868053Abstract: Expandable pelletized styrene polymer materials with at least bi- or multimodal molecular weight distribution, to a process for their preparation, and to use for producing moldable-foam moldings.Type: GrantFiled: December 10, 2004Date of Patent: January 11, 2011Assignee: BASF SEInventors: Klaus Hahn, Gerd Ehrmann, Joachim Ruch, Markus Allmendinger, Bernhard Schmied, Jan Holoch, Franz-Josef Dietzen
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Publication number: 20110003904Abstract: A lightweight ready-mix concrete composition that contains 8-20 volume percent cement, 11-50 volume percent sand, 10-31 volume percent prepuff particles, 9-40 volume percent coarse aggregate, and 10-22 volume percent water, where the sum of components used does not exceed 100 volume percent;. The prepuff particles have an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.02 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3. The slump value of the composition measured according to ASTM C 143 is from 2 to 8 inches. After the lightweight ready-mix concrete composition is set for 28 days, it has a compressive strength of at least 1400 psi as tested according to ASTM C39.Type: ApplicationFiled: September 14, 2010Publication date: January 6, 2011Applicant: NOVA CHEMICALS INC.Inventors: Tricia Guevara, Michael T. Williams, Rick Hughes, Michael R. Kelley, John K. Madish, Kristen Van Buskirk
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Patent number: 7855237Abstract: The method for the manufacture of foamed or foamable polymer particles employs a mixture of a polymer melt and a recycled polymer melt produced from recycled, propellant-containing polymer particles. The associated plant for the manufacture of the foamed or foamable polymer particles is provided with an apparatus for the processing of recycled, propellant-containing polymer particles.Type: GrantFiled: October 20, 2009Date of Patent: December 21, 2010Assignee: Sulzer Chemtech AGInventor: Philip Nising
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Patent number: 7767723Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 50 to 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains less than 2 wt % of a gel component comprising a graft polymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.Type: GrantFiled: March 22, 2004Date of Patent: August 3, 2010Assignee: Sekisui Plastics Co., Ltd.Inventors: Hideyasu Matsumura, Yasutaka Tsutsui
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Patent number: 7767724Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 300 parts by weight and less than 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains 2 to 40 wt % of a gel component comprising a graft copolymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.Type: GrantFiled: March 22, 2004Date of Patent: August 3, 2010Assignee: Sekisui Plastics Co., Ltd.Inventors: Hideyasu Matsumura, Yasutaka Tsutsui
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Publication number: 20100190877Abstract: Bead foam moldings obtainable by fusing prefoamed foam beads composed of expandable thermoplastic polymer granules, comprising from 5 to 100% by weight of a component (A) comprising a1) from 5 to 100% by weight (based on (A)) of an ?-methylstyrene/acrylonitrile copolymer and/or ?-methylstyrene/styrene/acrylonitrile terpolymer and a2) from 0 to 95% by weight (based on (A)) of a styrene/acrylonitrile copolymer; from 0 to 95% by weight of polystyrene (B) and from 0 to 95% by weight of a thermoplastic polymer (C) other than (A) and (B), feature good thermal and solvent stability.Type: ApplicationFiled: June 26, 2008Publication date: July 29, 2010Applicant: BASF SEInventors: Carsten Schips, Klaus Hahn, Ingo Bellin, Daniela Longo, Jens Assmann, Andreas Gietl, Jochen Gassan
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Patent number: 7741378Abstract: To provide porous monodispersed particles obtained by preparing, as seed particles, poly(methyl methacrylate) particles or acrylic resin particles comprising 70% by mass or more of methyl methacrylate as a copolymerization component, swelling the seed particles 20 to 80 times the size of the original seed particles by mass using a swelling solution comprising an oil-soluble polymerization initiator and a monomer mixture containing 70% by mass or more of methyl methacrylate and 3 to 8% by mass of divinylbenzene, and polymerizing the monomers. The particles are porous particles with a diameter of the order of micrometers and a narrow particle-size distribution and are monodispersed. Colored monodispersed particles obtained by agglomerating a pigment in the porous monodispersed particles are monodispersed and spherical, and contain a large amount of pigment therein.Type: GrantFiled: March 1, 2006Date of Patent: June 22, 2010Assignee: Soken Chemical & Engineering Co., Ltd.Inventor: Ying Cui
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Publication number: 20100130627Abstract: A process for the continuous production of granules based on thermoplastic polymers includes at least one expandable agent and, optionally, other polymers or additives, among which inorganic pigments insoluble in the polymeric matrix, wherein a first main stream is prepared, in the molten state, and a second stream in the molten state, which englobes the additives and which is added to the first stream. The mixture is extruded through a die which is cooled by means of water jets from nozzles positioned behind the cutting blades.Type: ApplicationFiled: May 15, 2008Publication date: May 27, 2010Applicant: POLIMERI EUROPA S.P.A.Inventors: Alessandro Casalini, Riccardo Felisari
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Patent number: 7718751Abstract: The present invention concerns a pre-mix for a syntactic phenolic foam composition; a syntactic phenolic foam composition; and a process for preparing the syntactic phenolic foam composition. The pre-mix comprises thermally expandable and/or expanded thermoplastic microspheres, the microspheres comprising a thermoplastic polymer shell made of a homopolymer or copolymer of 100 to 25, for example 93 to 40, parts by weight of a nitrile-containing, ethylenically unsaturated monomer, or a mixture thereof; and 0 to 75, for example 7 to 60, parts by weight of a non-nitrile-containing, ethylenically unsaturated monomer, or a mixture thereof; and a propellant, or a mixture thereof, trapped within the thermoplastic polymer shell; and one of either a highly reactive phenolic resole resin capable of fully crosslinking at temperatures between 15° C. and 60° C.Type: GrantFiled: March 15, 2006Date of Patent: May 18, 2010Assignee: Pyro Technologies LimitedInventor: Murray Orpin
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Publication number: 20100113627Abstract: This invention provides a water-based coating-type damping material whereby detachment or deformation of a sealer can be prevented and anti-blister performance can be improved. Such water-based coating-type damping material comprises at least an aqueous resin emulsion, an inorganic filler, a water retention agent that retains the moisture of the resin emulsion, and microballoon particles comprising balloons encapsulating an expansion agent that is evaporated by heating so as to expand, the microballoon particles starting to expand in the presence of the expansion agent under heating temperature conditions of the water boiling point or lower.Type: ApplicationFiled: November 3, 2009Publication date: May 6, 2010Inventors: Shota MATSUMOTO, Haruhisa Suzuki, Junichi Kawai, Masaki Kawai