Ingredient Is Ether, Alcohol, Or Inorganic Alcoholate, E.g., Phenol, Etc. Patents (Class 521/88)
  • Publication number: 20130245143
    Abstract: The invention encompasses compositions and methods for the preparation thereof, wherein the composition comprises a polymeric foam that comprise a plurality of polymeric struts having an air-foam interface, wherein a composition comprising inorganic particulate matter is disposed upon the air-foam interface, the inorganic particulate material comprising inorganic particles coated with a hydrophobic amine modifier.
    Type: Application
    Filed: February 25, 2013
    Publication date: September 19, 2013
    Applicant: Soane Labs, LLC
    Inventor: David S. Soane
  • Patent number: 8513317
    Abstract: Provided is a process for producing expanded polyolefin resin particles whose cells are not made nonuniform or extremely smaller as seen in conventional expanded particles, whose cell diameter and expansion ratio can be easily controlled independently, and which, when subjected to in-mold expansion molding, give in-mold expanded molded products satisfactory in fusibility and excellent in surface properties.
    Type: Grant
    Filed: December 3, 2008
    Date of Patent: August 20, 2013
    Assignee: Kaneka Corporation
    Inventors: Jun Fukuzawa, Hiroshi Tsuneishi
  • Publication number: 20130210621
    Abstract: A breathable film formed from a thermoplastic composition that contains a rigid renewable polyester and has a voided structure is provided. To achieve such a structure, a thermoplastic composition that contains a renewable polyester and polymeric toughening additive is extruded onto a surface to form a precursor film in which the toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. The precursor film is thereafter stretched or drawn at a temperature below the glass transition temperature of the polyester (i.e., “cold drawn”). Without intending to be limited by theory, the present inventors believe that the deformation force and elongational strain of the drawing process causes debonding to occur in the renewable polyester matrix at those areas located adjacent to the discrete domains. This creates a network of voids located adjacent to the discrete domains.
    Type: Application
    Filed: February 10, 2012
    Publication date: August 15, 2013
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Ryan J. McEneany, Neil T. Scholl, Thomas A. Eby
  • Publication number: 20130203878
    Abstract: Foamed polymeric compositions containing clay nucleating agents are described. The clays are preferably sepioiite, palygorskite/attapulgite, or combinations thereof. Also described are processes for forming the foamed compositions. The resulting products find particular application as insulation and packaging materials.
    Type: Application
    Filed: May 12, 2011
    Publication date: August 8, 2013
    Applicant: FERRO CORPORATION
    Inventors: Juan-Antonio Igualada, Jose-Luis Feijoo
  • Publication number: 20130184366
    Abstract: The present invention discloses aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising 80 mole percent or greater of terephthalic acid; B) a polyether polyol having a nominal functionality greater than 2 and less than or equal to 4, a molecular weight of 250 to 1000 and has a polyoxypropylene content of at least 70% by weight of the polyol; and C) a glycol other than B having a molecular weight from 60 to 250; wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 15 to 70 weight percent of B); and 10 to 50 weight percent of C).
    Type: Application
    Filed: September 15, 2011
    Publication date: July 18, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Jorge Jimenez, Woo-Sung Bae, Giuseppe Lista, Mikhail Y. Gelfer, Vanni Parenti, Hans Kramer
  • Publication number: 20130172434
    Abstract: Provided herein are a method for preparing a resin composition for an expandable polypropylene carbonate and an expandable polypropylene carbonate prepared therefrom. More particularly, the present invention relates to a method for preparing a resin composition for an expandable polypropylene carbonate capable of using supercritical carbon dioxide as a foaming agent and preparing a foam having excellent moldability by an appropriate foaming method, and an expandable polypropylene carbonate prepared therefrom. The expandable polypropylene carbonate capable of having high magnification, excellent thermal stability, and dimensional stability may be prepared by using the resin composition according to the present invention.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 4, 2013
    Applicants: SK GLOBAL CHEMICAL CO., LTD., SK INNOVATION CO., LTD.
    Inventors: SK INNOVATION CO., LTD., SK GLOBAL CHEMICAL CO., LTD.
  • Publication number: 20130143975
    Abstract: The presently disclosed subject matter relates generally to method of producing thermoplastic foam from a blend of polyolefin and acrylated epoxidized fatty acid using a phsyical blowing agent. Specifically, the presently disclosed subject matter includes embodiments wherein the acrylated epoxidized fatty acid is added to the polyolefin resin in an amount of from about 0.1% to about 10%, based on the total weight of the resin. The presently disclosed subject matter also includes the foam produced by the disclosed method.
    Type: Application
    Filed: December 1, 2011
    Publication date: June 6, 2013
    Applicant: Sealed Air Corporation (US)
    Inventors: Edward F. Cassidy, William J. Mahon, Natarajan S. Ramesh, Parimal M. Vadhar
  • Patent number: 8415411
    Abstract: A filler composition comprising one or more ester-containing compounds and one or more ether-containing compounds.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: April 9, 2013
    Inventor: John Paul Simmons, II
  • Publication number: 20130065044
    Abstract: Disclosed are bowing agent compositions, foamable compositions, foams, foaming methods and/or foamed articles comprising one or more C2 to C6 fluoroalkenes, more preferably one or more C3 to C5 fluoroalkenes, and even more preferably one or more compounds having Formula I as follows: XCFzR3-z??(I) where X is a C1, C2, C3, C4, or C5 unsaturated, substituted or unsubstituted radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3, it generally being preferred that the fluoroalkene of the present invention has at least four (4) halogen substituents, at least three of which are F and even more preferably none of which are Br.
    Type: Application
    Filed: August 14, 2012
    Publication date: March 14, 2013
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: James M. Bowman, David J. Williams
  • Publication number: 20130058858
    Abstract: A method for producing a porous body containing polyacrylonitrile as a main component, and the method includes the steps of obtaining a polyacrylonitrile solution by heating and dissolving the polyacrylonitrile in a solvent, obtaining a product precipitated by cooling the polyacrylonitrile solution, and obtaining the porous body containing the polyacrylonitrile as a main component by separating and drying the product. The solvent contains a poor solvent for the polyacrylonitrile and a good solvent for the polyacrylonitrile.
    Type: Application
    Filed: May 2, 2011
    Publication date: March 7, 2013
    Applicant: OSAKA UNIVERSITY
    Inventors: Hiroshi Uyama, Takashi Tsujimoto, Keisuke Okada, Tatsuya Oka
  • Patent number: 8378001
    Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, a polystyrene/polyethylene oxide copolymer, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the blowing agent includes at least one hydrofluorocarbon blowing agent. The maleic anhydride-styrene copolymer grafted with polyethylene oxide provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: February 19, 2013
    Assignee: Owens Corning Intellectual Capital, LLC
    Inventors: Yadollah Delaviz, Raymond M. Breindel, Mitchell Z. Weekley, John F. Budinscak
  • Patent number: 8349909
    Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an infrared attenuating agent, and a polystyrene/polyethylene oxide copolymer are provided. In exemplary embodiments, the blowing agent contains an HFC. The maleic anhydride-styrene copolymer grafted with polyethylene oxide increases the cell size of the polymer foam and offsets or even negates the decreased cell size caused by an HFC blowing agent and/or infrared attenuating agents. In addition, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: January 8, 2013
    Assignee: Owens Corning Intellectual Capital, LLC
    Inventors: Yadollah Delaviz, Raymond M. Breindel, Klin Rodrigues, Bharat Patel
  • Publication number: 20130004435
    Abstract: The present invention relates, in part, to ternary azeotropic compositions and mixtures including chlorotrifluoropropene, methanol, and a third component selected from isohexane, trans-1,2-dichloroethylene, and petroleum ether. The present invention further relates to ternary azeotropic compositions and mixtures including chlorotrifluoropropene, cyclopentane, and a alcohol selected from methanol, ethanol, and isopropanol.
    Type: Application
    Filed: August 23, 2012
    Publication date: January 3, 2013
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: Kane D. COOK, Rajat S. BASU, Ryan HULSE
  • Publication number: 20120323339
    Abstract: The present invention refers to a porous PEEK-type polymer article comprising a porous PEEK-type polymer structure and presenting at least a trimodal pore distribution. The invention describes a process for the production of said porous PEEK-type polymer article comprising: a) contacting a PEEK-type polymer with a composition comprising at least a organic solvent, b) heating at a temperature at which the PEEK-type polymer is dissolved, c) adding at least a porogen agent, d) cooling the mixture obtained in c) at a temperature at least equal or lower than the temperature at which the PEEK-type polymer precipitates, e) forming said cooled mixture into a shaped article, f) removing the organic solvent and the porogen agent, and g) recovering the PEEK-type polymer article.
    Type: Application
    Filed: December 23, 2010
    Publication date: December 20, 2012
    Inventors: Beatriz Olalde Graells, María Jesús Jurado Oñate
  • Patent number: 8323787
    Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an additive blend of polyethylene oxide and a copolymer of polystyrene and maleic anhydride, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the polyethylene oxide is ethoxylated polyethylene oxide. Additionally, in at least one embodiment, the blowing agent includes at least one hydrofluorocarbon blowing agent. The blend of ethoxylated polyethylene oxide and copolymer of polystyrene and maleic anhydride provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product and increases the average cell size of the foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the additive acts as a cell enlarger, a water vapor permeability enhancer, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: December 4, 2012
    Assignee: Owens Corning Intellectual Capital, LLC
    Inventors: Yadollah Delaviz, Raymond M. Breindel, John F. Budinscak, Jr.
  • Publication number: 20120283344
    Abstract: A polyethylene resin expanded particle has an expansion ratio of not less than 10 times and not more than 50 times, and in a DSC curve obtained by differential scanning calorimetry (DSC), the polyethylene resin expanded particle (i) shows two melting peaks, the two melting peaks being a low-temperature side melting peak and a high-temperature side melting peak, and (ii) further has a shoulder in a region not less than 100° C. and not more than the low-temperature side melting peak temperature, the shoulder having a shoulder ratio which is not less than 0.2% and not more than 3%.
    Type: Application
    Filed: January 14, 2011
    Publication date: November 8, 2012
    Inventors: Kiyotaka Nakayama, Toru Yoshida
  • Publication number: 20120208911
    Abstract: A method of making a foamable polystyrene composition includes combining a styrenic monomer and a co-monomer containing a polar functional group to obtain a mixture, subjecting the mixture to polymerization to obtain a styrenic co-polymer, and combining the styrenic co-polymer with a blowing agent in a foaming process to obtain foamed articles.
    Type: Application
    Filed: January 11, 2012
    Publication date: August 16, 2012
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Wei Wang, David W. Knoeppel, Melissa Greenberg
  • Publication number: 20120190761
    Abstract: Provided are a composition for preparing expandable polypropylene carbonate and an expandable polypropylene carbonate prepared therefrom, and more particularly, to a composition for preparing expandable polypropylene carbonate capable of using supercritical carbon dioxide as a foaming agent and producing a foam having excellent moldability by using an appropriate foaming method. By using the composition according to the present invention, highly magnificated expandable polypropylene carbonate capable of having excellent thermal stability and dimensional stability can be prepared.
    Type: Application
    Filed: October 10, 2011
    Publication date: July 26, 2012
    Applicant: SK INNOVATION CO., LTD.
    Inventors: Minho JEON, Younghyo PARK, Kwangjin CHUNG, Myungahn OK
  • Publication number: 20120184636
    Abstract: Process for the preparation of beads of expandable vinyl aromatic polymers by means of polymerization in aqueous suspension, which comprises polymerizing at least one vinyl aromatic monomer in aqueous suspension in the presence of a peroxide initiator system, active at a temperature higher than 800 C, an expanding agent, and in the presence of:—an amide having the general formula R1CONHCH2—CH2NHCOR2 (I) a flame retardant system comprising a brominated additive with a bromine content higher than 30% by weight.
    Type: Application
    Filed: August 6, 2010
    Publication date: July 19, 2012
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Dario Ghidoni, Alessandra Simonelli, Antonio Ponticiello, Andrea La Piccirella
  • Publication number: 20120168986
    Abstract: Disclosed is a blown rigid semi-flexible urethane material that is loaded by using a wide variety of filler materials which become encapsulated in the urethane matrix. Disclosed are sample formulation and material variations, possible products that can be manufactured from the material, and possible material processing options and methods of manufacturing the material. Disclosed are possible methods of molding the material including a new cost effective method of molding variations of many interior and exterior products.
    Type: Application
    Filed: December 29, 2010
    Publication date: July 5, 2012
    Inventors: Kenneth J. Warnshuis, Felipe R. Terrones, Daniel M. Morris
  • Publication number: 20120141385
    Abstract: A composition including an effective amount of trans-1,3,3,3-tetrafluoropropene component combined with an effective amount of an alcohol selected from the group of methanol, ethanol, propanol, isopropanol, tert-butanol, isobutanol, 2-ethyl hexanol and any combination thereof, where the composition has azeotropic properties.
    Type: Application
    Filed: February 13, 2012
    Publication date: June 7, 2012
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: Jim M. BOWMAN, David J. WILLIAMS, Rajiv R. SINGH, Hang T. PHAM, Justin L. BECKER
  • Publication number: 20120136081
    Abstract: The present invention relates to a biocompatible, resorbable polyurethane foam wound cover with open pores and an adjustable resorption rate having improved properties when used on skin or connective tissue wounds as well as a method of production of such a polyurethane foam wound cover.
    Type: Application
    Filed: August 3, 2010
    Publication date: May 31, 2012
    Applicant: NOLAX AG
    Inventors: Jessica Blume, Stephan Buser, Andreas Dobmann, Erika Zimmermann
  • Publication number: 20120122745
    Abstract: Various esterified alkyl ketal ester or hydroxyalkyl ketal ester products are useful as components of organic polymer compositions. The ketal esters are produced in certain transesterifications between alkyl ketal esters and/or hydroxyalkyl ketal esters and polyols, aminoalcohols, polyamines and/or polycarboxylic acids. The products are excellent plasticizers for a variety of organic polymers, notable poly(vinyl chloride) plastisols. The products are also very good lubricants for many lubrication applications.
    Type: Application
    Filed: December 21, 2011
    Publication date: May 17, 2012
    Applicant: SEGETIS, INC.
    Inventors: Brian D. MULLEN, Chunyong WU, Tara J. MULLEN, Marc D. SCHOLTEN, Vivek BADARINARAYANA
  • Publication number: 20120088854
    Abstract: The present invention provides pre-expanded polypropylene resin beads comprising (A) a glycerin monoester of a C6 to C24 fatty acid and/or a polyglycerin monoester of a C6 to C24 fatty acid and (B) a glycerin diester of a C6 to C24 fatty acid(s) and/or a polyglycerin diester of a C6 to C24 fatty acid(s), in such a manner that a weight ratio [=(A)/(B)] between (A) and (B) in the polypropylene resin particles is 1.3 or more but 10 or less, and a total content [=(A)+(B)] is 0.3 parts by weight or more but 5 parts by weight or less with respect to 100 parts by weight of the polypropylene resin. The resin particles can be excellently used in in-mold foaming, without requiring washing with a chemical like nitric acid or methaphosphate soda, and can provide a polypropylene resin in-mold foamed product with good antistatic properties.
    Type: Application
    Filed: June 17, 2010
    Publication date: April 12, 2012
    Applicant: KANEKA CORPORATION
    Inventor: Taro Kiguchi
  • Publication number: 20120077893
    Abstract: Premixes suitable for the production of membrane materials are described. Products of this invention are suitable for the formation of membranes and membrane modules that may be in the form of flat sheets, tubes, or hollow fibers.
    Type: Application
    Filed: March 26, 2010
    Publication date: March 29, 2012
    Applicant: ISP INVESTMENTS INC.
    Inventor: David K. Hood
  • Publication number: 20120071575
    Abstract: Surfaces of thermoplastic articles are rendered microporous by contacting the surface with a composition that includes a solvent. The article has a birefringence of 0.0001 or greater and the composition has a solvent strength configured to swell but not dissolve the polymer.
    Type: Application
    Filed: August 25, 2011
    Publication date: March 22, 2012
    Inventors: Michael Edward DeRosa, Mircea Despa
  • Publication number: 20120070545
    Abstract: A method and system for oxygen molecule scavenging is disclosed. The system employs as an amphiphilic dendritic polymer as the reducing agent for oxygen molecules in a thermoplastic compound. Clarity of the compound, nearly the same as thermoplastic matrix itself in the compound, is achieved by the addition of an epoxy-functional styrene-acrylate oligomer. Food and beverage containers now made of polyethylene terephthalate can be molded from the compound and have substantially the same haze as the polyethylene terephthalate itself but with the oxygen scavenger to maintain freshness of the food or beverage from oxidation.
    Type: Application
    Filed: May 17, 2010
    Publication date: March 22, 2012
    Applicant: POLYONE CORPORATION
    Inventors: Ling Hu, Roger W. Avakian
  • Patent number: 8119701
    Abstract: Disclosed is a method for making polystyrene foam which utilizes one or more atmospheric gases, particularly combinations of HFCs and CO2, as the blowing system in combination with a polymer processing aid (PPA), typically an ester that is relatively non-volatile at the extrusion temperature range. The blowing system and the PPA may both be introduced into the molten thermoplastic polystyrene resin or the PPA may be incorporated in the solid source polystyrene resins. The resulting foams will typically exhibit improved dimensional stability at ambient temperatures.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: February 21, 2012
    Assignee: Owens Corning Intellectual Capital, LLC
    Inventors: Yadollah Delaviz, Bharat Patel, Mark Polasky, Raymond M. Breindel, Roland R. Loh, Mitchell Z. Weekley
  • Publication number: 20120035286
    Abstract: The invention relates to polymer mixtures comprising at least one polymer, at least one organic halogenated compound such as halogenated flame retardants and also at least one further compound to thermally stabilize the organic halogenated compound, this further compound having a saponification number of 80 to 300 mg KOH/g and an OH number of 200 to 800 mg KOH/g.
    Type: Application
    Filed: August 4, 2011
    Publication date: February 9, 2012
    Applicant: BASF SE
    Inventors: Ingo Bellin, Klaus Hahn, Gregor Haverkemper, Horst Fischer
  • Publication number: 20120029102
    Abstract: Systems for bone fracture repair are disclosed. One system includes a biocompatible putty that may be packed about a bone fracture to provide full loadbearing capabilities within days. The disclosed putties create an osteoconductive scaffold for bone regeneration and degrade over time to harmless 5 resorbable byproducts. Fixation devices for contacting an endosteal wall of an intramedullary (IM) canal of a fractured bone are also disclosed. One such fixation device includes a woven elongated structure fabricated from resorbable polymer filaments. The woven elongated structure has resilient properties that allow the woven 10 structure to be radially compressed and delivered to the IM canal using an insertion tube. When the insertion tube is removed, the woven structure expands towards its relaxed cross-sectional width to engage the endosteal wall. The woven elongated structure is impregnated with a resorbable polymer resin that cures in situ, or in the IM canal.
    Type: Application
    Filed: July 24, 2009
    Publication date: February 2, 2012
    Inventors: John Rose, Charles C. Martin
  • Publication number: 20120010307
    Abstract: The invention provides a composition and process for producing expandable beads from a compostable or biobased thermoplastic polymer. A key aspect of this invention is the ability to incorporate sufficient amounts of hydrocarbon blowing agent into the matrix of the compostable or biobased polymer. The following process may be used. First, the raw materials of compostable or biobased polymers, hydrophobic additive, and other additives are mixed by melt processing techniques. Next, a hydrocarbon blowing agent is added to the admixture, either by addition into the melt or by impregnation into the solid, to produce an expandable bead. Small, lightweight, foamed beads are produced by heating the expandable bead. Then, the expanded beads are subsequently used in conventional operations for molding into foamed articles.
    Type: Application
    Filed: July 7, 2011
    Publication date: January 12, 2012
    Applicant: Lifoam Industries
    Inventors: Adam R. Pawloski, Jeffrey J. Cernohous, Kent Kaske
  • Publication number: 20120010309
    Abstract: Disclosed is a polyol composition comprising an aliphatic polyester polyol having a hydroxyl value of less than about 100 and prepared by the reaction of at least a polycarboxylic acid with a polyhydroxy compound; an aromatic polyester polyol; a Novolac-type polyether polyol; and a hydrofluorocarbon blowing agent; that may be storage-stable for at least 60 days. This composition may be reacted with a polyisocyanate at an isocyanate index of from about 2.5 to about 4 to form a rigid poly-isocyanurate foam. The foam shows improved cohesion in general and also improved adhesion and a reduced incidence of voids when applied to a metal substrate.
    Type: Application
    Filed: March 16, 2010
    Publication date: January 12, 2012
    Applicant: DOW GLOBAL TECHNOLOGIIES LLC
    Inventors: Paolo Golini, Francesca Pignagnoli
  • Publication number: 20120004299
    Abstract: This invention relates to azeotrope-like compositions, methods and systems having utility in numerous applications, and in particular, uses for azeotrope-like compositions comprising effective amounts of the compound cis-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzzm), which has the following structure: and another material selected from the group consisting of water, fluoroketones, alcohols, hydrochlorofluoroolefins, and combinations of two or more thereof. These compositions may be used in a wide variety of applications such as, blowing agents, refrigerants, heating agents, power cycle agents, cleaning agents, aerosol propellants, sterilization agents, lubricants, flavor and fragrance extractants, flammability reducing agents, and flame suppression agents.
    Type: Application
    Filed: December 14, 2010
    Publication date: January 5, 2012
    Applicant: Honeywell International Inc.
    Inventors: Ryan Hulse, Rajiv Ratna Singh, Martin R. Paonessa, Hang T. Pham, Mary Bogdan, Cliff Gittere, Martin Cheney, Linda L. Cheney
  • Publication number: 20120004334
    Abstract: The present invention discloses polyol formulations containing a polyester polyol having a functional of 2.5 to 4; an aromatic amine polyol and a polyether polyol having a functionality of 6 to 8. The polyol mixture are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.
    Type: Application
    Filed: March 8, 2010
    Publication date: January 5, 2012
    Applicant: Dow Global Technologies LLC
    Inventor: Hans Kramer
  • Patent number: 8084511
    Abstract: The invention is a flame retardant for styrene foams. The flame retardant contains both aromatic bromine and an olefin. The olefin is an internal olefin. Desirable flame retardants are selected from: formula I: wherein R1 is C1-C6 and optionally containing a heteroatom or olefin; R2 is C1-C6 and optionally containing a heteroatom or olefin; and R3-R12 is H, C1-C6 (optionally containing a heteroatom), or halogen; and further wherein the compound of formula I is present in a concentration of at least 50 percent of a trans isomer; formula II: wherein R1 is Halogen, C1-C6 and optionally containing a heteroatom or olefin; R2 is Halogen, C1-C6 and optionally containing a heteroatom or olefin; and R3-R7 is H, C1-C6 (optionally containing a heteroatom), or halogen; and formula III: wherein R1 is Halogen, C1-C6 and optionally containing a heteroatom or olefin; R2 is Halogen, H, C1-C6 and optionally containing a heteroatom or olefin; and R3-R6 is H, halogen.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: December 27, 2011
    Assignee: Chemtura Corporation
    Inventors: Mark V. Hanson, Stephen B. Falloon, Wayne Meyer
  • Publication number: 20110313069
    Abstract: In a flame-retarded foamable styrene-based resin composition comprising a bromine-containing flame retardant, the flame retardant is a mixture of (a) an organic bromine-containing compound having a 2,3-dibromopropyl group or an organic bromine-containing compound having a bromine content of greater than 60 wt % in which all bromine atoms are attached to a benzene ring, and (b) an organic bromine compound having a 2,3-dibromo-2-alkylpropyl group. The composition comprises this mixture in amount from 0.5 to 10 parts by weight per 100 parts by weight of the styrene-based resin. The composition exhibits high flame retardant and heat stabilizing effects yet allowing recycling.
    Type: Application
    Filed: April 2, 2011
    Publication date: December 22, 2011
    Inventors: Hideaki Onishi, HIsanori Semori, Masashi Asaoka
  • Publication number: 20110309288
    Abstract: Provided are azeotrope or azeotrope-like compositions comprised of E-1-chloro-3,3,3-trifluoropropene (HCFO-E-1233zd) and isopropanol, and uses thereof.
    Type: Application
    Filed: January 13, 2010
    Publication date: December 22, 2011
    Applicant: ARKEMA INC.
    Inventors: Benjamin Bin Chen, Laurent Abbas, Philippe Bonnet
  • Patent number: 8080592
    Abstract: Extruded polymer foams are prepared using brominated fatty acids, an ester, amide or ester-amide of a brominated fatty acid, a glyceride of one or more brominated fatty acids, or a polymerized brominated fatty acid as an FR additive. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the foams.
    Type: Grant
    Filed: October 8, 2008
    Date of Patent: December 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: William J. Kruper, Jr., David R. Arrowsmith, Duane R. Romer, Bruce M. Bell, William G. Stobby, Inken Beulich, Zenon Lysenko, John Gordon-Duffy, Chau V. Vo
  • Publication number: 20110288192
    Abstract: The present invention relates to blowing agent compositions comprising tetrafluoropropene (HFO) and at least one co-blowing agent selected from carbon dioxide, water, alkanes and an alcohol used in the preparation of foamable thermoplastic compositions having low density. The HFOs include, but are not limited too, cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), 2,3,3,3-tetrafluoropropene (HFO 1234yf), or mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved R value.
    Type: Application
    Filed: January 28, 2010
    Publication date: November 24, 2011
    Applicant: Arkema Inc.
    Inventor: Brett L Van Horn
  • Publication number: 20110263730
    Abstract: Provided are: a manufacturing method for polymer particles, including: mixing a polymer solution, which is obtained by dissolving a polymer in a good solvent, and a polymer non-solvent, which is a non-solvent for the polymer and has compatibility with the good solvent, in a continuous or intermittent manner; and allowing a mixed solution of the polymer solution and the polymer non-solvent to flow down through a tubular body provided substantially vertically, thereby completing the precipitation of polymer particles; and a manufacturing apparatus for polymer particles. The manufacturing method enables the manufacture of polymer particles which have a relatively narrow particle diameter distribution even when the polymer particles are kept in a dispersion solution state.
    Type: Application
    Filed: September 28, 2009
    Publication date: October 27, 2011
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Tadatoshi Aridomi, Yukihiko Asano, Junya Takahashi, Tatsuya Shoji, Shyusei Ohya
  • Publication number: 20110263731
    Abstract: There is provided an expandable phenolic resin composition comprising: a phenolic resin; an acid curing catalyst for the resin; a foaming agent; and a surfactant, wherein the foaming agent comprises a hydrocarbon-based foaming agent; and the surfactant is a polyoxyethylene alkyl ether having an alkyl ether moiety having 14 to 22 carbon atoms, and the content of the surfactant is 0.01 to 10 parts by weight relative to 100 parts by weight of the phenolic resin.
    Type: Application
    Filed: November 4, 2009
    Publication date: October 27, 2011
    Applicant: ASAHI KASEI CONSTRUCTION MATERIALS CORPORATION
    Inventors: Takatoshi Kitagawa, Hisashi Mihori, Yoshihito Fukasawa
  • Publication number: 20110257282
    Abstract: Disclosed herein is a sealer and inflator composition, comprising: a concentrate; and a propellant/inflator comprising tetrafluoropropene. Also disclosed is a container comprising the sealer and inflator composition as well as a method for using the sealer and inflator composition to inflate an inflatable object.
    Type: Application
    Filed: April 19, 2011
    Publication date: October 20, 2011
    Applicant: HONEYWELL INTERNATIONAL, INC.
    Inventor: Mark Veselinovich Alexander
  • Patent number: 8030366
    Abstract: The invention relates to the use of polyethers containing urethane or urea groups as foam stabilizers, obtained by reacting at least one isocyanate with (a) at least one hydrophilic polyether which statistically carries at least one OH and/or NH2 and/or NH function and (b) at least one hydrophobic polyether which statistically carries at least one OH and/or NH2 and/or NH function and optionally (c) further compounds which carry at least one OH and/or NH2 and/or NH function and/or other isocyanate-reactive groups, such as carboxyl or epoxide functions, with the proviso that at least one isocyanate is ?difunctional.
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: October 4, 2011
    Assignee: Evonik Goldschmidt GmbH
    Inventors: Michael Ferenz, Christian Eilbracht, Jutta Esselborn, Sascha Herrwerth, Gabriele Platte
  • Publication number: 20110237691
    Abstract: A cured porous phenolic resin is provided that can be made by cross-linking a phenol-formaldehyde pre-polymer in the presence of a pore former, preferably ethylene glycol. The resin may be formed in situ by condensing a phenol with or without modifying agents and with cross-linking agent by pouring partially cross-linked resin into hot oil, in which case mesoporous resin beads are obtained. The resulting resin has mesopores observable in carbon derived from said resin by a pore structure of said derived carbon that comprises mesopores of diameter of 20-500 ?, as estimated by nitrogen adsorption porosimentry, the value for the differential of pore volume V with respect to the logarithm of pore radius R (dV/d log R) for the mesopores being greater than 0.2 for at least some values of pore size in the range 20-500 ?. Microporous beads of the resin may be carbonized into mesoporous carbon beads.
    Type: Application
    Filed: April 29, 2011
    Publication date: September 29, 2011
    Inventors: Stephen Robert TENNISON, Oleksundr Prokopovych KOZYNCHENKO, Volodymyr Vasyljovych STRELKO, Andrew John BLACKBURN
  • Publication number: 20110213044
    Abstract: Polystyrene is dispersed into a polyol via a mechanical dispersion process. A stabilizer is present to stabilize the dispersed polymer particles. The stabilizer includes a copolymer of (1) from 10 to 70% by weight of a branched polyol which has a molecular weight of from 4000 to 20,000, from 0.2 to about 1.2 polymerizable ethylenically unsaturated groups per molecule and from about 3 to about 8 hydroxyl groups per molecule with (2) from 30 to 90% by weight of styrene or a mixture of styrene and one or more other low molecular weight monomers.
    Type: Application
    Filed: June 18, 2009
    Publication date: September 1, 2011
    Inventors: Hanno R. Van der wal, Ronald Wevers, Freddy Van Damme, Francois M. Casati, Georges Kanaan, Fernand Pla, Sandrine Hoppe, Bart Noordover
  • Patent number: 7994229
    Abstract: The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 ?m and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: August 9, 2011
    Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.
    Inventors: Katsushi Miki, Toshiaki Masuda, Ichiro Takahara, Takashi Fujie, Ikuo Yosejima
  • Publication number: 20110190405
    Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, a polystyrene/polyethylene oxide copolymer, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the blowing agent includes at least one hydrofluorocarbon blowing agent. The maleic anhydride-styrene copolymer grafted with polyethylene oxide provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid.
    Type: Application
    Filed: January 29, 2010
    Publication date: August 4, 2011
    Inventors: Yadollah Delaviz, Raymond M. Breindel, Mitchell Z. Weekley, John F. Budinscak
  • Publication number: 20110189484
    Abstract: A porous polybenzimidazole (PBI) particulate resin is disclosed. This resin is easily dissolved at ambient temperatures and pressures. The resin is made by: dissolving a virgin PBI resin in a highly polar solvent; precipitating the dissolved PBI in a bath; and drying the precipitated PBI, the dried precipitated PBI being porous. The porous PBI resin may be dissolved by: mixing a porous PBI resin with a highly polar solvent at ambient temperatures and pressures to form a solution.
    Type: Application
    Filed: January 27, 2011
    Publication date: August 4, 2011
    Inventors: John B. Hopkins, JR., Karin M. Hudson, Gregory S. Copeland, Michael Gruender
  • Publication number: 20110189461
    Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an additive blend of polyethylene oxide and a copolymer of polystyrene and maleic anhydride, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the polyethylene oxide is ethoxylated polyethylene oxide. Additionally, in at least one embodiment, the blowing agent includes at least one hydrofluorocarbon blowing agent. The blend of ethoxylated polyethylene oxide and copolymer of polystyrene and maleic anhydride provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product and increases the average cell size of the foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the additive acts as a cell enlarger, a water vapor permeability enhancer, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.
    Type: Application
    Filed: January 29, 2010
    Publication date: August 4, 2011
    Inventors: Yadollah Delaviz, Raymond M. Breindel, John F. Budinscak, JR.
  • Publication number: 20110178193
    Abstract: To provide a method for easily producing an ethylene/tetrafluoroethylene copolymer porous material having excellent chemical resistance and filtration performance and has a high heat resistance, within a wide range of the porosity, and an ethylene/tetrafluoroethylene copolymer porous material obtained by such a process. A process for producing an ethylene/tetrafluoroethylene copolymer porous material which comprises a step of dissolving an ethylene/tetrafluoroethylene copolymer having repeating units based on ethylene and repeating units based on tetrafluoroethylene at a temperature of at most 300° C. in a solvent which can dissolve the ethylene/tetrafluoroethylene copolymer at a temperature of at most 300° C., to achieve a predetermined concentration to obtain a solution, a step of forming the solution to obtain a formed product, and a step of cooling the formed product to a temperature of at most the phase separation temperature of the solution to solidify the ethylene/tetrafluoroethylene copolymer.
    Type: Application
    Filed: March 25, 2011
    Publication date: July 21, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Ken IRUYA, Takashi Nakano, Tomoyuki Fujita, Yoshitomi Morizawa