Abstract: A composition useful in producing an open-cell, elastomeric silicone foam combines a silicone oil-in-water emulsion, which forms an elastomer upon removal of the water, with an aerosol propellant. When the composition is discharged to atmospheric pressure, a froth is formed. Removing water from the froth yields an open-cell foam. The froth is stabilized by surfactants, thickeners, or froth stabilizers selected from fibers or lauryl alcohol.

Abstract: Novel fluorine-containing polyorganosiloxanes comprise repeating units of the formula [F(CF.sub.2).sub.m (CH.sub.2).sub.n ].sub.p SiO.sub.(4-p)/2, R.sub.3 SiO.sub.1/2 and SiO.sub.4/2 where R represents a monovalent hydrocarbon radical containing from 1 to 20 carbon atoms, m has an average value from 1 to 20, n is 1 or 2 and p is 1, 2 or 3. The polyorganosiloxanes are particularly useful as stabilizers for foams prepared by introducing gaseous blowing agents into liquid polydimethylsiloxanes.

Abstract: Polyorganosiloxane foams are prepared by the volatilization of a blowing agent within a polyorganosiloxane composition that is curable by a hydrosilation reaction and includes as a foam stabilizer a resinous polyorganosiloxane comprising trimethylsiloxy units, SiO.sub.4/2 units and a specified class of fluorine-containing siloxane units.

Abstract: The present invention relates to a flame-retardant polyolefin foam comprising a polyolefinic thermoplastic resin consisting mainly of a homopolymer of .alpha.-olefin or copolymer of .alpha.-olefins having 2 to 10 carbon atoms; 2 to 10 percent by weight as bromine content, based on the weight of the foam, of a bisphenol A-based brominated epoxy resin or a crosslinked product thereof; and 0 to 25 percent by weight, based on the weight of the foam, of an inorganic filler. The foam of the present invention has superior flame retardancy and thermoformability in addition to the superior heat insulating property and shock absorbing property of the polyolefin foam, and because of these superior characteristics it is useful as an automotive interior material, etc.

Abstract: Elastomer compositions are provided which contain high molecular weight water-insoluble humic acid humates. The compositions show improved bloom resistance in both the uncured and the vulcanized or otherwise cured state. Methods to make sponge rubber are also disclosed in which the humic acid humate is the gas producing agent. A predominantly humic acid humate containing composition maintains a clean mold, and curing an uncured article coated with the humate at elevated temperature will clean metal molds which have dirty surfaces, particularly when green coated articles are vulcanized in contact with the mold's surfaces.

Abstract: Bis-crown-ether derivatives having such configuration that the two crown rings may easily overlap spatially, holding a potassium or the like ion between them, and ion-selective membranes used for said bis-crown-ether derivatives as neutral carrier, which are useful as an ion sensor and are superior to the ion-selective membrane containing valinomycin.

Abstract: Polyoxyalkylene surfactants for cellular foams can be prepared by reacting under free radical polymerization conditions a polyoxyalkylene adduct, a cyclic nitrogenous vinyl monomer and an esterified unsaturated dibasic acid in the presence of an organic or inorganic per-compound and a metal catalyst.

Abstract: A process for producing a resin foam by using an aqueous medium, which comprises(a) treating a resin compound with said aqueous medium to cause the aqueous medium to adhere to and be held by the resin compound, said resin compound being composed of porous agglomerated particles resulting from partial melt-adhesion of thermoplastic resin particles coated with a fine hydrophilic solid powder which does not substantially melt at the melting temperature of the resin particles, said solid powder being embedded in the resin particles but partly exposed at their surfaces,(b) melt-kneading the resin compound treated with the aqueous medium under such an elevated pressure that evaporation of the aqueous medium is substantially inhibited, and(c) thereafter releasing the kneaded resin composition from the pressurized state to foam it; and a thermoplastic resin compound used for the aforesaid process.

Abstract: A hydrophilized membrane of a porous hydrophobic material having micropores each defined by a surface at least part of which is coated with polyethylene glycol. Water is allowed to pass through the micropores. There is also disclosed a process for hydrophilizing such a porous hydrophobic membrane.

Abstract: A novel tire sealant and inflator composition comprising a resin, a latex sealant, alkylene glycol, fibers, an alkanolamine, a foaming agent, and water. The composition is packaged in aerosol cans with a chlorofluorocarbon propellant/inflator and used to seal and inflate punctured tires. The composition is applied to the punctured tire through the valve stem, and acts to seal the puncture and inflate the tire sufficiently to support the weight of the car.

Abstract: The flowability of foamable compositions comprising a hydroxyl-containing polyorganosiloxane, a polyorganosiloxane containing silicon-bonded hydrogen atoms, a platinum catalyst and a catalyst inhibitor is eliminated by including in the composition a solid filler exhibiting a mean particle size of one micron or less and either (1) organosilicon compound containing at least 0.5% by weight of carboxyl groups or silicon-bonded hydroxyalkyl groups, or (2) a partially esterified polyfunctional alcohol. In addition, the pot life of the composition is increased without adversely affecting the structure of the cured foam or the adhesion of the foam to various substrates.

Abstract: Composition which comprises a mixture of (A) a polydiorganosiloxane having a viscosity of from 200 to 100,000 cP at 25.degree. C. and having at least two silicon-bonded vinyl groups, (B) an organohydrogensiloxane, (C) a platinum catalyst, (D) a substance which inhibits the reaction between (A) and (B) in the presence of (C) e.g. an acetylenic alcohol, and (E) a blowing agent selected from p,p'-oxybis(benzenesulphonylhydrazide) and dinitrosopentamethylene tetramine.The composition can be converted by heat into an elastomeric sponge and is useful for the production of articles such as seat cushions, heat and sound insulation and shock absorbers.

Abstract: Styrenic foams are prepared with water as a blowing agent component and polyhydric alcohol as a corrosion inhibitor.

Abstract: A foamable ink composition which comprises a water-based printing ink, a foaming agent and a pseudoplastic additive. The ink, foaming agent and pseudoplastic additive are foamed with a compressed gas. The pseudoplastic additive aids in the mixing of the ink with the gas and enhances the stability of the foam. The foam is especially adapted for application to a gravure cylinder where it is doctored to convert the foam bubbles into thin discrete membranes spanning the gravure cells. These membranes then are transferred, either directly or indirectly to a moving web.

Abstract: A method for producing cross-linked polyethylene resin foams which comprises mixing a polyolefin resin, a blowing agent and, optionally, a surface active agent containing hydroxyl groups or an acid amide compound under pressure, said polyolefin resin containing a cross-linkable ethylene polymer having on the side chains thereof silyl groups which effect cross-linking upon contact with water; extruding the mixture into a low pressure zone where the extrudate is allowed to expand; and bringing the expanded extrudate into contact with a silanol condensing catalyst so that the expanded extrudate is cross-linked on contact with water.

Abstract: A rigid porous, deformation resisting, nonresilient inflexible thermoset resin foam having macroscopic open cells and the method of making the same. The method comprises foaming and partially curing a polyepoxide or polyurethane resin in which the cells are closed. The partially cured resin is softened by heating and then crushed to compress the cells to produce an open-celled product. The crushed foam is reexpanded and finally cured. The foam may be filled for strengthening with a filler such as carbon black before or after the final cure.

Abstract: Alkali metal polyester silicate resinous products are produced by mixing a polyhydroxy organic compound, an alkali metal silicate and a polycarboxylic acid, then heating the mixture to a temperature between the melting point of the polycarboxylic acid and the boiling temperature of the polyol while agitating until the reaction is complete.

Abstract: Process and apparatus are disclosed for manufacturing foamed articles such as tubes used as pipe insulation, which tubes are of a high impermeability and flexibility and are formed of a polymer, such as polyethylene or polypropylene, containing up to about 25% of an elastomer.

Abstract: Expandable styrene-maleic anhydride copolymer particles which comprises a copolymer resin obtained by reaction of a styrene-maleic anhydride copolymer with a hydroxy compound and further impregnated with a volatile blowing agent.

Abstract: An improved expandable polymeric styrene particle is provided containing a blowing agent, a minor amount of pentaerythritol tetrastearate, overcoated with a minor amount of glyceryl monostearate. The improved particle results in a significantly reduced final mold cooling cycle in producing the finished molded article. Pentaerythritol tetrastearate is preferably incorporated during impregnation with the blowing agent and glyceryl monostearate overcoated by blending with the expandable particles after impregnation.

Abstract: Mechanically stable styrene polymer foams having highly desirable physical properties are prepared employing as a blowing agent a mixture of lower alcohols with chlorofluoromethanes.

Abstract: A method of making light weight flame resistant structures from bonded polyimide macroballoons and products thereof. An aromatic tetracarboxylic acid dianhydride is reacted with an oxoimine to produce an N-substituted imide, which is then esterfied with a suitable alcohol. The resulting liquid is dried and the dry residue is reduced to a uniform powder having particles with diameters generally in the 0.5 to 10 mm. range. The powder is preferably further dried, either before or after final size reduction, in a moderate vacuum at moderate temperature to remove any excess residual alcohol. The powder spontaneously expands to form a closed cell foam when heated to a temperature in the range of about 90.degree. to 150.degree. C. for a suitable period. When the powder is expanded in a closed mold, a well consolidated, uniform, closed cell foam product results. The closed cell foam produced has excellent flexibility and resistance to heat and flame, and does not shrink appreciably when exposed to flame.

Abstract: An improved expandable polymeric styrene particle is provided containing a blowing agent, a minor amount of pentaerythritol tetrastearate, overcoated with a minor amount of glyceryl monostearate. The improved particle results in a significantly reduced final mold cooling cycle in producing the finished molded article. Pentaerythritol tetrastearate is preferably incorporated during impregnation with the blowing agent and glyceryl monostearate overcoated by blending with the expandable particles after impregnation.

Abstract: In producing a crosslinked polypropylene foam, 0.5 to 4 parts by weight of a compound selected from triacrylate and trimethacrylate of aliphatic polyhydric alcohol and a blowing agent are mixed with 100 parts by weight of propylene homopolymer or copolymer. Then, the mixture is shaped under heat, followed by irradiation with an ionizing radiation such that the dose of the radiation absorbed by the shaped mass ranges between 0.1 and 10 Mrad. Finally, the irradiated mass is heated for foaming.

Abstract: A composition for a crosslinked polyolefin foam is prepared from 20 to 75% by weight of a crystalline propylene copolymer containing 1 to 15% by weight of ethylene and having a crystallinity higher than 50% and 80 to 25% by weight of polyethylene.

Abstract: Mechanically stable styrene polymer foams having highly desirable physical properties are prepared employing as a blowing agent a mixture of lower alcohols with chlorofluoromethanes.

Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis(allyl ether) of tetrabromobisphenol A and a minor amount of dibromoethyldibromocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.

Abstract: Particulate absorbents of a water-insoluble water-swellable polymer having a gel capacity of at least 10 are immobilized with a composition comprising the absorbent in a liquid polyhydroxy organic compound. The composition may be employed by applying to an appropriate surface and subjecting the liquid film to solidifying conditions. The solidified film product has high absorptive capacity and is free of undesirable movement when positioned in absorbent articles.A foam product having both absorptive and cushioning properties is prepared from a solid, particulate, water-insoluble, water-swellable polymer having a gel capacity of at least 10, a solid, particulate blowing agent, and a liquid polyhydroxy organic compound. Foamable compositions and articles employing the foam are also described.

Abstract: A flame retardant thermoplastic polymer containing a flame retardant amount of a flame retardant additive mixture. The mixture is comprised of halogenated imide-containing polyols having the formula: ##STR1## and the corresponding ethers having the formula: ##STR2## wherein R is a hydrocarbon group having the valence n+2 and is selected from the group consisting of benzene groups, naphthalene groups and alicyclic hydrocarbon groups containing 5 to 10 carbon atoms, X is selected from the group consisting of bromine and chlorine, n is an integer from 1-6 and p is an integer from 2-6. The preferred flame retardant mixture is a derivative of tetrabromophthalic anhydride.

Abstract: A foam product having both absorptive and cushioning properties is prepared from a solid, particulate, water-insoluble, water-swellable polymer having a gel capacity of at least 10, a solid, particulate blowing agent, and a liquid polyhydroxy organic compound. Foamable compositions and articles employing the foam are also described.

Abstract: Mono- and polyazoformamide, sulfonyl hydrazide, sulfonyl semicarbazide and/or dinitrosomethylene amine compounds act as chemical blowing agents and curatives for carbon monoxide-containing ethylene copolymers.

Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis(allyl ether) of tetrabromobisphenol A and a minor amount of pentabromomonochlorocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.

Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis (allyl ether) of tetrabromobisphenol A and a minor amount of dibromoethyldibromocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.

Abstract: An improved process for the foaming of polyolefin materials is disclosed where the polyolefin is crosslinked by a peroxide and foamed by a chemical foaming agent combined with an auxiliary foaming agent is disclosed. According to the invention, the auxiliary foaming is a sterically hindered phenol and/or an organic phosphorus compound.

Abstract: A fluid transmitting polyolefin foam having a special open-cell cellular structure as compared with the conventional polyolefin foams having all cells closed is disclosed. Such a novel fluid transmitting polyolefin foam is produced by mixing a polyolefin with a polymer other than a polyolefin, said polyolefin and/or said polymer other than a polyolefin having a blowing agent incorporated therein and/or adhered thereto and subjecting the resulting mixture to extrusion moulding. The present fluid transmitting polyolefin foam has a wide variety of uses, for example, as a synthetic leather, synthetic filter cloth, separator of storage battery, synthetic paper, package, etc.

Abstract: This invention concerns sprayable emulsions of a foamable polymer in water which are useful as aerosol caulking or insulating compositions.

Abstract: Disclosed are self-extinguishing polystyrenic compositions with improved thermal stability properties, comprising a styrenic resin and a fire-retardant agent which can either comprise solely a brominated pentaerythritol having at least one free-OH group or such a compound in combination with a peroxide.

Abstract: Composition of matter adapted to be foamed into essentially a closed cell structure, preponderance of the cells being less than 500 microns in size and containing a chlorofluoroalkane of 1 to 2 carbon atoms, said composition comprising chlorinated polyvinyl chloride resin, and effective amount of a blowing agent, an effective amount of a nucleating agent, and 5 to 20 parts of a processing aid per 100 parts of said resin, said processing aid has a dilute solution viscosity of greater than 2.5 and is selected from copolymers of styrene and acrylonitrile containing 10 to 40% of acrylonitrile.

Abstract: Particulate styrene polymers which contain a blowing agent and are surface-coated with from 0.05 to 1% by weight of an ester. The coating agent is a hydroxycarboxylic acid ester, or an ester of a carboxylic acid with an oxyalkylated alcohol; tristearyl citrate is a preferred ester.The styrene polymers can be used to produce foam moldings, with short mold dwell times and good welding of the foam particles.

Abstract: Substantially closed-cell aliphatic olefin polymer foams having improved dimensional stability are provided by the inclusion therein of from 0.1 to 10 weight percent, based upon the olefin polymer, of certain higher aliphatic hydrocarbyl ether, ester or anhydride compounds.

Abstract: Disclosed is a self-extinguishing polystyrenic composition comprising a polystyrenic resin, a fire-retardant amount of a halogenated organic fire-retardant agent and a nitrogen-containing organic compound selected from the group consisting of amines, amides and ammonium compounds containing from 20 to 40 carbon atoms and their mixtures, said nitrogen-containing compound being used in an amount varying between 0.5 and 50% based on the weight of fire-retardant agent.

Abstract: The dimensional stability, especially at elevated temperatures such as 70.degree. C., of thermoplastic resin foams, such as those of aliphatic olefin polymers, is substantially improved by the inclusion therein of from 0.01 to 5 weight percent, based upon said resin, of certain benzylideneaniline derivatives, azobenzene derivatives, azooxybenzene derivatives and the like.

Abstract: A process is provided for preparing propellant compositions including a film-forming synthetic polymer that are capable of forming foamed structures containing open and/or closed cells, which may optionally contain a material which is deposited in the pores and/or walls of the structure as the structure is formed, which comprises coating the synthetic polymer in particulate form with an inert solid material insoluble in the propellant and in solutions of the synthetic resin the propellant at atmospheric temperature; and then adding the propellant and dissolving the synthetic polymer in the propellant.

Abstract: Copolymers of monovinyl aromatic monomers and the anhydrides of ethylenically unsaturated dicarboxylic acid monomers are blended with water as a blowing agent, bromodiphenylethers as fire retardants, and metal oxides as synergist for the ethers to form a composition which can be foamed to densities of between 1 and 10 pounds per cubic foot, said composition having fire retardant properties.

Abstract: Substantially closed-cell aliphatic olefin polymer foams having improved dimensional stability are provided by the inclusion therein of from 0.1 to 10 weight percent, based upon the olefin polymer, of certain higher aliphatic hydrocarbyl ether, ester or anhydride compounds.

Abstract: Copolymers of monovinyl aromatic monomers and ethylenically unsaturated monocarboxylic acid monomers are blended with water as a blowing agent, bromodiphenylethers as fire retardants, and metal oxides as synergist for the ethers to form a composition which can be foamed to densities of between 1 and 10 pounds per cubic foot, said foam composition having fire-retardant properties.

Abstract: Rubber-modified copolymers of monovinyl aromatic monomers and the anhydride of ethylenically unsaturated dicarboxylic acid monomers are blended with water as a blowing agent, bromodiphenylethers as fire retardants, and metal oxides as synergist for the ethers to form a composition which can be foamed to densities of between 1 and 10 pounds per cubic foot, said foam composition having fire-retardant properties.

Abstract: Terpolyimides prepared from tetracarboxylic acid esters and combinations of heterocyclic, aromatic, and aliphatic diamines and artifacts composed of those terpolymers. Precursors, and methods of converting them to the corresponding terpolymers.

Abstract: A molded article simulating the appearance of natural plantation crepe rubber and a method for producing this article. Styrene/butadiene linear or radial block copolymer having a polymerized styrene content of the range of about 20 to about 50 weight percent of the total block copolymer and resinous polymer of vinyl-substituted aromatic compound in the range of about 10 to about 60 parts resinous polymer per 100 parts block copolymer are blended with a sufficient amount of polarizing agent to achieve rapid heating through response to microwave treatment. The composition is melted, molded against a surface mirroring the appearance of plantation crepe rubber, and removed from the mold as an article simulating plantation crepe rubber.

Abstract: A thermoplastic synthetic resin such as polyethylene or ethylene-vinyl acetate copolymer resin containing 0.1 to 10 wt. % of a specific additive selected from specific classes of compounds, namely saturated higher fatty acid amides, saturated higher aliphatic amines and complete esters of saturated higher fatty acids is found to be very suitable for production of expanded articles and can be easily formed into expanded articles with little shrinkage after expansion, free from creases on the surface or cracks on the cell walls, and having excellent characteristics such as good closed cellular characteristic, high compressive strength, low density, etc.