Metal Atom Is Part Of An Organic Compound Patents (Class 521/93)
  • Patent number: 9713886
    Abstract: A cavity between inner and outer walls of an open-box-shaped mold is filled with a polyurethane reaction mixture, containing an isocyanate and an emulsion of an isocyanate-reactive composition with three polyols and a blowing agent, which is cured to a polyurethane containing polymer. The inner and outer wall are a fixed distance from one another and each wall comprises a bottom and sides. The mixture is fed through an inlet in the bottom of the outer wall. Before filling the cavity, the mold is turned downwards so that the mixture foams upwards, filling the cavity. The three polyols are polyether polyol obtained by adding an epoxy to carbohydrates or difunctional or higher-functional alcohols; polyether polyol obtained by adding an epoxy to an aromatic amine; and polyester polyether polyol obtained by adding an epoxy to the esterification product of an aromatic dicarboxylic acid derivative and a difunctional or higher-functional alcohol.
    Type: Grant
    Filed: February 20, 2014
    Date of Patent: July 25, 2017
    Assignee: Covestro Deutschland AG
    Inventors: Stephanie Vogel, Reinhard Albers, Michael Loof, Frank Otto
  • Patent number: 9000330
    Abstract: The present invention relates to a connecting apparatus used for connecting underground pipes and to a composition for preparing a foamed sheet for the same. Specifically, the present invention relates to a sheet composition for pipe connection which comprises 1 to 10 parts by weight of a masterbatch including low-density polyethylene, high-density polyethylene, a maleic anhydride graft copolymer, a metallocene polyethylene elastomer, a foaming agent, and an additive, based on 100 parts by weight of a base resin including low-density polyethylene, high-density polyethylene, a maleic anhydride graft copolymer, and a metallocene polyethylene elastomer. When using the composition according to the present invention, a non-foamed sheet is produced during melt extrusion, and a foamed sheet is obtained at a high temperature by laminating the non-foamed sheet with a heater line and applying electricity thereto. Therefore, the sheet composition can be fused and filled into a pipe.
    Type: Grant
    Filed: November 17, 2010
    Date of Patent: April 7, 2015
    Inventor: Soo Young Joo
  • Publication number: 20140034864
    Abstract: A fire-extinguishing and/or fire-inhibiting composition is based on polymers capable of swelling. In order to bind fumes containing fluorine and/or phosphorous, for example in the event of fires of lithium-ion batteries, the composition includes at least one alkaline-earth carboxylate, in particular calcium carboxylate, of one or more carboxylic acids.
    Type: Application
    Filed: February 6, 2012
    Publication date: February 6, 2014
    Applicants: Samsung SDI Co., Ltd., Robert Bosch GmbH
    Inventors: Rainer Kern, Thomas Woehrle
  • Publication number: 20130338246
    Abstract: Provided are (i) polyethylene resin foamed particles which are obtained by foaming polyethylene resin particles to be foamed having good productivity and a high expansion ratio and which are suppressed in reduction of cell diameters, and (ii) a polyethylene resin in-mold foam molded article obtained from the polyethylene resin foamed particles which has good surface smoothness while being reduced in surface yellowing. The polyethylene resin foamed particles (i) contain, as a base resin, a polyethylene resin composition containing, in an amount of not less than 1000 ppm to not more than 4000 ppm in total, one or more compounds selected from the group consisting of antioxidants, metal stearates, and inorganic substances and (ii) have Z-average molecular weight of not less than 40×104 to not more than 70×104, an average cell diameter of not less than 180 ?m to not more than 450 ?m, and an open-cell ratio of not more than 12%.
    Type: Application
    Filed: March 2, 2012
    Publication date: December 19, 2013
    Applicant: KANEKA CORPORATION
    Inventor: Toru Yoshida
  • Patent number: 8563621
    Abstract: The present invention relates to the preparation and use of a blowing agent in the form of of nanoparticles of an inorganic carbonate, and an acid. The acid is capable of being liquefied by heating to be reactive with the carbonate to release carbon dioxide that is useful as a blowing agent in all types of organic foams. The blowing agent, optionally pelletized in a suitable polymer carrier, is useful as a heat-activated blowing agent additive in polymer compositions.
    Type: Grant
    Filed: April 21, 2010
    Date of Patent: October 22, 2013
    Assignee: Polyfil Corporation
    Inventor: Renee M. Lapierre
  • Publication number: 20130274349
    Abstract: The present invention relates to an open-celled foam comprising: (a) an aqueous-based polymer dispersion, said polymer dispersion comprising a polyethylene copolymer and an ethylene-acrylic acid copolymer; and (b) from about 5% to about 15% of a foaming composition, said foaming composition comprising at least a foaming agent and a stabilizing agent; further comprising a particulate superabsorbent polymer material within the voids and pores of said open-celled foam and the method of making the same.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 17, 2013
    Inventors: Jian Qin, Deborah Calewarts, Charles W. Colman, Jenny L. Day, Cathleen M. Uttecht
  • Publication number: 20130082413
    Abstract: A foaming composition for filling and sealing includes a polymer, azodicarbonamide, a fatty acid metal, and a basic magnesium carbonate.
    Type: Application
    Filed: October 4, 2012
    Publication date: April 4, 2013
    Applicant: NITTO DENKO CORPORATION
    Inventor: NITTO DENKO CORPORATION
  • Publication number: 20130018116
    Abstract: An object is to provide a resin foam sheet having good reformability, and a method for easily producing such a resin foam sheet. Provided are a resin foam sheet formed by extrusion foaming with an extruder a polypropylene-based resin composition mainly composed of a polypropylene-based resin component containing a polypropylene-based resin and a high melt tension polypropylene resin having a higher melt tension than that of the polypropylene-based resin, wherein the high melt tension polypropylene resin has a melt tension after being passed through the extruder of 4 cN or more and 10 cN or less, and a rate at breakage after being passed through the extruder of 12 m/min or higher and 26 m/min or lower, and the like.
    Type: Application
    Filed: February 25, 2011
    Publication date: January 17, 2013
    Applicant: SEKISUI PLASTICS CO., LTD.
    Inventors: Tadakazu Anan, Toshiyuki Oonishi
  • Publication number: 20120273474
    Abstract: The present invention relates to a connecting apparatus used for connecting underground pipes and to a composition for preparing a foamed sheet for the same. Specifically, the present invention relates to a sheet composition for pipe connection which comprises 1 to 10 parts by weight of a masterbatch including low-density polyethylene, high-density polyethylene, a maleic anhydride graft copolymer, a metallocene polyethylene elastomer, a foaming agent, and an additive, based on 100 parts by weight of a base resin including low-density polyethylene, high-density polyethylene, a maleic anhydride graft copolymer, and a metallocene polyethylene elastomer. When using the composition according to the present invention, a non-foamed sheet is produced during melt extrusion, and a foamed sheet is obtained at a high temperature by laminating the non-foamed sheet with a heater line and applying electricity thereto. Therefore, the sheet composition can be fused and filled into a pipe.
    Type: Application
    Filed: November 17, 2010
    Publication date: November 1, 2012
    Inventor: Soo Young Joo
  • Publication number: 20120178838
    Abstract: The invention is related to an elastomer composition comprising an elastomeric polymer comprising ethylene and ?-olefin derived units, a curing package and a blowing agent wherein the blowing agent comprises a compound containing water of crystallization. The invention also relates to a process for the manufacture of a foamed article comprising the steps of preparing an elastomeric composition, shaping, foaming and curing the elastomeric composition. The invention further relates to a foamed article.
    Type: Application
    Filed: September 23, 2011
    Publication date: July 12, 2012
    Applicant: LANXESS Elastomers B.V.
    Inventor: Peter Wilbert Leonie Jeanette Meijers
  • Publication number: 20120045603
    Abstract: The invention relates to a foamed fluoropolymer, preferably a polyvinylidene fluoride (PVDF) structure, such as from Kynar® resins. The foamed structure is continuous self-supporting, sized, and has a dense skin. The foamed structure is manufactured in a process using foaming agents and nucleating agents. The structure is sized into a specific shape during the manufacturing process—requiring a good melt viscosity of the PVDF foam. In one process, a master batch containing the nucleating agent is used. The foamed article could be a sheet, film, profile, tube, pipe, article, rod foam-core structure, or other self-supporting shape. Foamed tubes, pipes, rods, sheets and conduit are especially useful. The foamed structure of the invention provides added value by being lighter weight, more flexible, and more impact resistant than a comparable non-foamed PVDF structure. It also has increased hysteresis, increased insulation properties, reduced dielectric constant, and increased compressibility.
    Type: Application
    Filed: April 22, 2010
    Publication date: February 23, 2012
    Applicant: Arkema Inc.
    Inventors: Saeid Zerafati, Sean M. Stabier
  • Publication number: 20110263732
    Abstract: A foam precursor mixture of polylactic acid (PLA) resin having a D-lactic acid content that is about 3 mole % or less; nucleating agent; chain extender; and hydrocarbon blowing agent is provided. The foaming mixture is substantially free of a crosslinking agent. The foam premixture can be used to prepare PLA foams having improved heat resistance, lower densities, smaller cells, and higher cell counts. PLA foams in accordance with the invention may be useful for preparing thermoformed articles such as trays. PLA foamed articles may be prepared that exhibit heat resistance above a temperature of about 49° C. or more, and in particular, a heat resistance at 5 minutes of exposure in excess of about 74° C.
    Type: Application
    Filed: April 22, 2010
    Publication date: October 27, 2011
    Inventors: Natarajan S. Ramesh, A. Victoria Nawaby, Nilesh Amrutiya
  • Publication number: 20110230108
    Abstract: A process for preparing polymers, especially multi-block copolymer containing therein two or more segments or blocks differing in chemical or physical properties, by contacting propylene, 4-methyl-1-pentene, or other C4-8 ?-olefins and one or more copolymerizable comonomers, especially ethylene in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
    Type: Application
    Filed: April 19, 2011
    Publication date: September 22, 2011
    Applicant: Dow Global Technologies LLC
    Inventors: Daniel J. Arriola, Edmund M. Carnahan, David D. Devore, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel
  • Publication number: 20110196055
    Abstract: A process for preparing a cavity-filling, fast-gelling closed cell rigid polyurethane foam comprises preparing a formulation including at least a polyisocyanate, a relatively high viscosity polyol system including at least about 10 percent by weight of an amine-initiated polyol, a physical blowing agent, a blowing catalyst and a curing catalyst, and, optionally, less than about 1.6 weight percent of water based on the polyol system. Other conventional components, such as a chain extender and/or crosslinker, surfactant, and the like may also be included. The formulation is injected under a reduced atmospheric pressure to achieve a closed cell, rigid polyurethane foam having a density of less than about 40 kg/m3, an average cell diameter of less than about 250 microns, and a thermal conductivity of less than about 19 mW/mK at 10° C. average plate temperature.
    Type: Application
    Filed: October 20, 2009
    Publication date: August 11, 2011
    Applicant: Dow Global Technologies LLC
    Inventors: Hans Kramer, Vanni Parenti
  • Publication number: 20110172320
    Abstract: The density of rigid foamed articles made by the thermal decomposition of a blowing agent in a vinyl chloride polymer is reduced by the use of a tin based blowing agent activator(s). The tin based activator also reduces the activation temperature of a chemical blowing agent, allowing for more optimal evolution of gas during plastic processing. Dibutyl tin oxide or tin maleates are superior activators of vinyl chloride polymer blowing agents.
    Type: Application
    Filed: September 16, 2009
    Publication date: July 14, 2011
    Applicant: Arkema Inc.
    Inventor: Paul R. Lavallee
  • Publication number: 20110152392
    Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.
    Type: Application
    Filed: December 14, 2010
    Publication date: June 23, 2011
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: MICHAEL VAN DER PUY, DAVID John WILLIAMS, CLIFFORD P. GITTERE
  • Patent number: 7939573
    Abstract: Provided is a modified blowing agent, wherein the surface of a blowing agent powder is coated with a metallic siloxylated compound. When the modified blowing agent is included in a polymer resin, dispersibility of the modified blowing agent is excellent in the polymer resin and fluidity of the polymer resin is improved in an extrusion molding machine and an injection molding machine, and thus productivity and processability can be improved. In addition, the foam that is formed using the polymer resin composition including the modified blowing agent has excellent tear strength, durability, and masking sound properties due to fine and uniform size of foam cells and increased number of foam cells per unit surface area.
    Type: Grant
    Filed: October 16, 2007
    Date of Patent: May 10, 2011
    Assignee: J & J Chemical Co.
    Inventors: Yong Yon Jo, Heung Oh Son
  • Patent number: 7915318
    Abstract: A water soluble ROMP catalyst, which has high catalytic efficiency for ring opening metathesis is use in the preparation of polymeric blends for use in monolithic columns. In one embodiments a method for making a polymeric blend is discolosed comprising reaction of a water-soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor, and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support. In another embodiment a monolithic bed is disclosed comprising the water-soluble ROMP catalyst immobilized on a surface of a solid support. Also disclosed is a monolithic bed comprising: a polymer blend, the polymer blend produced from contacting a water soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor; and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support.
    Type: Grant
    Filed: September 9, 2008
    Date of Patent: March 29, 2011
    Assignee: General Electric Company
    Inventors: Su Lu, Liangliang Qiang, Yanrong Zhu, Zhida Pan
  • Patent number: 7875656
    Abstract: A foamable sealant composition having a density, when foamed, of from 0.4 to 1.8 g/cc, and containing a latex binder, foam-generating composition, foam stabilizer, rheology modifier and water, is provided. Also provided is a method of sealing a vehicle using the foamable sealant composition.
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: January 25, 2011
    Assignee: Rohm and Haas Company
    Inventor: William Edward deVry
  • Publication number: 20100140154
    Abstract: The present invention discloses methods of preparing a continuous, porous metal oxide monolith in a container. The method involves providing a reaction mixture containing a metal salt or metal alkoxide compound, a solvent, and a porogenic reagent. Next, an epoxide is added to the reaction mixture under conditions effective to initiate condensation and polymerization of the reaction mixture. Then, a container is filled with the reaction mixture after epoxide addition to obtain a continuous, porous metal oxide monolith in the container. The present invention also discloses columns including a tubular container and a continuous, porous Group IV metal oxide monolith in contact with the inner walls of the tubular container, where the Group IV metal oxide monolith is free of any support or matrix material, and other articles including a continuous, porous Group IV metal oxide monolith, where the metal oxide monolith is free of any support or matrix material.
    Type: Application
    Filed: March 9, 2005
    Publication date: June 10, 2010
    Applicant: The Research Foundation of State University of New York
    Inventors: Luis A. Colon, David C. Hoth
  • Publication number: 20090165645
    Abstract: A method of making a crosslinked polyimide membrane is described. A monoesterified membrane is formed from a monoesterified polyimide polymer. The monoesterified membrane is subjected to transesterification conditions to form a crosslinked membrane. The monoesterified membrane is incorporated with an organic titanate catalyst before or after formation of the monoesterified membrane. A crosslinked polyimide membrane made using the aforementioned method and a method of using the membrane to separate fluids in a fluid mixture, such as methane and carbon dioxide, are also disclosed.
    Type: Application
    Filed: December 31, 2007
    Publication date: July 2, 2009
    Inventors: John D. Wind, Stephen J. Miller, Oluwasijibomi O. Okeowo
  • Publication number: 20090099272
    Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a catalyst which is an adduct of an amine and an organic acid.
    Type: Application
    Filed: September 30, 2008
    Publication date: April 16, 2009
    Inventors: DAVID J. WILLIAMS, Michael Van Der Puy
  • Publication number: 20080281009
    Abstract: The invention pertains to a process for producing a cross-linked polyolefin foam in a continuous process using standard processing equipment without using a moisture cross-linking step after processing. In this method, a vinyl functional silane compound is melt grafted onto a low density polyethylene in the presence of a free radical generator. The resulting silane grafted polyethylene resin is mixed and melted with a blowing agent in a continuous process in the presence of water to form a vinyl functional silane foam.
    Type: Application
    Filed: December 3, 2007
    Publication date: November 13, 2008
    Applicant: Ingenia Polymers, Inc.
    Inventors: Jianzhong Hu, Salvatore D'Uva, Arthur Tinson
  • Publication number: 20080132593
    Abstract: A two-component polyurethane/vinyl ester hybrid foam system is formed of a polyol component (A), which contains at least one polyol, a catalyst for the reaction of the polyol with the polyisocyanate, at least one polymerizable vinyl monomer and water or a blowing agent on the basis of a compressed or liquefied gas as foam-forming agent, and a polyisocyanate component (B), which contains at least one polyisocyanate and a catalyst for the polymerization of the vinyl monomer, and is designed for use as a flame retardant material and material for filling openings, cable and pipe bushings in walls, floors and/or of buildings for the purpose of fire protection.
    Type: Application
    Filed: November 28, 2007
    Publication date: June 5, 2008
    Inventor: Arne Reinheimer
  • Patent number: 7198771
    Abstract: The invention comprises a chemical composition with the structure shown below. The composition can be polymerized or pyrolyzed, forming transition metal nanoparticles homogeneously dispersed in a thermoset or carbon composition. The size of the nanoparticles can be controlled by manipulating the number and arrangement of functional groups in the composition and by changing the conditions of the polymerization or pyrolysis. The resulting thermosets and carbon compositions have useful magnetic, electric, mechanical, catalytic and/or optical properties.
    Type: Grant
    Filed: August 28, 2003
    Date of Patent: April 3, 2007
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Joseph Perrin, Syed B. Qadri
  • Patent number: 7091302
    Abstract: The invention describes a process for the preparation of polycarbonate. The process includes (a) transesterifying at least one aromatic dihydroxyaryl compound and a diaryl carbonate in the melt in the presence of a catalyst, (b) mixing the melt obtained in step (a) with a foaming agent (c) passing the mixture at 250 to 340° C. through inlet openings of a separating vessel at a rate of 0.1 to 20 kg/hour, to obtain a plurality of streams of foamed polycarbonate and degassing the streams of foamed polycarbonate in the separating vessel wherein the pressure is 0.1 to 20 mbar.
    Type: Grant
    Filed: April 14, 2005
    Date of Patent: August 15, 2006
    Assignee: Bayer Materialscience AG
    Inventors: Jörg Kirchhoff, Thomas König, Klemens Kohlgrüber, Steffen Kühling, Melanie Möthrath, Dirk Van Meirvenne
  • Patent number: 7026365
    Abstract: Nano-sized particles such as nano-clays can be mixed with polymers through either melt compounding or in-situ polymerization. By modifying the particle surface with various surfactants and controlling processing conditions, we are able to achieve either intercalated (partial dispersion) or exfoliated (full dispersion) nano-clay distribution in polymers with the clay content up to 35% by weight. When a blowing agent is injected into the nanocomposite in an extruder (a continuous mixer) or a batch mixer, polymeric foam can be produced. Supercritical carbon dioxide, an environmentally friendly, low-cost, non-flammable, chemically benign gas is used as the blowing agent. This process forms a microcellular foam with very high cell density (>109 cells/cc) and small cell size (<5 microns) can be achieved by controlling the CO2 content, melt and die temperature, and pressure drop rate.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: April 11, 2006
    Assignee: The Ohio State University Research Foundation
    Inventors: L. James Lee, Kurt W. Koelling, David L. Tomasko, Xiangmin Han, Changchun Zeng
  • Patent number: 6797737
    Abstract: This invention relates to crosslinked polymer foam compositions of an ethylene vinyl acetate copolymer, an acid copolymer or ionomer, and a crosslinking agent. Such compositions exhibit enhanced melt strength, as well as lower density and compression set. They are especially useful as midsoles or insoles for footwear.
    Type: Grant
    Filed: June 23, 2000
    Date of Patent: September 28, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Chin-Fu Hsu, Richard T. Chou, Wayne C. Whelchel, Yun-Tong Ou
  • Patent number: 6765033
    Abstract: An expandable vinyl chloride resin composition that the expansion ratio of a vinyl chloride resin can be greatly increased by the use of thermally decomposable inorganic blowing agents without the use of organic solvent blowing agents, and which comprises 100 parts by weight of a vinyl chloride resin, 5 to 30 parts by weight of, as a processing aid, a (meth)acrylic acid ester polymer having a specific viscosity of not less than 0.73 measured at 30° C. with respect to a solution of 0.1 g of the polymer dissolved in 100 ml of chloroform, and 2 to 25 parts by weight of a thermally decomposable inorganic blowing agent.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: July 20, 2004
    Assignee: Kaneka Corporation
    Inventors: Takenobu Sunagawa, Noriko Sakashita, Toshiyuki Mori, Akira Takaki
  • Patent number: 6759446
    Abstract: Nano-sized particles such as nano-clays can be mixed with polymers through either melt compounding or in-situ polymerization. By modifying the particle surface with various surfactants and controlling processing conditions, we are able to achieve either intercalated (partial dispersion) or exfoliated (full dispersion) nano-clay distribution in polymers with the clay content up to 35% by weight. When a blowing agent is injected into the nanocomposite in an extruder (a continuous mixer) or a batch mixer, polymeric foam can be produced. Supercritical carbon dioxide, an environmentally friendly, low-cost, non-flammable, chemically benign gas is used as the blowing agent. This process forms a microcellular foam with very high cell density (>109 cells/cc) and small cell size (<5 microns) can be achieved by controlling the CO2 content, melt and die temperature, and pressure drop rate.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: July 6, 2004
    Assignee: The Ohio State University Research Foundation
    Inventors: L. James Lee, Kurt W. Koelling, David L. Tomasko, Xiangmin Han, Changchun Zeng
  • Patent number: 6723762
    Abstract: There is provided a foamable poly(vinyl chloride) resin composition which can remarkably improve an expansion ratio. There is used a foamable poly(vinyl chloride) resin composition comprising 100 parts by weight of (A) a poly(vinyl chloride) resin, 0.5 to 30 parts by weight of (B) a processing aid, and 0.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: April 20, 2004
    Assignee: Kaneka Corporation
    Inventors: Takenobu Sunagawa, Noriko Sakashita, Mitsutaka Sato, Mamoru Kadokura
  • Patent number: 6673953
    Abstract: The invention comprises a chemical composition with the structure shown below. The composition can be polymerized or pyrolyzed, forming transition metal nanoparticles homogeneously dispersed in a thermoset or carbon composition. The size of the nanoparticles can be controlled by manipulating the number and arrangement of functional groups in the composition and by changing the conditions of the polymerization or pyrolysis. The resulting thermosets and carbon compositions have useful magnetic, electric, mechanical, catalytic and/or optical properties.
    Type: Grant
    Filed: December 10, 2001
    Date of Patent: January 6, 2004
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Joseph Perrin, Syed B. Qadri
  • Patent number: 6635687
    Abstract: An expandable vinyl chloride resin composition which can provide foamed articles having a greatly enhanced expansion ratio without remarkably lowering the surface property and strength by the use of thermally decomposable blowing agents without the use of organic solvent blowing agents, and which comprises 100 parts by weight of a vinyl chloride resin, 0.5 to 30 parts by weight of, as a processing aid, a two stage (meth)acrylic ester polymer having a specific viscosity of at least 0.5 (0.1 % chloroform solution, 30° C.) prepared by polymerizing a monomer component containing as a main component a monomer selected from acrylic esters and methacrylic esters excepting methyl methacrylate in the presence of a latex of a methyl methacrylate polymer having a specific viscosity of at least 0.7, 0.3 to 25 parts by weight of a thermally decomposable inorganic blowing agent, 0.01 to 15 parts by weight of a thermally decomposable organic blowing agent and 0 to 20 parts by weight of a filler.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: October 21, 2003
    Assignee: Kaneka Corporation
    Inventors: Takenobu Sunagawa, Mitsutaka Sato, Mamoru Kadokura
  • Patent number: 6632850
    Abstract: Microporous materials and articles are disclosed. The microporous materials contain a crystallizable propylene-containing polymer, a beta-nucleating agent, and a diluent that is miscible with the polymer at a temperature above the melting temperature of the polymer and that phase separates from the polymer at a temperature below the polymer crystallization temperature. The invention is also directed to methods of forming the microporous material using thermal induced phase separation and subsequent processing.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: October 14, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Shannon Kay Hughes, Robert Steven Kody, James Stephen Mrozinski, Myles Lee Brostrom
  • Patent number: 6610757
    Abstract: An expandable vinyl chloride resin composition that the expansion ratio of a vinyl chloride resin can be greatly increased by the use of thermally decomposable inorganic blowing agents without the use of organic solvent blowing agents, and which comprises 100 parts by weight of a vinyl chloride resin, 0.5 to 30 parts by weight of, as a processing aid, a (meth)acrylic acid ester polymer having a specific viscosity of not less than 0.73 measured at 30° C. with respect to a solution of 0.1 g of the polymer dissolved in 100 ml of chloroform, and not less than 0.3 to less than 2 parts by weight of a thermally decomposable inorganic blowing agent such as sodium bicarbonate.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: August 26, 2003
    Assignee: Kaneka Corporation
    Inventors: Takenobu Sunagawa, Mitsutaka Sato, Noriko Sakashita, Mamoru Kadokura
  • Patent number: 6608115
    Abstract: Polyvinyl chloride resin compositions and methods of preparation and use thereof for increasing the degree of whiteness in finished polyvinyl chloride foam. The resin compositions contain sulfur compounds selected from sulfonic acid derivatives, sulfinic acid derivatives, and mercapto acetic acid sodium salt, and optionally contain water soluble salts and/or t-butyl hydroperoxide.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: August 19, 2003
    Assignee: Occidental Chemical Corporation
    Inventors: Michael T. Moran, Thomas E. Moses, Sherry Rohn Clancy
  • Patent number: 6605649
    Abstract: Polyvinyl chloride resin compositions and methods of preparation and use thereof for increasing the degree of whiteness in finished polyvinyl chloride foam. The resin compositions contain sulfur compounds selected from sulfonic acid derivatives, sulfinic acid derivatives, and mercapto acetic acid sodium salt, and optionally contain water soluble salts and/or t-butyl hydroperoxide.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: August 12, 2003
    Assignee: Occidental Chemical Corporation
    Inventors: Michael T. Moran, Thomas E. Moses, Sherry Rohn Clancy
  • Patent number: 6562447
    Abstract: Foamable polypropylene composition comprising a polypropylene resin having an D1238L melt flow rate of from about 0.5 to about 30 g/10 min, and a method for extruding rigid, foamed polypropylene sheet with improved surface appearance having a density in the range 0.4 to about 0.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: May 13, 2003
    Assignee: BP Corporation North America Inc.
    Inventors: Jesse Wu, James H. Han, Phil Jacoby, Mark C. Novak, Constantine Metaxas, Chin Choi-Feng, Ray O. Mills, Daan Feng
  • Patent number: 6555591
    Abstract: The present invention has its object to provide a foam outstanding in electrification and heat insulating and sound insulating properties and has high compressive strength even when it has low density. The present invention relates to a foam comprising an organic polymer expanded matrix (I) and at least one kind of inorganic substance (II) selected from the group consisting of metals, metal compounds and non-metal inorganic fillers, wherein said expanded matrix (I) contains metal salt-crosslinks and the relation between the weight percentage (M) of the metal forming said metal salt-crosslinks in the expanded matrix (I) based on the total weight of the expanded matrix (I) and the inorganic substance (II) and the weight percentage (S) of the inorganic substance (II) based on the total weight of the expanded matrix (I) and the inorganic substance (II) satisfies the following expression. M≧10−S/4  (1) wherein M≦50 and S≧5.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: April 29, 2003
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Tsuyoshi Tomosada, Kimihiko Noda, Satoshi Sasaki, Hideo Nishiguchi, Hideyuki Nishida
  • Patent number: 6548562
    Abstract: Foamed thermoplastic polyolefin elastomer is formed by heating a foamable thermoplastic polyolefin elastomer-containing polymeric composition containing each of a first water-releasing blowing agent which is at least one of metal hydroxide and water hydrate of a salt of a metal of Group 1 or Group 2 of the Periodic Table and a second blowing agent which is neither a metal hydroxide nor a water hydrate of a salt of a metal of Group 1 or Group 2 of the Periodic Table, to a temperature above the melting point of the polyolefin elastomer. The second blowing agent may be a chemical blowing agent and may release, water, a mixture of water and carbon dioxide or another gas, including carbon monoxide, carbon dioxide, and nitrogen.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: April 15, 2003
    Assignee: DSM N.V.
    Inventors: Ryszard Brzoskowski, Mohammad R. Sadeghi, Yungdong Wang
  • Patent number: 6528550
    Abstract: This invention relates to crosslinked polymer foam compositions of an ethylene vinyl acetate copolymer, an ethylene/acrylic acid copolymer or ionomer, and a crosslinking agent. Such compositions exhibit enhanced melt strength, as well as lower density and compression set. They are especially useful as midsoles or insoles for footwear.
    Type: Grant
    Filed: June 23, 2000
    Date of Patent: March 4, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Chin-Fu Hsu, Richard T. Chou, Wayne C. Whelchel, Yun Tong Ou
  • Patent number: 6521675
    Abstract: Foamable polypropylene composition comprising a polypropylene resin having an D1238L melt flow rate of from about 0.5 to about 30 g/10 min, and a method for extruding rigid, foamed polypropylene sheet with improved surface appearance having a density in the range 0.4 to about 0.8 g/cm3.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: February 18, 2003
    Assignee: BP Corporation North America Inc.
    Inventors: Jesse Wu, James H. Han, Phil Jacoby, Mark C. Novak, Constantine Metaxas, Chin Choi-Feng, Ray O. Mills
  • Patent number: 6500873
    Abstract: Polyvinyl chloride resin compositions and methods of preparation and use thereof for increasing the degree of whiteness in finished polyvinyl chloride foam. The resin compositions contain sulfur compounds selected from sulfonic acid derivatives, sulfinic acid derivatives, and mercapto acetic acid sodium salt, and optionally contain water soluble salts and/or t-butyl hydroperoxide.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: December 31, 2002
    Assignee: Occidental Chemical Corporation
    Inventors: Michael T. Moran, Thomas E. Moses, Sherry Rohn Clancy
  • Publication number: 20020143077
    Abstract: The elastomeric composition for preparing an olefinic elastomer crosslinked foam according to the present invention contains an ethylene/&agr;-olefin copolymer (A) having a specific density and MFR, an organic peroxide (D), a crosslinking assistant (E), a foaming agent (F), an organic metal compound (G), and as necessary, a high pressure low density polyethylene (B) having a specific MFR, and an ethylene/vinyl acetate copolymer (C) having a specific amount of vinyl acetate and a specific MFR. An olefinic elastomer crosslinked foam of the present invention can be obtained by crosslinking and foaming the above composition. Further, another olefinic elastomer crosslinked foam of the present invention can be obtained by a secondary compression of the above crosslinked foam. The footwear part of the present invention is made of these crosslinked foams.
    Type: Application
    Filed: February 1, 2002
    Publication date: October 3, 2002
    Inventors: Takanori Sueda, Naoto Yasaka, Chong-Sun Yoo, Jeong-Sik Yoon, Kyung-Man Choi
  • Patent number: 6444714
    Abstract: A process for preparing expandable particulate styrene polymers wherein from 5 to 50% by weight of expanded graphite and also, if desired, from 2 to 20% by weight of a phosphorus compound, are present as flame retardants, by suspension polymerization of styrene in the presence of the flame retardants.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: September 3, 2002
    Assignee: BASF Aktiengesellshaft
    Inventors: Guiscard Glück, Franz-Josef Dietzen, Klaus Hahn, Gerd Ehrmann
  • Patent number: 6441055
    Abstract: The invention relates to sensor membranes for determining oxygen concentrations and to a process for the preparation thereof, in which, in a polymer matrix which is permeable to oxygen, an indicator is present whose optical and physicochemical properties can be influenced by the respective analytes. Starting from the disadvantages of known sensor membranes, it is the object of the invention to provide a sensor membrane which is thermally and also dimensionally stable, and can be prepared simply and flexibly. This object is achieved according to the invention in that the polymer matrix which contains the optical oxygen indicator is formed from a polymer containing sulfur, preferably in the main chain, particularly preferably containing sulfide and/or sulfone functionalities in the main chain.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: August 27, 2002
    Assignee: Institut fur Chemo-und Biosensorik Munster e.V.
    Inventors: Andreas Katerkamp, Maria Hiegemann, Erk Gedig
  • Patent number: 6423758
    Abstract: A foam composition and method of making the same. The foam of the present invention comprises a mixture of glutarate ester plasticizer, adipate ester plasticizer, alcohol carboxylic acid ester, cell stabilizer, barium/zinc activator stabilizer, potassium/zinc activator stabilizer or zinc stabilizer, azodicarbonamide blowing agent, low-fogging vinyl dispersion resin, vinyl blending resin, and black acrylic pigment dispersion. The foam is made by the process of mixing the ingredients until a homogenous liquid mixture is present, de-airing the homogeneous liquid mixture, casting the liquid mixture on a non-fogging release-coated surface, expanding the cast liquid mixture by exposing it to an elevated temperature for a prescribed duration of time, and then either cooling the expanded mixture and winding it into rolls, or coating the stabilized composition with pressure sensitive adhesive, cooling it, and then winding it into rolls.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: July 23, 2002
    Assignee: Gaska Tape, Inc.
    Inventor: Lawrence A. Cascino
  • Patent number: 6372809
    Abstract: A foamable rubber composition comprising 100 parts by weight of a nitrile group-containing highly saturated copolymer rubber, 5 to 100 parts by weight of polyethylene, 3 to 100 parts by weight of a metal salt of an ethylenically unsaturated carboxylic acid, 0.5 to 10 parts by weight of an organic peroxide and 1 to 15 parts by weight of a foaming agent is foamed and shaped into a foamed rubber product.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: April 16, 2002
    Assignee: Zeon Corporation
    Inventors: Manabu Asai, Yoshiaki Aimura
  • Patent number: 6355698
    Abstract: It provides a blowing agent which is significantly inhibited from solidification and is exceedingly useful as a blowing agent satisfactory in flowability, dispersibility into resins, and the like, even after the lapse of a prolonged period of time, and a process for producing the same. The blowing agent of the present invention is substantially anhydrous blowing agent, and it is obtained by treating a blowing agent with a surface-treating agent capable of removing water from the blowing agent, followed by optionally heating during or after the treatment.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: March 12, 2002
    Assignee: Otsuka Chemical Co., Ltd.
    Inventors: Tsukasa Maekawa, Nobuyuki Ueda, Sadafumi Shono, Yoshifumi Tachi, Shigeru Sumitomo
  • Patent number: 6348512
    Abstract: The present invention relates to a medium density chlorinated polyvinyl chloride foam and the method of preparing such a foam. The foam having a specific gravity in the range of about 0.3 to about 1.5 comprises chlorinated polyvinyl chloride, a nitrogen containing decomposition type blowing agent, a tin stabilizer, a costabilizer and a high molecular weight process aid.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: February 19, 2002
    Assignee: PMD Holdings Corp.
    Inventor: Paul M. Adriani