Carbocyclic Ring Containing, E.g., Styrene, Etc. Patents (Class 522/160)
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Patent number: 10774062Abstract: An object of the present invention is to provide a photocuring method, which makes it possible to rapidly and efficiently obtain a crosslinked product (resin), a compound used in the photocuring method, and a photocuring resin composition containing the compound. The present invention relates to a photocuring method, which comprises a step 1 and a step 2 performed after the step 1, a compound used in the photocuring method, and a photocuring resin composition containing the compound. Step 1: this is a step in which in the presence of (A) compound having a carbonyl group generating a radical by photoirradiation and a carboxyl group decarboxylated by photoirradiation, (B) silane coupling agent having a mercapto group or a (meth)acryl group is reacted with (C) water under acidic conditions to obtain (D) silane compound having a mercapto group or a (meth)acryl group and at least one silanol group.Type: GrantFiled: January 25, 2017Date of Patent: September 15, 2020Assignees: FUJIFILM Wako Pure Chemical Corporation, TOKYO UNIVERSITY OF SCIENCE FOUNDATIONInventors: Nobuhiko Sakai, Kosuke Yanaba, Shigeaki Imazeki, Koji Arimitsu
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Patent number: 9005743Abstract: The present invention relates to a polarizing plate, a method for producing the same, and an image display device comprising the same, and more specifically to a polarizing plate which is characterized by comprising: a) a polarizer, b) a hardening resin layer which is provided on at least one side of the polarizer and formed from a photocurable composition comprising: 4 to 95 parts by weight of (A) a photocurable acrylic polymer, 4 to 95 parts by weight of (B) a poly-functional acrylic monomer, and 1 to 20 parts by weight of (C) a photo-polymerization initiator, based on 100 parts by weight of the photocurable composition, a method for manufacturing the same, and an image display device using the same. According to the present invention, a polarizing plate, which exhibits excellent polarizing properties and durability, has high surface hardness, and may be formed as a thin plate, may be provided.Type: GrantFiled: December 15, 2010Date of Patent: April 14, 2015Assignee: LG Chem, Ltd.Inventors: Jin-Young Ryu, Young-Jun Hong, Soon-Yeol Lee, Woo-Sung Kim, Han-Na Lee
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Publication number: 20150044425Abstract: There is provided with a method for manufacturing a resin product. One embodiment includes performing a modification process on a portion of a surface of the resin product not less than two times by different methods to modify the portion such that a plating metal can be deposited on the portion.Type: ApplicationFiled: August 8, 2014Publication date: February 12, 2015Inventors: Taisuke IWASHITA, Yoshihisa NEGISHI, Yoshihiro HATTORI, Naoki TATEBAYASHI
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Patent number: 8940810Abstract: An optical component and an electrical board that have a low coefficient of linear expansion and small mold shrinkage, a method for producing the optical component, and a method for producing the electronic board are provided. An optical component includes a polymer having a repeating structural unit represented by general formula (1) where R1 and R2 each independently represent —H or —CH3; m and n each independently represent an integer in the range of 0 to 3; asterisk denotes a dangling bond that bonds to one of Xa and Xb; and —H bonds to the other one of Xa and Xb.Type: GrantFiled: June 5, 2013Date of Patent: January 27, 2015Assignee: Canon Kabushiki KaishaInventors: Ryo Ogawa, Seiji Okada
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Patent number: 8822125Abstract: A composition for forming a pattern includes: about 1% to about 10% by weight of a liquid prepolymer, about 40% to about 60% by weight of an acrylate having a hydrophilic group, about 10% to about 20% by weight of a viscosity modifier, about 1% to about 5% by weight of a photoinitiator, and an additive.Type: GrantFiled: May 23, 2007Date of Patent: September 2, 2014Assignee: LG Display Co., Ltd.Inventor: Jin-Wuk Kim
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Patent number: 8822563Abstract: Disclosed is a curable resin composition comprising a polymer (A) that has a main chain comprising carbon atoms and a side chain having a polymerizing unsaturated linking group and has a cyclic structure in the main chain and/or the side chain, and a compound having a polymerizing unsaturated group. The curable resin composition has good optical characteristics, good heat resistance and good moldability.Type: GrantFiled: January 18, 2013Date of Patent: September 2, 2014Assignee: FUJIFILM CorporationInventors: Hiroaki Mochizuki, Naoyuki Morooka, Rie Okutsu, Tatsuhiko Obayashi
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Patent number: 8796350Abstract: An ultraviolet (UV) crosslinkable acrylic pressure sensitive adhesive comprises an acrylic copolymer and a cationic photoinitiator. The acrylic copolymer comprises pendant reactive functional groups. The pressure sensitive adhesive formed from the acrylic copolymer with the pendant reactive functional groups result in high green strength and/or high temperature holding strength of the adhesive.Type: GrantFiled: September 7, 2012Date of Patent: August 5, 2014Assignee: Henkel US IP LLCInventors: Yuxia Liu, Peter Palasz, Charles W. Paul, Paul B. Foreman
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Publication number: 20140044950Abstract: A chain olefin-cyclic olefin copolymer is irradiated with an electron beam for crosslinking to prepare a crosslinked product of a cyclic olefinic polymer. The cyclic olefin contains a bicyclic olefin. The proportion of the cyclic olefin in the total amount of the chain olefin and the cyclic olefin is more than 15% by mol and not more than 40% by mol. The chain olefin-cyclic olefin copolymer has a glass transition temperature of 20 to 80° C. or has a degree of crystallinity of not more than 1%. The crosslinked product may have a haze of not more than 2%. The crosslinked product of the present invention has a low haze and a high transparency and combines heat resistance and flexibility.Type: ApplicationFiled: April 23, 2012Publication date: February 13, 2014Applicant: DAICEL CORPORATIONInventors: Koichi Umemoto, Haruo Ichikawa
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Patent number: 8648149Abstract: The invention relates to the field of chemistry and relates to radically coupled PTFE polymer compounds that can be used, for example, as tribo materials, and a method for the production thereof. The object of the invention is to disclose radically coupled PTFE polymer compounds which exhibit improved wear resistances with comparable gliding properties, and furthermore a simple and efficient method for the production of such compounds. The object is attained through radically coupled PTFE polymer compounds comprising radiation-chemically and/or plasma-chemically modified PTFE powders, on the particle surface of which olefinically unsaturated polymers are chemically radically coupled by a reactive conversion into a melt.Type: GrantFiled: June 7, 2010Date of Patent: February 11, 2014Assignee: Leibniz-Institut fuer Polymerforschung Dresden E.V.Inventors: Dieter Lehmann, Bernd Kluepfel
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Patent number: 8642247Abstract: The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B?) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.Type: GrantFiled: February 14, 2012Date of Patent: February 4, 2014Assignee: FUJIFILM CorporationInventors: Ippei Nakamura, Masaharu Sugai
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Publication number: 20130331477Abstract: An optical component and an electrical board that have a low coefficient of linear expansion and small mold shrinkage, a method for producing the optical component, and a method for producing the electronic board are provided. An optical component includes a polymer having a repeating structural unit represented by general formula (1) where R1 and R2 each independently represent —H or —CH3; m and n each independently represent an integer in the range of 0 to 3; asterisk denotes a dangling bond that bonds to one of Xa and Xb; and —H bonds to the other one of Xa and Xb.Type: ApplicationFiled: June 5, 2013Publication date: December 12, 2013Inventors: Ryo Ogawa, Seiji Okada
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Patent number: 8598246Abstract: Methylated polystyrene having pendant N-halamine and N-halamine precursor groups. Biocidal particles have been prepared by reacting highly crosslinked methylated polystyrene beads as starting materials with various N-halamine precursor compounds. The resulting polymer beads are halogenated with chlorine or bromine. The porous beads will be useful in disinfection applications as well as for sanitization and controlling noxious odor when mixed with absorbent materials in items such as disposable diapers, infant swimwear, incontinence pads, bandages, sanitary napkins, pantiliners, mattress covers, shoe inserts, sponges, animal litter, carpets, and fabrics.Type: GrantFiled: October 25, 2011Date of Patent: December 3, 2013Assignee: Auburn UniversityInventors: Shelby D. Worley, Yongjun Chen
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Patent number: 8552084Abstract: A process for preparing a pressure sensitive adhesive using a modified planetary roller extruder is described. The process in accordance with one aspect of the invention is a continuous process that includes introducing primary raw materials comprising a non-thermoplastic elastomer into a planetary roller extruder, introducing a heat-activatable crosslinker into the planetary roller extruder for mixing with the primary raw materials, and compounding the primary raw materials and the heat activatable crosslinker to form an adhesive composition while maintaining the temperature of the adhesive composition between about 25° C. and about 100° C. The non-thermoplastic elastomer is masticated during compounding and at least some of the heat-activatable crosslinker remains generally unactivated and is available for later activation.Type: GrantFiled: December 27, 2011Date of Patent: October 8, 2013Assignee: Intertape Polymer Corp.Inventors: John Kinch Tynan, Jr., Richard Walter St. Coeur, David Michael Kovach, Thomas Lombardo
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Patent number: 8461225Abstract: The present invention relates to methods for making oxidation resistant homogenized polymeric materials and medical implants that comprise polymeric materials, for example, ultra-high molecular weight polyethylene (UHMWPE). The invention also provides methods of making antioxidant-doped medical implants, for example, doping of medical devices containing cross-linked UHMWPE with vitamin E by diffusion and annealing the antioxidant doped UHMWPE in a super critical fluid, and materials used therein.Type: GrantFiled: August 18, 2006Date of Patent: June 11, 2013Assignee: The General Hospital CorporationInventors: Orhun K. Muratoglu, Ebru Oral
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Patent number: 8426487Abstract: The present invention provides a fluorine-based compound and a coating composition and a film including the same. By using the fluorine-based compound according to the present invention, a film having excellent functionalities of water repellency, oil repellency, weatherability and contamination resistance can be provided.Type: GrantFiled: September 18, 2009Date of Patent: April 23, 2013Assignee: LG Chem, Ltd.Inventors: Chong-Kyu Shin, Yeong-Rae Chang, Joon-Koo Kang
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Patent number: 8404797Abstract: An end-modified soluble polyfunctional vinyl aromatic copolymer, which is improved in heat resistance, thermal stability, solvent solubility, and compatibility with acrylate compounds, and a curable resin composition using the same are disclosed. The end-modified soluble polyfunctional vinyl aromatic copolymer is obtained by allowing a divinyl aromatic compound (a), a monovinyl aromatic compound (b), and an aromatic ether compound (c) to react with each other, and has, at an end, an end group derived from the aromatic ether compound and having an acrylate bond. The copolymer has a number average molecular weight Mn of 500 to 100,000, an introduction amount (c1) of the end group derived from the aromatic ether compound satisfies (c1)?1.0 (group/molecule), a molar fraction a? of a structural unit derived from the divinyl aromatic compound and a molar fraction b? of a structural unit derived from the monovinyl aromatic compound in the copolymer satisfy 0.05?a?/(a?+b?)?0.95.Type: GrantFiled: March 3, 2009Date of Patent: March 26, 2013Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Masanao Kawabe, Hiroko Terao, Natsuko Okazaki
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Patent number: 8399536Abstract: The present subject matter relates generally to polymer compositions, and more particularly to irradiated polymer compositions comprising at least one non-phenolic stabilizer. The present polymer compositions comprise an unexpected balance of properties after being subjected to irradiation treatments, including an unexpected combination of a lower melt flow rate ratio (MFRr) and high melt tension after being irradiated, while minimizing negative yellowing effects.Type: GrantFiled: June 27, 2008Date of Patent: March 19, 2013Assignee: Basell Poliolefine Italia, s.r.l.Inventors: Jeffrey D. Abata, Ronald F. Becker, Vu A. Dang, Anthony J. De Nicola, Jr., Theodore Dziemianowicz
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Patent number: 8362151Abstract: The present invention provides novel hybrid polymer useful for alignment layers for inducing alignment of a liquid crystal medium. Hybrid polymers of this invention are prepared from a) at least one component selected from the group consisting of oligomer(s) and polymer(s) within the class of polyimides, poly(amic acids) and esters thereof wherein the at least one component comprises at least one initiator generating moiety, and b) at least one component selected from the group consisting of addition monomer(s) and addition polymer(s), wherein the two components are covalently bonded to form a copolymer. The invention further describes liquid crystal elements such as all liquid crystal display products or modes, liquid crystal devices and liquid crystal optical films comprising the novel hybrid polymer alignment layers.Type: GrantFiled: December 15, 2009Date of Patent: January 29, 2013Assignee: Elsicon, Inc.Inventors: Chunhong Li, Wayne Gibbons
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Patent number: 8354459Abstract: An object of the present invention is to provide a method for producing a block copolymer solid in which microphase-separated structures are formed with good productivity. The present invention provides a method for producing a block copolymer solid in which a microphase-separated structure is formed, or an alloy, blend or composite solid containing a block copolymer in which a microphase-separated structure is formed, which comprises the following steps (1) to (3): (1) immersing a block copolymer solid or an alloy, blend or composite solid containing a block copolymer in a solvent in which each component is insoluble; (2) putting the solid obtained in (1) above in a pressure-resistant container; and (3) irradiating the solid or the solvent in (2) above with microwave.Type: GrantFiled: August 17, 2010Date of Patent: January 15, 2013Assignee: Japan Science and Technology AgencyInventors: Hiroshi Yabu, Takeshi Higuchi
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Patent number: 8227551Abstract: Disclosed herein is a polymeric composition comprising a polymeric composition comprising a first crosslinked network; and a second crosslinked network; wherein the first crosslinked network is crosslinked at a first stress and/or a first strain and the second crosslinked network is crosslinked at a second stress and/or a second strain; where the first stress and/or the first strain is different from the second stress and/or the second strain either in magnitude or direction. Disclosed herein is a method comprising subjecting a polymeric mass to a first stress and/or a first strain level; crosslinking the polymeric mass to form a first crosslinked network; subjecting the polymeric mass to a second stress and/or a second strain level; and crosslinking the polymeric mass to form a second crosslinked network; where the first stress and/or the first strain level is different from the second stress and/or the second strain level.Type: GrantFiled: November 10, 2009Date of Patent: July 24, 2012Assignee: The University of MassachusettsInventors: Alan James Lesser, Naveen Kumar Singh, Mohit Mamodia
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Patent number: 8217128Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.Type: GrantFiled: September 1, 2009Date of Patent: July 10, 2012Assignee: Amyris, Inc.Inventor: Derek James McPhee
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Patent number: 8153702Abstract: The present invention relates to a method of producing an electret material, to a new class of electret materials and to a device comprising such electret materials.Type: GrantFiled: September 14, 2009Date of Patent: April 10, 2012Assignee: Sony CorporationInventors: Nikolaus Knorr, Silvia Rosselli, Tzenka Miteva, Gabriele Nelles
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Publication number: 20120064336Abstract: An ultraviolet-curable pressure-sensitive adhesive composition, comprising one or more monomer components comprising an acrylic monomer; an aromatic low-molecular-weight polymer having a weight-average molecular weight of 500 to 4000 inclusive, the molecular weight being according to gel permeation chromatography; and a photopolymerization initiator; wherein when the composition is turned into a pressure-sensitive adhesive layer, the haze value of the composition is 10% or less.Type: ApplicationFiled: May 18, 2010Publication date: March 15, 2012Inventors: Akiko Tanaka, Yutaka Moroishi, Fumiko Nakano
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Patent number: 8110612Abstract: A process for preparing a pressure sensitive adhesive using a modified planetary roller extruder is described. The process in accordance with one aspect of the invention includes introducing primary raw materials including a non-thermoplastic elastomer into a feeding section of the modified planetary roller extruder, conveying the raw materials from the feeding section to a compounding section of the modified planetary roller extruder, continuously mixing the primary raw materials in the compounding section to produce a homogeneous adhesive composition. The adhesive composition may be applied to a web-form material. The compounding section of the modified planetary roller extruder includes a main spindle surrounded by and intermeshed with a plurality of planetary spindles at least one of which is a double transversal mixing spindle having a plurality of back-cut helical flights.Type: GrantFiled: February 5, 2007Date of Patent: February 7, 2012Assignee: Intertape Polymer Corp.Inventors: John Kinch Tynan, Jr., Richard Walter St. Coeur, David Michael Kovach, Thomas Lombardo
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Publication number: 20110165404Abstract: The present invention provides a fluorine-based compound and a coating composition and a film including the same. By using the fluorine-based compound according to the present invention, a film having excellent functionalities of water repellency, oil repellency, weatherability and contamination resistance can be provided.Type: ApplicationFiled: September 18, 2009Publication date: July 7, 2011Inventors: Chong-Kyu Shin, Yeong-Rae Chang, Joon-Koo Kang
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Publication number: 20110024356Abstract: Embodiments of the invention provide separation cartridges, methods for fabricating separation cartridges, and methods for using separation cartridges. One aspect of the invention provides a separation cartridge including a first end, a second end, and one or more sorbents located between the first end and the second ends, the one or more sorbents arranged from the first end to the second end in order of increasing hydrophobicity. Another aspect of the invention provides a method of creating a separation cartridge having varying hydrophobicity. The method includes loading a filtration material and a cross-linking agent into a cylinder and selectively exposing the material to an energy source to selectively initiate a cross-linking reaction within the filtration material.Type: ApplicationFiled: October 15, 2010Publication date: February 3, 2011Applicant: BIOCIUS LIFE SCIENCES, INC.Inventor: Can C. Ozbal
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Patent number: 7767726Abstract: According to an aspect of the invention, medical devices are provided which contain at least one polymeric region. The polymeric region contains at least one copolymer, which includes at least one high Tg vinyl aromatic monomer and at least one low Tg monomer. Moreover, the polymeric region contains at least one surface sub-region that is crosslinked and at least one bulk sub-region that is substantially non-crosslinked. According to another aspect of the invention, a method is provided which includes exposing a polymeric region of a medical device to energetic species such that at least one surface sub-region of the polymeric region becomes crosslinked and at least one bulk sub-region remains substantially non-crosslinked. The polymeric region contains at least one copolymer, which includes at least one high Tg vinyl aromatic monomer and at least one low Tg monomer.Type: GrantFiled: May 11, 2007Date of Patent: August 3, 2010Assignee: Boston Scientific Scimed, Inc.Inventors: Derek Sutermeister, Jay Rassat
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Patent number: 7632875Abstract: The present invention provides novel hybrid polymer useful for alignment layers for inducing alignment of a liquid crystal medium. Hybrid polymers of this invention are prepared from at least one component selected from the group consisting of monomer, oligomer and polymer within the class of polyimides, poly(amic acids) and esters thereof and at least one component selected from the group consisting of addition monomer and functionalized addition polymer wherein the two components are covalently bonded to form a copolymer. The invention further describes liquid crystal optical elements such as all liquid crystal display products or modes, liquid crystal devices and liquid crystal optical films comprising the novel hybrid polymer alignment layers.Type: GrantFiled: July 18, 2005Date of Patent: December 15, 2009Assignee: Elsicon, Inc.Inventors: Wayne M. Gibbons, Michael G. P. Reppy, Patricia A. Rose, Hanxing Zheng
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Patent number: 7569620Abstract: The present invention provides an irradiated crosslinked polyethylene containing reduced free radicals, preferably containing substantially no residual free radical. Disclosed is a process of making irradiated crosslinked polyethylene by irradiating the polyethylene in contact with a sensitizing environment at an elevated temperature that is below the melting point, in order to reduce the concentration of residual free radicals to an undetectable level. A process of making irradiated crosslinked polyethylene composition having reduced free radical content, preferably containing substantially no residual free radicals, by mechanically deforming the polyethylene at a temperature that is below the melting point of the polyethylene, optionally in a sensitizing environment, is also disclosed herein.Type: GrantFiled: October 17, 2007Date of Patent: August 4, 2009Assignees: Massachusetts General Hospital, Cambridge Polymer Group, Inc.Inventors: Orhun K. Muratoglu, Stephen H. Spiegelberg, Gareth H. McKinley
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Publication number: 20090081797Abstract: Plasma treated cyclic polyolefin copolymer surfaces having enhanced binding density for binding biologically active agents and cells are provided. These plasma treated cyclic polyolefin copolymer surfaces may be further enhanced for binding biologically active agents or cells by the application of conjugates. Methods of making and characterizing treated polymer surfaces are also provided.Type: ApplicationFiled: August 29, 2008Publication date: March 26, 2009Inventors: ANDREI G FADEEV, Santona Pal, David Michael Weber
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Patent number: 7507774Abstract: The present invention provides an irradiated crosslinked polyethylene containing reduced free radicals, preferably containing substantially no residual free radical. Disclosed is a process of making irradiated crosslinked polyethylene by irradiating the polyethylene in contact with a sensitizing environment at an elevated temperature that is below the melting point, in order to reduce the concentration of residual free radicals to an undetectable level. A process of making irradiated crosslinked polyethylene composition having reduced free radical content, preferably containing substantially no residual free radicals, by mechanically deforming the polyethylene at a temperature that is below the melting point of the polyethylene, optionally in a sensitizing environment, is also disclosed herein.Type: GrantFiled: October 17, 2007Date of Patent: March 24, 2009Assignees: The General Hospital Corporation, Cambridge Polymer Group, Inc.Inventors: Orhun K. Muratoglu, Stephen H. Spiegelberg, Gareth H. McKinley
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Patent number: 7470727Abstract: A polypropylene resin composition comprising (A) 99.8 to 80 weight parts of a polypropylene resin having a melt flow rate of 0.1 to 50 g/10 min and (B) 0.2 to 20 weight parts of an olefin copolymer rubber having an intrinsic viscosity [?] of 0.5 to 4.0 dl/g and/or a polyethylene resin having a density of 0.895 to 0.945 g/cc and a melt flow rate of 0.05 to 15 g/10 min, which have undergone an ionization ray-irradiation treatment and/or a treatment of adding 0.05 to 5 weight parts of an organic peroxide to 100 weight parts of the aforesaid polypropylene resin composition comprising (A) and (B) and then melting.Type: GrantFiled: May 21, 2002Date of Patent: December 30, 2008Assignee: Basell Poliolefine Italia S.p.A.Inventor: Toshiyuki Iwashita
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Patent number: 7452923Abstract: The present invention discloses an anisotropic conductive adhesive comprising an insulating adhesive component and a number of conductive particles dispersed in the insulating adhesive component, wherein the insulating adhesive component contains a crosslinked rubber resin. The anisotropic conductive adhesive of the present invention prevents exfoliation of an adhesive or reduction in adhesive strength of circuit by minimizing its the heat-contraction occurring in the process of a polymerization or a hardening reaction when connecting micro-circuits, whereby a short circuit between adjacent electrodes can be prevented when connecting the circuits, and excellent connection reliability according to a long-term use is achieved.Type: GrantFiled: October 5, 2004Date of Patent: November 18, 2008Assignee: LG Cable Ltd.Inventors: Young Mi Jeon, Yoon Jae Chung, Jong Yoon Jang, Woo Young Ahn, Yong Seok Han
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Publication number: 20080279911Abstract: According to an aspect of the invention, medical devices are provided which contain at least one polymeric region. The polymeric region contains at least one copolymer, which includes at least one high Tg vinyl aromatic monomer and at least one low Tg monomer. Moreover, the polymeric region contains at least one surface sub-region that is crosslinked and at least one bulk sub-region that is substantially non-crosslinked. According to another aspect of the invention, a method is provided which includes exposing a polymeric region of a medical device to energetic species such that at least one surface sub-region of the polymeric region becomes crosslinked and at least one bulk sub-region remains substantially non-crosslinked. The polymeric region contains at least one copolymer, which includes at least one high Tg vinyl aromatic monomer and at least one low Tg monomer.Type: ApplicationFiled: May 11, 2007Publication date: November 13, 2008Inventors: Derek Sutermeister, Jay Rassat
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Patent number: 7423092Abstract: The present invention relates to radiation-curable compositions useful as ink vehicles or inks, in particular UV-curable inks, such as UV-litho inks, comprising a (meth)acrylated styrene allyl alcohol copolymer obtained from the (meth)acrylation of a styrene allyl alcohol (SAA) copolymer with (meth)acrylic acid and/or one or more alkyl(meth)acrylates, and at least one alkoxylated acrylated monomer.Type: GrantFiled: August 26, 2004Date of Patent: September 9, 2008Assignee: Cytec Surface Specialties, SAInventors: Isabelle Fallais, Luc Lindekens, Paul Gevaert
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Patent number: 7294673Abstract: A method of modifying a polymeric material whereby the polymeric material is modified to give a highly durable surface without decreasing its strength. Namely, a polymeric material is modified by the method comprising a combination of an impregnation step, an activation step, a step of grafting a monomer and a step of a treatment with a hydrophilic polymer. Thus, the hydrophilic nature, adhesiveness, and so forth of polymeric materials such as polyolefins can be improved without causing any decrease in the practical strength. The thus obtained polymeric materials are usable in articles with a need for high water absorptivity and high adhesiveness, for example, water-absorbing materials and water-retaining materials for medical, sanitary, cosmetic articles or supplies, agricultural materials, synthetic papers, filters and fiber products for clothes, for improving adhesiveness of composite materials and the like.Type: GrantFiled: June 28, 2002Date of Patent: November 13, 2007Assignee: FiberMark Gessner GmbH & Co.Inventor: Hitoshi Kanazawa
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Patent number: 7232595Abstract: Disclosed are photo or electron beam curable polymerizable compositions, and preparation thereof and devices containing such cured material. The composition contains completely or substantially completely hydrogenated hydrocarbon-based material completely free or substantially free of carbon-carbon double and triple bonds containing photo or electron beam curable terminal or pendant groups, low-outgassing photoinitiators, an optional viscosity adjustment component and an optional filler. The composition is visible light, UV or electron beam curable. It cures into a low-modulus, low outgassing polymer material. The composition can be used as an adhesive, sealant or lens potting material. It is ideal for use in lithographic tools and other optical devices involving deep or vacuum ultraviolet radiations, in particular, as lens potting materials for 248 nm, 193 nm and 157 nm lithographic tools, as well as other optical devices involving using high fluence irradiation.Type: GrantFiled: December 1, 2004Date of Patent: June 19, 2007Assignee: Corning IncorporatedInventors: Kelsee L. Coykendall, Paul G. Dewa, Robert Sabia, David Sauer, Paul J. Shustack, Kamal K. Soni
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Patent number: 7208532Abstract: A method for the production of a cross-linked support matrix that in form of a bed will permit liquid flow velocities above 5 cm/h, preferably above 50 cm/h, to pass through the bed. The method is characterized in that it comprises the steps: (a) providing a starting support matrix that has pendent unsaturated groups, and (b) subjecting said starting support matrix to electron beam or gamma-ray irradiation. The use of a cross-linked support matrix produced by a method comprising the steps of: (a) providing a starting support matrix that has pendent unsaturated groups, and (b) subjecting said starting support matrix to electron beam or gamma-ray irradiation as a support matrix in liquid chromatography, cell culturing, step-wise solid phase synthesis of organic compounds, running catalytic reactions by the use of a solid phase bound catalyst.Type: GrantFiled: December 11, 2000Date of Patent: April 24, 2007Assignee: GE Healthcare Bio-Sciences ABInventors: Eva Berggren, Dag Lindstrom
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Patent number: 7169827Abstract: A process for producing polypropylene having increased melt strength, the process comprising irradiating polypropylene which has been polymerised using a Ziegler-Natta catalyst with an electron beam having an energy of at least 5 MeV and a radiation dose of at least 10 kGray and mechanically processing the irradiated polypropylene to form long chain branches on the polypropylene molecules, whereby the polypropylene has a melt flow index (MFI) of at least 25 dg/min.Type: GrantFiled: June 27, 2001Date of Patent: January 30, 2007Assignee: Total Petrochemicals Research FeluyInventors: Guy Debras, Marc Dupire, Jacques Michel
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Patent number: 7163968Abstract: UV curable adhesives are provided that comprise epoxidized monohydroxylated polydiene polymers, hydrogenated hydroxylated polydiene polymers, and selectively hydrogenated starblock copolymers. The adhesive formulations provide both excellent room temperature properties of tack and peel and excellent holding power at temperatures as high as 95° C.Type: GrantFiled: March 16, 2004Date of Patent: January 16, 2007Assignee: Kraton Polymers U.S. LLCInventor: James R. Erickson
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Patent number: 7087660Abstract: This invention relates to a process of preparation of components and articles of manufacture containing at least one of such components, such as tires, and the resulting prepared components and fabricated articles, by use of directed high frequency energy internally heated silica-rich rubber compositions which contain sulfur curative and a significant content of high softening point polymer, namely a polymer and/or elastomer having a melting point (Tm) and/or high glass transition temperature (Tg) above 0° C., and particularly above 30° C., and which contains a minimal, if any, carbon black reinforcement. Such directed high frequency energy heating is provided, individually, by directed radio frequency (electromagnetic) radiation and/or by directed microwave radiation.Type: GrantFiled: July 29, 2003Date of Patent: August 8, 2006Assignee: The Goodyear Tire & Rubber CompanyInventors: Thomas Robert Maier, Bruce Raymond Hahn, Brian John Doucet, Thierry Florent Edme Materne
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Patent number: 7019044Abstract: A process for producing polypropylene having increased melt strength, the process comprising (i) homopolymerising polypropylene or copolymerising propylene with one or more comonomers selected from ethylene and C4 to C101-olefins to produce a polypropylene homopolymer or copolymer respectively having a double bond concentration of at least 0.1 per 10,000 carbon atoms, (11) irradiating the polypropylene with an electron beam having an energy of at least 5 MeV and at radiation dose of at least 5 kGray, and (iii) melting and mechanically processing the melt of polypropylene to form long chain branches on the polypropylene molecules.Type: GrantFiled: June 27, 2001Date of Patent: March 28, 2006Assignee: Total Petrochemicals Research FeluyInventors: Guy Debras, Marc Dupire, Jacques Michel
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Patent number: 7015256Abstract: A photosensitive composition for forming a dielectric of the present invention comprising inorganic particles, an alkali developable resin and additives, wherein the additives comprise a compound having a quinonediazido group (C1), a compound containing at least two alkyletherified amino groups in the molecule (C2) and a thermal acid generator (C3), or wherein the inorganic particles comprise inorganic superfine particles (A-I) having a mean particle diameter of less than 0.05 ?m and inorganic fine particles (A-II) having a mean particle diameter of not less than 0.05 ?m. The composition can be calcined at low temperatures to form a dielectric layer with high dimensional precision, said layer having a high dielectric constant and a low dielectric loss. Also provided are a dielectric and an electronic part prepared from the composition.Type: GrantFiled: December 26, 2002Date of Patent: March 21, 2006Assignee: JSR CorporationInventors: Nobuyuki Ito, Hideaki Masuko, Satomi Hasegawa, Atsushi Ito, Katsumi Inomata
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Patent number: 6927242Abstract: A resin composition of the present invention is obtainable by adding a photo-polymerization initiator (d) to a resin solution (a) containing a modified product of a thermoplastic resin (A). The modified product is prepared by conducting radical polymerization of the thermoplastic resin (A) with a (co)polymer (B) of a copolymerizable monomer (C) comprising a monomer having an ?,?-mono-ethynically unsaturated group, or the monomer and other copolymerizable monomers in a weight ratio (A)1(B) of 1/9 to 9/1, in an organic solvent, or by conducting polymerization of a copolymerizable monomer (C) comprising a monomer having an ?,?-mono-ethylenically unsaturated group, or the monomer and other copolymerizable monomers in a weight ratio (A)/(C) of 1/9 to 9/1, in an organic solvent in the presence of the thermoplastic resin (A), and then conducting radical polymerization thereof. A paint including the resin composition and a process for forming a coating film are also disclosed.Type: GrantFiled: January 15, 2002Date of Patent: August 9, 2005Assignee: Mitsui Chemicals, Inc.Inventors: Keiichi Asami, Tsukasa Murakami, Yugo Hasegawa
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Patent number: 6924323Abstract: A compound shown by the general formula [1] (wherein R1, R2 and R3 are each independently an aromatic hydrocarbon residual group, Yn? is an anion derived from a carboxylic acid having 3 or more carbon atoms with substituted fluorine atoms, and n is 1 or 2, provided that R1, R2 and R3 each is not a phenyl group having substituents at an ortho and/or a meta position), and a composition consisting of the compound and a diazodisulfone compound are disclosed. Use of the compound or the compound as an acid generator for resists produces the effects of improving the profiles of ultra-fine patterns or diminishing sidewall irregularities in ultra-fine patterns. The compound is also useful as a cationic photopolymerization initiator.Type: GrantFiled: June 27, 2001Date of Patent: August 2, 2005Assignee: Wako Pure Chemical Industries, Ltd.Inventors: Masami Ishihara, Motoshige Sumino, Kazuhito Fukasawa, Naoki Katano, Shigeaki Imazeki
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Patent number: 6869981Abstract: The invention includes an optical fiber coating that exhibits the characteristics of a pressure sensitive adhesive. A viscoelastic window for the coating will include at least one set of coordinates that is within Quadrants 2, 3, or 4 or the Transition Flow Region of the Chang viscoelastic of the rheological master curves or will not include at least one set of coordinates that is not within Quadrant 1 of the Chang viscoelastic of the rheological master curves.Type: GrantFiled: March 1, 2002Date of Patent: March 22, 2005Assignee: Corning IncorporatedInventors: Edward J. Fewkes, Gregory F. Jacobs, Inna I. Kouzmina, Kevin R. McCarthy, Huan-Hung Sheng, Kristi L. Simonton
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Patent number: 6844136Abstract: This present invention discloses a photopolymerisable mixture comprising a polymer binder, a radically photopolymerisable component containing at least one photooxidisable group, a polyethylene glycol di(meth)acrylate containing 2 or more ethylene glycol units, a photoreducible dye and a metallocene. This mixture can be used for preparing high-speed light-sensitive recording materials showing a particularly high resolution, especially for small negative types.Type: GrantFiled: August 24, 2000Date of Patent: January 18, 2005Assignee: AGFA-GevaertInventors: Thorsten Lifka, Sabine Kosack, Thomas Leichsenring, Hans-Joachim Schlosser
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Patent number: 6822015Abstract: The object of the invention is to provide a rubber composition or its crosslinked product used for a rubber stopper for a medicament or a rubber article for a medical treatment, suitable for radiation treatments to be carried out for the purpose of sterilizing. Accordingly, the present invention provides a rubber composition or its crosslinked product used for a rubber stopper for a medicament or a rubber article for a medical treatment, comprising an isobutylene copolymer, as a predominant component, with a density of at most 0.95, capable of being readily subjected to a radiation treatment.Type: GrantFiled: January 30, 2002Date of Patent: November 23, 2004Assignee: Daikyo Seiko, Ltd.Inventor: Tomoyasu Muraki
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Patent number: 6803014Abstract: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.).Type: GrantFiled: July 10, 2002Date of Patent: October 12, 2004Assignee: Dow Global Technologies Inc.Inventors: Thoi H. Ho, Selim Bensason, Rajen M. Patel, Kimberly S. Houchens, Rona L. Reid, Pak-Wing S. Chum, Leonie K. Walsh
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Patent number: 6750267Abstract: Disclosed herein are radiation-curable polymers, a method of preparing radiation-curable polymers and compositions containing radiation-curable polymers. Radiation-curable polymers and compositions containing radiation-curable polymers are useful as coatings and adhesives.Type: GrantFiled: December 24, 2001Date of Patent: June 15, 2004Assignees: University of Massachusetts Lowell, Dow Corning CorporationInventors: Rudolf Faust, Savvas Hadjikyriacou, Toshio Suzuki, Maneesh Bahadur