Processes Of Preparing A Solid Polymer From Heterocyclic Nitrogen Monomers; Or Compositions Therefore, E.g., Carbazole, Etc. Patents (Class 522/167)
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Patent number: 12163017Abstract: Pressure sensitive macromolecular adhesive polymers and compositions capable of integrating fluoropolymeric properties with a catechol-amine functionality to form an adhesive system that allows bonding between metallic substrates and fluoropolymers are disclosed. Also disclosed are core-shell polymeric particles comprised of a core and a shell comprising a thermoplastic polydopamine polymer that may be prepared as a colloidal suspension and used as a hot-melt pressure sensitive adhesive capable of binding low surface energy materials, such as polyolefins and fluoropolymers, to diverse materials including metals.Type: GrantFiled: October 21, 2020Date of Patent: December 10, 2024Assignee: Nautilus Solutions, Inc.Inventors: Charles Terrell Williams, Edward Ewart La Fleur
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Patent number: 12122927Abstract: Provided is a photo-curable inkjet printing ink composition, comprising (A) an acrylicated amine compound having two photopolymerizable functional groups and two amino groups in a molecule, (B) a (meth)acrylic monomer having an alkoxy group, and (C) at least one selected from the group consisting of hexanediol acrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, and neopentyl glycol diacrylate hydroxypivalate, wherein a content of the component (A) is 3 to 18% by mass in the ink composition, wherein a content of the component (B) is 5 to 35% by mass in the ink composition, and wherein a content of the component (C) is 30 to 60% by mass in the ink composition.Type: GrantFiled: November 28, 2019Date of Patent: October 22, 2024Assignee: SAKATA INX CORPORATIONInventors: Okinori Nakashima, Takuya Myose, Jun Kawabata
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Patent number: 11999865Abstract: The present invention relates to photocurable compositions, comprising (A1) a N-vinyloxazolidinone of formula (I), wherein R1, R2, R3 and R4 are independently of each other a hydrogen atom or an organic group having not more than 10 carbon atoms, (A2) optionally one, or more second reactive diluents, (B) one, or more oligomers, and (C) a photoinitiator (C), wherein the amount of component (A1) is 5 to 70% by weight based on the amount of components (A1), (A2) and (B), wherein the viscosity of said photocurable composition is in the range 10 to 3000 mPa·s, preferably 10 to 1500 mPa·s at 30° C. The compositions, from which cured three-dimensional shaped articles having balanced mechanical properties combining stiffness with high toughness can be made, are particularly suitable for the production of three-dimensional articles by stereolithography and photopolymer jetting.Type: GrantFiled: September 20, 2019Date of Patent: June 4, 2024Assignee: BASF SEInventors: Giovanni D'Andola, Andre Fuchs, Edouard Loisel, Dagmar Pascale Kunsmann-Keitel, Erhard Guenther
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Patent number: 11947259Abstract: Provided is a photoinitiator composition containing an acylcarbazole derivative and a carbazolyl oxime ester. The photoinitiator composition is used in a photocurable composition, especially a photoresist formulation, and exhibits the best sensibilization effect when the molar ratio of the acylcarbazole derivative to the carbazolyl oxime ester photoinitiator is between 0.1 and 1.4.Type: GrantFiled: March 17, 2020Date of Patent: April 2, 2024Assignee: IGM (ANQING) HIGH TECHNOLOGY DEVELOPMENT CO., LTDInventors: Wenchao Zhao, Chenlong Wang, Jiaqi Li, Yonglin Wang
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Patent number: 11851517Abstract: A polymer dispersant includes a first block; and a second block, the first block has a structural unit derived from a first monomer having an imidazolium salt portion and a hydrophobic portion, and the second block has a structural unit derived from a second monomer having an imidazolium salt portion and a hydrophilic portion.Type: GrantFiled: July 29, 2020Date of Patent: December 26, 2023Inventor: Toshihiro Otake
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Patent number: 11827799Abstract: Provided is an ultraviolet curable silicone composition capable of being ejected via inkjet ejection. The composition of the invention is an ultraviolet curable silicone composition comprising: (A) an organopolysiloxane represented by the following general formula (1) wherein each R1 independently represents a group selected from a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms, an acryloyl group, a methacryloyl group, an alkyl acrylate group and an alkyl methacrylate group, while the component (A) has per molecule at least two groups selected from an acryloyl group, a methacryloyl group, an alkyl acrylate group and an alkyl methacrylate group; n represents a number satisfying 10?n?1,000; (B) a monofunctional (meth)acrylate compound having no siloxane structure; and/or (C) a multifunctional (meth)acrylate compound having no siloxane structure; and (D) a photopolymerization initiator.Type: GrantFiled: December 30, 2021Date of Patent: November 28, 2023Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Nobuaki Matsumoto, Taichi Kitagawa, Atsushi Yaginuma, Masaaki Shirota
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Patent number: 11773208Abstract: A cationic curable composition that generates a silanol group by light irradiation and is cured by heat, the cationic curable composition including: a cationic curable component; porous particles holding an aluminum chelate; and a photodegradable silicon compound that generates a silanol group by photodegradation.Type: GrantFiled: June 7, 2019Date of Patent: October 3, 2023Assignee: DEXERIALS CORPORATIONInventors: Kazunobu Kamiya, Hiroki Shibuya
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Patent number: 11773295Abstract: Methods of bonding together substrates that do not require use of primers, mixing, fixturing, or autoclaving. These methods can include the steps of disposing an adhesive layer on a bonding surface of either substrate, the adhesive layer comprising a curable composition that is dimensionally stable at ambient conditions; either before or after disposing the adhesive layer on the bonding surface, irradiating the adhesive layer with ultraviolet radiation to initiate curing of the curable composition; placing one substrate so as to be bonded to the other substrate by the adhesive layer; and allowing the adhesive layer to cure.Type: GrantFiled: June 6, 2022Date of Patent: October 3, 2023Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Cyrus A. Anderson, Thomas Q. Chastek, Xiao Gao, Kathleen S. Shafer, Sheng Ye
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Patent number: 11567360Abstract: A backlight unit for a liquid crystal display device, the backlight unit including: an light emitting diode (“LED”) light source; a light conversion layer disposed separate from the LED light source to convert light emitted from the LED light source to white light and to provide the white light to the liquid crystal panel; and a light guide panel disposed between the LED light source and the light conversion layer, wherein the light conversion layer includes a semiconductor nanocrystal and a polymer matrix, and wherein the polymer matrix includes a first polymerized polymer of a first monomer including at least two thiol (—SH) groups, each located at a terminal end of the first monomer, and a second monomer including at least two unsaturated carbon-carbon bonds, each located at a terminal end of the second monomer.Type: GrantFiled: August 10, 2020Date of Patent: January 31, 2023Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Hyun A Kang, Eun Joo Jang, Hyo Sook Jang, Shin Ae Jun
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Patent number: 11535709Abstract: Embodiments in accordance with the present invention encompass polyamic acid or polyimide polymers containing a reactive maleimide end group as well as photosensitive compositions made therefrom which are useful for forming films that can be patterned to create structures for microelectronic devices, microelectronic packaging, microelectromechanical systems, optoelectronic devices and displays. In some embodiments the compositions of this invention are shown to feature excellent hitherto unachievable mechanical properties. The negative images formed therefrom exhibit improved thermo-mechanical properties, among other property enhancements.Type: GrantFiled: March 5, 2020Date of Patent: December 27, 2022Assignee: PROMERUS, LLCInventors: Pramod Kandanarachchi, Cheryl Burns, Brian Knapp, Larry F Rhodes
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Patent number: 11098208Abstract: Provided is a multilayer lamination film for laser printing that does not require a special ink that discolors by laser light irradiation, and that makes it possible to obtain a printed line having high visibility by irradiation of laser light having a power sufficiently low to avoid damaging a base film. The multilayer lamination film for laser printing includes at least a base material layer, a printing layer, and a sealant layer. The printing layer is a layer made of an ink composition enabling printing by means of laser light. The ink composition is made of white ink containing at least a titanium oxide and a binder resin, the binder resin containing a crystalline component.Type: GrantFiled: April 3, 2017Date of Patent: August 24, 2021Assignee: DAI NIPPON PRINTING CO., LTD.Inventors: Aya Suzuki, Hiroshi Matsuzaki, Katsunobu Ito
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Patent number: 11041049Abstract: A dual curable thiol-ene composition comprising a polythiol, an unsaturated compound, a photoinitiator, an organic hydroperoxide (thermal initiator) and optionally a nitrogen-containing base, such as e.g. an N-heterocyclic compound (together with the organic hydroperoxide a redox initiator system). A cross-linked polymer prepared therefrom. A method of making such a polymer. A cured sealant comprising such a polymer. The sealant is preferably for use in aerospace.Type: GrantFiled: June 27, 2017Date of Patent: June 22, 2021Assignee: 3M Innovative Properties CompanyInventors: William H. Moser, Erik M. Townsend, Brian S. Lam, Jonathan D. Zook, Susan E. DeMoss, Sheng Ye, Andrew R. Davis, Michael D. Swan
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Patent number: 10968303Abstract: In various embodiments, the present invention provides a strong, synthetic elastomer materials (and related methods for making same) with mechanical properties that are controlled by the stereochemically-defined double bonds within their backbone, yet have physical properties that are derived from monomer selection and defined, modifiable, chain end groups. The use of the organocatalyzed, stereospecific addition of thiols to activated alkynes, affords isolated high molar mass materials (>100 kDa) via step-growth polymerization with high levels of cis- or trans-double bond content. Furthermore, in various aspects of the present invention, it has been found that changing the monomer composition and chain end groups provides additional control over the materials' physical properties to provide more efficient compounding with polar additives. Using this approach to elastomer synthesis, further end group modification and toughening through various vulcanization strategies are also possible.Type: GrantFiled: August 29, 2016Date of Patent: April 6, 2021Assignee: THE UNIVERSITY OF AKRONInventors: Matthew L. Becker, Andrew P. Dove, Vinh X. Truong, Craig A. Bell, Ian A. Barker, Jiayi Yu
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Patent number: 10920002Abstract: The present disclosure provides a novel method of 3D printing using frontal polymerization chemistry. This method enables the printing of tough, high quality thermosets in a short time with the option of adding fiber reinforcement. As such, it facilitates fabrication of mechanically robust 3D-printed devices and structures.Type: GrantFiled: May 14, 2018Date of Patent: February 16, 2021Assignee: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOISInventors: Jeffrey S. Moore, Scott R. White, Ian D. Robertson, Nancy R. Sottos, Jia En Aw
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Patent number: 10721950Abstract: The present invention is directed to a process for the removal of mycotoxins from insoluble plant-derived protein using density-based particle separators. The end product contains a substantial portion of the proteins, including insoluble proteins, and a low concentration of mycotoxin. The process is particularly useful for removing aflatoxins from corn meal protein.Type: GrantFiled: September 12, 2016Date of Patent: July 28, 2020Assignee: ARCHER DANIELS MIDLAND COMPANYInventors: Michael J. Cecava, Perry H. Doane, Thomas V. Gottemoller, Scott Tilton
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Patent number: 10655272Abstract: Fabrics are treated with a hydrophobic treatment that includes at least one hydrophobic monomer and a crosslinker. The treatment is low in volatile organic compounds and water. It is a liquid at 22° C. or a suspension having a phase that is liquid at 22° C. The monomer and crosslinker are cured in a free radical polymerization to form a hydrophobic coating on a fibrous substrate.Type: GrantFiled: October 16, 2017Date of Patent: May 19, 2020Assignee: Green Theme Technologies Inc.Inventor: Gary S. Selwyn
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Patent number: 10624820Abstract: Slip for the stereolithographic preparation of ceramic or glass ceramic shaped parts which comprises (a) at least one radically polymerizable monomer, (b) at least one photoinitiator, (c) ceramic and/or glass ceramic particles and (d) at least one non-ionic surfactant.Type: GrantFiled: September 23, 2016Date of Patent: April 21, 2020Assignee: Ivoclar Vivadent AGInventors: Lorenz Josef Bonderer, Jürgen Laubersheimer
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Patent number: 9987393Abstract: A thiol-yne polymeric material and methods for producing said polymers are disclosed. The material is produced by the radically mediated polymerization of monomers having alkyne and thiol functional groups. The alkyne moiety, internal or terminal, may react with one or two thiols. Degradable monomers may be used to form degradable polymers.Type: GrantFiled: January 18, 2017Date of Patent: June 5, 2018Assignee: THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODYInventors: Kristi Anseth, Ben Fairbanks, Christopher Bowman
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Patent number: 9617383Abstract: Synthesis of monodisperse PEG-based microparticles with stable coupling chemistries. Biomolecules are conjugated to monodisperse PEG microparticles using non-amine chemistries, such as sulfhydryl groups, azide, or alkyne-based chemistries.Type: GrantFiled: April 8, 2015Date of Patent: April 11, 2017Assignee: DNA Medicine Institute, Inc.Inventors: Eugene Y. Chan, Moon Bae
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Patent number: 9598534Abstract: Described are shape memory polymers and methods of making shape memory polymers and actuators from the shape memory polymers.Type: GrantFiled: October 29, 2015Date of Patent: March 21, 2017Assignee: The University of RochesterInventors: Mitchell Anthamatten, Yuan Meng
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Patent number: 9593248Abstract: Ink contains at least one of a compound represented by the following chemical formula 1, a compound represented by chemical formula 2, a compound represented by chemical formula 3, or a compound represented by chemical formula 4.Type: GrantFiled: May 27, 2014Date of Patent: March 14, 2017Assignee: Ricoh Company, Ltd.Inventors: Mitsunobu Morita, Soh Noguchi, Okitoshi Kimura
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Patent number: 9134608Abstract: A positive photosensitive resin composition including: (a) a resin capable of being dissolved in an aqueous alkaline solution; (b) a compound having two or more oxetanyl groups; (c) a diazonaphthoquinone compound; and (d) a solvent.Type: GrantFiled: January 18, 2011Date of Patent: September 15, 2015Assignee: HITACHI CHEMICAL DUPONT MICROSYSTEMS, LTD.Inventors: Masashi Kotani, Masayuki Ooe, Taku Konno, Tomonori Minegishi, Keishi Ono
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Patent number: 8999323Abstract: The present invention relates to a polymerization-curable composition for the preparation of biodegradable, biocompatible, cross-linked polymers on the basis of polyvinyl alcohol comprising: 5 to 100% by weight of (a) vinyl ester monomer(s) of one of the general formulas (I) to (III): wherein X is oxygen, sulfur, nitrogen, or phosphorus; n is 1 to 1000, at least 20% of the n being ?2; the R1 are selected from hydrogen; straight, branched or cyclic, saturated or unsaturated, n-valent hydrocarbon groups having 1 to 30 carbon atoms, which optionally have heteroatoms and are optionally substituted with one or more substituents selected from —OH, —COON, —CN, —CHO, and ?O, and n-valent radicals of biodegradable, biocompatible oligomers and polymers; m is an integer from 1 to 5; the R2 are selected from hydrogen, —OH, ?O, and the options listed for R1; and the R3 are selected from hydrogen, —OH, and the options listed for R1; 0 to 50% by weight of ethylenically unsaturated co-monomers; 0 to 10% by weight of (a)Type: GrantFiled: November 21, 2008Date of Patent: April 7, 2015Assignee: Technische Universität WienInventors: Robert Liska, Jürgen Stampfl, Franz Varga, Heinrich Gruber, Stefan Baudis, Christian Heller, Monika Schuster, Helga Bergmeister, Günter Weigel, Claudia Dworak
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Publication number: 20150090482Abstract: Provided are: a curable composition which can attain both good adhesion to a printed circuit board, particularly to a flexible substrate or the like; a resist coating film of the curable composition; and a printed circuit board comprising a resist pattern formed by the curable composition. By the present invention, a curable composition for a printed circuit board comprising (A) a compound having a triazine ring, (B) a (meth)acrylate compound having a hydroxyl group and (C) a photopolymerization initiator; a coating film obtained by photo-curing the curable composition; and a printed circuit board comprising a resist pattern formed by the curable composition, are obtained.Type: ApplicationFiled: September 30, 2014Publication date: April 2, 2015Applicant: TAIYO INK MFG. CO., LTD.Inventors: Masayuki SHIMURA, Yoshiyuki FURUTA, Masao YUMOTO
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Patent number: 8940808Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.Type: GrantFiled: October 13, 2010Date of Patent: January 27, 2015Assignees: Kabushiki Kaisha Toyota Jidoshokki, Toagosei Co., Ltd.Inventors: Tetsuya Mitsuoka, Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Naoharu Ueda, Kazumasa Inata, Takeshi Fujita, Yasuyuki Sanai, Eiichi Okazaki, Hiroshi Suzuki, Naomasa Furuta
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Patent number: 8937110Abstract: The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.Type: GrantFiled: December 19, 2012Date of Patent: January 20, 2015Assignee: Johnson & Johnson Vision Care, Inc.Inventors: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
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Publication number: 20150011672Abstract: The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.Type: ApplicationFiled: September 24, 2014Publication date: January 8, 2015Inventors: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
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Publication number: 20140364531Abstract: The present invention is: a curable resin composition comprising a thermoplastic resin (A), a curable monomer (B), and a photoinitiator (C), the thermoplastic resin (A) including an aromatic ring in its molecule, and having a glass transition temperature (Tg) of 140° C. or more, and the photoinitiator (C) having an absorbance at 380 nm of 0.4 or more when measured in a 0.1 mass % acetonitrile solution; a curable resin formed article obtained by forming the curable resin composition; a cured resin formed article obtained by curing the curable resin formed article; a laminate comprising at least one layer that is formed of a cured resin obtained by curing the curable resin composition. The present invention provides: a cured resin formed article that exhibits excellent heat resistance, includes only a small amount of residual low-boiling-point substance (e.g.Type: ApplicationFiled: December 11, 2012Publication date: December 11, 2014Inventors: Masaharu Ito, Wataru Iwaya, Hironobu Fujimoto, Naoki Taya
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Patent number: 8883392Abstract: A radiation curing composition suitable for building a three-dimensional object by a solid freeform method is disclosed. The composition includes one or more mono-functional monomers where a respective polymer has a Glass Transition Temperature higher than about 60° C., one or more di-functional oligomers where a respective polymer has a Glass Transition Temperature lower than about 40° C. and a phase separation inducing component. The phase separation may be induced during curing, resulting in a non-clear cured material having an improved impact strength and higher elongation, when compared to similar compositions without a phase separation inducing component.Type: GrantFiled: June 13, 2013Date of Patent: November 11, 2014Assignee: Stratasys Ltd.Inventors: Eduardo Napadensky, David Brusilovsky
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Publication number: 20140315115Abstract: The present invention concerns the preparation of an anion binder for a solid alkaline fuel cell which enhances durability to electrochemical reactions and makes the production of electrode slurry easy. A method of preparing an anion binder for a solid alkaline fuel cell includes: (A) mixing an electrolytic monomer of quaternary ammonium salts having a cation group, a bisacrylicamide crosslinking agent having a tertiary amino group, and water together by stirring; (B) mixing the mixture with a photoinitiator; (C) interposing the solution between polyethylene terephthalate films and irradiating the solution with ultraviolet light for crosslinking and polymerization; and (D) pulverizing crosslinked polymerized resin to a nano size.Type: ApplicationFiled: June 24, 2013Publication date: October 23, 2014Inventors: Young Woo Choi, Mi Soon Lee, Tae Hyun Yang, Chang Soo Kim, Young Gi Yoon, Seok Hee Park, Sung Dae Yim, Gu Gon Park, Young Jun Sohn, Minjin Kim, Byungchan Bae
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Patent number: 8853338Abstract: Presently described are curable dental compositions comprising a polymerizable ionic liquid. The polymerizable ionic liquid comprises one or more ethylenically unsaturated (e.g. free-radically polymerizable) groups. Various embodiments of curable dental compositions are described. In some embodiments, the polymerizable ionic liquid is a monofunctional polymerizable ionic liquid comprising an ethylenically unsaturated group. In other embodiments, the polymerizable ionic liquid is a multifunctional polymerizable ionic liquid comprising at least two ethylenically unsaturated groups. The curable dental compositions describe herein can be utilized as dental primers, dental adhesives, dental sealants, and dental composites. In many embodiments, the curable dental compositions further comprise an initiator such as a photoinitiator.Type: GrantFiled: December 6, 2010Date of Patent: October 7, 2014Assignee: 3M Innovative Properties CompanyInventors: Yizhong Wang, Joel D. Oxman, Larry R. Krepski, Peiwang Zhu, Kevin M. Lewandowski, Brian N. Holmes
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Publication number: 20140271774Abstract: Coatings for a surface, especially a priming coating, of the present invention have been found to be durable, resistant to oxidative degradation, erosion and depolymerisation, stable to sterilization and low particulating, and are easily applied to the required surface of a substrate in a surface-independent manner. Such coatings, when used as priming coatings to be coated with a subsequent coating, in at least some embodiments, form exterior coatings which are also highly durable and are stable to sterilisation and aging.Type: ApplicationFiled: March 13, 2014Publication date: September 18, 2014Applicant: W. L, Gore & Associates, Inc,Inventors: Paul D. Drumheller, Charles D. Claude
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Publication number: 20140248498Abstract: The present invention relates to a method for producing an optical member, in which at least two optical substrates, of which at least either has a light shielding portion, are bonded to each other using an ultraviolet ray cured resin composition containing (A) a (meth)acrylate and (B) a photopolymerization initiator, the method having specific Process 1 to Process 3, an optical member obtained by the producing method, the use of an ultraviolet ray cured resin composition containing (A) a (meth)acrylate and (B) a photopolymerization initiator, and the ultraviolet ray cured resin composition.Type: ApplicationFiled: October 19, 2012Publication date: September 4, 2014Applicant: Nippon Kayaku Kabushiki KaishaInventors: Daisuke Kobayashi, Hayato Motohashi, Yuichiro Matsuo
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Patent number: 8816029Abstract: Presently described are curable compositions comprising a mixture of at least one (e.g. free-radically) polymerizable ionic liquid and at least one other ethylenically unsaturated monomer, oligomer, or polymer. The polymerizable ionic liquid is characterized as having an air to nitrogen curing exotherm ratio of at least 0.70. Also described are articles and methods of making articles from such curable compositions. A monofunctional polymerizable ionic liquid is also described comprising a non-polymerizable substituted imidazolium cationic group and a polymerizable sulfonate anion.Type: GrantFiled: August 26, 2010Date of Patent: August 26, 2014Assignee: 3M Innovative Properties CompanyInventors: Yizhong Wang, Joel D. Oxman, Larry R. Krepski, Peiwang Zhu, Kevin M. Lewandowski, Brian N. Holmes, Richard L. Severance, Joseph D. Rule, Thomas P. Klun
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Publication number: 20140235746Abstract: There is provided a curable resin composition that exhibits high adhesive properties to materials such as glass, copper, aluminum, PET, and PC, which have been regarded as poor adherends relative to photo-curable compositions, and high adhesive properties also between adherends different from each other. A curable resin composition including a polyene compound of Formula (1): (where n1, n2, and n3 are each independently an integer of 2 to 4; and R1 to R9 are each independently a hydrogen atom or a C1-10 alkyl group). The composition may further include a thiol compound or a photopolymerization initiator. The thiol compound may be a compound having two to six thiol groups in the molecule, or be an aliphatic thiol, or be produced by a reaction of an aliphatic mercapto carboxylic acid and a polyhydric alcohol. The polyhydric alcohol may be an aliphatic polyhydric alcohol or hydroxyalkyl isocyanurate.Type: ApplicationFiled: September 24, 2012Publication date: August 21, 2014Inventors: Kentaro Ohmori, Takeo Moro, Yuki Endo
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Publication number: 20140228468Abstract: A curing-type coating-agent composition according to the present invention contains: Component (A) (e.g., an isocyanuric ring-containing urethane (meth)acrylate compound) in an amount of from 20 to 80 parts by mass; Component (B) (e.g., an isocyanuricring-containing tri(meth)acrylate compound free from any urethane bond) in an amount of from 10 to 70 parts by mass; Component (C-1) (e.g., a reaction compound between a colloidal silica and an alkoxysilane compound having a maleimide group) in amount of from 1 to 35 parts by mass, or Component (C-2) (e.g., a specific organosilicon compound) in an amount of from 5 to 35 parts by mass; a radical-polymerization initiator serving as Component (D) in an amount of from 0.Type: ApplicationFiled: August 27, 2012Publication date: August 14, 2014Applicants: TOAGOSEI CO., LTD., KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Hiroaki Takashima, Kyoko Kumagai, Hidetaka Hayashi, Tetsuya Mitsuoka, Naoharu Ueda, Hisashi Muramatsu, Kazumasa Inata, Takeshi Fujita, Yasuyuki Sanai, Eiichi Okazaki, Satoshi Yoneda, Naomasa Furuta
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Patent number: 8796350Abstract: An ultraviolet (UV) crosslinkable acrylic pressure sensitive adhesive comprises an acrylic copolymer and a cationic photoinitiator. The acrylic copolymer comprises pendant reactive functional groups. The pressure sensitive adhesive formed from the acrylic copolymer with the pendant reactive functional groups result in high green strength and/or high temperature holding strength of the adhesive.Type: GrantFiled: September 7, 2012Date of Patent: August 5, 2014Assignee: Henkel US IP LLCInventors: Yuxia Liu, Peter Palasz, Charles W. Paul, Paul B. Foreman
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Patent number: 8796349Abstract: There is provided a photosensitive resin composition for microlenses. A photosensitive resin composition for microlenses including a component (A), a component (B) and a solvent. The component (A): a copolymer having a maleimide structural unit of Formula (1) and a repeating structural unit of Formula (2). The component (B): a photosensitizer (in Formula (2), R0 is a hydrogen atom or a methyl group; R1 is a single bond or a C1-5 alkylene group; R2 is a thermally cross-linkable monovalent organic group; and in the repeating structural unit of Formula (2), R0s are optionally different from each other).Type: GrantFiled: November 21, 2011Date of Patent: August 5, 2014Assignee: Nissan Chemical Industries, Ltd.Inventors: Hiroyuki Soda, Takahiro Sakaguchi, Takahiro Kishioka
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Publication number: 20140213685Abstract: A material is provided for contact lens including a first siloxane macromer represented by the following formula (I): wherein R1, R2 and R3 are independently C1-C12 hydroxyl group, C1-C12 alkyl groups or C1-C12 siloxane group; R4 is C1-C6 alkylene group or C1-C6 alkylene substituted with ether group; R5 is —H, —CH3, —CH(CH3)2, —CH(CH3)CH2(CH3), —CH2CH(CH3)2, —CH2C6H5, —CH2OH, —CH(OH)CH3, —CH2CONH2 or —CH2CH2CONH2: R6 is —NHCONH—, —NHCO—, —R8NHCONH— or —R8NHCO—, wherein R8 is —O—, —O(CH2)n— or —(CH2)n— and n is an integer of 1-10; R7 is hydrogen or methyl; and m is an integer of 10-100.Type: ApplicationFiled: June 13, 2013Publication date: July 31, 2014Inventor: Fan-Dan JAN
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Publication number: 20140160215Abstract: An active-energy-ray-curable inkjet recording ink composition is provided, in which a polymerizable compound having an active-energy-ray-polymerizable group and a polymerizable compound having at least two active-energy-ray-polymerizable groups are used in amounts of 60 to 95 mass % and 5 to 40 mass % relative to the total amount of the active-energy-ray-polymerizable compound, respectively; the polymerizable compound having an active-energy-ray-polymerizable group includes N-vinyl-2-caprolactam and isobornyl acrylate in amounts of 1 to 15 mass % and 1 to 25 mass % relative to the total amount of the active-energy-ray-polymerizable compound, respectively; and the polymerizable compound having at least two active-energy-ray-polymerizable groups includes a polymerizable compound having a vinyl ether group. Furthermore, a method for forming an image is provided.Type: ApplicationFiled: May 30, 2012Publication date: June 12, 2014Applicant: DIC CORPORATIONInventors: Naohito Saito, Yutaka Yamada, Maiko Kitade
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Patent number: 8729402Abstract: An object of the present invention is to provide (i) a polyimide precursor composition which is curable at a low temperature (not more than 250° C.) and which has a low viscosity despite having a high concentration, and a production method thereof, (ii) a polyimide coating film obtained from the polyimide precursor composition and having good properties, and a production method thereof, (iii) a photosensitive resin composition prepared by use of the polyimide precursor composition, and a production method thereof. The object of the present invention can be attained by a polyimide precursor composition containing an imidized tetracarboxylic acid having a specific structure and an isocyanate compound having a specific structure, or optionally a diamine.Type: GrantFiled: May 14, 2009Date of Patent: May 20, 2014Assignee: Kaneka CorporationInventor: Yoshihide Sekito
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Publication number: 20140135417Abstract: Provided is a transparent pressure-sensitive adhesive agent convertible into an adhesive agent that allows adherends to be instantly fixed to each other, allows the adherends to be reattached to each other, is excellent in processability such as being able to be cut into a sheet shape, is not peeled from the adherends even when exposed to a high-temperature atmosphere such as one in a fire, and has such transparency as to hardly impair the designs of the adherends. The transparent pressure-sensitive adhesive agent convertible into an adhesive agent has pressure-sensitive adhesive property before being sintered, and has adhesive property after being sintered.Type: ApplicationFiled: July 13, 2012Publication date: May 15, 2014Applicant: NITTO DENKO CORPORATIONInventors: Yusuke Sugino, Kunio Nagasaki, Kohei Doi, Takafumi Hida, Yusuke Nakayama
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Publication number: 20140128496Abstract: Provided is an ultraviolet-curable ink jet ink composition with excellent curability and storage stability, the composition containing a monomer A represented by Formula (I): CH2?CR1—COOR2—O—CH?CH—R3 (wherein R1 represents a hydrogen atom or a methyl group, R2 represents a C2-C20 divalent organic residue, and R3 represents a hydrogen atom or a C1-C11 monovalent organic residue); a (meth)acrylated amine compound; a hindered amine compound other than the (meth)acrylated amine compound; and a photopolymerization initiator.Type: ApplicationFiled: January 15, 2014Publication date: May 8, 2014Applicant: Seiko Epson CorporationInventors: Hiroaki KIDA, Chigusa SATO, Hiroyuki KAJIMOTO, Toru SAITO
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Publication number: 20140109784Abstract: The present invention relates to a curable jettable fluid for making a flexographic printing master characterized in that the jettable fluid comprises a monofunctional (meth)acrylate monomer, a polyalkylene glycol di(meth)acrylate monomer of which the polyalkylene glycol chain has a MW of at least 300 and at least 1 wt. % of a difunctional (meth)acrylate monomer according to Formula I) or (II), wherein k and m in Formula (I) is an integer ranging from 0 to 5, l in Formula (I) is an integer ranging from 1 to 20, n in Formula (II) is 1, 2, 3 or 4, R in Formula (I) and (II) is H or CH3, and R? in Formula (II) is H or an alkyl group.Type: ApplicationFiled: June 18, 2012Publication date: April 24, 2014Applicant: AGFA GRAPHICS NVInventors: Eddie Daems, Luc Vanmaele
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Publication number: 20140104356Abstract: An active-energy-ray-curable ink jet recording ink composition is provided, in which (1) a polymerizable compound having an active-energy-ray-polymerizable group and a polymerizable compound having at least two active-energy-ray-polymerizable groups are used in amounts of 10 to 25 mass % and 75 to 90 mass % relative to the total amount of the active-energy-ray-polymerizable compounds, respectively; (2) the polymerizable compound having an active-energy-ray-polymerizable group includes 10 to 20 mass % of N-vinylcaprolactam; and (3) the polymerizable compound having at least two active-energy-ray-polymerizable groups includes 15 to 35 mass % of 2-(2-vinyloxyethoxy)ethyl(meth)acrylate. Furthermore, a method for forming an image is provided.Type: ApplicationFiled: May 30, 2012Publication date: April 17, 2014Applicant: DIC CorporationInventors: Maiko Kitade, Yutaka Yamada, Naohito Saito
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Patent number: 8691924Abstract: The present invention provides an optical-use pressure-sensitive adhesive sheet, which includes a pressure-sensitive adhesive layer containing a polymer formed of one or more monomer ingredients containing, as an indispensable monomer ingredient, a monomer of which homopolymer has a glass transition temperature of not lower than ?10° C., said sheet having a moisture content of at least 0.65% by weight after stored in an environment at 60° C. and 95% RH for 120 hours. The pressure-sensitive adhesive layer is preferably an acrylic pressure-sensitive adhesive layer.Type: GrantFiled: November 8, 2010Date of Patent: April 8, 2014Assignee: Nitto Denko CorporationInventors: Shou Takarada, Takahiro Nonaka, Hiroaki Kishioka, Hiroaki Fumoto, Tomohide Banba, Masayuki Okamoto, Masahito Niwa
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Patent number: 8669300Abstract: The present invention is related to a radiation curable binder, comprising the reaction product of a polyisocyanate having 3 free isocyanate moieties with an acrylate having isocyanate-reactive groups and a component selected from the group consisting of a C12-C22 carboxylic acid having one isocyanate-reactive group or a C12-C22 fatty alcohol. The present invention is furthermore related to a radiation curable printing ink, comprising said binder, at least one diluent, at least one pigment, and optionally additives, as well as to a process of preparing said radiation curable binder. Said binder or said printing ink can be used in offset printing or letterpress printing.Type: GrantFiled: March 19, 2009Date of Patent: March 11, 2014Assignee: Siegwerk Druckfarben AG & Co. KGaAInventors: Gilles Eisele, Thierry Marsille, Gilles Catherin
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Publication number: 20140031447Abstract: The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.Type: ApplicationFiled: December 19, 2012Publication date: January 30, 2014Applicant: Johnson & Johnson Vision Care, Inc.Inventor: Johnson & Johnson Vision Care, Inc.
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Publication number: 20130323291Abstract: A hydrophilic copolymer is designed and synthesized by copolymerization of an acidic monomer and a second hydrophilic monomer. The copolymer is non-thrombogenic, hydrophilic and incorporates reactive functional groups. The copolymer can then be covalently attached to a primer/base coat through its functional groups, to form a durable lubricious coating on medical devices. A coating formed of the polymer on a surface is non-thrombogenic and non-cytotoxic. The coating shows good stability in gamma ray, e-beam and ethylene oxide sterilization.Type: ApplicationFiled: May 31, 2012Publication date: December 5, 2013Applicant: BIOCOAT INCORPORATEDInventors: Junwei Li, William J. Work
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Publication number: 20130295342Abstract: An active energy ray-curable ink composition includes (component A) monofunctional radically polymerizable monomers, (component B) a polyfunctional oligomer having a glass transition temperature of 20° C. or lower and an acrylate value of 300 g/value or more, and (component C) a bifunctional radically polymerizable monomer having a viscosity at 25° C. of 15 mPa·s or less, wherein the component A includes an N-vinyl compound and a compound represented by the following formula (I), the content of the N-vinyl compound with respect to the total amount of the ink composition is from 10 to 50% by mass, and the content of the component A with respect to the total amount of the ink composition is 70% by mass or more.Type: ApplicationFiled: April 18, 2013Publication date: November 7, 2013Inventors: Kenjirou ARAKI, Atsushi SAKAMOTO, Kazuhiro YOKOI