Mercapto Group Attached Directly To Aromatic Ring, E.g., Thiophenol, Etc. Patents (Class 522/56)
  • Patent number: 8507573
    Abstract: There is provided an inkjet ink which has satisfactory storage stability and inkjet ejection stability, exhibits excellent curability, and is capable of forming high quality images on coated paper by an inkjet system. Disclosed is an active energy ray curable inkjet ink composition comprising: 15-75% by weight of at least one polymerizable bifunctional monomer selected from the group consisting of dipropylene glycol diacrylate and 1,9-nonanediol diacrylate; and 1% by weight to 10% by weight of [4-(methylphenylthio)phenyl]phenylmethanone as a photopolymerization initiator.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: August 13, 2013
    Assignees: Toyo Ink SC Holdings Co., Ltd., Toyo Ink Co., Ltd.
    Inventors: Yuji Kameyama, Norio Suzuki, Yohei Konda, Kazuhiro Jonai
  • Patent number: 8361605
    Abstract: A photosensitive resin composition which is effective in avoiding troubles in the step of plating with various metals in printed wiring board production, such as under-film metal deposition and film peeling, and which forms a wiring-protecting film excellent in adhesion, flexibility, insulation reliability, and heat resistance. The photosensitive resin composition comprises (A) a carboxylated polymer, (B) a compound having at least two photopolymerizable unsaturated double bonds, (C) a photopolymerization initiator, and (D) a nitrogen compound represented by a specific feature.
    Type: Grant
    Filed: April 23, 2008
    Date of Patent: January 29, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Katsuhiko Funaki, Etsuo Ohkawado, Kousuke Hirota, Syuji Tahara
  • Publication number: 20120040190
    Abstract: An improved coating system for an ophthalmic lens that provides improved characteristics in the form of abrasion resistance, while also providing improved manufacturability and rapid curing as compared to prior art coating systems. The coating system is a composite coating that hybridizes both epoxy and acrylate coating materials into a single coating system. The coating material of the present disclosure includes at least a poly (meth) acrylate polymer, a polymerizable monomer containing at least one epoxy group and a cationic polymerization initiator. The coating may be further enhanced by the addition of colloidal nano-silica particles that serve to reinforce the mechanical properties of the coating system without compromising the overall transparency and optical clarity of the coating.
    Type: Application
    Filed: July 11, 2011
    Publication date: February 16, 2012
    Applicant: HONEYWELL INTERNATIONAL, INC.
    Inventors: Xiaorong You, Phil Johnson
  • Publication number: 20120003435
    Abstract: There is provided an inkjet ink which has satisfactory storage stability and inkjet ejection stability, exhibits excellent curability, and is capable of forming high quality images on coated paper by an inkjet system. Disclosed is an active energy ray curable inkjet ink composition comprising: 15-75% by weight of at least one polymerizable bifunctional monomer selected from the group consisting of dipropylene glycol diacrylate and 1,9-nonanediol diacrylate; and 1% by weight to 10% by weight of [4-(methylphenylthio)phenyl]phenylmethanone as a photopolymerization initiator.
    Type: Application
    Filed: June 29, 2011
    Publication date: January 5, 2012
    Applicants: TOYO INK CO., LTD., TOYO INK SC HOLDINGS CO., LTD.
    Inventors: Yuji KAMEYAMA, Norio SUZUKI, Yohei KONDA, Kazuhiro JONAI
  • Publication number: 20110262711
    Abstract: Curable, phase-change compositions and inks used for printing three-dimensional objects including a curable monomer, a photoinitiator, a wax and a gellant, where the composition of the cured formulation has a room temperature modulus of from about 0.01 to about 5 Gpa. The curable monomer includes acrylic monomer, polybutadiene adducted with maleic anhydride, aliphatic urethane acrylate, polyester acrylate, 3-acryloxypropyltrimethoxysilane, or acryloxypropyl t-structured siloxane.
    Type: Application
    Filed: April 22, 2010
    Publication date: October 27, 2011
    Applicant: XEROX CORPORATION
    Inventors: Naveen CHOPRA, Michelle N. Chretien, Barkev Keoshkerian
  • Publication number: 20110195194
    Abstract: A UV radiation curable composition includes a cationic photoinitiator according to Formula (I) or (II): wherein R1, R2 and R3 independently represent a group selected from the group consisting of an aryl group and a heteroaryl group, with the proviso that R1, R2 and R3 are each substituted by at least one substituent including at least one cationically polymerizable group selected from the group consisting of an alkenyl ether, an epoxide and an oxetane; and P and Q independently represent the necessary atoms to form a substituted or unsubstituted 5 or 6-membered aromatic or heteroaromatic ring, with the proviso that at least one of P, Q and L is substituted by at least one substituent including at least one cationically polymerizable group, selected from the group consisting of an alkenyl ether, an epoxide and an oxetane; and L represents a group selected from the group consisting of a direct bond, O, S, SO, SO2, CR5R6, C(?O), S(?O), C(NR8) and NR7.
    Type: Application
    Filed: December 1, 2009
    Publication date: August 11, 2011
    Applicant: AGFA GRAPHICS NV
    Inventor: Johan Loccufier
  • Publication number: 20110123723
    Abstract: A photosensitive resin composition comprises: 0.01 wt %-10 wt % of reflective particles; 0 wt %-12 wt % of pigment; 1 wt %-10 wt % of dispersant; 1.5 wt %-5 wt % of dispersion resin; 2 wt %-25 wt % of optically active polymer; 1 wt %-22 wt % of optical active monomer; 0.4 wt %-5 wt % of epoxy resin; 5 wt %-85 wt % of solvent; 0.1 wt %-3 wt % of photoinitiator; and 0.01 wt %-3.5 wt % of additives.
    Type: Application
    Filed: November 24, 2010
    Publication date: May 26, 2011
    Applicant: BOE TECHNOLOGY GROUP CO., LTD.
    Inventor: Jiuxia YANG
  • Patent number: 7740482
    Abstract: Stable and substantially filled cationic dental compositions are described which include: (1) at least one cationically reactive compound (A); (2) at least one dental filler (B); (3) optionally, at least one dispersant (C) composed of at least one organic polymer or copolymer; (4) at least one cationic photoinitiator (D); and (5) optionally, at least one photosensitizer (E). The dental filler (B) is treated with at least one organosilicon coupling agent (F), and at least one compound (G). The organosilicon coupling agent (F) has at least one reactive function (rfA) directly linked to a silicon atom forming after activation of a chemical bond with the dental filler, and at least one reactive function (rfB) not directly linked to a silicon atom, forming after activation, a chemical bond with a reactive function (rfC) of the compound (G).
    Type: Grant
    Filed: May 2, 2008
    Date of Patent: June 22, 2010
    Assignee: Bluestar Silicones France
    Inventors: Jean-Marc Frances, Martial Deruelle, Yves Giraud
  • Patent number: 7709546
    Abstract: An ink composition is provided that includes a compound represented by Formula (I) or (II). (In Formulae (I) and (II), R1 and R2 independently denote a monovalent substituent, R3 to R6 independently denote a hydrogen atom or a monovalent substituent, n denotes an integer of 0 to 5, and n? denotes an integer of 0 to 5; n and n? are not both 0, when n is 2 or greater a plurality of R1s may be identical to or different from each other, and when n? is 2 or greater a plurality of R2s may be identical to or different from each other.) There are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: May 4, 2010
    Assignee: FUJIFILM Corporation
    Inventors: Tomotaka Tsuchimura, Tetsunori Matsushita
  • Publication number: 20090163615
    Abstract: The present application provides a latent ink-jet ink formulation suitable as solder mask. The composition generally comprises: (a) at least one compound capable of self cross-linking (USM); (b) at least one phenolic resin; (c) at least one solvent; (d) at least one mineral filler; (e) at least one polyol; and (f) at least one photoinitiator.
    Type: Application
    Filed: August 31, 2006
    Publication date: June 25, 2009
    Inventors: Izhar Halahmi, Shalom Luski, Michal Cohen
  • Patent number: 6916919
    Abstract: The present invention relates to a process for separating nucleic acid molecules, preferably open circular and supercoiled plasmid DNA and RNA molecules from each other, comprising the steps of providing a solution comprising the molecules; adsorbing the molecules to adsorbing groups on a carrier; and optionally washing the column with a suitable solution. The present process is especially suitable for large-scale isolation of supercoiled ccc DNA to be used in gene therapy.
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: July 12, 2005
    Assignee: Amersham Biosciences AB
    Inventors: Raf Lemmens, Tomas Nyhammar, Jan Berglof, Joachim Stadler
  • Patent number: 6824858
    Abstract: A photocurable and thermosetting composition which is useful in forming a matte film and can be developed with an aqueous alkaline solution is provided. The composition comprises (A) a photosensitive prepolymer obtained by causing a saturated or unsaturated polybasic acid anhydride to react with a hydroxyl group of an esterification product of a novolak type epoxy compound and an unsaturated monocarboxylic acid, (B) a carboxyl group-containing copolymer resin, (C) a photopolymerization initiator, (D) a diluent, (E) a polyfunctional epoxy compound having at least two epoxy groups in its molecule, and, when necessary, (F) an inorganic filler. The composition may further comprise (G) an epoxy resin curing agent. This composition can be advantageously used for the formation of a solder resist on a printed circuit board.
    Type: Grant
    Filed: August 13, 2002
    Date of Patent: November 30, 2004
    Assignee: Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Satoru Iwaida, Yoshihiro Ohno, Masayuki Isono, Akio Sekimoto
  • Publication number: 20030082355
    Abstract: A photocurable and thermosetting composition which is useful in forming a matte film and can be developed with an aqueous alkaline solution is provided. The composition comprises (A) a photosensitive prepolymer obtained by causing a saturated or unsaturated polybasic acid anhydride to react with a hydroxyl group of an esterification product of a novolak type epoxy compound and an unsaturated monocarboxylic acid, (B) a carboxyl group-containing copolymer resin, (C) a photopolymerization initiator, (D) a diluent, (E) a polyfunctional epoxy compound having at least two epoxy groups in its molecule, and, when necessary, (F) an inorganic filler. The composition may further comprise (G) an epoxy resin curing agent. This composition can be advantageously used for the formation of a solder resist on a printed circuit board.
    Type: Application
    Filed: August 13, 2002
    Publication date: May 1, 2003
    Inventors: Satoru Iwaida, Yoshihiro Ohno, Masayuki Isono, Akio Sekimoto
  • Patent number: 6489374
    Abstract: The invention relates to &agr;-ammonium alkenes, iminium alkenes and amidinium alkenes in the form of their tetraaryl- or triaryl-alkylborate salts that can be converted photochemically into amines, imines or amidines, and to a process for the preparation thereof. The invention relates also to compositions polymerisable or crosslinkable under basic conditions comprising such &agr;-ammonium alkenes, iminium alkenes or amidinium alkenes in the form of their tetra- or tri-arylalkylborate salts, to a method of carrying out photochemically induced, base-catalysed reactions, and to the use of such compounds as photoinitiators for base-catalysed reactions.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: December 3, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Gisèle Baudin, Sean Colm Turner, Allan Francis Cunningham
  • Patent number: 6313257
    Abstract: Polyfunctional mercaptoalkyl-substituted aryl compounds, one and two-part adhesive compositions including the compounds, and methods of making and using the compounds are disclosed. The compounds include one or more aromatic rings, wherein at least one, and in one embodiment, only one aromatic ring is substituted with at least one alkylthio group and at least one oxyalkylthio group, and preferably do not include hydrolyzable linkages. The aromatic nucleus can provide the cured products with higher glass transition temperatures (Tg's) than are available from most commercially available polymercaptans. The adhesive systems include an epoxy resin or other compounds such as terminal olefins which are known to react with thiols (polymerizable material). Preferably, the compounds are used in combination with amine curatives as a two-component curing system for epoxy resins.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: November 6, 2001
    Assignee: Lord Corporation
    Inventor: Kirk J. Abbey
  • Patent number: 6156815
    Abstract: 1,2-Disulfones are particularly suitable as thermally and photochemically activatable latent acid catalysts for binder systems which contain at least one acid-curable component.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: December 5, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ekkehard Bartmann, Jorg Ohngemach
  • Patent number: 5429846
    Abstract: The present invention provides a photo-setting conductive coating composition which is used as an antistatic material constituting articles wherein static electrification must be avoided, such as storage vessels for semi-conductor wafers, electronic/electric parts, floor/wall coverings for a production factory of semi-conductors, etc.The photo-setting conductive coating composition comprising 100 parts by weight of an antimony oxide-containing tin oxide powder (a) having a particle size of 0.01 to 0.4 .mu.m, 10 to 100 parts by weight of a (meth)acrylate compound (b) having at least two (meth)acryloyl groups in a molecule, 10 to 100 parts by weight of an acetal resin (c) having a residual hydroxyl group of 20 to 80 molar %, 0.1 to 10 parts by weight of a photopolymerization initiator (d) and 100 to 1000 parts by weight of an organic solvent (e).
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: July 4, 1995
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Toshiya Sugimoto, Minoru Suezaki, Kouji Maruyama
  • Patent number: 5399782
    Abstract: Compounds of formula I ##STR1## wherein n is 0 or 1, p is a number from 1 to 8,q is 2 or 3, andR.sub.1 is unsubstituted phenyl or phenyl which is substituted by one to three halogen, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.2 -C.sub.8 alkoxyalkyl or/and C.sub.1 -C.sub.4 alkylthio, are suitable for use as initiators for photopolymerising compounds containing ethylenically unsaturated double bonds.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: March 21, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: David G. Leppard, Ljubomir Misev, Gebhard Hug
  • Patent number: 4826888
    Abstract: A photopolymerizable composition comprising a vinyl monomer, a mercaptocarboxylic acid/.alpha.-diketone photopolymerization initiator and a storage stabilizer. The composition may admit of a filler, and exhibits excellent mechanical strength, storage stability, color and resistance to coloring, and availability.
    Type: Grant
    Filed: April 2, 1986
    Date of Patent: May 2, 1989
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Isao Sasaki, Nobuhiro Mukai, Hitoshi Ige
  • Patent number: 4762887
    Abstract: A process for preparing radiation polymerizable acrylate-functional organopolysiloxane-urethane copolymers by reacting aminofunctional polysiloxanes with acrylated urethane oligomers in the presence of a solvent.
    Type: Grant
    Filed: January 15, 1987
    Date of Patent: August 9, 1988
    Assignee: Wacker Silicones Corporation
    Inventors: Roy M. Griswold, Douglas G. Vanderlaan
  • Patent number: 4665106
    Abstract: A radiation curable pressure-sensitive adhesive composition comprising a liquid oligomer having one or more acrylic double bonds in its molecule, a chain transfer agent and an aliphatic polar monomer having a carboxyl group can give an adhesive tape excellent in rubber-like properties, high in cohesive force and good in adhesiveness at low temperatures.
    Type: Grant
    Filed: July 23, 1985
    Date of Patent: May 12, 1987
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Tomohisa Ohta, Akihiko Dobashi, Hisashige Kanbara, Yasuyuki Seki