Silicon Containing Dnrm Patents (Class 522/77)
  • Patent number: 7727599
    Abstract: The invention relates to a durably homogeneous, low-viscosity, radiation-curable coating material comprising a) x (meth)acrylated polysiloxanes and if desired b) y (meth)acrylated organic compounds and c) at least one particulate emulsifier having an average particle size of <1000 nm in at least one dimension, with the proviso that x?1, y?0, the sum of x+y?2 and the mixture of components a) and b) alone is not durably homogeneous.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: June 1, 2010
    Assignee: Goldschmidt GmbH
    Inventors: Hardi Doehler, Michael Ferenz, Sascha Herrwerth, Matthias Naumann, Joachim Venzmer, Andreas Landgraf
  • Publication number: 20100129587
    Abstract: Disclosed is a composition capable of imparting high hardness, abrasion resistance, excellent contamination resistance and durability of such contamination resistance even in the form of a thin film. Specifically disclosed is a composition including an organic polymer containing 5-30% by mass of a radically polymerizable monomer with a perfluoroalkyl group, 0.01-5% by mass of ?,?-dimercaptopolysiloxane, 5-40% by mass of a radically polymerizable monomer with a cationically photopolymerizable epoxy group and 25-75% by mass of another radically polymerizable monomer which is copolymerizable with the aforementioned substances. The organic polymer has a structure corresponding to a radically polymerized copolymer of the monomer mixture wherein the molar ratio of the mercapto group to the epoxy group is 0.0001-0.025 and/or a structure obtained by reacting a (meth)acrylic acid with the epoxy group of the radically polymerized copolymer.
    Type: Application
    Filed: December 2, 2005
    Publication date: May 27, 2010
    Applicant: Mitsubishi Chemical Corporation
    Inventor: Makoto Terauchi
  • Patent number: 7709551
    Abstract: The present invention relates to a coating composition for a film with low refractive index and a film prepared therefrom, and more precisely, a coating composition with low refractive index which contains dispersed porous organic/inorganic hybrid nano-particles or a colloid containing the dispersed nano-particles, a photocurable compound having unsaturated functional groups, photoinitiator or photosensitizer, or an organic siloxane thermosetting compound, and a solvent and a film prepared therefrom. According to the present invention, porous particles have been formed by using a structural regulator in a silane compound at a specific size, in order to be fitted for a film with low refractive index, and then the structural regulator has been eliminated by a simple process before forming the film, resulting in preparation of a film with extremely low refractive index at a low temperature of up to 120° C.
    Type: Grant
    Filed: June 1, 2006
    Date of Patent: May 4, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Jung-Won Kang, Min-Jin Ko, Myung-Sun Moon, Bum-Gyu Choi, Jeong-Man Son, Dae-Ho Kang
  • Publication number: 20100101723
    Abstract: Disclosed is an acrylic pressure-sensitive adhesive composition that gives a pressure-sensitive adhesive layer exhibiting superior adhesiveness even to coatings, which are likely to cause low adhesion due to bleeding typically of a surface conditioner, without requiring, for example, washing process. The acrylic pressure-sensitive adhesive composition contains a vinyl monomer or a partial polymer thereof (a); and a (meth)acrylate co-oligomer (b), in which the vinyl monomer contains, as a main component, an alkyl(meth)acrylate monomer (a1) having an alkyl group with 2 to 14 carbon atoms, and the (meth)acrylate co-oligomer (b) has a weight-average molecular weight of from 1000 to 30000 and contains, as monomer components, 96 to 99.5 percent by weight of an alkyl(meth)acrylate (b1) and 0.1 to 4 percent by weight of a (meth)acryloyl group-containing silicone oil (b2).
    Type: Application
    Filed: April 15, 2008
    Publication date: April 29, 2010
    Applicant: NITTO DENKO CORPORATION
    Inventors: Masayuki Okamoto, Mitsuyoshi Shirai, Masanori Uesugi, Takashi Kondou, Masahito Niwa, Shinji Inokuchi
  • Patent number: 7659322
    Abstract: The invention provides a method for preparing a polyanhydride by irradiating one or more diacids with microwave radiation in the presence of a carboxylic anhydride so as to acylate the one or more diacids to yield at least one prepolymer, and irradiating the prepolymer with microwave radiation so as to polymerize said prepolymer to yield the polyanhydride, as a homopolymer or a copolymer. High purity polyanhydrides can be prepared by this method. Reaction times compared to conventional melt polycondensations can be significantly reduced. Copolymer polyanhydrides can also be prepared by the microware radiation techniques described herein.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: February 9, 2010
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Brandon M. Vogel, Surya K Mallapragada
  • Patent number: 7659321
    Abstract: Photoinitiator modified silicate and ethylenically unsaturated monomer are reacted in solvent to cause living polymerization of monomer and exfoliation of silicate layers and cause attachment of silicate layers to polymer chains, thereby providing dispersed homopolymer or block copolymer silicate nanocomposites.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: February 9, 2010
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Dotsevi Y. Sogah, Jianbo Di, Xiao-Ping Chen
  • Patent number: 7619015
    Abstract: The present invention relates to an ink composition containing fine particles having an amino group on surfaces thereof. According to the invention, there can be provided an ink composition which prevents volatilization or bleedout of an amine compound to cause no discharge of the amine compound into the environment and is also excellent in curability. Further, there can be provided an ink composition which is excellent in curing efficiency, surface curability and internal curability, and can prevent the occurrence of cracks.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: November 17, 2009
    Assignee: Eiko Epson Corporation
    Inventors: Takashi Oyanagi, Keitaro Nakano
  • Publication number: 20090176891
    Abstract: A dental composition for sealing a portion of a tooth includes a liquid acrylic or acrylate monomer, an acrylic or acrylate polymer that is soluble in the liquid acrylic or acrylate monomer, a photo-initiator for cross-linking the liquid acrylic or acrylate monomer, and a nanoparticle material dispersed within the composition.
    Type: Application
    Filed: December 8, 2008
    Publication date: July 9, 2009
    Inventors: SAMI CHOGLE, Sohel Shaikh, Andre Mickel, Syed Qutubuddin, Mohan Sankaran
  • Publication number: 20090163614
    Abstract: The invention provides a coating composition comprising a thermal plastic resin selected from the group consisting of a polycycloolefin resin, polyester resin, polyacrylate resin, and a mixture thereof; and a radiation curable resin comprising a radiation polymer containing at least one mono- or multi-functional acrylic acid based monomer as a polymerization unit, an oligomer containing an ethylenically unsaturated functional group, and a photoinitiator, wherein the radiation curable resin is used in an amount of 220-1000% by weight on the basis of the weight of the thermal plastic resin. The invention improves the hardness of the coating composition, prevent the coated substrate from being scratched or impaired, and impart the substrate with high transparency without causing warping problem.
    Type: Application
    Filed: December 19, 2008
    Publication date: June 25, 2009
    Inventors: Lung-Lin HSU, Sue-Hong LIU
  • Patent number: 7514479
    Abstract: An active energy ray curable coating composition comprising a mixture (A) of compounds each having a (meth)acryloyl group and a colloidal silica (B), wherein the mixture (A) contains from 22 to 62% of a copolymer (A1) having (meth)acryloyl groups and obtained by reacting a specific amount of a radical polymerizable monomer (a1) having a quaternary ammonium salt group, a radical polymerizable monomer (a2) having a hydroxyl group and a radical polymerizable monomer (a3) having a lactone ring-opening addition structure. A molded product having a coating film made of a cured product of the coating composition. To form a coating film made of a cured product which provides excellent abrasion resistance, transparency and antistatic property and undergoes little decrease in the antistatic property even when kept at a high humidity.
    Type: Grant
    Filed: September 26, 2006
    Date of Patent: April 7, 2009
    Assignee: Asahi Glass Company, Limited
    Inventor: Satoshi Kondo
  • Patent number: 7498362
    Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultraviolet and visible radiation. In certain embodiments, the disclosed coating compositions are suitable for coating flexible objects and/or objects having angular features, such as, but not limited to, flexible metal objects with angular features. In other embodiments, the cured coatings have improved slip properties and at least 6 H hardness. Such embodiments can served as substitutes for “hard chrome” coatings, TEFLON® coatings, coatings comprising TEFLON®, or TEFLON® like coatings. In addition, methods are disclosed for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, including, for example leaf springs, hydraulic rods and cylinders.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: March 3, 2009
    Assignee: Ecology Coatings, Inc.
    Inventor: Sally Judith Weine Ramsey
  • Patent number: 7495035
    Abstract: It is an object of the present invention to provide a photo-curable resin composition which provides a sealing agent for a flat panel display with good moisture permeation resistance and excellent adhesion. The present inventors have conducted extensive studies to solve the above-described problems, and as a result, they have found a photo-curable resin composition which comprises a cationic photopolymerization initiator (A), a cationically polymerizable compound (B), a cyclic polyether compound (C) and another organic compound (D), wherein the amount of (B) is 1.0 to 99.9% by mass and the amount of (C) is 0.0 to 10.0% by mass, both based on the sum of (B), (C) and (D), and the sum (F) of the fluorine atoms in a fluorine-containing organic compound is 0.0 to 40.0% by mass, based on the sum of (B), (C) and (D), and wherein at least 1/1000 mass ratio of the (B) component is a compound containing an oxetanyl group, and both of the contents of (C) and (F) are not 0.0% by mass at the same time.
    Type: Grant
    Filed: August 10, 2004
    Date of Patent: February 24, 2009
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yugo Yamamoto, Yasushi Mizuta, Yuichi Ito
  • Publication number: 20090045729
    Abstract: A composition usable as a moisture absorbent for an organic electroluminescence device. A photocurable hygroscopic composition comprising (a) a moisture-reactive organic metal compound, (b) a (meth)acrylate, (c) a carboxyl group-containing polymerizable monomer, and (d) a photopolymerization initiator. The proportion of the moisture-reactive organic metal compound (a) is from 5 to 70 wt % based on the entire composition, and the proportion of the carboxyl group-containing polymerizable monomer (c) is from 0.1 to 50 mol % based on the moisture-reactive organic metal compound (a).
    Type: Application
    Filed: January 12, 2007
    Publication date: February 19, 2009
    Inventors: Jun Fujita, takashi Yamasaki
  • Publication number: 20090025870
    Abstract: An object of the present invention is to provide a curable composition excellent in on-site formability, excellent in heat resistance, chemical resistance and oil resistance, and low in compression set. The invention relates to a curable composition comprising (a) a vinyl-based polymer containing at least one (meth)acryloyl group in a molecule thereof and having a number average molecular weight of 500 to 1,000,000, (b) an ethylenic unsaturated group-containing compound, (c) a thixotropic property-imparting agent, (d) fumed silica surface-treated with a (meth)acryloyl group-containing silane and (e) a photopolymerization initiator.
    Type: Application
    Filed: June 30, 2006
    Publication date: January 29, 2009
    Applicant: THREE BOND CO., LTD.
    Inventor: Masayuki Tanaka
  • Publication number: 20090000508
    Abstract: Disclosed herein are non-aqueous, radiation curable inkjet inks exhibiting stability at high shear rate (good rheological stability), stability at high temperatures, and/or stability in inkjet print heads, especially impulse inkjet print heads. The inks have a wide process window at a variety of print speeds using an impulse inkjet print head.
    Type: Application
    Filed: July 14, 2005
    Publication date: January 1, 2009
    Inventors: Sara Edison, Matthew M. Ellison, John Fech, Xin Huo, Sudhaker Madhusoodhanan, Devdatt S. Nagvekar, Paul E. Snowwhite, Stephen Sung, Kim Lynn Webb
  • Patent number: 7465758
    Abstract: Polymerizable compositions and methods are provided that include an ethylenically unsaturated compound and an arylsulfinate salt. The polymerizable compositions are useful as hardenable dental compositions.
    Type: Grant
    Filed: July 16, 2007
    Date of Patent: December 16, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Afshin Falsafi, Rajdeep S. Kalgutkar, Joel D. Oxman
  • Patent number: 7462651
    Abstract: A radiation-curable desiccant-filled adhesive/sealant composition comprising a radiation-curable resin, one or more desiccant fillers, one or more photoinitiators or photosensitizers, and optionally, one or more inorganic or organic fillers.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: December 9, 2008
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Jie Cao, Donald E. Herr
  • Publication number: 20080287562
    Abstract: Stable and substantially filled cationic dental compositions are described which include: (1) at least one cationically reactive compound (A); (2) at least one dental filler (B); (3) optionally, at least one dispersant (C) composed of at least one organic polymer or copolymer; (4) at least one cationic photoinitiator (D); and (5) optionally, at least one photosensitizer (E). The dental filler (B) is treated with at least one organosilicon coupling agent (F), and at least one compound (G). The organosilicon coupling agent (F) has at least one reactive function (rfA) directly linked to a silicon atom forming after activation of a chemical bond with the dental filler, and at least one reactive function (rfB) not directly linked to a silicon atom, forming after activation, a chemical bond with a reactive function (rfC) of the compound (G).
    Type: Application
    Filed: May 2, 2008
    Publication date: November 20, 2008
    Applicant: RHODIA CHIMIE
    Inventors: Jean-Marc Frances, Martial Deruelle, Yves Giraud
  • Publication number: 20080280144
    Abstract: A coating composition based upon at least partially hydrolyzed epoxy-functional alkoxy silanes and having particular utility in forming tintable, abrasion resistant coatings on lenses. Incorporation in the composition of a non-hydrolyzed epoxy-functional alkoxy silane provides a desired reduction in viscosity. Incorporation in the composition of a polyether surfactant provides a cured coating of the composition with increased tintability.
    Type: Application
    Filed: June 9, 2008
    Publication date: November 13, 2008
    Applicant: THE WALMAN OPTICAL COMPANY
    Inventor: Gerald D. Treadway
  • Patent number: 7439279
    Abstract: To provide a coating composition which forms a coating film having excellent fingerprint removability and having favorable abrasion resistance and transparency, and a molded product having a coating film made of a cured product of the composition. An active energy ray curable coating composition comprising an active energy ray curable polymerizable monomer (A), a water and oil repellency-imparting agent (B) and an active energy ray polymerization initiator (C), wherein the water and oil repellency-imparting agent (B) contains a water and oil repellency-imparting agent (B-T) having a moiety (b-1) exerting water and oil repellency, an active energy ray curable functional group (b-2) and a moiety (b-3) excellent in compatibility with the polymerizable monomer (A) and a molded product having a coating film made of a cured product of the composition.
    Type: Grant
    Filed: May 13, 2005
    Date of Patent: October 21, 2008
    Assignee: Asahi Glass Company, Limited
    Inventors: Satoshi Kondo, Daisuke Shirakawa, Toshihiko Higuchi, Hirotsugu Yamamoto
  • Patent number: 7439277
    Abstract: A process for the preparation of a hydroperoxide functionalized rubber compound by the conversion of triplet state oxygen to singlet state oxygen in the presence of oxygen and a light-induced photoreductant. A dispersion of an unsaturated rubber component in a carrier solvent is introduced into a reactor containing a permeable catalyst bed comprising a light-induced photoreductant component supported on a particulate substrate component and passed through the catalyst bed. A gaseous oxidizing agent is passed through the catalyst bed in contact with the rubber-containing dispersion. The catalyst bed is irradiated with electromagnetic light radiation in the ultraviolet or visible light range at an intensity sufficient to convert triplet oxygen in the oxygenated rubber component to singlet oxygen. The oxygenated rubber component is then recovered from the reactor.
    Type: Grant
    Filed: May 19, 2005
    Date of Patent: October 21, 2008
    Assignee: Fina Technology, Inc.
    Inventors: Jay Reimers, Jose Sosa
  • Patent number: 7420005
    Abstract: The photocurable resin composition in the first aspect of the invention comprises, as essential components, (A) a binder resin having photopolymerizable functional groups and (B) inorganic superfine particles in the order of sub-micron which can be dispersed in a colloidal form; the photocurable resin composition in the second aspect comprises, as essential components, (C) a binder resin containing photopolymerizable functional groups and (D) hydrophobic fine silica particles; and the photocurable resin composition in the third aspect comprises, as essential components, (E) a binder resin containing acrylic resin and urethane acrylate resin and/or polyester acrylate having photopolymerizable functional groups and (F) an organometallic coupling agent.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: September 2, 2008
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Mikiko Hojo, Toshio Yoshihara
  • Patent number: 7378455
    Abstract: A curable method useful for encapsulating solid state devices includes (A) an epoxy resin; (B) an effective amount of a cure catalyst comprising (B1) a first latent cationic cure catalyst comprising a diaryl iodonium hexafluoroantimonate salt; (B2) a second latent cationic cure catalyst comprising (B2a) a diaryl iodonium cation, and (B2b) an anion selected from perchlorate, imidodisulfurylfluoride anion, unsubstituted and substituted (C1-C12)-hydrocarbylsulfonates, (C2-C12)-perfluoroalkanoates, tetrafluoroborate, unsubstituted and substituted tetra-(C1-C12)-hydrocarbylborates, hexafluorophosphate, hexafluoroarsenate, tris(trifluoromethylsulfonyl)methyl anion, bis(trifluoromethylsulfonyl)methyl anion, bis(trifluoromethylsulfuryl)imide anion, and combinations thereof; and (B3) a cure co-catalyst selected from free-radical generating aromatic compounds, peroxy compounds, copper (II) salts of aliphatic carboxylic acids, copper (II) salts of aromatic carboxylic acids, copper (II) acetylacetonate, and combinations
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: May 27, 2008
    Assignee: General Electric Company
    Inventors: Qiwei Lu, Michael O'Brien, Michael Vallance
  • Patent number: 7368484
    Abstract: The present invention relates to novel polymeric compositions that exhibit Reverse Thermal Gelation (RTG) properties for use as Support Materials (SM) in the manufacture of three-dimensional objects. These polymers are Temperature Sensitive Polymers that respond with a significant change of properties to a small change in temperature. Temperature Sensitive Polymers exhibit cloud point (CP) or lower critical solution temperature (LCST) in aqueous solutions. Water-soluble Temperature Sensitive Polymers are chosen to give low viscosity liquid at low temperature when dissolved in water and by that to permit easy dispensing at low temperature. Raising the temperature above their gelation temperature (Tgel) will result in solidification of the composition. At its gel position the material has favorable characteristics as a support and building material. The gel layers have the appropriate toughness and dimensional stability to support the model layers during the building process.
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: May 6, 2008
    Assignee: Objet Geometries Ltd.
    Inventor: Avraham Levy
  • Publication number: 20080076043
    Abstract: According to the present invention, there is provided a curable composition, containing a compound (A) having at least one ethylenically unsaturated double bond, a photopolymerization initiator (B), a coloring agent (C), an alkali-soluble resin (D), and a compound (E) having in the molecule a partial structure of urethane, amide or urea.
    Type: Application
    Filed: September 10, 2007
    Publication date: March 27, 2008
    Applicant: FUJIFILM CORPORATION
    Inventors: Hisahiro MORI, Taeko AIZAWA
  • Patent number: 7338985
    Abstract: A rustproofing composition has superior properties satisfying rustproofing quality requirements and workability requirements for car underbodies, parts around tires, parts with pockets, plate-bonded parts or the like of car bodies, and containing volatile organic solvent of 20 mass % or less. In a rustproofing composition containing UV curable resin and photopolymerizing initiator and at least one of rustproofing oil and rustproofing wax, the content of nonvolatile component at 105° C. for 3 hours in the rustproofing oil and rustproofing wax is 80 mass % or more, the UV curable resin and photopolymerizing initiator are dissolved or dispersed in the rustproofing oil and rustproofing wax, and the UV curable resin is contained at 0.3 to 10 weight % to the total weight of the composition.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: March 4, 2008
    Assignees: Honda Motor Co., Ltd., Parker Industries, Inc.
    Inventors: Takahide Maeda, Toshiya Nishino, Yoichiro Inaba, Kazuo Igarashi, Noriharu Tanaka, Kazuhiko Maesori, Takeshi Masuda
  • Patent number: 7304096
    Abstract: There is provided a highly functional one-step light-curing dental adhesive composition i) based on a multifunctional prepolymer mixture of 2,2-bis-[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane (“Bis-GMA”) and a multifunctional prepolymer formed by substitiuting hydrogen atoms of hydroxyl groups present in Bis-GMA molecules with methacrylate groups, in which the Bis-GMA is used as a base prepolymer of conventional dental adhesive compositions; and ii) comprising and acidic monomer for removing a portion of smear layer, which is allowed to be bonded without separate treatment of acid etchant, an adhesive monomer having both hydrophobic and hydrophilic properties, a hydrophilic monomer which is allowed to be bonded in the present of moisture, an inorganic filler for improving mechanical properties, diluent, water for demineralization, a photoinitiation system and other additives.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: December 4, 2007
    Assignee: Korea Institute of Science and Technology and Dentkist, Inc.
    Inventors: Dong Keun Han, Kyu Hyun Baek, Min Sung Kim, Sang Soon Park, Hyun Chul Goo, Choong Ho Kim
  • Patent number: 7276543
    Abstract: The present invention relates to a coated optical fiber comprising a glass optical fiber with a single protective coating or a combination of an inner and an outer primary coating applied thereon and optionally with a colored coating subsequently applied thereon wherein the inner primary coating or at least a portion of the single coating is prepared from a radiation curable composition which when cured as a capillary film with a 100W medium pressure mercury lamp has a percentage reacted acrylate unsaturation of at least about 54% after exposure to a dose of about 4.4 mJ/cm2 or wherein the outer primary coating is prepared from a radiation curable composition which when cured as a capillary film with a 100 W medium pressure mercury lamp has a percentage reacted acrylate unsaturation of at least about 56% after exposure to a dose of about 4.4 mJ/cm2. The invention further relates to a radiation curable composition having a high cure speed.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: October 2, 2007
    Assignee: DSM IP Assets B.V.
    Inventors: Timothy E. Bishop, Paul E. Snowwhite, Tyson Norlin, James J. Schouten, John Southwell, Anthony Toussaint
  • Patent number: 7256222
    Abstract: To provide a radiation-curable ink composition that can form a high-quality image on not only liquid absorbing materials to be recorded but also non-liquid absorbing materials to be recorded, is superior in curing properties in air, and is superior in storage stability, color tone, light fastness and water resistance of ink, and also to provide an image recording method. The radiation-curable ink composition comprises a monomer having a polymerizable group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group, and a vinyl group, an oil-soluble dye, and from 0.005 to 1% by weight of a storage stabilizer, wherein the oil-soluble dye is dissolved in the ink.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: August 14, 2007
    Assignee: Fujifilm Corporation
    Inventors: Takahiro Ishizuka, Kazue Sano, Junichi Yamanouchi, Keiichi Tateishi
  • Patent number: 7238731
    Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultraviolet and visible radiation. In addition, the disclosed coating compositions are suitable for coating flexible objects and/or objects having angular features, such as, but not limited to, flexible metal objects with angular features. In addition, methods are disclosed for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, including, for example leaf springs. Also disclosed are methods, processes, production lines, articles of manufacture, and factories which incorporate these environmentally friendly, substantially all solids coating compositions curable using ultraviolet and visible radiation.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: July 3, 2007
    Assignee: Ecology Coating, Inc.
    Inventor: Sally Judith Weine Ramsey
  • Patent number: 7223476
    Abstract: Methods for making composite flakes are disclosed. The composite flakes are formed from particles and one or more monomers and/or resins or resin systems. The polymer matrix of the flakes is highly crosslinked and/or high molecular weight. Use of the particles in powder coatings is also disclosed.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: May 29, 2007
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Robert D. Edwards, Jackie L. Kulfan, Calum H. Munro
  • Patent number: 7202285
    Abstract: Compositions suitable for use as base coats and varnishes, preferably for use in combination with electrostatic of set inks printed onto plastics substrates, particularly polycarbonate compact discs. They contain a photopolymerisable material, a photoinitiator, an inorganic transfer agent and heavy metal salt, preferably a metallic carboxylate. They have a good shelf life and good adhesion after hardening with ultraviolet light.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: April 10, 2007
    Assignee: Sericol Limited
    Inventors: Angelique Runacre, Paul Geoffrey Day
  • Patent number: 7183363
    Abstract: A resin-based casting compound which cures by a chemical reaction is described; it is suitable in particular for insulation of electric components and it contains an epoxy resin component (A), a silicone-containing component (B), a filler (C), by the choice of which the thermal conductivity of the casting compound is adjustable, and a thermal initiator (D). The casting compound has a thermal conductivity of ?2 W/mK.
    Type: Grant
    Filed: November 14, 2001
    Date of Patent: February 27, 2007
    Assignee: Robert Bosch GmbH
    Inventors: Irene Jennrich, Kristian Leo, Markus Muzic, Wolfgang Endres
  • Patent number: 7060737
    Abstract: The invention relates to a curable resin composition, cured products thereof, and laminated materials. The curable composition comprises: (A-1) acicular oxide particles, the oxide being an oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, (B) a compound having two or more polymerizable unsaturated groups, (C) a photopolymerization initiator is provided. After cure, the composition has excellent scratch resistance. In addition, it may have excellent antistatic characteristics and transparency. In a preferred embodiment the composition also comprises (A-2) particles other than the acicular particles (A-1), being oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: June 13, 2006
    Assignees: DSM IP Assets B.V., JSR Corporation, Japan Fine Coatings Co., Ltd.
    Inventors: Yoshikazu Yamaguchi, Takayoshi Tanabe, Hiroki Nakajima, Hideaki Takase
  • Patent number: 7005233
    Abstract: SU-8 photoresist compositions are modified to improve their adhesion properties by adding 1% to 6% of an adhesion promoter selected from the group consisting of glycidoxypropanetrimethoxysilane, mercaptopropyltrimethoxysilane, and aminopropyltrimethoxysilane. SU-8 photoresist compositions are modified to improve their resistance to cracking and film stress by adding 0.5% to 3% of a plasticizer selected from the group consisting of dialkylphthalates, dialkylmalonates, dialkylsebacates, dialkyladipates, and diglycidyl hexahydrophthalates. The improvements can be obtained simultaneously by adding both the adhesion promoter and the plasticizer to SU-8 photoresist compositions.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: February 28, 2006
    Assignee: FormFactor, Inc.
    Inventor: Treliant Fang
  • Patent number: 6946498
    Abstract: A coating composition comprising (1) an anionic surfactant comprising a sulfonic acid salt, (2) a sol of fine inorganic oxide particles, (3) a silicon compound having one acryl or methacryl group and a hydrolyzable group or a product of hydrolysis of the compound, (4) a compound having at least two photopolymerizable unsaturated groups, and (5) a photopolymerization initiator; and a coated article obtained by applying the coating composition to a base and then photocuring the coating. The coated article combines antifogging properties with abrasion resistance sufficient for practical use.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: September 20, 2005
    Assignee: Nippon Arc Co., Ltd.
    Inventor: Hisayuki Kayanoki
  • Patent number: 6943201
    Abstract: A surface treatment composition of the present invention comprises (A) urethaneacrylate oligomer, (B) acrylate based monomer, (C) photoinitiator, (D) silicon additive, and (E) silica matting agent. The present invention provides a surface treatment composition in which imparts abrasion and scratch resistance to the surface of a soft type urethaneacrylate oligomer decorative floor covering, and ameliorates the problem of low stain resistance caused a low density of elaborate crosslinks by using a small amount of single functional group monomer. The present invention also provides a surface treatment composition in which employs only hard type urethaneacrylate without single functional group monomer so that cross linking density is increased and the effects of oxygen that prohibits the surface curing are minimized, resulting in improved stain resistance.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: September 13, 2005
    Assignee: LG Chem Ltd.
    Inventors: Ho-Zun Park, Min-Ho Son
  • Patent number: 6939898
    Abstract: A surface treatment composition of the present invention comprises (A) urethaneacrylate oligomer, (B) asrylate based monomer, (C) photoinitiator, (D) silicon additive, and (E) silica matting agent. The present invention provides a surface treatment composition in which imparts abrasion and scratch resistance to the surface of a soft type urethaneacrylate oligomer decorative floor covering, and ameliorates the problem of low stain resistance caused a low density of elaborate crosslinks by using a small amount of single functional group monomer. The present invention also provides a surface treatment composition in which employs only hard type urethaneacrylate without single functional group monomer so that cross linking density is increased and the effects of oxygen that prohibits the surface curing are minimized, resulting in improved stain resistance.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: September 6, 2005
    Assignee: LG Chem Ltd.
    Inventors: Ho-Zun Park, Min-Ho Son
  • Patent number: 6905735
    Abstract: The present invention discloses an ultraviolet light curable paint composition and method for applying and making such a composition to a substrate. Suitable substrates include glass, metals, and various plastics such as polycarbonates. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the coating or are released to ambient after curing.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: June 14, 2005
    Assignee: Allied PhotoChemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 6894084
    Abstract: The present invention provides radiation curable resin compositions that contain no or essentially no volatile organic components (VOCs), and to methods of using these compositions. The radiation curable resin compositions find particular use as coating compositions. In particular, the radiation curable resin compositions of this invention comprise a vinyl dioxolane end-capped oligomer blended with a photoinitiator.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: May 17, 2005
    Assignee: Foster-Miller, Inc.
    Inventors: Robert F. Kovar, Nese Orbey, Stanley Wentworth
  • Patent number: 6887918
    Abstract: A fast-curing, low viscosity composition for coating an optical waveguide, more specifically, an optical fiber, and optical fibers coated therewith are disclosed. The coating composition is a radiation curable composition containing: a radiation curable oligomer, a free radical photoinitiator, and a mixture of reactive diluents including a low molecular weight (meth)acrylate having tri-, tetra-, penta- or higher functionality.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: May 3, 2005
    Assignee: Alcatel
    Inventors: Igor V. Khudyakov, Michael B. Purvis, Robert J. Overton
  • Patent number: 6883908
    Abstract: Methods, systems, and compositions that make it possible to form high resolution, pressure sensitive adhesive patterns or films on a wide range of substrates. The compositions generally incorporate a curable, fluid composition (i.e., pressure sensitive adhesive precursor). When cured, a pressure sensitive adhesive is formed. Ink jet printing and subsequent curing allows pressure sensitive adhesive features to be formed with high resolution and tremendous flexibility in the patterns by which adhesive features may be formed. Preferred embodiments of the invention incorporate rheology modifying agents that can be used to promote favorable dot gain and other printing characteristics, the ability to build print thickness, and mechanical properties of resultant cured adhesives.
    Type: Grant
    Filed: January 8, 2001
    Date of Patent: April 26, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: James K. Young, Brant U. Kolb, Albert I. Everaerts, Kevin M. Eliason, Diana M. Eitzman, Kejian Chen, John P. Banovetz, Gregory J. Anderson
  • Patent number: 6860600
    Abstract: The disclosure relates to the provision of a lens having front and back optical surfaces bound by a peripheral edge, wherein the peripheral edge is coated with an edge coating that strongly bonds to the edge but that only weakly bonds to the optical surface, and wherein the edge coating is durable. A method of coating and a composition are also disclosed. The composition is preferably selected from a limited group of UV curable acrylates.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: March 1, 2005
    Assignee: Sola International Holdings, Ltd.
    Inventor: Fang Chen
  • Patent number: 6852768
    Abstract: The invention provides curable organic coatings with improved scratch resistance. More particularly, the present invention relates to a combination of inorganic filler having a 50th percentile particle diameter of from about 3 to about 9 micrometers comprised of aluminum oxide, silicon dioxide, ceramic spheres or mixtures thereof, and particles having a 50th percentile particle diameter of from about 10 to about 150 micrometers. The liquid coatings have a viscosity before curing of from about 100 cps (mPa-s) to about 70,000 cps (mPa-s) at a shear rate of 0.15 s?1. The use of inorganic filler materials of the defined type and particle size are combined with the curable organic coating to improve the scratch resistance of the coating without a negative impact on the physical and performance properties or application parameters of the original coating material.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: February 8, 2005
    Assignee: Lord Corporation
    Inventors: Pei Wen Jin, Kimberly R. Benca, Ian C. Quarmby, Thomas Kurpiewski, Victor E. Ferrell
  • Patent number: 6852770
    Abstract: The present invention provides radiation-curable compositions and products coated therewith, such as coated optical fibers. The present compositions have a low amount of, or are even absent of, reactive diluents while still exhibiting a sufficiently low viscosity to be useful in a wide variety of coating applications, such as in processes for coating optical fibers.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: February 8, 2005
    Assignee: DSM IP Assets, B.V.
    Inventors: Timothy E. Bishop, Jibing Lin, David Krumin, Lindsay S. Coons, Paulus F. A. Buijsen
  • Patent number: 6846852
    Abstract: This invention provides for compositions, which can be crosslinked by radiation to give elastomeric coatings, which comprises: (a) high-molecular weight siloxanes with multiple (meth)acrylate functional groups; and (b) reinforcing fillers selected from the group consisting of silicone resins and silicone dioxide fillers, wherein the siloxanes (a) have the general structure: [R3SiO1/2]a[(Z)nG—Ym—R2SiO1/2]a?[R2SiO2/2]b[(Z)nG—Ym—RSiO2/2]b?[RSiO3/2]c[SiO4/2]d.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: January 25, 2005
    Assignee: Goldschmidt AG
    Inventors: John Allen, Thomas E. Hohenwarter, Jr., Peter Lersch, Ernest D. Moore, Angela Dawn Paez, Jörg Simpelkamp, Steven Paul Smith
  • Patent number: 6844950
    Abstract: Blends of oligomeric urethane multi(meth)acrylate; optionally at least one other monomer selected from the group consisting of acrylic monomers, styrenic monomers and ethylenically unsaturated nitrogen heterocycles, preferably a polyol multi(meth)acrylate; and nanoparticles of an ethylenically unsaturated, preferably (meth)acrylic-functionalized, titanium or zirconium compound can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having high refractive indices, haze ratings of at most 5% and other properties which may be tailored according to the desired use.
    Type: Grant
    Filed: January 7, 2003
    Date of Patent: January 18, 2005
    Assignee: General Electric Company
    Inventors: Bret Ja Chisholm, Dennis Joseph Coyle, James Alan Resue
  • Patent number: 6844374
    Abstract: The invention provides organic coatings with improved scratch resistance. More particularly, the present invention relates to the use of inorganic filler materials of a defined type and particle size which can be added to curable organic coatings to improve the scratch resistance of the coating without a negative impact on the physical and performance properties or application parameters of the original coating material.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: January 18, 2005
    Assignee: Lord Corporation
    Inventors: Pei Wen Jin, Kimberly R. Benca, Ian C. Quarmby, Thomas Kurpiewski, Victor E. Ferrell
  • Patent number: 6838536
    Abstract: A substantially reactive and gel-free composition which comprises: a. particles capable of reaction with a radiation curable resin; b. a coupling agent for modification of the surface of said particles; c. a radiation curable resin; d. a radiation curable salt capable of inhibiting gel formation in said composition.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: January 4, 2005
    Assignee: UCB, S.A.
    Inventors: Zhikai Wang, Carol Black, Jun Qiao
  • Patent number: RE40087
    Abstract: There are provided a composition for coating which can form an ink receiving layer having excellent adhesion with hydrophobic substrates, water-resistance and printing stability, and an optical recording medium having an ink receiving layer formed from this composition. The composition contains a radiation-curable compound (A) composed of 50 to 90% by weight of a monofunctional (meth) acrylic monomer and 10 to 50% by weight of a multifunctional (meth) acrylic monomer, a water-absorbing organic filler (C) in an amount of 10 to 60% by weight relative to (A), and a water-absorbing inorganic filler (D) in an amount of 1 to 20% by weight relative to (A). This composition is applied on a protecting film (6) and cured to form an ink receiving layer (7), to obtain an optical disk (1).
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: February 19, 2008
    Assignee: TDK Corporation
    Inventor: Tsuyoshi Komaki