Carbon And Hydrogen Only Containing Dnrm Patents (Class 522/80)
  • Patent number: 6124372
    Abstract: Disclosed is a composition comprising a polymer with a weight average molecular weight of from about 1,000 to about 100,000, said polymer containing at least some monomer repeat units with a first, photosensitivity-imparting substituent which enables crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer also containing a second, thermal sensitivity-imparting substituent which enables further crosslinking or chain extension of the polymer upon exposure to temperatures of about 140.degree. C.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: September 26, 2000
    Assignee: Xerox Corporation
    Inventors: Thomas W. Smith, Timothy J. Fuller, Ram S. Narang, David J. Luca
  • Patent number: 6110988
    Abstract: Described is a preferred UV curable coating composition comprising (exclusive of any solvent present): (a) about 5% to 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 500 to 2000 and formed by the reaction of a multifunctional acrylate with a molecular weight of about 190 to 500 and containing at least three polymerizable unsaturated groups per molecule, with an aliphatic urethane based on a polymer of alkyl carbomonocycle diisocyanate with alkanepolyol polyacrylates; (b) about 5% to 30% by weight of a multifunctional acrylate having a molecular weight of about 170 to 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes and coated articles involving the preferred coating compositions.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 29, 2000
    Assignee: Red Spot Paint & Varnish Co, Inc.
    Inventor: Randall Todd Lake
  • Patent number: 6107360
    Abstract: This invention provides a resin composition which is cured by active radiation rays, shows less absorption in the visible light region, has solar radiation blocking ability and is excellent in scratch resistance, and a film coated with the resin composition. Said resin composition comprises solar radiation absorbable fine particles of a metal oxide such as zinc antimonate anhydride, tin oxide, ATO (antimony doped tin oxide), ITO (tin doped indium oxide) or the like and an active radiation ray polymerizable (meth)acrylate having a (meth)acryloyl group, and a coating obtained therefrom has excellent paint film hardness and scratch resistance.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: August 22, 2000
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Shoichi Kaneko, Hiroshi Sakurai, Kaoru Izumi, Kenichiro Yoshioka
  • Patent number: 6099415
    Abstract: Ultraviolet radiation curing of inks on game balls, golf balls and the like is disclosed. Production inks, logo inks and methods for forming production prints and logos on golf balls, game balls and the like are disclosed. To form an ultraviolet radiation curable water-insoluble production ink, at least an adhesion promoting component is added to an ink base.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: August 8, 2000
    Assignee: Acushnet Company
    Inventor: Mitchell E. Lutz
  • Patent number: 6087413
    Abstract: An ultraviolet curable clearcoat composition comprising (exclusive of any solvent present): (a) about 30% to about 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 1200 to 2600 and formed by the reaction of a multifunctional acrylate with a molecular weight of between about 110 and about 500 with an aliphatic urethane based on a polyether and having a molecular weight of about 800 to about 2200; (b) about 15% to about 70% by weight of a multifunctional acrylate having a molecular weight of about 170 to about 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes and clearcoated articles involving preferred clearcoat compositions.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: July 11, 2000
    Assignee: Red Spot Paint and Varnish Co., Inc.
    Inventor: Randall T. Lake
  • Patent number: 6022050
    Abstract: A release coating composition containing about 50 to about 75 wt. % of an epoxy functional silicone; about 8 to about 25 wt. % of a reactive solvent; about 5 to about 25 wt. % of a reactive diluent; about 6 to about 12 wt. % of a wax-treated silica powder; and, about 2 to about 4 wt. % of a photoinitiator is disclosed. The composition is useful in preparing a low-gloss release coating for use on linerless labels.
    Type: Grant
    Filed: September 2, 1998
    Date of Patent: February 8, 2000
    Assignee: Monarch Marking Systems, Inc.
    Inventor: James R. Kline
  • Patent number: 6007877
    Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with water-solubility- or water-dispersability-imparting substituents and at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units. In one embodiment, a single functional group imparts both photosensitivity and water solubility or dispersability to the polymer. In another embodiment, a first functional group imparts photosensitivity to the polymer and a second functional group imparts water solubility or dispersability to the polymer.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: December 28, 1999
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 5994424
    Abstract: A free-radical curable polish composition is described. The composition can be applied and cured as an ultra thin film on finished surfaces to provide enhanced chemical and mar resistance. The composition comprises an aqueous emulsion including an olefin-functional polymer or an olefin-functional prepolymer, and a silicone or silicone copolymer preferably with photoinitiators for UV and EB cure. The polish/emulsion can be applied, for example, to wet the surface of nitrocellulose lacquer wood finishes. The polish wet surface is first wiped to remove excess polish and thereafter exposed to UV radiation to provide a thin, polymerized protective film.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: November 30, 1999
    Assignee: Lilly Industries, Inc.
    Inventors: Eugen Safta, Frank Chen, Greg Muselman, James V. Mirante, Danny R. Linthicum
  • Patent number: 5990189
    Abstract: A photopolymerizable material is provided that is suitable for use in the production of coatings or resists on printed circuit boards, for example The material is an ethylenically unsaturated polymerizable reaction product of a polyepoxide and a mixture of (i) a major proportion of an ethylenically unsaturated carboxylic acid and (ii) a minor. proportion of a saturated aliphatic or aromatic carboxylic acid, the reaction product being further modified by reaction with a dicarboxylic acid or anhydride thereof.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: November 23, 1999
    Assignee: Coates Brothers PLC
    Inventors: Stephen Anthony Hall, Nicholas Eric Ivory
  • Patent number: 5977200
    Abstract: An ultraviolet curable clearcoat composition comprising (exclusive of any solvent present): (a) about 30% to about 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 1200 to 2600 and formed by the reaction of a multifunctional acrylate with a molecular weight of between about 110 and about 500 with an aliphatic urethane based on a polyether and having a molecular weight of about 800 to about 2200; (b) about 15% to about 70% by weight of a multifunctional acrylate having a molecular weight of about 170 to about 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes and clearcoated articles involving preferred clearcoat compositions.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 2, 1999
    Assignee: Red Spot Paint & Varnish Co., Inc.
    Inventor: Randall T. Lake
  • Patent number: 5948514
    Abstract: A photocurable and thermosetting resin composition developable with an aqueous alkali solution is disclosed. The composition comprises in combination: (A) a photosensitive prepolymer soluble in a dilute aqueous alkali solution obtained by esterifying an epoxy resin represented by the following general formula (1) with (meth)acrylic acid and further adding an acid anhydride thereto until an acid value reaches a level in the range of 60 to 120 mg KOH/g, (B) a diglycidyl ether type epoxy compound containing two epoxy groups in the molecular unit thereof, (C) a photopolymerization initiator, and (D) a diluent at such ratios of combination that said epoxy compound (B) accounts for a proportion in the range of 5 to 120 parts by weight and said photopolymerization initiator (C) for a proportion in the range of 0.1 to 30 parts by weight, based on 100 parts by weight of said photosensitive prepolymer (A): ##STR1## wherein X represents CH.sub.2, C(CH.sub.3).sub.2, or SO.sub.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: September 7, 1999
    Assignee: Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Shigeru Komori, Kazuo Suda, Masao Arima, Miyako Juni
  • Patent number: 5945462
    Abstract: The present invention relates to an aqueous-based coating composition for forming strippable, protective coating for protecting surfaces, such as glass, metal, ceramic, plastic or other materials of construction. More specifically, the compositions and coatings formed therefrom of this invention are particularly useful in connection with protecting precision surfaces, such as optical lenses, including but not limited to ophthalmic lenses, telescopic lenses, microscopic lenses, and the like, which protection is desirably only of a temporary nature.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: August 31, 1999
    Assignee: Loctite Corporation
    Inventor: Peter A. Salamon
  • Patent number: 5908873
    Abstract: A one-part, cured, radiation-curable liquid matrix composition for affixing coated and inked optical fibers in a ribbon configuration which is peelable from the coated and inked fibers without damage to the integrity of itself or the fibers is disclosed. The composition comprises an aliphatic urethane acrylate oligomer; a reactive monomer having one or more acrylate or methacrylate moieties; a release agent; and an optional photoinitiator. Also disclosed are an optical fiber ribbon array prepared therefrom; a process for removing such matrix composition from inked and coated fibers; a process for preparing such ribbon array; and a radiation-curable coating composition generally applicable for coating a substrate.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: June 1, 1999
    Assignee: Borden Chemicals, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5891573
    Abstract: A method is disclosed for providing a friable polytetrafluoroethylene (PTFE) product that has particles of a desired size which are flowable and do not tend to agglomerate. To achieve this result, the PTFE starting material is handled at a temperature below 66.degree. F., and preferably below 55.degree. F., before irradiating. The PTFE starting material may be mixed with a wetting agent before irradiating to provide a product that has enhanced dispersibility. The source of radiation may include electron beam radiation, nuclear radiation, or radiation from a cobalt-60 (CO.sub.60) source.
    Type: Grant
    Filed: August 8, 1997
    Date of Patent: April 6, 1999
    Assignee: Shamrock Chemicals Corporation
    Inventors: Nicholas W. Neuberg, George Poszmik, Manshi Sui
  • Patent number: 5863963
    Abstract: Disclosed is a process which comprises the steps of (a) providing a polymer containing at least some monomer repeat units with halomethyl group substituents which enable crosslinking or chain extension of the polymer upon exposure to a radiation source which is electron beam radiation, x-ray radiation, or deep ultraviolet radiation, said polymer being of the formula ##STR1## wherein x is an integer of 0 or 1, A is one of several groups as specified in the claims, B is one of several groups as specified in the claims, and n is an integer representing the number of repeating monomer units, and (b) causing the polymer to become crosslinked or chain extended through the photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead by the aforementioned curing process.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: January 26, 1999
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 5859085
    Abstract: The present invention relates to a low electronic conductivity polymer composition having well dispersed metal granules, a stable powder made from photosensitive polycrystalline complexes of pyrrole, or its substituted derivatives and silver cations for making the polymer composition, and methods of forming the stable powder and polymer composition, respectively. A polycrystalline complex of silver and a monomer, such as pyrrole, its substituted derivatives or combinations thereof, is precipitated in the form of a stable photosensitive powder upon addition of the monomer to a solvent solution, such as toluene containing an electron acceptor. The photosensitive powder can be stored in the dark until needed. The powder may be dissolved in a solvent, cast onto a substrate and photopolymerized.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: January 12, 1999
    Assignee: Lynntech, Inc.
    Inventors: Dalibor Hodko, Oliver J. Murphy, G. Duncan Hitchens
  • Patent number: 5846447
    Abstract: A process for forming a dispersion of polytetrafluoroethylene particles in a liquid containing a dispersant by passing the mixture through a plurality of nozzles within a liquid-jet interaction chamber at a pressure of to deagglomerate and stabilize the polytetrafluoroethylene particles.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: December 8, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard P. Beatty
  • Patent number: 5837745
    Abstract: A free-radical polish composition is described. The composition can be applied and cured as an ultra thin film on finished surfaces to provide enhanced chemical and mar resistance. The composition comprises an aqueous emulsion including an olefin-functional polymer having low glass transition temperature or an olefin-functional prepolymer, and a silicone or silicone copolymer preferably with photoinitiators for UV and EB cure. The polish/emulsion can be applied, for example, to wet the surface of nitrocellulose lacquer wood finishes. The polish wet surface is first wiped to remove excess polish and thereafter exposed to UV radiation to provide a thin, polymerized permanent protective film on the polished surface.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: November 17, 1998
    Assignee: Lilly Industries, Inc.
    Inventors: Eugen Safta, James V. Mirante, Danny R. Linthicum, Greg Muselman
  • Patent number: 5777039
    Abstract: Block copolymers suitable for hot melt adhesive composition characterized in that they have the general formula (AB).sub.p (B.sup.1).sub.q X, wherein A is poly(vinylaromatic) block and B and B.sup.1 are the same or different poly(butadiene) blocks, wherein the 1,2 addition (vinyl) content is in the range of from 25 to 70% by weight, wherein X is the residue of a multivalent coupling agent having a maximum of active sites (m) in the range of from 3 to 6, wherein p and q both are integers of from 0 to m, provided that the sum of p and q values is less than m and the coupling efficiency is less than 90%, said block copolymer having an average total vinyl aromatic content in the range of from 10 to 50 wt % and preferably in the range of from 10 to 30 wt %, and having a total apparent molecular weight in the range of from 100,000 to 500,000.
    Type: Grant
    Filed: February 5, 1997
    Date of Patent: July 7, 1998
    Assignee: Shell Oil Company
    Inventors: Luc Ives Jaak De Craene, Martine Jeanne DuPont, Eric-Jack Gerard, Noel Raymond Maurice De Keyzer, Karin Marie-Louise Renee Morren, Jeroen Van Westrenen
  • Patent number: 5723513
    Abstract: Radiation-sensitive organo-halogen compounds that have a photo-labile halomethyl-1,3,5-triazine moiety and a polymeric moiety within the same molecule. The compounds of this invention are comprised of a polymeric moiety having attached or incorporated within its structure at least one 1,3,5-triazine nucleus, said triazine nucleus having at least one halomethyl substituent attached to a carbon atom of the triazine nucleus. These compounds are capable of being stimulated by actinic radiation at wavelengths of from about 250 to about 900 nanometers to generate free radicals and/or acids. The compounds of this invention are useful as photoinitiators in free radical polymerization reactions, oxidation-reduction reactions, or reactions sensitive to acid, and they also exhibit the capability to crosslink upon exposure to light.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: March 3, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James A. Bonham, Mitchell A. Rossman, Richard J. Grant
  • Patent number: 5700576
    Abstract: A coating agent for producing scratch-resistant coatings on plastic articles, which comprises:(1) 1-30 wt. % of a prepolymer, as a thickener (IP thickener), which prepolymer is bound in the composition of the coating by polymerization;(2) 20-80 wt. % of multifunctional acrylates, multifunctional methacrylates or mixtures thereof;(3) 5-75 wt. % of a thinner;(4) 0.01-10 wt. % of a UV-initiator;(5) 0-20 wt. % of customary additives; wherein the prepolymer (1) is obtained by radical polymerization of:(a) 90-99 wt. % of C.sub.1 -C.sub.8 -alkyl esters of acrylic- or methacrylic acid; and(b) 1-10 wt. % of a sulfur-containing regulator having at least three thiol groups. The coating system is distinguished by high scratch-resistance and good weatherability.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: December 23, 1997
    Assignee: Roehm GmbH Chemische Fabrik
    Inventors: Manfred Brehm, Rolf Neeb, Wolfgang Scharnke, Volker Kerscher
  • Patent number: 5514730
    Abstract: The present invention provides a radiation curable vinyl-silicone pressure-sensitive adhesive composition which combines the advantages of silicone and acrylate pressure-sensitive adhesives and which does not experience gross phase separation problems. The composition comprises at least about 20 weight percent of a certain telechelic silicone polymer, about 0.5 to about 80 weight percent of monofunctional free-radically polymerizable vinyl monomer copolymerizable with the silicone polymer, and a sufficient amount of a silicate MQ tackifying resin to impart a degree of adhesive tack to the cured composition at the use temperature, wherein the weight percentages of the silicone polymer and the monomer are based upon the total weight of the silicone polymer and monomer.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: May 7, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mieczyslaw H. Mazurek, Steven S. Kantner, David J. Kinning, Yvan A. Bogaert
  • Patent number: 5470910
    Abstract: Composite materials that contain nanoscaled particles are produced in thata) a compound, which is soluble in the solvent and belongs to a metal of the groups 6 to 15 of the periodic system or lanthanides,is reacted in an organic solvent withb) a precipitating reagent in order to form antimonides, arsenides, chalcogenides, halogenides or phosphides of the metal of the metal compound (a) in the present ofc) a bifunctional compound, which exhibits at least one electron pair-donor group and at least one group, which can be converted through polymerization or polycondensation into an organic or inorganic network;the resulting stabilized sol of nanoscaled particles is mixed withd) a compound, which can be polymerized or cured thermally or photochemically into a polymer, ande) a polymerization initiator;a hydrolysis and polycondensation of the optionally present groups that can be converted into an inorganic network is conducted; and the material is cured thermally of photochemically.
    Type: Grant
    Filed: June 28, 1994
    Date of Patent: November 28, 1995
    Assignee: Institut Fuer Neue Materialien Gemeinnuetzige GmbH
    Inventors: Lubomir Spanhel, Ertugrul Arpac, Rudiger Nab, Helmut Schmidt
  • Patent number: 5461087
    Abstract: A UV curable adhesive composition contains a C4 to C14 alkyl alcohol-acrylic acid ester monomer and a monofunctional oligoester acrylate. The composition is cured with UV rays to produce an adhesive the glass transition temperature of which is to be lower than -20.degree. C. Preferably, the composition also contains glass powders and/or polyolefin powders. A double-face adhesive tape includes two porous base sheets in an adhesive layer produced on curing a UV curable adhesive composition.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: October 24, 1995
    Assignee: Sony Corporation
    Inventors: Satoshi Takahashi, Ikuo Mitushima
  • Patent number: 5429846
    Abstract: The present invention provides a photo-setting conductive coating composition which is used as an antistatic material constituting articles wherein static electrification must be avoided, such as storage vessels for semi-conductor wafers, electronic/electric parts, floor/wall coverings for a production factory of semi-conductors, etc.The photo-setting conductive coating composition comprising 100 parts by weight of an antimony oxide-containing tin oxide powder (a) having a particle size of 0.01 to 0.4 .mu.m, 10 to 100 parts by weight of a (meth)acrylate compound (b) having at least two (meth)acryloyl groups in a molecule, 10 to 100 parts by weight of an acetal resin (c) having a residual hydroxyl group of 20 to 80 molar %, 0.1 to 10 parts by weight of a photopolymerization initiator (d) and 100 to 1000 parts by weight of an organic solvent (e).
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: July 4, 1995
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Toshiya Sugimoto, Minoru Suezaki, Kouji Maruyama
  • Patent number: 5420171
    Abstract: A UV curable organic solvent soluble, aqueous nonalkaline soluble and peelable temporary solder mask composition to be applied to a surface to be protected, having a reactive diluent monomer capable of polymerization upon exposure to ultraviolet light and a photoinitiator serving as a free radical source to initiate polymerization.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: May 30, 1995
    Assignee: Tech Spray, Inc.
    Inventor: Greg R. Unruh
  • Patent number: 5407970
    Abstract: The invention relates to adhesive compositions comprising terpolymers C.sub.6 to C.sub.10 unsaturated .alpha.-olefin monomers, C.sub.2 to C.sub.5 .alpha.-olefin monomers and polyene monomers and an effective amount of photoactive cross-linking agent to cross-link composition upon radiation from a source of active radiation.
    Type: Grant
    Filed: April 13, 1993
    Date of Patent: April 18, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James R. Peterson, Gaddam N. Babu
  • Patent number: 5389701
    Abstract: A crosslinked adhesive composition is provided comprising a tackifying resin and an epoxidized diolefin block polymer wherein the polymer is crosslinked through at least some of the epoxy functionality. A process to prepare this polymer is also provided. The preferred polymer is partially hydrogenated and lightly epoxidized.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: February 14, 1995
    Assignee: Shell Oil Company
    Inventor: James R. Erickson
  • Patent number: 5384339
    Abstract: A balancing compound comprising an epoxy resin, a photoinitiator in an effective amount to cure the resin at ambient temperatures upon the application of ultraviolet light (10 nm to 400 nm) of less than 40 watts per square centimeter in less than about 30 seconds, and a filler in an effective amount to give the compound a specific gravity above 1.1.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: January 24, 1995
    Inventor: Donn R. Starkey
  • Patent number: 5378735
    Abstract: An ultraviolet-curing covering composition comprising Component A which is obtained by reacting a hydroxyl group-containing polyfunctional acrylate with a silane coupling agent containing an isocyanate group(s), Component B of a polyfunctional acrylate having 3 or more acryloyl groups in the molecule, Component C of a silica sol in an organic solvent, and Component D of a photopolymerization initiator. This composition forms a coating film shows excellent hardwearing properties and adhesion to plastic substrates after ultraviolet-curing. Blending Component E of an acrylic resin and Component F of a solvent to the composition forms a coating film which can be processed before curing.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: January 3, 1995
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Noritaka Hosokawa, Kazuhide Hayama
  • Patent number: 5376691
    Abstract: The invention describes a material for making temporary crowns and bridges that comprises two pastes and can be mixed in a static mixer/application in one cycle without the incorporation of bubbles, and can be easily pressed out. The polymers produced from this are aesthetically pleasing and remarkably break-resistant. Their polymerization-related shrinkage proves to be extremely low. Their radiopaqueness meets clinical requirements.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: December 27, 1994
    Assignee: Ernst Muhlbaner KG
    Inventors: Ulrich May, Jurgen Engelbrecht, Ernst Muhlbauer, Edgar Lein
  • Patent number: 5364889
    Abstract: A method and composition for forming investment casting patterns wherein thermally-collapsible microspheres are incorporated into the pattern composition. The patterns can be made either by conventional pattern forming techniques or by solid imaging techniques. After investing the microsphere containing pattern in the ceramic shell, the pattern and shell are heated, causing a collapse of the microspheres and thereby preventing cracking of the shell. The shell is then heated to burn-out the remaining pattern material and fire the shell, thereby creating a mold.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: November 15, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John A. Quinn, Roxy N. Fan
  • Patent number: 5318808
    Abstract: Compositions for photocurable coatings are disclosed. The compositions comprise (a) an epoxidized vegetable oil, (b) a low molecular weight epoxy resin, (c) a photoinitiator for cationic polymerization and (d) a wax. Processes for making and using the coatings are also disclosed as are containers coated according to the invention.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: June 7, 1994
    Assignee: Polyset Company, Inc.
    Inventors: James V. Crivello, Ramkrishna Ghoshal
  • Patent number: 5296511
    Abstract: The present film-former composition comprises (a) an organosilazane copolymer having a perfluoroalkyl group-containing structural unit and a methacryloyloxy group-containing structural unit, (b) a photosensitizer soluble in an organic solvent, and (c) an organic solvent. The composition is cured by irradiation with ultraviolet light for a short period of time to form a film excellent in water repellency, oil repellency, and hardness.
    Type: Grant
    Filed: February 7, 1992
    Date of Patent: March 22, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihito Ohsawa, Kohei Hasegawa, Masanori Sutou, Satoshi Kuwata
  • Patent number: 5182786
    Abstract: This invention provides:(i) an acitve energy beam-curable composition for coating the surface of optical fibers therewith, the composition comprising about 100 parts by weight of an active energy beam-curable substance, about 0.5 to about 100 parts by weight of a particulate substance having a mean particle size of about 0.2 to about 200 .mu.m and optionally a photopolymerization initiator;(ii) a coated optical fiber prepared by applying the composition of item (i) to the surface of an optical fiber and curing the coating;(iii) a bundle-type optical fiber cable prepared using the coated optical fiber of item (ii);(iv) an optical fiber unit of the tape type prepared by applying the composition of item (i) to optical fibers and curing the coating; and(v) an optical fiber prepared using the optical fiber unit of item (iv).
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: January 26, 1993
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yoshimasa Kinaga, Masao Ogawa, Yoshihiro Kiyomura
  • Patent number: 5158991
    Abstract: An ultraviolet radiation-curable epoxyfunctionalized silicone controlled release composition having increased release levels is provided, comprising:(A) an epoxyfunctional diorganopolysiloxane;(B) a catalytic amount of a photocatalyst or a combination of photocatalysts; and(C) from about 1% to about 30% by weight based on (A) of an epoxyfunctional siloxane resinous controlled release addditive comprising monovalent siloxane and epoxyfunctional siloxane units and tetravalent SiO.sub.2 units.A release of at least 500 grams/2 inches is achieved by using from about 20% to about 30%, preferably from about 25% to about 30%, of component (C) and dispersing components (A)-(C) in (D) an amount of a hydrocarbon solvent sufficient to provide the composition with a solids content of about 20% and a solvent content of about 80%.
    Type: Grant
    Filed: August 24, 1990
    Date of Patent: October 27, 1992
    Assignee: General Electric Company
    Inventor: Karen D. Riding
  • Patent number: 5104921
    Abstract: A cured composition possessing excellent cohesive strength at high temperatures along with excellent adhesion, shear strength and solvent resistance is prepared by the high energy ionizing radiation initiated curing of a polymer composition comprising an alkenyl arene/conjugated diene block copolymer and a oligomer such that the unsaturation index of the composition is minimized. The radiation initiated curing of the adhesive composition is accomplished without requiring the aid of a coupling agent to promote crosslinking of the block copolymer during exposure to the radiation.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: April 14, 1992
    Assignee: Shell Oil Company
    Inventors: James R. Erickson, Earle E. Ewins, Jr.
  • Patent number: 5078791
    Abstract: A film forming composition including a film forming substance having amphiphilic molecules and being dispersed in a gel-like carrier having a non-liquid state below about 20.degree. C. The carrier stabilizes the film forming substance, and inhibits diffusion of moisture and oxygen into the composition. This minimizes deterioration of the film forming substance, and also minimizes undesirable formation of agglomerations of such substance. When the composition is applied to a surface, an ultra thin substantially continuous film of substantially uniform thickness forms spontaneously and attaches to the surface. The excess composition is then washed away.
    Type: Grant
    Filed: February 6, 1990
    Date of Patent: January 7, 1992
    Assignee: NanoFilm Corporation
    Inventors: Brij P. Singh, Raj Subramaniam
  • Patent number: 5008303
    Abstract: A molding composition for making casting patterns is described containing(a) 10-99.89, preferably 20-90%, by weight of at least one di or polyfunctional acrylic acid and/or methacrylic acid ester which burns without residue,(b) 0.01-5% by weight of an initiator system which can initiate the radical polymerization and(c) 0-80, preferably 10-70%, by weight of organic fillers, pigments and other auxiliary substances burning without residue,the quantity particulars each being related to the total amount of (a)+(b)+(c), characterized in that it further contains(d) 0.1-30, preferably 1-20%, by weight with respect to the component (a) of a chemically inert organic compound burning without residue and having a boiling point and/or sublimation point in the range >150.degree. C.This molding composition is distinguished by not causing any faults in the casting jacket, in particular no crack formation, on burning out of the mold.
    Type: Grant
    Filed: January 26, 1990
    Date of Patent: April 16, 1991
    Assignee: ESPE Stiftung & Co. Produktions- und Vertriebs KG
    Inventors: Oswald Gasser, Rainer Guggenberger, Klaus Ellrich
  • Patent number: 4902721
    Abstract: Foamed products are prepared by subjecting a crosslinked polymer such as an ethylene-carbon monoxide copolymer susceptible to heating by high frequency electromagnetic radiation such as microwave or radio frequency which has been imbibed or impregnated with a suitable mechanical or physical blowing agent such as a halogenated hydrocarbon to sufficient high frequency electromagnetic radiation to cause foaming of the polymer.
    Type: Grant
    Filed: July 19, 1989
    Date of Patent: February 20, 1990
    Assignee: The Dow Chemical Company
    Inventors: Tu-Anh Pham, Gerald M. Lancaster
  • Patent number: 4885315
    Abstract: Foamed products are prepared by subjecting a crosslinked polymer such as an ethylene-carbon monoxide copolymer susceptible to heating by high frequency electromagnetic radiation such as microwave or radio frequency which has been imbibed or impregnated with a suitable mechanical or physical blowing agent such as a halogenated hydrocarbon to sufficient high frequency electromagnetic radiation to cause foaming of the polymer.
    Type: Grant
    Filed: September 7, 1988
    Date of Patent: December 5, 1989
    Assignee: The Dow Chemical Company
    Inventors: Tu-Anh Pham, Gerald M. Lancaster
  • Patent number: 4842968
    Abstract: There is disclosed herein a hologram recording medium comprising of substrate formed of transparent and non-light scattering material having a plurality of open pores for said substrate and photopolymerization composition impregnated in said open pores. The photopolymerization composition consists essentially of a photopolymerizable monomer or oligomer which adheres to the surface of said open pores, a photopolymerization initiator and activator for controlling the photopolymerization speed.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: June 27, 1989
    Assignee: Sony Corporation
    Inventors: Chiaki Kojima, Hidetoshi Shimizu
  • Patent number: 4818621
    Abstract: A pressure sensitive adhesive film reducible in the adhesive force by the application thereto of ultraviolet light which comprises:(a) a base film permeable to ultraviolet light; and(b) a layer of a pressure sensitive adhesive formed on one side of the base film, the adhesive comprising:(i) at least one elastic polymer selected from the group consisting of a polymer mainly composed of an acrylic acid ester copolymer and a saturated copolyester mainly composed of dibasic carboxylic acids and dihydroxy alcohols;(ii) an ultraviolet light polymerizable acrylic acid ester having not less than two acryloyl or methacryloyl groups in the molecule and having a molecular weight of not more than about 1000, in amounts of about 15-200 parts by weight in relation to 100 parts by weight of the elastic polymer; and(iii) a photopolymerization initiator in amounts sufficent to induce the photopolymerization of the ultraviolet light polymerizable acrylic acid ester;The film is especially suitable for use as a dicing film in di
    Type: Grant
    Filed: February 14, 1986
    Date of Patent: April 4, 1989
    Assignee: Bando Chemical Industries, Ltd.
    Inventors: Hideo Kuroda, Masao Taniguchi
  • Patent number: 4716183
    Abstract: This invention comprises to styrene-diene block copolymer-oil-coupling agent compositions which are radiation cross-linked. In another aspect this invention relates to similar composition wherein the styrene-diene block copolymer is a blend of two different poly(styrene-ethylenebutylene-styrene) triblock copolymers, which composition may also be radiation cross-linked.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: December 29, 1987
    Assignee: Raychem Corp.
    Inventors: Jose P. Gamarra, C. John Swinmurn
  • Patent number: 4649062
    Abstract: Vehicles for ultraviolet radiation-curable ceramic enamels comprise (a) acrylate- or methacrylate-modified oligomers; (b) acrylate or methacrylate monomers, the functionality of (a) and (b) being selected to provide desired film and firing characteristics; (c) a combination of photoinitiators to provide a balance of surface and through cure; and an inhibitor to enhance shelf life. Printing media comprising pigmented frits and the vehicles are described, as are methods for their application to heat-resistant substrates, especially glass.
    Type: Grant
    Filed: April 25, 1985
    Date of Patent: March 10, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Raymond S. Kosiorek, Leslie R. Gatechair
  • Patent number: 4647598
    Abstract: An improved process for preparing a water-soluble polymer having an excellent water solubility and a high molecular weight, which comprises subjecting a thin layer of an aqueous solution of a water-soluble vinyl monomer to polymerization on a solid support, covering the thin layer with a substantially water-insoluble organic material, e.g. a paraffin, a silicone oil or a low molecular polyethylene, and/or a slightly water-soluble or substantially water-insoluble alkylene oxide adduct at least at a point of time when the aqueous monomer solution has not freely flowed, and further continuing the polymerization.
    Type: Grant
    Filed: January 4, 1985
    Date of Patent: March 3, 1987
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Yada, Shusaku Matsumoto, Yoshihiro Kawamori, Takao Saito, Tadashi Nishiyama, Yoshitugu Adachi
  • Patent number: 4569962
    Abstract: Polymeric compositions are provided in which perfluoropolyethers have been solubilized in non-fluorinated solvents by combining them with a solubilizing agent such as azotic conjugated compounds, and phosphorylated compounds. Typical of the perfluoropolyethers is ##STR1## Typical of the solubilizing agents is phosphorylated methacryloyloxyhydroxypropylisophthalate. The perfluoropolyether and the solubilizing agent are mixed to form a paste which is soluble in organic solvents such as methylethylketone. These compositions find utility as protective lubricant coatings for thin film magnetic recording media. They have the advantage that only one coating step is required in order to apply both the phosphorylated compound and the lubricating polyether. Recording media lubricated with these compositions have demonstrated excellent wear characteristics.
    Type: Grant
    Filed: September 19, 1983
    Date of Patent: February 11, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mario D. Burguette, George D. Foss