Composition Containing An Additive Which Enhances Degradation By Environmental Stimuli Or Process Of Preparing Patents (Class 523/124)
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Patent number: 6488997Abstract: There is disclosed a kind degradable material and its disposable products, and their manufacturing process. The primary raw material used in the process consists of powdered shell or stalk of crops, urea-formaldehyde resin, and melamine resin. The materials are mixed thoroughly and hot pressed in a single step forming of the products. Oven drying or spray coating is not needed in the process. The products have the following characteristics: simple formula, simple process, low price; and the following properties: with natural color, dense; tough and tensile; and easy for coloring. In addition, they are water, heat and freezing resistant, anti-corrosion, non-poisonous, anti-pollution and biodegradable. They are entirely new environmental protection green products.Type: GrantFiled: March 31, 2000Date of Patent: December 3, 2002Assignee: Enviro Concept Ltd.Inventor: Wang You Tong
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Publication number: 20020173558Abstract: Devices formed of or including biocompatible polyhydroxyalkanoates are provided with controlled degradation rates, preferably less than one year under physiological conditions. Preferred devices include sutures, suture fasteners, meniscus repair devices, rivets, tacks, staples, screws (including interference screws), bone plates and bone plating systems, surgical mesh, repair patches, slings, cardiovascular patches, orthopedic pins (including bone filling augmentation material), adhesion barriers, stents, guided tissue repair/regeneration devices, articular cartilage repair devices, nerve guides, tendon repair devices, atrial septal defect repair devices, pericardial patches, bulking and filling agents, vein valves, bone marrow scaffolds, meniscus regeneration devices, ligament and tendon grafts, ocular cell implants, spinal fusion cages, skin substitutes, dural substitutes, bone graft substitutes, bone dowels, wound dressings, and hemostats.Type: ApplicationFiled: May 1, 2002Publication date: November 21, 2002Applicant: Metabolix, Inc.Inventors: Simon F. Williams, David P. Martin, Frank A. Skraly
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Publication number: 20020173586Abstract: Disclosed is a thermogelling biodegradable aqueous polymer solution useful in providing a bioactive agent delivery system. The present invention provides a thermogelling biodegradable aqueous polymer solution with a polyethylene glycol (PEG) block and a biodegradable polyester block, where the blocks are linked to form a polymer of a general structure comprising the formula of An(B), where n is greater than 2 and A is selected from the group consisting of a polyethylene glycol block and a biodegradable polyester block, B is selected from the group consisting of a polyethylene glycol block and a biodegradable polyester block, and A is different from B.Type: ApplicationFiled: April 11, 2001Publication date: November 21, 2002Inventors: Byeong Moon Jeong, Anna Gutowska
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Patent number: 6482872Abstract: A process for manufacturing polymers containing a degradant component that increases the rate of polymer degradation. The process involves adding a degradant component to a fluid polymer immediately after the polymer is synthesized and while the polymer is still fluid to form a blend of the fluid polymer component and degradant component and mixing the blend of the fluid polymer component and degradant component to distribute the degradant component substantially homogeneously throughout the fluid polymer component.Type: GrantFiled: March 30, 2000Date of Patent: November 19, 2002Assignee: Programmable Materials, Inc.Inventor: Robert H. Downie
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Publication number: 20020151618Abstract: The invention relates to a mixture of biodegradable polyesters comprising: (A) a polyhydroxy acid of the poly-&egr;-caprolactone type and its copolymers, (B) aliphatic polyester, and (C) a polymer of polylactic acid, in which the concentration of (A) varies with respect to (A+B) in the range between 40 and 70% by weight, and the concentration of (C) with respects to (A+B+C) lies between 2 and 30%.Type: ApplicationFiled: January 25, 2002Publication date: October 17, 2002Inventors: Catia Bastioli, Gianfranco Del Tredici, Italo Guanella, Roberto Ponti, Claudio Russo
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Publication number: 20020123546Abstract: The present invention is directed to a method for reducing waste accumulation by using an environmentally degradable disposable material. The disposable material, which includes a hydroxycarboxylic acid-containing polymer, degrades hydrolytically during operative and disposal stages in a controlled manner such that the disposal degradation rate of the material is accelerated relative to the operative degradation rate of the material.Type: ApplicationFiled: February 12, 2001Publication date: September 5, 2002Applicant: Ecopol, LLCInventors: Donald M. Bigg, Richard G. Sinclair, Edward S. Lipinsky, John H. Litchfield, Billy R. Allen
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Publication number: 20020103273Abstract: To provide a plastic material suitable for preservation of the environment and a method for producing the same by adding organic or inorganic sludge to a resin derived from waste plastics to form a flame-retarded resin, an antistatic resin, or a biodegradable resin so that the electrical and physical properties of the resin are improved and sludge and waste plastics are effectively utilized.Type: ApplicationFiled: October 25, 2001Publication date: August 1, 2002Inventors: Yasuhito Inagaki, Yuko Fujihira
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Patent number: 6403675Abstract: Biodegradable, flowable or flexible polymer compositions are described comprising a polymer having the recurring monomeric units shown in formula I: wherein: each of R and R′ is independently straight or branched alkylene, either unsubstituted or substituted with one or more non-interfering substituents; L is a divalent cycloaliphatic group; R″ is selected from the group consisting of H, alkyl, alkoxy, aryl, aryloxy, heterocyclic or heterocycloxy; and n is 5 to 1,000, wherein said biodegradable polymer is biocompatible before and upon biodegradation. In one embodiment, one or more of R, R′ or R″ is a biologically active substance. Amorphous compositions containing a biologically active substance, in addition to the polymer, and methods for controllably releasing biologically active substances using the compositions, are also described.Type: GrantFiled: April 30, 1998Date of Patent: June 11, 2002Assignees: Guilford Pharmaceuticals, Inc., Johns Hopkins UniversityInventors: Wenbin Dang, Hai-quan Mao, Irina Kadiyala, Kam W. Leong, Zhong Zhao, James P. English
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Patent number: 6387386Abstract: Controlled release compositions of matter are disclosed comprising complexes for treating a population of one or more aquatic organisms in a column of water. The complexes comprise at least one system wherein the system comprises at least one bioactive agent as a component selected for treating a population of aquatic organisms, at least one carrier component, and at least one coating component for regulating the controlled release rate and release profile of the bioactive agent in water or at least one bioactive agent and one joint-function component that can serve as both a carrier and coating to regulate the controlled release rate and release profile of the bioactive agent in water, with or without optional binder components and/or additional formulation materials. The components are selected to sink or float so that the complexes will permeate and/or remain in any planar or volumetric segment of a water column for a period of time that is sufficient to effectively treat a population of aquatic organisms.Type: GrantFiled: December 10, 1999Date of Patent: May 14, 2002Assignee: Lee County Mosquito Control DistrictInventor: Richard Levy
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Patent number: 6380282Abstract: A method of producing an electrically conductive plastic molded article comprising blending 1 to 40 we. % of content shell fiber powder obtained by dry compressing a fiber contained in the mesocarp of the coconut fruit and processing the resulting fiber mass to 98 to 59 we. % of a biodegradable plastic or a non-biodegradable plastic, and adding 1 to 20 we. % of an electrically conductive additive. A molded article eliminating electrostatic troubles due to electrical chargeability, and improving biodegradable plastic is used, can be obtained.Type: GrantFiled: December 13, 1999Date of Patent: April 30, 2002Inventor: Ichiro Sugimoto
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Publication number: 20020045057Abstract: This invention relates to an article comprising a bio-supportive media which bio-degrades at a preferred rate, comprising at least one bio-limiting agent and at least one nutritional source on a substrate. The media may be characterized as a polymer, composite, or amalgam of commonly used materials. The invention relates to altering the physical/chemical composition of the media such that biodegradation can occur at a specific, usually accelerated, preferred rate. Further, the biodegradation rate may be managed and balanced concurrently with the ability to provide for the exposure of integral component(s) which are bio-active. This relationship essentially provides for a managed release or managed availability of agent(s) which creates a new set of ecological conditions.Type: ApplicationFiled: February 2, 2001Publication date: April 18, 2002Inventor: Dennis A. Guritza
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Patent number: 6368356Abstract: The invention provides a means of boosting the mechanical performance of shaped shaped medical devices comprising polymer hydrogels, such as stents, so that they may be more easily inserted into or removed from the body. In one aspect, the invention provides shaped medical devices having increased mechanical strength and comprising both ionic and covalent crosslinks. In another aspect, the invention provides a shaped medical device having a heterogeneous polymer composition and a variable dissolution or degradation rate along its length. The shaped medical devices according to the present invention retain their shape and stiffness during insertion into the body and can swell and soften inside the body to enhance patient comfort.Type: GrantFiled: February 25, 2000Date of Patent: April 9, 2002Assignee: SciMed Life Systems, Inc.Inventors: Sheng Ping Zhong, Arthur R. Madenjian, Douglas E. Godshall, John M. Ronan, Samuel A. Thompson
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Publication number: 20020035181Abstract: The present invention relates to a polymer dispersion with improved biodegradability.Type: ApplicationFiled: May 24, 2001Publication date: March 21, 2002Inventors: Kurt Willner, Thomas Fischer
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Publication number: 20020028857Abstract: The present invention relates to thermoplastic compositions which are degradable and/or compostable, the method of preparation of the degradable and/or compostable compositions and use of the degradable and/or compostable compositions in a monofilament, shaped article or film, or may be used as a coating, e.g., of paper, to achieve a stronger article. These compositions have the advantage over existing biodegradable and compostable compositions by exhibiting a higher dimensional stability and comparatively low cost.Type: ApplicationFiled: March 30, 2001Publication date: March 7, 2002Inventor: Norman L. Holy
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Patent number: 6344496Abstract: Biodegradable polymeric therapeutic substantially nonporous implant materials incorporating bioactive ceramics such as Bioglass® ceramic are provided. These implants provide increased mechanical properties and pH control, enabling the use of these materials to design porous and nonporous therapeutic implants used as cell scaffolds for healing of tissue defects or fixation devices, having desired degradation times, mechanical properties, elasticity and biocompatibility.Type: GrantFiled: October 5, 1999Date of Patent: February 5, 2002Assignees: OsteoBiologics, Inc., USBiomaterials CorporationInventors: Gabriele Niederauer, Kristine Kieswetter, Neil C. Leatherbury, David C. Greenspan
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Publication number: 20020006973Abstract: The present invention provides a biodegradable recycled polyester resin and a production process therefor, wherein the polyester resin is inexpensive and economical due to use of recycled aromatic polyesters, and further, can solve problems of wastes by affording biodegradability to the aromatic polyester which has so far been assumed to have no biodegradability. The biodegradable recycled polyester resin, according to the present invention, is obtained by a process including the step of carrying out a reaction of a recycled aromatic polyester (A) with an aliphatic polyester (B) having a number-average molecular weight of 3,000 to 300,000 in a reaction ratio (weight ratio) of (A)/(B)=95/5 to 5/95, thereby affording biodegradability to the recycled aromatic polyester (A).Type: ApplicationFiled: May 24, 2001Publication date: January 17, 2002Applicant: Nippon Shokubai Co., Ltd.Inventors: Hiroshi Itoh, Kazumi Fujioka
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Patent number: 6313194Abstract: A method for degrading a polymer by bringing same into contact with a solid phase composed of a carrier, a microorganism and an aqueous solution. The aqueous solution contains nutrients required for the growth of the microorganism and water. The carrier has a maximum water retention of at least 40 wt. % but at most 4,000 wt. %, the aqueous solution is retained in the carrier in an amount of at least 10% but at most 100% of the maximum water retention of the carrier, and the solid phase has a percentage of interstices of 25% or greater but smaller than 100%.Type: GrantFiled: October 4, 1996Date of Patent: November 6, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Tadashi Yagi, Kazuto Ishihara, Takeshi Irimajiri
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Patent number: 6312826Abstract: Biodegradable, agricultural mulches are prepared by coating paper with a cross-linked drying oil or a cross-linked, functionally modified drying oil. These mulches are inexpensive to produce, and are also water-resistant, mechanically stable and highly effective as weed barriers. The reactivities of various drying oils permit the development of a broad spectrum of coating systems and coating properties. In one embodiment of the invention, it is contemplated to complete cross-linking of coated paper in the field through either oxidative or photoinitiated processes.Type: GrantFiled: January 15, 1999Date of Patent: November 6, 2001Assignee: The United States of America as represented by the Secretary of AgricultureInventor: Randal L. Shogren
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Publication number: 20010027225Abstract: A process for manufacturing polymers containing a degradant component that increases the rate of polymer degradation. The process involves adding a degradant component to a fluid polymer immediately after the polymer is synthesized and while the polymer is still fluid to form a blend of the fluid polymer component and degradant component and mixing the blend of the fluid polymer component and degradant component to distribute the degradant component substantially homogeneously throughout the fluid polymer component.Type: ApplicationFiled: March 30, 2000Publication date: October 4, 2001Inventor: Robert H. Downie
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Patent number: 6258899Abstract: A cleavable epoxy resin composition suitable for encapsulating electronic chips comprising the cured reaction product of a diepoxide containing a cyclic anhydride curing agent or and an amine promoter.Type: GrantFiled: April 7, 1999Date of Patent: July 10, 2001Assignee: International Business Machines CorporationInventors: Stephen Leslie Buchwalter, Joseph Paul Kuczynski, John Gregory Stephanie
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Patent number: 6251968Abstract: The present invention relates to a method for modifying articles and/or semi-finished products made from polymer resin moulding compositions, wherein said articles and/or semi-finished products, which substantially consist of moulding compositions comprising mixtures of thermoplastic polymers where exhibit good biodegradability and thermoplastic polymers which exhibit poor biodegradability, are subjected to biodegradation.Type: GrantFiled: August 16, 1999Date of Patent: June 26, 2001Assignee: Wolfe Walsrode AGInventors: Ralf Schledjewski, Dirk Schultze, Gunter Weber, Rainhard Koch
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Patent number: 6245831Abstract: A disposable article including a biodisintegratable nonwoven material having improved fluid management properties. The nonwoven material may be produced using a thermoplastic composition that comprises a unreacted mixture of an aliphatic polyester polymer selected from the group consisting of a polybutylene succinate polymer, a polybutylene succinate-co-adipate polymer, a polycaprolactone polymer, a mixture of such polymers, or a copolymer of such polymers; a multicarboxylic acid; and a wetting agent. The thermoplastic composition exhibits substantial biodegradable properties yet is easily processed. The biodisintegratable nonwoven materials may be used in a disposable absorbent product intended for the absorption of fluids such as body fluids.Type: GrantFiled: June 29, 2000Date of Patent: June 12, 2001Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Fu-Jya Daniel Tsai, Brigitte C. Wertheim
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Patent number: 6239192Abstract: The present invention relates to new shaped articles which comprise active compounds and are based on thermoplastically processable, biologically degradable polymers, preferably polyesters, polyester amides, polyester urethanes and polyester urethane ureas, and their production and use for combating parasites on, around and in the environment of host animals, the shaped articles optionally serving, after use, for combating phytopathogenic insects on open-air or indoor plants.Type: GrantFiled: May 5, 1999Date of Patent: May 29, 2001Assignee: Bayer AktiengesellschaftInventors: Hanns Peter Müller, Doris Hackemüller-Bruns, Horst Gruttmann, Kerstin Heeschen
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Patent number: 6235825Abstract: A polylactic acid-based resin composition composed of a high molecular ingredient (A) comprising polylactic acid (a1) and an aliphatic polyester (B), and a film, particularly an inflation film, prepared from the resin composition. The film comprising the polylactic acid-based resin composition of the invention is biodegradable and excellent in flexibility and resistance to blocking of film and bleeding-out of plasticizer, has no anisotropy in tear strength, and can be suitably used for an agricultural multi-film and garbage bag. When the film of the invention is used for food wrapping, the film prevents fungus growth and contamination of color or odor, and thus can be suitably used.Type: GrantFiled: October 14, 1999Date of Patent: May 22, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Yasunori Yoshida, Shoji Obuchi, Yasuhiro Kitahara, Takayuki Watanabe, Hisashi Aihara, Tomoyuki Nakata, Kazuhiko Suzuki, Masanobu Ajioka
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Patent number: 6133362Abstract: An organo-metallic compound for use as a chemical aid in using scrap plastics in rubber formulations. The organo-metallic compound includes a zeolite, a starch, and a high molecular weight fatty acid soap. The compounds are in powder form and mixed together by a high-speed blender. The inventive compound creates a bridge between the scrap plastic and the rubber formulation allowing a blend between the two compounds. The compound accomplishes this while using a non-toxic substance. A method for using scrap plastics in rubber formulations is also provided. The method includes the step of adding the inventive compound to the scrap plastic and the virgin rubber.Type: GrantFiled: November 2, 1998Date of Patent: October 17, 2000Assignee: Polymer Process Technologies, IncInventor: Harvey Lewis Kaufman
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Patent number: 6117928Abstract: The invention relates to polylactide films the mechanical properties of which, in particular bursting strength, elongation and tearing strength, have been improved by adding to the polymer certain plasticizers. These plasticizers are preferably glycerol esters.Type: GrantFiled: February 1, 1999Date of Patent: September 12, 2000Assignee: Neste OyInventors: Elina Hiltunen, Johan-Fredrik Selin, Maria Skog
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Patent number: 6083621Abstract: Processed plant fine fibers such as those from the mesocarp of a coconut together are blended with a biodegradable plastic to produce a biodegradable plastic product that can be further made into other items. Plastics thus made from coconut husk fine fiber powder will return to the environment after disposal much more rapidly than those without coconut husk fine fiber powder. In the process, a dry compressed plant fine fiber powder is created from fine fibers of the coconut mesocarp. An example product created from this raw material is composed of 10 to 40% by weight of dry coconut husk powder mixed with environmentally degradable plastic. Environmentally non-degradable plastic may be added to the dry powder as a biodegradation rate modulator to create a modified raw material with a modified biodegradation rate. Plastic additives, standard in the industry, can be added to achieve additional desired properties.Type: GrantFiled: February 17, 1998Date of Patent: July 4, 2000Inventor: Ichiro Sugimoto
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Patent number: 6071984Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: June 25, 1998Date of Patent: June 6, 2000Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
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Patent number: 6010870Abstract: The present invention relates to the use of a composite material made of a fibrous material and binders in the form of a polymer of hydroxyfatty acids for the preparation of molded parts in the automobile field, in particular, for acoustic attenuation in the areas of the hood, bulkhead (on both sides), tunnel, door, roof, footwell, pumps, A to D pillars and air distribution duct, and as an optionally self-supporting base for interior trims, especially for instrument panel covers, tunnel linings, door trims, seat back linings, A to D pillar linings and spare wheel covers, and as parts with a double function, especially as roof liner, rear shelf, filling piece, trunk mat or undershield.Type: GrantFiled: November 3, 1998Date of Patent: January 4, 2000Assignee: HP-Chemie Pelzer Research and Development Ltd.Inventors: Helmut Pelzer, Alexander Steinbuchel
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Patent number: 6001382Abstract: Controlled release compositions of matter are disclosed comprising complexes for treating a population of one or more aquatic organisms in a column of water. The complexes comprise at least one system wherein the system comprises at least one bioactive agent as a component selected for treating a population of aquatic organisms, at least one carrier component, and at least one high molecular weight organic plasticizer coating component for regulating the controlled release rate and release profile of the bioactive agent in water or at least one bioactive agent and one joint-function component that can serve as both a carrier and coating to regulate the controlled release rate and release profile of the bioactive agent in water, with or without optional binder components and/or additional formulation materials.Type: GrantFiled: July 3, 1996Date of Patent: December 14, 1999Assignee: Lee County Mosquito Control DistrictInventor: Richard Levy
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Patent number: 5998500Abstract: This invention relates to a filter and a method of making a filter. The filter is made of randomly orientated fibers made from an interpenetrating network formed from at least two polymers which are substantially water soluble in their salt form and which ionically interact in an aqueous solution to form the interpenetrating network. The filter is made without organic solvents, particularly, volatile organic compounds, and the filter is sufficiently water soluble to biodegrade upon disposal. A desired use of the filter is a cigarette filter.Type: GrantFiled: June 23, 1998Date of Patent: December 7, 1999Inventors: Scott A. Cahill, Benjamin M. Chaloner-Gill, Amin Hassan
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Patent number: 5973024Abstract: The present invention provides a biodegradable plastic composition obtained by adding a carbodiimide compound to a biodegradable plastic, and a method for control of biodegradation rate of biodegradable plastic, which comprises adding a carbodiimide compound to a biodegradable plastic. According to the present invention, the biodegradation rate of biodegradable plastic can be controlled stably.Type: GrantFiled: June 17, 1998Date of Patent: October 26, 1999Assignee: Nisshinbo Industries, Inc.Inventors: Yasuo Imashiro, Ikuo Takahashi, Naofumi Horie, Shigekazu Suzuki
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Patent number: 5939467Abstract: The present invention relates to polymeric compositions that are biodegradable and that can be melt processed into various forms, including films, fibers, and nonwovens. The compositions include compatible or semicompatible blends of biodegradable polymers and have physical and thermomechanical integrity. Films formed from preferred polymeric compositions are suitable for use as backsheets in disposable absorbent articles. In a preferred embodiment, the polymeric composition includes a polyhydroxyalkanoate and at least one other biodegradable polymer selected from aliphatic polyester-based polyurethanes, a polylactide, polycaprolactone, or a mixture of two or more of these polymers. Where the second polymer is polycaprolactone, the composition preferably also includes a third polymer for enhancing the melt processability of the composition.Type: GrantFiled: September 16, 1994Date of Patent: August 17, 1999Assignee: The Procter & Gamble CompanyInventors: Andrew Julian Wnuk, David Harry Melik, Terrill Alan Young
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Patent number: 5916947Abstract: A non-toxic, antifouling coating composition is provided which comprises zinc oxide which has ben surface coated by photosensitizer(s) which increase the capability of zinc oxide to absorb visible light.Type: GrantFiled: September 18, 1996Date of Patent: June 29, 1999Assignee: Cape Cod Research, Inc.Inventors: Robert S. Morris, Myles A. Walsh, IV
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Patent number: 5908918Abstract: The present invention is directed to degradable blends containing polylactide, a degradable impact modifier, and a degradable plasticizer for use in packaging films. The degradable impact modifier can be a degradable, non-toxic elastomer or a degradable, non-toxic, non-elastomeric polymer having a low glass transition temperature, such as polycaprolactone and poly(ethylene glycol). The degradable plasticizer can be any plasticizer having a relatively low molecular weight, a high degree of miscibility with polylactide, and non-toxicity. The film has excellent flexibility and impact strength for packaging applications.Type: GrantFiled: May 26, 1998Date of Patent: June 1, 1999Assignee: Chronopol, Inc.Inventors: Xiaomao Chen, Kevin H. Schilling, William E. Kelly, Jr.
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Patent number: 5891576Abstract: A card having a paper as a base material laminated with decomposable plastic layers having such properties as durability, banding resistance, water resistance, chemical resistance, waterproofness, surface smoothness, glossiness end workability. Any visible information/design portion and/or a magnetic recording portion may be formed as required. The present invention improves the durability of a card using paper as a base material and provides the card which spontaneously decomposes even when left after being discarded.Type: GrantFiled: October 10, 1995Date of Patent: April 6, 1999Assignee: Toppan Printing Co., Ltd.Inventors: Toshibumi Imai, Akihiko Kobayashi, Tsutomu Shikakubo, Masayuki Taniguchi, Kazuya Yabusa, Testuo Aizawa, Motoko Yoshikawa
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Patent number: 5885602Abstract: The invention provides contaminant-reducing agent delivery compositions that are useful for the control of organic or inorganic contaminants in aquatic or terrestrial environments. The compositions comprise one or more superabsorbent solid organic polymers and at least one contaminant-reducing agent. These superabsorbent polymers act as the primary carriers of one or more contaminant-reducing agents effective for the control of organic or inorganic contaminants in aquatic or terrestrial environments. Contaminant-reducing agents include film-forming agents, microbial agents, nutrient agents, and mixtures thereof. The invention also provides a method to entrap and accumulate organic and inorganic contaminants in one or more superabsorbent polymer compositions containing no contaminant-reducing agent. The invention also provides a method to entrap water in superabsorbent polymers to activate natural and applied microbial and nutrient contaminant-reducing agents in terrestrial environments.Type: GrantFiled: May 27, 1997Date of Patent: March 23, 1999Assignee: Lee County Mosquito Control DistrictInventor: Richard Levy
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Patent number: 5880184Abstract: A biodegradable composition suitable for the manufacture of low density loose-fill packing by extrusion, which is an aqueous dispersion comprising (1) finely divided particles of a gelatinizable starch product and (2) a water-soluble polymer dispersed in (3) water having dissolved therein (4) a copolymer of vinyl, methyl, ether and maleic anhydride.Type: GrantFiled: January 27, 1998Date of Patent: March 9, 1999Assignee: Environmental PackingInventor: Charles Raphael Lazarus
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Patent number: 5866634Abstract: The present invention provides a novel biodegradable polymer compositions effecting superiority in elongation at break, Izod impact strength and mold releasability which has not been obtained before the past and provides a biodegradable shrink film exceling in transparency, strength, flexibility, mold releasability and shrinkability by applying the biodegradable polymer composition to the shrink film. Thus, the biodegradable polymer compositions are provided which comprise as a main component a mixture of two or more of polylactic acids, glycol/aliphatic dicarboxylic acid copolymers and polycaprolactones and these biodegradable polymer compositions are applied to shrink films.Type: GrantFiled: August 28, 1996Date of Patent: February 2, 1999Assignee: Shin-Etsu Chemical Co., LtdInventors: Yuji Tokushige, Makoto Ooura, Norio Nakamura, Shuhei Ueda
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Patent number: 5859090Abstract: Nontoxic, biodegradable injection-molded, plastic shotshell components, and method of manufacturing same, the components having a fused degradation composition comprising as its active ingredients polycaprolactone, amide stearate and vegetable oil, the latter two enhancing the degradation activity of the polycaprolactone and imparting injection-moldability thereto.Type: GrantFiled: January 16, 1996Date of Patent: January 12, 1999Assignee: Federal Cartridge CompanyInventors: Mohammed Shahid, David C. Longren
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Patent number: 5859166Abstract: The present invention provides a hydrophilic resin composition which is obtained by adding, to a hydrophilic resin selected from a carboxyl group-containing hydrophilic acrylic copolymer resin, a carboxyl group-containing hydrophilic polyester resin and a carboxyl group-containing hydrophilic polyurethane resin, a hydrophilic carbodiimide represented by the following general formula (1): ##STR1## (wherein n is an average polymerization degree and is an integer of 1-30; m is an integer of 4-30; R.sub.1 is a lower alkyl group; and R.sub.2 is a hydrogen atom or a methyl group) and which has an acid value based on the carboxyl group of the hydrophilic resin, of 10-400 mg KOH/g and a molar ratio of the carbodiimide group to the carboxyl group, of 0.2-5.0.Type: GrantFiled: August 1, 1997Date of Patent: January 12, 1999Assignee: Nisshinbo Industries, Inc.Inventors: Eiji Sasaki, Yasuo Imashiro, Ikuo Takahashi, Naofumi Horie
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Patent number: 5854304Abstract: The present invention is directed to an additive degradable/compostable package, the combination of a metal carboxylate and an aliphatic poly hydroxy-carboxyl acids, which is added to polyolefin resins in the production of specific products. The addition of the additive degradable/compostable package produces a packaging product which is degradable/compostable. The additive package may include calcium oxide (CaO) to make the modified polyolefin resin more processable. Further, stabilizers or oxidizers may be added to the additive package. The additive package is specifically modified or tailored to the application of the packaging product, e.g. trash bag, compost bag, merchant bag, diaper liner, wrapping film, agricultural film, landfill cover or foamed planks. The present invention further includes the method or process of producing the degradable/compostable concentrates and the improvement of the process of making the degradable/compostable packaging products by the addition of calcium oxide (CaO).Type: GrantFiled: July 24, 1997Date of Patent: December 29, 1998Assignee: EPI Environmental Products Inc.Inventors: Rodrigo A. Garcia, Joseph Gock Gho
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Patent number: 5834582Abstract: Disclosed are degradable materials which-include a nontoxic hydrolytically degradable polymer and nontoxic modifier, wherein the modifier is compatible with the polymer and the modifier is nonvolatile and nonfugitive. Also disclosed are processes for forming the various degradable materials, which include films, molded products, laminates, foams, powders, nonwovens, adhesives and coatings. The disclosed materials and processes are particularly useful for the production of commercial and consumer products in high volumes which are suitable for recycling after use or which are discarded into the environment in large volumes.Type: GrantFiled: February 20, 1996Date of Patent: November 10, 1998Assignee: Chronopol, Inc.Inventors: Richard G. Sinclair, Edward S. Lipinsky
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Patent number: 5827905Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: September 18, 1996Date of Patent: October 27, 1998Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
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Patent number: 5824751Abstract: The biodegradable composition comprises at least poly(beta-hydroxybutyric acid) or a biodegradable copolymer thereof and a stereospecifically regular block copolymer having the structure units of formula (I): ##STR1## where R1 is a hydrocarbon group having 1 to 14 carbon atoms, optionally including double bonds, oxygen atoms or both of them; and m and n are respectively an integer ranging from 300 to 5,000, or having the structure units of formula (II): ##STR2## where R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are either a hydrogen atom or a methyl group; and m and n are respectively an integer ranging from 300 to 5,000.Type: GrantFiled: January 26, 1996Date of Patent: October 20, 1998Assignee: Takasago Koryo Kogyo Kabushiki Kaisha (Takasago International Corporation)Inventors: Yoji Hori, Yoko Takahashi, Hideyuki Hongo, Akio Yamaguchi, Toshimitsu Hagiwara
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Patent number: 5786408Abstract: Disclosed are a biodegradable polyester resin composition, and a biodegradable article molded from the composition.The polyester resin composition and the molded article of the present invention are excellent in biodegradability without any loss of mechanical properties.Type: GrantFiled: June 20, 1996Date of Patent: July 28, 1998Assignee: Daicel Chemical Industries, Ltd.Inventors: Takayuki Kuroda, Masahiko Ono, Terumasa Daito, Kazushi Watanabe
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Patent number: 5760118Abstract: Disclosed are products made of degradable materials which include a hydrolytically degradable polymer. The degradable materials can be internally or externally modified. The internally modified polymer composition has polymers modified by the use of comonomers having a relatively high molecular weight. The externally modified polymer composition includes a modifier, wherein the modifier is compatible with the polymer and the modifier is nontoxic, nonvolatile and nonfugitive. The various degradable materials include films, fibers, extruded and molded products, laminates, foams, powders, nonwovens, adhesives and coatings. The disclosed materials are particularly useful for the production of a variety of products in high volumes which are suitable for recycling after use or which are discarded into the environment in large volumes.Type: GrantFiled: June 5, 1995Date of Patent: June 2, 1998Assignee: Chronopol, Inc.Inventors: Richard G. Sinclair, Edward S. Lipinsky, James D. Browning, Donald Bigg, Thomas A. Rogers
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Patent number: 5756651Abstract: The present invention is directed to degradable blends containing polylactide, a degradable impact modifier, and a degradable plasticizer for use in packaging films. The degradable impact modifier can be a degradable, non-toxic elastomer or a degradable, non-toxic, non-elastomeric polymer having a low glass transition temperature, such as polycaprolactone and poly(ethylene glycol). The degradable plasticizer can be any plasticizer having a relatively low molecular weight, a high degree of miscibility with polylactide, and non-toxicity. The film has excellent flexibility and impact strength for packaging applications.Type: GrantFiled: July 17, 1996Date of Patent: May 26, 1998Assignee: Chronopol, Inc.Inventors: Xiaomao Chen, Kevin H. Schilling, William E. Kelly, Jr.
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Patent number: 5753724Abstract: A hot melt adhesive composition can be made using a polyester derived from 2-propanoic acid (lactic acid). A thermoplastic resin grade polyester can be formulated into a functional adhesive using adhesive components. A lower molecular weight material can be used as a tackifying resin with a biodegradable/compostable resin in a formulated hot melt adhesive. The adhesive material can be made pressure sensitive and can be made entirely by a degradable by combining the polyester polymer with other biodegradable/compostable ingredients. The resulting adhesive composition that can be used in a variety of applications. The biodegradable/compostable adhesive material can be used as a substitute for non-biodegradable materials made from commercial polymers that resist attack by bacteria, fungi and other microbial populations. The hot melt adhesives can be used in (e.g.) packaging and the manufacture of disposable articles which are made from degradable materials.Type: GrantFiled: January 21, 1997Date of Patent: May 19, 1998Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Garry J. Edgington, Christopher M. Ryan
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Patent number: RE36548Abstract: The present invention relates to biodegradable PHA copolymers comprising at least two randomly repeating monomer units. The present invention further relates to a plastic article comprising a biodegradable copolymer, wherein the biodegradable copolymer comprises at least two randomly repeating monomer units (RRMU) wherein the first RRMU has the structure ##STR1## wherein R.sup.1 is H, or C.sub.1 or C.sub.2 alkyl, and n is 1 or 2; the second RRMU has the structure ##STR2## wherein R.sup.2 is a C.sub.4 -C.sub.19 alkyl or alkenyl; and wherein at least 50% of the RRMUs have the structure of the first RRMU. The present invention further relates to an absorbent article comprising a liquid pervious topsheet, a liquid impervious backsheet comprising a film comprising a PHA of the present invention and an absorbent core positioned between the topsheet and the backsheet.Type: GrantFiled: October 23, 1998Date of Patent: February 1, 2000Assignee: The Procter & Gamble CompanyInventor: Isao Noda