Containing Carbohydrate Or Cellular Material Derived From Plant Or Animal Patents (Class 523/128)
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Patent number: 6235816Abstract: A biologically degradable polymer mixture containing at least one biopolymer made from renewable raw materials and a polymer selected from the following materials: an aromatic polyester; a polyester-copolymer with both aliphatic and aromatic blocks; a polyesteramide; a polyglycol; a polyester urethane; and/or mixtures of these components. The preferred renewable raw material is starch, more preferably native starch, most preferably native starch that has been predried.Type: GrantFiled: October 27, 1999Date of Patent: May 22, 2001Assignee: Biotec Biologische Naturverpackungen GmbHInventors: Jurgen Lorcks, Winfried Pommeranz, Harald Schmidt
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Patent number: 6218321Abstract: Articles of manufacture which comprise biodegradable fibers and fabrics made therefrom. The fibers are made from starch-based biodegradable thermoplastic polymers, which preferably include a an additional biodegradable thermoplastic polymer blended with thermoplastic starch for improved chemical and physical properties. Threads or fibers for the manufacture of these articles are drawn in a process that improves their mechanical properties, particularly their strength. These threads or fibers can be used in the manufacture of articles that have open, semi-densely packed or densely packed structures.Type: GrantFiled: August 25, 1997Date of Patent: April 17, 2001Assignee: Biotec Biologische Naturverpackungen GmbHInventors: Jurgen Lorcks, Winfried Pommeranz, Harald Schmidt
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Patent number: 6184272Abstract: A fiber-reinforced molded plastic part, a process for its manufacture and a use. The fiber-reinforced molded plastic part consists of a plastic matrix with natural fibers particularly arranged in a uniformly distributed manner in the plastic matrix. The plastic matrix has at least two mutually mixed polymers, of which one is a biopolymer and the other is a polymer which is at least largely resistant to biological stress.Type: GrantFiled: February 12, 1998Date of Patent: February 6, 2001Assignee: DiamlerChrysler AGInventors: Thomas Foelster, Ralph Greiner, Dirk Schaefer
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Patent number: 6177183Abstract: The present invention includes processes and resulting structures for producing a modified polymer having interconnecting channels. The interconnecting channels act as controlled transmission passages through the polymer. A hydrophilic agent is blended into the polymer so that it is distributed within the polymer. In one embodiment, an activation material is blended into the polymer so that the activation material is distributed within the product. The product is solidified so that the hydrophilic agent forms passages in the product through which a desired composition is communicable to the activation material that is entrained within the product. The solidified product may be used to form a desired shaped article such as plug type inserts and liners for closed containers, or it may be formed into a film, sheet, bead or pellet.Type: GrantFiled: September 18, 1998Date of Patent: January 23, 2001Assignee: Capitol Specialty Plastics, Inc.Inventor: Ihab M. Hekal
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Patent number: 6096809Abstract: A biologically degradable polymer mixture contains at least one starch biopolymer made from renewable raw materials, a plasticizer, and a polymer selected from the following materials: an aromatic polyester; a polyester-copolymer with both aliphatic and aromatic blocks; a polyesteramide; a polyglycol; a polyester urethane; and/or mixtures of these components.Type: GrantFiled: December 15, 1997Date of Patent: August 1, 2000Assignee: Bio-Tec Biologische Naturverpackungen GmbH & Co. KGInventors: Jurgen Lorcks, Winfried Pommeranz, Harald Schmidt
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Patent number: 6083621Abstract: Processed plant fine fibers such as those from the mesocarp of a coconut together are blended with a biodegradable plastic to produce a biodegradable plastic product that can be further made into other items. Plastics thus made from coconut husk fine fiber powder will return to the environment after disposal much more rapidly than those without coconut husk fine fiber powder. In the process, a dry compressed plant fine fiber powder is created from fine fibers of the coconut mesocarp. An example product created from this raw material is composed of 10 to 40% by weight of dry coconut husk powder mixed with environmentally degradable plastic. Environmentally non-degradable plastic may be added to the dry powder as a biodegradation rate modulator to create a modified raw material with a modified biodegradation rate. Plastic additives, standard in the industry, can be added to achieve additional desired properties.Type: GrantFiled: February 17, 1998Date of Patent: July 4, 2000Inventor: Ichiro Sugimoto
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Patent number: 6072015Abstract: A method is provided for producing a painted article comprising: (a) preparing a lignin solution comprising lignin and a dye or pigment; (b) mixing the lignin solution with a phenol oxidizing enzyme; (c) incubating the mixture from said step (b) under conditions and for a time sufficient to form a solution of a desired viscosity; (d) contacting or spreading the mixture from the step (c) on an article to be painted; and (e) allowing the mixture to set onto the article by subjecting the article to conditions and for a time sufficient to form a paint on the surface of the article.Type: GrantFiled: December 8, 1998Date of Patent: June 6, 2000Assignee: Genencor International, Inc.Inventors: Rob Bolle, Wolfgang Aehle
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Patent number: 6071984Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: June 25, 1998Date of Patent: June 6, 2000Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
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Patent number: 6011092Abstract: The invention relates to a process for thermoplasticizing starch, a melt-processible polymer composition, which contains a starch-based component and a thermoplastisized polymer component, and a method for preparating such a composition. According to the invention the starch component, which contains hydroxyl groups capable of reacting with isocyanate groups, is modified so that it can be dissolved or gelatinized/plastisized in the melt of a hydroxy acid polymer. The starch component is then reacted with a thermoplastic component formed by a hydroxy acid polymer, in particular a lactic acid polymer, in order to produce a melt-processible, biologically degradable starch-based polymer, which can be used as an adhesive and for coating of paper and cardboard products and for preparation of injection moulded and thermoformed articles.Type: GrantFiled: January 12, 1998Date of Patent: January 4, 2000Assignee: Valtion teknillinen tutkimuskeskusInventors: Jukka Seppala, Minna Malin, Soili Peltonen, Elina Heikkila, Jani Vuorenpaa
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Patent number: 6010870Abstract: The present invention relates to the use of a composite material made of a fibrous material and binders in the form of a polymer of hydroxyfatty acids for the preparation of molded parts in the automobile field, in particular, for acoustic attenuation in the areas of the hood, bulkhead (on both sides), tunnel, door, roof, footwell, pumps, A to D pillars and air distribution duct, and as an optionally self-supporting base for interior trims, especially for instrument panel covers, tunnel linings, door trims, seat back linings, A to D pillar linings and spare wheel covers, and as parts with a double function, especially as roof liner, rear shelf, filling piece, trunk mat or undershield.Type: GrantFiled: November 3, 1998Date of Patent: January 4, 2000Assignee: HP-Chemie Pelzer Research and Development Ltd.Inventors: Helmut Pelzer, Alexander Steinbuchel
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Patent number: 6008276Abstract: Thermoplastically moldable, biodegradable, starch-containing polymer blends consisting essentially ofA) 100 parts by weight of anhydrous starch,B) from 0.1 to 70 parts by weight of polyurethane containing urea groups and based on selected starting materials,C) from 0.5 to 70 parts by weight of a plasticizer component andD) from 2 to 20 parts by weight of water,a process for producing these blends by mixing the individual components in plastics processing machines and their use for producing moldings, films, fibers, coatings or laminates by thermoplastic processing.Type: GrantFiled: November 24, 1997Date of Patent: December 28, 1999Assignee: Bayer AktiengesellschaftInventors: Jochen Kalbe, Hanns-Peter Muller, Rainhard Koch
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Patent number: 6001382Abstract: Controlled release compositions of matter are disclosed comprising complexes for treating a population of one or more aquatic organisms in a column of water. The complexes comprise at least one system wherein the system comprises at least one bioactive agent as a component selected for treating a population of aquatic organisms, at least one carrier component, and at least one high molecular weight organic plasticizer coating component for regulating the controlled release rate and release profile of the bioactive agent in water or at least one bioactive agent and one joint-function component that can serve as both a carrier and coating to regulate the controlled release rate and release profile of the bioactive agent in water, with or without optional binder components and/or additional formulation materials.Type: GrantFiled: July 3, 1996Date of Patent: December 14, 1999Assignee: Lee County Mosquito Control DistrictInventor: Richard Levy
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Patent number: 5964933Abstract: The object of the present invention is to provide an inexpensive biodegradable molding material which allows easy adjustment of the biodegradability of the material as a molding material, which undergoes 100% degradation within a fixed period following use in molded articles without requiring any excessively long time for degradation, which has a high heat resistance, and therefore, can be used to mold disposable food containers or foodstuff packaging trays which are steam-sterilizable, as well as planting pots which allow the transplantation of young plants, etc. into the soil together with the planting pots, which possesses water resistance, and which is superior in terms of material strength and moldability. 51 to 70 wt % powdered paper and 30 to 49 wt % biodegradable aliphatic polyester resin are mixed with a consideration of biodegradability, moldability and material strength, etc. in accordance with the application involved so as to obtain a biodegradable molding material.Type: GrantFiled: June 30, 1997Date of Patent: October 12, 1999Assignee: Industrial Technical R & D Laboratory, Inc.Inventor: Kenichi Nakamura
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Patent number: 5939467Abstract: The present invention relates to polymeric compositions that are biodegradable and that can be melt processed into various forms, including films, fibers, and nonwovens. The compositions include compatible or semicompatible blends of biodegradable polymers and have physical and thermomechanical integrity. Films formed from preferred polymeric compositions are suitable for use as backsheets in disposable absorbent articles. In a preferred embodiment, the polymeric composition includes a polyhydroxyalkanoate and at least one other biodegradable polymer selected from aliphatic polyester-based polyurethanes, a polylactide, polycaprolactone, or a mixture of two or more of these polymers. Where the second polymer is polycaprolactone, the composition preferably also includes a third polymer for enhancing the melt processability of the composition.Type: GrantFiled: September 16, 1994Date of Patent: August 17, 1999Assignee: The Procter & Gamble CompanyInventors: Andrew Julian Wnuk, David Harry Melik, Terrill Alan Young
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Patent number: 5910520Abstract: The invention presents classes of thermoplastic, biodegradable compositions. Tests indicate that these compositions exhibit good mechanical properties, and readily degrade in the presence of microorganisms. The compositions of this invention are useful for producing injection-molded, thin-walled articles that are capable of appreciably degrading in the sewage system within thirty (30) days.Type: GrantFiled: January 15, 1993Date of Patent: June 8, 1999Assignee: McNeil-PPC, Inc.Inventors: Shmuel Dabi, Ram L. Kataria
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Patent number: 5891576Abstract: A card having a paper as a base material laminated with decomposable plastic layers having such properties as durability, banding resistance, water resistance, chemical resistance, waterproofness, surface smoothness, glossiness end workability. Any visible information/design portion and/or a magnetic recording portion may be formed as required. The present invention improves the durability of a card using paper as a base material and provides the card which spontaneously decomposes even when left after being discarded.Type: GrantFiled: October 10, 1995Date of Patent: April 6, 1999Assignee: Toppan Printing Co., Ltd.Inventors: Toshibumi Imai, Akihiko Kobayashi, Tsutomu Shikakubo, Masayuki Taniguchi, Kazuya Yabusa, Testuo Aizawa, Motoko Yoshikawa
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Patent number: 5880184Abstract: A biodegradable composition suitable for the manufacture of low density loose-fill packing by extrusion, which is an aqueous dispersion comprising (1) finely divided particles of a gelatinizable starch product and (2) a water-soluble polymer dispersed in (3) water having dissolved therein (4) a copolymer of vinyl, methyl, ether and maleic anhydride.Type: GrantFiled: January 27, 1998Date of Patent: March 9, 1999Assignee: Environmental PackingInventor: Charles Raphael Lazarus
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Patent number: 5874486Abstract: A polymeric composition comprises a matrix including a starch component and at least one synthetic thermoplastics polymeric component in which a filler is dispersed, characterised in that the matrix includes a fluidising agent selected from the group consisting of C.sub.12 -C.sub.22 fatty acids, C.sub.12 -C.sub.22 fatty alcohols, esters and amides of the said fatty acids, poly and polyglycol ethers of alditols or polyglycerols esterified with the said fatty acids and their mixtures and the said filler comprises natural fillers of an organic nature dispersed in the matrix in quantities of from 5% to 70% by weight with reference to the total weight of the composition.Type: GrantFiled: March 27, 1995Date of Patent: February 23, 1999Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Matteo Nicolini
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Patent number: 5852114Abstract: Biodegradable thermoplastic polymer blend compositions are presented in which a first polymer and a second polymer are intimately associated together in a uniform, substantially homogeneous blend. The second polymer of the composition acts to facilitate biodegradation of the composition, and of shaped articles manufactured therefrom, at a rate which is enhanced over that of the most slowly biodegrading individual polymer component of the composition. The composition may further comprise a polysaccharide component, such as a starch component like destructurized starch.Type: GrantFiled: March 20, 1995Date of Patent: December 22, 1998Assignee: Novon International, Inc.Inventors: Gary L. Loomis, Michael J. Izbicki, Anthony Flammino
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Patent number: 5852069Abstract: In this disclosure, there are provided materials which completely degrade in the environment far more rapidly than pure synthetic plastics but which possesses the desirable properties of a thermoplastic: strength, impact resistance, stability to aqueous acid or base, and deformation at higher temperatures. There is provided a method for using the degradable plastic materials in preparing strong, moldable solids. There is further provided a method of making and applications for macromolecular, surface active agents that change the wetting behavior of lignin-containing materials. These surface active agents are used to provide a method of making and applications for synthetic polymers coupled to pieces of a vascular plant using macromolecular surface active agents.Type: GrantFiled: October 2, 1997Date of Patent: December 22, 1998Inventors: John J. Meister, Meng-Jiu Chen
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Patent number: 5827905Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: September 18, 1996Date of Patent: October 27, 1998Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
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Patent number: 5753724Abstract: A hot melt adhesive composition can be made using a polyester derived from 2-propanoic acid (lactic acid). A thermoplastic resin grade polyester can be formulated into a functional adhesive using adhesive components. A lower molecular weight material can be used as a tackifying resin with a biodegradable/compostable resin in a formulated hot melt adhesive. The adhesive material can be made pressure sensitive and can be made entirely by a degradable by combining the polyester polymer with other biodegradable/compostable ingredients. The resulting adhesive composition that can be used in a variety of applications. The biodegradable/compostable adhesive material can be used as a substitute for non-biodegradable materials made from commercial polymers that resist attack by bacteria, fungi and other microbial populations. The hot melt adhesives can be used in (e.g.) packaging and the manufacture of disposable articles which are made from degradable materials.Type: GrantFiled: January 21, 1997Date of Patent: May 19, 1998Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Garry J. Edgington, Christopher M. Ryan
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Patent number: 5741832Abstract: A mechanically-bonded, water-absorbent fiber mulch including natural and crimped synthetic fibers that are intimately mixed to form a mechanically-bonded fiber mulch. A water-absorbent polymer-based material is dispersed throughout the fiber mulch to increase its water absorption capacity.Type: GrantFiled: November 5, 1996Date of Patent: April 21, 1998Inventor: Kevin Scott Spittle
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Patent number: 5741875Abstract: In this disclosure, there are provided materials which completely degrade in the environment far more rapidly than pure synthetic plastics but which possesses the desirable properties of a thermoplastic: strength, impact resistance, stability to aqueous acid or base, and deformation at higher temperatures. There is provided a method for using the degradable plastic materials in preparing strong, moldable solids. There is further provided a method of making and applications for macromolecular, surface active agents that change the wetting behavior of lignin-containing materials. These surface active agents are used to provide a method of making and applications for synthetic polymers coupled to pieces of a vascular plant using macromolecular surface active agents.Type: GrantFiled: March 8, 1995Date of Patent: April 21, 1998Inventors: John J. Meister, Meng-Jiu Chen
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Patent number: 5719203Abstract: A method of producing a composition which is composed of from 5 to 50 wt. % of caoutchouc, preferably natural caoutchouc; from 4 to 25 wt. % of starch powder; from 10 to 50 wt. % of one of polybetahydroxybutyrate or cellulose; and from 0 to 15 wt. % of auxiliary agent, and which is biodegradable includes providing caoutchouc in one of flaked or granular form; providing initial materials selected from the group consisting of starch, polybetahydroxybutyrate, cellulose, and auxiliary agent, in ground form as one of a powder or granulated; homogeneously mixing the initial materials into the caoutchouc to provide a homogeneous mixture: plasticizing the homogeneous mixture by heating in one of a screw-type extruder or injection molding machine to provide a plasticized mass; and ejecting the plasticized mass from the extruder or injection-molding machine and allowing the mass to cool. Preferably, plasticizing is carried out of a temperature ranging from 170.degree. C. to 180.degree. C.Type: GrantFiled: February 14, 1997Date of Patent: February 17, 1998Assignee: Metraplast H. Jung GmbHInventor: Michael Thobor
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Patent number: 5698612Abstract: The present invention provides thermoplastically workable and completely biodegradable moulding compositions, a process for the preparation thereof and the use thereof as biodegradable materials for the production of, for example, injection-moulded parts, films, fibres or coatings.Type: GrantFiled: December 11, 1996Date of Patent: December 16, 1997Assignee: Bayer AkteingesellschaftInventors: Joachim Simon, Hanns Peter Muller, Dirk Jacques Dijkstra, Jurgen Engelhardt, Volkhard Muller, Gunter Weber
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Patent number: 5667574Abstract: A starch-based composition for preparing an environment degradable .alpha.-olefinic polymer molding material, which includes 95-99 wt % of starch, 0.2-0.8 wt % of a titanate coupling agent having the following formula (I), 0-2 wt % of paraffin and 0-2 wt % of fatty acid: ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen, or R.sub.1 and R.sub.2 together are .dbd.O.Type: GrantFiled: November 6, 1996Date of Patent: September 16, 1997Assignee: Chi May Co., Ltd.Inventor: Yuan Qing Zhang
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Patent number: 5662731Abstract: Compositions, methods, and systems for manufacturing articles, particularly containers and packaging materials, having a fiber-reinforced, starch-bound cellular matrix. Suitable mixtures used to form the articles are prepared by first preparing a viscous preblended mixture comprising water, a gelatinized starch-based binder, and fibers having an average length greater than about 2 mm. The highly viscous preblended mixture effectively transfers the shearing forces of the mixer to the fibers. The final moldable mixture is then prepared by mixing into the preblended mixture the remaining starch-based binder, water, and other desired admixtures, e.g., mold-releasing agents, inorganic filler rheology-modifying agents, plasticizers, coating materials, and dispersants, in the correct proportions to form an article which has the desired performance criteria.Type: GrantFiled: October 21, 1994Date of Patent: September 2, 1997Assignee: E. Khashoggi IndustriesInventors: Per Just Andersen, Simon K. Hodson
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Patent number: 5663216Abstract: In order that a substantially biologically degradable polymer is prevented from at least partially losing its biological degradability when reinforced by additives such as fibers and the like, it is proposed that natural fibers such as, in particular, sisal or ramie fibers, be used.Type: GrantFiled: January 26, 1996Date of Patent: September 2, 1997Assignee: Bio-Tec Biologische Naturverpackungen GmbHInventor: Ivan Tomka
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Patent number: 5635550Abstract: The invention relates to an alloy composition possessing improved properties of mechanical resistance. The composition contains a starch, which is preferably plasticized, and a polymer which acts as coupling agent which is chosen from the group consisting of polyolefins modified by chemical functional groups which are active toward the hydroxyl functional groups of starch. Generally, the composition also contains a thermoplastic polymer. The invention also relates to the process for preparing this composition and the use of these compositions for the manufacture of films intended for the paper market and for packages made from biodegradable plastic.Type: GrantFiled: August 10, 1994Date of Patent: June 3, 1997Assignee: Solvay (Societe Anonyme)Inventors: Claude Dehennau, Thierry Depireux
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Patent number: 5609817Abstract: Moisture-shrinkable films can be extrusion blown from flour-poly(methyl acrylate) graft copolymers. The films shrink when exposed at room temperature to relative humidities approaching 100%. The films have potential application in shrink-wrapping irregularly shaped articles without application of heat. Easy removal of the films by water washing is another feature suitable for this use. This invention allows the use of unmodified cereal flour in lieu of gelatinized starch as the substrate for graft polymerization. This substitution greatly simplifies the preparation and isolation of the graft copolymers and reduces the expense of the process by lowering raw material costs.Type: GrantFiled: June 6, 1995Date of Patent: March 11, 1997Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Damodar R. Patil, George F. Fanta
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Patent number: 5574076Abstract: Hot melt adhesive compositions are prepared from a water sensitive or biodegradeable thermoplastic adhesive polymer using sucrose benzoate as a tackifier. More particularly, hot melt adhesive compositions are prepared from 10 to 90% by weight of a biodegradable or water sensitive thermoplastic polymer, 5 to 80% by weight sucrose benzoate, 0 to 80% by weight plasticizing diluent, 0 to 50% by weight wax and 0 to 3% by weight antioxidant.Type: GrantFiled: May 3, 1995Date of Patent: November 12, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Matthew L. Sharak, Charles W. Paul
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Patent number: 5565503Abstract: The present invention is directed to melt blown polyolefin film which is produced cheaply by melt blowing polyolefin resins which contain 25 to 60 wt % fillers selected from the fillers including an inorganic carbonate, synthetic carbonates, nepheline syenite, talc, magnesium hydroxide, aluminum trihydrate, diatomaceous earth, mica, natural or synthetic silicas and calcined clays or mixtures thereof, having a particle size less than 150 mesh.A further aspect of the present invention is directed to polyolefin resins, especially polyethylene, which are chemically degradable by the incorporation of the combination of the above group of fillers and a metal carboxylate. The metal carboxylates of the present invention are inclusive of a large number of metals, such as cerium, cobalt, iron, and magnesium.Type: GrantFiled: January 18, 1995Date of Patent: October 15, 1996Assignee: EPI Environmental Products Inc.Inventors: Rodrigo A. Garcia, Joseph G. Gho
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Patent number: 5549048Abstract: A shot-gun cartridge case is disclosed which is made by extrusion or equivalent pressure forming of high density polyolefin-based composition containing biodegradable starch, a fatty acid ester to initiate peroxide attack on the double bonds of the polyolefin and an anti-oxidant stabilizing compound. The composition is stable to biological and chemical degradation until the cartridge is fixed, upon which fixing, the anti-oxidant stabilizing compound is partially destroyed or dispersed so that degradation of said composition takes place.Type: GrantFiled: October 18, 1993Date of Patent: August 27, 1996Assignee: The Kent Cartridge Manufacturing Company LimitedInventors: Arthur H. Godfrey-Phillips, Graham Chapman
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Patent number: 5545485Abstract: A biodegradable resin molded article molded from a kneaded material obtained by kneading, melting or mixing a biodegradable resin raw material and at least one of a biodegradable additive and an additive made of a substance existing in the nature, an injection molded article of a biodegradable resin containing a biodegradable resin and an anti-biotic substance, a molded article of a resin composition including a polymer material having an ester bond in the polymer main chain thereof and an alkali or acid component in an amount effective for neutralizing an acidic or alkaline component contained in the polymer material, and a resin molded article having a layer of a biodegradable resin, and a layer of a photolytic resin covering the resin layer and containing an antibiotic.Type: GrantFiled: May 17, 1995Date of Patent: August 13, 1996Assignee: Fujitsu LimitedInventors: Takafumi Hashitani, Shozo Fujita, Makoto Iijima, Koji Asano
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Patent number: 5532298Abstract: A degradable agricultural ground cover which is composed of high density polyethylene polymer fiber and cellulose pulp which is 100% photo and biodegradable for use in weed control and moisture retention in soil. The unique agricultural mat or cover lasts 8-12 weeks before serious photo and biodegradability occurs, while allowing crop plants sufficient time to mature and produce. The sheet totally disappears with plowing and tilling, becoming a soil extender until complete degradation occurs.Type: GrantFiled: February 10, 1995Date of Patent: July 2, 1996Assignee: International PaperInventors: Stephen H. Monroe, James A. Goettmann, Gerald A. Funk
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Patent number: 5523331Abstract: A rubber composition or a rubber composite which is biodegradable in soil and is used to hold pot soil to the roots of plants to facilitate transplanting, said rubber composition containing a natural or synthetic rubber component and a water-soluble additive which does not bind to the rubber component and thus can elute into the soil.Type: GrantFiled: October 19, 1993Date of Patent: June 4, 1996Assignee: Asahi Co., Ltd.Inventor: Shoji Ezoe
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Patent number: 5521233Abstract: A biodegradable air drying screen printing ink. The ink includes a base made of water and a colloidal gum, preferably sodium alginate. A naturally-occurring binder is added to the base, preferably natural latex. The ink also includes one or more pigments made from natural ingredients, preferably plants or insects.Type: GrantFiled: February 9, 1995Date of Patent: May 28, 1996Inventor: Shari Shifrin
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Patent number: 5516815Abstract: A starch fiber produced by a spinning process and comprising:A A first amount of 1 to 100 parts of a starch melt-spinnable composition comprising1. a second amount of 56 to 96 parts of at least one modified and/or unmodified starch,2. a third amount of 4 to 40 parts of at least one destructuring agent,3. a fourth amount of 0 to 4 parts of at least one additive, selected from urea, urea derivatives, emulsifiers, lubricants, and proteins and their alkali salts,components 1, 2 and 3 totaling 100 parts; andB a fifth amount of 99 to 0 parts of at least one melt-spinnable polymer,ingredients A and B totaling 100 parts.In addition, there may also be included 0 to 20 parts of conventional additives for melt spinning compositions.The invention further relates to a process for the production of these starch fibers from this melt spinning composition, and to uses for fibers which, by modification with the starch melt-spinnable composition, have special properties.Type: GrantFiled: February 17, 1995Date of Patent: May 14, 1996Assignee: EMS-Inventa AGInventors: Friedrich Buehler, Viktor Baron, Eduard Schmid, Peter Meier, Hans-Joachim Schultze
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Patent number: 5500465Abstract: Compatibilized blends of a biodegradable hydrophobic polyester, unmodified starch or other similar polysaccharide containing less than 1% water by weight, other biodegradable polymers that may be hydrophobic, plasticizer, and other additives. The blends are produced in the absence of water. The preferred polyester polymer is poly(.epsilon.-caprolactone) and the preferred starch is from corn. A small amount of a unique stretching agent is incorporated to provide high elongations at break, especially in film forming compositions containing a significant amount of starch. The starch is a discontinuous phase that may be completely or partially plasticized and the polyester polymer is the continuous phase. The preferred polymers have unique film forming properties and are resistant to water and moisture.Type: GrantFiled: March 10, 1994Date of Patent: March 19, 1996Assignee: Board of Trustees operating Michigan State UniversityInventors: Mohan Krishnan, Ramani Narayan
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Patent number: 5462983Abstract: Biodegradable moldable products and films prepared from a compatible blend containing a biodegradable, hydrophobic, starch ester and a biodegradable polyester, and optionally a biodegradable and miscible plasticizer and/or a compatible filler.Type: GrantFiled: July 27, 1993Date of Patent: October 31, 1995Assignee: Evercorn, Inc.Inventors: Steven Bloembergen, Ramani Narayan
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Patent number: 5461094Abstract: The present invention relates to a biodegradable film prepared by chemical bonding of starch and polyethylene chains using polyethylene, which is polyolefin having the most widest general application, coupling agent such as maleic anhydride, methacrylic anhydride or maleimide which bonds with starch and polyethylene, and acid catalytic comonomer like acrylic acid and/or methacrylic acid and to a process for preparing thereof.The present invention was accomplished varying coupling agent such as maleic anhydride, methacrylic anhydride or maleimide at an amount of 0.01-10 weight %, acid catalytic comonomer such as acrylic acid and/or methacrylic acid at an amount of 0.01-10 weight % and radical initiator at an amount of 0.01 1.0 weight % based on the amount of polyethylene, and the reactive extrusion was appelied to lower the production cost by process simplification.There was no difference in tensile strength and tensile elongation of the prepared biodegradable films comprising up to 20 wt.Type: GrantFiled: November 23, 1993Date of Patent: October 24, 1995Assignee: Yukong LimitedInventors: Yong-deuk Yoo, Yong-wook Kim, Won-yung Cho
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Patent number: 5461093Abstract: In the present invention, the lowering of physical properties is minimized by bonding matrix resin and starch chemically using a coupling agent in the presence of an organic acid catalyst, at the same time lowering of the production cost is achieved by simplyfing the process. In the prior arts, the problems associated with low physical properties caused by starch incorporation were approached only in terms of enhanced physical interacting strength between matrix resin and starch.The purposes of the present invention are to provide a biodegradable polyethylene composition chemically bonded with starch comprising 100 parts by weight of matrix resin, 5-400 parts by weight of biodegradable incorporating material, 0.01-10 parts by weight of coupling agent, 0.01-1.0 parts by weight of radical initiator, 0.01-5 parts by weight of Lewis acid catalyst, 0.01-10 parts by weight of autoxidizing agent and 0.01-10 parts by weight of plasticizer and to provide a process for preparing thereof.Type: GrantFiled: November 23, 1993Date of Patent: October 24, 1995Assignee: Yukong LimitedInventors: Yong-deuk Yoo, Yong-wook Kim, Won-yung Cho
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Patent number: 5457144Abstract: This invention provides hydrolytically labile polyamide compositions and articles containing an ester derived moiety in the polymer backbone which will degrade after exposure to water over long periods of time.Type: GrantFiled: February 2, 1994Date of Patent: October 10, 1995Assignee: Rohm and Haas CompanyInventors: Norman L. Holy, Newman M. Bortnick
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Patent number: 5449708Abstract: A method for continuous preparation of a starch-based biodegradable polymer. A homogeneous mixture of starch, an ethylene acrylic acid co-polymer, and a salt of stearic acid are premixed before addition of an aqueous lubricant material. An increase in temperature gelatinizes the starch and melts the co-polymer. Excess moisture is removed under reduced pressure and a plastic material is extruded.Type: GrantFiled: June 25, 1993Date of Patent: September 12, 1995Inventor: David C. Schiltz
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Patent number: 5444107Abstract: A degradable polymer composition essentially consisting of a mixture of a thermoplastic polymer composition primarily comprising polylactic acid or lactic acid-hydroxycarboxylic acid copolymer and one or more substance selected from starch and modified starch, and is a degradable polymer which does not cause problems such as environmental pollution and can be used for films, filaments and packaging materials, food packaging materials in particular.Type: GrantFiled: July 23, 1992Date of Patent: August 22, 1995Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masanobu Ajioka, Katashi Enomoto, Akihiro Yamaguchi, Hosei Shinoda
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Patent number: 5416133Abstract: The present invention is directed to melt blown polyolefin film which is produced cheaply by melt blowing polyolefin resins which contain 25 to 60 wt% fillers selected from the fillers including an inorganic carbonate, synthetic carbonates, nepheline syenite, talc, magnesium hydroxide, aluminum trihydrate, diatomaceous earth, mica, natural or synthetic silicas and calcined clays or mixtures thereof, having a particle size less than 150 mesh.A further aspect of the present invention is directed to polyolefin resins, especially polyethylene, which are chemically degradable by the incorporation of the combination of the above group of fillers and a metal carboxylate. The metal carboxylates of the present invention are inclusive of a large number of metals, such as cerium, cobalt, iron, and magnesium.Type: GrantFiled: August 10, 1993Date of Patent: May 16, 1995Assignee: Gaia Research Limited PartnershipInventors: Rodrigo A. Garcia, Joseph G. Gho
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Patent number: 5393804Abstract: There is provided a biodegradable composition as obtained from a melt comprising converted starch, a plasticizer and at least one member selected from alkenol homopolymers and/or alkenol copolymers which are combined under conditions sufficient to ensure uniform melt formation, in which the at least one member is present in the composition at a concentration of from 10 to 200 parts per 100 parts of dry converted starch.The invention further relates to methods of making the composition, and to articles made from said composition.Type: GrantFiled: June 10, 1993Date of Patent: February 28, 1995Assignee: Parke, Davis & CompanyInventors: Eric George, Eddie Park, Paul A. Altieri, Charles W. Paul
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Patent number: 5387623Abstract: A method and composition of packaging an adhesive composition, especially a thermoplastic or thermosetting hot melt adhesive. The method comprises the steps of providing one substantially uniform separate portion of the adhesive composition; sufficiently solidifying said portion for packaging; and substantially completely surrounding said sufficiently solidified portion with a biodegradable polymeric packaging material. The packaging material being meltable together with the adhesive composition and blendable into said molten adhesive composition, the kind and amount of said biodegradable packaging material being chosen so as not to disadvantageously affect the properties of the adhesive composition when blended into the molten adhesive and applied to a substrate.Type: GrantFiled: June 6, 1992Date of Patent: February 7, 1995Assignee: H. B. Fuller CompanyInventors: Lisa L. Ryan, Alain Rouyer, Emmanuelle Pariente, Peter Yeboa-Kodie
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Patent number: 5378738Abstract: A biodegradable plastic added at an amount of a hydrophilic property imparting-substance providing wettability such that the contact angle of plastic surface to water is 70.degree. or less whereby the decomposability thereof with Basidiomycetes, the cultured products thereof and/or the processed products thereof is improved. A method for decomposing plastic under the conditions with limitation to nitrogen and/or carbon in decomposing such biodegradable plastic. In accordance with the present invention, the plastic which has conventionally been decomposed with difficulty can be decomposed efficiently.Type: GrantFiled: June 25, 1993Date of Patent: January 3, 1995Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Tetsuya Deguchi, Tomoaki Nishida, Yoshimasa Takahara