Abstract: The invention provides a composition having shear-gelling and shear-thickening properties based on a amphiphilic polymer combined with hydrophilic particles and polyethyleneoxide.

Abstract: A method of controlling the loss of a drilling fluid from a well bore into a subterranean formation in which one illustrative embodiment includes: drilling the well bore with an aqueous based drilling fluid that includes an aqueous phase and a shale hydration inhibitor that is a polyether amine compound, and circulating into the well bore a fluid pill including a dialdehyde crosslinking agent. The dialdehyde crosslinking agent reacts with the polyether amine compound and forms a polymeric material.

Abstract: A copolymer based on olefinic sulphonic acids as monomer component a) and an organosilicone-containing compound as reactive component b) is proposed, for which in particular 2-acrylamido-2-methylpropanesulphonic acid (AMPS®) is suitable as component a) and vinyltrimethoxysilane, vinyltriethoxysilane and trichlorosilane as component b). This copolymer, which may have a molecular weight of from 5,000 to 5,000,000 g/mol, may also comprise further reaction components c) and d) in addition to the two main components for which further reaction components (meth)acrylamides or vinyl ethers are suitable. These copolymers, which are obtainable in particular by precipitation or gel polymerizations, are used in particular in applications in construction chemistry and here especially as water retention agents and fluid loss additives in drilling fluids and for well cementing.

Abstract: The present invention includes methods and compositions that include a latex, and at least one of a natural pozzolan or cement kiln dust. An embodiment includes a method comprising: placing a latex composition in a subterranean formation, wherein the latex composition comprises: latex, a component selected from the group consisting of a natural pozzolan, cement kiln dust, and a combination thereof, and water; and allowing the latex composition to set. Another embodiment of the present invention includes a latex composition comprising: latex, a component selected from the group consisting of a natural pozzolan, cement kiln dust, and a combination thereof.

Abstract: Sealant compositions and methods of using the same to isolate a subterranean zone are provided. The compositions include partially polymerized furfuryl alcohol/aldehyde, a coupling agent, a diluent, a curing agent, a ductility imparting agent, and a filler for increasing the compressive strengths of the sealant compositions. Methods of isolating a subterranean zone include pumping the foregoing sealant composition into a well bore down through a conduit and up through an annulus disposed between the conduit and the walls of the well bore. The sealant composition exhibits a sufficiently long cure time such that it does not harden until it reaches the annulus. Thus, the sealant composition effectively attaches the conduit to the walls of the well bore. The sealant composition is substantially resistant to degradation by waste chemicals disposed of in the well bore.

Abstract: Methods are provided comprising providing a sealant composition comprising an aqueous fluid, a diutan composition, at least one gel system, and a leak off prevention material; introducing the sealant composition into a well bore penetrating the subterranean formation; and allowing the sealant composition to form a seal.

Abstract: A wellbore sealant composition including a modified latex and a cross-linking agent, wherein the modified latex has undergone a dry particulate state, the modified latex is present in an amount of from 5% to 50% by total weight of the composition, and the modified latex is prepared by removing water from an emulsion polymerized latex system.

Abstract: The invention discloses a cement slurry composition for cementing a well comprising: an hydraulic cement, water and a combination made of a cellulosic polymer and an acrylamido-methyl-propane sulfonate co- or ter-polymer, wherein the density of said cement slurry is above 1700 kg/m3.

Abstract: It is proposed a new fluid loss control agent useful for the cementation of oil or gas wells. This fluid loss control agent consists of a mixture of a styrene-butadiene latex and a high molecular weight water-soluble polymer such as a copolymer AMPS-Am. The addition of the water-soluble polymer allows drastic reduction of the quantity of latex required to achieve fluid loss control performance and even gas migration control.

Abstract: A composition for wellbore consolidation, comprising fibres having a core formed from a material that is electrically and/or magnetically susceptible, and a polymeric coating, characterised in that when the composition is placed in a wellbore in a zone to be consolidated and an electric current or magnetic field is applied, the fibres bond together by melting or setting of the polymeric coating.

Abstract: Exemplary embodiments of the cement compositions comprise water, a cement, and a fluid loss control additive, the fluid loss control additive comprising a graft copolymer. The graft copolymer comprises a backbone and at least four grafted monomers selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid, vinylphosphonic acid, diallyldimethylammonium chloride, and salts thereof. The backbone of the graft copolymer comprises a humic acid salt. Methods of cementing using exemplary embodiments of the cement compositions are also provided.

Abstract: A well cement composition for plugging a bore at the location for initiating sidetracking to bore a lateral well is formulated as a slurry of hydraulic cement that contains at least two, but preferably all three of the following additives: (1) a source of silicon dioxide, (2) fracturing proppants and (3) an expansion compound selected from the group consisting of 1%-5% crystalline silica and 60%-99% MgO or CaO, and their mixtures.

Abstract: A cement composition for cementing an oil or gas well includes Portland cement, water and a sulfur component. The cement composition may be used to cement a well bore by creating a cement slurry including the sulfur component, pumping the slurry into the well bore to a selected location and allowing it to solidify.

Abstract: A method of servicing a wellbore comprising preparing a cement slurry by premixing at least one latex, at least one stabilizer, and optionally water to form a homogeneous solution, further mixing the homogeneous solution with an ionic compound, cement, and optionally additional water to form the slurry, and placing the slurry in the wellbore. A method of stabilizing latex in cement slurry containing saltwater, comprising premixing the latex with a stabilizer until a homogenous solution forms prior to contacting the latex with the saltwater. A cement slurry comprising a latex, a stabilizer, a cement, an ionic compound, and water wherein the latex and stabilizer are contacted prior to contact of the latex with the ionic compound.

Abstract: Exemplary embodiments of the cement compositions comprise water, a cement, and a fluid loss control additive, the fluid loss control additive comprising a graft copolymer. The graft copolymer comprises a backbone and at least four grafted monomers selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid, vinylphosphonic acid, diallyldimethylammonium chloride, and salts thereof. The backbone of the graft copolymer comprises a humic acid salt. Methods of cementing using exemplary embodiments of the cement compositions are also provided.

Abstract: The invention discloses a cement slurry composition for cementing a well comprising: an hydraulic cement, water and a combination made of a hydroxyethyl cellulose and an acrylamido-methyl-propane sulfonate-acrylamide copolymer.

Abstract: Water problems in the production of oil or gas from subterranean formations is addressed by providing a method of restricting passage of a fluid from a first location to a second location in a subterranean formation by injecting into the formation a formulation comprising a first material, for example a dialdehyde, arranged to cross-link a second polymeric material, for example a polyvinyl alcohol, thereby to form a polymeric material of high viscosity which may block the passage between the first and second locations.

Abstract: The present invention is directed to an aqueous superabsorbent polymer paste comprising from about 1 to about 5 wt % of superabsorbent particles and from about 95 to about 99 wt % of an aqueous water-soluble solution having from about 0.5 to about 5%, preferably from about 1 to about 3% solid level. The present invention is also directed to a coated substrate comprising a substrate material and an aqueous superabsorbent polymer paste comprising a blend of i) from about 1 to about 5 wt % of superabsorbent particles and ii) from about 95 to about 99 wt % of an aqueous water-soluble solution. The present invention is also directed to a method for reducing the loss of circulation fluids into flow passages of a subterranean formation during well drilling, completion or work over operations, by using the aqueous superabsorbent polymer paste of the present invention.

Abstract: A two-component reaction resin includes a resin component (A), which contains, as curable constituent (a), at least one free radical-curable, ethylenically unsaturated compound, an agent (b) for adjusting the reactivity and the gel time and at least one comonomer (c) and a curing component (B), which is disposed separate therefrom to inhibit any reaction and is a curing agent for the resin of the resin component (A) and which, as agent (b) for adjusting the reactivity and the gel time, contains a pyrocatechol derivative of the general Formula (I):

Abstract: Exemplary embodiments of the cement compositions comprise water, a cement, and a fluid loss control additive, the fluid loss control additive comprising a graft copolymer. The graft copolymer comprises a backbone and at least four grafted monomers selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid, vinylphosphonic acid, diallyldimethylammonium chloride, and salts thereof. The backbone of the graft copolymer comprises a humic acid salt. Methods of cementing using exemplary embodiments of the cement compositions are also provided.

Abstract: Methods for stabilizing portions of a subterranean formation and controlling the production of water from those subterranean formations. In one embodiment, the methods of the present invention comprise: providing a consolidating agent; introducing the consolidating agent into an unconsolidated portion of a subterranean formation using a fluid diversion tool; allowing the consolidating agent to at least partially consolidate the unconsolidated portion of the subterranean formation; providing a relative permeability modifier; introducing the relative permeability modifier into the subterranean formation using a fluid diversion tool; and allowing the relative permeability modifier to modify the relative permeability of at least a portion of the subterranean formation.

Abstract: A gas migration prevention additive for use in cementing wells comprising a solid crosslinked poly(vinyl)alcohol microgel.

Abstract: A delayed gelling system useful in conformance control in the production of petroleum from subterranean formations is disclosed. The gelling system comprises an acidic aqueous solution of acid-soluble or cationic polyacrylamide, an at least partially neutralized acid aluminum salt, an activator comprising a hydroxyl donor, and an optional gel modifier. The gelling system may be pumped into formations with excessive water production and thermally activated in the formation at downhole conditions to form a co-gel of polyacrylamide interspersed in an inorganic gel network to reduce water production.

Abstract: Disclosed is a method and material for forming a fluid barrier in the material surrounding a wellbore. The method involves temporarily opening a fracture extending from the wellbore and then depositing particulates in the fracture which will swell when exposed to the fluid. The particles are deposited in the fracture without causing appreciable swelling thereof and then, after the fracture closes, the particles are allowed to swell when contacted with the fluid to form a fluid barrier.

Abstract: Sulfonated graft copolymer obtained by radical graft copolymerization of one or more synthetic monomers in the presence of hydroxyl-containing naturally derived materials. The graft copolymer includes 0.1 to 100 wt %, based on weight of the total synthetic monomers, of at least one monoethylenically unsaturated monomer having a sulfonic acid group, monoethylenically unsaturated sulfuric acid ester or salt thereof, with the monomer and hydroxyl-containing naturally derived materials present in a weight ratio of 5:95 to 95:5.

Abstract: A method of treating an earth formation that includes injecting at least one lipophilic monomer into the earthen formation; wherein the at least one lipophilic monomer is selected from epoxide-functionalized derivative of soybean oil linseed oil, rapeseed oil, cashew nut shell oil; perilla oil, tung oil, oiticia oil, safflower oil, poppy oil, hemp oil, cottonseed oil, sunflower oil, high-oleic triglycerides, triglycerides of euphorbia plants, peanut oil, olive oil, olive kernel oil, almond oil, kapok oil, hazelnut oil, apricot kernel oil, beechnut oil, lupine oil, maize oil, sesame oil, grapeseed oil, lallemantia oil, castor oil, herring oil, sardine oil, menhaden oil, whale oil, and tall oil, injecting at least one crosslinking agent into the earthen formation; wherein the at least one crosslinking agent comprises at least one primary amine; and allowing the lipophilic monomer and the crosslinking agent to react in the earth formation is disclosed.

Abstract: The present invention is a composition for forming seals. The composition includes a base material and a hydrogel. The base materials is preferably an elastomer or a thermoplastic. Seals formed with the composition are particularly suited for use in a wellbore environment. The inclusion of hydrogel in the seals allows the seals to be manipulated or altered through certain environmental factors. For instance, temperature, oil/water ratio, pH and the electronic field may all be used to alter the characteristics of the hydrogel. In this way, the seal may be caused to swell in response to a specific stimulus, thereby preventing or sealing a leak without requiring additional work or input from the operator.

Abstract: A liner is the product of reaction of (a) a hydrophilic prepolymer bearing isocyanate groups; and (b) a water-borne polymer dispersion, the polymer bearing groups that are reactive to isocyanate groups; wherein the dispersion has a sufficiently high solids content, and the polymer has a sufficiently high modulus and glass transition or crystalline melting temperature, that the product of reaction exhibits a 24-hour Tensile Strength of at least about 2.5 MPa.

Abstract: Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer present on or in the substrate as an amount sufficient to improve the dust suppression of the particle above that which would occur if the thermoplastic elastomer was absent. Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer, wherein the particle has a compressive strength retention of greater than about 50% as measured by a UCS test and a turbidity of about 10 to 200 NTU after a one hour ball mill test.

Abstract: The invention provides a method of well treatment comprising introducing into the matrix surrounding a hydrocarbon well bore hole an emulsion the discontinuous phase of which comprises a non-polymerizable, water or oil miscible liquid carrier, a polymerizable monomer and a thermally activated polymerization initiator, said monomer constituting from 2 to 40% wt. of said discontinuous phase.

Abstract: A composition which is applied to substrate surfaces to form a membrane to provide structural reinforcement thereto and prevent the release of gases and moisture from the substrate. The composition consists of polymer resin binders and gypsum. Further provided is a method for dividing the composition into two separate components in order to preclude premature setting up of the composition ingredients until applied to the substrate. The present invention is particularly useful for creating membranes on the exposed surfaces of newly excavated rocks in subterranean mine systems. The composition may also be used in the construction industry as coatings for sandwich panels, molding, duct-work, piping and cladding systems. It also is useful in traffic paint applications and other transportation industry safety coatings. In addition, the invention may be used in the manufacture of fiber reinforced composite structures and composite construction components.

Abstract: Coated particle substrates having a coating of resin and/or water soluble polymers and soluble, fibrous material are provided for use in subterranean formations. The coated particle substrate particles are typically proppants used to prop open subterranean hydrocarbon formations during recovery processes, such as after a hydraulic fracture, and provide both improved settling characteristics and improved hydrocarbon flow characteristics due to the conductive channels formed by the soluble fibers downhole. Methods of making the coated particles are also described.

Abstract: Storable water-silica suspensions and methods of cementing well bores are provided. The storable water-silica suspensions are basically comprised of water, silica and an effective amount of a suspending agent selected from the group consisting of colloidal materials, clays and gel forming polymers.

Abstract: A two-component mortar composition is described with a curable resin component containing at least one free radical-polymerizable resin, fillers, reactive diluents, solvents, accelerators and/or further conventional mortar components and, separated therefrom to inhibit reaction, a curing agent component for chemically fastening anchoring means in boreholes, characterized in that the resin component, in order to improve the adhesion to different mineral substrates of the borehole, contains a reactive diluent mixture of at least one hydroxyalkyl (meth)acrylate and at least one acetoacetoxyalkyl (meth)acrylate. Furthermore, the use of the two-component mortar composition for chemically fastening anchoring means in boreholes of different mineral substrates is also described.

Abstract: A process is described for reducing the production of water in oil wells which comprises the injection into the formation around the well of an aqueous solution of one or more polymers selected from those having general formula (I), wherein: n ranges from 0.70 to 0.98; m ranges from 0.30 to 0.02; n+m=1; X1 and X2, the same or different, are selected from H and CH3; R1, R2, R3, the same or different, are selected from C1–C10 monofunctional hydrocarbyl groups; and x ranges from 2 to 5.

Abstract: The present invention is directed to an aqueous superabsorbent polymer paste comprising from about 1 to about 5 wt % of superabsorbent particles and from about 95 to about 99 wt % of an aqueous water-soluble solution having from about 0.5 to about 5%, preferably from about 1 to about 3% solid level. The present invention is also directed to a coated substrate comprising a substrate material and an aqueous superabsorbent polymer paste comprising a blend of i) from about 1 to about 5 wt % of superabsorbent particles and ii) from about 95 to about 99 wt % of an aqueous water-soluble solution. The present invention is also directed to a method for reducing the loss of circulation fluids into flow passages of a subterranean formation during well drilling, completion or work over operations, by using the aqueous superabsorbent polymer paste of the present invention.

Abstract: A method for reducing or completely eliminating water influx in an oil or natural gas borehole includes introducing in the borehole an aqueous solution of a copolymer comprising: A) 40–98 wt. % of structural units of formula (I), wherein: R1 is hydrogen or methyl; R2 represents C2–C10 alkylene; and Me+ represents an ammonium metal ion and an alkali metal ion; B) 0.1 to 58 wt. % of structural units of formula (II); C) 0.1 to 10 wt. % of structural units of formula (III), wherein: R3 and R4 independently of each other represent hydrogen, methyl or ethyl, or R3 and R4 represent together a propylene group, which, with inclusion of a radical (A), form a pyrrolidon radical or, with inclusion of a pentamethylene group, forms a caprolactam radical; D) 0.10 to 10 wt % of structural units of formula (IV). The method also includes introducing in the ground or deposit, simultaneously with the copolymer or subsequently, an agent for crosslinking the copolymer.

Abstract: A composition including two components is provided. When the two components are admixed in the method of the invention a polymer-modified gypsum composition is provided. The admixture exhibits a useful balance of setting time and stability.

Abstract: A method and cementing composition for sealing a subterranean zone penetrated by a well bore, wherein the cementing composition comprises a mixture of cementitious material, acrylonitrile butadiene styrene (ABS), and sufficient water to form a slurry.

Abstract: The present invention provides a method and treatment fluid for blocking the permeability of an elevated-temperature zone in a reservoir of a subterranean formation penetrated by a wellbore, the method comprising the steps of: a) selecting the zone to be treated, wherein the upper limit of the temperature range of the zone is equal to or greater than 190° F. (88° C.); b) forming a well treatment fluid comprising: water; a water-soluble polymer comprising polymerized vinyl amine units; and an organic compound capable of crosslinking with the vinyl amine units of the water-soluble polymer; c) selecting the water-soluble polymer and the organic compound of the well treatment fluid such that the gel time of the well treatment fluid is at least 2 hours when measured at the upper limit of the temperature range of the zone; and d) injecting the well treatment fluid through the wellbore and into the zone.

Abstract: A method and composition is provided for a relative permeability modifier for use with aqueous well treatment fluids that comprises a hydrophobically modified water soluble polymer or a hydrophilically modified water soluble polymer.

Abstract: Methods of cementing subterranean zones penetrated by well bores and well cement compositions. A well cement composition of the invention basically comprises a hydraulic cement, water in an amount sufficient to form a pumpable slurry and a fluid loss control polymer additive comprising 77.9 weight % of the calcium salt of 2-acrylamido-2-methyl propane sulfonic acid, 8 weight % of the calcium salt of maleic acid, 11 weight % of N-vinyl caprolactam, 3 weight % of 4-hydroxybutyl vinyl ether and 0.1 weight % of methylene bisacrylamide.

Abstract: A water-soluble resin composition comprising a water-soluble resin and a colorant, which copolymer has a weight average molecular weight of at least 8,000 and is prepared by polymerizing an ethylenically unsaturated carboxylic acid monomer and a monomer copolymerizable therewith in the presence of an alcoholic hydroxyl group-containing water-soluble high polymer or a copolymerizable surface active agent to give a copolymer having an acid value in the range of 5 to 120 and then neutralizing the thus-obtained copolymer with a basic, exhibits a reduced viscosity change when it is stored for a long period, and is useful as an aqueous ink capable of giving an image having good dot reproducibility and good abrasion resistance.

Abstract: A liner is the product of reaction of (a) a hydrophilic prepolymer bearing isocyanate groups; and (b) a water-borne polymer dispersion, the polymer bearing groups that are reactive to isocyanate groups; wherein the dispersion has a sufficiently high solids content, and the polymer has a sufficiently high modulus and glass transition or crystalline melting temperature, that the product of reaction exhibits a 24-hour Tensile Strength of at least about 2.5 MPa.

Abstract: A process is described for reducing the production of water in oil wells, with temperatures of up to (90° C.), which comprises the injection in the formation around the well of an aqueous solution of one or more polymers selected from those having general formula (I) wherein: n ranges from (0.40) to (0.70), preferably from (0.5) to (0.65); m ranges from (0.15) to (0.65), preferably from (0.3) to (0.5); p ranges from (0.02) to (0.20), preferably from (0.05) to (0.

Abstract: A composition comprising expandable cross linked polymeric microparticles having an unexpanded volume average particle size diameter of from about 0.05 to about 10 microns and a cross linking agent content of from about 9,000 to about 200,000 ppm of labile cross linkers and from 0 to about 300 ppm of non-labile cross linkers. The composition is used for modifying the permeability of subterranean formations and increasing the mobilization and/or recovery rate of hydrocarbon fluids present in the formations.

Abstract: For well plug treatment to plug an abandoned well, a well plug additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and filter aid, and optionally, a reinforcing material preferably of fibers and/or comminuted plant materials. The method of forming a well plug fluid includes contacting the additive with water or an aqueous solution, with a method of plugging the well further including the step of injecting the fluid into the wellbore.

Abstract: A method and composition is provided for sealing a subterranean zone penetrated by a well bore and restoring lost circulation, wherein the composition basically comprises a mixture of latex, melamine-formaldehyde resin, and a catalyst.

Abstract: A cement composition is basically comprised of a hydraulic cement, water in an amount sufficient to form a pumpable slurry and a fluid loss control polymer additive comprised of 69 weight % of the calcium salt of 2-acrylamido-2-methyl propane sulfonic acid, 14 weight % of the calcium salt of maleic acid, 14 weight % of N-vinyl caprolactam and 3 weight % of 4-hydroxybutyl vinyl ether.

Abstract: Methods and compositions for cementing subterranean zones penetrated by well bores are provided. The methods are basically comprised of the steps of providing a cement composition which comprises a hydraulic cement, sufficient water to form a slurry and a dispersing agent comprising a tetrapolymer formed of methacrylic acid, methacrylate, methallyl sulfonic acid and ethoxylated acrylic acid. The cement composition is placed in the subterranean zone to be cemented and allowed to set into an impermeable solid mass therein.