Solar Energy Absorption Or Solar Reflection Composition Or Process Of Preparing Patents (Class 523/135)
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Patent number: 6838494Abstract: The present invention provides a light reflecting polymeric composition that includes at least one halogenated-flame-retardant-additive-free polymer having dispersed therein a pigment package including a combination of Sb2O3 and TiO2. The Sb2O3 and TiO2 preferably have an average particle size within the range of from about 0.05 ?m to about 1.0 ?m, and more preferably about 0.2 ?m. When used in combination, the Sb2O3 and TiO2 pigments synergistically interact together to provide a polymeric composition exhibiting a reflectivity that is substantially higher than can be obtained by the use of either of the pigments alone.Type: GrantFiled: December 30, 2002Date of Patent: January 4, 2005Assignee: Ferro CorporationInventors: Deenadayalu Chundury, Richard Abrams, Ronald M. Harris, Mir Ali, Theophilus G. McGee, II, Susan T. Schmidt
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Publication number: 20040238799Abstract: A polymer-chain-grafted carbon nanocapsule. The polymer-chain-grafted carbon nanocapsule includes a carbon nanocapsule and at least one kind of polymer chain grafted thereon, forming a polymer-chain-grafted carbon nanocapsule in which the carbon nanocapsule is the core thereof. The polymer-chain-grafted carbon nanocapsules have the following formula: F(−P)m, in which F is the carbon nanocapsule, P is the polymer chain, and m is the number of the polymer chain. By grafting high-purity carbon nanocapsules with polymer chains, the application thereof is expanded.Type: ApplicationFiled: December 22, 2003Publication date: December 2, 2004Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Gan-Lin Hwang, Abraham Joseph K
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Patent number: 6815010Abstract: A method of inhibiting the loss of solar reflectivity over time of an exterior elastomeric coating composition comprising an organic binder and at least one inorganic additive comprises: replacing at least a part of the at least one inorganic additive with a solid, particulate, organic polymer having a Tg greater than 70° C. An improved exterior elastomeric coating composition is also disclosed.Type: GrantFiled: May 1, 2001Date of Patent: November 9, 2004Assignee: Rohm and Naas CompanyInventors: William Henry Elfring, Donald Alfred Winey
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Patent number: 6787585Abstract: A coating material for interior walls and exterior facades has heat reflection and oleophobicity/hydrophobicity, properties. The material is either opaque to visible light and/or contains a material which provides opacity. It includes: a) at least one silane of the formula (I) XaRbSiR14−a−b (I) in which X is a hydrolyzable group, R is optionally substituted alkyl, alkenyl, aryl, alkylaryl or arylalkyl, R1 is an organic radical which is attached to the silicon via carbon and carries a reactive group, a is an integer from 1 to 3, and b is an integer from 0 to 2, or a (partial) condensate of this silane, b) at least one infrared-reflecting pigment whose particle size is situated primarily in the range from 1 to 50 &mgr;m, and c) a solvent and/or dispersion medium.Type: GrantFiled: September 6, 2001Date of Patent: September 7, 2004Assignee: Fraunhofer-Gesellschaft zur ForderungInventors: Klaus Rose, Matthias Heinrich, Karl-Heinz Haas, Michael Köhl
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Patent number: 6656981Abstract: The present invention provides a method for reducing dust deposits on polyolefin films. Further subjects of the invention are the use of a polyetheresteramide for reducing dust deposits on polyolefin films and coextruded multilayer polyolefin films containing a polyetheresteramide at least in one outer layer.Type: GrantFiled: August 27, 2001Date of Patent: December 2, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Nicola Lelli, Nadi Ergenc
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Patent number: 6587263Abstract: An method, and method of production thereof, which provides excellent performance, reduced cost, and reduced breakage due to reduced manual handling. The present invention comprises a substrate, a bond layer coating the substrate, a reflective layer coating the bond layer, and a radiative layer coating the reflective layer. Preferably, the radiative layer comprises SiO2, Si3N4 or SiOxNy, low absorbency of electromagnetic radiation having wavelengths of approximately 200 nm to approximately 2500 nm and high absorbency and emissivity electromagnetic radiation having wavelengths of approximately 2.5 &mgr;m to approximately 25 &mgr;m. Preferably, the bond layer comprises chromium, titanium, or titanium-tungsten and the substrate comprises aluminum, aluminum alloys, polyimide, carbon-filled polyimide, or carbon composite.Type: GrantFiled: March 31, 2000Date of Patent: July 1, 2003Assignee: Lockheed Martin CorporationInventors: Charles Dominic Iacovangelo, Yiqun Pan, Chang Wei, Mao Chen
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Publication number: 20020182422Abstract: Plasticized polyvinyl butyral sheet containing dispersed therein, an infrared-absorbing effective amount of at least one quaterrylenetetracarboxylic diimide infrared-absorbing additive of formula I in the specification. A glass laminate having visible light transmitting and infrared light absorbing properties contains such sheet sandwiched between glass layers.Type: ApplicationFiled: March 22, 2002Publication date: December 5, 2002Inventors: Paul D. Garrett, Arno Boehm, Howard D. Booth
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Patent number: 6441059Abstract: Composite material for the screening of radiation, comprising a polymer, an additive and the customary stabilizers and processing aids necessary for the particular polymer. The additive is preferably an interference pigment.Type: GrantFiled: June 20, 1995Date of Patent: August 27, 2002Assignees: Merck Patent Gesellschaft MIT Beschrankter Haftung, Hyplast N.V.Inventors: Manfred Kieser, Gerhard Edler, Tony Leon Filip Daponte, Patrick Corneel Mathilde Verschaeren
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Patent number: 6418661Abstract: A hydrotalcite compound which has the excellent ability to absorb infrared rays and has excellent light transmission when contained in an agricultural film; a process for producing the compound; and an infrared absorber and an agricultural film both containing the compound. The hydrotalcite compound is characterized by retaining as the interlayer anions at least one kind of anions selected among ions of silicon-, phosphorus-, and boron-containing polymeric oxyacids and another kind of anions.Type: GrantFiled: August 1, 2000Date of Patent: July 16, 2002Assignee: Kyowa Chemical Industry Co LtdInventors: Hideo Takahashi, Akira Okada
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Patent number: 6384104Abstract: A method for improving the storage stability of personal care formulations containing ultraviolet (UV) radiation-absorbing agents (sunscreen agents) is disclosed. Latex polymer particles containing a void, having a particle size from 50 to 1000 nanometers, and having at least 4% polymerized crosslinker monomer units in the shell portion of the particle are especially effective in maintaining storage stability and effectiveness of sunscreen formulations when added to personal care compositions containing at least one sunscreen agent.Type: GrantFiled: October 3, 2000Date of Patent: May 7, 2002Assignee: Rohm and Haas CompanyInventors: Ching-Jen Chang, Charles Elwood Jones, Barry Weinstein
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Patent number: 6340765Abstract: A photochromic compound having a high color-developing sensitivity, a large fading rate and good durability of photochromic property. A novel chromene compound is, for example, represented by the following formula, and in which, as a basic structure, a condensed ring having a particular divalent group bonded to carbon atoms at the fourth and fifth positions of a fluoreno group is spiro-bonded to the first position of an indene ring, a particular divalent group is bonded to carbon atoms at the fifth and sixth positions of a chromene ring to form a condensed ring, and particular substituents are bonded to a carbon atom at the second position of the chromene ring.Type: GrantFiled: May 18, 2000Date of Patent: January 22, 2002Assignee: Tokuyama CorporationInventors: Junji Momoda, Yuichiro Kawabata
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Patent number: 6296004Abstract: A sun shield capable of protecting persons or plants against the harmful effects of incident radiation and being formed from a substantially transparent flexible material (13) which at least substantially absorbs and/or reflects incident radiation in the ultraviolet and infrared frequency ranges and which may be repeatedly folded without becoming damaged. The supple, flexible and durable transparent material (13) may be mounted on a framework (14) to be attached to, for example, a child's car seat (11) or pushchair (26) or to serve as a parasol or canopy, or to protect plants from excessive ultraviolet or infrared radiation.Type: GrantFiled: September 24, 1999Date of Patent: October 2, 2001Inventor: Linda Carol Gordon
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Patent number: 6248817Abstract: An infrared absorber which comprises containing as an effective ingredient a hydroxide complex salt represented by the formula [Al2(Li(1−x).+M2+(x+y)(OH)(6+2y)]n(An−)(1+x).mH2O (wherein M2+ is a divalent metal, An− is an anion having a valence of n, and m, x and y are numbers respectively in the ranges of 0≦m<5, 0.01≦x≦0.5 and 0≦y≦0.5), which has a high ability to absorp infrared rays and a refractive index close to that of the resin so that it has a good dispersibility with the resins when incorporated in the resin and the shaped film therefrom is excellent in the heat insulation property and transparency so that it is suitable as an agricultural film.Type: GrantFiled: April 20, 1999Date of Patent: June 19, 2001Assignee: Fuji Chemical Industry Co., Ltd.Inventor: Kanemasa Takado
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Patent number: 6197853Abstract: A thermoplastic polycarbonate molding composition having improved resistance to gamma radiation-induced yellowing is disclosed. Particularly suitable for the manufacture of devices geared for medical applications, the composition contains an additive amount of a stabilizing compound conforming structurally to where R1 denotes a C1-30-alkyl group and R2 denotes an aryl radical.Type: GrantFiled: July 1, 1999Date of Patent: March 6, 2001Assignee: Bayer CorporationInventors: Daniel H. Bolton, Sivaram Krishnan, David M. Derikart, James B. Johnson
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Patent number: 6194484Abstract: The invention relates to a coating material comprising a binding agent with high transparency in the thermal infrared range; first, plate-shaped particles, which reflect in the wavelength range of thermal infrared, and/or first spherical particles which backscatter in the wavelength range of thermal infrared; and/or second spherical particles which, in the dry state, have and/or form a hollow space, and consist of a material which is transparent in the thermal infrared range; second particles which reflect and/or backscatter in the wavelength range of visible light from 0.35-0.7 &mgr;m, and are transparent in the wavelength range of thermal infrared, and/or polymer pigments which are transparent in the thermal infrared range and which, in the dry state, have and/or form a hollow space,; third spherical particles which are electrically conductive and hare a low absorption in the thermal infrared range; other admixtures known per se, that are usually used for coating.Type: GrantFiled: June 4, 1999Date of Patent: February 27, 2001Inventor: Gerd Hugo
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Patent number: 6184266Abstract: Shaped medical devices, e.g. stents, having improved mechanical properties and structural integrity are disclosed. The devices comprise shaped polymeric hydrogels which are both ionically and non-ionically crosslinked and which exhibit improved structural integrity after selective removal of the crosslinking ions. Process for making such devices are also disclosed wherein an ionically crosslinkable polymer is both ionically and non-ionically crosslinked to form a shaped medical device. When implanted in the body, selective in-vivo stripping of the crosslinking ions produces a softer, more flexible implant having improved structural integrity.Type: GrantFiled: February 2, 2000Date of Patent: February 6, 2001Assignee: Scimed Life Systems, Inc.Inventors: John M. Ronan, Samuel A. Thompson
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Patent number: 6171525Abstract: Disclosed is a process for the production of a photochromic object, composed of a polymer and containing at least one spirooxazin compound, having the following process steps: an acrylate monomer or a methacrylate monomer, respectively a mixture of a multiple thereof is utilized as the polymerizable monomer, the photochromic dyes as well as a polymerization initiator are mixed in the polymerizable monomer, the mixture yielded thereby is placed in a casting mold, polymerized and hardened. The present invention is distinguished by, in order to obtain a neutral gray, neutral brown or green photochromic tint of the polymerizable mixture, several photochromic dyes being added of which at least one is not a spirooxazin, and by the concentration of the spirooxazin compound(s) amounting to no more than 0.045 weight percent relative to the mass of the utilized monomer, and that of the polymerization initiator(s) amounting to more than 1 weight percent relative to the mass of the utilized monomer.Type: GrantFiled: January 12, 1998Date of Patent: January 9, 2001Assignee: Optische Werke G. RodenstockInventors: Erhard Effer, Manfred Melzig, Herbert Zinner, Herbert Schuster
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Patent number: 6158169Abstract: A method and apparatus for controlling light and temperature necessary for the optimum growth of vegetables and plants for backyard gardeners. This is achieved by using a photo-transforming membrane supported by a light-weight, luminescent, portable and easily-assembled without tools frame. The components of the apparatus can be efficiently and compactly packaged, suitable for mass distribution. The membrane has photo-transforming qualities which transform UV-light into a bandwith of light that promotes photosynthesis. This, in turn, enhances crop growth and increases internal ambient temperature.Type: GrantFiled: April 22, 1998Date of Patent: December 12, 2000Assignee: General Phosphorix LLCInventors: E. Tim Goldburt, Albert Sieignano, Matt Sandy, Peter von Gundlach
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Patent number: 6153665Abstract: A mechanically strong doped polymer sheeting--high-density polyethylene (HDPE) film--that provides excellent durability, high-maintenance and photo-transforming properties for covering hotbeds and greenhouses is comprised of: a light-transforming additive based on yttrium-europium oxysulfide; a light-stabilizing agent based on polyaminosuccinate; and a polymer resin used to form the high-density polyethylene 6-mil film. A preferred embodiment includes following composition and ratios: yttrium-europium oxysulfide content is 0.05-0.5% by weight; polyaminosuccinate content is 0.1-1% by weight; the ratio of yttrium-europium oxysulfide to polyaminosuccinate ranges from 0.5:1 to 1:2; and high-density polyethylene content is over 98.5% by weight according to above percentage of the additives. The doped polymer sheeting, HDPE film, for instance, can be fabricated efficiently and compactly packaged making it suitable for mass distribution.Type: GrantFiled: October 26, 1998Date of Patent: November 28, 2000Assignee: Ram Phosphorix LLCInventors: E. Tim Goldburt, Vladimir A. Bolchouchine, Boris N. Levonovitch, Naoum P. Sochtine
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Active radiation ray curable, solar radiation blocking resin compositions and films coated therewith
Patent number: 6107360Abstract: This invention provides a resin composition which is cured by active radiation rays, shows less absorption in the visible light region, has solar radiation blocking ability and is excellent in scratch resistance, and a film coated with the resin composition. Said resin composition comprises solar radiation absorbable fine particles of a metal oxide such as zinc antimonate anhydride, tin oxide, ATO (antimony doped tin oxide), ITO (tin doped indium oxide) or the like and an active radiation ray polymerizable (meth)acrylate having a (meth)acryloyl group, and a coating obtained therefrom has excellent paint film hardness and scratch resistance.Type: GrantFiled: August 18, 1997Date of Patent: August 22, 2000Assignee: Nippon Kayaku Kabushiki KaishaInventors: Shoichi Kaneko, Hiroshi Sakurai, Kaoru Izumi, Kenichiro Yoshioka -
Patent number: 6001755Abstract: The invention relates to a thin layer of UV absorbing material, and a method of making such material by grinding UV absorbing glass into fine powder which can be suspended in a liquid matrix, for example, in index matching oil, thereby producing a transparent liquid which can be used to coat any material to impart UV absorption to such material.Type: GrantFiled: August 7, 1998Date of Patent: December 14, 1999Assignee: Corning IncorporatedInventors: Roger J. Araujo, Alain R. E. Carre, Serge A. M. Renault
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Patent number: 5892621Abstract: The present invention relates to surfaces used to reflect light, and particularly to highly light reflectant surfaces that provide even diffusion of light for the purpose of maximizing light efficiency and/or uniformity in a luminaire. By employing an expanded polytetrafluoroethylene (PTFE) comprising a microstructure of polymeric nodes and fibrils, the material of the present invention demonstrates exceptional diffuse reflectivity across a wide spectrum of visible light. Additionally, the material of the present invention provides many properties that have been previously unavailable in highly diffuse reflective material, including a high degree of malleability, moldability and flexibility, and effective reflectivity even at relatively thin cross-sections.Type: GrantFiled: April 10, 1996Date of Patent: April 6, 1999Assignee: W. L. Gore & Associates, Inc.Inventors: Gordon L. McGregor, Raymond B. Minor, Gregory E. Hannon
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Patent number: 5800861Abstract: Infrared absorbing compositions useful as high solid coatings comprising 5-50% of a volatile solvent portion and 50-95% of a non-volatile portion which comprises a film-forming binder having dispersed within the binder opacifying polymeric beads and an infrared radiation absorbing pigment selected from the group consisting of copper phosphate, basic copper phosphate, copper pyrophosphate, tungsten trioxide and mixtures thereof.Type: GrantFiled: December 28, 1988Date of Patent: September 1, 1998Assignee: The Sherwin-Williams CompanyInventors: Chwan-Hwa Peter Chiang, William Roland Dawson, Layton Fredrick Kinney, Charles J. Sherman
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Patent number: 5770269Abstract: An article includes a substrate having a thermal control coating formed of 1 part by weight of a silicone polymeric matrix having from about 3 to about 4 parts by weight aluminum-doped zinc oxide pigment particles distributed therein. The article may be either relatively thick or flexibly thin, and the coating may be greater than 0.0015 inches thick so as to have a low solar absorptance. The coating has an absorptance of about 0.2-0.3 and an emittance of about 0.9, and is sufficiently electrically conductive to dissipate electrostatic charges.Type: GrantFiled: September 20, 1996Date of Patent: June 23, 1998Assignee: Hughes Aircraft CompanyInventors: Lynn E. Long, Joan L. Lum
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Patent number: 5767179Abstract: A novel hydroxide complex with condensed silicate represented by the formula (I)?Al.sub.2 (Li.sub.(1-x).M.sup.2+.sub.x)(OH).sub.6 !.sub.2 (Si.sub.y O.sub.2y+1.sup.2-).sub.1+x.mH.sub.2 O (I)wherein M.sup.2+ is a divalent metal, m, x and y are numbers respectively in the ranges of 0.ltoreq.m<5, 0.ltoreq.x<1 and 2.ltoreq.y.ltoreq.4, a process for preparing the same, an infrared absorber containing the same as an effective ingredient, and an agricultural film containing said infrared absorber.Type: GrantFiled: February 21, 1997Date of Patent: June 16, 1998Assignee: Fuji Chemical Industry Co., Ltd.Inventor: Kanemasa Takado
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Patent number: 5540998Abstract: This invention relates to a solar heat-shielding coating composition which consists mainly of two kinds or more of pigments selected from red, orange, yellow, green, blue and purple pigments in such a manner as to yield a color of low lightness, particularly achromatic black, by additive mixture and a weather-resistant vehicle and a structure covered with said coating composition, with the composition capable of covering the outside of said structure exposed directly to the sun and suppressing a rise in the inside temperature.Type: GrantFiled: November 30, 1994Date of Patent: July 30, 1996Assignee: Nippon Steel Chemical Co. Ltd.Inventors: Naofusa Yamada, Hatsuo Inagaki, Hironobu Kawasaki
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Patent number: 5434197Abstract: Decreasing the transmittal of near infra-red radiation through transparent glassy polymers, such as methacrylic ester polymers or those containing a high proportion of N-methyl dimethylglutarimide units, by use of a blended absorber is extremely difficult to accomplish because of the thermal instability of such absorbers under conditions necessary to process the glassy polymer. Use of very low levels of a specific class of thermally stable additives produces a thermally stable polymer blend which may be converted into transparent sheet exhibiting lowered transmittal of near infra-red radiation and useful for many glazing applications.Type: GrantFiled: July 12, 1994Date of Patent: July 18, 1995Assignee: Atohaas B.V.Inventor: Leslie A. Cohen
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Patent number: 5405958Abstract: Described are novel reversible photochromic spiro(indoline) naphthoxazine compounds of improved photocolorability that may be graphically represented by the formula, ##STR1## In preferred embodiments, R.sub.1 is allyl, alkoxyalkyl, and alkyl; each R.sub.2 is alkyl or alkoxy; R.sub.3 and R.sub.4 are alkyl; R.sub.5 is alkoxycarbonyl; and R.sub.6 is hydroxy, alkoxy, or carboxy, e.g., acetoxy. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the naphthoxazine compounds or combination thereof with complementary photochromic compounds, e.g., naphthopyran or benzopyran compounds, are also described.Type: GrantFiled: December 21, 1992Date of Patent: April 11, 1995Assignee: Transitions Optical, Inc.Inventor: Barry VanGemert
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Patent number: 5026429Abstract: A luster pigment is described which is made up of a metal oxide film on a colored platelet-like support. The support is a pigment having a length of 3-150 .mu.m, a width of 3-150 .mu.m, and a thickness of 0.1-2 .mu.m. A process is described for the preparation of the pigment in which an organic platelet-like pigment is coated with a metal-oxide film by chemical vapor deposition. The preferred platelet-like organic pigment is .beta.-copper phthalocyanine.Type: GrantFiled: January 25, 1990Date of Patent: June 25, 1991Assignee: BASF AktiengesellschaftInventors: Norbert Mronga, Werner Ostertag, Gustav Bock
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Patent number: 4895904Abstract: The invention relates to polymer sheets or films for use in greenhouses. The polymer sheets or films contain components which absorb or reflect in the near I.R. (NIR) i.e. in the 0.7 to 2.0.mu. region, and which transmit at least 75 percent in the photosynthesis active radiation (PAR) region, which is essentially the 0.4.mu. to 0.7.mu. region of the solar spectrum. The compositions of the invention contain UV radiation stabilizers. The NIR absorbers and reflectors in the films of the invention are certain specific oxides or metals in a very fine particle size, in the submicron or micron range.Type: GrantFiled: October 26, 1987Date of Patent: January 23, 1990Inventor: Yael Allingham
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Patent number: 4761913Abstract: Greenhouse screen for use as a filter for short-day treatment of plants and made of a film, textile, non-woven material or a combination thereof with high light resitance and good weathering conditions. The greenhouse screen at least partly consists of a material which in one or more layers has high absorption of light in a significant part of the wavelength interval 575-800 nm and with substantially total absorption in the wavelength interval 600-750 nm and which has high transmittance of light in the wavelength interval 400-575 nm.Type: GrantFiled: September 29, 1987Date of Patent: August 9, 1988Assignee: Ludvig Svensson International BVInventors: Goran Henningsson, Olof Hellgren
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Patent number: 4728677Abstract: The invention relates to a vinyl halide polymer composition suitable for outdoor use in the sunlight. The change in color as measured by .DELTA.E in articles made from the polymeric composition is found to be substantially lower than other compositions. The lower .DELTA.E provides a measurement for improved weatherability of the compositions in such applications as housing siding, window profiles, shutters and roof vents.Type: GrantFiled: May 30, 1986Date of Patent: March 1, 1988Assignee: The B. F. Goodrich CompanyInventors: Emilia E. Lacatus, Elvira B. Rabinovitch, James W. Summers
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Patent number: 4720516Abstract: A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.Type: GrantFiled: December 16, 1982Date of Patent: January 19, 1988Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori, Yasuaki Ii
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Patent number: 4608309Abstract: A thermal energy storage composition is provided comprising a slurry of polyolefin particles in a liquid. The particles have their surfaces crosslinked in a cold plasma so that the crosslinked surfaces have a heat of fusion substantially identical to the uncrosslinked portion of the particles.Type: GrantFiled: April 22, 1985Date of Patent: August 26, 1986Assignee: Massachusetts Institute of TechnologyInventors: Ih-Houng Loh, Robert E. Cohen, Raymond F. Baddour
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Patent number: 4587279Abstract: A cementitious composition comprising a cementitious material and polyethylene glycol or end-capped polyethylene glycol as a phase change material, said polyethylene glycol and said end-capped polyethylene glycol having a molecular weight greater than about 400 and a heat of fusion greater than about 30 cal/g; the compositions are useful in making pre-formed building materials such as concrete blocks, brick, dry wall and the like or in making poured structures such as walls or floor pads; the glycols can be encapsulated to reduce their tendency to retard set.Type: GrantFiled: August 31, 1984Date of Patent: May 6, 1986Assignee: University of DaytonInventors: Ival O. Salyer, Charles W. Griffen
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Patent number: 4518722Abstract: A highly diffuse, reflective paint comprising an alcohol soluble binder, polytetrafluoroethylene (TFE) and an alcohol for coating a substrate and forming an optical reference with a superior Lambertian characteristic. A method for making the paint by first mixing the binder and alcohol, and thereafter by mixing in outgassed TFE. A wetting agent may be employed to aid the mixing process.Type: GrantFiled: April 26, 1984Date of Patent: May 21, 1985Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: John B. Schutt, Michael C. Shai
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Patent number: 4492648Abstract: Light-collecting system, characterized in that it contains a dyestuff of the formula ##STR1## in which Hal designates identical or different halogen atoms from the series comprising fluorine, chlorine and bromine,R.sub.1 and R.sub.2 designate hydrogen or optionally substituted C.sub.1 -C.sub.18 -alkyl and n designates 4-5,and new dyestuffs of the formula I which in a 0.5-2 mM solution in path lengths of 10 cm display an increase in transmission from 0 to >95% with a change in the wavelength of 25-120 nm.Type: GrantFiled: December 7, 1982Date of Patent: January 8, 1985Assignee: Bayer AktiengelsellschaftInventor: Uwe Claussen
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Patent number: 4426465Abstract: A coating composition for solar selective absorption comprising, in solvent, particles of an inorganic black pigment dispersed in a dissolved binder of a thermosetting acrylic resin and particles of a low molecular weight fluorocarbon resin contained in an amount of 5-15 parts by weight per 100 parts by weight of the acrylic resin. The inorganic black particles have a size of 0.01-0.5 microns and are contained in an amount of 45-65 parts by weight per 100 parts by weight of the acrylic resin. An article having a metal substrate and a paint film formed thereon from the composition in a dry thickness of 1.5 microns or more is also described.Type: GrantFiled: February 18, 1982Date of Patent: January 17, 1984Assignee: Matsushita Electric Industrial Company, LimitedInventors: Masao Maki, Hiroshi Fukuda, Seiichi Sano
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Patent number: 4423164Abstract: There are provided polymeric compositions in sheet or film form adapted to transmit a large part of incident sunlight, a substantial part thereof by forward scattering, and to retain in an agricultural structure such as a greenhouse or tunnel-structure covered with such sheets a substantial part of IR radiation. The compositions comprise a polymer containing micron size particles of magnesium oxide and/or calcium carbonate.Type: GrantFiled: January 18, 1982Date of Patent: December 27, 1983Inventor: Rami Bar
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Patent number: 4395497Abstract: A process for the preparation of electrically conductive heteropolyphenylenes, wherein from 0.5 to 5 per cent by weight of an activating additive is introduced, in the absence of moisture and of oxygen, into a heteropolyphenylene of the general formula ##STR1## where X is O, S, Se, SO or SO.sub.2 and Y has one of the meanings given for X or is NH, CH.sub.2, CO or C.sub.6 H.sub.4, and n is from 2 to 250. The activating additive is preferably one of the compounds AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, SbCl.sub.5, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid and 2,4,6-trinitrophenylcarboxylic acid, or is sodium, potassium, rubidium, cesium, calcium or barium or one of their amides, the latter being added, if appropriate, in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene.Type: GrantFiled: June 15, 1981Date of Patent: July 26, 1983Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Dieter Naegele, Klaus Penzien, Johannes Schlag
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Patent number: 4360588Abstract: Light-sensitive photographic material which contains a non-light sensitive uv-filter layer comprising a compound of the formula ##STR1## wherein R is alkyl, sulphoalkyl, carboxyalkyl, alkaryl or aryl, X is --S--, --CH.sub.2 -- or --C(CH.sub.3).sub.2 --, T and Q are each an organic grouping or together complete a carbocyclic or heterocyclic ring, there being present in at least one of T and Q or in the ring which together they complete at least one electron withdrawing group.These compounds exhibit a very sharp cut-off point at about 400 nm.Type: GrantFiled: August 10, 1981Date of Patent: November 23, 1982Assignee: Ciba-Geigy AGInventor: Stephen R. Postle
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Patent number: 4359523Abstract: Light-sensitive photographic material which contains a non-light sensitive uv-filter layer comprising a compound of the general formula ##STR1## wherein R.sub.1 is alkyl or a group of the formula ##STR2## wherein R.sub.6 is alkylene and R.sub.7 and R.sub.8 are each alkyl or one of R.sub.7 and R.sub.8 can be hydrogen, R.sub.2 and R.sub.3 are each hydrogen or alkoxy, Z is oxygen or sulphur, Y is oxygen or sulphur or a group --NR.sub.5 --, wherein R.sub.5 is hydrogen or optionally substituted alkyl, aryl or carboxyalkyl, and R.sub.4 is hydrogen or optionally substituted alkyl, aryl or carboxyalkyl. These compounds exhibit a very sharp cut-off point at about 400 nm.Type: GrantFiled: August 10, 1981Date of Patent: November 16, 1982Assignee: Ciba-Geigy AGInventor: Stephen R. Postle
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Patent number: 4359522Abstract: Light-sensitive photographic material which contains as a uv-filter layer a non-light sensitive layer comprising a compound of the formula ##STR1## wherein W is the residue of an oxazolone, isoxazolone or pyrazolone ring, R.sub.1, R.sub.2 and R.sub.5 are each hydrogen or halogen or --OCOR.sub.10 wherein R.sub.10 is an optionally substituted alkyl or alkoxy, alkaryl or aryl, and R.sub.3 and R.sub.4 are each hydrogen or alkoxy.These compounds exhibit a very sharp cut-off point at about 400 nm.Type: GrantFiled: August 10, 1981Date of Patent: November 16, 1982Assignee: Ciba-Geigy AGInventor: Stephen R. Postle