Containing At Least Two Organic Materials, E.g., Binder Plus Other Organic Material, Etc. Patents (Class 523/156)
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Patent number: 8013178Abstract: Mercaptosilanes are disclosed of the formula I wherein R1 is an alkyl polyether group —O—(R5—O)m—R6. They are prepared by a procedure in which a silane of the formula II is subjected to a catalyzed reaction with an alkyl polyether R1—H, R7—OH being split off, the molar ratio of the alkyl polyethers R1—H to the silane of the formula II is at least 0.5 and R7—OH is separated off from the reaction mixture continuously or discontinuously. They can be used in shaped articles.Type: GrantFiled: January 20, 2006Date of Patent: September 6, 2011Assignee: Evonik Degussa GmbHInventors: Oliver Klockmann, Philipp Albert, Andre Hasse, Karsten Korth, Reimund Pieter
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Publication number: 20110213049Abstract: Rubber compositions for use in tire treads are disclosed and described. Such a composition may include a rubber component having from 40 to 80 parts by mass of a natural rubber and from 20 to 60 parts by mass of a diene rubber (other than said natural rubber) and, per 100 parts by mass thereof, from 80 to 150 parts by mass of a carbon black having a nitrogen specific surface area of from 250 to 450 m2/g and from 30 to 80 parts by mass of a resin.Type: ApplicationFiled: February 25, 2011Publication date: September 1, 2011Inventor: Yoichi Takizawa
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Publication number: 20110203712Abstract: Rubber composition, especially for a tire, based on at least one diene elastomer, a reinforcing filler, a crosslinking system and an antioxidant system, wherein said antioxidant system contains at least two antioxidants “A” and “B”: A. an N-alkyl-N?-phenyl-para-phenylenediamine corresponding to the formula (I): B. a 4,4?-bis(alkylamino)triphenylamine corresponding to the formula (II): in which formulae, R1, R2 and R3, which are identical or different, each represent a linear or branched alkyl group having from 1 to 12 carbon atoms or a cycloalkyl group having from 5 to 8 carbon atoms, the A/B weight ratio being between 0.2 and 5.0. Such an antioxidant system gives the composition of the invention a better long-term resistance to fatigue and to crack propagation.Type: ApplicationFiled: April 29, 2011Publication date: August 25, 2011Applicant: Michelin Recherche et Technique S.A.Inventors: José Carlos Araujo Da Silva, Pierre-Antoine Niore, Arnaud Remy
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Publication number: 20110196063Abstract: The present invention relates to a rubber composition for tread which is capable of improving wear resistance and tear resistance and reducing rolling resistance in a compatible manner. Specifically, the present invention relates to a rubber composition for tread, produced by blending carbon black with rubber components including modified conjugated diene-based polymer having at least one nitrogen-containing functional group, wherein the carbon black is obtained by a specific process and light transmittance of toluene extract thereof observed at the multi-stage rapid cooling medium introduction means satisfies relationships of formula (I) and formula (II) below.Type: ApplicationFiled: September 1, 2009Publication date: August 11, 2011Applicant: BRIDGESTONE CORPORATIONInventor: Daigo Yonemoto
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Publication number: 20110190417Abstract: The invention relates to a rubber mixture, in particular for pneumatic vehicle tires, more particularly for the inner liner of a pneumatic vehicle tire, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: 30 to 100 phr of at least one halobutyl rubber, 0 to 70 phr of at least one other diene rubber, 5 to 100 phr of at least one dry mixture compound containing at least 25% of at least one delaminated alumohydrosilicate modification, the delaminated alumohydrosilicate modification having a two-layer grid, 10 to 100 phr of at least one carbon black with an STSA surface as defined according to ASTM-D 6556 of from 10 to 60 m2/g and a DBP number defined according to ASTM-D 2414 of from 50 to 160 mL/100 g, 3 to 20 phr of at least one mineral-oil softener, and other additives.Type: ApplicationFiled: March 29, 2011Publication date: August 4, 2011Inventors: Thomas Müller-Wilke, Mario R. Conde, Steffi Meissner
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Publication number: 20110184084Abstract: A rubber composition for tires which comprises at least one rubber component selected from natural rubber and synthetic rubbers and, based on 100 parts by mass of the rubber component, 0.1 to 45 parts by mass of (A) a terpene phenol resin and 1 to 150 parts by mass of (B) a softener comprising a process oil which comprises polycyclic aromatic compounds (PCA) in an amount such that the content of extracts with dimethyl sulfoxide (DMSO) in accordance with the method of IP346 is controlled to a value smaller than 3%. A rubber composition for tires which overcomes problems arising due to the use of a highly aromatic oil having a content of polycyclic aromatic compounds (PCA) controlled to a value smaller than 3% as the process oil in place of conventional highly aromatic oils and exhibits excellent loss property and rigidity and a tire which uses the rubber composition and exhibits excellent steering stability on dry road surfaces and excellent braking property on wet road surfaces can be provided.Type: ApplicationFiled: April 6, 2009Publication date: July 28, 2011Inventor: Seiichi Katou
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Publication number: 20110184086Abstract: This invention relates to a rubber composition which has an excellent processability but also improves a storage modulus (G?) and loss tangent (tan ?) at a low temperature and further improves a wear resistance, and more particularly to a rubber composition characterized by compounding more than 1 part by mass but less than 30 parts by mass of a low-molecular weight polymer component (B) having an amount of an aromatic vinyl compound bonded of less than 30 mass % and a weight average molecular weight as converted to polystyrene of 0.2×104-8.0×104 and not less than 5 parts by mass of a filler (C) based on 100 parts by mass of a high-molecular weight polymer component (A) having an amount of an aromatic vinyl compound bonded of not more than 80 mass % and a weight average molecular weight as converted to polystyrene of not less than 1.Type: ApplicationFiled: June 26, 2009Publication date: July 28, 2011Applicant: BRIDGESTONE CORPORATIONInventors: Urara Takado, Koji Masaki
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Publication number: 20110184087Abstract: Rubber compounds containing a halobutyl elastomer, at least one additional elastomer, a mineral filler and at least a three component mixed modifier system comprising a silane compound, a phosphine compound and an additive containing at least one hydroxyl group and a functional group containing a basic amine. A process for preparing the compounds is also disclosed. The compounds are particularly useful in tire treads and exhibit improved processability, traction, rolling resistance and wear properties.Type: ApplicationFiled: April 5, 2011Publication date: July 28, 2011Applicant: LANXESS INC.Inventors: Ezio Campomizzi, Ralf-Ingo Schenkel, Lionel Cho-Young, Kevin Kulbaba
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Publication number: 20110184085Abstract: It is an object of the present invention to provide a tread rubber composition for a two-wheeled vehicle tire which can exhibit both good wet grip performance and good chunk resistance, and a two-wheeled vehicle tire including a tread produced using the rubber composition. The present invention relates to a tread rubber composition for a two-wheeled vehicle tire, including: a rubber component, silica, and carbon black, wherein the rubber component contains natural rubber, and styrene butadiene rubber and/or butadiene rubber, the silica has a CTAB specific surface area of 180 m2/g or more and a BET specific surface area of 185 m2/g or more, and the amount of the carbon black is 15 parts by mass or more per 100 parts by mass of the rubber component.Type: ApplicationFiled: January 26, 2011Publication date: July 28, 2011Inventor: Shigeki OTSUBO
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Publication number: 20110180195Abstract: Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.Type: ApplicationFiled: September 16, 2010Publication date: July 28, 2011Applicant: Bridgestone CorporationInventors: William L. Hergenrother, Chenchy J. Lin, Terrence E. Hogan, Ashley S. Hilton
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Publication number: 20110144235Abstract: A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling.Type: ApplicationFiled: February 18, 2011Publication date: June 16, 2011Inventors: William L. Hergenrother, James H. Pawlow, Terrence E. Hogan, Ashley S. Hilton
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Publication number: 20110144234Abstract: A rubber composition comprising: (A) 100 parts by weight of a rubber component mainly containing at least one rubber selected from the group consisting of natural rubber and/or isoprene rubber, (B) 0.5 to 3 parts by weight of a condensation product of resorcin and a ketone, and (C) 0.5 to 2 parts by weight of a condensation product of melamine, formaldehyde and methanol wherein the ratio of methylol groups to melamine structures is 0.35 to 0.55 and the average degree of polymerization is 1.2 to 1.6.Type: ApplicationFiled: June 2, 2009Publication date: June 16, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Naoki Inui
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Publication number: 20110112212Abstract: Provided is a tire using a rubber composition, in which: the rubber composition contains a rubber component and a filler; the rubber component contains (A) a modified conjugated diene polymer and (B) a modified conjugated diene-aromatic vinyl copolymer; a modifying agent used for each of the component (A) and the component (B) includes (C) a hydrocarbyloxysilane compound containing a nitrogen atom and a silicon atom or (D) a hydrocarbyloxysilane compound containing a silicon atom; a combination of an unmodified conjugated diene polymer and the modifying agent, and a combination of an unmodified conjugated diene-aromatic vinyl copolymer and the modifying agent include any one of the following items 1 to 3: 1: the conjugated diene polymer and the component (C), and the conjugated diene-aromatic vinyl copolymer and the component (D); 2: the conjugated diene polymer and the component (D), and the conjugated diene-aromatic vinyl copolymer and the component (C); and 3: the conjugated diene polymer and the componentType: ApplicationFiled: December 8, 2008Publication date: May 12, 2011Applicant: BRIDGESTONE CORPORATIONInventors: Takumi Kimura, Satoshi Ishikawa
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Rubber mixture comprising environmentally friendly softeners cross reference to related applications
Publication number: 20110112213Abstract: The invention relates to a rubber mixture, in particular for vehicle air-inflated tires, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: at least one polar or non-polar rubber and at least one bright and/or dark filler and at least one softener, wherein the softener is free of polycyclic aromatics according to Directive 76/769/EEC, and wherein the carbon source for the softener comes from non-fossil sources, and other additives.Type: ApplicationFiled: January 13, 2011Publication date: May 12, 2011Inventors: Carla Recker, Thorsten Reese, Jens Schöning -
Publication number: 20110112214Abstract: The present invention aims to provide a rubber composition that improves heat resistance and particularly inhibits the changes in properties such as hardness of the vulcanized rubber composition (rubber hardening degradation) due to long-term use without an increased amount of an age resistor, thereby extending the life-span without deterioration of performance on ice, and reduces vulcanization time while maintaining good scorch resistance, and increases cross-linking efficiency; and a studless tire having a cap tread produced from the composition. The rubber composition for a cap tread of the invention comprises: a rubber component containing an isoprene-based rubber; silica; a compound represented by formula (I) and/or (II); and a thiuram vulcanization accelerator, wherein R1 and R2 may be the same or different, and each represent a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, provided that the case where R1 and R2 are simultaneously hydrogen atoms is excluded.Type: ApplicationFiled: November 5, 2010Publication date: May 12, 2011Inventor: Ryoji KOJIMA
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Publication number: 20110094649Abstract: An object of the present invention to provide a rubber composition for sidewall and a tire having sidewall using thereof as well as a rubber composition for clinch and a tire having clinch using thereof that adjust scorch time and suppress surface bloom, reduce rolling resistance, can obtain sufficient rigidity as sidewall and clinch, and can improve elongation at break and durability. The present invention relates to a rubber composition for sidewall and a rubber composition for clinch including specific amount of an alkylphenol-sulfur chloride condensate indicated by the formula (B1): and specific filler, based on a rubber component including specific amount of a natural rubber and/or an isoprene rubber and a butadiene rubber and/or an epoxidized natural rubber, and a tire having sidewall using thereof and clinch using thereof.Type: ApplicationFiled: September 24, 2008Publication date: April 28, 2011Inventor: Tatsuya Miyazaki
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Publication number: 20110098378Abstract: A composition includes a vulcanizable diene rubber, a silica filler, and a metal-functionalized polyisobutylene succinic anhydride derivative. In one embodiment the composition has a reduced amount of oil and may include no oil. A tire tread composition includes, a silica filler, a metal-functionalized polyisobutylene succinic anhydride derivative, a rubber matrix, an optional oil, and one or more components selected from the group consisting of carbon black, vulcanizing agent, vulcanization accelerator, tackifier resin, antioxidant, wax, peptizer, vulcanization retarder, activator, processing additive, plasticizer, pigments, and antiozonant. A method for making the rubber composition and the tire tread is also provided.Type: ApplicationFiled: June 26, 2009Publication date: April 28, 2011Inventors: Xiaorong Wang, Victor J. Foltz
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Publication number: 20110077326Abstract: The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer, mineral filler and a silylated additive. The present invention also provides a filled halobutyl elastomer containing a mineral filler and a silylated additive.Type: ApplicationFiled: September 29, 2010Publication date: March 31, 2011Applicant: LANXESS INC.Inventors: Rui Resendes, Janice Nicole Hickey
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Publication number: 20110041976Abstract: This invention relates to a rubber composition capable of improving wear resistance without losing low heat buildup and a heavy duty pneumatic tire in which the low heat buildup and the wear resistance are simultaneously established, and more particularly to a rubber composition characterized by comprising 40 to 60 parts by mass of a carbon black based on 100 parts by mass of a rubber component composed of natural rubber and a diene-based synthetic rubber and satisfying a relation of the following formula (1): ?E?<0.29×A?11??(1) [wherein ?E? is a difference between a storage modulus (MPa) at a strain of 0.1% and a storage modulus (MPa) at a strain of 2% measured at 25° C., and A is an amount (parts by mass) of the carbon black compounded based on 100 parts by mass of the rubber component] and a heavy duty pneumatic tire characterized by using the rubber composition in a tread.Type: ApplicationFiled: September 14, 2007Publication date: February 24, 2011Applicant: Bridgestone CorporationInventors: Yasuyuki Saeki, Mami Tajima
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Publication number: 20110034584Abstract: Mixtures of silicon-containing coupling reagents comprising (mercaptoorganyl)alkylpolyethersilanes containing silanol groups and (mercaptoorganyl)alkylpolyethersilanes free of silanol groups in a weight ratio of from 5:95 to 95:5. The mixtures can be prepared by transesterification and hydrolysis. The mixtures can be used in rubber mixtures.Type: ApplicationFiled: June 11, 2007Publication date: February 10, 2011Inventors: Philipp Albert, Manuel Friedel, Karsten Korth, Andre Hasse, Oliver Klockmann
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Publication number: 20110003912Abstract: Rubber compositions of the invention give crosslinked rubber products having excellent flexibility. The rubber compositions include 50 to 99 parts by weight of a diene rubber (A) and 50 to 1 part by weight of a ricinoleic acid (co)polymer (B) having a weight average molecular weight of not less than 20,000 according to GPC (wherein the total of the diene rubber (A) and the ricinoleic acid (co)polymer (B) is 100 parts by weight).Type: ApplicationFiled: March 2, 2009Publication date: January 6, 2011Inventor: Hiroki EBATA
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Publication number: 20100256259Abstract: The purpose of the present invention is to provide a wet friction material which has a high coefficient of friction, has reduced overall thickness change, and excellent heat resistance (resistance to heat spots). In order to accomplish the purpose, the present invention provides a wet friction material prepared by impregnating a base material comprising a fibrous substance with a thermosetting resin, and then thermally curing it, wherein the aspect ratio of the fibrous substance is 10 or higher, and the fibrous substance is contained in the base material in an amount of 60 to 75 weight % .Type: ApplicationFiled: October 2, 2008Publication date: October 7, 2010Applicant: SHOWA HIGHPOLYMER CO., LTD.Inventor: Toshihiko Kozutsumi
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Patent number: 7767733Abstract: Clutch lings comprising fiber-reinforced ceramic materials which comprise carbon fibers and whose matrix material is selected from among inorganic polymers, oxidic ceramics, set cements, organoelement polymers and finely divided inorganic solids which are held together by an inorganic or organic binders.Type: GrantFiled: August 17, 2004Date of Patent: August 3, 2010Assignee: SGL Carbon AGInventors: Andreas Kienzle, Mario Krupka, Gustavo Cabello, Ronald Hüner, Moritz Bauer
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Publication number: 20100099796Abstract: Tyre tread comprising a rubber composition, the said composition comprising at least one diene elastomer, one reinforcing filler and one plasticizing system, characterized in that the said plasticizing system comprises, in combination: a plasticizing hydrocarbon resin, the glass transition temperature of which is greater than 0° C.Type: ApplicationFiled: December 19, 2007Publication date: April 22, 2010Applicant: MICHELIN RECHERCHE ET TECHNIQUES S.A.Inventors: Garance Lopitaux, Didier Vasseur
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Publication number: 20100084233Abstract: A non-asbestos friction material includes at least one binder, fiber, lubricant, abrasive and titanate in a range of volume fractions in combination with other materials such as fillers and is substantially free of copper and asbestos.Type: ApplicationFiled: October 3, 2008Publication date: April 8, 2010Applicant: FEDERAL-MOGUL PRODUCTS, INC.Inventor: Vijay Subramanian
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Publication number: 20100084065Abstract: The present invention has its object to provide a rubber composition having excellent low-exothermic property and high strength together, and a pneumatic tire produced using the rubber composition. The present invention relates to a rubber composition which contains a rubber component and 10 to 150 parts by mass of silica per 100 parts by mass of the rubber component. The rubber component contains a butadiene rubber modified by a compound represented by the formula (1): wherein, R1, R2 and R3 are the same or different and independently represent an alkyl group, an alkoxy group, a silyloxy group, an acetal group, a carboxyl group, a mercapto group, or a derivative thereof; R4 and R5 are the same or different and independently represent a hydrogen atom or an alkyl group; and n represents an integer.Type: ApplicationFiled: July 29, 2009Publication date: April 8, 2010Inventors: Kenichi Uesaka, Toshiro Matsuo
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Publication number: 20100036018Abstract: The invention is directed to an activated halo-containing aralkylsilanes possessing at least one hydrolyzable group bonded to a silicon atom and at least one halo functional group bonded to a carbon atom to which both the silicon atom and an aromatic group are covalently bonded. The invention is also directed to a process for making such a silane as well as its use in rubber compositions and articles containing such rubber compositions, such as tires.Type: ApplicationFiled: August 7, 2008Publication date: February 11, 2010Inventors: Ping Jiang, Juan Alfonso, Eric R. Pohl
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Publication number: 20090054551Abstract: The invention relates to a rubber mixture that can be cross-linked by sulphur and contains, in order to achieve low-temperature flexibility and high-temperature rigidity, at least one diene rubber, between 5 and 150 phr (weight parts in relation to 100 weight parts of the total rubber mass) of at least one type of soot with an iodine adsorption index >65 g/kg and a DBP index >90 cm3/100 g, and between and 150 phr of a type RAE (residual aromatic extract) crude oil fraction as a softener. The weight ratio of the soot to the crude oil fraction in the mixture is 1:1 to 1:10.Type: ApplicationFiled: May 5, 2006Publication date: February 26, 2009Inventors: Steffi Meissner, Hajo Weinreich, Fabian Dettmer, Jurgen Wagemann
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Publication number: 20090050250Abstract: There are provided a rubber composition for coating a steel cord, containing 100 parts by mass of diene-based rubber; 0.5 to 5 parts by mass of a metal salt of an organic acid; and 30 to 100 parts by mass of a filler, wherein the filler contains 3 to 30 parts by mass of glass beads having a particle diameter of 10 to 100 ?m, relative to 100 parts by mass of the diene-based rubber, and a tire reinforcement belt and a pneumatic tire using the rubber composition. The rubber composition reduces heat generation and improves adhesiveness with a steel cord. A pneumatic tire having a tire reinforcement belt using the rubber composition has excellent steering stability and rolling resistance.Type: ApplicationFiled: August 7, 2008Publication date: February 26, 2009Inventor: Tetsuya KUNISAWA
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Publication number: 20090025847Abstract: The present invention relates to a run flat tire having improved durability during a blowout, an increased running distance and velocity, and using for a side portion reinforcing layer a rubber composition including a rubber component containing 20 to 80% by mass of styrene-butadiene rubber including 5 to 60% by mass of syndiotactic 1,2-polybutadiene crystal, and 10 to 80% by mass of natural rubber and/or polyisoprene rubber, and carbon black blended in an amount of 10 to 80 parts by mass with 100 parts by mass of the rubber component. The rubber composition preferably contains a C5-based petroleum resin having a number-average molecular weight of 300 to 10000, which is obtained by polymerizing C5-based petroleum hydrocarbon, in an amount of 0.5 to 10 parts by mass with respect to 100 parts by mass of the rubber component.Type: ApplicationFiled: July 11, 2008Publication date: January 29, 2009Inventor: Kazuo Hochi
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Patent number: 7459490Abstract: Process for providing a binder for mineral wool products, said process comprising the steps of: mixing together under reactive conditions a carboxylic acid with an alkanolamine, whereby optionally these are firstly mixed to provide a resin, which resin is subsequently reacted with a separate carboxylic acid group containing polymer.Type: GrantFiled: January 28, 2005Date of Patent: December 2, 2008Assignee: Rockwool International A/SInventors: Thor Husemoen, Erling Lennart Hansen, Povl Nissen
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Patent number: 7338987Abstract: There are disclosed a friction material composition which comprises a fibrous material except for asbestos, an inorganic friction regulator, an organic friction regulator and a binder, part of the inorganic friction regulator is ? alumina and ? alumina in combination, a weight ratio of the ? alumina and the ? alumina, ? alumina:? alumina, is in the range of 1:20 to 1:5, and part or whole part of the binder is a silicon-containing phenol resin, and a friction material obtained by molding the friction material composition under heating and pressure.Type: GrantFiled: May 21, 2004Date of Patent: March 4, 2008Assignees: Hitachi Chemical Co., Ltd., Nissan Motor Co., Ltd.Inventors: Manabu Ono, Teruyuki Nagayoshi, Mitsuhiro Inoue, Hiroki Morozumi, Takahiro Mibe, Yukio Takai
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Patent number: 7326742Abstract: The present invention provides a wet type friction material comprising a paper base material and binder, in which the paper base material includes silica having an average particle diameter of 1 to 10 ?m and disc-shaped diatom earth, and the binder comprises a cured substance of liquid resin composition material obtained by mixing resol type phenol resin with silicone resin, where a weight ratio between non-volatile components of the resol type phenol resin and the silicone resin is adjusted to a range of 95/5 to 85/15.Type: GrantFiled: October 16, 2003Date of Patent: February 5, 2008Assignees: Toyota Jidosha Kabushiki Kaisha, NSK-Warner K.K.Inventors: Masataka Kawabata, Atsushi Suzuki, Hideki Tatewaki, Katsumi Takezawa
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Patent number: 7297728Abstract: A friction material is made by molding and curing a composition containing a fibrous base that includes stainless steel fibers but not other steel fibers, a binder, and a friction modifier that includes at least two types of hard particles having a large Mohs hardness, bronze powder and a specific amount of tin sulfide. The friction material has a excellent balance of properties, including a high strain linearity that provides a excellent brake feel, a high torque linearity and a excellent effectiveness, and also minimizes disc rotor attack, disc pad wear and metal pickup. Such friction materials are particularly suitable for automotive applications, such as disc pads.Type: GrantFiled: July 1, 2004Date of Patent: November 20, 2007Assignee: Nisshinbo, Industries, Inc.Inventors: Kazuhide Yamamoto, Yasuki Hattori
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Patent number: 7294188Abstract: An improved method of producing a friction material for use in the production of brake pads. A first mixing step blends binder, fiber, and filler materials together in a mixer to create a pre-mix, with one of the materials doubling as a wetting agent promoting the homogeneity of the mixture. A second non-asbestos material is added to the pre-mix in the same mixer, and the two are mixed together to produce the final friction material.Type: GrantFiled: December 20, 2005Date of Patent: November 13, 2007Assignee: Akebono Corporation (North America)Inventors: Xinming Shao, Sunil Kesavan
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Patent number: 7160378Abstract: The present invention provides a friction control composition comprising a binder a rheological control agent, and optionally a lubricant. The liquid friction control composition may also comprise other components a wetting agent, a consistency modifier, and a preservative. The liquid friction control compositions may be used to modify the interfacial friction characteristics in sliding and rolling-sliding contact such as steel wheel-rail systems including mass transit and freight systems. A method of reducing lateral force, reducing energy consumption, or controlling friction between a metal surface and a second metal surface by applying the composition to metal surface, for example a top of rail or wheel, is also provided. The composition may be sprayed onto the rail surface.Type: GrantFiled: August 13, 2004Date of Patent: January 9, 2007Assignee: Kelsan Technologies Corp.Inventors: Don Eadie, Xin Lu, John Cotter
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Patent number: 7033663Abstract: A functionally graded friction material 18 having improved wear resistance and thermal conductivity with fibers 10 and heat conducting elements 12 disposed in an arrangement that conducts heat away from a first surface 20 to a second surface 22. Preferably, the heat conducting elements 12 are copper, copper alloy, filaments, threads, or wire situated substantially perpendicular to the engaging surface and extending to the non-engaging surface 22.Type: GrantFiled: June 27, 2000Date of Patent: April 25, 2006Assignee: Eaton CorporationInventor: Tulin Kuzulugil Hidayetoglu
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Patent number: 6887549Abstract: A friction material obtainable by molding and curing a material composition having a fibrous base, a binder, and a filler, wherein an amount of sulfate ions extracted from the friction material measured in accordance with JIS K 0127 is about 0.2 mg/g or smaller and the pH of the friction material is about 10.0 or higher and less than about 13.0.Type: GrantFiled: June 24, 2004Date of Patent: May 3, 2005Assignee: Nisshinbo Industries, Inc.Inventors: Seiji Suzuki, Yasuki Hattori, Kazuhide Yamamoto
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Patent number: 6849683Abstract: Process for providing a binder for mineral wool products, said process comprising the steps of: mixing together under reactive conditions a carboxylic acid with an alkanolamine, whereby optionally these are firstly mixed to provide a resin, which resin is subsequently reacted with a separate carboxylic acid group containing polymer.Type: GrantFiled: June 15, 2001Date of Patent: February 1, 2005Assignee: Rockwool International A/SInventors: Thor Husemoen, Erling Lennart Hansen, Povl Nissen
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Patent number: 6831146Abstract: A resin composition for wet friction materials contains as a main component a phenolic resin formed as a result of the reaction between phenols and aldehydes in the presence of a basic catalyst, and a particulate filler having a specific surface area of 35 to 410 m2/g as an additive. A wet friction material is formed using the resin composition for wet friction materials described above as a binder. The thus formed wet friction material exhibits a small initial rate of change in friction coefficient, a large positive gradient of &Dgr;&mgr;-V characteristic, and excellent durability.Type: GrantFiled: March 31, 2003Date of Patent: December 14, 2004Assignees: Sumitomo Bakelite Company Limited, NSK-Warner K.K.Inventors: Hiroshi Aiba, Masahiro Mori
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Patent number: 6620860Abstract: A friction material suitable for mating with a disk rotor or drum consisting mainly of an aluminum alloy reinforced by a hard material. The friction material suppresses the generation of a scoring on the disk rotor or drum. It also suppresses the change in the coefficient of friction before and after a heat history. The friction material comprises not only an organic-fiber base material, a binder resin, a friction-adjusting agent, a filler, and an inorganic powder, but also an inorganic fiber and a metal powder having a particle diameter of 1 to 180 &mgr;m.Type: GrantFiled: February 28, 2001Date of Patent: September 16, 2003Assignee: Sumitomo Electric Industries, Ltd.Inventors: Katsuya Okayama, Yukinori Yamashita, Hiroyuki Fujikawa
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Patent number: 6617375Abstract: A non-asbestos friction material is obtained by molding and curing a composition comprising a fibrous base, a filler and a binder. The binder is present in a total amount V1 and the filler contains in part graphite present in an amount V2, each expressed in volume percent of the overall composition, such that the product V1×V2 is from 10 to 100 and the sum V1+V2 is from 10 to 30. When used as a brake lining in drum brakes, for example, the friction material exhibits low wear during high-speed braking, excellent heat resistance, stable braking effectiveness and good strength.Type: GrantFiled: March 2, 2001Date of Patent: September 9, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Mitsuru Kobayashi, Shinya Sawamura
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Patent number: 6596789Abstract: A non-asbestos friction material made by molding and curing a composition comprised of a fibrous base, a binder, and a filler has a 100 Hz vibration damping factor (tan &dgr;) at 300° C. minus tan &dgr; at 50° C. value of at least −0.030. The binder may be a rubber-modified high-ortho phenolic resin, a resin mixture of a rubber-modified high-ortho phenolic resin and a rubber-modified phenolic resin, or a resin mixture of two or more rubber-modified phenolic resins. The friction material has an excellent and long-lasting noise performance, and good wear resistance, functional stability, and fade resistance. The rapid curability of the composition enables a short molding cycle.Type: GrantFiled: August 26, 1999Date of Patent: July 22, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Tomoki Nakamura, Takeo Nagata, Kazuhiro Takeuchi, Mitsuru Kobayashi
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Publication number: 20030015817Abstract: The present invention relates to a resinous composition comprising a carbon powder and a polybenzimidazole resin powder, and a tribological material using the resinous composition. This tribological material can be produced by blending a carbon powder and a polybenzimidazole resin powder together to prepare a composition and molding the composition with heating under pressure. The present invention provides a tribological material which possesses excellent tribological properties under high temperature conditions and has a low coefficient of friction.Type: ApplicationFiled: June 19, 2002Publication date: January 23, 2003Inventors: Noriyuki Niwa, Masami Aizawa
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Publication number: 20020169231Abstract: A friction material suitable for mating with a disk rotor or drum consisting mainly of an aluminum alloy reinforced by a hard material. The friction material suppresses the generation of a scoring on the disk rotor or drum. It also suppresses the change in the coefficient of friction before and after a heat history. The friction material comprises not only an organic-fiber base material, a binder resin, a friction-adjusting agent, a filler, and an inorganic powder, but also an inorganic fiber and a metal powder having a particle diameter of 1 to 180 &mgr;m.Type: ApplicationFiled: February 28, 2001Publication date: November 14, 2002Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Katsuya Okayama, Yukinori Yamashita, Hiroyuki Fujikawa
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Patent number: 6479413Abstract: A composite friction unit of a three dimensional composite body is formed of a substantially uniform array of predominately glass strands of primary reinforcing fibers in matrix of phenolic resin material, the reinforcing fibers in the form of fabric distributed throughout the body forming a friction unit having a predetermined size and configuration and uniform distribution and alignment of fibers throughout. An alternate friction unit includes a substantially rigid backing co-pultruded in forming the unit. The units are produced in a pultrusion process wherein the reinforcing fibers and matrix are pulled through a forming die.Type: GrantFiled: August 30, 2000Date of Patent: November 12, 2002Inventor: Benjamin V. Booher
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Patent number: 6475614Abstract: In a friction material including a fibrous reinforcement, a friction modifier and a binder, no whisker-like potassium titanate fiber is contained, but powdery or flaky potassium titanate with an aspect ratio of not higher than 3 is mixed as a friction component. The diameter of the powdery or flaky potassium titanate is preferably in a range of from 0.05 &mgr;m to 150 &mgr;m. In addition, the powdery or flaky potassium titanate is preferably subjected to surface treatment with a silane coupling agent, phenolic resin, or the like. Further, fibrous potassium titanate may be mixed at a volume ratio of not higher than 30% with respect to the powdery or flaky potassium titanate. The fibrous potassium titanate is a by-product when the powdery or flaky potassium titanate is produced and which has a length of not longer than 5 &mgr;m or a diameter of not smaller than 3 &mgr;m.Type: GrantFiled: December 19, 2000Date of Patent: November 5, 2002Assignee: Akebono Brake Industry Co., Ltd.Inventor: Akihiro Hikichi
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Patent number: 6451872Abstract: A non-asbestos friction material is comprised of a molded and cured composition which includes a fibrous base, a binder, a filler, and particles of a rubber composite composed primarily of at least one fibrous substance and rubber, or of at least one fibrous substance, at least one type of hard particle and rubber. The rubber composite particles enable the fibrous substance to be uniformly dispersed and mixed without forming clumps and without segregation of the hard fibrous substance and the hard particles in the finished article. The qualities of each constituent can thus be used to full advantage to give friction materials such as automotive disk pads which have an excellent friction performance.Type: GrantFiled: July 28, 2000Date of Patent: September 17, 2002Assignees: Nisshinbo Industries, Inc., BBA Friction GmbHInventor: Takeshi Yamane
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Patent number: 6231977Abstract: A wet friction material with small initial variations in friction coefficient, suppressing occurrence of heat spots, and with excellent heat resistance and friction resistance is provided. In the wet friction material including a fiber base material, a filler, a friction controller, and a resin binder, the resin binder is a phenolic resin modified with p-nonyl phenol.Type: GrantFiled: August 18, 1999Date of Patent: May 15, 2001Assignee: NSK-Warner, K. K.Inventors: Makoto Suzuki, Masahiro Mori
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Patent number: 6221475Abstract: A friction element is made out of a composite material comprising carbon fiber reinforcement and a matrix which, at least in the vicinity of the or each friction face, comprises: a first phase in the vicinity of the reinforcing fibers and containing pyrolytic carbon obtained by chemical vapor infiltration; a refractory second phase of carbon or ceramic obtained at least in part by pyrolysis of a liquid precursor; and a silicon carbide phase obtained by siliciding, for example. At least in the vicinity of the or each friction face, the composite material is preferably constituted, by volume, at least as follows: 15% to 35% carbon fibers; 10% to 55% first matrix phase containing pyrolytic carbon; 2% to 30% second matrix phase of refractory material; and 10% to 35% silicon carbide. The invention is applicable in particular to braking for rail or road vehicles.Type: GrantFiled: April 13, 1999Date of Patent: April 24, 2001Assignee: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation - S.N.E.C.M.A.Inventors: Jean-Marc Domergue, Jean-Michel Georges, Michel Laxague