Abstract: A colored lead for writing, drawing and coloring implements, more particularly erasable, sintered colored lead, or to a colored chalk, more particularly erasable, sintered colored chalk, having a sintered lead or chalk base body which is formed from a lead or chalk base material containing at least one binder with a proportion of from 1 to 25% by weight and at least one filler with a proportion of from 25 to 99% by weight. The sintered lead or chalk base body is impregnated with at least one colorant and at least one lubricant.

Abstract: Methods described herein may be useful in the fabrication and/or screening of devices (e.g., sensors, circuits, etc.) including conductive materials. In some embodiments, a conductive material is formed on a substrate using mechanical abrasion. The methods described herein may be useful in fabricating sensors, circuits, tags for remotely-monitored sensors or human/object labeling and tracking, among other devices. In some cases, devices for determining analytes are also provided.

Abstract: This invention relates to a solid marking composition comprising at least one resin, at least one pigment, at least one dispersant, at least one solvent, and a gelling agent. This invention also provides a method of making the solid marking composition.

Abstract: A lead for painting includes a water-insoluble lead basic mass in which a water-soluble dye is present. A method of painting with a lead is also provided.

Abstract: A polymer-bound writing substance for writing, drawing and/or painting tools, particularly for pencils or colored pencils, including at least one polymer bonding agent, at least one wax, and at least one filler material, wherein the writing substance is further provided with 0.1 to 5 wt % of palm kernel oil, and/or coconut butter, and/or coconut oil, and/or oleic acid.

Abstract: A colorized pen with high elasticity and plasticity is composed of 20-40 wt % of a high molecular polymer as a main part, 20-38 wt % of a white or colorless solid powder as a part for the color carrier, 2-20 wt % of a pigment as a coloration part, and 2-20 wt % of a suitable regulator as an auxiliary part. A process for manufacturing a colorized pen with high elasticity and plasticity comprises the following steps: mixing raw materials uniformly, then extrusion molding the same at 120° C.-250° C., cooling, curing and then cutting the same. The pen of the present invention has high elasticity and plasticity, is environmentally friendly and safe, and possesses a clear color during writing; its manufacturing process is simple and environmentally friendly, and it has a wide applicability and reliable safety.

Abstract: The invention provides a crayon which comprises an alternative plasticizer in place of the conventional phthalate ester plasticizers and yet provides writings excellent in water resistance, the crayon comprising a colorant, a gelling agent, an organic solvent, a resin component, and a plasticizer, wherein the plasticizer is at least one selected from diisononyl adipate, acetyltributyl citrate, 1,2-cyclohexanedicarboxylic acid diisononyl, and alkylsulfonic acid phenyl ester and is contained in an amount of 1 to 20% by weight based on the crayon.

Abstract: A polymer-bonded pencil lead for writing, drawing, and/or painting devices, including at least one polymer binder, one wax, and at least one filler. The pencil lead includes 0.5 to 2.5% by weight palm oil.

Abstract: The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises: dissolving and dispersing a resin component and carbon black having a pH of not less than 5.0 in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution, pouring the raw material solution into a molding container, and cooling and gelling the raw material solution.

Abstract: A polymeric material comprised of (i) at least one random copolymer comprised of ethylene oxide and one or more other alkylene oxide(s) and (ii) at least one non-random polymer comprised of one or more poly(alkylene oxide)s has been discovered. Preferably, it is a polymer alloy. Alkylene oxide homo-polymers or block copolymers may be the non-random polymer. In a related discovery, an adhesive material can be made by suspending (a) particles in (b) a matrix of at least one poly(ethylene oxide) copolymer of ethylene oxide and propylene oxide, or a combination thereof. The handling characteristics may be adjusted for different utilities (e.g., from runny oil to hard wax). Applications include use as adhesive, cohesive, filler, lubricant, surfactant, or any combination thereof. In particular, the hard materials may be used for cleaning or waxing.

Abstract: The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises: dissolving and dispersing a resin component, carbon black having a pH of less than 5.0 and an organic amine in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution, pouring the raw material solution into a molding container, and cooling and gelling the raw material solution.

Abstract: Inventive subject matter described herein includes a powder comprising: a wax having a melt point within a range of 45 to 100 degrees Centigrade and sodium polyacrylate or salts of sodium polyacrylate or sodium polyacrylate and salts of sodium polyacrylate wherein the wax concentration falls within a range of 99.9% to 0.1% by weight and the sodium polyacrylate concentration falls within a range of 0.1% to 99.9% by weight, wherein the powder is effective for forming a cream or lotion or gel or coating when mixed with water at room temperature or cooler than room temperature.

Abstract: The invention relates to an aqueous pigment preparation, containing (A) at least one organic and/or inorganic pigment, (B) a dispersing agent of the formulas (I), (II), (III), or (IV), or mixtures of the dispersing agent of the formulas (I), (II), (III), or (IV), (C) optionally a wetting agent, (D) optionally further surfactants and/or dispersing agents, (E) optionally one or multiple organic solvents, or one or multiple hydrotropic substances, (F) optionally further additives common for the production of aqueous pigment dispersions, and (G) water.

Abstract: A lead for painting includes a water-insoluble lead basic mass in which a water-soluble dye is present. A method of painting with a lead is also provided.

Abstract: The invention relates to a polymer-bonded pencil lead for writing, drawing or painting devices, in particular for lead pencils or colored pencils, comprising a polymer binder, at least one wax and at least one filler, wherein the pencil lead further comprises 0.1 to 5 wt.-% palm oil.

Abstract: The invention provides a process for producing a crayon without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises dissolving and dispersing carbon black and a resin component in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating, pouring the obtained raw material solution into a molding container, and then cooling and solidifying the solution, wherein carbon black having an average particle diameter of primary particles of 20 to 100 nm is used as the carbon black.

Abstract: A polymeric material comprised of (i) at least one random copolymer comprised of ethylene oxide and one or more other alkylene oxide(s) and (ii) at least one non-random polymer comprised of one or more poly(alkylene oxide)s has been discovered. Preferably, it is a polymer alloy. Alkylene oxide homopolymers or block copolymers may be the non-random polymer. In a related discovery, an adhesive material can be made by suspending (a) particles in (b) a matrix of at least one poly(ethylene oxide) copolymer of ethylene oxide and propylene oxide, or a combination thereof. The handling characteristics may be adjusted for different utilities (e.g., from runny oil to hard wax). Applications include use as adhesive, cohesive, filler, lubricant, surfactant, or any combination thereof. In particular, the hard materials may be used for cleaning or waxing.

Abstract: The invention provides a crayon which comprises an alternative plasticizer in place of the conventional phthalate ester plasticizers and yet provides writings excellent in water resistance, the crayon comprising a colorant, a gelling agent, an organic solvent, a resin component, and a plasticizer, wherein the plasticizer is at least one selected from diisononyl adipate, acetyltributyl citrate, 1,2-cyclohexanedicarboxylic acid diisononyl, and alkylsulfonic acid phenyl ester and is contained in an amount of 1 to 20% by weight based on the crayon.

Abstract: The invention relates to aqueous pigment preparations containing (A) at least one organic and/or inorganic pigment, (B) a dispersant of formula (I) or (II), or mixtures of the dispersants of formulas (I) and (II), (C) optionally wetting agents, (D) optionally other surfactants and/or dispersants, (E) optionally one or more organic solvents or one or more hydrotropic substances, (F) optionally other additives used conventionally for the production of aqueous pigment dispersions and (G) water.

Abstract: The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises: dissolving and dispersing a resin component, carbon black having a pH of less than 5.0 and an organic amine in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution, pouring the raw material solution into a molding container, and cooling and gelling the raw material solution.

Abstract: The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises: dissolving and dispersing a resin component and carbon black having a pH of not less than 5.0 in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution, pouring the raw material solution into a molding container, and cooling and gelling the raw material solution.

Abstract: The invention provides a process for producing a crayon without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises dissolving and dispersing carbon black and a resin component in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating, pouring the obtained raw material solution into a molding container, and then cooling and solidifying the solution, wherein carbon black having an average particle diameter of primary particles of 20 to 100 nm is used as the carbon black.

Abstract: The invention provides a crayon having excellent feel when writing while having high gel hardness. The crayon comprises a colorant, a gelling agent, an organic solvent and a resin component, wherein the gelling agent is at least one selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof, and the resin component comprises a combination of polyvinyl butyral resin having an average degree of polymerization of less than 350 and polyvinyl butyral resin having an average degree of polymerization of 350 or more.

Abstract: With respect to the metal colloid of the present invention, metal colloidal particles capable of forming a metal colloid by dispersing in either or both of an aqueous dispersion medium and a nonaqueous dispersion medium in a predetermined proportion while mixing, comprise metal particles and a protective agent coordination-modified on the surface of the particles, the protective agent having a carbon skeleton containing either or both of sulfur and oxygen in the molecule, and having a structure of being coordination-modified on the surface of the metal particles using an atom or an atomic group of either or both of sulfur and oxygen as an anchor, wherein the protective agent has one, or two or more functional groups selected from the group consisting of alkoxysilyl group, silanol group and hydroxyalkyl group in a molecular structure.

Abstract: Disclosed is an erasable colored pencil lead composition comprising, in an embodiment, a colorant, one or more binder resins, an antioxidant, a fibrillatable or fibrillated material, and a filler. Also disclosed is a colored pencil lead composition which produces marks on paper, which are easily erased by ordinary pencil eraser. The mark made using the composition has a cohesive nature that assists in the removal from paper in sheet or film like sections by the use of an ordinary pencil eraser without smearing or leaving a residue. In a preferred embodiment, the composition is free or substantially free of low melting waxes or waxy materials. The colored pencil lead composition may further include a lubricant. Also disclosed is a method for using a colored pencil lead composition.

Abstract: A water-based solid marking composition comprises water, a humectant and a solidifying agent present in the weight ratio of 2˜3:1˜2:1. A water-based marking instrument comprising the water-based solid marking composition includes a body surrounding the water-based solid marking composition, a packing for supporting the lower portion of the water-based solid marking composition and for assisting the transportation of the water-based solid marking composition, and a screw facing the packing so as to move the packing upwardly and downwardly, which have advantages in color miscibility, affinity to paper, usability, color tone, less sludge on paper and removal of stains on undesired sites, can render watercolor images using a crayon pastel, a crayon, a colored pencil or a marker, can prevent the composition from feeling sticky in a user's hands and conserves resources, and protects our environment.

Abstract: The invention relates to a colored lead or a colored chalk with a porous basic lead body, the primary components of which are a filler material and a non-ionic associative thickener, wherein the cavities in the porous basic lead body are filled with a solid or liquid phase.

Abstract: A composition for a pencil casing comprising 45-55% by weight polystyrene polymer or copolymer, 35-45% by weight wood fiber, 0-6% by weight lubricant, and 4-6% by weight compatibilizing agent. A preferred compatibilizing agent is polystyrene maleic anhydride. The preferred polystyrene is acrylonitrile butadiene styrene. The preferred lubricants are selected from aluminum stearate, calcium stearate, and zinc stearate, with zinc stearate the most preferred. The invention may optionally include 0-5% by weight polyethylene terephthalate and 0-5% by weight polyethylene. Also included are a pencil casing made from the composition and a pencil made from the composition.

Abstract: The present invention provides an erasable colored pencil lead composition comprising a colorant, one or more binder resins, a fibrillatable or fibrillated material, and a filler. The colored pencil lead of the present invention produces marks on paper, which are easily erased by ordinary pencil eraser. The mark made using the composition has a cohesive nature that assists in the removal from paper in sheet or film like sections by the use of an ordinary eraser without smearing or leaving a residue. In a preferred embodiment, the composition is free or substantially free of low melting waxes or wax like materials. Examples of suitable binder resins include high density polyethylene, low density polyethylene, polypropylene, and high melting waxes. Examples of fibrillated or fibrillatable materials include fibrillatable or fibrillated polytetrafluoroethylene and ethylene-vinyl acetate copolymer. The colored pencil lead composition may further include a lubricant.

Abstract: A simplified method for producing a lead for color pencils, cosmetic pencils and colored chalk with good down stroke behavior involves mixing powdered or granular base materials containing a thermolabile, polymeric binding agent, inorganic filler materials and a coloring agent with water and then extruding the mixed materials to form raw leads, which extruded material is subsequently heat treated at the binding agent decomposition temperature for a time sufficient to partially decompose the binding agent. Enough water is mixed with the base material to achieve a lead mass of approximately 5 parts by weight of base material and 1 part by weight of water.

Abstract: The present invention provides an erasable colored pencil lead composition comprising a colorant, one or more binder resins, a fibrillatable or fibrillated material, and a filler. The colored pencil lead of the present invention produces marks on paper, which are easily erased by ordinary pencil eraser. The mark made using the composition has a cohesive nature that assists in the removal from paper in sheet or film like sections by the use of an ordinary eraser without smearing or leaving a residue. In a preferred embodiment, the composition is free or substantially free of low melting waxes or wax like materials. Examples of suitable binder resins include high density polyethylene, low density polyethylene, polypropylene, and high melting waxes. Examples of fibrillated or fibrillatable materials include fibrillatable or fibrillated polytetrafluoroethylene and ethylene-vinyl acetate copolymer. The colored pencil lead composition may further include a lubricant.

Abstract: The present invention provides an erasable colored pencil lead composition comprising a colorant, one or more binder resins, a fibrillatable or fibrillated material, and a filler. The colored pencil lead of the present invention produces marks on paper which are easily erased by ordinary pencil eraser. The mark made using the composition has a cohesive nature which assists in the removal from paper in sheet or film like sections by the use of an ordinary eraser without smearing or leaving a residue. In a preferred embodiment, the composition is free or substantially free of low melting waxes or wax like materials. Examples of suitable binder resins include high density polyethylene, low density polyethylene, polypropylene, and high melting waxes. Examples of fibrillated or fibrillatable materials include fibrillatable or fibrillated polytetrafluoroethylene and ethylene-vinyl acetate copolymer. The colored pencil lead composition may further include a lubricant.

Abstract: A water-based coloring composition suitable for use in children's markers comprising a carrier, submicron polymeric particles, and a neutral buoyancy additive. The coloring compositions produce unique opaque images on a wide variety of writing surfaces. Additionally, the invention includes a water-based dry erase coloring composition suitable for use in children's markers comprising a carrier, submicron polymeric particles, a neutral buoyancy additive, and a release agent.

Abstract: A solid fritted bonding material consisting essentially of a blended wax composition and a powder is provided. The solid fritted bonding material is used to secure at least two articles together by applying the solid fritted bonding material to mating surfaces of each article; joing the mating surfaces of each article together; and heating the joined articles to a temperature wherein the blended wax composition burns away and the powder becomes activated to form a permanent bond between each article.

Abstract: The present invention provides a colored pencil lead composition comprising a colorant, one or more binder resins, a fibrillatable or fibrillated material, a non-fibrillatable particulate lubricant, and a filler. An example of a suitable binder resin is high density polyethylene, and an example of a fibrillated or fibrillatable material is fibrillatable polytetrafluoroethylene. An example of a non-fibrillatable particulate lubricant is micronized polytetrafluoroethylene. The colored pencil lead of the present invention produces marks on paper which are easily erased by ordinary pencil eraser. The present invention further provides a process for preparing the colored pencil lead of the present invention comprising compounding the colorant, the binder resin or resins, the fibrillatable or fibrillated material, the non-fibrillatable particulate lubricant, and the filler to obtain a blend and forming the pencil lead from the blend.

Abstract: A solid, air stable adhesive composition containing wax and a polyolefin having a viscosity no greater than 2,000 centipoise and a needle penetration hardness of at least 50 dmm is disclosed. It is further disclosed that propylene-ethylene copolymer is the preferred polyolefin of the present invention.

Abstract: An aqueous-based erasable ink composition suitable for use in highlighters and other writing instruments includes a styrene-butadiene copolymer and a water-insoluble pigment. It preferably also includes a release agent and an anti-oxidant, and has a viscosity of between 10 cps and 30 cps.

Abstract: Baked pencil leads are disclosed herein which are prepared by kneading, extruding and baking a composition containing a graphite as a filler and a binder, wherein a degree of orientation .pi. of the graphite in the direction of an extrusion axis measured by X-ray diffraction is 0.85 or more and the resultant leads have a flexural modulus of 100 GPa or more and a bending strength of 320 MPa or more. The baked pencil leads can be manufactured by carrying out the extrusion so that back face pressure just above an extrusion nozzle may be 300 kg/cm or more and a shear rate at a time when the molten kneaded composition passes through the nozzle may be 5.times.10.sup.4 (1/sec) or more.

Abstract: By kneading a composition containing a filler and an organic forming binder, extruding the composition, baking the composition in a non-oxidizing atmosphere, there is obtained a first baked lead containing, as a binder, a carbon obtained by the carbonization of the organic forming binder. Then, by heating the first baked lead in an oxidizing atmosphere to remove the binder carbon, there is formed a second baked lead composed of at least the filler. The pores of the second baked lead are impregnated with a solution containing perhydropolysilazane, subjecting the lead to a heat treatment in an inert atmosphere or an ammonia gas atmosphere to form a third baked lead containing the resultant silicon nitride. Finally, ink is filled into the pores of the third baked lead to provide a baked color pencil lead.

Abstract: The glue crayons comprising acrylate polymers, tackified acrylate polymers, acrylate polymers containing specific, pendent, macromeric units, acrylate polymers containing high chain length alkyl (meth)acrylate monomers, acrylate polymers containing both macromeric and high chain length alkyl groups and acrylate polymers containing crystalline additives and includes (a) an acrylate-based adhesive polymer, (b) a tackifier; (c) a crystalline additive; and (d) at least one filler.

Abstract: An aqueous-based erasable ink composition suitable for use in highlighters and other writing instruments includes a styrene-butadiene copolymer and a water-insoluble pigment. It preferably also includes a release agent and an anti-oxidant, and has a viscosity of between 10 cps and 30 cps.

Abstract: A fluorescent color hard lead for color pencils and marking crayons includes a matrix comprised of at least one material selected from the group consisting of a fatty acid metal salt, a fatty acid ester, and a wax; a binder; and a filler which is aluminum silicate; and particles which are intimately mixed into the matrix and which are comprised of at least one synthetic polymer and at least one fluorescent dye with which the at least one synthetic polymer is dyed, the at least one synthetic polymer being selected from the group consisting of homopolymers from one monomer and copolymers from at least two monomers, the monomers being selected from the group consisting of acrylic acids, acrylates, acrylonitriles, and styrene, which monomers have been polymerized in an aqueous solution into which is added the at least one fluorescent dye to provide a dispersion, which dispersion is added to the matrix directly, wherein the dyed particles are uniformly distributed throughout the matrix whereby the fluorescent colo

Abstract: An improved pumpable anti-abrasion/slip ink additive is disclosed comprising a mixture of polytetrafluoroethylene and polyalphaolefin. As an alternative, additional material, such as phenolic resins and oils can be added to the mixture. The additives permit the less costly manufacture of printing inks, most particularly heat set inks and results in print which has improved rub, slip and anti-mar characteristics.

Abstract: Baked pencil leads in which a filler such as flaky graphite is oriented in a concentric tubular form in an outer peripheral portion of each lead and which has one or more layers spaced in a radial direction from the outer peripheral portion and comprising the filler oriented in the concentric tubular form between the central portion and the outer peripheral portion of each lead and in which the filler is at random or radially oriented in the other portions of each lead.The baked pencil leads can be obtained by the use of a plurality of concentric conical tubular straightening plates having the sectional area of a flow path continuously decreased toward a nozzle orifice, in extruding a kneaded material mainly comprising the filler and a binder.In the baked pencil leads, strength can be remarkably improved without lowering density, and thus these baked pencil leads are excellent in the balance between the strength and the density.

Abstract: An erasable marking composition comprising a noncarboxylated styrene-butadiene copolymer resin, a colorant, and a solvent. The composition can be applied to substrates by a variety of delivery means, such as porous-tipped and brush-tipped writing instruments, as well as brushes, and can be easily erased with a substantially nonabrasive eraser, such as a common pencil eraser, for an extended period of time.

Abstract: A rigid fiberboard suitable as a replacement for the natural woods presently used for the manufacture of pencils is provided. The fiberboard essentially comprises a fiber network, together with a filler and binder. A lubricant is added to improve the sharpening characteristics of the fiberboard, and dimensional stability is preserved by incorporating a waterproofing agent to minimize the absorption of water by the fiber network.

Abstract: This invention relates to thermoplastic, pressure-sensitive solid adhesives capable of transferring an adhesive film to a substrate by friction rubbing of the adhesive on the substrate. The adhesives of this invention consist essentially of polyisobutylene, wax and optionally an adhesive promoter resin. Said ingredients are within certain proportions, molecular weights, melting points, or hardness values.

Abstract: An erasable highlighting composition is provided including a block copolymer, a wax, and a fluorescent pigment. The composition is in solid form, and, when applied to an underlying marking on a substrate, is capable of forming a highlighting marking which may be erased without lifting the underlying marking.

Abstract: Correction stick comprising a gelatinizer, white pigments, dispersant, water-soluble or dispersible film-forming resin and a gelation modifier, said gelatinizer being alkali metal salts or ammonium salts of aliphatic carboxylic acids having carbon atoms of 8 to 36 and said gelation modifier being organic or inorganic salts which form univalent metallic positive ion in an aqueous solution such as sodium or potassium positive ion or sequestering agents or the mixture thereof with the organic or inorganic salts.

Abstract: This invention relates to water soluble crayon compositions which are comprised of (i) one or more water soluble block polymers characterized by an ABCBA structure and (ii) a coloring agent, and to crayons produced therefrom. This invention also relates to processes for the production of water soluble crayon compositions and for the manufacture of crayons.