Glass Enamel Composition Or Process Of Preparing Patents (Class 523/170)
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Patent number: 10809427Abstract: An infrared-absorbing composition according to the present invention includes: an infrared absorber formed by a phosphonic acid represented by the following formula (a) and copper ion; and a phosphoric acid ester allowing the infrared absorber to be dispersed. The phosphoric acid ester includes at least one of a phosphoric acid diester and a phosphoric acid monoester. R1 is a phenyl group or a phenyl group in which at least one hydrogen atom is substituted by a halogen atom. When molar contents of the phosphonic acid, the copper ion, and the phosphoric acid ester are respectively defined as CA mol, CC mol, and CE mol and a total molar content of reactive hydroxy groups is defined as CH mol, the relations CA/CE<1 and CH/CC>1.95 are satisfied.Type: GrantFiled: April 19, 2017Date of Patent: October 20, 2020Assignee: NIPPON SHEET GLASS COMPANY, LIMITEDInventors: Yuichiro Kubo, Katsuhide Shimmo
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Patent number: 9375927Abstract: An apparatus for digital printing on articles (2), comprises a drum (3) rotatable about a central axis (C), carrying piece-holder elements (4) circumferentially distributed around said central axis (C) and each configured for carrying an article (2) being processed. The drum (3) rotates to transfer the piece-holder element (4) through printing stations (9) carrying printheads (10), each operating according to a printing area (15) of predetermined length (L), to create a printing pattern (M) on a side surface (2a) of each article (2), driven in rotation around its own axis (X). Auxiliary movement devices (21) shift the printhead (10) parallel to the main extension direction (D) of the printing area to allow the articles to be processed having an extension greater than the length of the printing area (15). It is also described a printing process implemented by the apparatus.Type: GrantFiled: June 25, 2015Date of Patent: June 28, 2016Assignee: TAPEMATIC S.P.A.Inventor: Luciano Perego
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Patent number: 9352594Abstract: Articles each having a reference mark located around a respective extension axis, are loaded on piece-holder assemblies distributed around a central axis of a rotatable drum, and each including a pair of spindles operable in rotation by a same motor, each around a respective longitudinal axis. The drum rotates about said central axis to transfer said piece-holder assembly to a printing station, where a printing pattern is formed on a side surface of each article driven in rotation by the respective spindle. Before transferring to the printing station, at least one of the articles is oriented around the respective spindle, to place the reference marks of the articles along a same angular orientation around the respective extension axes.Type: GrantFiled: June 30, 2015Date of Patent: May 31, 2016Assignee: TAPEMATIC S.P.A.Inventor: Luciano Perego
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Patent number: 9199343Abstract: An apparatus (1) for the surface treatment of objects (2), comprising a drum (3) having a peripheral zone (3b); a plurality of gripping elements (4) disposed in the peripheral zone (3b) of the drum (3) and configured to each receive a respective object (2) to be treated; printing means (5) associated with the drum (3) and comprising at least one print head (6), the head (6) being positionable in front of the gripping elements (4) in order to print on an object (2); the printing means (5) are configured to print on a lateral surface (2a) and on a base surface (2b) of the caps (2) on the same drum (3).Type: GrantFiled: December 12, 2013Date of Patent: December 1, 2015Assignee: TAPEMATIC S.P.A.Inventor: Luciano Perego
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Patent number: 8329779Abstract: The invention relates to a translucent or transparent, colored enamel that contains metal nanoparticles that lost their natural tendency to aggregate with each other, and having a color essentially provided by the reflection of light. The nanoparticles have lost their natural capability to aggregate with each other due to the application of a coating, or because they have been functionalised electrostatically or using highly sterically hindered entities or using hydrophilic entities located at the surface thereof. The nanoparticles may be gold nanoparticles that impart an intense and deep red to said enamel.Type: GrantFiled: September 20, 2010Date of Patent: December 11, 2012Assignee: Rolex S.A.Inventors: Michele Reigner, Olivier Pujol
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Publication number: 20110009525Abstract: The invention relates to a translucent or transparent, coloured enamel that contains metal nanoparticles that lost their natural tendency to aggregate with each other, and having a colour essentially provided by the reflection of light. The nanoparticles have lost their natural capability to aggregate with each other due to the application of a coating, or because they have been functionalised electrostatically or using highly sterically hindered entities or using hydrophilic entities located at the surface thereof. The nanoparticles may be gold nanoparticles that impart an intense and deep red to said enamel.Type: ApplicationFiled: September 20, 2010Publication date: January 13, 2011Applicant: ROLEX S.A.Inventors: Michèle Reigner, Olivier Pujol
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Publication number: 20090197026Abstract: This composition for treating the surface of a glass-ceramic, especially in plate form, flat glass or hollowware, or glass in the form of fibers, is able to be applied as a thin coating to said glass-ceramic or said glass.Type: ApplicationFiled: June 15, 2005Publication date: August 6, 2009Applicant: EUROKERA S.N.C.Inventors: Pablo Vilato, Marie-Héléne Rouillon, Caroline Faillat, Sophie Besson, Stéphane Lohou, Olivier Gaume, Didier Le Couviour
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Patent number: 7524924Abstract: Disclosed herein is a process to produce a film comprising poly(vinyl alcohol), wherein the poly (vinyl alcohol) solution has been purified utilizing an ion exchange resin. An approximate 50 micrometer thick film produced from the purified aqueous poly(vinyl alcohol) solution has an APHA color value of 50 or less after the film has been heated at 150° C. for 60 minutes.Type: GrantFiled: April 10, 2008Date of Patent: April 28, 2009Assignee: Celanese International CorporationInventor: Bret F. Hann
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Publication number: 20090053534Abstract: Coating compositions, articles having a coating layer and an enamel layer applied thereto, enamel systems and processes for applying a coating to a glass composite are described. According to one or more embodiments, the coating composition comprises a refractory particulate material in an amount at least about 30% by weight. In other embodiments, the coating composition has an average particle size of less than about 30 ?m. In yet other embodiments, the coating composition can be applied to a glass composite having a layer of enamel disposed on the second surface, using a single firing step.Type: ApplicationFiled: August 21, 2007Publication date: February 26, 2009Inventor: Robert Prunchak
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Publication number: 20090030113Abstract: The invention relates to new universal pigment preparations having very good thermal stability and weathering stability as virtually foam-free aqueous, solventborne, and solvent-free pigment preparations and to their use in aqueous, solventborne or solvent-free coating materials, such as paints, adhesives, inks, including printing inks, and for coloring plastics.Type: ApplicationFiled: November 3, 2006Publication date: January 29, 2009Applicant: Evonil Degussa GmbHInventors: Patrick Glockner, Evelny Albrecht, Andreas Stuttgen, Andreas Wenning
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Publication number: 20080213210Abstract: Disclosed herein is a process to produce a film comprising poly(vinyl alcohol), wherein the poly (vinyl alcohol) solution has been purified utilizing an ion exchange resin. An approximate 50 micrometer thick film produced from the purified aqueous poly(vinyl alcohol) solution has an APHA color value of 50 or less after the film has been heated at 150° C. for 60 minutes.Type: ApplicationFiled: April 10, 2008Publication date: September 4, 2008Inventor: Bret F. Hann
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Patent number: 5714420Abstract: A ceramic enamel composition consists of an oxide frit, a bismuth silicate seed material, a pigment, and a vehicle. A preferred bismuth silicate seed material is selected from crystalline Bi.sub.12 SiO.sub.20, Bi.sub.4 (SiO.sub.4).sub.3, and Bi.sub.2 SiO.sub.5, and mixtures thereof. Upon firing a glass substrate coated with the enamel, components of the enamel adhere to the substrate. The glass can be formed with a die to a desired shape with reduced sticking of the coated region to the die. The ceramic enamel is particularly useful in providing a colored border around automotive glass, which enhances appearance and reduces degradation of adhesives by ultraviolet radiation.Type: GrantFiled: December 8, 1995Date of Patent: February 3, 1998Assignee: Cerdec Corporation - Drakenfeld ProductsInventors: George E. Sakoske, Joseph W. Ryan
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Patent number: 5422384Abstract: The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.Type: GrantFiled: November 25, 1992Date of Patent: June 6, 1995Assignee: Battelle Memorial InstituteInventors: W. D. Samuels, Gregory J. Exarhos
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Patent number: 5095086Abstract: An improved coating composition suitable for concealing scuff marks on glass articles is provided, comprising by weight (A) from about 70 to about 100 percent of a composition comprising by weight (1) from about 50 to 75 percent of an organooxy-chainstopped organopolysilsequioxane having a viscosity of from about 5 to about 1000 centipoise at 25.degree. C., (2) from about 5 to about 15 percent of tetraorganotitanate, (3) from about 0 to about 25 percent of an organotriorganooxysilane, and (4) from about 0 to about 15 percent of a carboxylic acid ester, and (B) from about 0 to about 30 percent of a volatile diluent. The coating formed from this composition has improved cure rate and masks wet bottles uniformly and completely.Type: GrantFiled: August 8, 1990Date of Patent: March 10, 1992Assignee: General Electric CompanyInventors: Prakash K. Pawar, Frank J. Traver
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Patent number: 4749592Abstract: A grouting composition for sealing structures to inhibit water leakage therethrough and for stabilizing soil is provided. The composition is provided as a two-part system. Part A is an aqueous solution of a hydrophililc, water soluble prepolymer having a polyether backbone and terminal active olefinic groups, the olefinic groups being connected to the polyether backbone by linking groups selected from --NH--, --CONH--, --OCONH--, and --NHCONH--, and tertiary amine catalyst. Part B is an aqueous solution of a initiator. Parts A and B are mixed and react to form a gel.Type: GrantFiled: September 11, 1986Date of Patent: June 7, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alton J. Gasper, Charles D. Wright
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Patent number: 4552915Abstract: A low-temperature sintered porcelain composition suitable for forming in which at least one of polystyrene, polyethylene and polypropylene, butyral resin, lubricant and, if required, a plasticizer are mixed in respective predetermined amounts with a mixture consisting of a vitreous composition, aluminum oxide, clay component and a binder, and a low-temperature sintered porcelain composition which further contains an acrylic resin in addition to the above components.Type: GrantFiled: March 27, 1984Date of Patent: November 12, 1985Assignee: Nippon Kouatsu Electric Co.Inventors: Toshio Fujita, Kazuhiro Watanabe
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Patent number: 4429007Abstract: An electromagnetic coil for high temperature and high radiation application in which glass is used to insulate the electrical wire. A process for applying the insulation to the wire is disclosed which results in improved insulation properties.Type: GrantFiled: October 21, 1981Date of Patent: January 31, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: George J. Bich, Tapan K. Gupta