Pavement Or Sign Marking Or Reflex Reflecting Composition Or Process Of Preparing Patents (Class 523/172)
  • Patent number: 6011085
    Abstract: A yellow, hot melt alkyd traffic marking composition is described. The yellow, hot melt alkyd traffic marking composition contains 10-25 percent by weight of a hot melt alkyd binder, 5-10 percent by weight of a thermally stable 1,5- or 1,8-substituted anthraquinone colorant selected from a 1,5- or 1,8-substituted anthraquinone aromatic thioether and a 1,5- or 1,8-substituted anthraquinone aromatic thioether polyester, and 65-85 weight percent of a filler. The yellow, hot melt alkyd traffic marking composition of the invention may also contain other components used in traffic marking compositions, such as a reflectivity aid, a plasticizer, or an impact modifier. Other optional components are discussed below. The yellow, hot melt alkyd traffic marking compositions may be applied to any paved surface.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: January 4, 2000
    Assignee: Eastman Chemical Company
    Inventors: Brian E. Maxwell, Max A. Weaver, Gary R. Robe, Richard A. Miller
  • Patent number: 6005024
    Abstract: The present invention pertains to novel durable, tough, transparent, luminescent overlay compositions, useful for highlighting and/or illuminating and preserving surfaces and markings thereupon, such as roadways/highways, pedestrian passageways, airport runways, traffic control surface markings on travelways such as those listed above, traffic control devices/signs, structures, and articles. The clear compositions contain a moisture sensitive luminescent substance (for example, a phosphorescent substance having increased brightness and longer lasting afterglow) and an epoxy resin which imparts moisture stability to the luminescent substance, and durability and longer life to the underlying markings, surface area, structure or article.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: December 21, 1999
    Inventors: Irving Anders, Bruce Anders
  • Patent number: 5980664
    Abstract: A substantially permanent pavement marking system using a polymer modified cement material to provide a raised marking that extends above the surface of the pavement. The lines are formed by taping off the desired outline shape of the marking. The pavement marking material is of such a consistency that it will set up to form a thick layer and not flow over the tape and will harden forming a raised marking.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: November 9, 1999
    Inventor: Jack H. Wilson, Sr.
  • Patent number: 5973028
    Abstract: A yellow, hot melt adhesive traffic marking composition is described. The yellow, hot melt adhesive traffic marking composition contains 10-25 percent by weight of a hot melt adhesive binder, 5-10 percent by weight of a thermally stable 1,5- or 1,8-substituted anthraquinone colorant selected from a 1,5- or 1,8-substituted anthraquinone aromatic thioether and a 1,5- or 1,8-substituted anthraquinone aromatic thioether polyester, and 65-85 weight percent of a filler. The yellow, hot melt adhesive traffic marking composition of the invention may also contain other components used in traffic marking compositions, such as a reflectivity aid, a plasticizer, or an impact modifier. Other optional components are discussed below. The yellow, hot melt adhesive traffic marking compositions may be applied to any paved surface.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: October 26, 1999
    Assignee: Eastman Chemical Company
    Inventors: Brian E. Maxwell, Max A. Weaver, Gary R. Robe
  • Patent number: 5972421
    Abstract: A method for producing a pelletized pavement marking mixture includes selecting an appropriate thermoplastic binder that is a solid at ambient temperatures and heating the appropriate thermoplastic binder in a reaction vessel to a temperature sufficient to form a liquid thermoplastic binder; forming a heated pavement marking mixture by adding a plasticizer and a filler to the liquid thermoplastic binder in the reaction vessel; forming a substantially homogeneous pavement marking mixture by blending the heated pavement marking mixture for period sufficient to substantially evenly distribute the plasticizer and the filler within the liquid thermoplastic resin while maintaining the heated pavement mixture at an elevated temperature; extruding the substantially homogeneous pavement marking mixture from the reaction vessel to form an extruded substantially homogeneous pavement marking mixture; and pelletizing the extruded substantially homogeneous pavement marking mixture.
    Type: Grant
    Filed: November 12, 1998
    Date of Patent: October 26, 1999
    Assignee: Stimsonite Corporation
    Inventor: Walter Brian Finley
  • Patent number: 5947632
    Abstract: A water-borne road marking paint is characterized in that incorporated within the paint are particles of a solid polymer or inorganic compound, which are capable of absorbing water. Preferred particles are ion exchange resin beads. Incorporation of such particles either during or immediately after application of the paint results in an accelerated speed of drying of the paint on the road.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: September 7, 1999
    Assignee: Rohm and Haas Company
    Inventors: Marico Giuseppe Pirotta, Angelo Sanfilippo, Andrew Paul Trapani
  • Patent number: 5948833
    Abstract: A water-borne road marking paint composition which includes a chelating agent capable of chelating iron ions to form a substantially colorless complex is provided. A road marking produced from the traffic paint of the present invention substantially reduces or prevents yellowing of white road marking from iron and iron compound debris strewn on the road surfaces. A method of reducing or preventing yellowing of a newly-applied road marking on a road surface of a water-borne road marking paint is also disclosed. The method comprises incorporating in the water-borne road marking paint a chelating agent capable of chelating iron ions to form a substantially colorless complex. Further reduction of yellowing of the road marking is observed when a pigment dispersant is incorporated in the water-borne road marking paint.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: September 7, 1999
    Assignee: Rohm and Haas Company
    Inventors: Josef Hans Jilek, Angelo Sanfilippo, Donald Craig Schall, Andrew Paul Trapani
  • Patent number: 5922398
    Abstract: Disclosed are aqueous coating compositions containing a latex having pendant amine-functional groups, wherein such latex has a Tg greater than about 0 .degree. C. and is capable of film formation at application temperatures, and an amount of base sufficient to raise the pH of the composition to a point where essentially all of the amine functional groups are in a non-ionic state. Also disclosed are methods for producing fast drying coatings on suitable substrates by application of such coatings, where such coatings develop early water-resistance.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: July 13, 1999
    Assignee: Rohm and Haas Company
    Inventors: Ann Robertson Hermes, Alvin Charles Lavoie, Donald Craig Schall
  • Patent number: 5880176
    Abstract: A fluorescent marking composition containing particles of an organic material which has a glass transition temperature of at least 30.degree. C. and an average particle size of at least 30 nm, and emitting fluorescence in a visible light range, or absorbing infrared light having a wavelength of at least 700 nm and emitting a light in an infrared wavelength range, which composition is excellent in dispersion stability, light resistance, and heat and light resistance, and provides a mark which does not bleed.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: March 9, 1999
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Takanori Kamoto, Yoshinori Yamamoto, Toshinobu Sueyoshi
  • Patent number: 5874491
    Abstract: The present invention relates to novel compositions useful, for example, in marking road surfaces. The compositions contain a moisture sensitive luminescent substance (for example a phosphorescent substance having increased brightness and longer lasting afterglow) and an epoxy resin or a polyurethane resin which is water miscible or soluble, and which impart moisture stability to the luminescent substance. The luminescent substance-resin mixtures may be mixed with water-based highway paints. As a result, these novel compositions impart an extended road surface life, and are environmentally friendly because they do not contaminate the surrounding environment with organic hydrocarbon products via vaporization or runoffs. In addition these compositions may be used both indoors and outdoors for nighttime marking and in other marking applications.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: February 23, 1999
    Inventor: Irving Anders
  • Patent number: 5861188
    Abstract: The present invention is directed to traffic paint compositions, which dry faster than conventional waterborne traffic paints and to a method of producing traffic paint road markings made therefrom. The traffic paint composition of the present invention includes a blend of an anionically stabilized polymer binder, a polyfunctional amine polymer having an amine and an acid functionality therein and an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine polymer is in a non-ionic state. The traffic paint composition of the present invention further provides improved storage stability.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: January 19, 1999
    Assignee: Rohm and Haas Company
    Inventors: Donald Craig Schall, Steven Scott Edwards
  • Patent number: 5858545
    Abstract: Free-radically polymerizable release coating compositions containing conductivity enhancers, which are capable of being electrosprayed onto a substrate. The compositions comprise (a) about 100 parts by weight of one or more free-radically polymerizable vinyl monomer(s), (b) from about 0.05 to about 250 parts by weight of one or more polydiorganosiloxane polymer(s) copolymerizable with the vinyl monomer(s), and (c) from about 0.10 to about 10 parts by weight, based on 100 parts by weight of (a) and (b), of one or more non-volatile conductivity enhancer(s), which are soluble in the monomer(s) and which do not interfere with polymerization, wherein the composition may be electrosprayed.The composition may further comprise from about 0.1 to about 5 parts by weight of one or more initiator(s) based on 100 parts by weight of monomer(s) and polydiorganosiloxane polymer(s).Another embodiment of the present invention further comprises at least 0.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: January 12, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Albert I. Everaerts, Mieczyslaw H. Mazurek, Albert E. Seaver
  • Patent number: 5853615
    Abstract: The present invention relates to a fluorescent covering for roads, parking areas and the like. The covering has a binder which fluoresces at the same energy as an organic optical whitener, thereby more uniformly dispersing energy and prolonging the life of the whitener.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: December 29, 1998
    Assignee: Cleanosol International AB
    Inventor: Jorn Arne Suhr
  • Patent number: 5736602
    Abstract: The present invention relates to a novel retroreflective coating composition which can be suitably applied to a metal substrate using a conventional coral coating process and apparatus. The retroreflective coating composition provides a retroreflective film upon application by coral coating without additional processing steps. The retroreflective coating composition is comprised of (a) 45 to 60% of a resin binder system and (b) 55 to 40% of reflective transparent glass microspheres having a refractive index of 2.1 to 2.5 and a diameter of 20 to 60 microns. The resin binder system is comprised of a thermosetting ethyl acrylate-styrene copolymer, cross-linking resin, aromatic volatile solvent, anti-gelling stabilizer, colloidal suspending agent, dibasic ester acetate, and cross-linking accelerator, and have a refractive index of 1.5 to 1.9. Hence, the novel retroreflective coating composition can provide a retroreflective article with less manufacturing steps and at a lower cost.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: April 7, 1998
    Inventors: George L. Crocker, Rickey L. Beam
  • Patent number: 5714527
    Abstract: A water-borne road marking paint composition which includes a chelating agent capable of chelating iron ions to form a substantially colorless complex is provided. A road marking produced from the traffic paint of the present invention substantially reduces or prevents yellowing of white road marking from iron and iron compound debris strewn on the road surfaces. A method of reducing or preventing yellowing of a newly-applied road marking on a road surface of a water-borne road marking paint is also disclosed. The method comprises incorporating in the water-borne road marking paint a chelating agent capable of chelating iron ions to form a substantially colorless complex. Further reduction of yellowing of the road marking is observed when a pigment dispersant is incorporated in the water-borne road marking paint.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: February 3, 1998
    Assignee: Rohm and Haas Company
    Inventors: Josef Hans Jilek, Angelo Sanfilippo, Donald Craig Schall, Andrew Paul Trapani
  • Patent number: 5665793
    Abstract: The present invention relates to novel compositions useful, for example, in water-based paints. The compositions contain a moisture sensitive luminescent substance (for example a phosphorescent substance having increased brightness and longer lasting afterglow) and a polyurethane resin which is water miscible or soluble, and which imparts moisture stability to the luminescent substance. As a result, this novel composition when used in, for example, water-based highway paints imparts an extended road surface life, and is environmentally friendly because it does not contaminate the surrounding environment with organic hydrocarbon products via vaporization or runoffs. In addition this paint composition may be used both indoors and outdoors for nighttime marking.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: September 9, 1997
    Inventor: Irving Anders
  • Patent number: 5595598
    Abstract: Disclosed herein is a met,hod for adjusting the consistency of concrete mix by adding an water-absorbing polymeric material or a thickening agent of carboxymethylcellulose to a fresh concrete mix.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: January 21, 1997
    Assignee: Taisei Rotec Co., Ltd.
    Inventors: Eiichi Yooda, Fumitaka Itoh
  • Patent number: 5544972
    Abstract: In the method for applying horizontal markings to road surfaces, a water-thinnable emulsion paint which is acid-coagulable is used and is brought into contact with an acid. This acid is scattered or sprayed onto or into the sprayed paint, the acid being in the form of an aqueous solution, a powder or particles wetted with acid. The method brings about drying within one or a few minutes. Using road-marking vehicles, horizontal markings can thus be put down with virtually no closing-off of the mobile operations site.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: August 13, 1996
    Assignee: Plastiroute S.A.
    Inventor: Peter C. Boldt
  • Patent number: 5472737
    Abstract: A water based luminescent highway or roadway paint composition that contains a fine powdered luminescent substance which does not require an organic solvent, a colored paint dispersion, and a polyurethane resin which is water compatible and which imparts an extended surface life under normal traffic conditions. The luminescent substance may be either a phosphorescent material or a combination of a phosphorescent and a fluorescent material. When the fluorescent material is present in the luminescent substance a daytime luminescence or reflectivity or coloration is produced in addition to the phosphorescence produced at night when light (head lights of an automobile) shine on the paint composition marking the median highway stripe or the highway edges.
    Type: Grant
    Filed: June 9, 1994
    Date of Patent: December 5, 1995
    Inventor: Irving Anders
  • Patent number: 5468795
    Abstract: Priming composition containing a homogeneous liquid solution containing a polymeric material and at least one water-miscible solvent in an amount sufficient to provide adhesion between wet or dry road surface materials and adhesive coated articles. The priming composition allows the marking of roadways with pressure sensitive adhesive articles even on wet or damp roadway surfaces. Also a method for priming roadway surfaces.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: November 21, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Harald Guder
  • Patent number: 5437907
    Abstract: Roadway traffic control marking tape and reflective sheeting are known in the art for providing temporary delineation and demarcation of traffic lanes in order to guide the flow of traffic through detours, construction areas and the like. Traffic channelizers and barricades are also well known in the art as barriers to discourage crossing the lanes onto the other side thereof. When work on highway lanes is completed, and traffic is redirected to newly opened lanes, the tape is generally removed. When it breaks during removal the job is particularly demanding. Damage to traffic channelizing devices which are hit by fast moving vehicles leads to their frequent replacement. Hence it has become desirable to recycle them. The recycling process requires that the reflective sheet first be removed. But the recycling process too has been hampered by the difficulty of sheet breaking during its removal.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: August 1, 1995
    Assignee: Flex-O-Lite, Inc.
    Inventors: Fred G. Peil, Herbert J. Kramer
  • Patent number: 5340870
    Abstract: A waterborne paint for traffic marking contains as an emulsion binder, a support polymer formed of styrene and acrylic acid monomers and having an acid value of between about 50 and about 250 and a hydrophobic emulsion polymer comprised of acrylic ester monomers and optionally including styrene monomers. The support polymer, in aqueous ammonia solution, acts as a surfactant, maintaining the emulsion polymer within micelles. Paints in accordance with the invention contain between about 10 and about 15 wt. percent of the emulsion polymer, between about 60 and about 75 wt. percent fillers or pigments and between about 9 and about 18 wt. percent water. Due to the high solids loading and low water content, the waterborne traffic marking paint is fast drying. Colored paints prefereably utilize banded pigments.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: August 23, 1994
    Assignee: Morton International, Inc.
    Inventors: David D. Clinnin, William G. Heiber, Ronald J. Lewarchik
  • Patent number: 5290833
    Abstract: An asphalt pavement material comprising an aggregate mixture of asphalt, gravel, sand and a pelletized composite of recycled rubber and thermoplastic material. The pelletized composite has a uniform size, smaller than the gravel and larger than the sand and is configured to fit within interstitial voids between the gravel. Sufficient pelletized composite is added to the asphalt pavement and mineral aggregate mixture (replacing mineral aggregate of comparable size) to substantially fill void spaces between the gravel.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: March 1, 1994
    Assignee: Carsonite International Corporation
    Inventor: Donald W. Schmanski
  • Patent number: 5256725
    Abstract: Polymerizable luminescent fluid composition, characterized by the fact that it contains by weight (a) 30 to 45% of one or more luminescent mineral pigments, (b) 10 to 30% of silica particles, having a diameter comprised between 7 and 1000 nm, not linked to each other by siloxane bonds, and (c) the complement to 100% of 2-hydroxy ethyl acrylate and/or 2-hydroxy ethyl methacrylate and use for obtaining luminescent compounds.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: October 26, 1993
    Assignee: Societe Francaise Hoechst
    Inventors: Armand Eranian, Eric Jacquinot
  • Patent number: 5169558
    Abstract: A two-part system and method for increasing the reflex-reflectivity of a substrate is disclosed wherein a first aerosol dispensing means containing a first coating composition capable of forming a base coating on a substrate and a second aerosol dispensing means containing a second coating composition capable of imparting reflex-reflectivity to the base coating is employed. The first coating composition comprises a binder resin and a solvent in which the binder resin is dissolved and the second coating composition contains transparent microspheres having a particle size from about 45 to about 90 microns and a carrier in which the transparent microspheres are dispersible. The substrate is coated first with the first coating composition via aerosol means to form a base coating which is subsequently coated with the second coating to impart reflex-reflectivity to the base coating.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: December 8, 1992
    Assignee: Fox Valley Systems, Inc.
    Inventors: Thomas J. Smrt, Abdul F. Khan
  • Patent number: 5057552
    Abstract: Flexible thermoplastic epoxy resins are prepared by reacting (1) an advanced epoxy resin prepared by reacting a mixture of an aromatic based epoxy resin and an aliphatic based epoxy resin with a polyhydric phenol in the presence of an advancement catalyst with (2) a monocarboxylic acid or anhydride thereof; reacting the resultant product with a mixture of an aromatic based epoxy resin and a monofunctional material reactive with vicinal epoxy groups; and reacting the resultant product with a carboxyl terminated elastomer. These resins are particularly useful in formulating pavement marking paints.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: October 15, 1991
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, David J. Duncan
  • Patent number: 5035920
    Abstract: A two-part system and method for increasing the reflex-reflectivity of a substrate is disclosed wherein a first aerosol dispensing means containing a first coating composition capable of forming a base coating on a substrate and a second aerosol dispensing means containing a second coating composition capable of imparting reflex-reflectivity to the base coating is employed. The first coating composition comprises a binder resin and a solvent in which the binder resin is dissolved and the second coating composition contains transparent microspheres having a particle size from about 45 to about 90 microns and a carrier in which the transparent microspheres are dispersible. The substrate is coated first with the first coating composition via aerosol means to form a base coating which is subsequently coated with the second coating to impart reflex-reflectivity to the base coating.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: July 30, 1991
    Assignee: Fox Valley Systems, Inc.
    Inventors: Thomas J. Smrt, Abdul F. Khan
  • Patent number: 4983458
    Abstract: A reflective marker for highway striping, signs and other surfaces is produced from a multiplicity of thermoplastic or thermosetting granules in the shape of tetrahedrons. A plurality of glass spheres having a diameter in the range of from about 6.0 microns to about 0.125 inches are substantially evenly dispersed throughout each granule with some of the spheres protruding through the outer granule surfaces. To form the granules the glass spheres, the granule material and a suitable pigment are mixed together and then applied to a flexible sheet or a roller containing a multiplicity of tetrahedron-shaped indentations. The mixture is urged into each of the indentations and is then cured. The resulting granules are removed from the indentations and are dropped from a random position onto a freshly painted highway line or other surface such that one of the flat faces on each granule is disposed in a downward direction.
    Type: Grant
    Filed: October 2, 1986
    Date of Patent: January 8, 1991
    Assignee: Potters Industries, Inc.
    Inventor: Robert Dejaiffe
  • Patent number: 4876295
    Abstract: Flexible thermoplastic epoxy resins are prepared by reacting (1) an advanced epoxy resin prepared by reacting a mixture of an aromatic based epoxy resin and an aliphatic based epoxy resin with a polyhydric phenol in the presence of an advancement catalyst with (2) a monocarboxylic acid or anhydride thereof; reacting the resultant product with a mixture of an armotic based epoxy resin and a monofunctional material reactive with vicinal epoxy groups; and reacting the resultant product with a carboxyl terminated elastomer. These resins are particularly useful in formulating pavement marking paints.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: October 24, 1989
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, David J. Duncan
  • Patent number: 4845135
    Abstract: Thermoplastic epoxy resins are prepared by (A) reacting an advanced epoxy resin prepared by reacting a mixture of (1) a relatively low equivalent weight aromatic based epoxy resin and (2) a (meth)acrylate polymer with (3) a dihydric phenol with (4) a monofunctional compound reactive with vicinal epoxide groups; and (B) mixing the product form (A) with the reaction product of (5) a relatively low equivalent weight epoxy resin and (6) a monofunctional compound reactive with vicinal epoxide groups. The resultant product is substantially free of residual epoxide groups. These resins are particularly useful in formulating pavement marking paints.
    Type: Grant
    Filed: August 25, 1988
    Date of Patent: July 4, 1989
    Assignee: The Dow Chemical Company
    Inventor: Michael B. Cavitt
  • Patent number: 4839198
    Abstract: A road marking composition is applied by applying (1) an aqueous dispersion of a film forming binder and (2) a water soluble salt. The process of the invention provides rapid drying, and the dried composition is not prone to smearing or adhesion of dirt.
    Type: Grant
    Filed: April 19, 1986
    Date of Patent: June 13, 1989
    Assignee: Akzo N.V.
    Inventors: Carolus J. M. Lonis, Klaas Nieuwenhuis
  • Patent number: 4837069
    Abstract: Procedure for making Al.sub.2 O.sub.3 spheroids, 600 micrometers in diameter or less, utilizes an AlOOH sol containing 0.25% weight percent MgO (in the form of Mg(NO.sub.3).sub.2 .multidot.6H.sub.2 O) and HNO.sub.3. The sol is dispersed into droplets in a particle forming fluid (e.g., 2-ethylhexanol) where gelling occurs. The gelled spheroids are collected, dried and pre-fired in air at temperatures less than 1,200.degree. C. for up to about 12 hours. The dried and prefired beads are fired in a 2-step process at temperatures of about 1,850-1,950.degree. C. in the following sequence:a first dry oxygen firing for about ten minutes, followed by a wet hydrogen firing for up to 350 minutes. Reasonably transparent microspheres having crystallites in the range of 5-100 micrometers are obtained with little intergranular porosity, and their density is estimated to be near theoretical.
    Type: Grant
    Filed: January 7, 1987
    Date of Patent: June 6, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Terrance L. Bescup, Benjamin T. Fellows, Charles J. Leedecke
  • Patent number: 4837248
    Abstract: Flexible thermoplastic epoxy resins are prepared by reacting (1) an advanced epoxy resin prepared by reacting a mixture of an aromatic based epoxy resin and an aliphatic based epoxy resin with a polyhydric phenol in the presence of an advancement catalyst with (2) a monocarboxylic acid or anhydride thereof; reacting the resultant product with a mixture of an aromatic based epoxy resin and a monofunctional material reactive with vicinal epoxy groups; and reacting the resultant product with a carboxyl terminated elastomer. These resins are particularly useful in formulating pavement marking paints.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: June 6, 1989
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, David J. Duncan
  • Patent number: 4812493
    Abstract: A two component water-based composition which cures in two stages, an initial rapid curing stage and a slower curing stage, comprising as the first component, a mixture of a polyaldehyde chosen from the group consisting of glyoxal glutaraldehyde and derivatives of glyoxal and gluteraldehyde, and a water dispersible component chosen from the group consisting of poxy resin emulsions which can be emulsified in water, synthetic latexes stable at about pH 7 or less, low molecular weight resin emulsions, epoxy ester emulsions, water emulsified alkyds, and cationic, anionic and non-ionic asphalt emulsions and, as the second component, the non-gel reaction product of N,N'-bis(methoxymethyl) uron and a polyamine chosen from a group consisting of primary and secondary amines and/or a monoamine.
    Type: Grant
    Filed: April 10, 1987
    Date of Patent: March 14, 1989
    Assignee: Adhesive Coatings Co.
    Inventor: Lowell O. Cummings
  • Patent number: 4797432
    Abstract: Thermoplastic epoxy resins are prepared by (A) reacting an advanced epoxy resin prepared by reacting a mixture of (1) a relatively low equivalent weight aromatic based epoxy resin and (2) a (meth)acrylate polymer with (3) a dihydric phenol with (4) a monofunctional compound reactive with vicinal epoxide groups; and (B) mixing the product from (A) with the reaction product of (5) a relatively low equivalent weight epoxy resin and (6) a monofunctional compound reactive with vicinal epoxide groups. The resultant product is substantially free of residual epoxide groups. These resins are particularly useful in formulating pavement marking paints.
    Type: Grant
    Filed: November 19, 1987
    Date of Patent: January 10, 1989
    Assignee: The Dow Chemical Company
    Inventor: Michael B. Cavitt
  • Patent number: 4755542
    Abstract: Flexible thermoplastic epoxy resins are prepared by reacting (1) an advanced epoxy resin prepared by reacting a mixture of an aromatic based epoxy resin and an aliphatic based epoxy resin with a polyhydric phenol in the presence of an advancement catalyst with (2) a monocarboxylic acid or anhydride thereof; reacting the resultant product with a mixture of an aromatic based epoxy resin and a monofunctional material reactive with vicinal epoxy groups; and reacting the resultant product with a carboxyl terminated elastomer. These resins are particularly useful in formulating pavement marking paints.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: July 5, 1988
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, David J. Duncan
  • Patent number: 4721743
    Abstract: A heat stable, non-thermoset epoxy resin composition is disclosed which comprises reacting (A) a mixture containing (1) a relatively high molecular weight epoxy resin and (2) a relatively low molecular weight epoxy resin with (B) a monohydric phenol, a monocarboxylic acid or anhydride thereof or a monohydric alcohol. The composition does not exhibit an excessive viscosity increase at elevated temperatures making it particularly suitable for use in highway marking paint applications.
    Type: Grant
    Filed: August 22, 1986
    Date of Patent: January 26, 1988
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, Christopher V. Beasley
  • Patent number: 4713404
    Abstract: A paint formulation for highway pavement marking is disclosed which comprises (I) a heat stable thermoplastic phenolic resin is prepared by (A) reacting (1) the reaction product of (a) at least one epoxy resin having an average of more than one vicinal epoxy group per molecule such as a diglycidyl ether of bisphenol A with (b) one or more polyhydric phenols such as bisphenol A; and optionally (2) one or more polyhydric phenols such as bisphenol A; with (B) a material having only one vicinal epoxy group per molecule such as the glycidyl ether of t-butyl phenol or mixture of such materials; in the presence of an effective quantity of a suitable catalyst such as ethyltriphenylphosphonium acetate acetic acid complex; and (II) at least one of (A) one or more pigments, (B) one or more dyes; (C) one or more fillers; or (D) any combination thereof.
    Type: Grant
    Filed: September 15, 1986
    Date of Patent: December 15, 1987
    Assignee: The Dow Chemical Company
    Inventor: Michael B. Cavitt
  • Patent number: 4690958
    Abstract: The inclusion of a substantially saturated dicarboxylic acid, anhydride or ester substituted with at least one hydrogen and carbon containing group of at least 30 carbon atoms and optionally an acidic C.sub.2 and/or C.sub.3 olefin polymer or copolymer of molecular weight 500 to 30,000 having an acid number from 30 to 300 wt. % of a resin in a resin based hot melt road marking formulation containing aggregate gives a formulation of improved colour and melt viscosity.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: September 1, 1987
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Olivier H. V. Lacoste, Alain De Regel, Hidenori Fujiwara, Raymond C. C. Yap
  • Patent number: 4672089
    Abstract: A retroreflective relatively flexible laminate sheet construction has a thermoplastic web with a smooth light-receiving first side and a second side coextensive with said first side. A retroreflective pattern is formed on the second side. A slurry of granular material is deposited on the second side to cover selected portions of the formed pattern with remaining portions of the formed pattern devoid of the granular material, and said slurry is dried or cured to produce a well-defined pattern. A layer of backcoating material is deposited on the second side to overlay the granular material, the backcoating material contacting the thermoplastic web where no granular material has been deposited, thereby encapsulating the granular material between the second side and the backcoating layer. An added, outer layer provides additional weather protection for the thermoplastic web. Methods are detailed to manufacture the laminate, and compositions of backcoating mixtures also are disclosed.
    Type: Grant
    Filed: March 4, 1985
    Date of Patent: June 9, 1987
    Assignee: Amerace Corporation
    Inventors: Robert M. Pricone, William N. Roberts
  • Patent number: 4613632
    Abstract: Ethylene-vinyl acetate copolymers having a melt index of 2,000 to 7,500 and containing from 10 to 22% vinyl acetate are useful in hot melt road marking compositions containing from 1 to 30% of the EVA copolymer; from 0 to 29% by weight of a binder resin; and from 0 to 5% by weight of a plasticizer, the balance of the composition typically comprising from 70 to 80% by weight of aggregates, made up of particulate materials such as sand and/or fillers and/or pigments such as calcium carbonate and titanium dioxide.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: September 23, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Giorgio Aliani, Jacques B. Lechat, Jozef A. F. Smits
  • Patent number: 4612152
    Abstract: A method for the production of a water-proofing sheet by mixing a thermoplastic rubber with asphalt, and then shaping the mixture directly into sheet having exhaust grooves on its surface.The vapor coming from water contained in foundation which is covered with the water-proofing sheet is exhausted through the grooves.
    Type: Grant
    Filed: October 29, 1984
    Date of Patent: September 16, 1986
    Assignee: Daiawa Kobunshi Kogyo Co., Ltd.
    Inventors: Kazuhisa Kawabata, Hirohide Kumabe, Shunzo Kawai
  • Patent number: 4436845
    Abstract: A traffic marking paint having an excellent drying property comprising a non-aqueous resin dispersion, a filler and a pigment. The traffic paint can be used with or without glass beads, and can be quickly dried without remaining the inside portion of the coated paint layer in the undried state.
    Type: Grant
    Filed: October 25, 1982
    Date of Patent: March 13, 1984
    Assignee: Toa Paint Co., Ltd.
    Inventor: Masao Kitano
  • Patent number: 4430464
    Abstract: An improved pavement binder composition comprises a digestion of rubber particles of low bulk density, preferably of the porous nodular surface morphological type, in a bituminous material.
    Type: Grant
    Filed: December 30, 1981
    Date of Patent: February 7, 1984
    Assignee: Australian Road Research Board
    Inventor: John W. H. Oliver
  • Patent number: 4429004
    Abstract: A light-reflecting body, in particular a car headlight, whose wall consists of a poly-(1,4-butylene terephthalate) which contains 10-60% by weight of a filler, having a particle size of at most 30 .mu.m, chosen from the group comprising kaolin, talc, mica, wollastonite, glass beads, zinc sulfide, lithopone, calcium sulfate and barium sulfate, onto which wall is applied a light-reflecting metal layer, if necessary over a previously applied lacquer layer.
    Type: Grant
    Filed: June 15, 1981
    Date of Patent: January 31, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Franz Breitenfellner
  • Patent number: 4419497
    Abstract: According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: December 6, 1983
    Assignee: Nippon Oil Company, Limited
    Inventors: Shozo Tsuchiya, Akio Oshima, Hideo Hayashi
  • Patent number: 4413067
    Abstract: According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below:GENERAL FORMULA (A): ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: November 1, 1983
    Assignee: Nippon Oil Company, Limited
    Inventors: Shozo Tsuchiya, Akio Oshima, Hideo Hayashi
  • Patent number: 4406704
    Abstract: Disclosed is a high solids single-package air-dryable primer containing about 15 to about 30% by weight air-dryable synthetic alkyd resin, about 10 to about 30% by weight organic solvents for the resin, at least about 0.4% by weight of a suspending agent, at least about 1 pbw of a polar additive for every pbw of the suspending agent, at least about 3% by weight of a coloring pigment, at least about 15% by weight of a corrosion inhibitor, at least about 0.3% by weight of a dryer, and about 30 to about 40% by weight of an extender pigment. The primer is prepared by mixing enough of the alkyd resin to wet the coloring pigment with enough of the solvent to optimize sheer. The suspending agent and polar additive are then added followed by the corrosion inhibitor and wetting agent. The coloring pigment is then added and the composition is ground to satisfactory particle size. Finally, the remaining ingredients are mixed in.
    Type: Grant
    Filed: April 16, 1982
    Date of Patent: September 27, 1983
    Assignee: Westinghouse Electric Corp.
    Inventor: Mark D. Troutman
  • Patent number: 4404316
    Abstract: A chemically modified asphalt prepared by reacting an asphalt with a polymerizable vinyl monomer (e.g., styrene) and a rubbery polymer including reclaimed rubber (either natural or synthetic) whereby the rubbery polymer is chemically integrated with the asphalt. The chemically modified asphalt compositions of the invention can be used in the treatment of glass fibers as well as in road paving applications and the like.
    Type: Grant
    Filed: November 3, 1981
    Date of Patent: September 13, 1983
    Assignee: Owens-Corning Fiberglas Corporation
    Inventors: Alfred Marzocchi, Michael G. Roberts, Charles E. Bolen, Edward L. Harrington
  • Patent number: 4403067
    Abstract: Sealant compositions, particularly for use in joints between adjacent concrete slabs and deck membranes are provided. The sealant compositions comprise the reaction product of a mixture consisting essentially of asphalt flux, styrene monomer and a vulcanizable rubber.
    Type: Grant
    Filed: April 12, 1982
    Date of Patent: September 6, 1983
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: William E. Uffner