Cable Filling Or Flooding Composition Or Process Of Preparing Patents (Class 523/173)
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Patent number: 11953746Abstract: Cables having buffer elements formed with two-dimensional fillers are described. A cable may include at least one optical fiber, and a buffer element may be formed around the at least one optical fiber. The buffer element may be formed from a material that includes a polyolefin resin, a filler added to the polyolefin resin that includes a plurality of two-dimensional particles, and a compatibilizer. A jacket may be formed around the at least one optical fiber and the buffer element.Type: GrantFiled: October 21, 2022Date of Patent: April 9, 2024Assignee: Superior Essex International Inc.Inventors: Bo Xu, Christopher W. McNutt
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Patent number: 11261272Abstract: A polyolefin composition comprising a polyolefin polymer, an alkenyl-functional monocyclic organosiloxane, and an organic peroxide; products made therefrom; methods of making and using same; and articles containing same.Type: GrantFiled: September 18, 2017Date of Patent: March 1, 2022Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Kainan Zhang, Yabin Sun, Jeffrey M. Cogen, Timothy J. Person
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Patent number: 11174408Abstract: A peroxide-curable polyolefin composition comprising a peroxide-curable polyolefin prepolymer, an organic peroxide, and 4-[[4,6-bis(octylthio)-1,3,5-triazin-2-yl]amino]-2,6-bis(1,1-dimethylethyl)-phenol. Also, a peroxide-cured polyolefin product prepared therefrom, methods of making and using same, and articles containing or made from same.Type: GrantFiled: November 27, 2017Date of Patent: November 16, 2021Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Manish Talreja, Jeffrey M. Cogen
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Patent number: 10632788Abstract: Provided are a rubber composition that achieves a balanced improvement in grip performance during the initial to late phases of running and abrasion resistance, and a pneumatic tire formed from the rubber composition. The present invention relates to a rubber composition containing a rubber component, sulfur, and a molten mixture of a solid resin and a plasticizer, the solid resin having an SP value of 9.2 to 13 and/or a softening point of 130° C. or higher, the plasticizer including at least one compound selected from the group consisting of phosphoric acid esters, phthalic acid esters, aliphatic polybasic acid esters, trimellitic acid esters, acetic acid esters, and ricinoleic acid esters, the solid resin being present in an amount of 1 part by mass or more per 100 parts by mass of the rubber component.Type: GrantFiled: April 11, 2016Date of Patent: April 28, 2020Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventor: Tatsuya Miyazaki
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Patent number: 10626265Abstract: The invention relates to a polymer composition with improved DC electrical properties, to the use of the composition for producing a cable layer and to a cable surrounded by at least one layer comprising the polymer composition.Type: GrantFiled: February 5, 2019Date of Patent: April 21, 2020Assignee: Borealis AGInventors: Ulf Nilsson, Per-Ola Hagstrand, Villgot Englund, Andreas Farkas, Janis Ritums
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Patent number: 10208196Abstract: The invention relates to a polymer composition with improved DC electrical properties, to the use of the composition for producing a cable layer and to a cable surrounded by at least one layer comprising the polymer composition.Type: GrantFiled: March 1, 2011Date of Patent: February 19, 2019Assignee: BOREALIS AGInventors: Ulf Nilsson, Per-Ola Hagstrand, Villgot Englund, Andreas Farkas, Janis Ritums
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Patent number: 10189975Abstract: A cable fill composition for an optical fiber cable, said cable fill composition comprising (i) a Fischer-Tropsch derived base oil; and (ii) a thickening system, wherein the thickening system comprises at least one block copolymer. The cable fill composition of the present invention provides improvements in rheological characteristics, low temperature properties, and colour stability properties, as well as minimizing the levels of additives such as antioxidants and pour point depressants which need to be used.Type: GrantFiled: July 30, 2013Date of Patent: January 29, 2019Assignee: SHELL OIL COMPANYInventor: Joerg Friedel
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Patent number: 10162141Abstract: The present disclosure provides a flooding composition. In an embodiment, the flooding composition includes in weight percent (wt %) based on the weight of the composition (A) from 10 wt % to 45 wt % of a silane-grafted polyolefin (Si-g-PO). The flooding composition also includes (B) from 5 wt % to 60 wt % of a poly?-olefin oil (PAO oil), (C) from 15 wt % to 90 wt % of a polysiloxane, and (D) from 0.05 wt % to 0.2 wt % of a catalyst.Type: GrantFiled: March 28, 2018Date of Patent: December 25, 2018Assignee: Dow Global Technologies LLCInventors: Karl M. Seven, Jeffrey M. Cogen, Mohamed Esseghir
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Patent number: 9268049Abstract: An embodiment of the disclosed invention includes a method for attenuating noise during acquisition of marine seismic date. The method includes placing a seismic streamer in a body of water. The seismic streamer includes a streamer body having a length and a channel, a seismic sensor disposed within the channel, and a gel disposed within the channel. The gel has a complex viscosity of at least 50 Pascals and includes a concentration of a polymer between the range of about 5% and about 25% by weight. The method also includes placing a source in the body of water. The seismic streamer and the source are towed through the body of water and the source is fired while being towed through the body of water. Data is collected from the seismic streamer as it is towed through the body of water.Type: GrantFiled: December 14, 2012Date of Patent: February 23, 2016Assignee: WesternGeco L.L.C.Inventors: Gary John Tustin, Steven Antony Gahlings, Robert Hughes Jones
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Patent number: 9260645Abstract: Thermal interface materials are disclosed that include or are based on thermally reversible gels, such as thermally reversible gelled fluids, oil gels and solvent gel resins. In an exemplary embodiment, a thermal interface material includes at least one thermally conductive filler in a thermally reversible gel.Type: GrantFiled: February 23, 2010Date of Patent: February 16, 2016Assignee: Laird Technologies, Inc.Inventor: Karen J. Bruzda
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Patent number: 8722763Abstract: The present invention relates to a process for preparing a polymer composition by using a masterbatch, as well as a process, wherein said polymer composition is used for preparing an article, preferably a cable. Also a masterbatch, a polymer composition comprising the masterbatch, and an article, preferably a cable, comprising the polymer composition are provided.Type: GrantFiled: December 21, 2009Date of Patent: May 13, 2014Assignee: Borealis AGInventors: Annika Smedberg, Philippe Ravera, Ulf Nilsson
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Publication number: 20140113133Abstract: Disclosed is a cross-linked polyethylene composition comprising (A) 100 parts by weight of a polyethylene base resin, (B) 0.1 to 0.6 parts by weight of a hindered phenol-based antioxidant, (C) 1 to 4 parts by weight of a crosslinking agent, (D) 0.2 to 1.9 parts by weight of magnesium oxide and (E) 0.1 to 1.0 parts by weight of a scorch inhibitor, thus advantageously exhibiting superior resistance to water tree generated when a power cable insulator is exposed to outside water and electric field, and superior electrical insulation characteristics.Type: ApplicationFiled: July 31, 2012Publication date: April 24, 2014Applicant: LG CHEM, LTD.Inventors: Ka Ram Sun, In Gyu Park, Youn Sun Nam, Young II Song, Sang Rok Do
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Publication number: 20130338258Abstract: A halogen-free polymer resin composition and a polymer resin material is prepared by using the composition, in particular a cable for using in ships or drillships. The polymer resin material prepared by using the composition maintains flexibility even at low temperature of ?40° C., and has fire retardant properties required to use in cable for general ships as well as oil resistance properties required to use in marine structures such as oil well drilling ships and oil well drilling structure, or drillships.Type: ApplicationFiled: December 4, 2012Publication date: December 19, 2013Applicant: NEXANSInventor: NEXANS
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Patent number: 8354469Abstract: The invention concerns a composition comprising: at least one melt-processible per(halo)fluoropolymer (polymer A); from 0.01 to 5% by weight of polymer A of at least one smoke-suppressant agent (S) having a decomposition temperature of at least 350° C., selected from the group consisting of molybdenum derivatives, borates of an alkaline-earth metal or of a group 12 transition metal, and mixtures thereof; optionally, at least one oxide of a metal different from molybdenum. The composition of the invention excels simultaneously in providing excellent insulating properties on meal wires or optical fibers, outstanding processing parameters for high speed cable manufacture and high performance ratings on flammability, smoke generation and fuel load. Advantageously, cables comprising said composition comply with 25/50/8 requirements according to NFPA-255 and -259 for limited combustible materials.Type: GrantFiled: November 23, 2006Date of Patent: January 15, 2013Assignee: Solvay Solexis, Inc.Inventors: Anthony V. Zangara, Jeffrey A. Hrivnak
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Patent number: 8338504Abstract: A method of treating filler can include the steps of providing the filler, disposing silica within the filler so that a bulk density of the filler is approximately 24 to 26 pounds per cubic feet, forming a silane compound that includes silane and paraffin wax, and combining the silane compound with the filler.Type: GrantFiled: January 8, 2010Date of Patent: December 25, 2012Assignee: General Cable Technologies CorporationInventors: David Camillo, Mark R. Easter
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Patent number: 8283391Abstract: Insulation compositions for electric power cables having a polyolefin base polymer and an additive comprising either low molecular weight wax or polyethylene glycol (PEG) and optionally further comprising one or more hindered amine light stabilizers, amine antioxidants and other antioxidant blends are disclosed. Also disclosed are insulation compositions comprising a C2 to C8 alpha olefin in combination with a polyethylene homopolymer together with, optionally, one or more hindered amine light stabilizer and a liquid cresol antioxidant.Type: GrantFiled: March 7, 2011Date of Patent: October 9, 2012Assignee: General Cable Technologies CorporationInventor: Mark R. Easter
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Patent number: 8045833Abstract: Shear thickening compositions can function in an energy or communications transmission cable to provide enhanced protection against externally applied forces, e.g., cutting or puncture from a shovel. As a free or bound layer, or when used via impregnation into a substrate used for an internal component or wrap, the shear thickening composition provides protection against mechanical damage that far surpasses conventional technologies. In foamable compositions for cable components, the shear thickening composition provides enhanced integrity of the polymer melt for enhanced foam performance. As a flame retardant component, the shear thickening composition provides an enhanced char formation mechanism for superior flame retardance.Type: GrantFiled: November 29, 2007Date of Patent: October 25, 2011Assignee: Union Carbide Chemials & Plastics Technology LLCInventors: Scott H. Wasserman, Jeffrey M. Cogen, Timothy J. Person, Laurence H. Gross
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Patent number: 7995886Abstract: A method for manufacturing an optical cable for communication includes at least one micromodule, said micromodule being blocked with respect to the propagation of water. The method includes the steps of providing at least one optical fiber; embedding the at least one optical fiber in a pseudoplastic filling compound having a viscosity of 3 Pa·s to 30 Pa·s, preferably 7 Pa·s to 25 Pa·s at a shear rate of 10 s?1 and at a temperature of 100° C., and a cross-over lower than 30 Hz, preferably 5 Hz to 25 Hz, at a temperature of 100° C.; and extruding a retaining element made of a thermoplastic polymeric composition around the at least one optical fiber so embedded in the filling compound to obtain a micromodule.Type: GrantFiled: September 27, 2004Date of Patent: August 9, 2011Assignee: Prysmian Cavi E Sistemi Energia S.R.L.Inventors: Massimo Pizzorno, Alessandro Ginocchio, Massimiliano Pavan, Davide Ceschiat
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Publication number: 20110172327Abstract: A method of treating filler can include the steps of providing the filler, disposing silica within the filler so that a bulk density of the filler is approximately 24 to 26 pounds per cubic feet, forming a silane compound that includes silane and paraffin wax, and combining the silane compound with the filler.Type: ApplicationFiled: January 8, 2010Publication date: July 14, 2011Applicant: General Cable Technology CorporationInventors: David CAMILLO, Mark R. EASTER
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Patent number: 7968623Abstract: Insulation compositions for electric power cables having a polyolefin base polymer and an additive comprising either low molecular weight wax or polyethylene glycol (PEG) and optionally further comprising one or more hindered amine light stabilizers, amine antioxidants and other antioxidant blends are disclosed. Also disclosed are insulation compositions comprising a C2 to C8 alpha olefin in combination with a polyethylene homopolymer together with, optionally, one or more hindered amine light stabilizer and a liquid cresol antioxidant.Type: GrantFiled: August 6, 2008Date of Patent: June 28, 2011Assignee: General Cable Technologies Corp.Inventor: Mark Easter
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Patent number: 7902273Abstract: Disclosed are a halogen-free resin composition, an insulated electric wire, and a wire harness, which can maintain long-term thermal resistance without decreasing established mechanical properties, flame retardancy, flexibility, and the like even when the insulated electric wire coated with the halogen-free resin composition is used in a state where it is mixed with an insulated electric wire coated with a PCV resin composition.Type: GrantFiled: February 22, 2008Date of Patent: March 8, 2011Assignee: Yazaki CorporationInventor: Makoto Kambe
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Patent number: 7893132Abstract: The present invention in a first embodiment relates to a conduit or automotive wire consisting of an inner conductor core surrounded by a flame retardant layer made of a polymer composition in a continuous process which composition comprises (A) an olefin homo- and/or copolymer, (B) a silicone-group containing compound, and (C) an inorganic filler, wherein the ratio of the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C. of component (A) to the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C. of the composition is higher than 3.5, and the wire has a length of at least 100 m. In a second embodiment, the present invention relates to a power or communications cable or wire comprising a flame retardant layer made of a polymer composition comprising (A) an olefin homo- and/or copolymer, (B) a silicone-group containing compound, and (C) an inorganic filler, wherein the ratio of the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C.Type: GrantFiled: February 22, 2006Date of Patent: February 22, 2011Assignee: Borealis Technology OyInventors: Bernt-{hacek over (A)}ke Sultan, Jonas Jungkvist, Urban Andreason, Lars-Erik Ahlstrand
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Patent number: 7884143Abstract: The present invention relates to a power and/or telecommunications cable including at least one component element made of a material extruded from an extrudable composition, wherein said extrudable composition comprises a biopolymer selected from polymers of cellulose ester, polymers of starch complexed with a biodegradable polyester, polymers of polyhydroxyalkanoate, and/or polymers of polylactic acid comprising a mixture of polylactic and of polyester.Type: GrantFiled: December 21, 2007Date of Patent: February 8, 2011Assignee: NexansInventors: Jérôme Fournier, Sophie Barbeau
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Publication number: 20100022683Abstract: Novel additive systems for lead-free filled cable insulation are disclosed. These systems provide improved electrical and mechanical properties. The composition contains a base polymer of a polyethylene and an elastomer, a filler, and additives of hindered amine light stabilizers and phenolic antioxidants.Type: ApplicationFiled: July 24, 2008Publication date: January 28, 2010Applicant: General Cable Technologies CorporationInventor: Mark Easter
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Patent number: 7615579Abstract: The invention relates to a superabsorbent polymer wherein an increased rate of water absorption is obtained by the addition of an encapsulated blowing agent. The invention relates to a superabsorbent polymer including an encapsulating blowing agent and having a vortex time of 40 seconds or less. In particular, the superabsorbent polymer includes from about 55 to about 99.9 wt. % of polymerizable unsaturated acid group containing monomers; from about 0.001 to about 5.0 wt. % of internal crosslinking agent; wherein the wherein the composition has a degree of neutralization of more than about 20%; and from about 0.05 to about 10.0 wt. % of an encapsulated blowing agent.Type: GrantFiled: December 14, 2006Date of Patent: November 10, 2009Assignee: Evonik Stockhausen, Inc.Inventors: Mark C. Joy, Whei-Neen Hsu
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Patent number: 7536071Abstract: An optical cable for communication includes at least one micromodule, wherein the micromodule is blocked with respect to the propagation of water. The at least one micromodule includes at least one optical fiber, a retaining element for housing the at least one optical fiber, and a thixotropic filling compound arranged within the retaining element. The filling compound is thixotropic, has a viscosity higher than or equal to 700 Pa·s at zero shear rate and at a first temperature of 20° C., a loss modulus G? lower than or equal to 3000 MPa at 1 Hz and at a second temperature of ?45° C., and is compatible with the retaining element.Type: GrantFiled: September 27, 2004Date of Patent: May 19, 2009Assignee: Prysmian Cavi E Sistemi Energia S.R.L.Inventors: Massimiliano Pavan, Massimo Pizzorno, Alessandro Ginocchio, Davide Ceschiat
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Patent number: 7511087Abstract: A sheath composition and a cable using the sheath composition are disclosed. The sheath composition contains a polyolefine resin and flame-retardant particles containing a metal hydrate. The flame-retardant particles are provided with a coating layer on the surfaces thereof and have a volume average particle diameter in a range from 1 to 500 nm.Type: GrantFiled: August 17, 2005Date of Patent: March 31, 2009Assignee: Fuji Xerox Co., Ltd.Inventors: Takuro Hoshio, Hitoshi Okazaki, Masayuki Okoshi, Michiaki Yasuno
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Publication number: 20090043012Abstract: Insulation compositions for electric power cables having a polyolefin base polymer and an additive comprising either low molecular weight wax or polyethylene glycol (PEG) and optionally further comprising one or more hindered amine light stabilizers, amine antioxidants and other antioxidant blends are disclosed. Also disclosed are insulation compositions comprising a C2 to C8 alpha olefin in combination with a polyethylene homopolymer together with, optionally, one or more hindered amine light stabilizer and a liquid cresol antioxidant.Type: ApplicationFiled: August 6, 2008Publication date: February 12, 2009Inventor: Mark Easter
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Publication number: 20090029166Abstract: The present invention relates to a crosslinkable polymer composition, comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.Type: ApplicationFiled: June 1, 2006Publication date: January 29, 2009Applicant: BOREALIS TECHNOLOGY OYInventors: Jan-Ove Bostrom, Annika Smedberg
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Publication number: 20080223498Abstract: An improved method for imparting excellent long-term dielectric performance to an in-service electrical cable section having a stranded conductor surrounded by a conductor shield encased in a polymeric insulation and having an interstitial void volume in the region of the conductor, the cable section having an average operating temperature T.Type: ApplicationFiled: August 29, 2006Publication date: September 18, 2008Applicant: Novinium, Inc.Inventors: Glen J. Bertini, Gary A. Vincent
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Publication number: 20080227887Abstract: The invention is an electrically conductive device, e.g., a wire or cable, having a crush resistance of at least about 18 pounds per square inch (psi), the device comprising: A. An electrically conductive member comprising at least one electrically conductive substrate, e.g., a wire strand or a pair of twisted wire strands; and B. At least one electric-insulating member substantially surrounding the electrically conductive member, e.g., a polymer coating or layer, the electric-insulating member comprising a polymer blend, the polymer blend comprising: 1. At least about 50 weight percent of a polypropylene, and 2. At least about 10 weight percent of an elastomer. In one embodiment, the blend is characterized as having (i) a hot creep of less than 200% at 150 C, (ii) a dielectric constant at 60 Hz and 90 C of less than about 2.5, (iii) a dissipation factor at 60 Hz and 90 C of less than about 0.005, and (iv) an AC breakdown strength of greater than about 600 v/mil.Type: ApplicationFiled: July 27, 2006Publication date: September 18, 2008Inventors: John Klier, David Paul Wright, Bharat Indu Chaudhary
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Publication number: 20080212927Abstract: An optical cable for communication includes at least one micromodule, wherein the micromodule is blocked with respect to the propagation of water. The at least ones micromodule includes at least one optical fiber, a retaining element for housing the at least one optical fiber, and a thixotropic filling compound arranged within the retaining element. The filling compound is thixotropic, has a viscosity higher than or equal to 700 Pa-s at zero shear rate and at a first temperature of 20° C., a loss modulus G? lower than or equal to 3000 MPa at 1 Hz and at a second temperature of ?45° C., and is compatible with the retaining element.Type: ApplicationFiled: September 27, 2004Publication date: September 4, 2008Inventors: Massimiliano Pavan, Massimo Pizzorno, Alessandro Ginocchio, Davide Ceschiat
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Publication number: 20080188589Abstract: The present invention in a first embodiment relates to a conduit or automotive wire consisting of an inner conductor core surrounded by a flame retardant layer made of a polymer composition in a continuous process which composition comprises (A) an olefin homo- and/or copolymer, (B) a silicone-group containing compound, and (C) an inorganic filler, wherein the ratio of the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C. of component (A) to the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C. of the composition is higher than 3.5, and the wire has a length of at least 100 m. In a second embodiment, the present invention relates to a power or communications cable or wire comprising a flame retardant layer made of a polymer composition comprising (A) an olefin homo- and/or copolymer, (B) a silicone-group containing compound, and (C) an inorganic filler, wherein the ratio of the MFR2 measured under a load of 2.16 kg and at a temperature of 190° C.Type: ApplicationFiled: February 22, 2006Publication date: August 7, 2008Inventors: Bernt-Ake Sultan, Jonas Jungkvist, Urban Andreason, Lars-Erik Ahlstrand
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Publication number: 20080182923Abstract: The present invention relates to a composition for manufacturing insulation materials of an electrical wire and an electrical wire manufactured using the same. The composition for manufacturing insulation materials of an electrical wire according to the present invention includes 100 parts by weight of a base resin, made by blending 20 to 70 weight % of any one resin of an unsaturated organosilane grafted polyethylene and an unsaturated organosilane grafted ethylene alpha olefine copolymer, and 30 to 80 weight % of an unsaturated organosilane grafted ethylene copolymer; 10 to 25 parts by weight of a brominated flame retardant; 10 to 50 parts by weight of an inorganic flame retardant; and 0.2 to 5 parts by weight of compound, as a crosslink retardant, represented as a general formula of XnSi(OR)4-n (X is a phenyl group, R is a methyl group and n is an integer of 1 to 3).Type: ApplicationFiled: November 8, 2007Publication date: July 31, 2008Inventors: Do-Hyun Park, Jin-Ho Nam, Ung Kim, Yong-Sun Lee
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Publication number: 20080153941Abstract: The present invention relates to a power and/or telecommunications cable including at least one component element made of a material extruded from an extrudable composition, wherein said extrudable composition comprises a biopolymer selected from polymers of cellulose ester, polymers of starch complexed with a biodegradable polyester, polymers of polyhydroxyalkanoate, and/or polymers of polylactic acid comprising a mixture of polylactic and of polyester.Type: ApplicationFiled: December 21, 2007Publication date: June 26, 2008Inventors: Jerome Fournier, Sophie Barbeau
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Publication number: 20080139695Abstract: The invention concerns the use as additive for improving properties of resistance to arc tracking and arc erosion: of a mixture A, B or C formed by: concerning mixture A: A1: platinum; and A2: at least an inorganic compound A2.1 of a metal with several degrees of oxidation selected from the group formed by V, Cr, Mn, Fe, Co, Ni, and Cu, in which the metal atom is at a degree of oxidation higher than zero, the least possible (abbreviation: DOX mini); or A3: a combination of at least an inorganic compound A2.1 with at least an inorganic compound A2.2 in which the atom of V, Cr, Mn, Fe, Co, Ni or Cu is at a degree of oxidation higher than DOX mini; concerning mixture B: B1 platinum; and B2: at least an inorganic compound B2.1 of cerium-IV or of lanthanum-III; or B3: a combination of at least an inorganic compound B2.1 with at least an inorganic compound B2.Type: ApplicationFiled: May 29, 2007Publication date: June 12, 2008Applicant: RHODIA CHIMIEInventors: Raymond Dubouis, Alain Pouchelon, Christian Pusineri
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Patent number: 7163966Abstract: The invention relates to a superabsorbent polymer wherein an increased rate of water absorption is obtained by the addition of an encapsulated blowing agent. The invention relates to a superabsorbent polymer including an encapsulating blowing agent and having a vortex time of 40 seconds or less. In particular, the superabsorbent polymer includes from about 55 to about 99.9 wt. % of polymerizable unsaturated acid group containing monomers; from about 0.001 to about 5.0 wt. % of internal crosslinking agent; wherein the wherein the composition has a degree of neutralization of more than about 20%; and from about 0.05 to about 10.0 wt. % of an encapsulated blowing agent.Type: GrantFiled: December 19, 2003Date of Patent: January 16, 2007Assignee: Stockhausen, Inc.Inventors: Mark C. Joy, Whei-Neen Hsu
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Patent number: 6911499Abstract: The present invention relates to powdered, crosslinked polymer compositions, containing a) 55-99.9 wt.-% of at least one polymerized, ethylenically unsaturated, polymerizable monomer which contains acid groups neutralized to at least 25 mole-%, b) 0-40 wt.-% of polymerized, unsaturated monomers copolymerizable with a), c) 0.01-5.0 wt.-%, preferably 0.1-2.0 wt.-% of one or more crosslinking agents, d) 0-30 wt.-% of a water-soluble polymer, the weight amounts a) through d) being based on anhydrous polymer composition, and the sum of these components always being 100 wt.-%, which compositions can be obtained by continuous polymerization wherein at least one parameter biasing the polymerization is varied according to a recurring pattern. The present invention also relates to a process for their production and to their use.Type: GrantFiled: August 2, 2000Date of Patent: June 28, 2005Assignee: Stockhausen GmbHInventors: Helmut Brehm, Hans-Georg Hartan
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Patent number: 6816655Abstract: A copper and optical fiber filling material that comprises a hydrocarbon component, which is semisolid at use temperatures in combination with an antioxidant system comprising of (a) sulfur containing primary phenolic antioxidant; (b) a mixture of mono- and di-alkyl butyl/octyl diphenylamine; (c) an organic phosphite or phosphonite and (d) optionally one or more hindered phenol antioxidants exhibits excellent oxidative stability.Type: GrantFiled: October 29, 2002Date of Patent: November 9, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Jose L. Reyes-Gavilan, Frederick T. Lichtenburg
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Patent number: 6723686Abstract: The invention relates to compositions for cables filling wherein a styrene-butadiene block copolymer with radial structure is used as a gelling agent. This polymer is obtained through styrene and butadiene sequential polymerization and subsequent reaction with a coupling agent preferably of type Cl4-nMRn, wherein M=Sn or Si, R is an alkyl or aryl group and n is an integer from 0 to 2, and hydrogenation of the resulting polymer. This type of copolymer brings a higher stability to the final properties of the gel as compared with the linear hydrogenated synthetic rubbers usually used in the prior art.Type: GrantFiled: October 9, 2001Date of Patent: April 20, 2004Assignee: Dynasol Elastomeros S.A.Inventors: Juan Antonio Barrio Calle, Carlos Gonzalez Gonzalez, Juan Antonio Prieto Noguera
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Publication number: 20030123821Abstract: Fiber optic cable containing optical fibers and a silicone waterblocking gel for low temperature applications. The silicone waterblocking gel has an extremely low crystalline melting point and may be used in low temperature environments since it does not experiencing low temperature attenuation caused by crystallization of the base oil at temperatures below about −45° C. Examples of the waterblocking silicone gel are poly(alkyl)(aryl)siloxane and mono or polyhalogenatedsiloxane.Type: ApplicationFiled: December 28, 2001Publication date: July 3, 2003Applicant: ALCATELInventors: Brian Risch, George J. Dallas
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Process for the preparation of superabsorbent polymers from polyacrylonitrile precipitation polymers
Patent number: 6573358Abstract: A process for the preparation of superabsorbers is disclosed. The process entails subjecting a polyacrylonitrile precipitation polymer alkaline hydrolysis to obtain a hydrolysis product. The hydrolysate that may optionally be neutralized is dried and ground and optionally modified by crosslinking of its surface. The inventive superabsorber is suitable for the preparation of nappies, incontinence articles, water-storage materials and electric cable coverings.Type: GrantFiled: April 16, 2001Date of Patent: June 3, 2003Assignee: Bayer AktiengesellschaftInventors: Gisbert Michels, Günter Sackmann, Klaus Struss -
Patent number: 6424771Abstract: A cable of this invention includes a core comprising a plurality of coated optical fibers and a filling composition of matter that is disposed about the fibers. Typically, the fibers and the filling material are disposed within a tubular member that is disposed within a sheath system. The sheath system includes longitudinally extending strength members and a plastic jacket. The filling composition that fills interstices in the core is one that includes an oil constituent that is a relatively high molecular weight aliphatic hydrocarbon. A relatively small percent by weight of a stereochemically hindered antioxidant system is used to prevent thermal oxidative degradation of the filling material as well as of materials in contact with the filling material. Such stereochemically hindered antioxidants will not migrate out of filling material into other cable and fiber materials, thereby increasing their effectiveness.Type: GrantFiled: February 21, 2000Date of Patent: July 23, 2002Assignee: Fitel USA Corp.Inventor: Jim Jenqtsong Sheu
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Patent number: 6414068Abstract: There is provided an olefin-based resin composition which may be applied to the coatings of electrical cables used in automobiles. The coatings have neatly balanced properties to satisfy product requirements, such as wear and flame resistance, tensile strength, flexibility, and heat and freeze resistance. The olefin-based resin composition includes: (i) polymeric material in an amount of 100 parts by weight which includes: (a) about 30 to 94 parts by weight of propylene polymer portion including at least one propylene polymer having a melt flow rate of up to about 5 g/10 min; (b) about 1 to 20 parts by weight of at least one polyolefin, a proportion of about 0.1 to 10% by weight of which is structurally modified through maleic acid anhydride treatment, so that the at least one polyolefin has a Shore D hardness of at least about 50; and (c) about 5 to 50 parts by weight of at least one olefin-based polymer, a proportion of about 0.Type: GrantFiled: January 16, 2001Date of Patent: July 2, 2002Assignees: Sumitomo Wiring Systems, Ltd., Sumitomo Electric Industries, Ltd.Inventors: Masashi Sato, Tatsuya Hase, Hiroshi Fujimoto
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Publication number: 20020061825Abstract: The invention relates to compositions for cables filling wherein a styrene-butadiene block copolymer with radial structure is used as a gelling agent. This polymer is obtained through styrene and butadiene sequential polymerization and subsequent reaction with a coupling agent preferably of type Cl4-nMRn, wherein M=Sn or Si, R is an alkyl or aryl group and n is an integer from 0 to 2, and hydrogenation of the resulting polymer. This type of copolymer brings a higher stability to the final properties of the gel as compared with the linear hydrogenated synthetic rubbers usually used in the prior art.Type: ApplicationFiled: October 9, 2001Publication date: May 23, 2002Applicant: DYNASOL ELASTOMEROS S.A.Inventors: Juan Antonio Barrio Calle, Carlos Gonzalez Gonzalez, Juan Antonio Prieto Noguera
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Patent number: 6387518Abstract: A composition which is useful for producing profiles and cable insulation which retain their function in the event of fire, comprise peroxidically crosslinking or condensation-crosslinking silicone rubber, metal oxides selected from magnesium oxide, aluminum oxide, tin oxide, calcium oxide and barium oxide and metal compounds of this class which produce oxides on heating, boric acid, zinc borate, and a platinum complex having at least one unsaturated group.Type: GrantFiled: December 1, 1999Date of Patent: May 14, 2002Assignee: Wacker-Chemie GmbHInventors: Dietrich Wolfer, Wilhelm Marsch, Peter Gerhardinger
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Patent number: 6374023Abstract: A cable containing at least one optical fiber within a tube, a space between the optical fiber and the tube and a filling material at least partially filling the space. The filling material contains thermoplastic polymeric molecules which have bonded to form a three-dimensional network substantially throughout said filling material.Type: GrantFiled: May 28, 1999Date of Patent: April 16, 2002Assignee: Corning Cable Systems LLCInventor: Donald R. Parris
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Patent number: 6369129Abstract: An insulating composition for an electric power cable, and an electric power cable comprising a conductor surrounded by an inner semiconducting layer, an insulating layer, and an outer semiconducting layer, where the insulating layer consists of said insulating composition, are disclosed. The insulating composition comprises a crosslinkable multimodal ethylene copolymer obtained by coordinating catalysed polymerization of ethylene and at least one alpha-olefin, and has a density of 0.890-0.940 g/cm3 and an MFR2 of 0.1-10 g/10 min. The insulating composition is characterized in that the ethylene copolymer has an MWD of 3-12, a melting temperature of at most 125° C., and a viscosity of 2500-7000 Pa.s at 135° C. and a shear rate of 10 s−1, 1000-1800 Pa.s at 135° C. and a shear rate of 100 s−1, and 250-400 Pa.s at 135° C.Type: GrantFiled: June 30, 2000Date of Patent: April 9, 2002Assignee: Borealis Technology OyInventors: Hans Mårtensson, Merja Poikela, Anders Nymark
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Patent number: 6258885Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs, etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs, etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: January 13, 1999Date of Patent: July 10, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
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Patent number: 6169160Abstract: Substrates that are moisture-sensitive and/or corrosion-sensitive, such as electrical components found in fiber optic cables, copper wires, terminal blocks, connections and junctions, are protected from moisture and/or corrosion with a protectant composition that includes a polyamide gelling agent, a gelled solvent, and optionally a bleeding agent. The electrical components are typically contacted with the protective composition to protect the sensitive component from moisture and/or corrosion.Type: GrantFiled: January 4, 1999Date of Patent: January 2, 2001Assignee: Union Camp CorporationInventors: Richard C. MacQueen, Marc Jackson, Mark S. Pavlin