Solid Polymer Particle Enclosed In Layer Of Diverse Solid Polymer, E.g., Core-shell, Etc. Patents (Class 523/201)
  • Publication number: 20130245157
    Abstract: It is an object of the present invention to provide a binder for ink-jet printing ink that achieves excellent rubfastness, high durability such as alkali resistance, and good ink dischargeability and that can form a printed image with high gloss and an ink-jet printing ink containing the binder. The present invention relates to a binder for ink-jet printing ink in which a vinyl polymer (B) is dispersed in an aqueous medium (D) by a urethane resin (A) having a hydrophilic group.
    Type: Application
    Filed: August 29, 2011
    Publication date: September 19, 2013
    Applicant: DIC Corporation
    Inventors: Chisato Kuriyama, Mitsuru Kitada, Sadamu Nagahama, Ryuichi Matsuoka
  • Patent number: 8536267
    Abstract: Methods of surface modification of polymer particle are useful in the development of marking fluids. The surface modification includes saponifying one or more acrylic ester groups on a surface of the polymer particle.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: September 17, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Doris Pik-Yiu Chun, Hou T. Ng
  • Patent number: 8530544
    Abstract: The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C?C—C?O and/or an a,b-unsaturated thiocarbonyl group C?C—C?S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N?C?O or thioisocyanate —N?C?S groups, and trivalent groups of formula >C?CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: September 10, 2013
    Assignee: Polyrise
    Inventors: Vincent Gaud, Fabien Rouge
  • Patent number: 8524824
    Abstract: To provide a resin composition comprising an aromatic polycarbonate resin and having excellent appearance, impact strength, thermal stability, hydrolysis resistance, and flame retardancy. The present invention relates to a resin composition comprising (A) 75 to 99.98 wt % of an aromatic polycarbonate resin (component A), (B) 0.01 to 5 wt % of a mixture of polytetrafluoroethylene particles and an organic polymer (component B) and (C) 0.01 to 20 wt % of a flame retardant (component C), wherein the sodium metal ion content of the component B (excluding sodium metal ion contained in the polytetrafluoroethylene particles) is 10 ppm or less, and molded articles therefrom.
    Type: Grant
    Filed: July 30, 2007
    Date of Patent: September 3, 2013
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Takuya Tomoda, Yoshihisa Shinagawa, Shinichi Soda
  • Patent number: 8524804
    Abstract: A resin composition includes a fiber and a polyolefin resin and can provide a molded article having excellent mechanical strength such as flexural strength and impact resistance. The resin composition includes (i) a surface-treated fiber (A) which comprises 100 parts by weight of a fiber (A-I) comprising a polyalkylene terephthalate and/or a polyalkylene naphthalene dicarboxylate and 0.1 to 10 parts by weight of a sizing agent (A-II) adhered to the surface of the fiber (A-I), and (ii) a polyolefin resin modified with an unsaturated carboxylic acid and/or an unsaturated carboxylic acid derivative (a modified polyolefin resin (B)) as a resin component.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: September 3, 2013
    Assignees: Sumitomo Chemical Company, Limited, Teijin Fibers Limited
    Inventors: Katsuhisa Kitano, Kenji Watanabe, Kenji Atarashi, Shinichi Takahashi
  • Patent number: 8519043
    Abstract: The present invention relates to coating compositions which comprise dispersions of polymers obtained by a two-stage procedure, to processes for preparing them, and to their use.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: August 27, 2013
    Assignee: BASF SE
    Inventors: Jens Hartig, Roelof Balk, Manfred Dargatz
  • Patent number: 8512757
    Abstract: The invention provides a block copolymer comprising at least a first block and a second block. The first block comprises a plurality of temperature-sensitive monomeric units, a plurality of hydrophilic monomeric units and a plurality of targeting monomeric units, and the second block comprises a plurality of hydrophobic monomeric units. The second block comprises at least one pH-sensitive moiety.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: August 20, 2013
    Assignee: Agency for Science, Techology and Research
    Inventors: Yi-Yan Yang, Shao-Qiong Liu
  • Patent number: 8501836
    Abstract: A sealing compound composition as an adhesive composition contains a vinyl chloride resin, a plasticizer, a filler, a moisture absorbent and an acrylic resin as a pH control material. The moisture absorbent is blended within a range of 0.3 to 2.0% by weight. The acrylic resin is blended within a range of 1.0% by weight or more to less than 7.0% by weight. A blending ratio of the moisture absorbent is half or less than that of the acrylic resin.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: August 6, 2013
    Assignee: Aisin Kako Kabushiki Kaisha
    Inventors: Hiroshi Tamura, Takaaki Nagano
  • Patent number: 8501827
    Abstract: A method of using heat-resistant hollow sphere polymers having at least on crosslinked polymer stage, and having a core stage that has been swollen with a volatile base, in applications in which the hollow sphere polymer is exposed to temperatures of from 100° C. to 350° C., is provided. Articles made by the method are also provided.
    Type: Grant
    Filed: August 8, 2006
    Date of Patent: August 6, 2013
    Assignee: Rohm and Haas Company
    Inventors: Chuen-Shyong Chou, John Robert Haigh
  • Patent number: 8492472
    Abstract: The present invention relates to coating compositions which comprise dispersions of polymers obtained by a multistage procedure, to processes for preparing them, and to their use in corrosion protection.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: July 23, 2013
    Assignee: BASF SE
    Inventors: Oihana Elizalde, Stephan Amthor, Jens Hartig
  • Publication number: 20130183529
    Abstract: The invention relates to powder, comprising composite particles comprising core particles completely or partially coated with a precipitated first polymer, where the core particles comprise a second polymer which differs from the precipitated first polymer, and where the ratio of the d50 median diameter of the composite particles to the d50 median diameter of the core particles is 1.15 or greater. The invention further relates to processes of using the powders of the present invention to making mouldings.
    Type: Application
    Filed: July 5, 2012
    Publication date: July 18, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Wolfgang DIEKMANN, Franz-Erich BAUMANN, Maik GREBE, Kristiane WARNKE, Sylvia MONSHEIMER
  • Patent number: 8481612
    Abstract: A curing agent for epoxy resins that is comprised of the reaction product of an amine, an epoxy resin, and an elastomer-epoxy adduct; compositions containing the curing agent and an epoxy resin; the compositions are useful in electronic displays, circuit boards, semi conductor devices, flip chips and other applications.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: July 9, 2013
    Assignee: Trillion Science, Inc
    Inventors: Yurong Ying, John J. McNamara, Jing Liang, Rong-Chang Liang
  • Patent number: 8470910
    Abstract: This invention is an aqueous paint composition comprising an alkyd emulsion; a dispersion of organic extender particles, which particles comprise, when dry, one or more void; and one or more pigment. The aqueous paint composition provides high gloss decorative and protective coatings for various substrates, which coatings are extended with lower cost-in-use opaque polymer while still providing the high gloss performance of unextended alkyd emulsion paints. Also provided is a method for providing the high gloss coating.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: June 25, 2013
    Assignee: Rohm and Haas Company
    Inventors: David Michael Fasano, Alain Jean-Pierre Garzon, Melina Guy
  • Patent number: 8466214
    Abstract: Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: June 18, 2013
    Assignee: Arkema France
    Inventors: Rosangela Pirri, Philippe Hajji
  • Patent number: 8466242
    Abstract: Polymers useful as catalysts in non-enzymatic saccharification processes are provided. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using these polymeric acid catalysts.
    Type: Grant
    Filed: February 27, 2012
    Date of Patent: June 18, 2013
    Assignee: Midori Renewables, Inc.
    Inventors: John M. Geremia, Brian M. Baynes, Ashish Dhawan
  • Publication number: 20130141503
    Abstract: An image recording method including applying an ink containing a coloring material and a polymer particle to a recording medium from a recording head of an ink jet system and applying a liquid composition which destabilizes a dispersed state of the polymer particle in the ink to at least a part of a region of the recording medium where the ink is applied, wherein the polymer particle in the ink has core and shell portions, the shell portion contains a copolymer A having a unit (50-90% mass) derived from a compound (a1) represented by a general formula (1) or (2) and a unit (10-50% mass) derived from an ?,?-unsaturated hydrophobic compound (a2), and the core portion contains a polymer of an ?,?-unsaturated hydrophobic compound (b).
    Type: Application
    Filed: October 31, 2012
    Publication date: June 6, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Canon Kabushiki Kaisha
  • Patent number: 8455571
    Abstract: A flame-retardant particle includes: a particle containing a compound having a structure represented by formula (1); and a coating particle that covers at least a part of a surface of the particle: -A(—O—CO—O—Ar)m??(1) wherein A represents a substituted or unsubstituted aromatic group; Ar represents a substituted or unsubstituted phenyl group; and m represents an integer of 1 to 3.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: June 4, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Masato Mikami, Masayuki Okoshi, Kazuya Yamanoi
  • Patent number: 8450395
    Abstract: Disclosed is a resin having excellent impact resistance and color, and a method of preparing the same, and more specifically, a resin having the excellent impact resistance and color, and a method of preparing the same, in which the resin includes (a) an occlusion seed consisting of i) a base seed including 99.95 to 99 wt % of alkyl methacrylate and 0.05 to 1 wt % of crosslinker, and ii) a copolymer of aromatic vinyl compound and alkyl acrylate occluding the base seed; (b) a polymer core surrounding the occlusion seed; and (c) a polymer shell surrounding the core, and according to the present invention, it is effective in providing a resin having superior impact strength, transparency, and color, in which the resin can be used as an excellent impact modifier when applying on a polymethylmethacrylate resin, and a method of preparing the same.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: May 28, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Se Eun Lee, Dong Jo Ryu, Seon Hee Han, Jeong Heon Ahn
  • Patent number: 8445559
    Abstract: A polymeric particle including a core, a first shell, and a second shell is provided: the core including, when dry, at least one void; the first shell polymer having a calculated glass transition temperature (“Tg”) greater than 50° C. and including, as polymerized units, from 15% to 60%, by weight based on the weight of the first shell, monomer selected from the group consisting of acrylonitrile, methacrylonitrile, acrylamide, methacrylamide, and mixtures thereof; and from 0.3% to 10%, by weight based on the weight of the first shell polymer, multiethylenically unsaturated monomer; and the second shell polymer having a Tg of from ?60° C. to 50° C.; wherein the weight ratio of the second shell polymer to the total of all other structures of the polymeric particle is from 0.5:1 to 3:1. The particle provides binding functionality and, when dry, opacity and energy savings. A method for providing a polymeric particle and a method for providing opacity to a dry coating are also provided.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: May 21, 2013
    Assignee: Rohm and Haas Company
    Inventor: James Keith Bardman
  • Patent number: 8426023
    Abstract: The present invention relates to coated polyoxymethylene moldings, comprising at least one polyoxymethylene homo- or copolymer A), and also, if appropriate, further additives B), which has been coated on the surface with at least one binder C) and one formaldehyde scavenger D), wherein the binder C) used comprises a polyalkylene oxide C1 or a polyvinyl ester C2 or a graft polymer C3 composed of C1 and C2 or a mixture of these, and the formaldehyde scavenger D) used comprises at least one lysine compound.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: April 23, 2013
    Assignee: BASF SE
    Inventors: Karthikeyan Sharavanan, Jens Assmann, Lidcay Herrera Taboada, Rainer Anderlik
  • Patent number: 8404762
    Abstract: Disclosed is a core-shell microparticle (10) which is produced by heating a mixture of a crosslinked microparticle (11) having an alkoxyamine group (12) and a monomer to 100 to 180° C. to cause graft polymerization. The crosslinked microparticle (11) is produced by allowing a seed particle to absorb a monomer mixture comprising 15 to 99% by mass of a crosslinkable monomer and 1 to 85% by weight of a monomer having an alkoxyamine group, and then adding a polymerization initiator to the resulting product to cause the polymerization of the monomer mixture.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: March 26, 2013
    Assignee: NOF Corporation
    Inventors: Masaki Hayashi, Masumi Takamura
  • Patent number: 8404347
    Abstract: Amphiphilic, magnetic composite particles are comprised of cores and shells. The core contains both hydrophobic vinylic graft copolymer, hydrophobic vinylic homopolymer and magnetic nanoparticles, and the shell to which the hydrophobic vinylic polymer is grafted is a hydrophilic, nitrogen-containing polymer. Typically, the composite particles are made by a process which involves generating radicals on nitrogen atoms of the water-soluble polymer, and then initiating free-radical copolymerization of said vinylic monomer(s) and vinylic-coated magnetic nanoparticles, whereby vinylic polymer(s) undergo(es) phase separation and the vinylic coated magnetic nanoparticles are encapsulated within the vinylic polymer to form a composite latex.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: March 26, 2013
    Assignee: Hong Kong Polytechnic University
    Inventors: Pei Li, Kin Man Ho
  • Patent number: 8378007
    Abstract: The invention relates to a colored polymer dispersion containing, as main ingredients: (a) a colored polymer produced by polymerization of monomer A with monomer B, monomer A being a pigment B which is coated with a polymerizable wax D wherein the polymerizable function is an ethylenically unsaturated group, monomer B being a ethylenically unsaturated compound; (b) at least one non-ionic surface-active additive E based on polyethers and/or polyglycerines; (c) at least one anionic surface-active additive F based on sulfonates, sulfates, phosphonates, phosphates or carboxylates; and (d) water.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: February 19, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Franz-Leo Heinrichs, Anais Bialy, Klaus Saitmacher, Josef Ritter
  • Patent number: 8362168
    Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.
    Type: Grant
    Filed: August 8, 2011
    Date of Patent: January 29, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Chie Sawauchi, Nobuhiko Tsuda
  • Patent number: 8349343
    Abstract: The present invention describes a novel antibacterial treatment on textile materials using polymeric core-shell particles dispersing in water. These particles are prepared from a surfactant-free emulsion polymerization according to the method of U.S. Pat. No. 6,573,313 and have average particle sizes in the range of 100 to 1000 nm in diameter. When applied to a textile article, the particles form a uniform coating, which prevents the growth of bacteria and microbes. The treatment does not affect the fabric mechanical properties, hand feeling and appearance. Antibacterial activity on cotton is maintained even after 50 times of home laundering.
    Type: Grant
    Filed: July 11, 2012
    Date of Patent: January 8, 2013
    Assignee: The Hong Kong Polytechnic University
    Inventors: John Haozhong Xin, Pei Li, Weijun Ye
  • Publication number: 20120309868
    Abstract: The invention relates to a process for producing a water-absorbing material by coating water-absorbing polymer particles with a film-forming polyurethane and silica, heat treating the coated particles and coating the heat-treated particles with pyrogenic hydrophilic silica. The invention further relates to the water-absorbing material obtainable according to the process of the invention. The water-absorbing material has improved wicking ability (FHA) and core shell saline flow conductivity (CS-SFC).
    Type: Application
    Filed: May 31, 2012
    Publication date: December 6, 2012
    Applicant: BASF SE
    Inventors: Yvonne Hagen, Klaus Dieter Hörner, Axel Meyer, Robin McKiernan, Carolyn A. Spitzmueller
  • Patent number: 8318833
    Abstract: The present invention is drawn to pigment suspensions, methods of forming pigment suspensions, and ink sets. The pigment suspension can comprise an aqueous liquid vehicle and a polymer-encapsulated pigment suspended in the liquid vehicle. The polymer-encapsulated pigment can include a pigment core, a passivation layer formed from a passivation component including an amphiphilic polymer and deposited on a surface of the pigment core, and a polymer-encapsulation layer attached to or deposited on the passivation layer.
    Type: Grant
    Filed: April 26, 2007
    Date of Patent: November 27, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Sivapackia Ganapathiappan
  • Patent number: 8313808
    Abstract: An inkjet receiver comprising a support and one or more layers coated on the support, at least one of which comprises a particulate material and a binder, the particulate material comprising composite particles having an inner portion and an outer portion or core-shell arrangement, wherein the inner portion comprises a negatively-charged, positively-charged or functionalized latex, and the outer portion comprises an inorganic material having enhanced keeping properties and reduced ozone-induced dye fade.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: November 20, 2012
    Assignee: Eastman Kodak Company
    Inventors: Gerard A. Friour, Stephanie V. Desrousseaux, Olivier J. Poncelet
  • Patent number: 8309630
    Abstract: A polymer-encapsulated pigment and a method of modifying a pigment use functional groups of an interface layer to attach a polymer to a pigment composition. The polymer-encapsulated pigment includes a pigment composition, a polymer and an interface layer. In the polymer-encapsulated pigment and the method, the interface layer is covalently attached to an outer surface of the pigment composition. The polymer is attached to the interface layer with a linking group. The linking group is attached to the interface layer by a covalent bond of a functional group. The linking group includes a nucleophilic carbon atom to which the polymer is covalently attached.
    Type: Grant
    Filed: January 25, 2010
    Date of Patent: November 13, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Doris Pik-Yiu Chun, Hou T. Ng
  • Patent number: 8304077
    Abstract: Metallic effect pigments with a platelet-shaped metallic substrate. The pigments have at least one metal oxide layer.
    Type: Grant
    Filed: July 8, 2009
    Date of Patent: November 6, 2012
    Assignees: Eckart GmbH, BYK-Chemie GmbH
    Inventors: Alfred Bubat, Wolfgang Griesel, Phu Qui Nguyen, Hans-Jörg Kremitzl
  • Patent number: 8289618
    Abstract: A method of controlling radiation reflected from a surface comprising: applying a composite material to a surface, where the composite material comprises an ordered periodic array of particles held in a polymeric matrix material; exposing the surface bearing the composite material to radiation; and reflecting invisible radiation from the composite material on the surface.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: October 16, 2012
    Assignee: PPG Industries Ohio, Inc
    Inventors: Calum H. Munro, Mark D. Merritt
  • Patent number: 8288453
    Abstract: A process to disperse organic microparticles/nanoparticles into non-aqueous resin medium is provided. The process includes the steps of a) preparing a resin dispersion/emulsion in water and/or solvent where the resin contains unsaturation in the polymer chain and optionally comprises an ethylenically unsaturated monomer; b) curing the resin dispersion/emulsion by adding monomer and/or initiator; and c) adding the cured dispersion/emulsion during a synthesis step of a resin medium. The amount of organic microparticles/nanoparticles in the resin medium can be about 2 to about 30% by weight based on the total weight of the composition.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: October 16, 2012
    Assignee: CCP Composites US
    Inventors: Chih-Pin Hsu, Ming Yang Zhao, Steven L. Voeks
  • Patent number: 8278377
    Abstract: A resin composition which is excellent in appearance, impact strength, hydrolysis resistance and drip prevention properties. The resin composition comprises (A) 100 parts by weight of an aromatic polycarbonate resin (component A), (B) 0.01 to 6 parts by weight of a polymer mixture (component B) obtained by suspension polymerizing a styrene monomer, a maleic anhydride monomer and an acrylic monomer in the presence of polytetrafluoroethylene particles, and (C) 0.01 to 30 parts by weight of a flame retardant (component C).
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: October 2, 2012
    Assignee: Teijin Chemicals, Ltd.
    Inventor: Takuya Tomoda
  • Publication number: 20120202082
    Abstract: An object of the present invention is to provide a copolymer having the characteristic of developing high viscosity, and lowering its viscosity with an increase in rate of shear, particularly a copolymer having the characteristic of developing viscosity, and lowering its viscosity with an increase in rate of shear even in an aqueous coating composition that contains a surfactant. The present invention provides a copolymer obtainable by copolymerization of a monomer component (m) that includes: (m-1), a macromonomer having (i) a backbone that comprises a polymer chain having a number average molecular weight of 1,000 to 10,000 obtainable by polymerizing a monomer component (I) that contains 5 to 100 mass % of a C4-C24 alkyl-containing polymerizable unsaturated monomer (a), and (ii) a polymerizable unsaturated group; and (m-2) a polymerizable unsaturated monomer containing a hydrophilic group.
    Type: Application
    Filed: September 8, 2010
    Publication date: August 9, 2012
    Inventor: Takeshi Fujii
  • Patent number: 8236876
    Abstract: The invention relates to absorptive, crosslinked polymeric compositions that are based on partly neutralized, monoethylenically unsaturated monomer carrying acid groups wherein the absorptive, crosslinked polymeric composition further includes an antioxidant and is color stable.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: August 7, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Iqbal Ahmed, Mirko Walden, Brian King, Scott J. Smith, Harald Schmidt
  • Patent number: 8235251
    Abstract: The invention relates to cured (meth)acrylate based adhesive composition, comprising at least two co-continuous phases of interpenetrating networks and at least two types of polymeric inclusions, in which one of the co-continuous phases comprises a polymer or copolymer based on at least one acrylic or methacrylic acid monomer or a derivative thereof. These compositions exhibit better facture toughness, especially at low temperatures.
    Type: Grant
    Filed: February 17, 2011
    Date of Patent: August 7, 2012
    Assignee: Huntsman International LLC
    Inventors: Pauline Goodall Barker, Dimiter Lubomirov Kotzev
  • Patent number: 8226962
    Abstract: The present invention describes a novel antibacterial treatment on textile materials using polymeric core-shell particles dispersing in water. These particles are prepared from a surfactant-free emulsion polymerization according to the method of U.S. Pat. No. 6,573,313 and have average particle sizes in the range of 100 to 1000 nm in diameter. When applied to a textile article, the particles form a uniform coating, which prevents the growth of bacteria and microbes. The treatment does not affect the fabric mechanical properties, hand feeling and appearance. Antibacterial activity on cotton is maintained even after 50 times of home laundering.
    Type: Grant
    Filed: January 31, 2005
    Date of Patent: July 24, 2012
    Assignee: The Hong Kong Polytechnic University
    Inventors: John Haozhong Xin, Pei Li, Weijun Ye
  • Patent number: 8227542
    Abstract: An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, when dry, at least one void; and, substantially encapsulating the first polymer, at least one second polymer comprising, as polymerized units, at least one ethylenically unsaturated monomer.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: July 24, 2012
    Assignee: Rohm and Haas Company
    Inventors: James Keith Bardman, Robert Mitchell Blankenship, John Michael Friel
  • Patent number: 8202955
    Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.
    Type: Grant
    Filed: July 5, 2007
    Date of Patent: June 19, 2012
    Assignee: Daikin Industries, Ltd.
    Inventors: Chie Sawauchi, Nobuhiko Tsuda
  • Patent number: 8193271
    Abstract: Process for preparing an aqueous polymer composition using water-soluble free radical chain regulators.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: June 5, 2012
    Assignee: BASF SE
    Inventors: Oihana Elizalde, Matthias Gerst
  • Patent number: 8192837
    Abstract: This invention relates to compositions suitable for the formation of an adhesive layer used for in-mold decoration. This invention also relates to in-mold decoration tape or strip, comprising: a carrier layer; a release layer; a durable layer; and an adhesive layer which comprises an adhesive binder, a polymeric particulate material and an inorganic particulate material.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: June 5, 2012
    Assignee: Etansi Inc.
    Inventors: Xiaojia Wang, Cheri Pereria, Pei-Lin Wang, Jing-Den Chen, Rong-Chang Liang
  • Publication number: 20120133702
    Abstract: An ink jet recording method including attaching a liquid dispersant in which an amphoteric polymer containing a core portion having a cation group and a shell portion having an anion group that covers the core portion is dispersed in a dispersing medium to a recording medium and discharging and attaching cationic ink containing a coloring material and water to the surface of the recording medium to which the liquid dispersant is attached.
    Type: Application
    Filed: November 2, 2011
    Publication date: May 31, 2012
    Applicant: RICOH COMPANY, LTD.
    Inventor: Mariko KOJIMA
  • Patent number: 8163818
    Abstract: The invention relates to a colored polymer dispersion containing, as main ingredients: (a) a colored polymer produced by polymerization of monomer A with monomer B, monomer A being a pigment B which is coated with a polymerizable wax D wherein the polymerizable function is an ethylenically unsaturated group, monomer B being a ethylenically unsaturated compound; (b) at least one non-ionic surface-active additive E based on polyethers and/or polyglycerines; (c) at least one anionic surface-active additive F based on sulfonates, sulfates, phosphonates, phosphates or carboxylates; and (d) water.
    Type: Grant
    Filed: June 30, 2007
    Date of Patent: April 24, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Franz-Leo Heinrichs, Anais Bialy, Klaus Saitmacher, Josef Ritter
  • Patent number: 8153738
    Abstract: A process for making an aqueous dispersion of fluoropolymer particles by providing dispersed particulate of fluorinated ionomer in an aqueous polymerization medium and polymerizing at least one fluorinated monomer in the aqueous polymerization medium in the presence of the dispersed particulate of fluorinated ionomer and initiator to form the aqueous dispersion of particles of fluoropolymer.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 10, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Kenneth Wayne Leffew, Ralph Birchard Lloyd, Charles Joseph Noelke
  • Patent number: 8147977
    Abstract: A thermoplastic resin composition that includes 100 parts by mass of a first vinyl (co)polymer (I) that is produced by (co)polymerization of at least one monomer component selected from the group consisting of aromatic vinyl compounds, vinyl cyanide compounds, and other vinyl monomers copolymerizable with these compounds, and 1 to 100 parts by mass of a vinyl copolymer (II) that is produced by copolymerization of a vinyl cyanide compound and another vinyl monomer copolymerizable with the vinyl cyanide compound and in which the content of the vinyl cyanide compound component in an acetone soluble fraction of the copolymer ranges from 0.1% to 15% by mass.
    Type: Grant
    Filed: May 8, 2007
    Date of Patent: April 3, 2012
    Assignee: UMG ABS, Ltd.
    Inventors: Kazuo Nishimoto, Katsuya Furushige, Koji Hirata, Yoshito Nagao
  • Patent number: 8143327
    Abstract: A core-shell fine particle (10) is produced as follows. First of all, a monomer mixture containing 15-99% by mass of a crosslinkable monomer and 1-85% by mass of a monomer having an ATRP initiating group is adsorbed into an organic monodispersed seed particle. Next, the monomer mixture is polymerized by a polymerization initiator, thereby forming a core layer composed of a monodispersed crosslinked fine particle (11) containing an ATRP initiating group (12). A shell layer (13) is then formed by graft polymerizing a monomer onto the thus-obtained core layer.
    Type: Grant
    Filed: April 15, 2008
    Date of Patent: March 27, 2012
    Assignee: NOF Corporation
    Inventors: Masaki Hayashi, Masumi Takamura
  • Patent number: 8143348
    Abstract: Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: March 27, 2012
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Charles M. Kania, Irina G. Schwendeman, Venkateshwarlu Kalsani, Richard J. Winters, Michael Ziegler, Manfred Wunsch, Carole A. Conley
  • Patent number: 8143328
    Abstract: The present invention relates to a methacryl resin composition having excellent impact strength and transmittancy, and more specifically, to a graft copolymer prepared by preparing graft prepolymer by inputting a monomer mixture comprising 60 to 100 wt % of alkyl methacrylate, and 0 to 40 wt % of one or more compound selected from a group consisting of aromatic vinyl compound and alkyl acrylate compound to perform graft polymerization and adding acid, salt, or polymer coagulant when the monomer conversion of the polymerization is 70% to 95% and then continuously performing the polymerization to have an increased particle size to 100 to 500 nm in a graft polymerization process among processes of preparing the graft polymer including a seed-rubber core-graft polymerization process, a preparing method thereof, and a methacryl resin composition including the graft polymer.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: March 27, 2012
    Assignee: LG Chem Ltd.
    Inventors: Dong-jo Ryu, Jeong-heon Ahn, Se-eun Lee
  • Patent number: 8142888
    Abstract: The present invention provides a polybutylene terephthalate resin composition which satisfies both performances such as high durability in an environment of heating and cooling cycle, and adhesion property to silicone rubber. Specifically, provided is a polybutylene terephthalate resin composition, exhibiting an excellent adhesion property to silicone rubber, containing: (A) 100 parts by weight of polybutylene terephthalate resin; (B) 5 to 30 parts by weight of a core-shell type polymer having a mean particle diameter of 2 ?m or larger, in which a core layer is structured by an acrylic-based rubber, and (C) 20 to 100 parts by weight of glass fiber.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: March 27, 2012
    Assignee: Wintech Polymer Ltd.
    Inventors: Kouichi Sakata, Hiroyuki Amano
  • Patent number: 8133938
    Abstract: A radiation diffraction material comprising an ordered periodic array of particles held in a polymeric matrix is disclosed; the particles each comprise a core surrounded by a shell of a non-film forming composition that is different from the matrix. Methods for using the material are also disclosed.
    Type: Grant
    Filed: November 1, 2005
    Date of Patent: March 13, 2012
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Calum H. Munro, Mark D. Merritt