Abstract: Concrete/mortar is manufactured with a small amount of water by using fine polymer particles containing frozen water. The water becomes available when the particles thaw or the particles may be used directly without freezing.

Abstract: There are provided novel mixtures and composites comprising a normally crystalline acetal polymer and a reinforcing material comprising glass fibers or filaments sized with a normally non-crystalline elastomeric copolymer of about 15 to 45 mol %, preferably about 25 to 35 mol % of trioxane, about 55 to 85 mol %, preferably about 65 to 75 mol % of 1,3-dioxolane, said mol percents based on the total of trioxane and 1,3-dioxolane, and about 0.005 to 0.15 wt. %, preferably about 0.05 to 0.12 wt. % of 1,4-butanediol diglycidyl ether or butadiene diepoxide as a bifunctional monomer, based on the total weight of copolymer.

Abstract: Composite materials based celluyloses grafted with titanium coupling agents reinforce polymeric resins, cement and gypsum. Processes for preparing said composites are disclosed.

Abstract: The water leaching of ammonium polyphosphate from compositions comprising organic polymer and particles of ammonium polyphosphate is reduced if the ammonium polyphosphate is surface-modified with copolymer of vinylpyrrolidone and comonomer selected from the group consisting of .alpha.-olefin containing from about 4 to about 50 carbon atoms, styrene, styrene substituted on the ring with at least one alkyl group containing from 1 to about 12 carbon atoms, and mixtures thereof.

Abstract: A cohesive polymer matrix comprising a matrix polymer and a coated particulate filler dispersed therein, characterized in that the matrix polymer is an emulsion rubber, and the filler is coated at least in part with a composition comprising an organic coating polymer of number average molecular weight of 4,500 to 200,000 which contains an acidic group (or a precursor thereof) and an unsaturated group, optionally linked to the matrix polymer and a process for its production.

Abstract: A low leaching nonpolluting marine antifouling coating formulation and a cess for preparing the same which comprises surface pretreatment of the metal oxide pigment particles with a water-dispersed organic polymeric resinous material, such as by intensively mixing or milling the metal oxide pigment and the resin, in order to recover a water-dispersable polymeric resin modified metal oxide pigment for subsequent incorporation into new water-based coating formulations.

Abstract: A cohesive polymer matrix comprising a matrix polymer and a coated particulate fillter dispersed therein, characterized in that the matrix polymer is a cross-linked olefin/acrylic polymer, and the filler is coated at least in part with a composition comprising an organic coating polymer of number average molecular weight of up to 200,000, which contains an acidic group (or a precursor thereof) and an unsaturated group optionally linked to the matrix polymer and a process for its production, and precursors thereof for use in the process.

Abstract: A glass fiber-reinforced composite material is produced by treating glass fibers with a silane composition comprising silane molecules having amine functional groups and silane molecules having ethylenically-unsaturated functional groups; admixing the treated glass fibers with a polyolefin resin, and a fiber bonding agent comprising a polymerizable unsaturated organic compound having at least two polymerizable unsaturation groups, a vinyl-polymerizable unsaturated, hydrolyzable silane, and a free radical generator, and exposing the resultant mixture to conditions of temperature and pressure sufficient to cause the formation of a glass fiber-reinforced composite material. The use of the silane composition promotes improved impact strength of the composite.

Abstract: A mineral particulate is disclosed selected from the group consisting of metal carbonates, glass fibers and layered lattice silicates, comprising particles of said mineral, the surface of which have been modified by a polymer synthesized in situ in the presence of a reactive gas selected from the group consisting of hydrogen, carbon monoxide and carbon dioxide; said particulate having a predetermined particle size distribution which substantially corresponds to the particle size distribution of the surface-unmodified feed particulate from which the product particulate is produced.

Abstract: A vinyl grafted lignite fluid loss additive comprising a lignite grafted with at least one vinyl monomer selected from the group consisting of: dimethylaminopropyl methacrylamide, methacrylamido propyltrimethyl ammonium chloride, N-vinylformamide, N-vinylacetamide, diallyl dimethyl ammonium chloride, and diallylamine. The vinyl monomer may also be blended with at least one co-monomer. Preferred co-monomers are: 2-acrylamido-2-methylpropanesulfonic acid, dimethylacrylamide, acrylamide, vinylpyrrolidone, vinylacetate, acrylonitrile, dimethylaminoethyl methacrylate, styrenesulfonate, vinylsulfonate, dimethylaminoethyl methacrylate methyl chloride quaternary, acrylic acid and its salts.

Abstract: A method comprising forming a water-in-oil emulsion of an aqueous phase comprising discrete water-insoluble particles an an aqueous solution of a water-soluble polymerizable monomer, polymerizing said monomer, phase-inverting the water-in-oil emulsion to an oil-in-water emulsion, removing the oil phase from the phase-inverted emulsion to form an aqueous latex, adding to the latex an ethylenically unsaturated polymerizable second monomer, and polymerizing said second monomer to produce hydrophobic resin-encapsulated water-insoluble particles; and the resulting encapsulated particles.

Abstract: Promotors for a crosslinking reaction involved in the curing of a system comprising crosslinkable polymers are bound to polymeric microparticles having a diameter of about 0.01 to 6 microns prepared by polymerizing a mixture of ethylenically unsaturated monomers. The microparticles carrying the crosslinking reaction promotor may be incorporated to coating compositions, printing inks, sealants, adhesives and other polymeric products in place of conventional crosslinking reaction promotors.

Abstract: A cohesive polymer matrix comprising a matrix polymer and a coated particulate filler dispersed therein, characterized in that the matrix polymer is a solution rubber, and the filler is coated at least in part with a composition comprising an organic coating polymer of number average molecular weight of up to 3,000 which contains an acidic group (or a precursor thereof) and unsaturated groups optionally linked to the matrix polymer at least 25% w/w of which are vinyl groups.

Abstract: A polymer granulate whose particles consist of a core component and a coating component can be prepared by mixing a granular polymer with a pulverulent coating agent. The core component is made of a water-soluble polymer, in particular a polyvinyl alcohol. The coating component is a water-soluble or water-insoluble substance which is applied to the water-moistened particles of the core component. The particles of the polymer granulate have diameters within the range from 0.6 to 6 mm. The granulate has particularly good freeflowing properties; it is especially suitable for preparing adhesives.

Abstract: A method of preparing mixtures of incompatible hydrocarbon polymers using a novel compatibilizing system. The compatibilizing system comprises a mineral filler and certain reinforcement additives. Flame retardant compositions and articles fabricated from such compositions also are disclosed.

Abstract: A method of producing a calcium carbonate, magnesium carbonate or calcium-magnesium carbonate which is surface modified with an organic material wherein the carbonate in substantially dry, particulate form is contacted with an organic monomer, copolymers or a prepolymer, and surface polymerization or reaction in situ on the carbonate in the presence of a gaseous hydrogen atmosphere is effected. In the case where the carbonate has been wet processed and residues of a dispersing agent employed remain as a coating on the carbonate particles after drying, a minor amount of a calcined kaolin or TiO.sub.2 is used as a polymerization catalyst. When the carbonate has been dry ground so that the particles are free from processing chemicals, no catalyst is needed to initiate the polymerization.

Abstract: The invention relates to the use of chemical grafting to produce a stable liquid composition that is capable of hardening following an optional polymerization process. Under the invention, in order to produce a composition that is liquid, at least initially and prior to any polymerization, a polymerizable organic acid comprising at least two double bonds in resonance is combined in a solvent with an inorganic filler having at least one hydroxylated group with the help of a catalyst acting as a radical upon said organic acid. By adjusting the concentration of catalyst and using a polymerizable monomer solvent, the liquid composition may be hardened by polymerization after the initial grafting reaction. By ensuring that a portion of the organic acid retains free bonds that have not combined with filler, it is also possible to induce the composition to become chemically attached to a resin or to reinforcing fibers. The invention may be applied to the production of molded objects.

Abstract: A rubber composition comprising 30-140 parts by weight of carbon black treated with a particular compound based on 100 parts by weight of rubber which provides an improved reinforcement property of the rubber composition and at the same time improvement of the efficiency of productivity in tire manufacturing.

Abstract: Compositions which are particularly useful as coupling agents and primers for polyolefin composites. The compositions comprise fumaric acid and diaminefunctional silanes in mole ratios from 1.0 to 1.4 in nonreactive solvent, particularly water. These compositions are particularly effective in polyethylene composite materials.

Abstract: A composition for artificial marble which comprises a polymer composition in which an inorganic substance and an organic polymer are firmly bound in one body and a vinyl compound, said polymer composition being obtained by polymerizing a polymerizable vinyl monomer, in the presence of at least one monomer selected from the group consisting of carboxylic acid monomer, sulfonic acid monomer, and sulfonate monomer, in an aqueous polymerization system containing an inorganic substance dispersed therein; and a processs for producing artificial marble from said composition by cast polymerization with the addition of a polymerization initiator.

Abstract: Particles, fibers, or filaments of alkali salts of ethylene/carboxylic acid copolymers or terpolymers, especially in highly porous form, are employed in removing contaminants from tertiary amines or quaternary amine salts, especially metal contaminants.

Abstract: The invention relates to a new process for producing titanium IV and zirconium IV pyrophosphates, certain of which are new compounds, and their uses. The pyrophosphates are prepared by reacting a metal tetraester with phosphorus pentoxide, with or without the addition of an hydroxyl compound, such as an alcohol or a phenol. Depending on the molar ratio of the components, the compounds produced may contain cyclic or straight chain pyrophosphate groups and alkoxy groups attached to the metallic ion. In addition to forming new compounds, the process of the invention produces the desired products without difficult-to-separate by-products.

Abstract: A composition of matter comprising neoalkoxy compounds having the following formula: ##STR1## wherein M is titanium or zirconium, R, R.sup.1 and R.sup.2 are each a monovalent alkyl, alkenyl, alkynyl, aralkyl, aryl or alkaryl group having up to twenty carbon atoms or a halogen or ether substituted derivative thereof, and, in addition, R.sup.2 may also be an oxy derivative or an ether substituted oxy derivative of said groups; A, B, and C are each a monovalent aroxy, thioaroxy, diester phosphate, diester pyrophosphate, oxyalkylamino, sulfonyl or carboxyl containing up to 30 carbon atoms; and a+b+c=3.

Abstract: Highly uniform polymeric microbeads of a predetermined size, preferably having an attached fluorescent label on the surface, are prepared by causing seed particles to swell by absorption of a plurality of low molecular weight substances, at least one of which is a monomer having a reactive functional group. After absorption, the monomer is internally polymerized, and the reactive functional group is preferably reacted with a polyfunctional spacing agent thereby to provide a second reactive functional group. The latter is then reacted with a fluorescent label to provide the labeled microbead.

Abstract: A process for producing a polyethylene composition which comprises polymerizing ethylene in the presence of a catalyst comprising (A) a contact treatment product of (a) a high activity catalyst component and (b) a filler, and (B) an organoaluminum compound.This process has no need for a deashing step, i.e., a step to remove the catalyst after polymerization, since the catalyst has a remarkably high activity.In the polyethylene composition produced, the filler is dispersed uniformly and the separation of the filler from the polyethylene is scarcely observed.

Abstract: There is provided a class of novel 3,4-dihydro-2H-benzopyran derivatives which either have excellent inhibitory activity against unfavorable effects of heat, light and oxidative factors or are of use as precursors of compounds having such activity, and methods for producing these derivatives. Also provided are methods of using such 3,4-dihydro-2H-benzopyran derivatives as stabilizers for organic materials sensitive to heat, light or/and oxidative factors, and organic compositions containing such stabilizers.

Abstract: According to the present invention a composition of matter is provided comprising the reaction product of a comminuted inorganic material and a substituted succinic anhydride having the formula: ##STR1## wherein at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a substituent selected from alkyl, alkenyl, alkynyl or aralkyl group having from 1 to about 30 carbon atoms or a substituted derivative thereof, and the remaining substituents are hydrogens. The substituent may be saturated or unsaturated, linear or branched, and may have from 1 to about 10 substitutions including halogen, tertiary amino, tertiary amide, ketal, episulfide, sulfonate, phosphonate, imide, carboxylate, carbonate, isocyanate, silane, epoxy, cyano, ether, thioether, carbonyl, aromatic nitro, or acetal. In a particular molecule, all of the R.sub.1, R.sub.2, R.sub.3 and R.sub.4 groups may be the same or different, so long as they fall within the above class.

Abstract: Integrally blended additives, consisting of a ternary mixture of gamma methacryloxypropyl trimethoxysilane, trimethylolpropane triacrylate and a siloxaneoxyalkylene block copolymer, in the absence of dicumyl peroxide do not consistently improve the mechanical properties of mica filled polyolefins. This is especially true under "low shear" melt processing conditions e.g. employing a conventional screw design in a single barrel extruder. However, when the ternary mixture is combined with a small amount of dicumyl peroxide (neat or dissolved in vinyltrialkoxy silane) there is a consistent improvement in composite mechanical properties above that of the composites containing the ternary mixture alone and in comparison to mica filled polyolefin composites without any additive or composites containing the peroxide alone. Furthermore, thermal aging tensile strength retention is improved in mica filled polypropylene composites containing the ternary mixture combined with dicumyl peroxide.

Abstract: A process for the production of sheet structure, including fibres from plastics solutions containing deped, burr-shaped or fibrous polyacetylene particles, in which process the solution is shaped to form a sheet and the solvent is removed and the sheet structure thus prepared.

Abstract: A composite material is provided by contacting a clay mineral having laminated aluminum silicate layers with an organic monomer to allow the organic monomer to be adsorbed on or intercalated between the aluminum silicate layers, and contacting the clay mineral with a silane compound having 2 to 4 chlorine atoms to promote polymerization of the organic monomer, thereby forming a composite material composed of a clay mineral having organic high polymer adsorbed thereon or intercalated therebetween. The composite material thus obtained has a strong chemical bond between inorganic clay mineral and organic high polymer.

Abstract: A ferromagnetic resin composition obtained by filling a thermoplastic resin with 70 to 97% by weight of rare earth-cobalt powder, the surface of which has been coated with a thermosetting resin or a thermoplastic resin. The composition gives a plastic magnet excellent in impact resistance.

Abstract: Water-insoluble, high water-absorbent polymer beads are prepared by dispersing and suspending an aqueous solution of a water-soluble, ethylenically unsaturated monomer containing a small amount of a crosslinking agent in a dispersion medium of a hydrocarbon or a halogenated aromatic hydrocarbon, carrying out the bead polymerization in the presence of a water-soluble radical polymerization initiator and a protecting colloid comprising a cellulose ester or cellulose ether which is oil-soluble at the polymerization temperature, and separating the resulting beads.

Abstract: An inorganic filler component for use in resin-based direct dental filling materials comprises fumed or submicron silica which has been silane treated and coated with a thin coating of an active polymerizable monomer of the type used as the binder in making the composition. The use of such a submicron material permits the total filler loading of the composition to be increased substantially, thereby increasing both the compressive and diametrical tensile strength of the cured material as well as improving its polishability and resistance to wear, and reducing its susceptibility to water absorption.

Abstract: Compositions including the dithiocarbamic acid derivative having ##STR1## group and at least one organo-tin compound selected from the group consisting of polymers having recurring units containing organo-tin, copolymers which are copolymerized with acryl compounds or vinyl compounds and organo-tin chemicals of ##STR2## are extremely effective for preventing the adhesion of marine organisms including marine microorganisms. This effect of the said composition is enlarged in the presence of copper compounds. R.sub.1, R.sub.2, and R.sub.3 represent an alkyl or phenyl, cycloalkyl group: Z; monovalent functional group containing sulphur or oxygen: and W; divalent functional group.

Abstract: Colloidal size particles of an inorganic solid such as magnetic iron oxide or titanium dioxide are encapsulated in a hydrophobic addition polymer such as a polymer of styrene by a polymerization process wherein a water-immiscible (hydrophobic) monomer is dispersed in an aqueous colloidal dispersion of the inorganic particles and subjected to conditions of emulsion polymerization. The resulting encapsulated particles are usefully employed as catalysts, toners, pigments and diagnostic latexes that have magnetic characteristics.

Abstract: A water absorbing composite comprises an inorganic powder, and a highly absorbent resin covering the whole surfaces of the individual particles of the inorganic powder. The resin is obtained by reacting with a basic substance a polymer containing as a monomeric constituent an .alpha.,.beta.-unsaturated compound having in its molecule one or two carboxyl groups, or one or two other groups convertible to a carboxyl group or groups, and by crosslinking the reaction product with a polyamine. The composite is useful as a water retaining agent for agriculture and horticulture, or as a dehydrating agent for oil.

Abstract: A reinforced, filled hydrocarbon polymer composition, having increased strength and ductility, contains synergistic mixtures of at least two copolymerizable interfacial agents including an adsorbable agent and a soluble agent.

Abstract: This invention concerns with an improved microcapsule dispersion prepared by adding the following components to a known microcapsule dispersion containing PVA; a pulp having a specific weighted average fiber length, another type of pulp, carboxymethyl cellulose and/or a specified periodic acid type compound, and is characterized by overcoming the drawbacks of known microcapsule dispersions attended by use of PVA.

Abstract: An improved curable chopped fiber loaded elastomer or plastic composition composed of a blend of about 5 to 50 percent of chopped fiber of up to 1.3 centimeters in length and 95 to 50 percent of particulate unvulcanized elastomer or plastic which is capable of passing a 6 mesh U.S. Standard Screen.

Abstract: Compositions are described comprising blends of nitrile rubber and cellulose ester.

Abstract: A reinforced, filled thermoplastic polymer composition, having increased strength and ductility, contains a reinforcement promoter having at least two reactive olefinic double bonds and a positive promoter index, based on the double bond resonance and polarity, and the promoter adsorptivity.