Product Having Two Or More Solid Synthetic Polymers, Or A Solid Polymer And A Solid Polymer-forming System Patents (Class 523/206)
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Patent number: 12202976Abstract: A thermally conductive silicone gel composition contains: (A) an organopolysiloxane having two or more alkenyl groups per molecule; (B) an organohydrogenpolysiloxane having two or more hydrogen atoms bonded directly to silicon atoms; (C) a platinum group metal-containing curing catalyst in a catalytic amount; and (D) aluminum hydroxide particles as thermally conductive particles in an amount of 200 to 600 parts by mass with respect to 100 parts by mass of a total amount of the components (A) to (C). The aluminum hydroxide particles contain, based on 100% by mass, aluminum hydroxide particles (D-1) having a median diameter (D50) of 30 ?m or more in an amount of more than 40% by mass and less than 75% by mass; and aluminum hydroxide particles (D-2) having a median diameter (D50) of less than 30 ?m in an amount of 25% by mass or more and 60% by mass or less. The thermally conductive silicone gel composition has a relative dielectric constant of 5.Type: GrantFiled: March 26, 2021Date of Patent: January 21, 2025Assignee: Fuji Polymer Industries Co., Ltd.Inventor: Shingo Todo
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Patent number: 12139808Abstract: Methods are provided for forming a coating on a surface of a substrate. The method may include: applying a negative charge to the surface of the substrate; electrophoretically depositing a slurry layer onto the surface of the substrate; and densifying the slurry layer on the surface of the substrate at a sintering temperature to form a sintered layer of the coating. The slurry layer may include a plurality of EBC material particles, a cationic polyelectrolyte, a plurality of polymeric binder particles, and a solvent. The plurality of EBC material particles may comprise barium strontium aluminosilicate (BSAS), mullite, silicon, rare earth compounds, or combinations thereof.Type: GrantFiled: January 12, 2022Date of Patent: November 12, 2024Assignee: General Electric CompanyInventor: Glen Harold Kirby
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Patent number: 12060486Abstract: Polymeric compositions, methods of making the compositions, and composites, such as computer chassis containing the compositions are described. The polymeric compositions can contain 20 wt. % to 50 wt. % of a post-consumer mechanical recycled polycarbonate; 10 wt. % to 50 wt. % of a renewably sourced polycarbonate; 10 wt. % to 30 wt. % of a filler containing carbon fibers, wherein at least a portion of the carbon fibers are obtained from a post-industrial recycled source; and 5 wt. % to 15 wt. % of a flame retardant, wherein the polymeric compositions have a total recycled and renewable content of 50 wt. % to 90 wt. %.Type: GrantFiled: September 11, 2023Date of Patent: August 13, 2024Assignee: DELL PRODUCTS L.P.Inventors: Nicholas D. Abbatiello, Xinhua Tian
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Patent number: 11926770Abstract: Disclosed is a composition comprising at least one interpolymer dispersed within an aqueous medium, the interpolymer comprising at least one unsaturated monomer and at least one selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof, and, optionally, at least one surfactant configured to stabilize the interpolymer within the aqueous medium. The conjugated acid may be derived from a naturally-occurring oil, such as tung oil. There is also provided a method for preparing a composition, comprising forming an interpolymer comprising the at least one unsaturated monomer and the at least one selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof. There is still further provided a pressure sensitive adhesive comprising the composition prepared according to the disclosed method.Type: GrantFiled: August 12, 2016Date of Patent: March 12, 2024Assignees: Rohm and Haas Company, Dow Global Technologies LLCInventors: Jiguang Zhang, Miao Yang, Shaoguang Feng, Zhaohui Qu
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Patent number: 11492464Abstract: A light-curable composition is provided which may be used as a photopolymerizable material in an additive manufacturing process. The additive manufacturing process involves heating the light-curable composition which has a viscosity at 20° C. of at least 20 Pa·s. The light-curable composition includes a photopolymerizable matrix material, at least one thermoplastic polymer dissolved therein, and at least one photoinitiator. Polycaprolactone or a derivative thereof is used as the dissolved thermoplastic polymer.Type: GrantFiled: April 27, 2018Date of Patent: November 8, 2022Assignee: TECHNISCHE UNIVERSITÄT WIENInventors: Bernhard Steyrer, Robert Liska, Jürgen Stampfl
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Patent number: 11242474Abstract: Provided are an adhesive resin laminate having an excellent adhesive force to two adherends, a laminate in which this adhesive resin laminate is laminated with two adherends, and a method of producing them. An adhesive resin laminate having at least a first adhesive layer and a second adhesive layer, in which the first adhesive layer includes a base resin and a crosslinking agent, the base resin is a modified polyolefin resin, the crosslinking agent is an epoxy-based compound, the second adhesive layer includes a polyolefin-based resin, and when an adhesion initiation temperature of the first adhesive layer is set to T1, and an adhesion initiation temperature of the second adhesive layer is set to T2, T2 is higher than T1 by 30° C. or more.Type: GrantFiled: February 8, 2018Date of Patent: February 8, 2022Assignee: FUJIMORI KOGYO CO., LTD.Inventors: Toshiyuki Takeda, Nagako Takahashi
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Patent number: 11236228Abstract: An epoxy resin composition includes a polyol (A) having a hydroxyl value of 130 to 600 mgKOH/g, an epoxy resin (B), an amine curing agent (C), and a toughener (D). The epoxy resin composition may satisfy both 0.1?Wt2/Wp?8.0 and 0.1?Wp?8.0, where Wp represents the polyol (A) content of the composition in % by weight and Wt represents the toughener (D) content of the composition in % by weight, relative to a total amount of the polyol (A), the epoxy resin (B), the amine curing agent (C), and the toughener (D).Type: GrantFiled: January 27, 2020Date of Patent: February 1, 2022Assignee: KANEKA CORPORATIONInventor: Nobuo Miyatake
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Patent number: 10954322Abstract: A prepolymer, which is prepared by subjecting an unsaturated bond-containing compound and a bis(vinylphenyl) compound monomer or a polymer thereof to a prepolymerization reaction, is provided. The bis(vinylphenyl) compound contains between 80% and 99% of para-para vinyl groups and has a monomer content of between 80% and 100%. Moreover, a resin composition comprising the prepolymer and an additive, a method of preparing the prepolymer, and an article made from the resin composition are also provided.Type: GrantFiled: December 20, 2018Date of Patent: March 23, 2021Assignee: Elite Electronic Material (Kunshan) Co., Ltd.Inventors: Rongtao Wang, Yan Zhang, Bingbing Li
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Patent number: 10947395Abstract: A multi-functional flow modifier that also serves as a wetting agent, gloss control additive, and rheology modifier is contemplated. The flow modifier itself is a mixture of polyurethane masterbatch and hydroxyl acrylic resin (free from any styrene components/resins), curatives, anti-corrosion pigments, degassers, and anti-oxidants. The flow modifier may be introduced to finished coating compositions by way of a silica carrier.Type: GrantFiled: December 19, 2018Date of Patent: March 16, 2021Assignee: PISON STREAM SOLUTIONS INC.Inventors: Joseph H. James, Subadhra Janardhanan, Sanjana Das, Kathleen McAfee
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Patent number: 10889707Abstract: Disclosed is a glass fiber composite material composition having further improved compatibility between glass fibers and polypropylene and thus maximized interfacial adhesion between the resin and the glass fibers in a glass fiber composite material. The present invention provides a glass fiber composite material composition comprising: (A) 60-93% by weight of polypropylene; (B) 1-30% by weight of glass fiber sized with a silane-based compound; and (C) 1-10% by weight of a polypropylene resin modified with maleic anhydride and a methacryloxysilane-based compound.Type: GrantFiled: September 18, 2017Date of Patent: January 12, 2021Assignee: LOTTE CHEMICAL CORPORATIONInventors: Ju Hee Park, Byung Kak Jang, Seung Ju Lee
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Patent number: 10836908Abstract: A composition and a method for preparing a polymer composite article. The composition comprises (A) a filler in an amount of from 10 to 90 wt. The composition also comprises (B) a polymer in an amount of from 10 to 90 wt. %, wherein the (B) polymer is selected from polyolefins, polyamides, polyesters, or combinations thereof. Further, the composition comprises (C) an organopolysiloxane in an amount of from greater than 0 to 10 wt. %; the (C) organopolysiloxane having at least one silicon-bonded hydroxyl group and a viscosity of from 1,000 to 60,000 mPa·s at 25° C. The ranges for components (A)-(C) are based on the total weight of components (A), (B) and (C) in the composition.Type: GrantFiled: February 1, 2019Date of Patent: November 17, 2020Assignees: Dow Silicones Corporation, Dow Global Technologies LLCInventors: Keith Bruce, Igor Chorvath, Marc-Andre Courtemanche, Jon V. Degroot, Jr., Sean Gaal, Craig Gross, James Keenihan, Shawn Mealey, Scott Miller, Tom Parsons, Andrew Schlader, Cristina Serrat, Lauren Tonge
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Patent number: 10774200Abstract: A transparent ABS resin composition which enables a production of a molded article retaining an excellent mechanical strength without decreasing the transparency and opacity, consisting of: based on a total mass of the transparent ABS resin composition, 70 to 98% by mass of a transparent ABS resin; and 2 to 30% by mass of a glass filler. The glass filler consists of glass components and optionally at least one oxide.Type: GrantFiled: October 30, 2015Date of Patent: September 15, 2020Assignee: Asahi Fiber Glass Co., Ltd.Inventors: Takenori Noguchi, Keiji Sekine
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Patent number: 10351695Abstract: Methods are described for activating a glass fiber or flake to participate in polymerizing a resin. The methods may include sizing the glass fiber or flake with a sizing composition that includes a solution containing a polymerization initiator, and activating the polymerization initiator by forming a free radical moiety on the polymerization initiator that can initiate the polymerization of the resin. Additional methods of making a glass reinforced composite are described. The methods may include sizing glass fibers or flakes with a sizing composition that includes a solution containing a polymerization initiator, forming a free radical moiety on the polymerization initiator to make activated glass fibers or flakes, and contacting the activated glass fibers or flakes with a polymer resin. The activated glass fibers or flakes initiate the polymerization of the resin around the glass fibers or flakes to form the glass reinforced composite.Type: GrantFiled: March 1, 2016Date of Patent: July 16, 2019Assignee: Johns ManvilleInventors: Kiarash Alavi, Jawed Asrar, Rajappa Tadepalli, Klaus Friedrich Gleich
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Patent number: 9725563Abstract: Methods of making a fiber-reinforced composite are described. The methods may include applying a sizing composition to a plurality of fibers to make sized fibers, where the sizing composition may include at least one of a curing agent or an accelerator for a resin composition. The sized fibers may be contacted with the resin composition to form a resin-fiber amalgam, where the resin composition includes 50 wt. % or less of a total amount of the curing agent and the accelerator that is also present on the sized fibers. The resin-fiber amalgam may then be cured to form the fiber-reinforced composite.Type: GrantFiled: February 5, 2014Date of Patent: August 8, 2017Assignee: Johns ManvilleInventors: Mingfu Zhang, Jawed Asrar, Asheber Yohannes, Klaus Friedrich Gleich
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Patent number: 9663610Abstract: A self-healing composite material includes a polymer matrix, microcapsules filled with a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives such as ethylidene norbornene, or cyclooctadiene), and polymeric particles comprised of a polymer that is soluble in the monomer with which the microcapsules are filled and having catalytic endgroups derived from an olefin metathesis catalyst, such as a Grubbs'-type catalyst. In some embodiments, the polymer having catalytic endgroups is synthesized via solution polymerization of a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives, or cyclooctadiene) in the presence of an olefin metathesis catalyst (e.g., Grubbs' 1st generation catalyst). The polymer having catalytic endgroups may then be processed via a grinding operation, for example, to prepare the small polymeric particles. In other embodiments, the polymeric particles are synthesized directly as microparticles (e.g., microspheres, granules, beads, etc.Type: GrantFiled: October 3, 2014Date of Patent: May 30, 2017Assignee: International Business Machines CorporationInventors: Dylan J. Boday, Timothy C. Mauldin
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Patent number: 9580579Abstract: Embodiments of the disclosure generally provide flame retardant compositions and methods comprising organic polymers, mineral fillers, high surface area mineral fillers and process aids. Compositions of the disclosure additionally are comprised of high surface area hydrated metal carbonate fillers, including the mesoporous amorphous magnesium carbonate filler Upsalite. The filler's porous structure and high surface area provides high water capacity, enhanced physical and chemical interaction with a polymer in composite, lower by weight loadings of filler in a composite, as well as effective flame retardancy.Type: GrantFiled: December 9, 2014Date of Patent: February 28, 2017Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Joseph Kuczynski, Melissa K. Miller, Heidi D. Williams, Jing Zhang
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Patent number: 9434828Abstract: A non-aqueous dispersion comprising the dispersion polymerization reaction product of an ethylenically unsaturated monomer and a nonlinear, random acrylic polymer stabilizer is disclosed. Related coatings, methods, and substrates are also disclosed.Type: GrantFiled: December 8, 2010Date of Patent: September 6, 2016Assignee: PPG Industries Ohio, Inc.Inventors: Mary Ann M. Fuhry, David Fenn, John M. Dudik, Linda K. Anderson, Wei Wang, Dennis A. Simpson, Scott Moravek, Ken W. Niederst
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Patent number: 9365685Abstract: A functionalized carbon fiber having covalently bound on its surface a partially cured epoxy or amine-containing sizing agent, wherein at least a portion of epoxide or amine groups in the sizing agent are available as uncrosslinked epoxide or amine groups, which corresponds to a curing degree of epoxide or amine groups of no more than about 0.6. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.Type: GrantFiled: February 28, 2012Date of Patent: June 14, 2016Assignee: UT-BATTELLE, LLCInventors: Frederic Vautard, Soydan Ozcan, Felix Leonard Paulauskas
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Patent number: 9205604Abstract: A method of modifying a thermoplastic polymer powder. A suspension of thermoplastic polymer powder and reinforcement elements in a liquid is heated within a reaction chamber so that the thermoplastic polymer powder becomes softened and the reinforcement elements migrate into the softened thermoplastic polymer powder to form modified thermoplastic polymer powder. The modified thermoplastic polymer powder is then separated from the liquid. The reinforcement elements have an electromagnetic moment and are subjected to an electromagnetic field as the suspension is heated. The interaction of the electromagnetic field with the electromagnetic moment of the reinforcement elements causes the reinforcement elements to become aligned with the electromagnetic field before they migrate into the powder.Type: GrantFiled: June 19, 2013Date of Patent: December 8, 2015Assignee: AIRBUS GROUP LIMITEDInventor: Benjamin Farmer
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Patent number: 9085712Abstract: The present invention provides a hybrid two component coating composition comprising as component I, (A) an N-alkoxysilylalkyl-aspartic acid ester, (B) a polysiloxane having a molecular weight in the range of from about 400 to 10,000, and optionally (C) at least one hydrolyzable silane; and as component II, (D) a polyisocyanate having an average NCO functionality of 2.5 to 5.5 and an isocyanate content, based on solids, of 9 to 50 wt % and containing aliphatic polyisocyanates; and (E) a catalyst. Methods of making and applying the hybrid coating composition are also provided.Type: GrantFiled: March 14, 2013Date of Patent: July 21, 2015Assignee: Bayer MaterialScience LLCInventor: Ahren Olson
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Patent number: 9012533Abstract: A fiber-reinforced resin composite and method of making the same. The fiber-reinforced resin composite includes a polymeric resin matrix and a plurality of fibers coated with a first distortional polymeric resin. The polymeric resin matrix has a first von Mises strain. The first distortional polymeric resin has a second von Mises strain in a range of approximately 0.25 to approximately 0.45. The plurality of fibers coated with the first distortional polymeric resin are disposed in the polymeric resin matrix. The second von Mises strain is greater than the first von Mises strain.Type: GrantFiled: February 4, 2014Date of Patent: April 21, 2015Assignee: The Boeing CompanyInventors: Terrence Lee Schneider, Stephen Christensen, Jonathan Henry Gosse
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Patent number: 8999505Abstract: The present invention relates to a sizing composition in the form of a physical gel for glass strands which contains 0.1 to 5% by weight of at least one texturing agent chosen from xanthans, guars and succinoglycans, 2 to 8% by weight of at least one film-forming agent, 0.1 to 8% by weight of at least one compound chosen from plasticizing agents, surface-active agents and dispersing agents, 0.1 to 4% by weight of at least one coupling agent, and 0 to 6% by weight of at least one additive. Another subject-matter of the present invention is glass strands coated with the abovementioned sizing composition and the composite materials containing an organic or inorganic material reinforced with the said glass strands.Type: GrantFiled: September 4, 2008Date of Patent: April 7, 2015Assignee: Saint-Gobain AdforsInventors: Dominique Serughetti, Jean-Baptiste Denis, Patrick Moireau
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Publication number: 20150051313Abstract: The present invention concerns a two-part sizing composition comprising: (A) A precursor comprising: (a) An aminosilane (e.g. A1100) and (b) a polymer or copolymer containing carboxylic acid and/or anhydride, both having a functionality, F?3, and (B) A binder comprising a multi-functional epoxy resin of functionality, F?3. Glass fibres sized with the reaction product of the above composition yield a higher resistance to hydrolysis of polymeric matrix composite materials reinforced with such fibres. The sizing composition of the present invention is particularly advantageous for use with polyester resins, such as PET.Type: ApplicationFiled: March 15, 2013Publication date: February 19, 2015Applicant: 3B-Fibreglass sprlInventors: Frédéric Van Hoof, Nadia Masson
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Patent number: 8957134Abstract: A process for encapsulating pigment dispersions is provided where a pigment is dispersed with a polymeric dispersant in an aqueous solvent system. The free polymer dispersant in the pigment dispersion is limited to less than 0.12 grams per gram of pigment. This dispersed pigment is then encapsulated by adding acrylate monomers and optionally acrylic and vinyl monomers and polymerizing. In the encapsulated pigment dispersion the weight ratio of final free polymer to polymer found to the final encapsulated pigment is less than 0.9. The free polymer dispersant is measured by a centrifugation method and the final free polymer is measured by a density gradient centrifugation method. Such encapsulated pigment dispersions may be used in inkjet inks and are stable to heat, aging test conditions, and solvent challenges. Prints from these inks have better durability.Type: GrantFiled: December 15, 2011Date of Patent: February 17, 2015Assignee: E I du Pont de Nemours and CompanyInventors: Hee Hyun Lee, Michael Joseph Otley, Michael Stephen Wolfe, Tristan Williams
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Patent number: 8912249Abstract: A process for encapsulating pigment dispersions is provided where a pigment is dispersed with a polymeric dispersant in an aqueous solvent system. An acrylate monomer and a polyurethane dispersion are added and the resultant mixture is polymerized. Optionally, the acrylate monomer/polyurethane mixture may be emulsified in water with an added surfactant or polymeric dispersant and up to 20% acrylic or other vinyl monomers based on the acrylate may be added to the acrylate monomer/polyurethane mixture before polymerization. Such encapsulated pigment dispersions may be used in inkjet inks and are stable to heat, aging test conditions, and solvent challenges. Prints from these inks have better durability.Type: GrantFiled: December 15, 2011Date of Patent: December 16, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Waifong Liew Anton, Hee Hyun Lee, Michael Joseph Otley, Michael Stephen Wolfe
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Patent number: 8895219Abstract: An ink is disclosed. The ink includes a carrier fluid; an encapsulated metallic pigment particle further including a metallic pigment particle and a polymer, wherein the polymer covers between 70% and 100%, inclusive, of the surface area of the metallic pigment particle and wherein the morphology of the metallic pigment particle by itself is substantially the same as the morphology of the metallic pigment particle covered by the polymer; and a polymer resin.Type: GrantFiled: April 30, 2012Date of Patent: November 25, 2014Assignee: Hewlett-Packard Development Company, L.P.Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
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Patent number: 8889788Abstract: The present invention provides aqueous dispersions comprising a pigment (B) at least partially enveloped by polyurethane (A) and further comprising at least one polymerization inhibitor (C), said polyurethane (A) being obtainable by reaction of (a) 15% to 70% by weight of di- or polyisocyanate comprising on average from 1 to 10 allophanate groups and on average from 1 to 10 C—C double bonds per molecule, and optionally (b) 0% to 60% by weight of further di- or polyisocyanate, with (c) 5% to 50% by weight of compound having at least two isocyanate-reactive groups, weight % ages being based on total polyurethane (A).Type: GrantFiled: February 13, 2008Date of Patent: November 18, 2014Assignee: BASF SEInventors: Holger Tuerk, Paul Andrew Simpson, Gernot Diehlmann
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Publication number: 20140329932Abstract: The present invention relates to a method of preparing an aqueous dispersion of polymer encapsulated particulate material, the method comprising: providing a dispersion of the particulate material in a continuous aqueous phase, the dispersion comprising ethylenically unsaturated monomer and a stabiliser for the particulate material; and polymerising the ethylenically unsaturated monomer by non-living free radical polymerisation to form polymer that encapsulates the particulate material, thereby providing the aqueous dispersion of polymer encapsulated particulate material; wherein polymerisation of the ethylenically unsaturated monomer comprises: (a) polymerising a monomer composition that includes ionisable ethylenically unsaturated monomer so as to form a base responsive water swellable non-living polymer layer that encapsulates the particulate material; and (b) polymerising a monomer composition that includes non-ionisable ethylenically unsaturated monomer so as to form an extensible, water and base permeabType: ApplicationFiled: May 31, 2012Publication date: November 6, 2014Applicant: THE UNIVERSITY OF SYDNEYInventors: Matthew Paul Baker, Timothy Warren Davey, Brian Stanley Hawkett, Duc Ngoc Nguyen, Christopher Henry Such
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Patent number: 8871835Abstract: The object of the present invention is to provide a heat conductive elastomer composite useful as the heat radiating member of electric parts or electronic parts, or the like. In the present invention, an aluminum hydroxide having a surface covered with an organic coupling agent and/or an inactivated magnesium oxide, being a magnesia clinker having a surface covered with an inorganic substance and/or an organic substance, is (are) combined as heat conductive filler(s) in an elastomer composite mainly composed of a styrenic elastomer.Type: GrantFiled: October 12, 2010Date of Patent: October 28, 2014Assignee: Aronkasei Co., LtdInventors: Masanori Shiraki, Noriaki Date, Yasujuki Agari
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Patent number: 8871347Abstract: An aluminum chelate-based latent curing agent having excellent latency and thermal response includes a latent curing agent in which an aluminum chelating agent is retained in a porous resin obtained by interfacial polymerization of a polyfunctional isocyanate compound, and an enzyme-treated gelatin film coating such latent curing agent. This microcapsule-type latent curing agent can be produced by dissolving an aluminum chelating agent and a polyfunctional isocyanate compound in a volatile organic solvent, charging the obtained solution into a gelatin-containing aqueous phase, carrying out interfacial polymerization by heating and stirring, and subjecting the gelatin to an enzyme treatment by adding an enzyme to the obtained polymerization reaction mixture.Type: GrantFiled: March 18, 2008Date of Patent: October 28, 2014Assignee: Dexerials CorporationInventor: Kazunobu Kamiya
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Patent number: 8865798Abstract: A self-healing material comprises a matrix embedded with micro-pockets of a healing-agent releasable by a crack in the matrix. The healing-agent is able to bond to the matrix to repair the crack. The healing-agent is contained in microcapsules. A corresponding catalyst for the healing-agent is embedded in the matrix and contained in a plurality of microcapsules as an emulsion. The emulsion comprises an oil, a perfluorated solvent, a hydrophobic ionic liquid, or mixtures thereof. A method of manufacturing the self-healing material comprises the steps of identifying an operational temperature range of the material, providing at least one substance as the healing-agent, which substance remaining substantially in a liquid state within the operational temperature range, identifying an operational evaporation rate of the healing-agent and providing the substance with a curing time according to the evaporation rate.Type: GrantFiled: October 17, 2007Date of Patent: October 21, 2014Assignees: Valorbec Societe en Commandite, MPB Communications Inc.Inventors: Philippe Merle, Yoann Guntzburger, Émile Haddad, Suong Van Hoa, Girish Thatte
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Patent number: 8859639Abstract: A capsulated colorant including a colorant and a polymer resin which is coated on the colorant and has a cross-linked structure, a method of preparing the capsulated colorant, and an ink composition including the capsulated colorant. By adjusting the extent of cross-linking of the colorant on which the polymer having a cross-linked structure is coated, a capsulated colorant having a cross-linking of larger extent and a capsulated colorant having a cross-linking of smaller extent are obtained. By using an ink composition including the capsulated colorant having a larger cross-linked extent, characteristics of excellent waterfastness, lighffastness, rubfastness and optical density can be realized. In addition, by using the ink composition including the capsulated colorant having a smaller cross-linked extent, images with excellent durability and printed gloss can be realized.Type: GrantFiled: July 23, 2008Date of Patent: October 14, 2014Assignee: Samsung Electronics Co., Ltd.Inventor: Jong-in Lee
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Patent number: 8859644Abstract: Processes for encapsulating pigment dispersions is described and are used in inkjet inks providing stability with regard to heat aging test conditions and solvent challenges. Prints from these inks have better durability than prints made from dispersions that are not encapsulated.Type: GrantFiled: December 15, 2011Date of Patent: October 14, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Michael Stephen Wolfe, Waifong Liew Anton, Hee Hyun Lee
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Patent number: 8835531Abstract: The invention provides a water-based ink for inkjet recording containing at least: a vinyl polymer particle containing an azo compound represented by Formula (1), a tautomer of the azo compound, a salt or a hydrate of the azo compound or the tautomer, or any combination thereof; a 1,2-alkylene glycol having from 4 to 10 carbon atoms; and a polyvalent alcohol that is not the 1,2-alkylene glycol and that has at most 10 carbon atoms. In Formula (1), Z represents a divalent group having a 5- to 8-membered nitrogen-containing heterocycle; Y1, Y2, R11 and R12 each independently represent a hydrogen atom or a substituent; G1 and G2 each independently represent a hydrogen atom, an alkyl, cycloalkyl, aralkyl, alkenyl, alkynyl, aryl or heterocyclic group; and W1 and W2 each independently represent an alkoxy group, an amino group, an alkyl group, or an aryl group.Type: GrantFiled: February 2, 2010Date of Patent: September 16, 2014Assignee: FUJIFILM CorporationInventor: Kiyoshi Morimoto
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Publication number: 20140249248Abstract: The present disclosure provides an inkjet ink comprising an aqueous vehicle and an encapsulated pigment dispersion. A process for encapsulating pigment dispersions is provided where a pigment is dispersed with a polymeric dispersant in an aqueous solvent system. The encapsulation process has at least two additions of encapsulating monomers followed by polymerization. To a pigment dispersed with a polymeric dispersant is added an encapsulating monomer(s) and a polymerization initiator is added which forms a stage 1 encapsulated pigment. Then a second encapsulating monomer(s) is added and these monomers are polymerized by a second addition of polymerization initiator, forming a second stage encapsulated pigment. The second encapsulating monomer(s) may be added continuously to the stage 1 encapsulated pigment. Such encapsulated pigment dispersions may be used in inkjet inks and are stable to heat, aging test conditions, and solvent challenges. Prints from these inks have better durability.Type: ApplicationFiled: December 15, 2011Publication date: September 4, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Hee Hyun Lee, Frank Leonard Schadt, Michael Stephen Wolfe
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Patent number: 8779057Abstract: The instant invention provides dye-encapsulated dispersions suitable for printing applications, method of producing the same, ink compositions made therefrom, delivery systems for such ink compositions, and articles having a coating layer derived from such ink compositions.Type: GrantFiled: November 14, 2011Date of Patent: July 15, 2014Assignee: Dow Global Technologies LLCInventors: Anne M. Kelly-Rowley, Timothy J. Young
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Publication number: 20140171549Abstract: A sizing composition includes a texturing agent, a film-forming agent, and a cationic polymer having a polyalykyleneimine backbone. A glass fiber strand is formed from a plurality of individual glass fibers coated with the sizing composition. A composite material includes such glass fiber strands.Type: ApplicationFiled: July 31, 2012Publication date: June 19, 2014Applicant: OCV Intellectual Capita, LLCInventors: Claire Genevieve Ceugniet, Dino Lombino
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Patent number: 8748511Abstract: Curable compositions comprising a) an alkoxysilane and/or acyloxysilane terminated polymer having at least one end group of the general formula (I) -An-R—SiXYZ (I) and b) hollow microspheres made of a copolymer obtained by the polymerization of methacrylonitrile and at least one monomer M2 selected from the group consisting of acrylic acid, methacrylic acid, acrylic acid alkyl esters and methacrylic acid alkyl esters, wherein the copolymer comprises at maximum 5 wt. % units that are due to the installation of additional monomers and is free of units containing chlorine, to a method for the production thereof and to the use thereof as silane cross-linking adhesive, sealing or coating substances.Type: GrantFiled: October 6, 2011Date of Patent: June 10, 2014Assignee: Henkel AG & Co., KGaAInventors: Andreas Bolte, Helene Boudet, Bernhard Schoettmer, Nick Spielkamp
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Publication number: 20140128501Abstract: In a fibrous planar structure in which fibers are embedded in a matrix, an increase in mechanical resistance is achieved by improving the adhesion between the fiber and the matrix.Type: ApplicationFiled: January 16, 2012Publication date: May 8, 2014Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Christian Seidel, Heinrich Zeininger
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Patent number: 8716365Abstract: An opacifying particle including a certain pigment particle at least partially encapsulated in a polymeric shell having a calculated thickness of from 35 nm to 200 nm, the polymeric shell including at least a first polymer phase and a second polymer phase, wherein the first polymer is substantially in contact with the surface of the pigment particle providing a calculated shell thickness of at least 25 nm and wherein the first polymer has a refractive index of at least 0.03 units less than that of the second polymer is provided. Further provided is a composition including certain pigment particles at least partially encapsulated in a shell of a first polymer having a calculated thickness of from 25 nm to 200 nm, and the encapsulated pigment particles in contact with a second polymer, wherein the first polymer has a refractive index of at least 0.03 units less than that of the second polymer.Type: GrantFiled: April 5, 2011Date of Patent: May 6, 2014Assignee: Rohm and Haas CompanyInventor: Ward T. Brown
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Publication number: 20140061967Abstract: A polymer composite and its method of manufacture using a recycled multilayer material. An example of the recycled multilayer material is comprised of a polyethylene/polyethylene terephthalate/aluminum film that may be extruded with organic filler to obtain desirable performance in wood-substitute products such as deck boards, railing, fencing, pergolas, residential cladding/siding, sheet products, and other applications.Type: ApplicationFiled: September 4, 2013Publication date: March 6, 2014Applicant: CPG International, Inc.Inventors: Bruce STANHOPE, Burch E. ZEHNER, Bryan K. BUHRTS
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Patent number: 8664298Abstract: Phase separated self-healing polymeric wood coatings having a “biphasic” thermoset/thermoplastic morphology to achieve self-healing. The biphasic structure has: (i) a major “load-bearing” thermoset phase that has superior strength and performs major mechanical and structural functions, and (ii) a “self-healing” phase of a thermoplastic healing agent to repair the material and restore its mechanical and structural integrity after being damaged. The phase-separated morphology is achieved through phase separation via a reaction process. Methodologies for achieving the above mentioned “biphasic” structure in solvent borne thermally cured resin, waterborne resin, and solvent borne UV-curable resin are described.Type: GrantFiled: August 15, 2011Date of Patent: March 4, 2014Assignee: NEI CorporationInventors: Runqing Ou, Kenneth Eberts, Ganesh Skandan, Sau Pei Lee, Robert Iezzi, Daniel E. Eberly
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Patent number: 8628852Abstract: Disclosed are core-shell resin particles (C2) each comprising one or more film-like shell layers (P) comprising a resin (a) which is a polyurethane resin and a core layer (Q) comprising a resin (b). A core-shell resin particle (C2) is characterized in that the weight ratio between (P) and (Q) is from 0.1:99.9 to 70:30, the volatile content in the resin particle (C2) is not more than 2 weight %, and the content of vinyl resins in the resin (b) is not more than 30 weight %. Such resin particles have a uniform particle diameter and are excellent in electrostatic properties, thermal and storage stability and thermal characteristics.Type: GrantFiled: July 27, 2006Date of Patent: January 14, 2014Assignee: Sanyo Chemical Industries Ltd.Inventors: Takashi Akutagawa, Tsuyoshi Izumi
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Patent number: 8618202Abstract: The present invention relates to the use of surface-modified nanoparticles to alter the morphology and microstructure of polymer blends. The addition of surface modified nanoparticles to polymer blends comprised of immiscible polymers facilitates the uniform distribution of the dispersed phase of the polymer blend. In an embodiment, the present invention relates to a polymer blend comprising (1) a continuous phase comprising at least one polymer, monomer or oligomer, and a plurality of surface-modified nanoparticles, having a particle diameter of less than about 100 nanometers, distributed in the continuous polymer phase; and (2) a dispersed phase comprising at least one polymer, monomer or oligomer, wherein the continuous polymer phase and the dispersed polymer phase are immiscible.Type: GrantFiled: December 22, 2005Date of Patent: December 31, 2013Assignee: 3M Innovative Properties CompanyInventors: Jimmie R. Baran, Jr., Michael A. Johnson, James D. Laperre
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Patent number: 8592509Abstract: A method includes: (a) mixing in a first step a first polymer and a filler, (b) mixing in a second step a second polymer and a polyhydroxy compound, and (c) mixing in a third mixing step the mixtures resulting from steps (a) and (b) and optionally additional filler, wherein said first polymer and second polymer may be the same polymer or different polymers, and wherein steps (a) and (b) can occur simultaneously or consecutively.Type: GrantFiled: December 30, 2010Date of Patent: November 26, 2013Assignee: Bridgestone CorporationInventors: Zhong-Ren Chen, Steven Luo
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Coated metal pigment, method for production of the same, and coating composition containing the same
Patent number: 8580382Abstract: Provided are a coated metal pigment which can satisfy both the coating stability in use as an aqueous coating, i.e., water resistance, and the chemical resistance of coating films produced by application thereof at practically satisfactory levels; a method for producing the same; and an aqueous coating containing the same. The invention relates to a coated metal pigment including a metal pigment and a composite coating layer, wherein the composite coating layer includes an adhesion layer which is disposed on the surface of the metal pigment either in contact with the metal pigment or at an interposition of another layer and contains polysiloxane and/or silica, and a resin layer which is disposed on the surface of the adhesion layer either in contact with the adhesion layer or at an interposition of another layer.Type: GrantFiled: October 6, 2006Date of Patent: November 12, 2013Assignee: Toyo Aluminium Kabushiki KaishaInventors: Takayuki Sato, Taro Morimitsu, Shunichi Setoguchi, Yoshiki Hashizume -
Patent number: 8536267Abstract: Methods of surface modification of polymer particle are useful in the development of marking fluids. The surface modification includes saponifying one or more acrylic ester groups on a surface of the polymer particle.Type: GrantFiled: September 11, 2009Date of Patent: September 17, 2013Assignee: Hewlett-Packard Development Company, L.P.Inventors: Doris Pik-Yiu Chun, Hou T. Ng
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Patent number: 8536248Abstract: The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.Type: GrantFiled: September 24, 2010Date of Patent: September 17, 2013Assignee: UMG ABS, Ltd.Inventors: Masahito Nakamoto, Koichi Tezuka
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Patent number: 8530544Abstract: The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C?C—C?O and/or an a,b-unsaturated thiocarbonyl group C?C—C?S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N?C?O or thioisocyanate —N?C?S groups, and trivalent groups of formula >C?CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.Type: GrantFiled: March 27, 2009Date of Patent: September 10, 2013Assignee: PolyriseInventors: Vincent Gaud, Fabien Rouge
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Patent number: 8524804Abstract: A resin composition includes a fiber and a polyolefin resin and can provide a molded article having excellent mechanical strength such as flexural strength and impact resistance. The resin composition includes (i) a surface-treated fiber (A) which comprises 100 parts by weight of a fiber (A-I) comprising a polyalkylene terephthalate and/or a polyalkylene naphthalene dicarboxylate and 0.1 to 10 parts by weight of a sizing agent (A-II) adhered to the surface of the fiber (A-I), and (ii) a polyolefin resin modified with an unsaturated carboxylic acid and/or an unsaturated carboxylic acid derivative (a modified polyolefin resin (B)) as a resin component.Type: GrantFiled: January 22, 2009Date of Patent: September 3, 2013Assignees: Sumitomo Chemical Company, Limited, Teijin Fibers LimitedInventors: Katsuhisa Kitano, Kenji Watanabe, Kenji Atarashi, Shinichi Takahashi