Abstract: Dental material based on polymerizable (for example ethylenically unsaturated) monomers, epoxides, ormocers, liquid crystal monomers, oxethanes, spiro-orthoesters or spiro-carbonates as binders, a catalyst for cold, hot and/or photo-polymerization, and fillers, and a process for its preparation. Porous glass ceramics, a process for their preparation and uses thereof are also described. Dental materials according to the invention are suitable as alternative materials to the use of amalgam fillings.

Abstract: A highly filled polymer composition with improved properties comprising: a continuous matrix material; a filler material in an amount of 10 to 80 wt. % of said composition; a polymer plasticizer dispersed in said continuous matrix material in an amount of 0.5 to 15 wt. % of said filler; a filler coating material which coats said filler particles in the form of a continuous coating layer thus forming coated filler particles; a diffusion zone around said coated filler particles where said filler coating and said continuous matrix material are mutually diffused into one another wherein said filler coating material is distributed with concentration decreasing in the direction outward from said continuous coating layer.

Abstract: The invention relates to a highly orientated flaky pigment being excellent in plane orientation (leafing effect), wherein a hydrated metal oxide and one or more fluorine-containing phosphates represented by the general formulae (A) and (B) shown in below or salts thereof are covered on the surface of a flaky pigment with a pearl gloss. The general formulae: (A) (RfCnH2nO)mPO(OM)3−m (B) (RfSO2NRCnH2nO)mPO(OM)3−m wherein Rf is the same or different and represents linear or branched C3 to C21 perfluoroalkyl group or perfluoroxyalkyl group, n is 1 to 12, m is 1 to 3, M represents hydrogen, alkali metal, ammonium group or substituted ammonium group, and R represents hydrogen or C1 to C3 alkyl group. A process for producing said pigment in a wet process is also disclosed.

Abstract: Finely divided powdered rubbers containing filler which remain free-flowing even after exposure to mechanical stresses and to a process for the production thereof, in which the rubber powder is obtained in two precipitation steps, and to the use of these powders for the production of vulcanizable rubber compounds. The fillers used, which are both precipitated silicas and carbon blacks known in the rubber art, are surface-modifed by organosilicon compounds.

Abstract: A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1  (I) ≡Si—OCOR2  (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms. The polysiloxane is impregnated in an inert powder.

Abstract: A liquid addition curing type silicone rubber composition comprising (A) an addition curing type organopolysiloxane component and (B) reinforcing silica fines having a specific surface area of 50-600 m2/g and surface treated with an organosilicon compound so as to bear 3-20% by weight of carbon on their surfaces prevents thickening after mixing and has an extended pot life.

Abstract: The invention provides polyamide resin compositions with good mechanical properties and dimensional stability during water absorption. Polyamide resin composition, comprising 100 parts by weight of resin contents composed of (A) 60 to 98% by weight of polyamide resin, (B) 40 to 2% by weight of polyolefine resin having dicarboxylic acid anhydride groups, as well as (C) 0.3 to 30 parts by weight of triazine-containing layered silicate with intercalated triazine compound derivatives with at least one positive charge.

Abstract: A colorant composition capable of giving a coating film excellent in heat resistance and weather resistance which not only can have a single clear color, such as, blue, green, yellow, or the like, and be used for forgery prevention based on discrimination by means other than visible light rays, but also does not suffer color fading even at a high temperature of 350° C. to 600° C. The colorant composition comprises at least a powder comprising a base particle coated with a multilayered film comprising layers differing from each other in refractive index to make the base particle have an interference color, wherein the powder is dispersed in a dispersion medium.

Abstract: A process for modifying superabsorbent polymers is disclosed. The surface of a polymer containing hydrolyzed polyacrylonitrile in the form of particulates, is modified by crosslinking in a water/alcohol reaction mixture and in the presence of silica. The resulting product features improved absorbency under load and lesser degree of gel blocking.

Abstract: This invention relates to a process for the production of composite wood products. This process comprises a) applying a thixotropic binder composition to wood particles, and b) molding or compressing the wood particles treated with the binder to form a composite wood product. Suitable thixotropic binder compositions comprise a polymethylene poly(phenyl isocyanate) and a thixotropic agent having a viscosity of less than 1,000 cps at high shear.

Abstract: Vulcanizable elastomeric compositions having enhanced dampening properties, among other things, in which the elastomeric composition contains surface-treated barium sulfate particles formed of a plurality of barium sulfate particles and a reaction product of the barium sulfate and silicon-hydride containing polysiloxane integrally located on the surfaces of the barium sulfate particles. Vulcanized products thereof are also encompassed. The elastomeric compositions of this invention can be vulcanized to retain appropriate shapes to provide tire parts (e.g., treads), v-belts, conveyor belts, sealants, shoe parts, and so forth, having enhanced vibration and noise dampening attributes, but without adversely impacting other performance-related properties of the rubber products.

Abstract: A composition comprising a filler material, a chemical compound and a polymer. A preferred filler material comprises carbon black and preferred polymers include ethylene-containing polymers such as ethylene-propylene copolymer or ethylene-propylene terpolymers. The present invention also includes articles of manufacture incorporating the polymer compositions.

Abstract: A wet friction material contains a fibrous base, a filler, a friction adjuster and a binder. The binder contains a material having siloxane bond. For example, the binder is a product of hardening of a hydrolytic solution of a silicon alkoxide.

Abstract: The present invention relates to inorganic particles, with the exception of silica, comprising at least one functionalized polyorganosiloxane grafted over all or part of their surface, the said polyorganosiloxane being functionalized by: at least one alkoxy group, and at least one organic group chosen from alkyls, alkenyls, mercaptoalkyls, sulphoxides, epoxys, (meth)acryloyloxy groups, amino groups, hydroxyl groups, siloxy groups, ethers, ketones, esters, phosphorus-containing groups or polymer portions comprising vinylaromatic, ether, amide or sulphur repeat units. The invention also relates to the process for the preparation of these particles. It also relates to compositions comprising the said particles and at least one thermoplastic polymer, particularly polyolefins.

Abstract: Organopolysiloxane particles containing hydrosilylation catalysts (H) and organopolysiloxane (O) and having a particle size of 0.01-10 &mgr;m have, at least in the outermost shell, no glass-transition temperature, softening point or melting point in the range 20° C.-260° C. These organopolysiloxane particles enable the preparation of one-component, addition-crosslinking, thermocurable silicone compositions having a long shelf life.

Abstract: A curable ceramer composition, coated articles and methods for making and curing the composition. The curable ceramer comprises a fluoro/silane, a crosslinkable silane, a curable binder precursor, and a colloidal inorganic oxide. The ceramer has a long shelf life before cure and can be used to provide cured ceramer coatings and articles having stain resistance, abrasion resistance and hardness.

Abstract: An easily shaped evacuated porous stonelike body is impregnated in a consistent manner with a fluid polymer forming composition or molten polymer composition and solidified to form a polymeric matrix stone product bearing a striking resemblance to a natural rock in texture, structure, and formation exhibited throughout any substantial cross section. The polymeric composition is decoratively enhanced by the labyrinthic skeletal framework of the porous body and the skeletal framework is structurally enhanced by the polymeric composition. The method of forming the product closely duplicates the natural formation of most of the rocks exposed at the surface of the earth. Therefore, a wide range of stonelike textures are now available in a dimensional stock product of pre-determined size and shape. A wide range of chemical and physical properties are also possible depending upon the specific combination of porous bodies and solidified polymeric compositions.

Abstract: A mixture of a first aluminum hydroxide surface treated with a silicon-containing compound and having a mean particle size of 5-20 &mgr;m and a second aluminum hydroxide surface treated with a silicon-containing compound and having a mean particle size of 0.1-2.5 &mgr;m is blended in a silicone rubber composition comprising an organopolysiloxane, finely divided silica, and an organic peroxide. The silicone rubber composition cures into silicone rubber having sufficiently improved properties to serve as high-voltage electrical insulators, even when exposed to air polluted conditions or rigorous weather conditions.

Abstract: A phyllosilicate material is exfoliated by admixture of the phyllosilicate with water, and a solvent for a water-insoluble oligomer or polymer that is sorbed or electrostatically bonded to the inner surfaces of the phyllosilicate platelets after exfoliation of the phyllosilicate. Intercalation and exfoliation can be achieved via contact of the phyllosilicate with an organic solvent and water to electrostatically bond one or more polar moieties from the organic solvent to a metal cation on the platelet inner surfaces, so that after evaporation of the water used for intercalation of the organic solvent between phyllosilicate platelets, the platelets do not then collapse together, but remain exfoliated. After exfoliation of the phyllosilicate, the exfoliated platelets are contacted with a polymer/carrier composition that includes a water-insoluble polymer or water-insoluble oligomer, and a solvent for the water-insoluble polymer or oligomer.

Abstract: Sulfanylsilanes of the formula X1X2X3Si—A—S—SiR1R2R3 are prepared by reacting mercaptosilanes of the formula X1X2X3Si—Alkyl—SH with chlorosilanes Cl—SiR1R2R3. They are used as coupling agents in rubber mixtures.

Abstract: Emulsion delivery systems for applying anti-stick additives to polymer particles, provide free-flowing particles of polymers or polymer blends, that without the anti-stick additives tend to agglomerate. The agglomeration presents storage and handling difficulties. The anti-stick additives are selected from the group consisting of primary amides, secondary amides, ethylene bisamides, waxes, talc and silica.

Abstract: A substrate with an organic undercoat as bonding layer for a printing medium to be deposited subsequently on the substrate in a printing process is such that the organic undercoat contains fine grained constituents of organic and/or inorganic substances, whereby the surface of the inorganic constituents is treated or provided with a coating of organic substances. Suitable inorganic constituents are e.g. highly dispersed silica, the surface of which is treated with a resin or a polymer. Suitable compositions for the organic undercoat layer on the substrate are organic coatings based on many commercially available organic coating materials with an addition of e.g. 0.3 to 20 wt. % silica. By adding highly dispersed silica to the undercoat the adhesion between the undercoat and the printing medium can be greatly improved, also in the case of laser printing methods with small thermal energy.

Abstract: A method of preparing a surface treated barium sulfate product is disclosed which has improved dispersibility in end use applications such as polymeric formulations. The method includes mixing a silicon-hydride containing polysiloxane, in neat or in aqueous emulsion form, with a quantity of barium sulfate particles and then optionally drying the resultant mixture. The silicon-hydride containing polysiloxane is deposited on and chemically bonded to the surface of the barium sulfate particles.

Abstract: Solid blends of rubbery polymers and amorphous or crystalline polymers, said blends being free-flowing at temperatures lower than the glass transition temperature or crystalline melting temperature of the amorphous or crystalline polymer, are prepared by intimate mixing procedures. In general, said mixing conditions include high shear conditions sufficient to convert polymer A to dispersed particles coated with polymer B and produce a free-flowing blend.

Abstract: An anaerobically curable composition for use in sealing gas pipeline leaks, comprising an anaerobically curable base preparation and a filler, wherein the filler is a metal-containing filler having a substantially metal free barrier coat.

Abstract: A process for making a flowable powdered base suitable for use in the formulation of liquid silicone rubber compositions that can be cured to form silicone elastomers. The process comprises (A) fluidizing a reinforcing silica filler in a high-shear mixer, (B) maintaining the content of the mixer at a temperature below about 60.degree. C. while adding to the mixer a silylating agent, a nitrogen containing compound to facilitate the silylation reaction, and water thereby forming an essentially homogeneous mixture comprising a treated reinforcing silica filler; (C) adding a polydiorganosiloxane having a viscosity of about 0.03 to 300 Pa.s at 25.degree. C. to the mixer and forming a flowable powdered base having an average particle size of from about 1 to 1000 microns, and (D) heating the flowable powdered base under conditions sufficient to remove volatiles.

Abstract: A composite of a thermosetting resin with a metallic oxide, prepared by a process which comprises subjecting a metal alkoxide containing a silicon alkoxide and/or a low condensate thereof to hydrolysis and polycondensation in a solution of a phenolic resin and/or thermosetting resin containing a phenolic resin while effecting the removal of the solvents and/or curling reaction of the resins to incorporate a particulate metallic oxide having an average particle diameter of from 0.01 to 5 .mu.m homogeneously in the thermosetting resin with a good interfacial wettability without causing macroscopic phase separation, as well as a process for the preparation of such a composite of a thermosetting resin with a metallic oxide and a process for the preparation of a crack-free molded composite product. A tribological material such as bearing, brake and clutch material includes such a composite as an essential constituent.

Abstract: A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a compounding agent consisting of a silane coupling agent and a carbon black, calcium carbonate or stearic acid powder impregnated with a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000:.tbd.Si--OR.sup.1 (I).tbd.Si--OCOR.sup.2 (II)wherein, R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R.sup.2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.

Abstract: A rubber composition containing a filler having individual aggregates containing both large and small particles, where the small particles are grafted onto the surface of the large particles. The small particles range from 1 to 30 weight percent of the overall weight of the filler. The large particles range from 70 to 99 weight percent of the overall weight of the filler. The small particles range in size of from 1 to 16 nanometers in diameter and the large particles range in size of from 17 to 500 nanometers in diameter.

Abstract: The stability of colloidal metal oxide particles which have been encapsulated in a polymer resin is extended by the addition of a water-soluble polyacrylamide polymer.

Abstract: The present invention relates to particulate concentrate compositions formed by intercalation of a polymer polymerizing component into the galleries of a layered inorganic cation exchange composition initially in proton exchanged form and to the use of the particulate concentrates for the preparation of cured polymer-inorganic nanolayer hybrid composite compositions. The polymer polymerizing component comprising the particulate concentrate contains a basic group for reaction with the protons of the inorganic cation exchanger. Also, the polymer polymerizing component contains a functional group for polymerization reaction with a polymer precursor, a mixture of polymer precursors, or a polymer melt which is introduced into the galleries of the inorganic cation exchanger and reacts with the polymer polymerizing component to form a cured polymer-inorganic nanolayer hybrid composite.

Abstract: A silicone rubber composition for application as electrical insulation that cures into a highly water-resistant silicone rubber that has excellent electrical properties and in particular has excellent high-voltage electrical insulation properties. The silicone rubber composition comprises(A) polyorganosiloxane,(B) surface-treated aluminum hydroxide powder surface treated with an organosilane or organosilazane, and(C) curing agent.Also, the composition afforded by the addition of 1 to 200 weight parts (D) microparticulate silica to components (A) to (C).

Abstract: Vinyl halide resin compositions containing a metal compound stabilizer and coated acid absorber particles, where the coating consists of a tin-based coating or a complex calcium/zinc/strontium phosphate-based coating, are used to confer heat stability to such compositions. Use of the costabilizers of this invention results in economic advantages and material cost savings.

Abstract: A silicone emulsion composition is disclosed which comprises specific amounts of (A) a colloidal silica-silicone core/shell material comprising (a) from 80 to 5 wt % colloidal-silica cores and (b) from 20 to 95 wt % shells comprising a specific polyorganosiloxane containing ethylenically unsaturated groups, (B) a specific polyorganohydrogensiloxane, (C) a curing catalyst, (D) an emulsifying agent, and (E) water. Also disclosed is a process for producing a silicone powder which comprises bringing the silicone emulsion composition into contact with a liquid or a gas while heating the composition at a temperature of 25.degree. C. or a higher and keeping the same in a dispersed state to thereby cure the silicone in the form of a powder. The silicone emulsion composition can give an elastomer having excellent mechanical properties upon the removal of the volatile components by heating.

Abstract: A resin composite comprising an organophilic clay and an ionomer resin is provided. The organophilic clay is dispersed in the ionomer resin to have excellent mechanical properties. A method for producing a resin composite comprises the steps of adding an organophilic clay to an ionomer resin, melting the mixture of the clay and the ionomer resin by heating and shearing the mixture.

Abstract: Oligomeric organosilicon compounds are disclosed of the formula I ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 independently of one another denote H, (C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4) alkoxy, (C.sub.1 -C.sub.4) haloalkoxy, (C.sub.1 -C.sub.4)haloalkyl, phenyl, aryl or aralkyl andZ denotes an alkylidene radical having 0-6 carbon atoms, x can be a statistical average of 1-6 andn=1-150 and . . . means that z can be bonded either to the one or the other C atom, and the particular free valency is occupied by a hydrogen.and their use in rubber mixtures and for the production of shaped articles, in particular pneumatic tires.

Abstract: More than about 9/10 (by weight as a platinum group metal atom) of the necessary amount of a platinum group metal catalyst enclosed in a compound having a melting or softening point of 40-200.degree. C., less than about 1/10 (by weight as a platinum group metal atom) of the necessary amount of a platinum group metal catalyst, and an addition reaction retarder are blended in an organopolysiloxane composition comprising an organopolysiloxane containing alkenyl or hydroxyl radicals and an organohydrogenpolysiloxane. The composition has improved shelf stability, an increased pot life, good curing capability, and fast curing upon heating.

Abstract: Wax coated silica matting agent wherein the silica is an amorphous silica having a pore volume of at least 1.5 cm.sup.3 /g, preferably at least 1.8 cm.sup.3 /g. The wax coating is present in the range from 6% to 15% by weight of the matting agent and comprises a synthetic polyethylene wax.

Abstract: A polymer nanocomposite composition having sufficiently low air permeability to be usefull as a tire inner liner, among other things, is prepared by blending a layered material with a metal processible non-ionic first polymer having a number average molecular weight greater than 50,000 g/mole and a second non-ionic polymer compatible with the first polymer and having a number average molecular weight less than that of the first polymer.

Abstract: A flame-retardant thermoplastic resin composition, comprising 100 parts by weight of a thermoplastic resin, from about 5 to 100 parts by weight of an inorganic filler surface-treated with a phosphate represented by the following formula (A) and from about 5 to 50 parts by weight of an aromatic orthophosphate. ##STR1## wherein R.sup.1 represents an organic group having at least one ethylenic double bond capable of radical polymerization and containing from about 5 to 60 carbon atoms, and l is 1 or 2.

Abstract: The present invention relates to particulate concentrate compositions formed by intercalation of a polymer polymerizing component into the galleries of a layered inorganic cation exchange composition initially in proton exchanged form and to the use of the particulate concentrates for the preparation of cured polymer-inorganic nanolayer hybrid composite compositions. The polymer polymerizing component comprising the particulate concentrate contains a basic group for reaction with the protons of the inorganic cation exchanger. Also, the polymer polymerizing component contains a functional group for polymerization reaction with a polymer precursor, a mixture of polymer precursors, or a polymer melt which is introduced into the galleries of the inorganic cation exchanger and reacts with the polymer polymerizing component to form a cured polymer-inorganic nanolayer hybrid composite.

Abstract: Modified mineral fillers, derived from either a coarse particle kaolin clay or a coarse particle ATH, having excellent utility in thermoset polymers as low paste viscosity fillers are disclosed. The method of treatment involves the use of specific weight ratio combinations of a silane and a long chain aliphatic alcohol. The treatment of clay can also involve the auxiliary use of a surfactant in small amounts, which is utilized to emulsify the silane and aliphatic alcohol treatment components in water either individually or as a co-emulsion blend prior to their addition to the clay. The surfactant, which is preferably a nonionic surfactant having a HLB value of 12-18, aides in uniformly treating all the clay particle surfaces with the silane/alcohol treatment combination. Coarse particle clays having general utility in the invention are those having an average Stokes equivalent particle diameter of at least 3.

Abstract: An epoxy and polyurethane-based sizing composition for fibers used in the reinforcement of engineered thermoplastic molded composites, which exhibits improved hydrolytic stability and reduced discoloration.

Abstract: The present invention discloses blends of silanes and specific silicas, characterized in that when the blend is compounded into a rubber formulation even after 4 months of storage following formation of the blend, an unexpectedly high proportion of the silane present is available as a coupling and reinforcing agent for the rubber formulation. Over 80% and even over 90% of the silica can be extracted or described from the blend even 4 months after formation of the blend, and rubber formulation properties indicate high availability of the silane for coupling and reinforcement.

Abstract: A dental resin material which is formed into a dental prosthesis by milling processing is disclosed, comprising an acrylic resin polymer containing from 20 to 70% by weight of an inorganic filler having a mean particle size of from 0.01 to 0.04 .mu.m in diameter. A process for producing a dental resin material is also disclosed, which comprises polymerizing for curing a mixture comprising a combination of from 20 to 70% by weight of an inorganic filler having a mean particle size of from 0.01 to 0.04 .mu.m in diameter, a methacrylate or acrylate monomer having at least one unsaturated double bond, and a heat polymerization initiator while elevating the pressure and heating under the conditions that the pressure is from 50 to 300 MPa and that the temperature is from 100 to 200.degree. C.

Abstract: The invention relates to polyurethane compositions and especially to elastic polyurethane fibers resulting therefrom which can be employed for swimwear in aqueous, chlorine-containing environments such as swimming pools, for example. The invention relates in particular to polyurethane compositions and especially to elastic polyurethane fibers resulting therefrom that contain hydrotalcites and/or other basic metal aluminium hydroxy compounds coated with polyorganosiloxane or with a mixture of polyorganosiloxane and polyorganohydrogensiloxane.

Abstract: Nanocomposites are made by melt-blending a melt processable polymer having a high melt processing temperature and an organophosphonium cation modified layered clay. Such modified layered clay is more stable at the higher temperatures encountered during the melt processing of such a melt processable polymer than the modified layered clays used in the prior art, enabling the preparation of the nanocomposite.

Abstract: Polymer (e.g., poly(ethylene oxide) or polystyrene is intercalated into galleries of 2:1 layered silicate in the absence of solvent to provide composite where the polymer does not demonstrate melting or glass transition. In a variation, polymer (e.g., polyamide) matrix containing layers of silicate of height less than 1 nanometer is produced by delaminating layers of silicate during the intercalation.

Abstract: Alkoxy-functional room temperature vulcanizing (RTV) compositions, curable in the presence of moisture, comprising polymers containing on average at least 1.2 alkoxysilyl chain terminations per molecule, a tetraalkoxytitanium compound containing on average greater than 90 mole percent of the alkoxy groups as tertiary amyloxy groups, a filler, and an alkoxysilane. The addition of these components in amounts to satisfy defined molar ratios provide alkoxy-functional RTV compositions having both improved storage stability and improved green strength upon curing.

Abstract: There is disclosed a composite powder composition which has excellent flowability and water repellency and finds utility as a modifier for paints and organic resins, said composition comprising:(A) 100 parts by weight of a cured silicone powder that has an average particle size of 0.1 to 500 micrometers and contains 0.5 to 80 weight percent of a non-crosslinking oil; and(B) 0.1 to 100 parts by weight of a microfine inorganic powder, said inorganic powder being coated on the surface of said cured silicone powder.