Product Having Elemental Carbon Patents (Class 523/215)
  • Patent number: 5744520
    Abstract: A process for the preparation of polymer compositions which comprises mixing a conductive component with an anionic polymeric latex containing a polymer; adding a cationic surfactant, or flocculant whereby the aggregation of the latex particles and the conductive component particles results; subsequently adding colloidal stabilizer, followed by the addition of a base to obtain a pH of from about 7 to about 12; heating above about the polymer glass transition temperature thereby enabling the severage, or breakage of the formed aggregated particles; further heating above about the polymer glass transition temperature enabling the coalescence of the polymer and conductive component particles; and optionally washing and drying the resulting coalesced product.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: April 28, 1998
    Assignee: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Richard P. N. Veregin, Raj D. Patel, Michael A. Hopper, Maria V. McDougall
  • Patent number: 5728766
    Abstract: Compounds having improved properties of processability and elasticity after heat aging for molded and extruded rubber parts can be prepared by utilizing improved processability EPM and/or EPDM rubber with effective amounts of carbon black prepared in a manner such that it has an average particle size of from 70 to 120 nanometers, a particle size distribution including from 40 to 225 nanometers sized particles, a surface area of 16 to 30 m.sup.2 /g as measured by the BET adsorption, and a structure of 90 to 125 as measured by DBP absorption. The EPM and EPDM rubber useful in accordance with the invention will include those multimodal polymer blends that comprise at least two fractions having different molecular weight and, optionally, monomer composition. The invention compounds find particular use in automotive industry parts requiring high temperature tolerance, such as coolant hoses.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: March 17, 1998
    Assignee: Exxon Chemical Co.
    Inventors: Jean-Roch Hector Schauder, Timothy Arthur Mills
  • Patent number: 5725650
    Abstract: A treated carbon black may be produced by treating carbon black with at least one polyethylene glycol having a molecular weight of from about 1,000 to about 1,000,000. The treated carbon black may be used in forming polymeric compositions, such as semi-conductive and insulating compounds, for example for use in electrical cables.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: March 10, 1998
    Assignee: Cabot Corporation
    Inventors: Cindy L. Flenniken, Jameel Menashi, Robert S. Whitehouse
  • Patent number: 5726238
    Abstract: A material composed of carbon compounds may be shaped into high-quality moulded bodies, foils, plates, pipes or the like by all usual plastics processing machines, and may further be reused several times with no perceptible loss of quality. Above all, it may be disposed of by incineration with a high calorific value without fouling the incineration plants or polluting the atmosphere with toxic, harmful substances in an inadmissible manner.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: March 10, 1998
    Assignee: Citadel Investments Limited
    Inventor: Klaus-Dietrich Nickel
  • Patent number: 5708055
    Abstract: What is disclosed is an improved thermoplastic composition for use in wire and cable manufacturing processes, which features the use of from about 15 to 45 percentage by weight of a modified furnace carbon black having a specific surface area of from about 35 to 250 m.sup.2 /g, preferably 35 to 60 m.sup.2 /g, as measured by the nitrogen adsorption surface area method. The modified carbon black is prepared by combining the carbon black with a specified amount of amine, under certain conditions, and heating the reactive mixture for an extended period.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: January 13, 1998
    Assignee: Columbian Chemicals Company
    Inventors: George Alfred Joyce, Edward Lester Little
  • Patent number: 5703144
    Abstract: Furfuryl alcohol-formaldehyde resins in solid form.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: December 30, 1997
    Assignee: QO Chemicals, Inc.
    Inventor: Denis W. Akerberg
  • Patent number: 5679728
    Abstract: A rubber composition containing a cross-linkable rubber component and a carbon black having silica adhered to the surface thereof and a silica surface-treated carbon black suitable for use in tire tread where the surface-treated carbon black has a nitrogen specific surface area (N.sub.2 SA) of 20 to 300 m.sup.2 /g, a ratio IA.sub.o /IA.sub.f of the adsorption amount of iodine (IA.sub.o) and the adsorption amount of iodine after treatment by hydrogen fluoride (IA.sub.f) of at least 0.30 but less than 1.0, and a ratio IA.sub.e /IA.sub.ef of the adsorption amount of iodine after extraction from a rubber compound (IA.sub.e) and the value of the same after treatment by hydrogen fluoride (IA.sub.ef) of at least 0.30 but less than 1.0.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: October 21, 1997
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Tetsuji Kawazura, Hiroyuki Kaido, Kouichi Ikai, Fumito Yatsuyanagi, Masayuki Kawazoe
  • Patent number: 5677372
    Abstract: An improved adhesion or bonding between diamond fibers and a matrix of at least one organic polymer such as a resin is achieved in a composite material reinforced with vapor-deposited diamond. To improve bonding to the matrix, hydrogen is removed from the surface of vapor-deposited diamond fiber. This can be achieved by heating the diamond under an oxidative atmosphere at a temperature of about 150.degree. C. to about 800.degree. C., or under a non-oxidative atmosphere at a temperature of about 800.degree. C. to about 1500.degree. C. The surface of the vapor-deposited diamond, which contains not more than about 1.times.10.sup.15 /cm.sup.2 of hydrogen atoms, is bonded to the matrix of resin for example with sufficient strength. To further improve bonding, diamond doped with B or N is employed as the reinforcing material or at least a surface layer thereof.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: October 14, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yoshiyuki Yamamoto, Takahiro Imai, Takashi Tsuno, Naoji Fujimori
  • Patent number: 5654395
    Abstract: This invention relates to a method of preparing a reinforced polyester composition comprising the steps of:I. mixing(a) at least one cyclic ester oligomer selected from the group consisting of ethylene terephthalate and cyclohexylenedimethylene terephthalate,(b) an organic initiator comprising one to five hydroxy groups which are capable of opening the cyclic ester rings,(c) a catalyst, and(d) a reinforcing material,II. heating the mixture of I at a temperature ranging from 270.degree. C. to 320.degree. C.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: August 5, 1997
    Assignee: Eastman Chemical Company
    Inventors: Winston Jerome Jackson, Jr., William Ronald Darnell
  • Patent number: 5639807
    Abstract: Carbon fiber pellets having improved flow characteristics are prepared by mixing chopped or milled carbon fibers with a solution or suspension of a sizing agent, shaping the agglomerated mixture on a tilted rotating surface to provide dense pellets of streamlined shape and drying the pellets. The carbon fiber pellets are especially suitable for use in the manufacture of reinforced thermoplastic resins.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: June 17, 1997
    Assignee: Akzo Nobel nv
    Inventors: Duane R. Secrist, William M. Jenkins
  • Patent number: 5614570
    Abstract: A method of producing easily densified high bulk fibers that have adhered particulates. The fibers have hydrogen bonding or coordinate covalent bonding functionalities, and a binder is applied to the fibers to bind the particles to the fibers. The binder has a functional group that forms a hydrogen bond or a coordinate covalent bond with the particles, and a functional group that forms a hydrogen bond with the fibers. A substantial portion of the particles that are adhered to the fibers are adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder is in turn adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: March 25, 1997
    Assignee: Weyerhaeuser Company
    Inventors: Michael R. Hansen, Richard H. Young, Sr.
  • Patent number: 5610237
    Abstract: A functionalized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: March 11, 1997
    Assignee: Bridgestone Corporation
    Inventors: David F. Lawson, Thomas A. Antkowiak, James E. Hall, Mark L. Stayer, Jr., John R. Schreffler
  • Patent number: 5604289
    Abstract: Thermoplastic material comprising at least one thermoplastic polymer and 1 to 1000 ppm (by weight) of at least one substance which substantially absorbs infrared radiation, such as carbon black. The reinforcement-fibre bundles impregnated with a thermoplastic polymer, in accordance with the invention, are particularly advantageous for reinforcing pipes by filament winding.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: February 18, 1997
    Assignee: Solvay (Societe Anonyme)
    Inventor: Didier Delimoy
  • Patent number: 5571852
    Abstract: Disclosed are structures comprising a composite of fluorinated particulate carbon dispersed in a polymer, the fluorinated carbon being present in an amount sufficient to reduce the dielectric constant of the composition, the structure also including electrical conductor patterns.The composite can be made conductive by irradiating it with an UV excimer laser.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 5, 1996
    Assignee: International Business Machines Corporation
    Inventors: Ali Afzali-Ardakani, Juan Ayala-Esquilin, Bodil E. Braren, Shahrokh Daijavad, Elizabeth Foster, James L. Hedrick, Jr., Jeffrey C. Hedrick, Rodney T. Hodgson, Ashit A. Mehta, Steven E. Molis, Jane M. Shaw, Stephen L. Tisdale, Alfred Viehbeck
  • Patent number: 5559169
    Abstract: A rubber composition prepared by the process comprising mixing 100 parts by weight of a rubber selected from EPDM, HNBR, and butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group. The organic group has the formula --Ar--S.sub.n --Ar'-- in which Ar and Ar' are arylene groups or --Ar--S.sub.n --Ar" in which Ar is an arylene group, Ar" is an aryl group and n is 1 to 8.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: September 24, 1996
    Assignee: Cabot Corporation
    Inventors: James A. Belmont, Thomas F. Reed
  • Patent number: 5556899
    Abstract: Disclosed is a process of effecting a change in the dielectric constant and coefficient of thermal expansion of a polyimide material, by forming a composite based on a dispersion of 2-60 wt. % of fluorinated particulate carbon material and a polyimide or polyimide precursor, and heating the dispersion to about 400.degree. C. at 65.degree.-200.degree. C./second.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: September 17, 1996
    Assignee: International Business Machines Corporation
    Inventors: Ali Afzali-Ardakani, Juan Ayala-Esquilin, Bodil E. Braren, Shahrokh Daijavad, Elizabeth Foster, James L. Hedrick, Jr., Jeffrey C. Hedrick, Rodney T. Hodgson, Ashit A. Mehta, Steven E. Molis, Jane M. Shaw, Stephen L. Tisdale, Alfred Viehbeck
  • Patent number: 5504137
    Abstract: The present invention relates to a rubber composition containing silica reinforcement and to pneumatic tires having treads comprised of such rubber composition.A rubber composition comprises at least one elastomer, silica, carbon black and a silica coupler comprised of nicotinamide.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: April 2, 1996
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul H. Sandstrom, Lawson G. Wideman
  • Patent number: 5458973
    Abstract: A granular filler comprising a particulate inorganic material; from 0.1% to 10% by weight, based on the weight of the organic material, of fine carbon black; and sufficient amount of a natural or synthetic latex composition to provide from 1% to 10% by weight of elastomer solids, based on the weight of the inorganic material, wherein the granules have diameters within the range of from 0.01 mm to 0.1 mm.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: October 17, 1995
    Assignee: ECC International Ltd.
    Inventor: David G. Jeffs
  • Patent number: 5447977
    Abstract: A method of producing easily densified high bulk fibers that have adhered particulates. The fibers have hydrogen bonding or coordinate covalent bonding functionalities, and a binder is applied to the fibers to bind the particles to the fibers. The binder has a functional group that forms a hydrogen bond or a coordinate covalent bond with the particles, and a functional group that forms a hydrogen bond with the fibers. A substantial portion of the particles that are adhered to the fibers are adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder is in turn adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: September 5, 1995
    Assignee: Weyerhaeuser Company
    Inventors: Michael R. Hansen, Richard H. Young, Sr.
  • Patent number: 5416156
    Abstract: A surface coating composition comprising, in combination, a fibrillated polymer matrix, at least one pigment, at least one binder, and at least one solvent, and a method for the manufacture thereof.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: May 16, 1995
    Assignee: Revlon Consumer Products Corporation
    Inventor: Melvin E. Kamen
  • Patent number: 5401574
    Abstract: A sliding member comprising a fluorine resin and carbon fibers treated with a fluorine-containing silane modifying agent represented by the formula R.sup.1 -SiX.sub.3 wherein R.sup.1 represents an alkyl group having from 1 to 10 carbon atoms, a part or the whole of the hydrogen atoms of which are replaced with fluorine atoms and X represents a hydrolyzable group or a chlorine atom.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: March 28, 1995
    Assignee: Nitto Denko Corporation
    Inventors: Noboru Masutani, Junichi Nakazono
  • Patent number: 5397807
    Abstract: Disclosed is a compatibilized carbon black useful in melt processing of plastic material. The carbon black is coated with a compatibilizing agent which enhances the dispersibility of the carbon black in a melt of the plastic material. Further disclosed are processes for making plastic foam structures with the compatibilized carbon black.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: March 14, 1995
    Assignee: The Dow Chemical Company
    Inventors: Martin K. Hitchcock, Kyung W. Suh, Arnold M. Bartz, Andrew N. Paquet, William G. Stobby
  • Patent number: 5369146
    Abstract: A sizing formulation adapted for use with carbon fiber yarn comprising an aqueous dispersion of a film-forming, heat-reactive resin having a Tg below about -50.degree. C. and a water-dispersible ethoxylated alkyl phenol provides yarn having improved resistance to abrasion, less breakage and low fuzz formation, permitting substantial handling of the fiber in fabrication and weaving operations with reduced losses. In addition, the sizing may be readily removed thermally without the production of noxious byproducts when deemed necessary for use in further processing and impregnation operations.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: November 29, 1994
    Assignee: Amoco Corporation
    Inventors: James D. Miller, Chris D. Levan
  • Patent number: 5369143
    Abstract: Inorganic fiber such as carbon fiber is modified by a surface treatment with a dinitrodiamine compound represented by the formula of ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen, an aliphatic group, an alicyclic group or an aromatic group, with the proviso that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, with the proviso that R.sup.2 and R.sup.3 may conjointly form a ring. The inorganic fiber thus modified is useful for reinforcement of resins.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: November 29, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Isao Kurimoto, Naoki Inui, Kohji Yamatsuta, Hitoshi Murotani, Hideo Nagasaki, Shinichi Yachigo
  • Patent number: 5362482
    Abstract: A water-in-oil type emulsified solid composition containing (a) an oil component such as a silicone oil, (b) a solid wax and/or an oil-gelling agent, (c) water, and (d) (i) a polyoxyalkylene modified organopolysiloxane or (ii) a lipophilic surfactant and a hydrophobically treated powder, wherein the water content is 5% by weight or more, based upon the total amount of the composition.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: November 8, 1994
    Assignee: Shiseido Company Ltd.
    Inventors: Toshio Yoneyama, Yasuo Matsuoka, Harumi Suzuki, Shigenori Kumagai, Susumu Takada
  • Patent number: 5338789
    Abstract: A fiber-reinforced molding composition, comprising:a) 97 to 50% by weight, relative to the sum of (a) and (b), of a mixture of 30 to 100 parts by weight of a polyphenylene ether, 0 to 70 parts by weight of a styrene polymer, 0 to 10 parts by weight of a polyoctenylene and 0.1 to 2.5 parts by weight of an .alpha.,.beta.-unsaturated carboxylic acid derivative or a precursor thereof;b) 3 to 50% by weight of carbon fibers and/or glass fibers whose surfaces bear functional groups which are capable of entering into chemical coupling reactions with the .alpha.,.beta.-unsaturated carboxylic acid derivatives; and optionallyc) dyes, pigments, plasticizers, flame retardant additives, processing auxiliaries, other customary additives or combinations thereof.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: August 16, 1994
    Assignee: Huels Aktiengesellschaft
    Inventors: Thomas Grosse-Puppendahl, Christian Baron, Friedrich G. Schmidt
  • Patent number: 5321071
    Abstract: The present invention provides a short-fiber containing composition inhibited from electrostatic charging and having practical insulating properties. This composition has a volume resistivity of 10.sup.5 -10.sup.13 .OMEGA.cm and comprises 10-40 parts by weight of at least one kind of short fibers having a volume resistivity of 10.sup.-1 -10.sup.3 .OMEGA.cm and 90-60 parts by weight of a polymer or comprises 10-40 parts by weight of a mixture comprising at least one kind of short fibers having a volume resistivity of less than 10.sup.-1 .OMEGA.cm and at least one kind of short fibers having a volume resistivity of 10.sup.-1 .OMEGA.cm or more and 90-60 parts by weight of a polymer. A method for controlling the polymer composition to 10.sup.5 -10.sup.13 .OMEGA.cm in volume resistivity is also provided.
    Type: Grant
    Filed: October 27, 1992
    Date of Patent: June 14, 1994
    Assignees: Nitto Boseki Co., Ltd., Kawasaki Steel Corporation, Mitsubishi Gas Chemical Company, Inc.
    Inventors: Eiji Fujisawa, Yasunobu Isobe, Hiroaki Shono
  • Patent number: 5308896
    Abstract: A method of producing easily densified high bulk fibers that have adhered particulates. The fibers have hydrogen bonding or coordinate covalent bonding functionalities, and a binder is applied to the fibers to bind the particles to the fibers. The binder has a functional group that forms a hydrogen bond or a coordinate covalent bond with the particles, and a functional group that forms a hydrogen bond with the fibers A substantial portion of the particles that are adhered to the fibers are adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder is in turn adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: May 3, 1994
    Assignee: Weyerhaeuser Company
    Inventors: Michael R. Hansen, Richard H. Young, Sr.
  • Patent number: 5290821
    Abstract: An electro-responsive elastomeric material comprising (A) an electrically insulating polymer having a specific modulus of elasticity and (B) a fine powder dispersed in the polymer which electrically polarizes under an electric field independent of water changes its viscoelasticity upon voltage application. The powder has a mean particle size of 0.5 to 500 .mu.m and is (1) a fine carbonaceous powder having a C/H atomic ratio of from 1.2 to 5, (2) composite particles having minute particulates of an insulating material dispersed in a matrix phase of a carbonaceous or carbide material, (3) composite particles having minute particulates of a carbonaceous or carbide material dispersed in a matrix phase of an insulating material, or (4) a fine composite powder of a stratum clay mineral having a two-dimensional stratum structure with a carbonaceous or carbide material incorporated between the strata.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: March 1, 1994
    Assignee: Bridgestone Corporation
    Inventors: Ryo Sakurai, Yasuo Kurachi, Yoshiki Fukuyama, Takayuki Maruyama, Tasuku Saito
  • Patent number: 5238542
    Abstract: Cyclic (and preferably aromatic) N-substituted methacrylamide monomers are electropolymerized onto electrically conductive (e.g., graphite) filler (e.g., fibers, plates, film or cloth) to form a novel polymer composite exhibiting high Tg as well as a controlled degree of cross-linking which can prevent flow at high temperature.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: August 24, 1993
    Assignees: The University of Connecticut, United Technologies Corporation
    Inventors: James P. Bell, Daniel A. Scola, Jengli Liang
  • Patent number: 5232560
    Abstract: In accordance with the present invention, electropolymerization in a substantially aqueous solution is used to form thick (e.g. greater than 2 microns or 30 weight %) and thermally stable coatings of thermoplastic materials onto electrically conductive filler materials (e.g. rods, plates, fibers). In a preferred embodiment, the thick thermoplastic matrix comprises a copolymer of 3-carboxyphenyl maleimide and styrene. This invention is particularly well suited for direct preparation of thermoplastic prepregs containing commercially available bundles of graphite fibers. These prepregs are then molded under heat and pressure so as to form a thermoplastic matrix composite with good fiber distribution, uniformity and high temperature resistance.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: August 3, 1993
    Inventors: James P. Bell, Jude O. Iroh, D. Scola
  • Patent number: 5223556
    Abstract: Resin compositions having excellent mechanical strength, especially at high temperatures are disclosed. The resin compositions comprise 95-60 wt. % of an aromatic polyetherketone having recurring units represented by the following formula: ##STR1## 5-40 wt. % of a polyetherimide having recurring units represented by the following formula: ##STR2## Also disclosed are fiber-reinforced resins, which comprise 75-55 wt. % of one of the above compositions and 25-45 wt. % of carbon fibers obtained by coating starting carbon fibers with an aromatic polysulfone resin and then heating the thus-coated carbon fibers at 300.degree.-400.degree. C., and mechanical components made of desired one of the fiber-reinforced resins which are suitable for use in internal combustion engines or auxiliary equipment.
    Type: Grant
    Filed: September 22, 1992
    Date of Patent: June 29, 1993
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Nissan Motor Co., Ltd.
    Inventors: Yoshihisa Gotoh, Toshihiko Tsutsumi, Toshiaki Takahashi, Takatoshi Sagawa
  • Patent number: 5218012
    Abstract: The present invention relates to a process for coating reinforcing elements preferably in fiber form, wherein said material is treated, between two electrodes, by the field obtained by means of a direct electric current of voltage included between 50 and 150,000 V and/or by means of an alternating electric current of frequency between 50 and 1,000 Hz and of voltage included between 10,000 and 30,000 V, and said element is placed in contact with a powder of a conductive or semi-conductive material.
    Type: Grant
    Filed: November 15, 1990
    Date of Patent: June 8, 1993
    Assignee: Pradom Limited
    Inventor: Michel Berger
  • Patent number: 5212222
    Abstract: Melt-stable polyacetal molding compositions include a polyacetal base resin, and a carbon black-impregnated ethylenic carrier polymer in amounts to yield between about 0.1 to 30 parts by weight of carbon black. The ethylenic carrier polymer is preferably present in an amount between 0.3 to 8 times by weight of the carbon black impregnated therewithin. The compositions of this invention further contain a co-stabilization package which includes a first stabilizer selected from nitrogen-containing compounds, fatty acid ester compounds, and metal-containing compounds which contain a hydroxide, an inorganic acid salt or a carboxylic acid salt of an alkali metal or an alkaline earth metal, and a second stabilizer which is a hindered phenolic compound. Preferably, the first and second stabilizers are each used in amounts between 0.01 to 5 parts by weight, based on 100 parts by weight of the polyacetal base resin.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: May 18, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventors: Masamichi Mitsuuchi, Tsuyoshi Minamisawa, Hiroshi Kitamura, Hideo Kakizaki
  • Patent number: 5140071
    Abstract: A sizing agent for carbon fibers and glass fibers is based on an aqueous dispersion containing an epoxy resin and from 5 to 40% by weight, based on the epoxy resin, of a nonionic emulsifier containing teritary amino groups and/or ether linkages and at least one functional radical capable of reaction with the epoxy resin, preferably a glycidyl radical, and also at least one emulsifying radical which preferably carries a polyethylene glycol group in the terminal position.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: August 18, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Joerg Kroker, Silvio Vargiu
  • Patent number: 5124372
    Abstract: A non-sag agent useful in providing non-sag properties to many conventional curable, polymeric adhesives and sealants, said agent comprising:a first component comprising crush resistant coated particles wherein the first component particles are less than about 1 and 1/2 microns in size and have a coating of about 0.1% to about 10% by weight of the particle and wherein said coating substantially comprises a first surface modifying agent,a second component comprising crush resistant coated particles wherein the second component particles are about 1 and 1/2 to about 3 microns in size and have a coating of about 0.
    Type: Grant
    Filed: November 15, 1990
    Date of Patent: June 23, 1992
    Assignee: Tremco Incorporated
    Inventors: Annette F. Katona, Steve L. Hannah
  • Patent number: 5093389
    Abstract: A room temperature-curable composition comprising (A) a silanol-terminated polydiorganosiloxane having a viscosity measured at 25.degree. C. of from 100 to 200,000 cSt, (B) an epoxy-terminated polyether, (C) an organosilicon compound, (D) an inorganic filler, and (E) a curing catalyst. The composition is suitably used as a building sealant which causes no fouling of the areas surrounding joints even after applied to the joints.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: March 3, 1992
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Chiyuki Shimizu
  • Patent number: 5071891
    Abstract: A coating composition for a particulate filler comprising an organic oligomer containing a plurality of oxy groups, less than 15% of which are comprised in hydroxy groups, organic oligomer components thereof, fillers coated with the coating compositions, organic polymer matrices filled with a dispersion of the coated filler, and processes for the preparation of the oligomer components, the coating compositions, the coated fillers and the filled matrices, and precursors of the coating compositions.
    Type: Grant
    Filed: July 5, 1990
    Date of Patent: December 10, 1991
    Assignee: Imperial Chemical Industrial PLC
    Inventors: David L. Harrison, Louis P. Bates
  • Patent number: 5001171
    Abstract: It now has been found that uncured modified rubber compositions comprising mixtures of elastomers and a reinforcing filler can be prepared having improved properties.
    Type: Grant
    Filed: October 21, 1988
    Date of Patent: March 19, 1991
    Assignee: Bridgestone/Firestone, Inc.
    Inventors: Georg G. Bohm, Daniel F. Graves
  • Patent number: 4940749
    Abstract: A carbon black-graft polymer, produced by causing a polymer possessing within the molecular unit thereof at least one reactive group selected from the class consisting of aziridine group, oxazoline group. N-hydroxyalkylamide group, epoxy group, and thioepoxy group to react with carbon balck. The polymer can be used as a toner for electrostatically charged image, resin composition, coating composition, ink for thermographic transer, coating gent for magnetic recording medium, rubber composition, and carbon black dispersion and the like.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: July 10, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hayato Ikeda, Nobuaki Urashima, Masuji Izubayashi, Shigeru Tanimori, Yoshihiro Arita, Kiyoshi Kawamura, Kenji Minami, Yoshinori Sano
  • Patent number: 4918117
    Abstract: Polymer composites reinforced with carbon fibers coated with polybutadiyne and the coated fibers are described. The polybutadiyne coating is formed in a closely adherent film on or slightly below the surface of carbon fibers by substantially simultaneously vapor depositing and polymerizing butadiyne on the fiber.
    Type: Grant
    Filed: October 12, 1988
    Date of Patent: April 17, 1990
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Arthur Snow, James P. Armistead
  • Patent number: 4902730
    Abstract: Improved fiber reinforcement of polyarylene sulphides is achieved by preparing the polyarylene sulphides in the presence of reinforcing fibers pretreated with arylsulphonic acid chlorides at elevated temperatures.
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: February 20, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz Reichert, Ingo Koschinski
  • Patent number: 4895785
    Abstract: A toner particle composition substantially spherical in form and comprising binder resin and carbon black dispersed thereon, the surface area of the particle being covered with the carbon black in an amount not greater than 25 percent of the entire surface area of the toner particle.
    Type: Grant
    Filed: January 3, 1989
    Date of Patent: January 23, 1990
    Assignee: Kao Corporation
    Inventors: Yoshiaki Torimoto, Yoshitsugu Shirasaki
  • Patent number: 4882370
    Abstract: A fiber reinforced composite structure having a glass transition temperature greater than 150.degree. C. is comprised of:a) reinforcing fiber andb) a curable epoxy resin composition comprising(i) one or more epoxides having more than one epoxide group per molecule, of which epoxides at least 10 percent by weight is a 9,9-bis[4-(2,3-epoxypropoxy)phenyl]fluorene, all of the fluorene epoxy present being free of ortho substitution;(ii) an effective amount of one or more epoxy curing agents.
    Type: Grant
    Filed: January 27, 1988
    Date of Patent: November 21, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robert C. Jordan, Gene B. Portelli
  • Patent number: 4880857
    Abstract: A carbon black-graft polymer, produced by causing a polymer possessing within the molecular unit thereof at least one reactive group selected from the class consisting of aziridine group, oxazoline group. N-hydroxyalkylamide group, epoxy group, and thioepoxy group to react with carbon black. The polymer can be used as a toner for electrostatically charged image, resin composition, coating composition, ink for thermographic transer, coating gent for magnetic recording medium, rubber composition, and carbon black dispersion and the like.
    Type: Grant
    Filed: December 16, 1987
    Date of Patent: November 14, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hayato Ikeda, Nobuaki Urashima, Masuji Izubayashi, Shigeru Tanimori, Yoshihiro Arita, Kiyoshi Kawamura, Kenji Minami, Yoshinori Sano
  • Patent number: 4861809
    Abstract: A friction material containing from about 0.5-29 wt % of carbonaceous fibers with a bond nitrogen content of from about 14 to 21 wt %, an auxiliary material and a thermosetting resin. The material has good wear and temperature resistance characteristics and can be used in power transmissions and brakes.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: August 29, 1989
    Assignee: Toho Rayon Co., Ltd.
    Inventors: Hiroyasu Ogawa, Kenji Shimazaki, Kenji Niijima
  • Patent number: 4857385
    Abstract: A coating of a viscous lubricant applied prior to stretch-breaking permits forming slivers of stretch-broken carbon fibers. When an anti-static ingredient is added to the viscous lubricant cohesive slivers of stretch-broken glass fibers can be formed. composites of matrix resin reinforced with these slivers exhibit high strength, tensile stiffness, and good formability.
    Type: Grant
    Filed: June 10, 1988
    Date of Patent: August 15, 1989
    Assignee: E. I. Du Pont De Nemours and Company
    Inventors: Thomas E. Armiger, David H. Edison, Herbert G. Lauterbach, James R. Layton, Richard K. Okine
  • Patent number: 4847145
    Abstract: Disclosed is a film for keeping freshness of vegetables and fruit which has an ethylene-adsorptive activity. The film preferably contains a fine-porous material. According to the film, the ethylene gas evolved from vegetables and fruit can be very effectively removed and thus freshness of vegetables and fruit can be maintained.
    Type: Grant
    Filed: July 17, 1987
    Date of Patent: July 11, 1989
    Inventor: Mitsuo Matsui
  • Patent number: 4820751
    Abstract: A rubber composition for tires having improved heat build-up and high temperature reinforcibility comprises specified amounts of particular surface-treated carbon black, silica and particular silane coupling agent based on 100 parts by weight of rubber ingredient.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: April 11, 1989
    Assignee: Bridgestone Corporation
    Inventors: Michitaka Takeshita, Uchu Mukai, Toshio Sugawara
  • Patent number: 4801445
    Abstract: A modified powder or particulate material having a silicone polymer film coated on substantially the entire surface thereof, this powder or particulate material being produced by bringing at least one silicone compound, in the form of a vapor, having the general formula (I):(R.sup.1 HSiO).sub.a (R.sup.2 R.sup.3 SiO).sub.b (R.sup.4 R.sup.5 R.sup.6 SiO.sub.1/2).sub.c (I)wherein R.sup.1, R.sup.2, and R.sup.3 represent, independently, hydrogen or a hydrocarbon residue having 1 to 10 carbon atoms, which may be substituted with at least one halogen atom, provided that R.sup.1, R.sup.2, and R.sup.3 are not hydrogen at the same time, R.sup.4, R.sup.5, and R.sup.
    Type: Grant
    Filed: June 17, 1986
    Date of Patent: January 31, 1989
    Assignee: Shiseido Company Ltd.
    Inventors: Hiroshi Fukui, Ryujiro Namba, Tsutomu Saito, Yutaka Ohtsu, Asa Kimura, Motokiyo Nakano, Okitsugu Nakata, Kenichi Tomita, Kazuo Tokubo, Kazuhisa Ohno, Toshio Yoneyama, Takashi Ogawa, Hideo Morohoshi, Junichi Koyama, Taketoshi Kanda, Kunihiro Kawaguchi, Yuzo Shimizu