Two Or More Solid Synthetic Polymers Having Defined Physical Dimension Or Surface Area Patents (Class 523/221)
  • Patent number: 4398000
    Abstract: A solid type golf ball comprising a central core and an outer cover for the core and having an excellent flight performance and durability and acceptable "click" characteristics is presented. The main component of the outer cover of this golf ball is a polyetherester block copolymer containing the following X, Y and Z units:X: Butylene terephthalate unitY: Ester unit other than butylene terephthalateZ: Polyetherester unit derived from a dicarboxylic acid component containing terephthalic acid and poly(alkylene oxide) glycol having a number average molecular weight of 400 through 3000, wherein the X, Y and Z units are present in the following amounts:30% by weight .ltoreq.X.ltoreq.80% by weight0% by weight .ltoreq.Y.ltoreq.50% by weight20% by weight .ltoreq.Z.ltoreq.70% by weight.
    Type: Grant
    Filed: August 7, 1981
    Date of Patent: August 9, 1983
    Assignees: Bridgestone Tire Co., Ltd., Toray Industries, Inc.
    Inventors: Nobuyuki Kataoka, Tasuku Saito, Tsutomu Matsunaga, Chiaki Tanaka, Yoko Furuta, Nagayoshi Naito
  • Patent number: 4395500
    Abstract: A protective colloid-free plastics dispersion yielding after drying a polymer film which under the influence of moisture has no or little tendency to whitening contains polymer particles having a bimodal size distribution, that is, on the one hand relatively coarse particles and on the other hand relatively fine particles. The polymer component consists of at least 10 weight % of particles having an average diameter of less than 0.2 .mu.m and of 90 weight % at most of particles having an average diameter of more than 0.25 .mu.m, and the ratio of average grain size of coarse to fine polymer is at least 2:1. The plastics dispersion is suitable especially as binder dispersion in plasters and gloss paints.
    Type: Grant
    Filed: September 29, 1981
    Date of Patent: July 26, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gernot Lohr, Rolf Reinecke
  • Patent number: 4384056
    Abstract: Aqueous dispersions of polymers containing (meth)acrylic acid alkyl ester units which contain the polymer in the form of relatively large, non-agglomerated, spherical particles (=main spheres) and relatively small, non-agglomerated, spherical particles (=filler spheres), wherein the smaller filler spheres have an average particle diameter d.sub.F measured using an electron microscope of from 50 to 150 nanometers (nm) and the average diameter of the large main spheres d.sub.H is from 1.35 to 3.5 times larger than the average particle diameter d.sub.F, provided that d.sub.H is at least 140 nm, and wherein the ratio of the total mass of the polymer composed of main spheres M.sub.H to the total mass of the polymer composed of filler spheres M.sub.F isM.sub.H :M.sub.F =20:1 to M.sub.H :M.sub.F =1:20and wherein at least 70% of the number of main spheres and at least 70% of the number of filler spheres lie in the range of .+-.25% of the respective average value of d.sub.H or d.sub.F.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: May 17, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Adolf Schmidt, Gunter Kolb, Werner Clarenz
  • Patent number: 4383055
    Abstract: Preparation of heat-curable, water-dilutable coating compositions based on (A) epoxy resins free from amino groups, (B) an aqueous dispersion or solution of saturated polyester resins or the modification products thereof with oils, (C) organic cross-linking agents and optionally (D) pigments and/or conventional adjuvants, in specific proportions, these components being processed together in one or more stages, while being comminuted from their original particle size, to form a homogeneous coating composition which has a particle size of less than 100 .mu.m, and the use of the coating compositions thus obtained as coating agents, particularly for coating metal substrates, by the use of current-free methods of application or electrostatic spraying.
    Type: Grant
    Filed: October 7, 1981
    Date of Patent: May 10, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Johannes, Helmut Durr, Dieter Plath, Diedrich Schneider, Klaus Esser
  • Patent number: 4379870
    Abstract: Reinforcing material for hydraulic substances such as cement, mortar, concrete or the like and a method for producing it. The reinforcing material consists essentially of an elongated product of a synthetic resin having protrusions on its surface and which was obtained by extruding and subsequent stretching. The method comprises mixing a polyethylene having a melt index of not more than 0.01 at 190.degree. C. under the load of 2.16 Kg with a polyethylene having a melt index of more than 0.01 thereby to obtain a polyethylene mixture having a melt index of 0.01 to 10, melt-extruding the polyethylene mixture under such conditions as to give an extruded product having a jagged surface and stretching the extruded product, whereby the reinforcing material having protrusions on its surface is obtained. Hydraulic substances with the reinforcing material incorporated therein is useful for production of concrete panel, concrete pipe, concrete channel, tetrapod, sleeper, tunnel, etc.
    Type: Grant
    Filed: June 30, 1981
    Date of Patent: April 12, 1983
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Hisashi Matsumoto
  • Patent number: 4368280
    Abstract: A composition essentially consisting of a monoolefin copolymer rubber such as an ethylene-propylene copolymer rubber and a polyolefin resin such as polypropylene is granulated and then suspended, by stirring, in water containing a suspending agent. Then, a cross-linking agent is dispersed in the resulting suspension and introduced into the granules at a temperature lower than the decomposition temperature of the cross-linking agent to obtain a granular composition uniformly impregnated with the cross-linking agent. This composition is used as such or as a masterbatch to prepare partially cross-linked thermoplastic elastomers. Such compositions having a cross-linking agent content of not greater than 5% by weight based on the amount of the rubber component can be converted into partially cross-linked thermoplastic elastomers having a uniform degree of cross-linking, simply by heating the impregnated granules statically to effect the cross-linking reaction.
    Type: Grant
    Filed: December 31, 1980
    Date of Patent: January 11, 1983
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Hiroshi Yui, Tetsuji Kakizaki, Yashinori Nishiya, Shinji Horie
  • Patent number: 4356283
    Abstract: A process is described for the preparation of mixtures for processing as plastisols or organosols, wherein at least one known plasticizer, at least one first vinyl chloride copolymer and at least one vinyl chloride homopolymer or a second vinyl chloride copolymer are mixed together, if appropriate with the addition of further known substances. The first copolymer is a specific vinyl chloride graft copolymer, of which 5 to 70% by weight are employed, relative to the total quantity of polymers present in the mixture. It contains 99.5 to 88% by weight of polymerized units of vinyl chloride, 0.1 to 11.9% by weight of polymerized units of vinyl acetate and 0.1 to 2.2% by weight of polymerized units of ethylene. The remaining polymer(s) employed is/are prepared in accordance with customary processes.Mixtures prepared in this manner produce plastisols or organosols which have a low viscosity and good stability on storage and which also enable uniform coatings to be obtained by applying a thin layer.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: October 26, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Weinlich, Otto Plewan, Hans-Joachim Leugering, deceased, by Ursula M. Leugering nee Wegener, heiress, by Lothar Leugering, heir, by Manfred Leugering, heir, by Rita Bahn nee Leugering, heiress, by Gunter Leugering, heir
  • Patent number: 4341691
    Abstract: An acrylic cement-like substance which permits seating and securing of a prosthesis into living bone which comprises a mixture of a liquid monomer component and a polymer powder component such that upon mixing the two components, a cement which maintains a low viscosity for a longer period of time is formed. The low viscosity bone cement is intended for syringe or injector gun use only as it is to be used before the cement becomes doughy. This low viscosity bone cement has a viscosity of approximately 20 degrees C. (68 degrees F.), of less than 1500 poise, and preferably less than 1000 poise up to the sixth or seventh minute after the two components are mixed. The cement used in the lower viscosity state is more capable of penetrating the trabeculae of bones when used to secure a prosthesis, than when the cement is applied in the doughy state.
    Type: Grant
    Filed: February 20, 1980
    Date of Patent: July 27, 1982
    Assignee: Zimmer, Inc.
    Inventor: David A. Anuta
  • Patent number: 4336173
    Abstract: The invention provides a process for preparing an aqueous emulsion or dispersion of a partly water-soluble material, and optionally further conversion of the prepared dispersion or emulsion to a polymer dispersion when the partly water-soluble material is a polymerizable monomer. In a first step a dispersion of polymer particles is prepared containing one or more materials having a very low solubility in water, then in a second step there is added the partly water-soluble material which diffuses into the particles from the first step, and then, if the partly water-soluble material is a polymerizable monomer, polymerization may be effected.
    Type: Grant
    Filed: September 10, 1980
    Date of Patent: June 22, 1982
    Assignee: SINTEF
    Inventor: John Ugelstad
  • Patent number: 4322330
    Abstract: An adhesive for floor coverings containing(a) 100 parts by weight of an aqueous polymer dispersion having a solids content of from 30% to 70% by weight of the total weight of said dispersion, the solids content consisting of synthetic resin particles of at least a bimodal particle size distribution wherein the majority of the larger particles is at least twice the size of the majority of the smaller particles and where the majority of the larger particles has a particle size distribution of from 0.5 to 3 .mu.m and the majority of the smaller particles has a particle size distribution of from 0.1 to 1 .mu.
    Type: Grant
    Filed: July 10, 1980
    Date of Patent: March 30, 1982
    Assignee: Wacker-Chemie GmbH
    Inventors: Ekkehard Merz, Gerhard Kothe