Abstract: A composition comprising the hydrosilylation addition product of a linear alkenyl functionalized polyorganosiloxane and an M.sup.H Q resin and a low molecular weight silicone when subjected to a new particle size reduction process that includes flow induced shearing provides for components in personal care formulations that have improved spreadability and substance as a consequence of a unique particle size distribution.

Abstract: This invention provides an ultraviolet ray absorbing polymer particle which includes a first ultraviolet particle which includes a first ultraviolet ray absorber represented by formula I: ##STR1## and a second ultraviolet ray absorber represented by formula II: ##STR2##

Abstract: The present invention provides a process for the preparation of microcapsule compositions, methods for using those microcapsule compositions, compositions containing those microcapsule compositions and microcapsules prepared by the process of the present invention.

Abstract: Micropowders having spherical particles possessing an essentially smooth surface structure contain, as essential components, polyarylene ether sulfones or polyarylene ether ketones and are obtainable by prilling melts thereof or spray-drying solutions thereof.

Abstract: The invention relates to a process for encapsulating biologically active compounds in the form of substantially spherical microparticles, comprising the steps ofa) preparing an aqueous solution of surfactants, catalysts and monomers or prepolymers which are suitable for forming a crosslinked polycondensate,b) forming an emulsion of the substantially water-insoluble biologically active compound or mixture thereof in the solution a) by adding said solution under high shear force, andc) forming a solid capsule wall around the biologically active compound or mixture thereof by heating the reaction mixture to a temperature at which the crosslinking reaction tales place,which process comprises fusing the biologically active compound or mixture thereof and adding the melt to the aqueous reaction mixture at a temperature which is higher than the temperature of the reaction mixture.

Abstract: A composition useful as a bouyant putty comprises a continuous phase having a viscosity of greater than 100,000 cs and less than a viscosity corresponding to a penetration number of 500 containing a polydimethylsiloxane which is a mixture of a silicone fluid with a viscosity of not more 100,000 cs and a silicone gum possessing a penetration number of from 500 to 1500, and a discontinuous phase of hollow, gas-filled organic polymer microspheres.

Abstract: The present invention relates to TiO.sub.2 pigments having TiO.sub.2 particles with substantially discrete inorganic particles dispersed on the surfaces of the TiO.sub.2 particles. Suitable inorganic particles include silica, calcium carbonate, and mixtures thereof. The substantially discrete inorganic particles have an average diameter size within the range of about 5 to about 50 nm and are dispersed on the surfaces of the TiO.sub.2 particles in an amount of less than 20 wt. % based on total pigment weight. This invention also includes coating compositions containing these pigments and processes for making these pigments.

Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion.

Abstract: A curable composition comprising (i) a polymerizable monomer, (ii) irregular-shaped inorganic particles (A) having an average particle diameter of from 1 to 9 .mu.m, and containing particles having particle diameters of not smaller than 10 .mu.m in an amount of not larger than 3% by weight, such as silica-zirconia irregular-shaped particles, (iii) spherical inorganic particles (B) having an average particle diameter of from 0.1 to 5 .mu.m, such as spherical silica-zirconia particles; (iv) inorganic fine particles (C) having an average particle diameter of from 0.01 to 0.1 .mu.

Abstract: A process is provided for preparing a silicone elastomer composition for cosmetic products which includes the steps of feeding the silicone elastomer composition comprising a silicone rubber in a carrier fluid into a reactor, mixing the composition in the reactor, delivering the composition from the reactor into a high pressure pump, pumping the fluid into a device for reducing particles of rubber into smaller sizes and recirculating the resultant size reduced particles back to the reactor. The device for reducing particle size is preferably a high pressure fed homogenizer, most advantageously a sonolator.

Abstract: A polyolefin-based flame retardant resin composition which emits no hazardous gases on combustion or incineration after use, requires no additional costs for treating ash, and has excellent flame resistance and mechanical strength is provided.To 100 parts by weight of a polyolefin-based resin, 2 to 60 parts by weight of melamine cyanurate surface-treated by fine silica, and 1 to 30 parts by weight of a phosphoric acid ester are compounded.

Abstract: Process for obtaining granular forms, from mixtures of powders of two or more additives for organic polymers, including extruding the mixture at a temperature of between about the melting point of the component with the lowest melting point and 140.degree. C., with the condition that, when the mixture consists of two additives, these are not tetrakis ?3-(3,5-di-t-butyl-4-hydroxyphenyl) propionyloxymethyl!methane, either in an amorphous or crystalline form, and an antiacid.

Abstract: A light weight, vibration-damping composition having effective amounts of at least one butyl rubber, at least one tackifying resin, at least one pigment and substantially spherical microspheres is disclosed. The present composition has a specific gravity of about 1.0 to 1.2 and has effective damping effects at low temperatures as well as temperatures up to about 60.degree. C. This composition is effective for use in the transportation industry, the building industry, the aerospace industry and the appliance industry.

Abstract: A silica filler containing from 30 to 90 wt % of particles having a particle size of at least 30 .mu.m, wherein the roundness of the particles having a particle size of at least 30 .mu.m, is from 0.83 to 0.94.

Abstract: The present invention is a hot melt adhesive composition comprising at least one ingredient present in an encapsulated form. The encapsulated ingredient may be any known hot melt adhesive formulation ingredient as well as any hot melt adhesive additive such as antioxidants and fragrances for which there is a desirable change in adhesive properties by isolating such ingredient for a duration of time. The encapsulated ingredient is released from the shell by means of pressure, temperature, diffusion, pH, light, radiation, ultrasound, and combinations thereof. Hot melt adhesive compositions comprising at least one encapsulated ingredient are useful for a variety of novel products including self-supported friction glue sticks, non-tacky pelletized pressure sensitive adhesives, cohesive adhesive systems, hot melt adhesive compositions exhibiting improved thermal stability and odor, as well as for a variety of other adhesive applications.

Abstract: Novel magnetic polymer particles which resists precipitation in an aqueous medium. The novel magnetic polymer particles can be widely used as carriers for diagnostics and immobilized enzymes, carriers for bacterial isolation, carriers for cell segregation, carriers for isolation and purification of ribonucleic acids and proteins, carriers for drug deliveries, and are usable as material for magnetic toners, magnetic inks, and magnetic coatings. The process for manufacturing the magnetic polymer particles comprising; dispersing a monomer mixture including a hydrophobic monomer containing more than 50% by weight of (meth)acrylic ester and a superparamagnetic substance in an aqueous medium to prepare an suspension, and polymerizing the monomers.

Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.

Abstract: A solid film of cured varnish formed froma liquid susppension varnish composition, the film of dried varnish consisting essentially of a solid coherent film polymer constituent formed by the drying of liquid component of said suspension varnish composition and embedded in said solid coherent film polymer solid ultraviolet absorbing crosslinked particles having an average size between 20 to 200 microns in the amount of from about two or three percent by weight or greater based on a weight of said coherent film polymer and methods and composition for making the same are disclosed.

Abstract: Redispersable polymer powder compositions are provided which contain homopolymers or copolymers of ethylenically unsaturated monomers and cyclodextrins or cyclodextrin derivatives having the general formula (I), ##STR1## in which n=6, 7 or 8, the substituents R are identical or different and cover H or R.sup.1, the substituents R.sup.1 are identical or different and cover for optionally substituted C.sub.1 -C.sub.4 -alkyl, carboxy-C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -carboxyly residues. Also disclosed are a process for preparing these compositions and their use, as well as polymer dispersions stabilised with cyclodextrins or cyclodextrin derivatives obtained as intermediate products.

Abstract: Stabilized microsphere adhesive composition comprising: a plurality of polymeric, elastomeric microspheres wherein the microspheres are the reaction product of reactants comprising polymerizable starting materials comprising at least one C.sub.4 -C.sub.14 alkyl (meth)acrylate monomer and optionally at least one comonomer, at least one vinyl-unsaturated additive having both an ionic moiety and a hydrophobic moiety and containing at least 5 but not more than 40 carbon atoms in an amount about 0.1 to 3 parts by weight of the microspheres; optionally, a polymeric stabilizer in an amount of between about 0.

Abstract: A process for the preparation of polymer compositions which comprises mixing a conductive component with an anionic polymeric latex containing a polymer; adding a cationic surfactant, or flocculant whereby the aggregation of the latex particles and the conductive component particles results; subsequently adding colloidal stabilizer, followed by the addition of a base to obtain a pH of from about 7 to about 12; heating above about the polymer glass transition temperature thereby enabling the severage, or breakage of the formed aggregated particles; further heating above about the polymer glass transition temperature enabling the coalescence of the polymer and conductive component particles; and optionally washing and drying the resulting coalesced product.

Abstract: A process for producing a polymer toner comprises the steps of pouring a polymerizable monomer composition containing at least a polymerizable monomer and a colorant, but containing no oil-soluble polymerization initiator into an aqueous dispersion medium containing a dispersing agent; adding an oil-soluble polymerization initiator to the polymerizable monomer composition while stirring the composition to form primary droplets thereof, thereby bringing the droplets of the polymerizable monomer composition into contact with droplets of the oil-soluble polymerization initiator to form droplets of a polymerizable monomer composition containing the oil-soluble polymerization initiator; further continuing the stirring to form secondary droplets having desired droplet sizes; and then conducting suspension polymerization of the polymerizable monomer composition.

Abstract: Mannich (alk)acrylamide microparticles are produced at high solids contents without a significant increase in bulk viscosity by inverse microemulsion polymerization and provide superior dewatering characteristics.

Abstract: A molding resin composition containing, in a resin, a filler comprising a globular powder of which mean particle diameter is not smaller than 0.1 .mu.m and not greater than 1.5 .mu.m (x component), a globular powder of which mean particle diameter is not smaller than 2 .mu.m and not greater than 15 .mu.m (y component) and a globular powder of which mean particle diameter is not smaller than 20 .mu.m and not greater than 70 .mu.m (z component), wherein proportions of the x, y and z components based on the total volume of x, y and z components are not smaller than 10% by volume and not greater than 24% by volume, not smaller than 0.1% by volume and not greater than 36% by volume and not smaller than 57% by volume and not greater than 76% by volume, exhibits an excellent fluidity even when loaded with a high percentage of filler. Further, their cured products are lowered in the moisture absorption and thermal expansion coefficient of which increases result from the resin itself present in the cured product.

Abstract: A resin composition comprising 30-95 parts by weight of a thermoplastic norbornene resin and 5-70 parts by weight of a spherical inorganic filler having an average particle diameter of 0.05-50 .mu.m; and a precision molding produced therefrom.

Abstract: The subject composite materials comprise an association of an organic elastic matrix with a network of non-oxidized quasi spherical particles, of submicronic dimension and of a diameter ranging between 0.1 .mu.m and 10 .mu.m, distributed uniformly in the matrix.The materials are intended to coat pieces subjected to the phenomena of wear, erosion, cavitation and abrasion notably in a corrosive medium.According to a method of manufacture of these composite materials, the nonoxidized submicronic particles are, immediately before their introduction in the organic matrix, plunged into an organic macromolecular dispersant chosen of such type that the macromolecular chains of the dispersant are fixed on the surface of the particles by noncovalent bonds.

Abstract: A process for making clusters of individual polymer beads bonded together to minimize attritition in use or processing but characterized by an open structure for fast absorption of aqueous solutions comprises suspending a monomer mixture in a continuous phase at high shear agitation such that fine droplets of monomer are formed in an inert organic phase. A suspending agent which prevents the clusters from coalescing is provided. A first polyethylenically unsaturated crosslinking monomer, having substantial solubility in the aqueous phase, and an organic phase soluble initiator system are provided such that polymerization at the surface of the polymer particles occurs to form the porous clusters of the invention, A second substantially oil soluble crosslinker is optionally provided to further crosslink the clusters such that they do not coalesce.

Abstract: A microcapsule-containing oil-based coating liquid wherein the coating liquid comprises a hydrophobic core material-containing microcapsule particles dispersed individually in a state of primary particle in an oil varnish for ink use or a resin for coating use, and a solvent having an affinity for both the varnish or the resin and the surface of the microcapsule wall material in a state of having been attracted with the affinity to both the varnish or the resin and the surface layer of the microcapsule wall material. The preferred solvent is a lower divalent or multivalent alcohol.A preparative method of the foregoing coating liquid by utilizing vacuum distillation is also proposed.A sheet, like a duplicating sheet of paper coated with the foregoing oil-based coating liquid is further provided.According to the present invention, a water-based microcapsules system can be advantageously converted into an oil-based one without coagulating the primary microcapsule particles.

Abstract: Moldable ferromagnetic particles and method of making a magnetizable molding therefrom. The ferromagnetic particles are spray-coated with a slurry comprising insoluble thermoplastic particles suspended in a solution of a soluble polymer to produce a coating on the ferromagnetic particles which comprises a majority of the insoluble thermoplastic particles embedded in a lesser amount of a binder polymer. When compression molded, the insoluble thermoplastic particles form a continuous matrix for the ferromagnetic particles.

Abstract: A composite mixture of spherical objects and lubricant useful for its cushioning properties is disclosed and claimed. The composite mixture may be composed of microspheres typically less than 2000 microns in diameter with inert atmospheres sealed within their interiors and any of a variety of lubricants facilitating sliding and rolling movement between microspheres. Typically the composite mixture includes lubricant in a quantity sufficient to substantially coat the exterior surface of essentially all of the spherical objects, but in a quantity less than would cause dispersion of the spherical objects in the lubricant sufficient to physically separate the spherical objects from each other and substantially reduce the sliding and rolling contact of the spherical objects with each other. The preferred lubricant is a visco-elastic fluid that has a principle molecule and a cross-linking agent.

Abstract: The present invention relates to a paint composition which comprises a binder to impart film forming properties compounded with quasi transparent polyolefin filler particles having a particle size below 110 micrometers, said polyolefin being selected from the group consisting of a polyethylene, a polypropylene, copolymers of ethylene and propylene and mixtures thereoof, said polyolefin filler particles being present in an amount between 0.1% to 10% by weight of the composition. These paint compositions were found to possess low gloss and matte properties at visible and high reflectance in the thermal infra-red wavelengths.

Abstract: A one-step emulsification process for preparing aqueous suspensions of hollow, acrylate polymer microspheres conducted in the presence of at least one acid that is not free radically polymerizable. Surprisingly, the use of such an acid eliminates the previous requirement of using a polar copolymerizable monomer in the one-step emulsification process. The hollow acrylate polymer microspheres prepared from the process of the invention may be tacky or tack-free.

Abstract: Moldable ferromagnetic particles and method of making a magnetizable molding therefrom. The ferromagnetic particles are spray-coated with a slurry comprising insoluble thermoplastic particles suspended in a solution of a soluble polymer to produce a coating on the ferromagnetic particles which comprises a majority of the insoluble thermoplastic particles embedded in a lesser amount of a binder polymer. When compression molded, the insoluble thermoplastic particles form a continuous matrix for the ferromagnetic particles.

Abstract: The present Application relates to an aqueous, reactive microgel dispersion, wherein the microgel particles have an average particle diameter of 0.01 to 1 .mu.m, are insoluble but are capable of swelling in the usual organic solvents, dry without additional film-forming agents to form uniform, transparent, reactive films, and have iodine numbers of 2 to 100.

Abstract: The disclosure describes a method for producing bulk, particulate material that includes solid, generally ellipsoidal particles by dispersing irregularly shaped feed particles including about 60 to 100% by weight of at least one silicate-containing material selected from among wollastonite, alkali feldspar, plagioclase feldspar and nepheline. While maintaining the feed particles in dispersion, they are heated sufficiently to bring about at least partial fusion within at least the surfaces of the particles. This produces a bulk particulate product of which about 15 to 100% by volume is generally ellipsoidal particles. Also described are compositions of matter including solid particles, at least a portion of which are substantially glassy and generally ellipsoidal. At least a portion of these particles have been respectively formed from feed particles composed substantially of at least one silicate selected from among wollastonite, alkali feldspar, plagioclase feldspar and nepheline.

Abstract: A solid, coherent film of dried varnish formed from liquid suspension varnish composition, the film of dried varnish consisting essentially of a solid coherent film polymer constituent formed by the drying of the liquid component of said suspension varnish composition, and, embedded in said solid coherent film polymer, solid ultraviolet absorbing polymer particles in the amount of from about two or three percent, by weight, or greater, based on the weight of said solid coherent film polymer, and methods and composition for making the same are disclosed.

Abstract: A polypropylene molding composition which comprises 0.5 to 15% by weight of dark mineral fibers, in particular basalt fibers, can be processed to moldings having a decorative surface. These moldings are used for domestic appliances, for motor vehicles, in the building sector for office items and many other applications.

Abstract: Exceptional whiteness of glass-filled thermoplastic resin compositions is achieved by incorporating a white-pigmenting effective amount of the anatase form of titanium dioxide. The anatase form of titanium dioxide surprisingly improves the whiteness of glass-filled thermoplastic resin materials while also improving its physical properties (e.g., tensile strength and tensile elongation properties).

Abstract: A curable material comprising a particulate filler and a blend of a fluorine-containing cyanate and a fluorine-containing arylene ether polymer. The cyanate is a monomer having the structureN.tbd.C--O--R--[R.sup.1 ].sub.n --O--C.tbd.Nand the fluorine containing arylene ether polymer has the structureX--R--[R.sup.1 ].sub.m --Xwherein X is any group capable of reacting with a --C.tbd.N group;R is an aliphatic or aromatic group which may or may not be fluorosubstituted;R.sup.1 is an aliphatic or aromatic group which may or may not be fluoro substituted or R.sup.1 is selected from the group consisting of ether, carbonyl, sulfone, phosphine oxide and sulfide, and at least one of R or R.sup.1 must be fluoro substituted;n is 0-10; andm is 0-100;The material in the cured state comprises a fluorine-containing polycyanurate network having a plurality of discrete phases of said fluorine-containing thermoplastic polymer dispersed therein wherein said thermoplastic polymer phases are of submicron size.

Abstract: The subject composite materials comprise an association of an organic elastic matrix with a network of non-oxidized quasi spherical particles, of submicronic dimension and of a diameter ranging between 0.1 .mu.m and 10 .mu.m distributed uniformly in the matrix.The materials are intended to coat pieces subjected to the phenomena of wear, erosion, cavitation and abrasion notably in a corrosive medium.According to a method of manufacture of these composite materials, the nonoxidized submicronic particles are, immediately before their introduction in the organic matrix, plunged into an organic macromolecular dispersant chosen of such type that the macromolecular chains of the dispersant are fixed on the surface of the particles by noncovalent bonds.

Abstract: The invention is a molding composition and molding process for use in the manufacture of lightweight composite vehicle parts and construction parts having smooth surfaces. The molding process may be at low pressures. The composition includes kaolin clay filler and, optionally, hydrophilic fumed silica thixotrope.

Abstract: A pressure sensitive adhesive that employs a water-dispersible polymer is provided. In one embodiment of the invention the adhesive comprises microparticles and the water-dispersible component. In another embodiment the adhesive comprises a novel water-dispersible polymer that contains a plurality of poly(alkoxyalkyl) acrylate units as a major component.The pressure sensitive adhesive may be provided as a tape and used with labels for containers, sterilization indicator tapes and labels, closure systems for envelopes, surgical wrappers, and mammalian body coverings. It may also be used in the preparation of paper web splices.In one embodiment of the invention the tape is repulpable. In another embodiment it is launderable.

Abstract: An isotropic resin matrix material includes resin doped with fiberballs. Fiberballs are formed from a plurality of fibers generally radiating outward from a common node. These fibers are of sufficient numbers and separation at a distal end to form a spherical shape. The fiberballs are uniformly distributed throughout the resin. Preferably, the fibers making up the fiberballs are carbon fibers. The carbon fibers impart thermal and electrical conductivity, or dielectric loss characteristics in some configurations. These conductivity and loss characteristics are isotropic in they are the same no matter where the electrical or thermal energy is applied due to the radial structure and uniform distribution of the fiberballs. The fiberballs may also be saturated with a phase change material and encapsulated in a shell so as to impart a heat dissipation capacity to the resin matrix material.

Abstract: A modeling dough comprising gelled poly(vinyl alcohol), water and a filler provides a dough resistant to flaking, cracking, and crumbling. In the disclosed invention, the poly(vinyl alcohol) resin is gelled, thereby providing a water-based resin system that is not sticky yet very ductile. Prior to drying, the dough also exhibits the properties of bounceability and the ability to pick up newsprint. After the dough is air-dried, the poly resin serves to bind the components into a solid, durable product. The filler accounts for a large portion of the volume of the dough, so the overall volume is not greatly affected by water loss upon drying. The dough is water-based and easy to wash from skin, carpets, and other surfaces. Dyes and pigments can be easily incorporated into the formula. The dried product is sandable and paintable.

Abstract: A process is provided for stabilizing thermoplastic particles with organic phosphite particles. The process involves applying a liquid, relatively low molecular weight, phosphite to the surface of thermoplastic particles. The particles exhibit hydrolysis compared to conventional phosphite shell/polymeric core structures. The particles may be molded into useful thermoplastic articles.

Abstract: Light-stabilized polymer microparticles, which contain at least one light stabilizer, and processes for the preparation of these microparticles by polymerization of suitable monomers, at least a part of the polymerization being carried out in the presence of at least one light stabilizer, are described. The polymer microparticles can be used in coating compositions which comprise a disperse phase containing these particles and a liquid continuous phase.Coatings and finishes based on the compositions according to the invention are distinguished by improved weathering resistance, in particular by a high light stability.

Abstract: Disclosed is a process for adding stabilizers and, optionally, additives to polyolefins in particle form obtained in liquid monomer by means of Ziegler-Natta catalysts, where the addition of stabilizers and, optionally, additives is carried out in liquid monomer in a step that follows polymerization, but precedes the flashing of the liquid monomer, after the aluminum alkyl has been deactivated.

Abstract: A novel high-performance binder system is provided for the fabrication of segregation-free iron based powder blends. The blends are prepared by using a binder system comprising thermoplastic resin polyvinylpyrrolidone and a suitable compatible plasticizer such as polyethylene glycol, and optional solid lubricants. The binder system enables the manufacture of segregation-free iron-based powder blends with high flow rate and compressibility, enhanced apparent density, green strength and transverse rupture strength, and low dimensional variations compared to unbonded powder blends and to blends made with PVP or PEG only as the binder.

Abstract: A coating composition and method of use thereof for coating metal substrates, especially galvanically active metals, containing a resinous organic polymer, a corrosion inhibiting leachable pigment and an ion reactive pigment generally in the form of metallic spheroid particles. Coated materials have improved corrosion resistance.

Abstract: An exothermic conductive coating comprises carbon particles, a substantial portion being spherical particles having a diameter of not more than 500 .mu.m, and a synthetic resin. A conductive heating unit is obtained by coating or impregnating a desirably-shaped solid or solid surface with the coating and curing it. The heating unit provides a uniform temperature distribution at any selected temperature up to about 450.degree. C., and can be formed in various shapes.