Utilizing Plural Mixing Operations In Preparation Of A Solid Polymer Inert Ingredient Concentrate, E.g., Master Batch, Etc. Patents (Class 523/351)
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Patent number: 7439284Abstract: A method of making a thermoplastic composition comprises melt mixing a concentrate comprising a first thermoplastic, a second thermoplastic and an additive with a component selected from the group consisting of a third thermoplastic, fire retardant additive, reinforcing agent, electrically conductive filler, non-electrically conductive filler and combinations of two or more of the foregoing.Type: GrantFiled: March 31, 2004Date of Patent: October 21, 2008Assignee: Sabic Innovative Plastics IP B.V.Inventors: Montgomery M. Alger, Robert Hossan, Torben P. Kempers, Geoffrey H. Riding, David J. Swanson, Michael L. Todt
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Publication number: 20080249211Abstract: A masterbatch composition is provided that includes a colorant, a thermoplastic carrier, a metallocene polymer processing aid, and optionally an additive. Also provided is a method for making a masterbatch composition and a method for making a colorized polymer.Type: ApplicationFiled: April 4, 2007Publication date: October 9, 2008Inventors: Jeffrey S. Smink, Ronald M. Harris, Robert R. Powers, Andrew J. Schwartz, Rick D. Martz
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Publication number: 20080234408Abstract: The invention is direct to a method of forming a polyolefin blend. First a diphosphate and clay are blended to form an organoclay. The organoclay is blended with a vectoring polymeric material to form a masterbatch. The masterbatch is blended with a polyolefin such as a polyethylene or a polypropylene.Type: ApplicationFiled: March 14, 2008Publication date: September 25, 2008Inventors: David Abecassis, Ed Wiegel
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Publication number: 20080207801Abstract: A polymer nanocomposite contains layered clay dispersed in a polymer matrix together with compatibilizers for the clay and polymer matrix. The compatibilizers are a combination of two or more graft polymers. One graft polymer has high functionality and short chain length and another graft polymer has low functionality and long chain length. Such polymer nanocomposites have improved dispersion and better strength and modulus, while maintaining good toughness and impact strength. The polymer nanocomposites are particularly useful in applications where good mechanical performance and light-weight are of importance.Type: ApplicationFiled: December 12, 2005Publication date: August 28, 2008Applicant: NATIONAL RESEARCH COUNCIL OF CANADAInventors: Minh-Tan Ton-That, Florence Perrin-Sarazin, Johanne Denault
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Publication number: 20080194734Abstract: Microspherical fillers are used to increase the scratch resistance of thermoplastic vulcanizates in extruded profiles while providing aesthetically attractive surface effects. The thermoplastic vulcanizates comprise a thermoplastic phase and a rubber that is at least partially cross-linked by dynamic vulcanization. The fillers can be added by melt blending with the pre-formed thermoplastic vulcanizate. An attractive, granite-like appearance can be achieved with enhanced scratch resistance that is particularly suitable as automotive interior or exterior trim parts.Type: ApplicationFiled: September 21, 2004Publication date: August 14, 2008Applicant: ADVANCED ELASTOMER SYSTEM, L.P.Inventor: Jean Maurice Lehmann
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Publication number: 20080161482Abstract: The present invention discloses a functional material powder, a method for fabricating the same and a functional staple fiber containing the same. The functional material powder comprises particles with a diameter of 50˜350nm, 0.5˜1.5% of a dispersant, 3˜5% of a surfactant, and 1˜2% of a coupling agent. A small-capacity mill is used to fabricate the functional material powder of the present invention, wherein the small-capacity mill operates at a high power to generate a great impact force and a great shear force to fast nanomize the particles of the functional material. Further, in considering the future application, a surfactant and a coupling agent are added into the functional material powder to disperse the powder and promote the coupling strength between the particles and the molecules of a chemical fiber.Type: ApplicationFiled: December 29, 2006Publication date: July 3, 2008Inventor: Chih-Lien Ko
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Publication number: 20080146699Abstract: The present invention is directed to the provision of premixed aqueous compositions which are used to provide a paint composition of varying finish characteristics at the point of sale. Thus, the merchant distributing the paint composition made from the subject premixed compositions need only maintain inventory of four compositions. The particular compositions which are the subject of the invention exhibit stable characteristics during storage in their respective reservoirs. The compositions include a pigment composition, a dispersant thickening agent, a high resin content binder, and a low resin content binder. The compositions are combined in differing amounts to produce paint compositions being suitable for either interior or exterior use and having differing sheens, quality levels, and color bases.Type: ApplicationFiled: February 26, 2008Publication date: June 19, 2008Applicant: COATINGS MANAGEMENT SYSTEMS INC.Inventors: C. Daniel McClain, Randall L. Hughes
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Publication number: 20080132608Abstract: A method for producing a rubber composition for a tire by compounding, at a first mixing step, into 50 parts by weight or more of 100 parts by weight of a diene-based rubber containing 50 parts by weight of natural rubber and/or synthetic polyisoprene rubber and 50 parts by weight or less of a butadiene rubber, 5 to 30 parts by weight of silica and 3 to 15% by weight of a silane coupling agent, based upon the weight of silica, to form a master batch, then, at a second mixing step, adding, to the resultant master batch, the balance of diene-based rubber and carbon black and other compounding agents, except for the vulcanization compounding agents, and finally, at a final mixing step, adding thereto the vulcanization compounding agents.Type: ApplicationFiled: November 30, 2007Publication date: June 5, 2008Applicant: The Yokohama Rubber Co., Ltd.Inventor: Yoshihisa Inoue
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Publication number: 20080114093Abstract: Thermoplastic polyurethane (TPU) compositions are disclosed comprising TPU polymer, polyisocyanate, and a salt of zirconium phosphate. The compositions have enhanced thermal properties, good processability, and good hydrolysis resistance. Processes are also disclosed to combine the ingredients by melt mixing or to prepare the compositions in-situ as the TPU is being polymerized.Type: ApplicationFiled: October 9, 2007Publication date: May 15, 2008Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Didier Lagneaux, Vicky M.J. Bertels, Robert Jansen
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Patent number: 7371369Abstract: This invention relates to a highly stable, dense interpenetrated crosslinked polymer network (ICPN) containing (a) a crosslinked, network-forming primary polymer containing vinyl lactam and/or acrylic acid moieties, and (b) a secondary, optionally crosslinked, distinctly different polymer interpenetrated into the network of (a) and derived from a monomer selected from the group consisting of an acrylate and/or acrylamide monomer. The invention also relates to the oil-suspension, sequential polymerization of (a) and (b) for producing the above described interpenetrated polymeric network.Type: GrantFiled: November 10, 2003Date of Patent: May 13, 2008Assignee: ISP Investments Inc.Inventor: Jenn S. Shih
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Patent number: 7358292Abstract: The present invention provides a relay block inhibited from occurrence of melt wrinkles and considerably inhibited from deformation of thin wall portions. That is, the present invention provides a relay block obtained by molding a resin composition which contains a polyamide, a polyphenylene ether and a block copolymer comprising at least one polymer block mainly composed of an aromatic vinyl compound and at least one polymer block mainly composed of a conjugated diene compound and which has a melt volume rate of not less than 60 cm3/10 min. and a dimensional change after water absorption of not more than 1.0%.Type: GrantFiled: April 2, 2003Date of Patent: April 15, 2008Assignee: Asahi Kasei Chemicals CorporationInventors: Takaaki Miyoshi, Shigeki Katayama
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Publication number: 20080047894Abstract: An improved method for fixedly binding particles of a solid, heat absorbing material or additive, especially polymer additives, to the surface of prepolymer and/or polymer particles.Type: ApplicationFiled: August 24, 2007Publication date: February 28, 2008Inventors: Jeffrey A. Trogolo, Edward K. Welch
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Patent number: 7323507Abstract: Dispersion concentrates are claimed which consist of: I) 10-80% by weight of a crosslinked copolymer obtained by polymerization of 1 to 50% by weight of a cyclic N-vinylcarboxamide and 49.99 to 98.99 by weight of acryloyldimethyltauric acid, II) 20-90% by weight of a phase selected from the group consisting of an emulsifier, an oil phase, and mixtures thereof, and III) up to 30% weight water based on the total weight of the stable dispersion concentrate. The stable dispersion concentrate is useful in preparing cosmetic, pharmaceutical, and dermatological compositions.Type: GrantFiled: March 13, 2003Date of Patent: January 29, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Löffler, Roman Morschhäuser, Livio Caribé Da Rocha
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Patent number: 7312271Abstract: Methods are provided for making a solution masterbatch containing a diene elastomer in an organic solvent and a reinforcing silica filler dispersed therein, comprising the steps of (a) mixing a precipitated silica having an average particle size substantially equivalent to an average particle size of a powdered silica, with a diene elastomer in a first organic solvent; and (b) desolventizing the mixture to form a solution masterbatch preparation. The use of such desolventized solution masterbatches in vulcanizable rubber compounds results in excellent processing characteristics with improved dispersion of fillers, including polymeric nanoparticles. The compounds also demonstrate improved properties, including reduced hysteresis.Type: GrantFiled: December 29, 2005Date of Patent: December 25, 2007Assignee: Bridgestone CorporationInventors: Zhong-Ren Chen, Sunji Araki, William M. Cole, William Hergenrother, Sandra Warren
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Patent number: 7288579Abstract: A method to reduce haze in the production of fire resistant polycarbonate compositions comprising flame retardant salts, wherein the salt is blended with a first polycarbonate to form a concentrate, and the concentrate is then added to a second polycarbonate resin.Type: GrantFiled: December 17, 2003Date of Patent: October 30, 2007Assignee: General Electric CompanyInventors: Eric Thomas Gohr, Niles Richard Rosenquist, Rajendra Kashinath Singh, Gregory James Stoddard, Shahrzad Zarkoob, Johannes Martinus Dina Goossens
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Patent number: 7252041Abstract: Polyolefin-based pallets capable of passing standard pallet flammability tests are prepared by molding the pallet or one or more subassemblies thereof, of a polyolefin molding resin containing a flame retardant package containing magnesium hydroxide, and optionally alumina trihydrate, and zinc borate. The flame retardants may be supplied as a master batch at a concentration higher than that desired in the pallet or subassembly, in a polyolefin-compatible polymer, and result in pallets having a significantly lower heat release rate.Type: GrantFiled: August 29, 2005Date of Patent: August 7, 2007Assignee: Rehrig Pacific CompanyInventors: Trenton M. Overholt, Justin M. Smyers
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Patent number: 7247661Abstract: A mixture including a high specific gravity masterbatch pellets group (A) with specific gravity within a range from 1.8 to 3.5, and a low specific gravity masterbatch pellets group (B) with specific gravity within a range from 0.5 to 1.6. The high specific gravity masterbatch pellets group (A) comprises m different columnar masterbatch pellets, each with a different specific gravity, and the low specific gravity masterbatch pellets group (B) comprises n different columnar masterbatch pellets, each with a different specific gravity. The high specific gravity masterbatch pellets group (A) and the low specific gravity masterbatch pellets group (B) satisfy a formula (1) shown below: 0.5 ? ? ( mm - 1 ) ? ? p = 1 m ? ( Hp Sp × Rp ) - ? q = 1 n ? ( Hq Sq × Rq ) ? 12 ? ? ( mm - 1 ) ? .Type: GrantFiled: April 28, 2004Date of Patent: July 24, 2007Assignee: Dainippon Ink and Chemical, Inc.Inventors: Haruo Otake, Yoshiro Tomita, Hideki Uchimi, Youko Nakayama
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Patent number: 7226963Abstract: The present invention relates to a thermoplastic resin composition and a method for making the same. The composition comprises the reaction product of about 10 wt % to about 50 wt % polyphenylene ether, about 35 wt % to about 65 wt % polyamide, preferably about 0.4 wt % to about 3.0 wt % carbon fibrils, and optionally about 5 wt % to about 40 wt % talc, up to about 10 wt % compatibilizing agent and up to about 20 wt % impact modifier. The method comprises forming a carbon masterbatch with polyamide and introducing the masterbatch and the polyamide subsequent to compounding the polyphenylene ether with a compatibilizing agent.Type: GrantFiled: May 20, 2003Date of Patent: June 5, 2007Assignee: General Electric CompanyInventors: Christiaan H. Koevoets, Johannes Matthijssen
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Patent number: 7226975Abstract: Golf ball compositions including novel processing aids, e.g., metal salts of unsaturated fatty acids, high styrene resins, transpolyisoprene, and transpolybutadiene, for inclusion in rubber-based compositions that reduce safety risks, mixer down time, increase dispersion of the ingredients during processing, and increase component COR over that of a component formed with a conventional processing aid.Type: GrantFiled: May 12, 2004Date of Patent: June 5, 2007Assignee: Acushnet CompanyInventors: Peter R. Voorheis, Samuel A. Pasqua, Jr.
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Patent number: 7205348Abstract: Process of producing unvulcanized rubber useful for producing vulcanized rubber with improved hysteresis, which comprises mixing a composition comprising unvulcanized rubber, carbon black and xanthogen polysulfide at an elevated temperature in a non-productive stage and composition suitable for producing unvulcanized rubber useful for producing vulcanized rubber with improved hysteresis, which comprises unvulcanized rubber, a filler comprising carbon black and xanthogen polysulfide.Type: GrantFiled: April 7, 2004Date of Patent: April 17, 2007Assignee: Uniroyal Chemical Company, Inc.Inventors: Joseph F. Stieber, Martin J. Hannon, L. P. Felipe Chibante, James R. Korte, Frank E. Welsh
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Patent number: 7192996Abstract: A method and apparatus for manufacturing small batches of solid paint is disclosed, which method includes a first step of providing a component of the solid paint as a liquid in a heated mixing container that has a base and sides and includes a stirrer for stirring the contents of the container. The next step of the method includes controlling, heating and stirring of the contents of the container and progressively adding other components of the solid paint as solids to the container. The liquid acts as a heat transfer medium that transfers heat from the heated container and from the stirrer to the solids. The mix is heated to a temperature of the solid paint and forms a melt that is a uniform liquid. The final step in the method includes discharging the melt from the container and allowing the melt to cool and form the solid paint.Type: GrantFiled: December 12, 2001Date of Patent: March 20, 2007Assignee: BHP Steel (JLA) Pty. Ltd.Inventor: Garry Michael McKay
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Patent number: 7182997Abstract: The invention relates to an opaque, white film with a thickness of from 10 to 500 ?m whose principal constituent is a crystallizable thermoplastic. The film comprises at least barium sulfate and at least one optical brightener. The barium sulfate and/or the optical brightener are incorporated directly into the crystallizable thermoplastic or are fed as a masterbatch during film production. At least one surface of the film bears a functional coating with a thickness of from 5 to 100 nm, in order to confer on the film surface an additional function such as sealability, printability, metallizability, sterilizability, antistatic properties, aroma barrier properties or improved adhesion to materials which would not adhere to the film surface without the coating, for example photographic emulsions.Type: GrantFiled: February 8, 2001Date of Patent: February 27, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Klaus Oberlaender
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Patent number: 7160939Abstract: A compound permitting the economic production of packaging containers, which when activated produces concentrated amounts of CO2 gas for extended periods for preservation of perishable products therein, comprises a mixture including a CO2 generating portion incorporated within a polymer matrix. Preferably, the mixture includes citric acid; calcium carbonate, and polyethylene resin. More preferably, the mixture includes a mixture of a carboxylic acid (0.1–40%); a hydrogen carbonate (0.1–40%) and any polyolefin resin. Even more preferably, the mixture includes a mixture including (0.01–40%) Citric Acid; (0.01–40%); and 30–75% polyethylene resin. Most preferably, the mixture includes by weight 12% citric acid; 38% calcium carbonate; and 50% low density polyethylene resin with a melt index of 20 and a density of 0.924 g/cc. Alternatively, the carboxylic acid and hydrogen carbonate components are compounded into separate polymer matrixes, and later combined.Type: GrantFiled: June 29, 2004Date of Patent: January 9, 2007Inventors: Michael J. Finnegan, Wesley L. Boldt
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Patent number: 7153895Abstract: Disclosed are methods for the formation of a rubber/filler/curative/plasticizer compacted masterbatch which may be performed in two ways. In one embodiment, a rubber and a filler are intimately mixed for a time and under shear conditions sufficient to form a free flowing associated composition, then the composition is mixed with a plasticizer and a curative to form the compacted masterbatch. Alternatively, the starting material may be an already-formed free flowing associated composition of rubber, filler and optional curative, which is mixed with a plasticizer and optional curative to form the compacted masterbatch.Type: GrantFiled: September 12, 2001Date of Patent: December 26, 2006Assignee: Uniroyal Chemical Company, Inc.Inventors: Joseph M. Hochheiser, Emmanuel G. Kontos, Richard W. Tomlinson
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Patent number: 7135514Abstract: The present invention provides a method and product that provides a dust-free homogeneous dispersion of zinc diacrylate in polybutadiene for use in golf balls. More specifically, the invention relates to a dispersion of zinc diacrylate in a special high-cis grade of polybutadiene commonly used by golf ball manufacturers. We have found that such a dispersion of ZDA can be made by using specific processing promoters, which not only allow the manufacture of the predispersion, but have a beneficial effect on the final properties of the golf ball. The processing promoters of the present invention enable more uniform dispersion of the ZDA into the polymer matrix, eliminate sticking to the mixer rotors, provide improved extrusion and pelletizing rates, as well as function as a separant to greatly minimize, if not totally eliminate, massing of the pelletized product.Type: GrantFiled: October 28, 2002Date of Patent: November 14, 2006Assignee: Rhein Chemie CorporationInventor: Anders H. Johansson
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Patent number: 7122586Abstract: The invention relates to preparation of silica-rich rubber compositions by a sequence of sequential mixing steps conducted in internal rubber mixer(s) with individual maximum temperature limitations. The mixing steps are comprised of at least two non-productive mixing steps followed by a productive mixing step. The non-productive mixing steps themselves are comprised of at least one preliminary non-productive mixing step followed by a final non-productive mixing step. Elastomer, silica and coupling agent are added in at least one of said preliminary non-productive mixing steps to the exclusion of said final non-productive mixing step and said productive mixing step. Sulfur and sulfur vulcanization accelerator(s) are added in said productive mixing step to the exclusion of said non-productive mixing steps. The preliminary non-productive mixing step(s) are individually conducted to a maximum mixing temperature in a range of from about 150° C.Type: GrantFiled: March 14, 2003Date of Patent: October 17, 2006Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, John Eugene Varner, Bernard Matthew Bezilla, Jr.
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Patent number: 7119134Abstract: A method of making a polymeric compound with nanofiller of a predetermined grade. The method includes the steps of providing a base grade of the polymeric material, and mixing a nanofiller concentrate material with the base grade polymeric material in a ratio sufficient to render the predetermined grade of filled polymeric compound, the ratio being nanofiller concentrate material to base grade polymeric material. A method for making the nanofiller concentrate material includes the steps of mixing a high flow carrier resin and a nanofiller to form a mixture, extruding the mixture, and pelletizing the extruded mixture. The mixture may advantageously include colorants, such as pigments or dyes.Type: GrantFiled: December 13, 2002Date of Patent: October 10, 2006Assignee: General Motors CorporationInventors: David Bruce Reed, Robert A. Ottaviani
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Patent number: 7091264Abstract: A method for improving the feel and rebound velocity of a golf ball, the method comprising preparing a golf ball from a rubber composition that comprises a rubber, from about 3 to about 12 parts by weight of a processing additive per 100 parts by weight rubber, from about 18 to about 32 parts by weight of a multi-functional crosslinking agent per 100 parts by weight rubber, from about 0.2 to about 1.0 parts by weight of a cure initiator per 100 parts by weight rubber, from about 0 to about 25 parts by weight zinc oxide per 100 parts by weight rubber, and from about 0 to about 0.Type: GrantFiled: April 25, 2003Date of Patent: August 15, 2006Assignee: Firestone Polymers, LLCInventors: Daniel F Graves, Mitch Barry
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Patent number: 7090915Abstract: The present invention relates to an opaque, white UV-stabilized low-flammability film with a thickness of from 10 to 500 ?m whose principal constituent is a crystallizable thermoplastic. It also comprises at least barium sulfate as pigment, at least one flame retardant, at least one UV stabilizer as light stabilizer and at least one optical brightener. The barium sulfate and/or the optical brightener and/or the flame retardant and/or the UV stabilizer here is either incorporated directly into the thermoplastic when the polymer is prepared or fed to the thermoplastic as a masterbatch during film production.Type: GrantFiled: January 22, 2001Date of Patent: August 15, 2006Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Klaus Oberlaender
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Patent number: 7053137Abstract: A process for producing cured rubber is disclosed wherein the process comprises: A) mixing rubber, carbon black, and azodicarbonamide without other curative ingredients; B) adding the remaining curative ingredients in one or more subsequent mixing steps; and then C) curing the rubber; whereby a cured rubber having improved hysteresis is obtained. The cured rubber thus obtained is particularly useful in tires and tire treads.Type: GrantFiled: February 4, 2003Date of Patent: May 30, 2006Assignee: Uniroyal Chemical Company, Inc.Inventors: Joseph F. Stieber, Martin J. Hannon
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Patent number: 7045202Abstract: A long glass fiber filler reinforced resin material for molding includes a masterbatch formed of a composite of a matrix resin with a polypropylene (PP) component and a long glass fiber filler and a diluent resin made from an ethylene-propylene block copolymer. The above-described matrix resin of the masterbatch includes the PP component having a pentad isotactic index of at least 95%, and a melt flow rate (MFR) of the matrix resin of the masterbatch is 100 to 500 g/10 min and larger than six times a melt flow rate of the diluent resin. The long glass fiber filler is in a content of 30 to 50 mass percent with respect to a total mass thereof.Type: GrantFiled: January 28, 2003Date of Patent: May 16, 2006Assignee: Mazda Motor CorporationInventors: Chikara Tanaka, Takahiro Tochioka
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Patent number: 7019050Abstract: Concentrates and method of making concentrates are disclosed. The concentrates may be incorporated into thermoformable articles as a concentrate powder or as a paste. Thermoformable articles, such as fibers, containing the concentrates and methods of making the thermoformable articles are also disclosed.Type: GrantFiled: July 3, 2003Date of Patent: March 28, 2006Assignee: BASF CorporationInventors: Frank R. Jones, Stanley A. McIntosh, Gary W. Shore
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Patent number: 7019084Abstract: The present invention relates to the preparation of rubber compositions for tire tread and tire sidewall component applications. A tire is provided having tread of such composition designed for relatively heavy loads such as, for example, truck tires. A tire having a sidewall of such composition is also provided. Such tire component rubber compositions are of rubber compositions reinforced with precipitated silica and selected carbon black in specified amounts and prepared with a prescribed order of addition to the rubber composition and composed of elastomers as a specific combination of high trans styrene-butadiene rubber with natural or synthetic cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber.Type: GrantFiled: December 11, 2002Date of Patent: March 28, 2006Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul Harry Sandstrom
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Patent number: 7019063Abstract: The rubber composition of the present invention is used for producing an inner liner of a pneumatic tire, and is obtained by compounding a rubber component and a layered or plate-like mineral. The layered or plate-like mineral has an aspect ratio of 3 or more and less than 30. The present invention further provides a production method of the rubber composition and a pneumatic tire which is produced by using the rubber composition. The present invention is applicable to a tire of passenger vehicles, bus or truck, and a tire of airplane. According to the present invention, the air permeation resistance is remarkably improved and the workability is also improved. Therefore, the rapture and hole defect of a non-vulcanized sheet during the tire construction can be avoided. By using the rubber composition, the gauge of the inner liner of pneumatic tire can be reduced while maintaining the inner pressure of tire, thereby reducing the weight of tire.Type: GrantFiled: February 28, 2001Date of Patent: March 28, 2006Assignee: Bridgestone CorporationInventors: Ichiro Wada, Masashi Ohara, Osamu Uchino, Toshiaki Koura, Naofumi Ezawa, Motoaki Kanoh, Yasuyoshi Kawaguchi, Shun Nakamura
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Patent number: 7008978Abstract: A process is described for the modification of polymer melts by means of finely divided inorganic solid particles (melt modification process), in which a powdery additive which contains the inorganic solid particles with a maximum particle size of 1 ?m embedded in finely divided form in a matrix of an organic substance, the organic substance containing one or more of the substances from the group consisting of polyols, polyglycols, polyethers, dicarboxylic acids and derivatives thereof, AH salt, caprolactam, paraffins, phosphoric acid esters, hydroxycarboxylic acid esters and cellulose, is incorporated into the polymer.Type: GrantFiled: October 5, 2001Date of Patent: March 7, 2006Assignee: Sachtleben Chemie GmbHInventors: Franz Meyers, Jurgen Kastner, Michael Wedler, Peter Weiser
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Patent number: 7001937Abstract: A process for the production of a colored resin composition, comprising a step (A) of producing an aqueous slurry of a pigment, a step (B) of producing a melting composition of metallocene type polyolefin containing a dispersant and a solvent, a step (C) of kneading the aqueous slurry obtained in the step (A) with the melting composition obtained in the step (B) and a step (D) of removing the solvent and the water from the kneaded mixture obtained in the step (C), a colored composition obtained in the above process has excellent in pigment dispersibility and high color developing properties, a colored resin molded article obtained from the colored resin composition do not give a physical-properties inhibition of 5% or higher and has a color developing properties.Type: GrantFiled: February 14, 2002Date of Patent: February 21, 2006Assignee: Toyo Ink Mfg. Co., Ltd.Inventors: Hitoshi Maki, Masayasu Kawamura, Masashi Koide
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Patent number: 6998433Abstract: Polyolefin-based pallets capable of passing standard pallet flammability tests are prepared by molding the pallet or one or more subassemblies thereof, of a polyolefin molding resin containing a flame retardant package containing magnesium hydroxide, and optionally alumina trihydrate, and zinc borate. The flame retardants may be supplied as a master batch at a concentration higher than that desired in the pallet or subassembly, in a polyolefin-compatible polymer, and result in pallets having a significantly lower heat release rate.Type: GrantFiled: February 27, 2003Date of Patent: February 14, 2006Assignee: Rehig Pacific CompanyInventors: Trenton M. Overholt, Justin M. Smyers
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Patent number: 6953815Abstract: The present invention provides a highly economical process for production of an inorganic filler-containing polyolefin resin composition, and a production apparatus to be used for the process, whose process is characterized by carrying out a continuous series of steps from an olefin polymerization step up to a kneading/pelletizing step wherein the polyolefin resin obtained by the polymerization step is kneaded and pelletized with an inorganic filler and various additives.Type: GrantFiled: April 4, 2002Date of Patent: October 11, 2005Inventors: Takehiko Enomoto, Tamio Serita
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Patent number: 6939600Abstract: The present invention relates to an opaque, white film with a thickness of from 10 to 500 ?m whose principal constituent is a crystallizable thermoplastic. It also comprises at least barium sulfate and at least one optical brightener. The barium sulfate and/or the optical brightener here is either incorporated directly into the thermoplastic during preparation of the polymer or fed as a masterbatch during film production. The novel film is particularly suitable for interior decoration, for constructing exhibition stands, for exhibition requisites, for displays, for placards, for labels, for protective glazing of machines or of vehicles, in the lighting sector, in the fitting out of shops or of stores, as a promotional requisite or a laminating material, or in applications associated with food or drink.Type: GrantFiled: May 5, 2003Date of Patent: September 6, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Klaus Oberlaender, Gottfried Hilkert
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Patent number: 6939902Abstract: A hydrocarbon-soluble drag-reducing suspension is described, along with a process for manufacturing the drag-reducing suspension. The drag-reducing suspension is easily transportable, non-hazardous, easily handled, and provides a significant increase in drag-reducing capability over existing products. The drag-reducing suspension is manufactured by grinding an ultra-high molecular weight polymer in the presence of a grinding aid and mixing it with a suspending fluid.Type: GrantFiled: September 27, 2002Date of Patent: September 6, 2005Assignee: ConocoPhillips CompanyInventors: Kenneth W. Smith, Stuart N. Milligan, Ray L. Johnston
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Patent number: 6908958Abstract: An organically modified layered clay ionically bonded with an organic compound having an ammonium group and an amino group, an organic polymer composition containing the same and an organic polymer capable of reacting with the amino group, and an inner liner using the same.Type: GrantFiled: March 26, 2003Date of Patent: June 21, 2005Assignee: The Yokohama Rubber Co., Ltd.Inventors: Tsukasa Maruyama, Kazunori Ishikawa, Naoya Amino, Masahiro Ikawa
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Patent number: 6881781Abstract: A non-toxic malleable, bounceable modeling compound stretchable in a manner similar to chewing gum which is particularly suitable for children. The compound is comprised essentially of a butyl rubber, vulcanized vegetable oil, one or more softening agents, an inorganic filler material, antioxidant and binder. The pliable compound can retain a molded shape for years and is an ideal sculpting material, stress reliever, and aid for improving dexterity. The compound is produced according to a tri-phase process that does not require heating or baking.Type: GrantFiled: December 1, 2003Date of Patent: April 19, 2005Assignee: The Wingum CompanyInventor: Guillermo Gamba
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Patent number: 6875805Abstract: An acrylic material which is flame retardant comprises 4.9 to 94.9% by wt of an acrylic composition, 5-95% by wt of a halogen-containing polymer, especially PVC, and 0.1-25% by wt of an inorganic composition comprising at least one of an oxide, hydroxide, carbonate, borate, stearate, chloride or bromide, zinc, magnesium, molybdenum, antimony, aluminum, tin, copper, manganese, cobalt or iron.Type: GrantFiled: May 29, 2003Date of Patent: April 5, 2005Assignee: Lucite International UK LimitedInventors: Paul Eustace, Neil Andrew McCathy, Nicholas John Marston
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Patent number: 6849677Abstract: Polyolefin-based pallets capable of passing standard pallet flammability tests are prepared by molding the pallet or one or more subassemblies thereof, of a polyolefin molding resin containing a flame retardant package containing a halogenated organic flame retardant, alumina trihydrate, and antimony trioxide. The flame retardants are advantageously supplied as a master batch at a concentration higher than that desired in the pallet or subassembly, in a polyolefin-compatible polymer.Type: GrantFiled: September 17, 2002Date of Patent: February 1, 2005Assignee: Rehrig Pacific CompanyInventor: Trenton M. Overholt
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Patent number: 6828361Abstract: A method for making a silicic acid containing rubber base composition includes providing composition ingredients of rubber, silicic acid, silane and additional additives except for vulcanization ingredients. First and second mixers separate from each other are provided wherein the ingredients except for the vulcanization ingredients can be mixed. All of the composition ingredients are introduced into the first mixer except for the vulcanization ingredients simultaneously or at time intervals. The composition ingredients introduced into the first mixer are mixed to a composition. The composition formed in the first mixer is transferred directly into the second mixer without an intermediate storage thereof. The transferred composition formed in the first mixer is mixed at least almost to completion in the second mixer with the temperature lying in the temperature range of 130° C. to 180° C.Type: GrantFiled: December 10, 2001Date of Patent: December 7, 2004Assignees: Continental AktiengesellschaftInventors: Julius Peter, Winfried Heidrich, Dirk Gross, Heinrich Sandau
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Patent number: 6825251Abstract: A unique treatment for pigments is provided. This treatment, which uses certain organo-acid phosphate molecules, imparts improved physical and chemical qualities including lacing resistance, improved dispersion and decreased chemical reactivity when these treated pigments are incorporated into polymeric matrices.Type: GrantFiled: August 13, 2003Date of Patent: November 30, 2004Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Modasser El-Shoubary, Robert J. Kostelnik
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Patent number: 6815473Abstract: The present invention relates to a cross-linkable or cross-linked rubber composition having improved hysteresis properties in the cross-linked state which is useful for constituting a tire tread, to a process for preparation of such a cross-linkable composition, to a tread of this type and to a tire having reduced rolling resistance. The rubber composition according to the invention is based on: an elastomeric matrix comprising at least one diene elastomer which comprises a carboxylic acid function at one or at each of its two chain ends, and a reinforcing filler comprising a reinforcing inorganic filler, wherein said diene elastomer has a molecular weight which is greater than 80,000 g/mol, and it is present in a majority quantity in said elastomeric matrix.Type: GrantFiled: January 23, 2002Date of Patent: November 9, 2004Assignee: Michelin Recherche Et Technique S.A.Inventors: Pierre Robert, Jean-Michel Favrot, Corinne Fradin-Cohas
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Patent number: 6806302Abstract: The invention relates to a process for the continuous production of liquid coating compositions by introducing one or more low-solvent or solvent-free binders in a solid or molten state into an extruder in one stage, together with pigments and auxiliaries, wherein the components are mixed and dispersed at elevated temperature in a viscous state, then introducing proportions of binders and proportions or organic or inorganic solvents into the extruder in one or more following stages, discharging the mixture from the extruder and adding further solvents and optionally further components of the coating composition and homogenizing the process mixture in one or more rotor/stator mixers.Type: GrantFiled: June 13, 2001Date of Patent: October 19, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Evert Kramer, Friedrich Domke
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Patent number: 6797749Abstract: The invention provides a powder coating composition in which powder particles are an agglomerate of individual particulate components fused or bonded together into composite particles. Maximizing the amount of larger-sized uncolored component(s) gives cost advantages, and the invention allows a rapid and flexible manufacture of a range of colored powder coating compositions.Type: GrantFiled: December 11, 2001Date of Patent: September 28, 2004Assignee: International Coatings LimitedInventor: Andrew George Cordiner
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Patent number: 6794432Abstract: The invention concerns transparent, flame-retardant, single layered or multilayered thermoformable films, containing a crystallizable thermoplastic material, preferably polyethyleneterephthalate, and at least one flame retarding agent as main components. Said films are characterized by good stretchability, thermoformability and good mechanical and optical properties, which makes them and the shaped bodies made from said films suitable for both inner and outer applications.Type: GrantFiled: July 18, 2002Date of Patent: September 21, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass